COLLEGE OF ENGINEERING Chemical, Biological ...

1
COLLEGE OF ENGINEERING Chemical, Biological & Environmental Engineering 0 5 10 15 20 Kelley Dissolved Kelley Total Fairbanks Dissolved Fairbanks Total Johnson Dissolved Johnson Total Milli-Q Copper (ppb) Influent Effluent 30% removal 0 50 100 150 200 250 300 Kelley Dissolved Kelley Total Fairbanks Dissolved Fairbanks Total Johnson Dissolved Johnson Total Milli-Q Zinc (ppb) Influent Effluent 60% removal Comparative Analysis of CONTECH StormFilters on OSU Campus Sam Albert, Maceo Gutierrez-Higgins, Jessalyn Imdieke* Conclusions & Observations Initial results show that filters are not consistently meeting desired TSS removal specifications Filter location/use may affect filter performance more than age Fairbanks and Johnson locations are difficult to sample due to submerged outlet pipe during nominal flow conditions Fairbanks location appears to be plugged, there is sludge buildup and bypass during storms smaller than design storm Kelley location operating below design flow rate of 15 gpm Recommendations Clean, maintain, and replace filter cartridges as needed Test filters throughout the Oregon wet season Future work Improve collection technique to reduce sludge disruption in outlet pipe or invest in automated sampler Determine method to estimate flow rates at the Johnson and Fairbanks locations Troubleshoot nitrates and total phosphates tests Determine if Fairbanks location is performing adequately during peak wet season Kelley, 2005/06 Fairbanks, 2013 Johnson, 2016 CONTECH Background CONTECH StormFilters are located around campus to remove contaminates from storm water. They use a ZPG Media blend of zeolite, perlite, and granular activated carbon to remove total suspended solids, and to a lesser extent some soluble metals and organics. We are testing three filter locations of various ages on campus: Kelley Engineering Center, Fairbanks Hall, and Johnson Hall. To our knowledge the filters have not undergone maintenance since installation. Suggested maintenance includes removing sludge from vault, replacing cartridges yearly or as needed, and performing monthly inspections during the wet-season. Our goal is to determine if OSU-installed CONTECH StormFilters meet local stormwater regulatory requirements as the system ages, and to propose any necessary mitigation. Acknowledgments Testing Methods Technical Assessment Protocol Ecology (TAPE) Testing Requirements* Influent Effluent goal Total suspended solids (TSS) < 100 ppm > 100 ppm < 20 ppm 80% removal Dissolved Copper 5 - 20 ppb 30% removal Dissolved Zinc 20 - 300 ppb 60% removal Total Phosphorous 0.1 - 0.5 ppm 50% removal EPA Industrial Stormwater Benchmark Nitrates - < 0.68 ppm Total Suspended Solids (TSS) SM 2450D Dissolved Metals (Zinc and Copper) SM 3030 E-2 Total Metals (Zinc and Copper) ICP-OES Nitrates SM 4500-NO3 B Total Phosphorus (TP) SM 4500-P B. 2 SM 4500-P E Sample W. M. Keck Collaboratory for Plasma Spectrometry http://www.lpdlabservices.co.uk/ Efficiency goals Preliminary Results Total Suspended Solids Dissolved and Total Metals Storm Information Figure 1. Schematic of a CONTECH StormFilter. Water enters under the filter hood, passes through the filter media for purification, and exits through the under-drain manifold. Design flow rate for an 18 inch tall cartridge is 7.5 gpm/filter. Figure 3. ICP-OES analysis for dissolved and total metals for A) copper and B) zinc in the influent and effluent for the April-11 th , April 