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Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2018.
Supporting Information
for Adv. Funct. Mater., DOI: 10.1002/adfm.201802016
Finely Crafted 3D Electrodes for Dendrite-Free and High-Performance Flexible Fiber-Shaped Zn–Co Batteries
Ming Li, Jiashen Meng, Qi Li,* Meng Huang, Xiong Liu,Kwadwo Asare Owusu, Ziang Liu, and Liqiang Mai*
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Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2018.
Supporting Information
Finely-Crafted 3D Electrodes for Dendrite-Free and High-Performance Flexible Fiber-
Shaped Zn-Co Battery
Ming Li, Jiashen Meng, Qi Li*, Meng Huang, Xiong Liu, Kwadwo Asare Owusu, Ziang Liu,
Liqiang Mai*
Mr. M. Li, Mr. J. S. Meng, Prof. Q. Li, Mr. M. Huang, Mr. X. Liu, Mr. K. A. Owusu, Mr. Z.
Liu, Prof. L. Q. Mai
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,
Wuhan University of Technology, Hubei, Wuhan 430070, P. R. China
E-mail: [email protected]; [email protected]
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Figure S1. Schematic illustration of the synthesis process of CC-ZnO@C-Zn anode.
Figure S2. XRD patterns of a) CC-ZnO and b) CC-ZnO@ZIF. c) FT-IR spectra of 2-
methylimidazole, CC-ZnO@ZIF-8, CC-ZnO and CC-ZnO@C.
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Figure S3. Schematic illustration of the synthesis process of the CC-CCH@CMO cathode.
Figure S4. Optical photographs of as prepared samples. From left to right in turn are bare CC,
CC-ZnO, CC-ZnO@C, CC-CCH and CC-CCH@CMO, respectively.
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Figure S5. SEM images of a,b,c) CC-ZnO and d,e,f) CC-CCH.
Figure S6. SEM images of ZIF-derived carbon tubes on CC.
Figure S7. a) XPS full spectrum, b) Zn 2p spectrum and c) N 1s spectrum of CC-ZnO@C.
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Figure S8. SEM image together with the corresponding elemental mapping images of CC-
ZnO@C.
Figure S9. Raman plots of CC-ZnO@C and CC-ZnO.
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Figure S10. The XRD patterns of a) CC-CCH, b) CC-CCH@CMO and c) CC-
Co3O4@CoMoO4. d) XPS full spectra of CC-CCH@CMO and CC-CCH. e) Mo 3d spectrum,
f) Co 2p spectrum of CC-CCH@CMO.
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Figure S12. Cycling performance of aqueous Zn-Co full battery using the Zn plate as the
anode at 40 mA cm-2
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Figure S13. The current-time (i-t) curves of CC and CC-ZnO@C, and corresponding SEM
images after Zn deposition.
Figure S14. Comparison of the EIS results of CC-ZnO@C-Zn, CC-ZnO@C, and Zn plate.
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Figure S15. a) CV curves, and b) charge-discharge curves of CC-CCH. c) EIS results of CC-
CCH@CMO and CC-CCH.
Figure S16. a) Charge-discharge curves, b) CV curves of aqueous Zn-Co full battery using
the CC-CCH as the cathode.
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Figure S17. Charge-discharge curves of the initial and the last several cycles during the
cycling test.
Figure S18. Cycling performance of the aqueous Zn-Co full battery using CC-ZnO@C-Zn as
the anode and CC-CCH@CMO as the cathode at 40 mA cm-2
.
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Figure S19. SEM images of 3D skeleton after 1500 cycles at 40 mA cm-2
.
Figure S20. a) Cycling performance of aqueous Zn-Co battery using CC-Zn as anode at 40
mA cm-2
. The inset images are the SEM images of CC-Zn anode after cycling test.
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Figure S21. EIS results of Zn-Co battery using aqueous electrolyte (6 M KOH with 1.5 M
ZnO) and solid-state (PVA-KOH) electrolyte.
Figure S22. The capacity of fiber-shaped Zn-Co battery under various deformation states.
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Figure S23. The capacity of fiber-shaped Zn-Co battery under a number of bending tests.
Figure S24. Galvanostatic discharge curves of a three-in-series battery. The inset digital
image is the voltage output of the three-in-series batteries.
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Figure S25. a) A digital watch was powered by two-in-series battery. b) A digital watch was
powered by a bracelet battery.
