Chemistry

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Strictly Based on the Latest Syllabus issued by CBSE Board for 2015 Examination

Chapter-Wise SolutionsQUESTION BANK

Includes Compartment (Solved) Paper - 2014

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09

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Compartment (Solved) Paper 2014 1 - 32

Solved Paper, 2014 1 - 31

Sample Question Paper, 2013 (Issued by CBSE) 1 - 7

As per Circular No. Acad. - 74/2013 Dt. 06 November 2013

Compartment Paper (Solved), 2013 9 - 32

1. The Solid State 1 - 20

2. Solutions 21 - 41

3. Electrochemistry 42 - 59

4. Chemical Kinetics 60 - 79

5. Surface Chemistry 80 - 93

6. General Principles and Process of Isolation of Elements 94 - 108

7. The p-Block Elements 109 - 128

8. The d-and f-Block Elements 129 - 145

9. Co-ordination Compounds and Organo metallics 146 - 162

10. Haloalkanes and Haloarenes 163 - 184

11. Alcohols, Phenols and Ethers 185 - 198

12. Aldehydes, Ketones and Carboxylic Acids 199 - 213

13. Organic Compounds Containing Nitrogen Amines 214 - 229

14. Biomolecules 230 - 243

15. Polymers 244 - 257

16. Chemistry in Everyday life 258 - 264

CONTENTS

OSWAAL CBSE Question Bank Chapterwise Solutions, Chemistry-XIIiv ]

One Paper Time : 3 Hours 70 Marks

Unit No. Title No. of Periods Marks

Unit I Solid State 10

Unit II Solutions 10

Unit III Electrochemistry 12 23

Unit IV Chemical Kinetics 10

Unit V Surface Chemistry 08

Unit VI General Principles and Processes of Isolation of Elements 08

Unit VII p-Block Elements 12

Unit VIII d- and f- Block Elements 12 19

Unit IX Co-ordination Compounds 12

Unit X Haloalkanes and Haloarenes 10

Unit XI Alcohols, Phenols and Ethers 10

Unit XII Aldehydes, Ketons and Carboxylic Acids 10

Unit XIII Organic Compounds containing Nitrogen 10 28

Unit XIV Biomolecules 12

Unit XV Polymers 08

Unit XVI Chemistry in Everyday Life 06

Total 160 70

Unit I : Solid State 10 Periods

Classification of solids based on different binding forces: molecular, ionic, covalent and metallicsolids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and threedimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids,number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.

Band theory of metals, conductors, semiconductors and insulators and n and p type semiconduc-tors.

Unit II : Solutions 10 Periods

Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gasesin liquids, solid solutions, colligative properties - relative lowering of vapour pressure, Raoult’slaw, elevation of boiling point, depression of freezing point, osmotic pressure, determination ofmolecular masses using colligative properties, abnormal molecular mass, Van’t Hoff factor.

Unit III : Electrochemistry 12 Periods

Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variationsof conductivity with concentration, Kohlrausch’s Law, electrolysis and law of electrolysis (elemen-tary idea), dry cell-electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standardelectrode potential, Nernst equation and its application to chemical cells, Relation between Gibbsenergy change and EMF of a cell, fuel cells, corrosion.

Unit IV : Chemical Kinetics 10 Periods

Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration,temperature, catalyst; order and molecularity of a reaction, rate law and specific rateconstant,integrated rate equations and half life (only for zero and first order reactions), concept ofcollision theory (elementary idea, no mathematical treatment). Activation energy, Arrhenious equation.

SYLLABUS Chemistry (043)Class XII (2014-15)

Total Periods (Theory 160 + Practical 60)

SYLLABUS [ v

Unit V : Surface Chemistry 08 Periods

Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids,catalysis, homogenous and heterogenous activity and selectivity; enzyme catalysis colloidal statedistinction between true solutions, colloids and suspension; lyophilic, lyophobic multimolecularandmacromolecular colloids; properties of colloids; Tyndall effect, Brownian movement,electrophoresis,coagulation, emulsion - types of emulsions.

Unit VI : General Principles and Processes of Isolation of Elements 08 Periods

Principles and methods of extraction - concentration, oxidation, reduction - electrolytic method andrefining; occurrence and principles of extraction of aluminium, copper, zinc and iron.

