Chemistry Syllabus at Iit Kanpur for Msc

8/12/2019 Chemistry Syllabus at Iit Kanpur for Msc

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COURSE CONTENTS2012

DEPARTMENT OF CHEMISTRY

INDIAN INSTITUTE OF TECHNOLOGY KANPUR

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Table of Contents

CHM 203: Basic Organic Chemistry-I .....................................................................................................4CHM 202: Basic Organic Chemistry-II.....................................................................................................6CHM 222: Basic Physical Chemistry........................................................................................................7CHM 242: Basic Inrganic Chemistry.......................................................................................................!

CHM 303: Organic Chemistry I ..............................................................................................................10CHM 30": Organic #$alitati%e an& #$antitati%e analysis ......................................................................11CHM 321: Physical Chemistry-1 ............................................................................................................12CHM 322: Physical Chemistry-2.............................................................................................................13CHM 34": Inrganic Chemistry -I...........................................................................................................14CHM 342: Inrganic Chemistry-II...........................................................................................................16CHM 344: Inrganic Chemistry 'a(ratry )*+eriments.......................................................................17CHM 423:Physical Chemistry 'a(ratry..............................................................................................1,CHM 402: Organic Chemistry II.............................................................................................................1!CHM 4,1: Bisystems.............................................................................................................................20CHM 602: &%ance& Organic Chemistry................................................................................................21

CHM 611: Physical Organic Chemistry...................................................................................................22CHM612 rntiers in Organic Chemistry................................................................................................23CHM614 Organic Phtchemistry...........................................................................................................24CHM616 CH)MI/ O OM)''IC COMPO5/.......................................................2"CHM 621: CH)MIC' BII.........................................................................................................27CHM 622 CH)MIC' I)IC/.........................................................................................................2,CHM 626 : /li& /tate Chemistry...........................................................................................................2!CHM 631: ++licatin 8 M&ern Instr$mental Meth&s.......................................................................30CHM632 )n9yme: reactins mechanism an& inetics............................................................................32CHM636 Physical +htchemistry..........................................................................................................33CHM637 Mlec$lar /+ectrsc+y...........................................................................................................34

CHM646 Bi-inrganic Chemistry I.......................................................................................................3"CHM647 Macrcycles; ings an& Plymers...........................................................................................36CHM 64, Chemistry 8 Metal Car(n Bn&: /tr$ct$re; eacti%ity an& ++licatins............................37CHM 6"0: /tatistical Mechanics an& its a++licatins t Chemistry........................................................3,CHM6"1 Crystal an& Mlec$lar /tr$ct$re eterminatin......................................................................3!CHM6"4 /$+ramlec$lar Chemistry.......................................................................................................40CHM662 Chemistry 8 at$ral Pr&$cts.................................................................................................41CHM 664: M&ern Physical Meth&s in Chemistry...............................................................................42CHM66, &%ance& Main r$+ Chemistry..........................................................................................43CHM67! Mlec$lar eactin ynamics.................................................................................................44CHM 6,1 Basic Bilgical Chemistry....................................................................................................4"

CHM6,4: Cm+$ter Prgramming in Chemistry....................................................................................46CHM6," Mlec$le a&iatin Interactins..............................................................................................47CHM6,! $clear Magnetic esnance..................................................................................................4,CHM6!1 rntiers in Inrganic Chemistry.............................................................................................4!CHM 6!3: Chemical /ynthetic /trategy 8 &%ance& Materials.................................................................................................................................................................."0CHM 6!" Mlec$lar M&eling in Chemistry.........................................................................................."2

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CHM 6!6


4/55

CHM 203: as!" O#$an!" C%e&!st#'(I

Prerequisites: NoneCredits: 3!! "#$

Co)#se Contents:

No%en&'(ture o) Or*(ni& %o'e&u'es: "+$,rie) re-ision. No%en&'(ture o) /o'0&0&'i& &o%/ounds in&'udin* 1rid*ed. s/iro (nd ot2er s/e&i('stru&tures

Stru&ture (nd ,ondin* : "4$N(ture o) 1ondin* in ('i/2(ti&. ('i&0&'i&. (ro%(ti& (nd 2etero&0&'i& &o%/ounds5 Aro%(ti&it0 in1en6enoid (nd non1en6enoid &o%/ounds A'tern(nt (nd non('tern(nt 20dro&(r1ons5 Di/o'e%o%ent5 Reson(n&e5 Indu&ti-e (nd Fie'd e))e&ts. 20/er&on7u*(tion. Steri& in2i1ition o) reson(n&e.stru&tur(' e))e&ts on (&idit0 (nd 1(si&it0

Stereo&2e%istr0: "+!$

Con)or%(tion(' (n('0sis o) (&0&'i& s0ste%s "Pit6er str(in. A str(in. et&$ (nd &0&'o2e8(ne s0ste%s"1rie) re-ie9 (s studied in C2% 4!+$ Introdu&tion o) ter%ino'o*ies su&2 (s er0t2ro. t2reo. . . e8o.endo. e/i%ers. et& Con)or%(tion(' (n('0sis o) de&('ins (nd ot2er /o'0&0&'i& &o%/ounds re'(ted tosteroids

A 1rie) introdu&tion to (s0%%etri& s0nt2esis5 Indu&tion o) &2ir('it0 on ( /ro&2ir(' &(r1on (to%5 R(nd Sno%en&'(ture in "i$ &0&'i& s0ste%s "ii$ in &o%/ounds 9it2 %ore t2(n one &2ir(' &entre (nd "iii$ in1i/2en0's. (''enes (nd s/iro &o%/ounds O/ti&(' iso%eris% in &o%/ounds 9it2out (n (s0%%etri&(to%. R(&e%i& %odi)i&(tionsCon)or%(tion o) (&0&'i& %o'e&u'es. to/i&it0 (nd /rostereoiso%eris% "to/i&it0 o) 'i*(nds (nd )(&es$.&2e%i&(' (nd 1io&2e%i&(' tr(ns)or%(tions o) 2eteroto/i& 'i*(nds (nd )(&es Con)or%(tions o) &0&'i&.)used (nd 1rid*ed rin* &o%/ounds A''0'i& str(in "A+.4(nd A+.3$ (nd ot2er str(ins

