Closing the active carbon cycle - tu-freiberg.de...Why Regenerate Activated Carbon-China, U.S and...
Transcript of Closing the active carbon cycle - tu-freiberg.de...Why Regenerate Activated Carbon-China, U.S and...
Closing the active carbon cycleREGENERATION OF SPENT ACTIVATED CARBON FOR RESOURCE OPTIMISATION
Jumoke Oladejo
PhD, MSc, BEng
New Materials Institute4th June 2018
Outline
Overview
Methodology
Results
Conclusion
Activated Carbon and Use
What is Activated Carbon
Bituminous coal
Lignite
Wood residues
Coconut shell
Physical or Chemical
activation
Granular activated carbon
Powder activated carbon- Carbonization (pyrolysis at 600 – 900°C)
- Oxidation (oxidized at 600 – 1200°C)
- Chemical activation (acid , base or salt, then carbonized at 450
– 900°C)
Use of Activated Carbon
The wide and diverse application of activated carbon in all aspects of industrial
and agricultural production would consequentially lead to increase in its demand
Use of Activated Carbon
The wide and diverse application of activated carbon in all aspects of industrial
and agricultural production would consequentially lead to increase in its demand
Doubt me?
Imagine everyone
decides to add active
carbon to their shelves
for these……
Why Regenerate Activated Carbon
- China, U.S and western Europe make up >50% of annual demand
- Water and air treatment are currently the largest market users
- Market forecasted to rise by ~300% by 2024 (grand view research)
- Major increase in water and waste water applications
Why Regenerate Activated Carbon
So... What happens to “spent“ activated carbon afterwards?
Incineration
Industrial Landfill(non-hazardous) Reactivation
Need for cost-effective
and quality restoring approach
- Growing waste management issues
- Hindering policies and regulations for carbon disposals
- Increasing price of activated carbon
- Pollutants considerations
Common Methods of Regeneration
Other methods....
- Electrochemical Regeneration
- Microwave Regeneration
First principle of circular economy:
“Waste is food” … or money
“no waste and pollution”
Microwave heating versus Conventional heating
Microwave Technology
Conventional
Heat transfer from surface
to center by convection,
conduction and radiation
Microwave
Transfer of electromagnetic
energy to thermal energy.
-Microwaves penetrate
materials, deposit energy
and heat is generated
throughout the volume
Microwave Technology Benefits
- Rapid heating
- Selective heating
- Enhanced chemical reactivity
- Energy Efficient
- Portability of system
- Ease of control
- Flexibility of process
Reactivation of ‘spent activated carbon’
Carbon from
Methodology
Regeneration Process
Material
Spent activated carbon from
Sewage treatment facility
Drying at 105°C
for 12 hours
Microwave and Conventional
Reactor
Powdered size <150µm
Schematic diagram of regeneration process
Methodology
- Gas flow (200ml/min)
- K-type thermocouple with Nb alloy tube
- Iodine sorption value(mg/g) –
GB/T 12496.8 (measure of microporosity)
- Methylene cyanine adsorption value(mg/g) –
GB/T 12496.10 (measure of mesoporosity )
Results
- Coconut activated carbon has Iodine value (900- 1250 mg/g) and Methylene value (135 – 210 mg/g)
- Iodine Value (IV) of spent AC was 70.9% of the lower limit
- Methylene Value (MV) of spent AC was 37.5% of the lower limit
- Negligible difference in IV and MV after drying (<2% reduction)
Activity Parameters of Activated Carbon
Regeneration of Activated Carbon at 500°C
- IV(0.01 – 1.9%) and MV (68.8 – 78.2%) increase in conventional reactor
- IV(3.2 – 8.3%) and MV (87.4 – 100.5%) increase in microwave assisted reactor
- Higher improvement in CO₂ atmosphere at 2 hours reaction time
Regeneration of Activated Carbon at 600°C
- IV(0.5 – 1.8%) and MV (99 – 119%) increase in conventional reactor
- IV(7.3 – 17.1%) and MV (97– 141%) increase in microwave assisted reactor
- Higher improvement in CO₂ atmosphere at 2 hours reaction time
Microwave Assisted Regeneration of Activated Carbon at 600 and 700°C
- IV(11.4 – 17.1%) and MV (124 – 145%) increase at 600°C
- IV(9.8 – 15.5%) and MV (101.5 – 116%) increase at 700°C
- Optimal improvement in both parameters was at 600°C (IV at 2hr/5hrs and MV at 3hrs)
- Best operating condition = 600°C at 2hrs (83% IV and 90.37% MV of Reference AC)
Concluding Remarks
Concluding Remarks
• MAP is an attractive technology for activated carbon regeneration applications at
lower temperature.
• Higher Iodine and Methylene Value from microwave compared with conventional
systems
• Optimal activity obtained at 600°C after 2 hours or 5hrs
• Scalability potential for in-house regeneration at various usage facilities
Merci
Thank you
Xie Xie
Gracias
Danke sha
Questions???
Proximate Analysis
- Reduction in moisture and volatile content with increase in regeneration time and temperature- Increase in Fixed carbon content with regeneration time