Unit VII : “p”-Block Elements 12 Periods

Group -15 Elements: General introduction, electronic configuration, occurrence, oxidation states,trends in physical and chemical properties; Nitrogen preparation properties and uses; compoundsof Nitrogen, preparation and properties of Ammonia and Nitric Acid, Oxides of Nitrogen(Structureonly) ; Phosphorus - allotropic forms, compounds of Phosphorus: Preparation and Properties ofPhosphine, Halides and Oxoacids (elementary idea only).

Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence,trends in physical and chemical properties, dioxygen: Preparation, Properties and uses, classifica-tion of Oxides, Ozone, Sulphur -allotropic forms; compounds of Sulphur: Preparation Propertiesand uses of Sulphur-dioxide, Sulphuric Acid: industrial process of manufacture, properties anduses; Oxoacids of Sulphur (Structures only).

Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence,trends in physical and chemical properties; compounds of halogens, Preparation, properties anduses of Chlorine and Hydrochloric acid, interhalogen compounds, Oxoacids of halogens (struc-tures only).

Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physicaland chemical properties, uses.

Unit VIII : “d” and “f” Block Elements 12 Periods

General introduction, electronic configuration, occurrence and characteristics of transition metals,general trends in properties of the first row transition metals - metallic character, ionization en-thalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial com-pounds, alloy formation, preparation and properties of K

2Cr

2O

7 and KMnO

4.

Lanthanoids - Electronic configuration, oxidation states, chemical reactivity and lanthanoid con-traction and its consequences.

Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.

Unit IX : Coordination Compounds 12 Periods

Coordination compounds - Introduction, ligands, coordination number, colour, magnetic proper-ties and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner’stheory, VBT, and CFT; structure and stereoisomerism, importance of coordination compounds (inqualitative inclusion, extraction of metals and biological system).

Unit X : Haloalkanes and Haloarenes. 10 Periods

Haloalkanes: Nomenclature, nature of C -X bond, physical and chemical properties, mechanism ofsubstitution reactions, optical rotation.

Haloarenes: Nature of C -X bond, substitution reactions (Directive influence of halogen in mono-substituted compounds only).

Uses and environmental effects of - dichloromethane, trichloromethane, tetrachloromethane, iodo-form, freons, DDT.

Unit XI : Alcohols, Phenols and Ethers 10 Periods

Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primaryalcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydra-tion, uses with special reference to methanol and ethanol.

Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic natureof phenol, electrophillic substitution reactions, uses of phenols.

Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.

OSWAAL CBSE Question Bank Chapterwise Solutions, Chemistry-XIIvi ]

Unit XII : Aldehydes, Ketones and Carboxylic Acids 10 Periods

Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physi-cal and chemical properties, mechanism of nucleophilic addition, reactivity of alpha hydrogen inaldehydes: uses.

Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemicalproperties; uses.

Unit XIII : Organic compounds containing Nitrogen 10 Periods

Amines: Nomenclature, classification, structure, methods of preparation, physical and chemicalproperties, uses, identification of primary, secondary and tertiary amines.

Cyanides and Isocyanides - will be mentioned at relevant places in text.

Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.

Unit XIV : Biomolecules 12 Periods

Carbohydrates - Classification (aldoses and ketoses), monosaccahrides (glucose and fructose), D-L configuration oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose,glycogen); Importance of carbohydrates.

Proteins -Elementary idea of - amino acids, peptide bond, polypeptides, proteins, structure of pro-teins -primary, secondary, tertiary structure and quaternary structures (qualitative idea only), dena-turation of proteins; enzymes. Hormones - Elementary idea excluding structure.

Vitamins - Classification and functions.

Nucleic Acids: DNA and RNA.

Unit XV : Polymers 08 Periods

Classification - natural and synthetic, methods of polymerization (addition and condensation),copolymerization, some important polymers: natural and synthetic like polythene, nylon polyes-ters, bakelite, rubber. Biodegradable and non-biodegradable polymers.

Unit XVI : Chemistry in Everyday life 06 Periods

Chemicals in medicines - analgesics, tranquilizers antiseptics, disinfectants, antimicrobials, anti-fertility drugs, antibiotics, antacids, antihistamines.

Chemicals in food - preservatives, artificial sweetening agents, elementary idea of antioxidants.

