CHM 2046 - Chemistry Fundamentals II Final Exam Study Union Packet (Tutor Lily L.)

Disclaimer: Practice problems are modified & compiled by the tutor. They do not

guarantee a good grade or serve as a replacement for studying; they are a supplement.

Ch. 12

1. Which answer has the compounds ordered in terms of increasing boiling point?

a) H2 < HF < HBr < HI b) H2 < HBr < HI < HF

c) HF < HBr < HI < H2 d) HF < HI < HBr < H2

2. Find the vapor pressure of a substance at 29°C whose normal boiling point is 76°C and has

a𝛥𝐻𝑣𝑎𝑝of 38.7 kJ/mol.

a) 87 mmHg b) 48 mmHg c) 101 mmHg d) 96 mmHg

3. Find the amount of heat (kJ) needed to raise the temperature of a 12.0 g sample of benzene

from -10°C to 25°C. (Specific heat of solid = 1.25 J/(g*°C), specific heat of liquid = 1.70

J/(g*°C), heat of fusion = 9.8 kJ/mol, melting point = 5.5°C, boiling point = 30°C)

a) 2.1 kJ b) .0026 kJ c) 24.4 kJ d) 1.7 kJ

Ch. 13

4. Iridium crystallizes in a face-centered cubic structure with an edge length of 3.83 angstroms.

Determine the density of iridium.

a) 22.7 g/cm^3 b) 12.2 g/cm^3 c) 15.0 g/cm^3 d) 2.77 g/cm^3

5. Which compound is soluble in hexane (C6H14)?

a) Water b) CH3CH2CH3 c) HCl d) NH3

6. Select the answer with the largest band gap.

a) Conductor b) Semiconductor c) Nonconductor d) Insulator

Ch. 14

7. Which aqueous solution has the highest freezing point?

a) 1.25 molal of C12H22O11 b) 0.5 molal of K3PO4

c) 2 molal of NaCl d) 1 molal of Mg(SO4)2

8. The osmotic pressure of a solution containing 22.7 mg of an unknown protein in 50.0 mL of

solution is 2.88 mmHg at room temperature. Determine the molar mass of the protein.

a) 246 g/mol b) 3.85 g/mol c) 2930 g/mol d) 147 g/mol

9. Calculate the vapor pressure at 25°C of an aqueous solution containing 55.3 g ethylene glycol

(HOCH2 CH2OH) and 285.2 g of water. (vapor pressure of pure water at 25°C = 23.8 torr)

a) 23.8 torr b) 20.9 torr c) 22.5 torr d) 25.5 torr

Ch. 16

10. In which of the following reactions will Kc equal Kp?

a) 4 NH3(g) + 3 O2(g)↔2 N2(g) + 6 H2(g) b) SO3(g) + NO(g)↔NO2(g) + SO2(g)

c) 2 N2(g) + O2(g)↔2 N2O(g) d) O2(g) + 2 SO2(g)↔2 SO3(g)

11. What would increasing the pressure do to the following reaction that was previously at

equilibrium? What if 3 atm of Ar is added? If this reaction is exothermic, what would raising the

temperature do? 2 H2O(g) + 2 SO2(g) 2 H2S(g) + 3 O2(g)

Equilibrium shifts to: a) Left, No change, Left b) No change, Right, Right

c) Left, Right, No change d) Right, Left, Right

12. Find the Kp of N2(g) + O2(g) + Br2(g) 2NOBr(g) using the given info below:

NO(g) + 1/2 Br2(g) NOBr(g) Kp = 5.3

2NO(g) N2(g) + O2(g) Kp = 2.1E30

a) 1.5E-28 b) 1.4E29 c) 1.3E-29 d) 1.3E-32

Ch. 17

13. Find the percent ionization of 0.60 M hydrazoic acid in water. Ka = 2.5E-5.

a) 65% b) 6.5% c) 0.65% d) 0.06%

14. Find the mass of the conjugate base in 1.6 L of 0.4 M H2SO4 aqueous solution.

a) 4 g b) 26.5 g c) 38.8 g d) 62 g

15. Find the pH when 1.3 M 𝐶𝑂32−is dissolved in an aqueous solution that initially had a pOH of

1. Kb=1.8E-4

a) 14 b) 13 c) 8 d) 6

Ch. 18

16. A 1.0 L buffer solution contains 0.100 mol HC2H3O2 and 0.100 mol NaC2H3O2. The weak

acid’s Ka is 1.8E-5. What is the pH after 0.010 moles of solid NaOH is added to the buffer?

