XL-H Chemistry

Section 1: Atomic Structure and Periodicity Plancks quantum theory, wave particle duality, uncertainty principle, quantum mechanical model of hydrogen atom, electronic configuration of atoms and ions. Periodic table and periodic properties: ionization energy, electron affinity, electronegativity and atomic size.

Section 2: Structure and Bonding Ionic and covalent bonding, MO and VB approaches for diatomic molecules, VSEPR theory and shape of molecules, hybridization, resonance, dipole moment, structure parameters such as bond length, bond angle and bond energy, hydrogen bonding and van der Waals interactions. Ionic solids, ionic radii and lattice energy (BornHaber cycle). HSAB principle.

Section 3: s, p and d Block Elements Oxides, halides and hydrides of alkali, alkaline earth metals, B, Al, Si, N, P, and S. General characteristics of 3d elements. Coordination complexes: valence bond and crystal field theory, color, geometry, magnetic properties and isomerism.

Section 4: Chemical Equilibria Colligative properties of solutions, ionic equilibria in solution, solubility product, common ion effect, hydrolysis of salts, pH, buffer and their applications. Equilibrium constants (Kc, Kp and Kx) for homogeneous reactions.

Section 5: Electrochemistry Conductance, Kohlrausch law, cell potentials, emf, Nernst equation, Galvanic cells, thermodynamic aspects and their applications.

Section 6: Reaction Kinetics Rate constant, order of reaction, molecularity, activation energy, zero, first and second order kinetics, catalysis and elementary enzyme reactions.

Section 7: Thermodynamics First law, reversible and irreversible processes, internal energy, enthalpy, Kirchoff equation, heat of reaction, Hesss law, heat of formation. Second law, entropy, free energy and work function. GibbsHelmholtz equation, ClausiusClapeyron equation, free energy change, equilibrium constant and Troutons rule. Third law of thermodynamics.

Section 8: Structure-Reactivity Correlations and Organic Reaction Mechanisms Acids and bases, electronic and steric effects, optical and geometrical isomerism, tautomerism, conformers and concept of aromaticity. Elementary treatment of SN1, SN2, E1 and E2 reactions, Hoffmann and Saytzeff rules, addition reactions, Markownikoff rule and Kharash effect. Aromatic electrophilic substitutions, orientation effect as exemplified by various functional groups. DielsAlder, Wittig and hydroboration reactions. Identification of functional groups by chemical tests.