Cleansing agents- soaps and detergents, cleansing action.

PRACTICALS

Evaluation Scheme for Examination Marks

Volumetric Analysis 08

Salt Analysis 08

Content Based Experiment 06

Project work 04

Class record and viva 04

Total 30

PRACTICALS SYLLABUS 60 Periods

Micro-chemical methods are available for several of the practical experiments.

Wherever possible, such techniques should be used.

A. Surface Chemistry

(a) Preparation of one lyophilic and one lyophobic sol

Lyophilic sol - starch, egg albumin and gum

Lyophobic sol - aluminium hydroxide, ferric hydroxide, arsenous sulphide.

(b) Dialysis of sol-prepared in (a) above.

(c) Study of the role of emulsifying agents in stabilizing the emulsion of different oils.

B. Chemical Kinetics

(a) Effect of concentration and temperature on the rate of reaction between Sodium Thiosulphate andHydrochloric acid.

SYLLABUS [ vii

(b) Study of reaction rates of any one of the following:

(i) Reaction of Iodide ion with Hydrogen Peroxide at room temperature using different concenration of Iodide ions.

(ii) Reaction between Potassium Iodate, (KIO3) and Sodium Sulphite: (Na2SO3) using starch solu-tion as indicator (clock reaction).

C. ThermochemistryAny one of the following experimentsi) Enthalpy of dissolution of Copper Sulphate or Potassium Nitrate.ii) Enthalpy of neutralization of strong acid (HCI) and strong base (NaOH).iii) Determination of enthaply change during interaction (Hydrogen bond formation) between Acetone

and Chloroform.D. Electrochemistry

Variation of cell potential in Zn/Zn2+|| Cu2+/Cu with change in concentration of electrolytes (CuSO4 or

ZnSO4)at room temperature.

E. Chromatographyi) Separation of pigments from extracts of leaves and flowers by paper chromatography and determi-

nation of Rf values.ii) Separation of constituents present in an inorganic mixture containing two cations only (constitu-

ents having large difference in Rf values to be provided).F. Preparation of Inorganic Compounds

i) Preparation of double salt of Ferrous Ammonium Sulphate or Potash Alum.ii) Preparation of Potassium Ferric Oxalate.

G. Preparation of Organic CompoundsPreparation of any one of the following compoundsi) Acetanilide ii) Di -benzal Acetoneiii) p-Nitroacetanilide iv) Aniline yellow or 2 - Naphthol Aniline dye.

H. Tests for the functional groups present in organic compounds:Unsaturation, alcoholic, phenolic, aldehydic, ketonic, carboxylic and amino (Primary) groups.

I. Characteristic tests of carbohydrates, fats and proteins in pure samples and their detection in givenfood stuffs.

J. Determination of concentration/ molarity of KMnO4 solution by titrating it against a standard solution of:i) Oxalic acid, ii) Ferrous Ammonium Sulphate

(Students will be required to prepare standard solutions by weighing themselves).K. Qualitative analysis

Determination of one cation and one anion in a given salt.Cation - Pb2+, Cu2+, As3+, Al3+, Fe3+, Mn2+, Zn2+, Lu2+, Co2+, Ni2+, Ca2+, Sr2+, Ba2+, Mg2+,NH+

4

Anions - Co2-3, S2-, SO2-

3, SO2-

4, NO-

2, Cl-, Br-, I-, PO3-

4, C

2O2-

4, CH

4COO–

(Note: Insoluble salts excluded)

PROJECT

Scientific investigations involving laboratory testing and collecting information from other sources.

A few suggested Projects.

• Study of the presence of oxalate ions in guava fruit at different stages of ripening.

• Study of quantity of casein present in different samples of milk.

• Preparation of soybean milk and its comparison with the natural milk with respect to curd forma-tion, effect of temperature, etc.

• Study of the effect of Potassium Bisulphate as food preservative under various conditions (tempera-ture, concentration, time, etc.)

• Study of digestion of starch by salivary amylase and effect of pH and temperature on it.

• Comparative study of the rate of fermentation of following materials: wheat flour, gram flour, potatojuice, carrot juice, etc.

• Extraction of essential oils present in Saunf (aniseed), Ajwain (carum), Illaichi (cardamom).