25 th , and April 27 th storms. Error bars represent the standard deviation of N=3 storm samples for Kelley and N=2 storm samples for Fairbanks and Johnson Hall. Milli-Q water was processed as a control after passing through a 0.45 μm filter used for all samples, using the total metals digestion protocol. Technical Assistance Nathan Patterson, OSU Capital Planning and Development Dr. Tyler Radniecki, CBEE Dr. Meghna Babbar-Sebens, CCE Andy Brickman, CBEE John Cochran, CBEE Gary Hickman, CH2M Dr. Jeff Nason, CBEE Sarah Burch, CBEE Graduate student Project Sponsors Dave Eckert, Corvallis Sustainability Coalition OSU Capital Planning and Development Dr. Phil Harding, CBEE TAPE Technical Advisors Dr. Doug Howie, Washington State Department of Ecology Carla Milesi, University of Washington Tacoma Center for Urban Waters A B Figure 4. Team Photo by the Kelley Engineering Center storm filter. Picture by Dr. Harding. Figure 2. Total suspended solids for storms on A) April 11 th , B) April 25 th , C) April 27 th , D) May 11 th , E) May 12 th , F) May 16 th . Error bars represent the standard error of the mean for N=3 replicates per site; storm A has N=1 replicates for all samples except Fairbanks inlet (N=5). A green check mark represents that TSS TAPE requirements have been met for that site location. A red or “X” represents an event that did not pass the required removal of TSS by TAPE. Storm Date Time Interval Sampling Time Total Precipitation (inch) Locations Sampled 11-Apr 4:00 pm – 12:00 am 5:30 pm 0.40 Kelley, Fairbanks 25-Apr 3:00 am - 6:30 pm 6:00 pm 0.20 Kelley, Johnson 27-Apr 12:00 am - 3:00 pm 12:00 pm 0.07 ** Kelley, Fairbanks, Johnson 11-May 4:00 am - 12:00 pm 4:00 am 0.29 Kelley, Fairbanks, Johnson 12-May 12:00 pm - 3:00 pm 12:00 pm 0.07 ** Kelley, Fairbanks 16-May 12:00 am – 10:00 am 2:00 am 0.25 Kelley, Fairbanks, Johnson * TAPE testing requirements are from Washington State Department of Ecology Disclaimer: Results are preliminary. We have analyzed all storms, including those that do not meet the minimum storm intensity defined by TAPE. Do not draw final conclusions from our data. A B C 17.20 16.60 2.21 0.63 23.19 23.75 0 20 40 60 80 100 120 FAIR IN FAIR OUT KELLEY IN KELLEY OUT JOHN IN JOHN OUT Total Suspended Solids (ppm) INLET TSS > 100 ppm: 80% removal TSS INLET TSS < 100 ppm: OUTLET < 20 ppm FAIR: KELLEY: 2.5 2.3 23.4 16.7 0 20 40 60 80 100 120 KELLEY IN KELLEY OUT JOHN IN JOHN OUT Total Suspended Solids (ppm) INLET TSS > 100 ppm: 80% removal TSS INLET TSS < 100 ppm: OUTLET < 20 ppm 67.8 30.0 10.4 6.3 48.6 33.1 0 20 40 60 80 100 120 FAIR IN FAIR OUT KELLEY IN KELLEY OUT JOHN IN JOHN OUT Total Suspended Solids (ppm) INLET TSS < 100 ppm: OUTLET < 20 ppm INLET TSS > 100 ppm: 80% removal TSS 41.1 18.6 12.3 13.1 36.4 18.3 0 20 40 60 80 100 120 FAIR IN FAIR OUT KELLEY IN KELLEY OUT JOHN IN JOHN OUT Total Suspended Solids (ppm) INLET TSS > 100 ppm: 80% removal TSS INLET TSS < 100 ppm: OUTLET < 20 ppm 118.2 29.0 5.6 2.7 0 20 40 60 80 100 120 FAIR IN FAIR OUT KELLEY IN KELLEY OUT Ttotal Suspended Solids (ppm) INLET TSS > 100 ppm: 80% removal TSS INLET TSS < 100 ppm: OUTLET < 20 ppm D KELLEY: JOHN: FAIR: KELLEY: JOHN: FAIR: KELLEY: JOHN: FAIR: KELLEY: FAIR: KELLEY: JOHN: 22.87 14.19 10.50 4.38 0 20 40 60 80 100 120 FAIR IN FAIR OUT KELLEY IN KELLEY OUT Total Suspended Solids (ppm) INLET TSS > 100 ppm: 80% removal TSS INLET TSS < 100 ppm: OUTLET < 20 ppm D E F ** Does not meet minimum storm intensity of 0.15 inches/storm event