Re(&ti-e Inter%edi(tes : "$C(r1o&(tions5 &(r1(nions5 )ree r(di&('s. r(di&(' (nions (nd &(tions5 (r0nes5 &(r1enes (nd nitrenes"Introdu&tion to stru&ture. st(1i'it0. (nd re(&tions$

Su1stitution (nd E'i%in(tion Re(&tions "#$ E'e&tro/2i'i& (ro%(ti& su1stitution "in det(i'$5 A'i/2(ti& su1stitutions: SN+. SN4. SN4; (nd SNi

re(&tions5 nei*21ourin* *rou/ /(rti&i/(tion Nu&'eo/2i'i& (ro%(ti& su1stitution "1rie)$5 Freer(di&(' su1stitutions "1ot2 ('i/2(ti& (nd (ro%(ti&$

E'i%in(tions: E+. E4. E+C, re(&tions "in det(i'$ E'i%in(tion -s Su1stitution

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6/55

CHM 202: as!" O#$an!" C%e&!st#'(II

Prerequisites: CH< 4!3Credits: 3!! "#$

Co)#se Contents:

O8id(tion: "B$>it2 Cr (nd itti* re(&tion. Die'sA'der (nd ene re(&tions. Re)or%(ts=0 re(&tion

A&eto(&eti& ester (nd %('oni& ester s0nt2esis A&0'(tion re(&tions En(%ine re(&tions G(tter%(nn('de20de s0nt2esis . Co'd2(%. I So%e


7/55

CHM 222: as!" P%'s!"al C%e&!st#'

Co)#se Des"#!+t!on: Int#o,)"t!on- la.s of t%e#&o,'na&!"s- a++l!"at!ons to !,eal an,non(!,eal s'ste&s- t#ans+o#t an, *!net!"s

P#e#e/)!s!tes: None

Un!ts: 3(0(0

Course Contents:

+ erot2 L(9 o) T2er%od0n(%i&s: Equi'i1riu%. St(te Fun&tions. Te%/er(ture. Equ(tions o)St(te

4 First L(9 o) T2er%od0n(%i&s: >or=. He(t. Intern(' Ener*0. He(t C(/(&it0. Con&e/t o)Ent2('/0

3 Se&ond L(9 o) T2er%od0n(%i&s: Re-ersi1'e (nd Irre-ersi1'e Pro&ess. He(t En*ines.C(rnot C0&'e. Di))erent st(te%ents o) t2e Se&ond L(9. S/ont(neous C2(n*e. Entro/0

@ T2ird L(9 o) T2er%od0n(%i&s: Con&e/t o) t2e (1so'ute 6ero te%/er(ture

B Free Ener*0 (nd St(nd(rd St(tes: Free ener*ies (nd T2er%od0n(%i& /otenti('s. Le*endreTr(ns)or%s. Equi'i1riu% (nd NonEqui'i1riu%. C2e%i&(' Potenti('s. Free Ener*0. St(nd(rdSt(tes. Re(&tion T2er%od0n(%i&s. Equi'i1riu% Const(nt

Equi'i1riu% T2er%od0n(%i&s: C2e%i&(' Potenti(' o)


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Re(' G(ses @

So'utions

Kineti& T2eor0 o) G(ses (nd Tr(ns/ortPro&esses

@

Re(&tion Kineti&s

Books:

+ P > At=ins (nd u'io de P(u'(. P20si&(' C2e%istr04 I N Le-ine. P20si&(' C2e%istr03 R Si'1e0. R A A'1ert0. (nd


9/55

CHM 22: as!" Ino#$an!" C%e&!st#'

Prerequisites: CHi'=inson. G. ,(si& Inor*(ni& C2e%istr0. 3rdEdn. o2n >i'e0 (nd Sons

+##B Cotton. FA5 C(r'os. A


10/55

CHM 303: O#$an!" C%e&!st#' I

P#e#e/)!s!tes:CH< 4!3 (nd CHitti* re(rr(n*e%ents "1ot2 +.4 (nd 4.3 >itti* re(rr(n*e%ents$5ene (nd %et(''oene re(&tions5 "44$. "34$ (nd "@4$ &0&'o(dditions5 ,(rton re(&tion

Or*(no%et(''i& C2e%istr0 : "B$(rren. (nd >ot2ers. Or*(ni& C2e%istr0. +sted. 4!!+

10


11/55

CHM 305: O#$an!" /)al!tat!8e an, /)ant!tat!8e anal's!s

P#e#e/)!s!tes: NoneC#e,!ts "Ne9 ARC$: !! "$

+ E8/eri%ent(' Te&2niques

"A$ Puri)i&(tion o) Or*(ni& Co%/ounds( Re&r0st(''is(tion1 Su1'i%(tion (t (t%os/2eri& /ressure (nd under redu&ed /ressure& Se/(r(tion or or*(ni& &o%/ounds 10 Ste(% disti''(tiond Disti''(tion o) or*(ni& &o%/ounds under redu&ed /ressuree ,u'1to1u'1 disti''(tion under redu&ed /ressure

",$ C2ro%(to*r(/20( T2in '(0er &2ro%(to*r(/20 "TLC$ (nd &('&u'(tion o) R) -('ues1 Co'u%n C2ro%(to*r(/20: se/(r(tion o) or*(ni& %i8ture

& Pre/(r(ti-e TLC: /re/(r(tion o) /'(tes (nd se/(r(tion o) or*(ni& %i8tures

"C$ P20si&(' Const(nts(


12/55

CHM 321: P%'s!"al C%e&!st#'(1

P#e#e/)!s!tes: None

Un!ts: 3(0(0

Co)#se Des"#!+t!on:,(si& u(ntu%


13/55

CHM 322: P%'s!"al C%e&!st#'(2

P#e#e/)!s!tes: NoneUn!ts: 3(0(0

Co)#se ,es"#!+t!on:Equi'i1riu% T2er%od0n(%i&s. St(tisti&('


