Corrosion Types and Rust-Preventive Coatings

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    Corrosion Types and

    Rust-PreventiveCoatings

    Preparing byEfekan BakIR

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    Contents

    Definition of Corrosion

    Types of Corrosion

    Definition of Rust

    Prevention of Rust

    Rust-Preventive Coatings

    Conclusion References

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    What is the Corrosion ?

    Corrosion is the gradual destruction of material, usuallymetals, by chemical reaction with its environment. In the most

    common use of the word, this means electrochemical oxidation of

    metals in reaction with an oxidant such as oxygen. Rusting, the

    formation of iron oxides, is a well-known example of

    electrochemical corrosion.

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    This type of damage typically produces oxide or salt of the

    original metal. Corrosion can also occur in materials other thanmetals, such as ceramics or polymers, although in this context, the

    term degradation is more common. any types and causes of

    corrosion and depending on a particular scientist's or corrosion

    engineer's tendencies to look upon the subject more broadly or

    narrowly there is no clear and exact total for the number ofcorrosion types. Most corrosion experts however can agree on the

    basic varieties of corrosion listed and described.

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    As a result, methods to reduce the activity of the exposedsurface, such as passivation and chromate conversion, can increase

    a material's corrosion resistance. However, some corrosion

    mechanisms are less visible and less predictable.

    Example of Corrosion

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    Types of Corrosion

    Corrosion comes in many different forms and can be classified

    by the cause of the chemical deterioration of a metal. Listed beloware 8 common types of corrosion:

    Galvanic Corrosion, Environmental Cracking, Erosion

    Corrosion , Intergranular corrosion, De-Alloying, Fretting corrosion,

    Pitting Corrosion,High-Temperature Corrosion.

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    Fretting corrosion

    Fretting corrosion refers to corrosion damage at the asperities

    of contact surfaces. This damage is induced under load and in the

    presence of repeated relative surface motion, as induced for

    example by vibration. Pits or grooves and oxide debris characterize

    this damage, typically found in machinery, bolted assemblies and

    ball or roller bearings. Contact surfaces exposed to vibration during

    transportation are exposed to the risk of fretting corrosion.

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    Galvanic Corrosion

    When dissimilar metals are connected in the presence of an

    electrolyte a galvanic corrosion reaction occurs. Both the presenceof an electrolyte solution and a bi-metallic coupling is required for

    this type of corrosion to occur.

    Example of Galvanic Corrosion

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    Environmental Cracking

    Environmental cracking is a corrosion process that can result

    from a combination of environmental conditions affecting the

    metal. Chemical, temperature and stress-related conditions canresult in the following types of environmental corrosion:

    Stress Corrosion Cracking (SCC)

    Corrosion fatigue

    Hydrogen-induced cracking Liquid metal embrittlement

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    Erosion Corrosion

    Erosion corrosion is an acceleration in the rate of corrosion

    attack in metal due to the relative motion of a corrosive fluid and a

    metal surface. The increased turbulence caused by pitting on the

    internal surfaces of a tube can result in rapidly increasing erosion

    rates and eventually a leak. Erosion corrosion can also be

    aggravated by faulty workmanship. For example, burrs left at cut

    tube ends can upset smooth water flow, cause localized turbulence

    and high flow velocities, resulting in erosion corrosion. A

    combination of erosion and corrosion can lead to extremely high

    pitting rates.

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    Intergranular corrosion

    The microstructure of metals and alloys is made up of grains,

    separated by grain boundaries. Intergranular corrosion is localized

    attack along the grain boundaries, or immediately adjacent to grain

    boundaries, while the bulk of the grains remain largely

    unaffected. This form of corrosion is usually associated with

    chemical segregation effects (impurities have a tendency to be

    enriched at grain boundaries) or specific phases precipitated on the

    grain boundaries. Such precipitation can produce zones of reduced

    corrosion resistance in the immediate vicinity.