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Table S1. Comparison of our Zn-Co battery with other aqueous batteries reported before.
Aqueous Batteries
Active
material
Mass (mg)
Specific
Capacity
(mAh g-1
)
Capacity
Retention
(%)
Power
Density
(kW kg-1
)
Energy
Density
(Wh kg-1
)
Ni-Zn battery
(CC-
CF@NiO//CC-
CF@ZnO)[1]
1.92 203
72.9%
(2400
cycles)
17.9 355.7
Ni-Zn battery
(NiAlCo
LDH/CNT//Zn)[2]
1.66 354 94% (2000
cycles) 16 274
Zn-Mn2 battery[3]
5.38 366.6 83.7% (300
cycles) 8.6 504
Ni-Fe battery
(CC-
CF@NiO//CC-
CF@Fe3O4)[4]
4.4 88.6 70.5 (2000
cycles) 1.2 94.5
Ni-based batteries
(GF/CNTs/Fe2O3-
Ni(OH)2)[5]
1.5 119
89.1%
(1000
cycles)
0.287 100.7
Ni-Bi battery
(Ni−Co LDH//
Bi2O3)[6]
2 110 93% (1000
cycles) 0.44 88.1
Ni-Zn battery
(Zn–NiO)[7]
Not
reported 155
65% (500
cycles) Not reported 228
Zn-ion batteries[8]
Not
reported 220
66.6% (35
cycles) Not reported
Not
reported
Na-Zn hybrid
aqueous battery[9]
Not
reported 76.2
81% (1000
cycles) Not reported 62.9
Zn//VS2
batteries[10]
Not
reported 190.3
98% (200
cycles) Not reported 123
Zn//Co3O4
Battery[11]
2 160
80% (2000
cycles) Not reported 241
Rocking-Chair
NH4-Ion
Battery[12]
Not
reported 158.9
67% (1000
cycles) Not reported 43
Aqueous Lithium-
Ion Battery[13]
Not
reported 40
82% (200
cycles) Not reported 60
Ni-Bi battery
(NiCo2O4//Bi)[14]
1.41 90
89% (1000
cycles) 21 85.8
Our work 4.98 143.2
71.1%
(5000
cycles)
12.6
(aqueous)
10.5
(solid-state)
235
(aqueous)
221.9
(solid-state)
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Table S2. Comparison of our flexible fiber-shaped Zn-Co battery with other reported before.
Flexible devices Power Density
(mW cm-3
)
Energy Density
(mWh cm-3
)
Ni-Zn battery[15]
82.2 2.1
MnO2//Fe2O3[16]
0.31 0.31
Ni/GF/H-
CoMoO4//Ni/GF/H-Fe2O3 [17]
150 1.13
CNTs//Fe3O4-C[18]
29 1.2
H-ZnO@MnO2
Symmetrical
supercapacitor[19]
2.44 0.04
TiN//Fe2N[20]
300 0.2
PEDOT paper[21]
52 1
Graphene//Co3O4[22]
1200 0.4
VOx//VN[23]
800 0.4
CoO@PPy//AC[24
] 100 1.3
TiO2@MnO2//TiO2@C[25]
210 0.5
MnO2//WON[26]
600 1.1
MnO2//Ti-
Fe2O3@PEDOT[27]
520 0.6
Fiber-Shaped
Ni–Zn Battery[28]
220 0.67
Our work 420 4.6
Reference
[1] J. Liu, C. Guan, C. Zhou, Z. Fan, Q. Ke, G. Zhang, C. Liu, J. Wang, Adv. Mater. 2016,
28, 8732.
[2] M. Gong, Y. Li, H. Zhang, B. Zhang, W. Zhou, J. Feng, H. Wang, Y. Liang, Z. Fan, J.
Liu, H. Dai, Energy Environ. Sci. 2014, 7, 2025.
[3] Y. Zeng, X. Zhang, Y. Meng, M. Yu, J. Yi, Y. Wu, X. Lu, Y. Tong, Adv. Mater. 2017, 29.
1700274.
[4] C. Guan, W. Zhao, Y. Hu, Q. Ke, X. Li, H. Zhang, J. Wang, Adv. Energy Mater.2016, 6,
1601034.