14/55

CHM 35: Ino#$an!" C%e&!st#' (I

Prerequisites: CH


15/55

Sele"te, Te7t oo*s:

+$ E's&2en1roi&2. C5 (nd S('6er. A.Or*(no%et(''i&s: A Con&ise Introdu&tion. 3rdEdn +###

4$ Green9ood. N N5 E(rns2(9. A. C2e%istr0 o) t2e E'e%ents. Per*(%on Press. 4

nd

Edn.4!!4

3$ Dou*'(s. ,5


16/55

CHM 32: Ino#$an!" C%e&!st#'(II

Prerequisites: CH5 L(n*)ord. C G. Inor*(ni& C2e%istr0 3rdEdn. O8)ord

Uni-ersit0. O8)ord. +###3$ Cotton. F A5


17/55

CHM 3: Ino#$an!" C%e&!st#' 6abo#ato#' E7+e#!&ents

Prerequisites: NoneCredits: !! "$

Co)#se "ontents:

Est!&at!on of !#on !n &!n)te /)ant!t!es b' U9(8!s s+e"t#o+%oto&et#'Prin&i/'es o) &o'ori%etri& (n('0sis: deter%in(tion o) iron &ontent o) (n un=no9n s(%/'e

P#e+a#at!on of %e7a&&!nen!"*elII"%lo#!,e: est!&at!on of a&&on!a an, n!"*el b't!t#!&et#!" an, $#a8!&et#!" &et%o,s

Deter%in(tion o) &o%/'e8 &o%/osition usin* si%/'e te&2niques

P#e+a#at!on of ,!a&a$net!" an, +a#a&a$net!" &a!n($#o)+ an, t#ans!t!on(&etala"et'la"etonates

S0nt2esis. iso'(tion (nd s/e&tros&o/i& &2(r(&teri6(tion o) t2e &o%/'e8es

S'nt%es!s an, "%a#a"te#!at!on of fe##o"ene an, a"et'lfe##o"eneS0nt2esis o) t2e &o%/'e8 (nd t2eir /uri)i&(tion usin* &2ro%(to*r(/20

A"!,(base an, #e,o7 t!t#at!on of tablets "onta!n!n$ 9!ta&!n(CEsti%(tion o) (s&or1i& (&id in ?it(%inC t(1'ets

Pa+e# "%#o&ato$#a+%!" se+a#at!on of C)2;- Fe3;an, N!2;

Uti'i6(tion o) /(/er &2ro%(to*r(/2i& te&2niques to se/(r(te t2e %et(' s('ts

S+e"t#o+%oto&et#!" ,ete#&!nat!on of +%os+%ate: est!&at!on of +%os+%ate !n "ola,#!n*s

Deter%in(tion o) &on&entr(tion o) /2os/2(tes (//'0in* ,eerL(%1ert '(9


18/55

CHM 23:P%'s!"al C%e&!st#' 6abo#ato#'

P#e#e/)!s!tes: NoneC#e,!ts: 0(0(> >

Co)#se ,es"#!+t!on:E8/eri%ent(' te&2niques in /20si&(' &2e%istr0. s/e&tros&o/0 (ndqu(ntu% &('&u'(tions

6!st of e7+e#!&ents:

1. C('i1r(tion o) -o'u%etri& (//(r(tus One ,a'

2. An('0sis o) t2e rot(tion('-i1r(tion(' s/e&tr( o) HC' %o'e&u'es One ,a'

3. Deter%in(tion o) /(rti(' %o'(' -o'u%e One ,a'

4. Deter%in(tion o) t2e isot2er% )or ( t2ree &o%/onent s0ste% T.o ,a's

". Kineti&s o) )(st re(&tions 10 sto//ed)'o9 te&2nique One ,a'

6. S/e&tro/2oto%etri& deter%in(tion o) t2e (&id disso&i(tion &onst(nt T.o ,a'

7. T2e %e(sure%ent o) e'e&tri&(' &ondu&t(n&e )or t2e deter%in(tion o) t2e equi-('ent&ondu&t(n&e (t in)inite di'ution T.o ,a's

,. R(te o) t2e 20dro'0sis o) su&rose usin* /o'(ri%eterT.o ,a'

!. Deter%in(tion o) /K( o) /o'01(si& (&id 9it2 t2e /H %eter One ,a'

10. Deter%in(tion o) &riti&(' %i&e''er &on&entr(tion One ,a'

11. Deter%in(tion o) tr(ns/ort nu%1er 10 %o-in* 1ound(r0 %et2od One ,a'

12. Po'(ri6(1i'it0 )ro% re)r(&ti-e inde8 %e(sure%ents One ,a'

13. For%u'( (nd st(1i'it0 &onst(nt o) ( &o%/'e8 10 s/e&tro/2oto%etr0 One ,a'

14. F'uores&en&e qu(ntu% 0ie'd deter%in(tion o) (n un=no9n %o'e&u'e One ,a'

1". F'uores&en&e s/e&tru% (nd stern-o'%er quen&2in* &onst(nt One ,a'

16. IR (nd R(%(n s/e&tros&o/0 o) so'-ent %i8tures T.o ,a's

17. Co%/utin* Potenti(' Ener*0 Sur)(&e o) %o'e&u'es usin* u(ntu%


19/55

CHM 02: O#$an!" C%e&!st#' II

P#e#e/)!s!tes:CH< 3!3C#e,!ts: 3!! "#$

O8id(tion: "$

O8id(tion in-o'-in* or*(nosu')ur "su&2 (s S9ern$ (nd or*(nose'eniu% &o%/ounds5 Dess. Co'd2(%. I So%e


20/55

CHM


21/55

CHM >02: A,8an"e, O#$an!" C%e&!st#'

Prerequisites: CH< @!4Credits: 3!! "#$

Prin&i/'es o) retros0nt2eti& (n('0sis: Line(r (nd &on-er*ent s0nt2esis. S0nt2esis

under steri& &ontro'. Re*io (nd stereose'e&ti-e s0nt2esis. ,(si& s0nt2eti& %et2ods

i'e0. +##Ni&o'(ou (nd Sorensen. C'(ssi&s in Tot(' S0nt2esis. +##Ni&o'(ou (nd Sn0der. C'(ssi&s in Tot(' S0nt2esis II. 4!!3C(re0 (nd Sund1er*. Ad-(n&ed Or*(ni& C2e%istr0. P(rt I (nd II. @t2ed. 4!!!