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    De-Alloying

    Dealloying or selective leaching refers to the selective removal

    of one element from an alloy by corrosion processes. A common

    example is the dezincification of unstabilized brass, whereby a

    weakened, porous copper structure is produced.

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    High-Temperature Corrosion

    Under very high temperature metals need only the presence

    of oxygen or other oxidizing gases to corrode. This type of corrosionis referred to as high temperature oxidation, scaling or tarnishing

    and requires neither moisture nor dissolved electrolytes (salts,

    acids) to proceed.

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    Definition of Rust

    Rust is another name for iron oxide, which occurs when iron or

    an alloy that contains iron, like steel, is exposed to oxygen and

    moisture for a long period of time. Over time, the oxygen combineswith the metal at an atomic level, forming a new compound called

    an oxide and weakening the bonds of the metal itself. Although

    some people refer to rust generally as "oxidation," that term is

    much more general; although rust forms when iron undergoes

    oxidation, not all oxidation forms rust. Only iron or alloys thatcontain iron can rust, but other metals can corrode in similar ways.

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    Prevention of RustBecause of the widespread use and importance of iron and steelproducts, the prevention or slowing of rust is the basis of major

    economic activities in a number of specialized technologies. A briefoverview of methods is presented here; for detailed coverage, seethe cross-referenced articles.

    Rust is permeable to air and water, therefore the interior metalliciron beneath a rust layer continues to corrode. Rust prevention thusrequires coatings that preclude rust formation.

    There are kinds 7 of prevention

    of rust : Rust-resistant alloys, Galvanization,

    Cathodic protection, Coatings and painting,

    Bluing, Inhibitors, Humidity control

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    Rust-Preventive Coatings

    Stop rust before it starts with water based rust preventive dip

    coating. In just one coat, corrosion control is achieved by using

    water based rust proofing that contains a balanced rust inhibitor

    system. This rust prevention product is a cream colored liquid when

    applied but upon drying turns to a translucent light brown dry to

    the touch wax coating. Dyes can be added if color coding is desired.

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    This corrosion resistant coatings will not transfer, abrade or

    run under normal handling. Therefore neither the floor of your

    packaging area, storage bins or the packages you send to yourcustomers will be oil stained and messy. Some materials active rust

    inhibitor system neutralizes metal corrosion normally attributed to

    fingerprints from parts handling. This protective coating and its rust

    inhibitor system are compatible with lube oil so they do not need to

    be removed from internal parts before assembly.

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    Rust formation can be controlled with coatings, such as paint,

    lacquer, or varnish that isolate the iron from the environment. Large

    structures with enclosed box sections, such as ships and modern

    automobiles, often have a wax-based product (technically aslushing oil) injected into these sections. Such treatments usually

    also contain rust inhibitors. Covering steel with concrete can

    provide some protection to steel because of the alkaline pH

    environment at the steel-concrete interface. However rusting of

    steel in concrete can still be a problem, since expanding rust can

    fracture or slowly "explode" concrete from within.

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    Conclusion

    Corrosion comes in many different forms and can be classified

    by the cause of the chemical deterioration of a metal. However,some corrosion mechanisms are less visible and less predictable.

    Rusting, the formation of iron oxides, is an example of

    electrochemical corrosion. Rust-Preventive Coatings is a well-known

    method for preventing the rust.

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    References

    http://www.corrosion-doctors.org/pict-type.htm

    http://www.counteractrust.com/types%20of%20corrosion.htm http://metals.about.com/od/metallurgy/a/Types-Of-Corrosion.htm

    http://www.corrosionist.com/Corrosion_Types_Uniform_Corrosion.

    htm

    http://en.wikipedia.org/wiki/Corrosion

    http://www.tis-gdv.de/tis_e/misc/korro.htm

    http://www.authorstream.com/Presentation/hitiboy-410714-

    corrosion-hiti-science-technology-ppt-powerpoint/

    http://www.sanchem.com/safegard_uses.html

    http://en.wikipedia.org/wiki/Rust#Prevention

    http://www.metaltreaters.net/rust-preventives.html