Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion –...

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Chemistry Day 23 Tuesday, November 5 th - Wednesday, November 6 th , 2019

Transcript of Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion –...

Page 1: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Chemistry Day 23 Tuesday, November 5th - Wednesday,

November 6th, 2019

Page 2: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Do-Now: “PT Quiz Review Do-Now” 1.  Write down today’s FLT 2.  What are valence electrons? 3.  Identify the group number, name, and number of

valence electrons for our four main representative groups

4.  Distinguish between transition metals and inner transition metals.

5.  Bob says that Na has a larger atomic radius than Cl. He says this is because Cl has more protons (17 versus 11), and therefore a greater effective nuclear charge that pulls electrons in closer, resulting in Cl’s smaller radius. What is MISSING from this explanation?

6.  Which has a bigger atomic radius and WHY: Na or Li? Be specific and descriptive.

7.  Take a few minutes to review your explanations for ALL of your trends.

Take out your planner and ToC

Page 3: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

FLT •  I will be able to explain how anions and

cations form by completing Ions CN

Standard HS-PS1-1:Usetheperiodictableasamodeltopredicttherelativepropertiesofelementsbasedonthepatternsofelectronsintheoutermostenergylevelofatoms.

Page 4: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ions

Page 5: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Recall

Page 6: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Valence Electrons

•  Valence electrons (ve-s) = e-s in the outermost shell (highest s and p orbitals) that can participate in chemical bonding

Page 7: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 8: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Valence Electrons •  Valence electrons à determine the

chemical properties of atoms •  These are located in the s and p orbitals

of the highest occupied energy level

Page 9: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Valence Electrons •  ve-s match the group number for

representative elements

Page 10: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Electron Dot Diagrams •  Lewis Dot Diagrams =

Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s

surrounding – Hund’s rule – don’t double up

until you have to X

Page 11: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Electron Dot Diagrams

•  Ex/ •  F •  Ne •  N

Page 12: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Forming Ions

Page 13: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Recall •  Noble gases are inert gases – they are

highly unreactive •  Noble gases = have eight ve-s and

completely filled outer sublevels

Page 14: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

The Octet Rule •  The Octet Rule = Elements gain or

lose e-s in order to obtain a noble gas configuration (8 ve-s or He 2ve-s) – Each noble gas (except He, which has 2) has 8

electrons in the outer level

Page 15: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ions •  Atoms can gain or lose electrons to form

ions – Cations = (+) charged ions

• Ex/ Ca2+ – Anions = (-) charged ions

• Ex/ F-

Page 16: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Cations •  Metals lose their ve-s to form cations –  They form the configuration of the closest noble gas

that’s smaller than them

Na 1s22s22p63s1 – 1 valence electron

•  Na+1 1s22s22p6 – This is a noble gas configuration with 8 electrons

in the outer level.

Page 17: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Cations •  Examples

– K

– Ca

– Al

Page 18: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Cations •  Their charge should match their group

number

Page 19: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Subatomic Particles •  Be sure to account for the change in

electron number for ions •  Ex/ How many protons and electrons in…

Ca vs Ca+2

Page 20: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

What are the e- configurations? •  Examples

– K+

– Al3+

Page 21: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Anions •  Nonmetals gain e-s to form anions

– They form the configuration of the closest noble gas that’s bigger than them

•  S = 1s22s22p63s23p4 – 6 valence electrons

•  S2- = 1s22s22p63s23p6 – noble gas configuration.

Page 22: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Anions •  Examples

– Br

– O

– N

Page 23: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Anions •  Group 7A: -1 •  Group 6A: -2 •  Group 5A: -3

Page 24: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

What are their e- configurations? •  Examples

– Br-

– O2-

Page 25: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Formation of Anions

Page 26: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Pair-Share-Respond1.   Whatarevalenceelectrons?2.   Distinguishbetweenanionsand

cations3.   Howdometalsandnonmetalsform

ions?4.   Statetheoctetrule5.   Whatwouldbelargerandwhy:ForF-?

Page 27: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Chemistry Day 24 Thursday, November 6th – Friday,

November 7th, 2019

Page 28: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Do-Now: “Cat Inquiry Do-Now” 1.  Write down today’s FLT

2.  Define the terms anions and cations 3.  Why do atoms form ions? 4.  What ion will the Rb form? Show your work 5. Copy and complete: N has a ____ atomic radius

compared to C. Since both N and C have a principal quantum number of ___, this means that the ____ are the ____ and the e-s are at about the ____ distance from the nucleus. However, since N has ____ protons compared to C’s ____ protons, this means that the __________ between protons and e-s is stronger in ______, causing the electrons to be pulled ______ and the overall atomic radius is _______ than C’s.

6.  Turn in your ToC#2 if you haven’t already. Take out your planner and ToC

Page 29: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Video Clip • Wewillwatchavideoclipaboutcatsandballoons

•  Underneathyourdo-now…•  Useyourpro-talksentenceframe“Inmyopinion…because…”tomakeapredictionaboutwhatyouTHINKwillhappen.