22/55


23/55

CHM>12 F#ont!e#s !n O#$an!" C%e&!st#'

Prerequisites: NoneCredits: 3(0(0 Ne. ARC

As0%%etri& S0nt2esis : In&'udin* or*(no (nd %et(' 1(sed &(t('0sis "+3$

S0nt2esis usin* Or*(no%et(''i& C2e%istr0 : Tr(nsition (nd %(in *rou/ e'e%ents 1(sedre(&tions in-o'-in* re*ion. stereo. (nd en(ntiose'e&ti-e re(&tions (nd (//'i&(tion inor*(ni& s0nt2esis"+4$

Su/r(%o'e&u'(r C2e%istr0 . Co%1in(tori(' C2e%istr0 . et& "B$

Green C2e%istr0. G'0&o1io'o*0. S0nt2eti& (s/e&ts usin* Do%ino re(&tions. "+4$Prin&i/'es o) (to% e&ono%0 9it2 e8(%/'es. Te%/'(ted (nd so'id su//ortedOr*(ni& S0nt2esis

oo*s:

(-e)un&tion. In& 4!!!H S&2%('6. T >irt2 Or*(ni& S0nt2esis Hi*2'i*2ts. 4!!3 Tsu7i. Tr(nsition %et(' re(*ents (nd &(t('0st inno-(tions in or*(ni& s0nt2esis o2n>i'e0

Sons. Ltd. Ne9 Yor=. 4!!!T K Lid2orst. Essenti('' o) &(r1o20dr(te &2e%istr0 (nd 1io&2e%istr0. >i'e0?CH. 4!!


24/55

CHM>1 O#$an!" P%oto"%e&!st#'

Prerequisites: CH


25/55

CHM>1> CHEMISTRY OF OR4ANMETA66IC COMPOUNDS

No o) Le&tures: @4Prerequisites: CH< 3@4Credits: 3!! "#$

Ne9er (s/e&ts o) or*(no%et(''i&s deri-ed )ro% di))erent e'e%ents su&2 (s Pd. Cu. Ti. R2. Ru.Li*(nd su1stitutions5 O8id(ti-e (ddition5 Redu&ti-e e'i%in(tion5 Intr(%o'e&u'(r

insertionse'i%in(tions5 Nu&'eo/2i''i&E'e&tro/2i''i& (tt(&=s on &oordin(ted 'i*(nds

Ho&o$eneo)s "atal's!s an, Catal'sts 10

Introdu&tion5 A'=ene iso%eri6(tion5 H0dro*en(tion5 H0dro)or%0'(tion5

+H N


26/55

oo*s:+ Tsu7i. Tr(nsition %et(' re(*ents (nd &(t('0st inno-(tions in or*(ni& s0nt2esis o2n

>i'e0 Sons. Ltd. Ne9 Yor=. 4!!!4 (-e)un&tion. In& 4!!!3 H S&2%('6. T >irt2 Or*(ni& S0nt2esis Hi*2'i*2ts. 4!!3

@ K C Ni&o'(ou. C'(ssi&s in Tot(' S0nt2esis ?o's IIII. >i'e0?CH. +##5 4!!35 4!++

5. "The Organoetallic Cheistry o! the Transition etals"10 Ro1ert Cr(1tree"3rd Edition. >i'e0$#. $The %rinciples and &pplications o! Transition etal Cheistry'. 10 Co''%(n. He*edus.Norton (nd Fin=e "4ndeds. Uni-ersit0 S&ien&e ,oo=s$ Or*(no%et(''i&s 10 . C2risto/2 E's&2en1roi&2 "3rdEdition. >i'e0$


27/55

CHM >21: CHEMICA6 INDIN4

No o) Le&tures: @4

P#e#e/)!s!tes: CH< 34+Un!ts: 3(0(0

Re-ie9 o) 1(si& /rin&i/'es o) qu(ntu% t2eor0 (nd (to%i& stru&ture Introdu&tion to &2e%i&('1ondin* (nd 9e(= inter%o'e&u'(r )or&es "@$

E'e&troni& stru&ture o) %(n0 e'e&tron (to%s (nd -(ri(tion /rin&i/'e E'e&troni& stru&ture o)di(to%i& %o'e&u'es ,ornO//en2ei%er (//ro8i%(tion. H4 ion. (//ro8i%(te %o'e&u'(ror1it('"


28/55

CHM >22 CHEMICA6 @INETICS

No o) Le&tures:@4

Un!ts: 3(0(0

P2eno%eno'o*i&(' =ineti&s: Si%/'e (nd &o%/'e8 s0ste%s in&'udin* o//osin*. &on&urrent (nd&onse&uti-e re(&tions "$

R(te '(9 (nd %e&2(nis%. re'(tion 9it2 t2er%od0n(%i&s "$

Pre&ision in r(te %e(sure%ent. d(t( (n('0sis "@$

S/e&i(' e8/eri%ent(' %et2ods in&'udin* )'(s2 /2oto'0sis. s2o&= tu1e. %o'e&u'(r 1e(% (ndre'(8(tion te&2niques "$

Os&i''(tor0 re(&tions "@$

T2eories o) re(&tion r(tes: 1i%o'e&u'(r re(&tions. r(te &oe))i&ient. (&ti-(tion ener*0. /otenti('

ener*0 sur)(&es. tr(7e&tor0 %et2ods (nd tr(nsition st(te t2eor0 Uni%o'e&u'(r (ndter%o'e&u'(r re(&tions "$