Section1: Engineering MathematicsSection 2: Flight MechanicsSection 3: Space DynamicsSection 4: AerodynamicsSection 5: StructuresSection 6: PropulsionSection 1: Engineering MathematicsSection 2: Farm MachinerySection 3: Farm PowerSection 4: Soil and Water Conservation EngineeringSection 5: Irrigation and Drainage EngineeringSection 6: Agricultural Processing EngineeringSection 7: Dairy and Food EngineeringArchitecture and PlanningARSection 1: Architecture and DesignSection 2: Building Materials, Construction and ManagementSection 3: Building and StructuresSection 4: Environmental Planning and DesignSection 5: Urban DesignSection 6: Urban Planning and HousingSection 7: Planning Techniques and ManagementSection 8: Services, Infrastructure and TransportationSection 1: Engineering MathematicsSection 2: General BiotechnologySection 3: Recombinant DNA TechnologySection 4: Plant and Animal BiotechnologySection 5: Bioprocess Engineering and Process BiotechnologySection 1: Engineering MathematicsSection 2: Structural EngineeringSection 3: Geotechnical EngineeringSection 4: Water Resources EngineeringSection 5: Environmental EngineeringSection 6: Transportation EngineeringSection 7: Geomatics EngineeringSection 1: Engineering MathematicsSection 2: Process Calculations and ThermodynamicsSection 3: Fluid Mechanics and Mechanical OperationsSection 4: Heat TransferSection 5: Mass TransferSection 6: Chemical Reaction EngineeringSection 7: Instrumentation and Process ControlSection 8: Plant Design and EconomicsSection 9: Chemical TechnologySection1: Engineering MathematicsSection 2: Digital LogicSection 3: Computer Organization and ArchitectureSection 4: Programming and Data StructuresSection 5: AlgorithmsSection 6: Theory of ComputationSection 7: Compiler DesignSection 8: Operating SystemSection 9: DatabasesSection 10: Computer NetworksSection 1: Physical ChemistrySection 2: Inorganic ChemistrySection 3: Organic ChemistrySection 1: Engineering MathematicsSection 2: Networks, Signals and SystemsSection 3: Electronic DevicesSection 4: Analog CircuitsSection 5: Digital CircuitsSection 6: Control SystemsSection 7: CommunicationsSection 8: ElectromagneticsSection 1: Engineering MathematicsSection 2: Electric CircuitsSection 3: Electromagnetic FieldsSection 4: Signals and SystemsSection 5: Electrical MachinesSection 6: Power SystemsSection 7: Control SystemsSection 8: Electrical and Electronic MeasurementsSection 9: Analog and Digital ElectronicsSection 10: Power ElectronicsSection 1: EcologySection 2: EvolutionSection 3: Mathematics and Quantitative EcologySection 4: Behavioural EcologyPart A: GeologyPart - B: GeophysicsSection 1: Engineering MathematicsSection 2: Electrical Circuits:Section 3: Signals and SystemsSection 4: Control SystemsSection 5: Analog ElectronicsSection 6: Digital ElectronicsSection 7: MeasurementsSection 8: Sensors and Industrial InstrumentationSection 9: Communication and Optical InstrumentationSection 1: Linear AlgebraSection 2: Complex AnalysisSection 3: Real AnalysisSection 4: Ordinary Differential EquationsSection 5: AlgebraSection 6: Functional AnalysisSection 7: Numerical AnalysisSection 8: Partial Differential EquationsSection 9: TopologySection 10: Probability and StatisticsSection 11: Linear programmingSection 1: Engineering MathematicsSection 2: Applied Mechanics and DesignSection 3: Fluid Mechanics and Thermal SciencesSection 4: Materials, Manufacturing and Industrial EngineeringSection 1: Engineering MathematicsSection 2: Mine Development and SurveyingSection 3: Geomechanics and Ground ControlSection 4: Mining Methods and MachinerySection 5: Surface Environment, Mine Ventilation, and Underground HazardsSection 6: Mine Economics, Mine Planning, Systems EngineeringSection 1: Engineering MathematicsSection 2: Thermodynamics and Rate ProcessesSection 3: Extractive MetallurgySection 4: Physical MetallurgySection 5: Mechanical MetallurgySection 6: Manufacturing ProcessesSection 1: Mathematical PhysicsSection 2: Classical MechanicsSection 3: Electromagnetic TheorySection 4: Quantum MechanicsSection 5: Thermodynamics and Statistical PhysicsSection 6: Atomic and Molecular PhysicsSection 7: Solid State Physics & ElectronicsSection 8: Nuclear and Particle PhysicsSection 1: Engineering MathematicsSection 2: General EngineeringSection 3: Manufacturing Processes ISection 4: Manufacturing Processes IISection 5: Qualityand ReliabilitySection 6: Industrial EngineeringSection 7: Operations research and Operations managementSection 1: Textile FibersSection 2: Yarn manufacture, Yarn structure and PropertiesSection 3: Fabric manufacture, Structure and PropertiesSection 4: Textile TestingSection 5: Chemical processingSection 1: Linear AlgebraSection 2: CalculusSection 3: Vector CalculusSection 3: Complex variablesSection 4: Ordinary Differential EquationsSection 5: Partial Differential EquationsSection 6: Probability and StatisticsSection 7: Numerical MethodsSection 1: Flow and Fluid PropertiesSection 2: KinematicsSection 3: Integral analysisSection 4: Differential AnalysisSection 5: Inviscid flowsSection 6: Dimensional analysisSection 7: Internal flowsSection 8: Prandtl boundary layer equationsSection 1: Processing of Materials:Section 2: Characterisation Techniques:Section 3: Structure and Imperfections:Section 4: Thermodynamics and Kinetics:Section 5: Properties of Materials:Section 6: Material typesSection 7: Environmental DegradationSection 8: Elements of Quantum Mechanics and MathematicsSection 1: Basic ConceptsSection 2: First Law of ThermodynamicsSection 3: Second Law of ThermodynamicsSection 4: Properties of Pure SubstancesSection 5: Thermodynamic RelationsSection 6: Thermodynamic CyclesSection 7: Ideal Gas MixturesSection 1: Chemistry of high polymersSection 2: Polymer CharacterizationSection 3: Synthesis and propertiesSection 4: Polymer blends and compositesSection 5: Polymer TechnologySection 6: Polymer rheologySection 7: Polymer processingSection 8: Polymer testingSection 1: Food Chemistry and Nutrition:Section 2: Food Microbiology:Section 3: Food Products Technology:Section 4: Food Engineering:Section 1: Atomic Structure and PeriodicitySection 2: Structure and BondingSection 3: s, p and d Block ElementsSection 4: Chemical EquilibriaSection 5: ElectrochemistrySection 6: Reaction KineticsSection 7: ThermodynamicsSection 8: StructureReactivity Correlations and Organic Reaction MechanismsSection 1:Section 2:Section 3:Section 4:Section 5:Section 6:Section 1: Plant SystematicsSection 2: Plant Anatomy:Section 3: Morphogenesis & DevelopmentSection 4: Physiology and BiochemistrySection 5: GeneticsSection 6: Plant Breeding and Genetic ModificationSection 7: Economic BotanySection 8: Plant PathologySection 9: Ecology and EnvironmentSection 1: Historical PerspectiveSection 2: Methods in MicrobiologySection 3: Microbial Taxonomy and DiversitySection 4: Prokaryotic and Eukaryotic Cells: Structure and FunctionSection 5: Microbial GrowthSection 6: Control of Micro-organismsSection 7: Microbial MetabolismSection 8: Microbial Diseases and Host Pathogen InteractionSection 8: Chemotherapy/AntibioticsSection 9: Microbial GeneticsSection 10: Microbial EcologySection 1: Animal worldSection 2: EvolutionSection 3: GeneticsSection 4: Biochemistry and Molecular BiologySection 5: Cell BiologySection 6: Gene expression in EukaryotesSection 7: Animal Anatomy and PhysiologySection 8: Parasitology and ImmunologySection 9: Development BiologySection 10: EcologySection 11: Animal BehaviourSection 1: Food Chemistry and NutritionSection 2: Food MicrobiologySection 3: Food Products TechnologySection 4: Food Engineering