Transcript of COLLEGE OF ENGINEERING Chemical, Biological ...

Page 1: COLLEGE OF ENGINEERING Chemical, Biological ...

COLLEGE OF ENGINEERING Chemical, Biological & Environmental Engineering

0

5

10

15

20

KelleyDissolved

KelleyTotal

FairbanksDissolved

FairbanksTotal

JohnsonDissolved

JohnsonTotal

Milli-Q

Co

pp

er (

pp

b)

Influent

Effluent

30% removal

0

50

100

150

200

250

300

KelleyDissolved

KelleyTotal

FairbanksDissolved

FairbanksTotal

JohnsonDissolved

JohnsonTotal

Milli-Q

Zin

c (p

pb

)

Influent

Effluent

60% removal

Comparative Analysis of CONTECH

StormFilters on OSU CampusSam Albert, Maceo Gutierrez-Higgins, Jessalyn Imdieke*

Conclusions & Observations• Initial results show that filters are not consistently

meeting desired TSS removal specifications

• Filter location/use may affect filter performance

more than age

• Fairbanks and Johnson locations are difficult to

sample due to submerged outlet pipe during nominal

flow conditions

• Fairbanks location appears to be plugged, there is

sludge buildup and bypass during storms smaller than

design storm

• Kelley location operating below design flow rate of

15 gpm

Recommendations• Clean, maintain, and replace filter cartridges as

needed

• Test filters throughout the Oregon wet season

Future work• Improve collection technique to reduce sludge

disruption in outlet pipe or invest in automated

sampler

• Determine method to estimate flow rates at the

Johnson and Fairbanks locations

• Troubleshoot nitrates and total phosphates tests

• Determine if Fairbanks location is performing

adequately during peak wet season

Kelley, 2005/06 Fairbanks, 2013 Johnson, 2016

CONTECH

BackgroundCONTECH StormFilters are located around campus to

remove contaminates from storm water. They use a

ZPG™ Media blend of zeolite, perlite, and granular

activated carbon to remove total suspended solids, and

to a lesser extent some soluble metals and organics.

We are testing three filter locations of various ages on

campus: Kelley Engineering Center, Fairbanks Hall, and

Johnson Hall. To our knowledge the filters have not

undergone maintenance since installation. Suggested

maintenance includes removing sludge from vault,

replacing cartridges yearly or as needed, and

performing monthly inspections during the wet-season.

Our goal is to determine if OSU-installed CONTECH

StormFilters meet local stormwater regulatory

requirements as the system ages, and to propose any

necessary mitigation.

Acknowledgments

Testing Methods

Technical Assessment Protocol Ecology (TAPE) Testing Requirements*

Influent Effluent goal

Total suspended solids (TSS) < 100 ppm

> 100 ppm

< 20 ppm

80% removal

Dissolved Copper 5 - 20 ppb 30% removal

Dissolved Zinc 20 - 300 ppb 60% removal

Total Phosphorous 0.1 - 0.5 ppm 50% removal

EPA Industrial Stormwater Benchmark

Nitrates - < 0.68 ppm

Total Suspended Solids (TSS)

SM 2450D

Dissolved Metals(Zinc and Copper)

SM 3030 E-2

Total Metals(Zinc and Copper)

ICP-OES

NitratesSM 4500-NO3 B

Total Phosphorus (TP)SM 4500-P B. 2 SM 4500-P E

Sample

W. M. Keck Collaboratory for Plasma Spectrometry

http://www.lpdlabservices.co.uk/Efficiency goals

Preliminary Results Total Suspended Solids

Dissolved and Total Metals

Storm Information

Figure 1. Schematic of a CONTECH StormFilter. Water enters under

the filter hood, passes through the filter media for purification, and

exits through the under-drain manifold. Design flow rate for an 18

inch tall cartridge is 7.5 gpm/filter.

Figure 3. ICP-OES analysis for dissolved and total metals for A) copper and B) zinc in the influent and effluent for the April-11th, April 25th, and

April 27th storms. Error bars represent the standard deviation of N=3 storm samples for Kelley and N=2 storm samples for Fairbanks and Johnson

Hall. Milli-Q water was processed as a control after passing through a 0.45 µm filter used for all samples, using the total metals digestion protocol.

Technical Assistance

• Nathan Patterson, OSU Capital

Planning and Development

• Dr. Tyler Radniecki, CBEE

• Dr. Meghna Babbar-Sebens, CCE

• Andy Brickman, CBEE

• John Cochran, CBEE

• Gary Hickman, CH2M

• Dr. Jeff Nason, CBEE

• Sarah Burch, CBEE Graduate

student

Project Sponsors

• Dave Eckert, Corvallis

Sustainability Coalition

• OSU Capital Planning and

Development

• Dr. Phil Harding, CBEE

TAPE Technical Advisors

• Dr. Doug Howie, Washington

State Department of Ecology

• Carla Milesi, University of

Washington Tacoma Center for

Urban Waters

A B

Figure 4. Team Photo by the Kelley Engineering Center

storm filter. Picture by Dr. Harding.