A//'i&(tions: /2oto&2e%istr0. so'ution =ineti&s. 2o%o*eneous (nd 2etero*eneous &(t('0sis(nd en60%e =ineti&s "$

Re"o&&en,e, oo*s

1. K L(id'er. C2e%i&(' Kineti&s. 3rdEd H(r/er Ro9. Ne9 Yor=. +#

2. R D Le-ine (nd R , ,ernstein. L H(se. C2e%i&(' Kineti&s (nd D0n(%i&s. 4ndedPrenti&eH(''. N +###


29/55

CHM >2> : Sol!, State C%e&!st#'

P#e#e/)!s!tes: NoneUn!ts: 3(0(0

C%e&!"al "#'stallo$#a+%' 10

Introdu&tion. S/(&e '(tti&e. Cr0st(' /oint *rou/s. s/(&e *rou/ "9or=in* =no9'ed*e$.Stereo*r(/2i& /ro7e&tions. P(&=in* in so'ids. Cr0st(' stru&tures o) re/resent(ti-e s0ste%s.Si'i&(tes (nd eo'ites. Ce%ents. G'(sses. u(si&r0st('s. N(nostru&tures

on,!n$ !n sol!,s an, C#'stal ene#$et!"s 03Cr0st(' &'(ssi)i&(tions.


30/55

CHM >31: A++l!"at!on of Mo,e#n Inst#)&ental Met%o,s

No o) Le&tures: @4Prerequisites: CH< @!4. CH< 3@4Credits: 3!! "#$

Inf#a#e, S+e"t#os"o+': Introdu&tion Identi)i&(tion o) )un&tion(' *rou/s. 20dro*en 1ondin*et&. %et(' 'i*(nd -i1r(tions "4 Le&tures$

N)"lea# Ma$net!" Resonan"e S+e"t#os"o+': Introdu&tion A//'i&(tion o) +H (nd +3C N


31/55

Fl)o#es"en"e s+e"t#os"o+': F'uores&en&e ener*0 tr(ns)er (nd its (//'i&(tions to%e(sure%ent o) dist(n&es in %o'e&u'es "4 Le&tures$

Ma$net!s&: Introdu&tion to i'e0. +#!


32/55

CHM>32 En'&e: #ea"t!ons &e"%an!s& an, *!net!"s

No o) Le&tures: @4Prerequisites: CH< @+Credits: 3!! "#$

En60%e =ineti&s o) sin*'e (nd %u'ti/'e su1str(te s0ste%s in&'udin* En60%e (ss(0s (ndin2i1ition "+B 'e&tures$

Coo/er(ti-it0 (nd %u'tien60%e s0ste%s "@ 'e&tures$

En60%e stru&ture (nd identi)i&(tion o) (&ti-e site residues '(1e'in. &2e%i&(' %odi)i&(tion (nd%ut(*enesis " 'e&tures$

En60%e


33/55

CHM>3> P%'s!"al +%oto"%e&!st#'

No o) Le&tures: @4P#e#e/)!s!tes: NoneUn!ts:3(0(0

1. T2eor0 o) e'e&troni& (1sor/tion s/e&tr(. ,eers '(9. A1sor/tion &rossse&tion.So'-(to&2ro%is% "@$

2. R(di(ti-e (nd nonr(di(ti-e tr(nsitions. ?i1r(tion(' re'(8(tion. Intern(' &on-ersion. Inters0ste% &rossin* "B$

3. F'uores&en&e. P2os/2ores&en&e. ?(rious /2oto/20si&(' /ro&esses. So'-ent e))e&t one%ission. Li//ert equ(tion. D0n(%i& sto=es s2i)t. D0n(%i& (nd st(ti& quen&2in*.Stern?o'%er equ(tion. Forster reson(n&e ener*0 tr(ns)er (nd t2eor0. F'uores&en&e(nisotro/0 (nd Perrin equ(tion. E8&ited st(te /rotone'e&tron tr(ns)er. E8&i%er (nde8&i/'e8 "4!$

4. L(ser )und(%ent('s. Sti%u'(ted e%ission. Po/u'(tion in-ersion. Li*2t (%/'i)i&(tion.Pu'sed '(ser: &(-it0 du%/in*. s9it2&2in*. %ode'o&=in* "@$

". S/e&tros&o/i& te&2niques. S/e&tro/2oto%eter. S/e&tro)'uori%eter. Ti%e &orre'(tedsin*'e /2oton &ountin*. Tr(nsient (1sor/tion. Stre(= &(%er(. F'uores&en&e u/&on-ersion "$

6. Sin*'e %o'e&u'e s/e&tros&o/0. F'uores&en&e &orre'(tion s/e&tros&o/0. Protein)'uores&en&e "3$

S)$$este, Te7t oo*s

1. Ni&2o'(s Turro.


34/55

CHM>3?Mole")la# S+e"t#os"o+'No o) Le&tures: @4P#e#e/)!s!tes: NoneUn!ts: 3(0(0

+ Grou/ t2eor0 "$ Re-ie9 o) /oint *rou/s. /er%ut(tion in-ersion (nd %o'e&u'(r s0%%etr0 *rou/s

4 Inter(&tion o) r(di(tion (nd %(tter "B$ u('it(ti-e (s/e&ts. Einstein A. , &oe &ients.ffi (1sor/tione%ission (nd 'ines2(/es

3 Rot(tion(' S/e&tros&o/0 "$ Ri*id 1od0. se'e&tion ru'es. -i1r(tion(' (n*u'(r %o%entu%. to/s

@ ?i1r(tion(' S/e&tros&o/0 "$

Nor%(' %odes. se'e&tion ru'es. Fer%i (nd Corio'is /ertur1(tions. /o'0(to%i& %o'e&u'esB E'e&troni& S/e&tros&o/0 "$ Introdu&tion. s0%%etr0 (s/e&ts. -i1roni& e e&tsff