• Study of common food adulterants in fat, oil, butter, sugar, turmeric power, chilli powder and pepper.

Note: Any other investigatory project, which involves about 10 periods of work, can be chosen with theapproval of the teacher.

QUESTION PAPER DESIGN

S. Typology of Questions VSA SA-I SA-II VBQ LA Total %No. (1 mark) (2 mark) (3 mark) (4 mark) (5 mark) Marks Weightage

1. Remembering- 2 1 1 – – 7 10%(Knowledge basedSimple recallquestions, to knowspecific facts, terms,concepts, principles,or theories, Identify,define,or recite,information)

2. Understanding- – 2 4 – 1 21 30%Comprehension -tobe familiar withmeaning and tounderstandconceptually,interpret, compare,contrast, explain,paraphraseinformation)

3. Application (Use – 2 4 – 1 21 30%abstract informationin concrete situation,to apply knowledgeto new situations,Use given content tointerpret asituation, provide anexample, or solve aproblem)

4. High Order 2 – 1 – 1 10 14%Thinking Skills(Analysis &Synthesis- Classify,compare, contrast, ordifferentiate betweendifferent pieces ofinformation,Organize and/orintegrate uniquepieces of informationfrom a variety ofsources)

5. Evaluation and 1 – 2 1 – 11 16%Multi-Disciplinary-(Appraise, judge,and/or justify thevalue or worth of adecision or outcome,or to predictoutcomes based onvalues)

TOTAL 5×1=5 5×2=10 12×3=36 1×4=4 3×5=15 70(26) 100%

QUESTION WISE BREAK UP

Type of Questions Mark per Question Tatal No. of Questions Total Marks

VSA 1 5 05SA-I 2 5 10SA-II 3 12 36VBQ 4 1 04LA 5 3 15

Total 26 70

1. Internal Choice : There is no overall choice in the paper. However, there is an internal choice in one questions of 2 marksweightage, one question of 3 marks weightage and all the three questions of 5 marks weightage.

2. The above template is only a sample. Suitable internal variations may be made for generating similar templates keeping theoverall weightage to different form of questions and typology of questions same.

( viii )

Compartment (Solved) Paper, 2014 | 1

C.B.S.E. 2014Class – XII

CompartmentSolvedPaper

Chemistry

Time allowed : 3 hours ] [ Maximum Marks : 70

General Instructions : (i) All questions are compulsory.

(ii) Questions Number 1 to 8 are very short answer questions and carry 1 mark each.

(iii) Questions Number 9 to 18 are short answer questions and carry 2 marks each.

(iv) Questions Number 19 to 27 are also short answer questions and carry 3 marks each.

(v) Questions Number 28 to 30 are long answer questions and carry 5 marks each.

(vi) Use Log Tables, if necessary. Use of calculators is not allowed.

Delhi Set I Code No. 56/1/1 1. How many atoms per unit cell (z) are present in bcc unit cell ? 1 2. What is the difference between lyophobic sol and lyophilic sol ? 1 3. Draw the structure of XeF2. 1 4. What is the function of SiO2 in the metallurgy of copper ? 1 5. Why do transition elements show variable oxidation states ? 1 6. Draw the structure of 2-bromopentane. 1 7. Write the IUPAC name of the following compound : 1 CH3 – CH – CHO | CH3

8. Out of CH3 –NH2 and (CH3)3N, which one has higher boiling point ? 1 9. How is the vapour pressure of a solvent affected when a non-volatile solute is dissolved in it ? 210. (a) For a reaction, A + B → Product, the rate law is given by, Rate = k[A]1 [B]2. What is the

order of the reaction ?

(b) Writetheunitofrateconstant‘k’forthefirstorderreaction. 211.Definethefollowingterms: (i) Roasting,

(ii) Calcination. 212. Draw the structure of each of the following :

(i) H2SO4

(ii) Solid PCl5 213. Assign a reason for each of the following observations :

(i) The transition metals (with the exception of Zn, Cd and Hg) are hard and have high melting and boiling points.

(ii) Theionisationenthalpies(firstandsecond)inthefirstseriesofthetransitionelementsare found to vary irregularly. 2

OR What is lanthanoid contraction ? Write a consequence of lanthanoid contraction.

cont inue

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