Figure 2. Total suspended solids for storms on A) April 11th, B) April 25th, C) April 27th, D) May 11th, E) May 12th, F) May 16th.

Error bars represent the standard error of the mean for N=3 replicates per site; storm A has N=1 replicates for all samples

except Fairbanks inlet (N=5). A green check mark represents that TSS TAPE requirements have been met for that site

location. A red or “X” represents an event that did not pass the required removal of TSS by TAPE.

Storm Date Time Interval Sampling Time Total Precipitation (inch) Locations Sampled

11-Apr 4:00 pm – 12:00 am 5:30 pm 0.40 Kelley, Fairbanks

25-Apr 3:00 am - 6:30 pm 6:00 pm 0.20 Kelley, Johnson

27-Apr 12:00 am - 3:00 pm 12:00 pm 0.07 ** Kelley, Fairbanks, Johnson

11-May 4:00 am - 12:00 pm 4:00 am 0.29 Kelley, Fairbanks, Johnson

12-May 12:00 pm - 3:00 pm 12:00 pm 0.07 ** Kelley, Fairbanks

16-May 12:00 am – 10:00 am 2:00 am 0.25 Kelley, Fairbanks, Johnson * TAPE testing requirements are from Washington State Department of Ecology

Disclaimer: Results are preliminary. We have analyzed all storms,

including those that do not meet the minimum storm intensity defined

by TAPE. Do not draw final conclusions from our data.

A B C

17.20 16.60

2.21 0.63

23.19 23.75

0

20

40

60

80

100

120

FAIR IN FAIR OUT KELLEYIN

KELLEYOUT

JOHN IN JOHNOUT

Tota

l Su

spe

nd

ed

So

lid

s (p

pm

)

INLET TSS > 100 ppm:80% removal TSS

INLET TSS < 100 ppm:OUTLET < 20 ppm

FAIR: KELLEY:

2.5 2.3

23.416.7

0

20

40

60

80

100

120

KELLEY IN KELLEY OUT JOHN IN JOHN OUT

Tota

l Su

spe

nd

ed

So

lid

s (p

pm

)

INLET TSS > 100 ppm:80% removal TSS

INLET TSS < 100 ppm:OUTLET < 20 ppm

67.8

30.0

10.46.3

48.6

33.1

0

20

40

60

80

100

120

FAIR IN FAIR OUT KELLEY IN KELLEYOUT

JOHN IN JOHN OUT

Tota

l S

usp

en

de

d S

oli

ds

(pp

m)

INLET TSS < 100 ppm:OUTLET < 20 ppmINLET TSS > 100 ppm:80% removal TSS

41.1

18.612.3 13.1

36.4

18.3

0

20

40

60

80

100

120

FAIR IN FAIR OUT KELLEYIN

KELLEYOUT

JOHN IN JOHNOUT

Tota

l Su

spe

nd

ed

So

lid

s (p

pm

)

INLET TSS > 100 ppm: 80%removal TSS

INLET TSS < 100 ppm: OUTLET< 20 ppm

118.2

29.0

5.6 2.70

20

40

60

80

100

120

FAIR IN FAIR OUT KELLEY IN KELLEY OUT

Tto

tal

Susp

en

de

d S

oli

ds

(pp

m)

INLET TSS > 100 ppm:80% removal TSS

INLET TSS < 100 ppm:OUTLET < 20 ppm

D

KELLEY: JOHN: FAIR: KELLEY: JOHN:

FAIR: KELLEY: JOHN: FAIR: KELLEY: FAIR: KELLEY: JOHN:

22.87

14.1910.50

4.38

0

20

40

60

80

100

120

FAIR IN FAIR OUT KELLEY IN KELLEY OUT

Tota

l Sus

pend

ed S

olid

s (p

pm)

INLET TSS > 100 ppm: 80%removal TSSINLET TSS < 100 ppm:OUTLET < 20 ppm

D E F

** Does not meet minimum storm intensity of 0.15 inches/storm event