CoalConversionFactsCalculations

Alain DELOYE - Technical Services Manager

DST- BP 4114 76020 Rouen Cedex - F

CCooaall CCoonnvveerrssiioonn FFaaccttss && CCaallccuullaattiioonnss 1. Analysis basis

1.1 Definitions

As Received (AR): includes Total moisture (Tm) Air Dried (AD): includes Inherent moisture (Im) only Dry Basis (DB): excludes all Moisture Dry Ash Free (DAF): excludes all Moisture & Ash

The Proximate Analysis of any coal ie the % contents of Moisture, Ash (A), Volatile Matter (VM), Fixed Carbon (FC) - also Sulphur (S) and Calorific Value (CV) - can be expressed on any of the above bases.

1.2 Conversions

To obtain: Air Dry Dry Basis As Received

multiply

AR by: (100 - Im%) (100 - Tm%)

100 (100 - Tm%)

-

AD by: - 100

(100 - Im%) (100 - Tm%) (100 - Im%)

DB by: (100 - Im%)

100 -

(100 - Tm%) 100

Where Im: inherent moisture

Where Tm: total moisture

[For DAF, multiply DB by 100/(100-A)]



Example:

AR AD DB DAF

Tm 11.0 - - -

Im 2.0 2.0 - -

Ash (A) 12.0 13.2 13.5 -

VM 30.0 33.0 33.7 39.0

FC 47.0 51.8 52.8 61.0

Sulfur (S) 1.0 1.1 1.12 -

2. MASS

2.1 Units:

Metric ton (t) = tonne = 1,000 kilograms (= 2,204.6 lb) Imperial or Long ton (lt) = 1,016.05 kilograms (= 2,240 lb) Short (US) ton (st) = 907.19 kilograms (= 2,000 lb) 2.2 Conversions:

From long ton to metric ton multiply by 1.016 From metric ton to long ton multiply by 0.984206 From short ton to metric ton multiply by 0.9072

Mt - million tonnes Mtce - million tonnes of coal equivalent (= 0.697 Mtoe) Mtoe - million tonnes of oil equivalent

3. CALORIFIC VALUES (CV)

3.1 Units:

kcal/kg - Kilocalories per kilogram MJ/kg* - Megajoules per kilogram Btu/lb - British Thermal Units per pound * 1 MJ/kg = 1 Gigajoule/tonne (GJ/t)



3.2 Gross & Net Calorific Values:

Gross CV or 'upper heating value' is the CV under laboratory conditions.

Net CV or 'Net Effective Calories' (NEC) is the useful calorific value in boiler plant. The difference is essentially the latent heat of the water vapor produced.

3.3 Conversions – Units:

From kcal/kg to MJ/kg multiply by 0.004187 From kcal/kg to Btu/lb multiply by 1.800 kcal/kg = Btu/lb / 1.800 From MJ/kg to kcal/kg multiply MJ/kg by 238.846 MJ/kg = kcal/kg / 238.846 From MJ/kg to Btu/lb multiply MJ/kg by 429.923 MJ/kg = Btu/lb / 429.923 From Btu/lb to kcal/kg multiply Btu/lb by 0.5556 From Btu/lb to MJ/kg multiply Btu/lb by 0.002326

3.4 Formulas and conversions - Gross/Net :

Ref: Net Calorific Value (ASTM D5865-03)

The heat produced by combustion of a substance at a constant pressure of 0.1 Mpa (1 Atm), with any water formed remaining as vapor.

ISO 1928-2009 at constant volume Qv, net,m, J/g = ( Q gr,v,d - 206.0 [ wHd ] ) x (1-0.01 x Tm) - (23.05 x Tm) Qv, net,m, kcal/kg = ( Q gr,v,d - 49.20 [ wHd ] ) x (1-0.01 x Tm) - (5.51 x Tm)

ISO 1928-2009 at constant pressure Qp, net,m, J/g = { Q gr,v,d – 212.0 [ wHd ] - 0.8 x [wOd + wNd] } x (1- 0.01Tm) - 24.43 x Tm Qp, net,m, kcal/kg = { Q gr,v,d - 50.64 [ wHd ] - 0.191 x [wOd + wNd] } x (1- 0.01Tm) - 5.84 x Tm



[ wHd ] = H content of the sample less hydrogen present in the moisture w(H)d = w(H) x 100/100-Tm Tm= Total moisture