Ad-(n&ed to/i&s "#$ Cou/'in* o) rot(tion(' (nd -i1r(tion(' %otions. nonri*id s0ste%s. 2i*2 reso'ution (nd 2i*2'0e8&ited st(tes. >i'sonHo9(rd>(tson H(%i'toni(n. ti%ede/endent -ie9/oint

Refe#en"e oo*s+ ,ern(t2. S/e&tr( o) Ato%s (nd


35/55

CHM>> !o(!no#$an!" C%e&!st#' I

No o) Le&tures: @4Credits: 3!! "#$

+ K(i% (nd ,S&29eders=i. o2n >i'e0 Sons In&. +##@

Re-ie9 (rti&'es


36/55

CHM>? Ma"#o"'"les- R!n$s an, Pol'&e#s

Prerequisites: CH< 3@4Credits: 3(0(0

Ino#$an!" Hete#o"'"l!" R!n$s

PN rin*s: C0&'o/2os/2(6enes (nd C0&'o/2os/2(6(nes S0nt2esis. stru&ture (nd re(&ti-it0,ondin* %ode'sPN rin*s: &(r1o/2os/2(6enes. t2io/2os/2(6enes. %et(''(/2os/2(6enesSiO rin*s: C0&'osi'o8(nesSnO rin*s: St(nno8(nes,&ont(inin* rin*s: ,or(nes. &(r1or(nes. %et(''(&(r1or(nes. ,or(6ine

A'&ont(inin* Rin*s: A'N rin*s (nd &(*es. A'C rin*s (nd &(*es. A'u%o8(nesZ4! 'e&tures[

Ino#$an!" Ho&o"'"l!" R!n$sInor*(ni& 2o%o&0&'i& rin*s (nd &(*es &ont(inin* si'i&on. *er%(niu% . 1oron. ('u%inu% (nd

*(''iu% ZB 'e&tures[Ino#$an!" Ma"#o"'"les


37/55

CHM >< C%e&!st#' of Metal Ca#bon on,: St#)"t)#e- Rea"t!8!t'an, A++l!"at!ons

No o) Le&tures: @4Prerequisites: CH


38/55

CHM >50: Stat!st!"al Me"%an!"s an, !ts a++l!"at!ons to C%e&!st#'

No o) Le&tures: @4P#e#e/)!s!tes: NoneUn!ts:3!! "#$

Course des&ri/tion: T2er%od0n(%i&s. St(tisti&('


39/55

CHM>51 C#'stal an, Mole")la# St#)"t)#e Dete#&!nat!on


Gener(tion o) r(0s. %ono&2ro%(tors. s()et0 "+ Le&ture$

Con&e/t o) dire&t (nd re&i/ro&(' '(tti&es. ,r(**s '(9 o) r(0 di))r(&tion in dire&t (ndre&i/ro&(' '(tti&e. &r0st(' s0ste%s. /oint *rou/s. ,r(-(is '(tti&es

"B Le&tures$

Rot(tion(' (8es o) s0%%etr0. s&re9 (8es. *'ide /'(nes. equi-('ent /oints. s0ste%(ti&(1sen&es. s/(&e *rou/s " Le&tures$

Ar*(nd di(*r(%. intensit0 d(t( &o''e&tion (nd qu(ntit(ti-e (s/e&ts o) r(0 di))r(&tion.te%/er(ture )(&tor (nd s&('in* o) d(t( "+! Le&tures$

T2e /2(se /ro1'e%. dire&t %et2od o) so'-in* stru&tures " Le&tures$

P(tterson %et2od. iso%or/2ous re/'(&e%ent %et2od" Le&tures$

Stru&ture re)ine%ent (nd t2eir &riti&(' e-('u(tion " B Le&tures$

oo*s

r(0 Stru&ture Deter%in(tion A Pr(&ti&(' Guide 10 G H Stout (nd H L ensen.


40/55

CHM>5 S)+#a&ole")la# C%e&!st#'

Credits: 3!! "#$

Introdu&tiont2e %e(nin* o) su/r(%o'e&u'(r &2e%istr0. /2eno%enon o) %o'e&u'(r re&o*nition(nd t2eir qu(nti)i&(tion " 4 Le&tures$

,ui'din* 1'o&=s o) su/r(%o'e&u'(r &2e%istr0 (&0&'i& re&e/tors )or neutr(' (nd &2(r*ed*uests. %(&ro&0&'es (nd &ro9n et2ers. %(&ro1i&0&'es (nd &r0/t(nds. %(&ro/o'0&0&'es.&u&ur1ituri's (nd &0&'ode8trins "+4 Le&tures$

Sensors (nd in)or%(tion /ro&essin*. e'e&troo/ti& /2eno%en(. %o'e&u'(r %(&2ines "+4Le&tures$

A%/2i/2i'i& %o'e&u'es (nd t2eir (**re*(tion. L(n*%uir,'od*ettr0. %o'e&u'(r re&o*nition (tt2e (ir9(ter inter)(&e "3 Le&tures$

Dis&rete (nd /o'0%eri& %et('or*(ni& 201rid %(teri('s *uest in&'usion. &(t('0sis (nd ot2er(//'i&(tions "+4 Le&tures$

Future s&o/es "+ Le&ture$

oo*s

Su/r(%o'e&u'(r C2e%istr0: Con&e/ts (nd Pers/e&ti-es. ein2ei%. +##B

Prin&i/'es (nd i'e0. Ne9 Yor=. 4!!!

