Chemistry 2

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Chemistry 2 Lecture 1 Quantum Mechanics in Chemistry

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Chemistry 2. Lecture 1 Quantum Mechanics in Chemistry. Your lecturers. 12pm Adam Bridgeman Room 543A adam.bridgeman@ sydney.edu.au. 8am Asaph Widmer -Cooper Room 316 asaph.widmer-cooper@ sydney.edu.au. Revision – H 2 +. Near each nucleus, electron should behave as a 1s electron. - PowerPoint PPT Presentation

Transcript of Chemistry 2

Page 1: Chemistry 2

Chemistry 2

Lecture 1 Quantum Mechanics in Chemistry

Page 2: Chemistry 2

Your lecturers

12pmAdam Bridgeman

Room [email protected]

8amAsaph Widmer-Cooper

Room 316 [email protected]

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Revision – H2+

• Near each nucleus, electron should behave as a 1s electron.

• At dissociation, 1s orbital will be exact solution at each nucleus

Y

r

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Revision – H2+

• At equilibrium, we have to make the lowest energy possible using the 1s functions available

Y

r

Y

r ?

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Revision – H2+

Y

1sA 1sB

Y

1sA 1sB

Y = 1sA – 1sB

1sA1sB

E

bonding

anti-bonding

Y = 1sA + 1sB

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Revision – H2

Y

1sA 1sB

Y

1sA 1sB

Y = 1sA – 1sB

1sA1sB

E

bonding

anti-bonding

Y = 1sA + 1sB

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Revision – He2

Y

1sA 1sB

Y

1sA 1sB

Y = 1sA – 1sB

1sA1sB

E

bonding

anti-bonding

Y = 1sA + 1sB

NOT BOUND!!

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2nd row homonuclear diatomics

• Now what do we do? So many orbitals!

1s 1s

2s 2s

2p2p

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Interacting orbitalsOrbitals can interact and combine to make new approximate solutions to the Schrödinger equation. There are two considerations:1.Orbitals interact inversely proportionally to their energy difference. Orbitals of the same energy interact completely, yielding completely mixed linear combinations. In quantum mechanics, energy and frequency are related (E=hn). So, energy matching is equivalent to the phenomenon of resonance.

2.The extent of orbital mixing is given by the resonance integral b. We will show how beta is calculated in a later lecture.

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Interacting orbitals1. Orbitals interact proportionally to the inverse of their energy

difference. Orbitals of the same energy interact completely, yielding completely mixed linear combinations.

1s 1s

2s 2s

2p2p

sBsA 2221

sBsA 2221

sA2 sB2

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(First year) MO diagramOrbitals interact most with the corresponding orbital on the other atom

to make perfectly mixed linear combinations. (we ignore core).

2s 2s

2p2p

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Molecular Orbital Theory - Revision

s p

s* p*

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Molecular Orbital Theory - Revision• Can predict bond strengths qualitatively

N2 Bond Order = 3

*2 sp

*2 pp

sp2

pp2

ss2

*2 ss

diamagnetic

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Interacting orbitals1. The extent of orbital mixing is given by the integral

somethingb

1s 1s

2s 2s

2p2p

s s2 s p2

The 2s orbital on one atom can interact with the 2p from the other atom, but since they have different energies this is a smaller interaction than the 2s-2s interaction. We will deal

with this later.

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Interacting orbitals1. The extent of orbital mixing is given by the integral

0b

1s 1s

2s 2s

2p2p

s s2 p p2

cancels

There is no net interaction between these orbitals.The positive-positive term is cancelled by the positive-negative term

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More refined MO diagrams orbitals can now interact

*2 sp*2 pp

sp2

pp2

ss2

*2 ss

s

s

somethingb

s s2 s p2

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More refined MO diagrams* orbitals can interact

*2 sp*2 pp

sp2

pp2

ss2

*2 ss

s

s

*s

*s

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More refined MO diagramp orbitals do not interact

*2 sp*2 pp

sp2

pp2

ss2

*2 ss

s

s

*s

*s

*p

p

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More refined MO diagramsp mixing

*2 sp*2 pp

sp2

pp2

ss2

*2 ss

s

s

*s

*s

*p

p

This new interaction energyDepends on b and the energy spacing between the 2ss and the 2ps

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sp mixing

2

2

nZEn

c.f.

2p

2s

Smallest energy gap, and thus largest mixing between 2s and 2p is for Boron.

Largest energy gap, and thus smallest mixing between 2s and 2p is for Fluorine.

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sp mixing

s

s

*s

*s

*p

p

Be2

s

s

*s

*s

*p

p

B2

s

s

*s

*s

*p

p

C2

s

s

*s

*s

*p

p

N2

weakly bound paramagnetic diamagnetic

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Learning outcomes

• Use the principle that the mixing between orbitals depends on the energy difference, and the resonance integral, b.

• Apply the separation of s and p bonding to describe electronic structure in simple organic molecules.

• Rationalize differences in orbital energy levels of diatomic molecules in terms of s-p mixing.

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Next lecture

• Particle in a box approximation– solving the Schrödinger equation.

Week 10 tutorials

• Wavefunctions and the Schrödinger equation.

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Practice Questions1. Why is s-p mixing more important in Li2 than in F2?2. How many core, s-bonding, and p-electrons are there in

a) acetyleneb) ethylenec) benzened) buckminsterfullerene

Check that your total number of electrons agrees with what is expected (6 per carbon, 1 per hydrogen).