ASTM 5865/3180 at constant pressure

Qp(net)ar,J/g = Qvar(gross) - (215.5 x Har) Qp(net)ar,Btu/lb = Qvar(gross) - (92.67 x Har) Qp(net)ar,kcal/kg = Qvar(gross) - (51.47 x Har)

Har = total hydrogen where hydrogen includes hydrogen in sample moisture Har = [(Had-0.1119xMad) x (100-Mar)/(100-Mad)] + 0.1119 x Mar

4. VARIOUS PARAMETERS CALCULATIONS:

4.1 Seyler’s Formula: Various parameters of coal can be estimated from the Ultimate Analysis and Calorific Value determinations, using Seyler's formula, and other similar calculations (e.g. Dulong's or Channivala’s formulas).

Reference:

VM daf = 10.61H daf - 1.24C daf + 84.15 H daf = 0.069 (Q daf/100+VM daf) - 2.86 C daf = [0.59 (Q daf/100 - 0.367VM daf) + 43.4] Estimate of the hydrogen content, calculated using Seyler's Formula: wH = 0.07 x w(V) + 0.000165 x qv,gr,m - 0.0285 x [ 100 - Tm - w(A)] w(H) = is the H content of sample less H contained in moisture, as % mass w(V) = is the VM content of sample with moisture content Tm, as % mass w(A) = is the ash content of sample with moisture content Tm, as % mass qv,gr,m = is the gross CV of sample with moisture content Tm, in j/g Note 1 * Only valid when the calculated H db is greater than 3%

*ISO 1928-2009 § E.3.3

Note 2 ** Only valid when the O daf content is less than 15% ** COAL -Typology -Physics -Chemistry -Constitution D.W. Van Krevelen (third edition 1993) 7

Note 3 Can give erroneous results if coal shipments are a blend of low and high rank coals.



4.1 Dulong's Formula: GCV(db) = 333xC(db) + 1442(H(db) - O(db) / 8) + 93xS(db) GCV is in (kJ/kg dry basis) - C, H, O, S as percent on a dry basis.

Other calculations formulas related to CV:

kcal/kg: Net CV = Gross CV - 50.6H - 5.85M - 0.191O MJ/kg: Net CV = Gross CV - 0.212H - 0.0245M - 0.0008O Btu/lb: Net CV = Gross CV - 91.2H - 10.5M - 0.34O

- where M is % Moisture, H is % Hydrogen, O is % Oxygen (from ultimate analysis, also As Received).

For typical bituminous coal with 10% M and 25% Volatile Matter, the differences between gross and net calorific values are approximately as follows:

260 kcal/kg 1.09 MJ/kg 470 Btu/lb

5. CO2 EMISSION FACTOR: t/CO2/TJ =

C % As Received x 3.667 x [NCV/10000)] in kJ/kg =

C % As Received x 3.667 x [NCV/2388.46/NCV] in kcal/kg Note 1 Coefficient is 3,664 for France.

6. POWER GENERATION:

1 MWh = 3,600 MJ 1 MW = 1 MJ/s 1 MW (thermal power) [MWth] = approx 1,000 kg steam/hour 1 MW (electrical power) [MWe] = approx MWth / 3

A 600 MWe coal-fired power station operating at 38% efficiency and 75% overall availability will consume approximately:

- Bituminous coal (CV 6,000 kcal/kg NAR): 1.5 Mt/year - Brown coal (CV 2,250 kcal/kg NAR): 4.0 Mt/year



7. MOISTURE: Two Stage Total Moisture Formula (Refer to ASTM / ISO) Two stage total moisture determination is used when the coal sample is too wet to divide or crush without the potential of loosing significant amounts of moisture.

Tm ar, % = [Rm ad, % x (100 – Fm ad, %) / 100] + Fm ad % Tm = Total moisture; Fm = Free moisture; Rm = Residual moisture.

8. FUEL RATIO:

= Fixed Carbon / Volatile Matter

9. HYDROGEN & OXYGEN

In Coal: (Refer to ASTM 3180 / ISO 1170) Inasmuch as hydrogen and oxygen values may be reported on the basis of containing or not containing the hydrogen and oxygen in water (moisture) associated with the sample, alternative conversion procedures are defined below:

Hydrogen and Oxygen Factors based on the atomic weight of H20: Hydrogen = Moisture X 0.1119 Oxygen = Moisture X 0.8881

Sources: GWC Coal Handbook, ASTM & ISO Standards & others.

http://www.greatbritain.co.uk/gwc

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