Su/r(%o'e&u'(r C2e%istr0. > Steed (nd L At9ood. o2n >i'e0 Sons. C2i&2ester.4!!#

Re-ie9 (rti&'es


41/55

CHM>>2 C%e&!st#' of Nat)#al P#o,)"ts

Prerequisites: CH< @!4Credits: 3(0(0

,ios0nt2eti& (s/e&ts (nd S0nt2esis o) se'e&ted n(tur(' /rodu&ts o) 1io'o*i&(' (nd stru&tur('

i%/ort(n&e: Dis&ussions on s0nt2eti& %et2ods. str(te*ies to9(rds t2ese n(tur(' /rodu&ts

%ost'0 in &2ir(' )or%s 9i'' 1e dis&ussed in det(i'

T2e n(tur(' /rodu&ts in&'ude &(r1(&0&'es (nd 2etero&0&'i& %oieties &ont(inin* stru&tures

r(nin* )ro% 3%e%e1ered to %(&ro&0'es. (nd &o%/'e8 n(tur(' /rodu&ts su&2 (s T(8o'.

r(/(%0&in. 'e7i%(i'de , et&

oo*s:

K C Ni&o'(ou. C'(ssi&s in Tot(' S0nt2esis ?o's IIII. >i'e0?CH. +##5 4!!35 4!++T Hud'i&=0 (nd > Reed. T2e 9(0 o) s0nt2esis . >i'e0?CH. 4!!E Core0 (nd i'e0 Sons. Ne9 Yor=

+##DH R ,(rton. K N(=(nis2i. O


42/55

CHM >>: Mo,e#n P%'s!"al Met%o,s !n C%e&!st#'


+ S0%%etr0 (nd Grou/ T2eor0: Grou/ %u'ti/'i&(tion t(1'e. e'e%ents o) ( s0%%etr0 *rou/.s0%%etr0 *rou/ &'(ssi)i&(tion. &2(r(&ters. *rou/ re/resent(tion. T2e Gre(t Ort2o*on('it0t2eore%. 1(sis o) re/resent(tion. 9(-e)un&tions (s 1(ses o) IR re/resent(tions. s0%%etr0(d(/ted 'ine(r &o%1in(tions. dire&t /rodu&ts. s/e&tr(' tr(nsitions

"+B$

4 Inter(&tion o) 'i*2t 9it2 %(tter. Einsteins &oe))i&ients. re'(tions2i/ o) Einsteins &oe))i&ients9it2 tr(nsition %o%ents "no deri-(tion$ (nd tr(nsition /ro1(1i'ities. os&i''(tor stren*t2 ,eerL(%1ert '(9. re'(tions2i/ 1et9een Einsteins &oe))i&ients (nd tot(' (1sor1(n&e ,ornO//en2ei%er (//ro8i%(tion. ener*0 'e-e's. /otenti(' ener*0 &ur-es.


43/55

CHM>>< A,8an"e, Ma!n 4#o)+ C%e&!st#'

Prerequisites:CH< 3@BNo o) Le&tures: @4Credits: 3!! "#$

A= To+!"s fo# Self(St),'+ ?SEPR T2eor0 (nd /redi&tion o) %o'e&u'(r *eo%etr04 S0%%etr0 S0%%etr0 e'e%ents (nd s0%%etr0 o/er(tions Point *rou/s Introdu&tion to

&2(r(&ter t(1'es Uses o) &2(r(&ter t(1'es

= C%e&!st#' of Ma!n($#o)+ Ele&ents

Cheistry o! +oron( Sel!st*dy: 1or(nes. 1ondin* in 1or(nes. to/o'o*0 o) 1or(nes. s0nt2esis(nd re(&ti-it0. C(r1or(nes (nd %et(''( &(r1or(nes Lo9-('ent 1oron &o%/ounds.or*(no1oron &o%/ounds (nd or*(ni& s0nt2esis Use o) ++, N


44/55

CHM>? Mole")la# Rea"t!on D'na&!"s


+ Introdu&tion "B$ Re-ie9 o) =ineti& t2eor0 o) *(ses. &o''isions (to%i& (nd %o'e&u'(r

4 R(te t2eories "$Tr(nsition st(te t2eor0 (nd RRK< t2eor0. s&(tterin* &'(ssi&(' (nd qu(ntu%

3 Re(&ti-e Co''isions "+!$ Potenti(' ener*0 sur)(&es. (to%di(to% re(&tions. /o'0(to%i& re(&tions. st(tese'e&ti-e.%o'e&u'(r 1e(%s. re(&tion r(tes (nd &ross se&tions

@ D0n(%i&s in *(s /2(se "$ P2otodisso&i(tion. ener*0 tr(ns)er. stereod0n(%i&s. &2e%istr0 in re(' ti%e 9it2 '(sers.

&ontro'

B D0n(%i&s in &ondensed /2(se "$ So'-(tion. di usion.ff 1(rrier &rossin*. Kr(%erGroteH0nes t2eor0. L(n*e-in equ(tion.&orre'(tion )un&tions

Ad-(n&ed to/i&s "B$ D0n(%i&s on sur)(&es. s/(tiote%/or(' (s/e&ts o) /(ttern )or%(tion. u'tr()(st d0n(%i&s

Refe#en"e oo*s+ Le-ine.


45/55

CHM >


46/55

CHM>i1er*. Co%/uter Pro*r(%%in* )or C2e%ists. >A ,en7(%in In&. Ne9 Yor= "+#B$"= SCC2(/r( (nd RPC(n('e. Nu%eri&('


47/55

CHM>


48/55

CHM>F(ir1rot2er. AGP('%er III (nd NS=e'ton. Protein N


49/55

CHM>1 F#ont!e#s !n Ino#$an!" C%e&!st#'

No o) Le&tures: @4Prerequisites: CH< 3@4Credits: 3!! "#$

De-e'o/in* )(&ets o) Inor*(ni& C2e%istr0 "4 Le&tures$

O8id(ti-e *ener(tion o) %o'e&u'(r o80*en )ro% 9(ter durin* /2otos0nt2esis " Le&tures$

Its i%/ort(n&e )ro% t2e st(nd/oint o) non&on-ention(' ener*0 rese(r&2 " Le&tures$

Redu&ti-e &'e(-(*e o) t2e dio80*en 1ond "3 Le&tures$

Redu&ti-e &'e(-(*e o) dio80*en 1ond (nd no-e' or*(ni& tr(ns)or%(tions in&'udin* %et2(ne to%et2(no' /er)or%ed 10 ( '(r*e nu%1er o) Fe &ont(inin* %et(''oen60%es " Le&tures$

Redu&ti-e &'e(-(*e o) dio80*en 1ond (nd no-e' or*(ni& tr(ns)or%(tions /er)or%ed 10 ('(r*e nu%1er o) Cu &ont(inin* %et(''oen60%es (nd s0nt2eti& &(t('0sts "+B Le&tures$

oo*s

,ioinor*(ni& C2e%istr0. I ,ertini. H , Gr(0. S Li//(rd (nd S ?('entine. Uni-ersit0S&ien&e ,oo=s.