Page 30: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 31: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Video Clip •  Now,writedownthreequestionsyouhaveaboutthevideo.

Page 32: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Video Clip •  Discussyourquestionswithyourgroup.•  Decideasagroupwhichquestionisthe“best”orthemostinteresting,andeveryoneshouldwriteitontheirpaper.

•  Pickaquestionthatshouldbeanswerableifgivensomeadditionalevidence.

•  Ifitisyourownquestion,placeastarnexttoit.

Page 33: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Video Clip •  Now,wewillwatchavideo.•  Duringthevideo,writedownoneortwopiecesofevidencethatcanhelpyouexplainwhat’shappening.

Page 34: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 35: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Video Clip •  Usetheinformationfromthevideotoansweryourquestion.

•  Useoneofthefollowingpro-talksentenceframes:– “FirstIconsidered…,then…____...Provesmyclaimbecause…”

– “Ifwelookatboth….and….Wecanseethat….”

– “Basedontheevidence,wecanconcludethat….”

Page 36: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

FLT •  I will be able to write the formulas and

describe properties of ionic compounds by completing Ionic Bonding CN

Standard HS-PS1-1:Usetheperiodictableasamodeltopredicttherelativepropertiesofelementsbasedonthepatternsofelectronsintheoutermostenergylevelofatoms.

Page 37: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding

Page 38: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Recall

Page 39: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

The Octet Rule •  The Octet Rule = Elements gain or lose

e-s in order to obtain a noble gas configuration (8 ve-s or He 2ve-s)

Page 40: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ions •  Atoms can gain or lose electrons to form

ions – Metals lose e-s to form cations

• Ex/ Ca2+ – Nonmetals gain e-s to form anions

• Ex/ F-

Page 41: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 42: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ions •  What charges would the following atoms

have if they became ions? – Na – Cl – F – Ba – Ca – O

Page 43: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Compounds

Page 44: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Compounds •  So far, we have been looking at atoms

by themselves •  Compounds = substances made of

atoms of 2+ elements chemically combined in fixed ratios

Examples: NaCl CaF2 H2O

Mg(OH)2

Page 45: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Compounds •  Compounds are held together by

chemical bonds such as ionic bonds, covalent bonds, and more!

CH4

Page 46: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding

Page 47: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding •  Anions and cations are held together by

opposite charges (+ and -) •  Ionic Bond = Strong electrostatic

attraction between an anion and cation

Page 48: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 49: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding •  Salts = Ionic compounds (ex/ NaCl)

– Formed through the transfer of e-s

Page 50: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding •  Also called SALTS •  Made from: a CATION with an ANION

– or literally from a metal (+) combining with a nonmetal (-)

Page 51: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Ionic Bonding

•  The metal (sodium) tends to lose its one electron from the outer level.

•  The nonmetal (chlorine) needs to gain one more to fill its outer level, and will accept the one electron that sodium is going to lose.

Na Cl

Page 52: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas

Page 53: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas •  Metals are always written 1st

– Ex: NaCl vs ClNa

Page 54: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas •  When ions have equal and opposite

charges, they bond together in a 1:1 ratio – Ex: Na and F

– Ex: Mg and S

– Ex: Al and P

Page 55: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas •  The charges of ions in a chemical

formula must always sum to 0 •  What happens if the charges are not

equal and opposite? – Ex/ Calcium and Fluorine

Page 56: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas •  If ions do not have the same charge, you

must find the lowest common multiple – Ex/ Ca and F

Page 57: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Writing Formulas •  If ions do not have the same charge, you

must find the lowest common multiple – Ex/ Mg and P

Page 58: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Do-Now •  Write the following formulas:

a. Mg and O

b. Li and F

c. Li and S

d. Mg and S

e. Ca and N

Page 59: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Properties of Ionic Compounds 1.  Ionic solids have crystalline

structures - a regular repeating arrangement of ions in the solid

–  Ions are strongly bonded together. –  Structure is rigid, but brittle

Page 60: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Coordination Numbers:

Both the sodium and chlorine have 6

Both the cesium and chlorine have 8

Each titanium has 6, and each oxygen has 3

NaCl

CsCl

TiO2

Coordination number- number of ions of opposite charge surrounding it

Page 61: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 62: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up
Page 63: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Properties of Ionic Compounds 2.  High melting points •  It requires a lot of energy to change

from a solid to a liquid •  High boiling point as well

Page 64: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Do they Conduct?

•  Conducting electricity means allowing charges to move.

•  In a solid, the ions are locked in place. •  Ionic solids are insulators. •  When melted, the ions can move around. 3.  Melted ionic compounds are

conductors. –  NaCl: must get to about 800 ºC. –  Dissolved in water, they also conduct (free

to move in aqueous solutions)

Page 65: Chemistry Day 23 · • Lewis Dot Diagrams = Notation for showing the ve-s for an atom or ion – Write symbol with valence e-s surrounding – Hund’s rule – don’t double up

Pair-Share-Respond1.   Whatarecompounds?2.   Definetheterm“ionicbond”3.   Howareionicbondsformed?4.   PredicttheformulaforAluminumand

Oxygen