a) 4.83 b) 2.90 c) 12.74 d) 7.83

17. Find the molar solubility of calcium phosphate in a 0.10 M 𝑃𝑂43− solution. Ksp = 2.07E-33

a) 1.14E-7 b) 1.97E-11 c) 3.09E-7 d) 2.07E-11

18. An aqueous solution with 0.100 M of weak solute is titrated by 0.100 M of titrant, producing

the titration curve below. With as little math possible, find the pH at the half-equivalence point

and equivalence point (Hint: X is strong). pKa = 4.76

a) 4.76, 5.28

b) 9.24, 5.28

c) 9.24, 7.00

d) 4.76, 2.00

Ch. 19

19. Find 𝛥𝑆∘of the reaction 2 H2S(g) + 3 O2(g) 2 H2O(g) + 2 SO2(g). Individual entropies

are as follows (J/(mol*K)): 205.8 205.2 188.8 248.2

a) -64 J/mol*K b) 52 J/mol*K c) -56 J/mol*K d) 64 J/mol*K

20. Patino wants to produce an exergonic reaction. If 𝛥H = -76 kJ and 𝛥S = -555 J/K, what is the

lowest possible temperature for this to happen?

a) 112 K b) 137 K c) 92 K d) 203 K

21. Find the ΔGrxn when T = 298 K and the pressures are such that PNO = 0.300 atm, PO2 =

0.100 atm, PNO2 = 0.500 atm. (Is the reaction more or less spontaneous under these conditions

than under standard conditions?) 2 NO(g) + O2(g) -> 2 NO2(g) ΔG°rxn = -710.2 J

a) 7525 kJ b) 7.161 kJ c) 7.525 kJ d) 7161 kJ

Ch. 20

22. Find the cell potential for the following electrochemical cell, given that for Sn^2+, Sn: E° = -

0.14 volts and for Ag+, Ag: E° = +0.80 volts. Ag(s) | Ag+ (1.0 M) || Sn2+ (1.8 M) | Sn(s)

a) +.86 V b) -.65 V c) +1.02 V d) -.93 V

23. Balance Cr2O7 2- + I- -> Cr 3+ + IO3 - in basic solution. What are the coefficients of OH-

and H+, respectively?

a) 0, 0 b) 0, 22 c) 22, 22 d) 22, 0

24. Copper is plated onto the cathode of an electrolytic cell containing CuCl2(aq). Calculate the

amount of time needed to plate 111 mg of copper with a current of 3.8 A.

a) 89 s b) 113 s c) 44 s d) 56 s

Ch. 15

25. If N2O5’s concentration decreases by 0.065 M over 10 seconds, find the rate that oxygen

gas is being formed over the same timeframe. 2 N2O5(g) -> 4 NO2(g) + O2(g)

a) 0.00034 M/s b) 0.0105 M/s c) 0.00625 M/s d) 0.00325 M/s

26. A laboratory has found the rate of a reaction to be 27.1 M/s when each of the five reactants

have a concentration of 2 M. The reaction orders are: second in respect to A, first for B and E,

zero for C, third for D. Find k and the effect on rate if all reactant concentrations are doubled.

a) 0.21𝑀−7𝑠−1, rate is divided by 128 b) 0.21𝑴−𝟔𝒔−𝟏, rate is multiplied by 128

c) 0.17𝑀6𝑠−1, rate increases by 128 d) 0.17𝑀−6𝑠−1, rate is multiplied by 128

27. The decomposition of N2O takes place on a graph with a y axis of ln[A] vs and x axis of t. It

has a rate constant of .76𝑠−1. If the initial concentration of N2O is 10.9 M, what is the

concentration of N2O after 9.6 seconds?

a) 7.4E-3 M b) 1.4E-3 M c) 3.6E-3 M d) 8.1E-3 M

Ch. 21

28. The answer choices are all parts of a partial decay series for Th-232 that has undergone this

sequence: 𝛼, 𝛽, 𝛽, 𝛼. Identify the third step.

a) 𝟖𝟗𝟐𝟐𝟖𝑨𝒄 → −𝟏

𝟎 𝜷 + 𝟗𝟎𝟐𝟐𝟖𝑻𝒉 b) 90

228𝑇ℎ → 24𝐻𝑒 + 88

224𝑅𝑎

c) 88228𝑅𝑎 → −1

0 𝛽 + 89228𝐴𝑐 d) 90

232𝑇ℎ → 24𝐻𝑒 + 88

228𝑅𝑎

29. Find the daughter nuclide of Sr’s beta decay where A = 89 and Z = 38.

a) 3890𝑆𝑟 b) 39

90𝑌 c) 3685𝐾𝑟 d) 𝟑𝟗

𝟖𝟗𝒀

30. Unknownium has a half-life of 4.5 years. How many years will have passed for a sample to

have 6.25% of its original amount?

a) 40.5 years b) 13.5 years c) 18 years d) 23 years

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