50/55

CHM >3: C%e&!"al S'nt%et!" St#ate$' of A,8an"e, Mate#!als


Int#o,)"t!on:

?(riet0 o) inor*(ni& "tr(dition(' to (d-(n&ed$ %(teri('s. I%/ort(n&e o) Stru&tur('re)r(&tor0.E'e&troni& (nd ,io%(teri('s. O8ide su/er&ondu&tors (nd no-e' %(teri('s Des&ri/tion o)&r0st('s. ,ondin*. Inor*(nu& stru&tures. Si'i&(tes (nd A''u%inosi'i&(tes. Po'0t0/is%.N(no&r0st(''ine(%or/2ous so'ids

2= C%a#a"te#!at!on te"%n!/)es: Bo#*!n$ @no.le,$e r(0 di))r(&tion. E'e&tron (nd Neutron Di))r(&tion. AF< SE< TE


51/55

G(sP2(se nu&'e(tion. F'(%e 20dro'06ed /o9ders. Dire&t nitrid(tion (nd &(r1ot2er%i&redu&tion. Non/'(s%( *(s /2(se re(&tions. P'(s%( re(&tions. E'e&tron ,e(%e-(/or(tion

11= F#eee(,#'!n$ an, Ra+!, e7+ans!on of s)+e#"#!t!"al sol)t!ons Neb)l!e, s+#a'+'#ol's!s= 2

12= S+e"!al #ea"t!ons:


52/55

CHM >5 Mole")la# Mo,el!n$ !n C%e&!st#'


,rie) Re-ie9 o) t2e 1(si& Prin&i/'es o) qu(ntu% %e&2(ni&s o) (to%s (nd %o'e&u'esPotenti(' ener*0 sur)(&es (nd inter%o'e&u'(r inter(&tions: u(ntu% %e&2(ni&(' (1 initio&('&u'(tions 9it2in ,ornO//en2ei%er (//ro8i%(tion (nd %ode''in* o) &('&u'(ted ener*ies 10%ode' /otenti('s )or si%/'e (to%s. %o'e&u'es (nd ions Ener*0 &('&u'(tions usin* %o'e&u'(r%e&2(ni&s "+$

Si%/'e (//'i&(tions o) %o'e&u'(r %ode''in*: Stud0 o) (n (sse%1'0 o) (to%s or %o'e&u'es"&'usters (ndor 1u'= /2(ses$ A//ro8i%(tion o) t2e tot(' /otenti(' ener*0 (s t2e su% o) /(ir/otenti('s Con&e/t o) '(r*e nu%1er o) %i&rost(tes. (-er(*es (nd 1(si& /rin&i/'es o)si%u'(tions Stud0 o) &'uster (nd 1u'= /ro/erties t2rou*2 si%u'(tions "+!$


53/55

CHM >> )ant)& Co&+)t!n$


T2er%od0n(%i&s o) &o%/utin*. S2(nnon T2eor0. e'e%ent(r0 in)or%(tion t2eor0 "4$

,(si&s o) &o%/uters. C2ur&2Turin* 20/ot2esis. 1(si&s o) &o%/utin* &o%/'e8it0 "@$

,(si& o) qu(ntu% %e&2(ni&s. Fe0n%(n,'o&= Pseudo/o'(ri6(tion ?e&tor


54/55

CHM>< C%e&!st#' of D#)$ Des!$n an, Metabol!s&

Prerequisites: CH< @+No o) Le&tures: @4Credits: 3!! "#$

P20si&o&2e%i&(' Prin&i/'es o) Dru* A&tion5 P(rtition Coe))i&ients5 Re&e/torE))e&tor T2eories5Ro'e o) Se&ond


55/55

CHM> 6ase#s !n C%e&!st#' an, !olo$'

No o) Le&tures: @4P#e#e/)!s!tes: NoneUn!ts: 3!! "#$

Fund(%ent('s o) '(sers "@$

Gener(' &on&e/ts o) '(ser s/e&tros&o/0 "3$

L(serindu&ed )'uores&en&e (nd %u'ti/2oton ioni6(tion /ro&esses o) %o'e&u'es. /ro1in* I?R(nd d0n(%i&s o) &2e%i&(' re(&tions in 'iquid (nd %o'e&u'(r 1e(% "@$

S/e&tros&o/0 o) sin*'e %o'e&u'e. &on)o&(' %i&ros&o/0 (nd )'uores&en&e &orre'(tions/e&tros&o/0 "B$

Pro1in* o) /rotone'e&tron d0n(%i&s. (nisotro/0 "@$

O/ti&(' tr(//in* (nd %(ni/u'(tion o) 1io'o*i&(' %(&ro%o'e&u'es. (//'i&(tions o) di(*nosti&s(nd 1iote&2no'o*0 "@$

Pu'sed '(ser (nd u'tr()(st s/e&tros&o/0 "+!$

Non'ine(r s/e&tros&o/0 "$

oo*s:+ L(ser C2e%istr0. Te''e. H H (nd Uren(. A G. o2n >i'e0 Sons. Ne9 erse0. 4!!4 A Guide To L(sers In C2e%istr0. ?(n. H (nd GERALD. R ,(rt'ett Pu1. ,oston. +##

3 Non'ine(r L(ser C2e%istr0. Leto=2o-. ? S. S/rin*er?er'(*. +#3@ L(sers. i'e0 Sons. +#

Chemistry Syllabus at Iit Kanpur for Msc

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Transcript of Chemistry Syllabus at Iit Kanpur for Msc