[5] J. Liu, M. Chen, L. Zhang, J. Jiang, J. Yan, Y. Huang, J. Lin, H. J. Fan, Z. X. Shen,
17
Nano Lett. 2014, 14, 7180.
[6] X. Li, C. Guan, Y. Hu, J. Wang, ACS Appl. Mater. Interfaces 2017, 9, 26008.
[7] X. Wang, M. Li, Y. Wang, B. Chen, Y. Zhu, Y. Wu, J. Mater. Chem. A 2015, 3, 8280.
[8] W. Kaveevivitchai, A. Manthiram, J. Mater. Chem. A 2016, 4, 18737.
[9] K. Lu, B. Song, J. Zhang, H. Ma, J. Power Sources 2016, 321, 257.
[10] P. He, M. Yan, G. Zhang, R. Sun, L. Chen, Q. An, L. Mai, Adv. Energy Mater. 2017, 7,
1601920.
[11] X. Wang, F. Wang, L. Wang, M. Li, Y. Wang, B. Chen, Y. Zhu, L. Fu, L. Zha, L. Zhang,
Y. Wu, W. Huang, Adv. Mater. 2016, 28, 4904.
[12] D. X. Wu, Y. Qi, J. J. Hong, Z. Li, A. S. Hernandez, P. X. Ji, Angew. Chem. Int. Ed.
2017, 129, 13206.
[13] J. Y. Luo, Y. Y. Xia, Adv. Funct. Mater. 2007, 17, 3877.
[14] Y. Zeng, Z. Lin, Y. Meng, Y. Wang, M. Yu, X. Lu, Y. Tong, Adv. Mater. 2016, 28, 9188.
[15] Z. Lu, X. Wu, X. Lei, Y. Li, X. Sun, Inorg. Chem. Front. 2015, 2, 184.
[16] P. Yang, Y. Ding, Z. Lin, Z. Chen, Y. Li, P. Qiang, M. Ebrahimi, W. Mai, C. P. Wong, Z.
L. Wang, Nano Lett. 2014, 14, 731.
[17] K. Chi, Z. Zhang, Q. Lv, C. Xie, J. Xiao, F. Xiao, S. Wang, ACS Appl. Mater.
Interfaces. 2017, 9, 6044.
[18] R. Li, Y. Wang, C. Zhou, C. Wang, X. Ba, Y. Li, X. Huang, J. Liu, Adv. Funct. Mater.
2015, 25, 5384.
[19] P. Yang, X. Xiao, Y. Li, Y. Ding, P. Qiang, X. Tan, W. Mai, Z. Lin, W. Wu, T. Li, ACS
nano 2013, 7, 2617.
[20] C. Zhu, P. Yang, D. Chao, X. Wang, X. Zhang, S. Chen, B. K. Tay, H. Huang, H.
Zhang, W. Mai, H. J. Fan, Adv. Mater. 2015, 27, 4566.
[21] B. Anothumakkool, S. N. Bhange, R. Soni, S. Kurungot, Energy Environ. Sci. 2015, 8,
1339.
[22] X. Wang, B. Liu, R. Liu, Q. Wang, X. Hou, D. Chen, R. Wang, G. Shen, Angew. Chem.
Int. Ed 2014, 53, 1849.
[23] X. Lu, M. Yu, T. Zhai, G. Wang, S. Xie, T. Liu, C. Liang, Y. Tong, Y. Li, Nano Lett.
2013, 13, 2628.
[24] C. Zhou, Y. Zhang, Y. Li, J. Liu, Nano Lett. 2013, 13, 2078.
[25] X. Lu, M. Yu, G. Wang, T. Zhai, S. Xie, Y. Ling, Y. Tong, Y. Li, Adv. Mater. 2013, 25,
267.
[26] M. Yu, Y. Han, X. Cheng, L. Hu, Y. Zeng, M. Chen, F. Cheng, X. Lu, Y. Tong, Adv.
Mater. 2015, 27, 3085.
[27] Y. Zeng, Y. Han, Y. Zhao, Y. Zeng, M. Yu, Y. Liu, H. Tang, Y. Tong, X. Lu, Adv.
Energy. Mater. 2015, 5, 1402176.
[28] Y. Zeng, Y. Meng, Z. Lai, X. Zhang, M. Yu, P. Fang, M. Wu, Y. Tong, X. Lu, Adv. Mater.
2017, 29, 1702698.