Chemistry 11 Name: Organic Chemistry Unit...

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Chemistry 11 Organic Chemistry Unit Review Name: Date: Block: Answer the questions in the space provided. 1. Of the following molecules, choose 2 that best fit each description. a) Structural Isomers a) A&E _________ , F&G ________ b) Unsaturated Hydrocarbons b) B&F&D ______ , ____________ c) Have the general formula CnH2n+2 c) A&C&E ______ , ____________ d) When water is added, forms an alcohol d) D&F&H ______ , ____________ e) Contain alkyl groups e) A&C ________ , ____________ 2. Explain what is wrong with each of the following. If a given name is incorrect, provide the correct name. a) 2-ethylheptane b) 5-methylhexane c) d) 2-fluoro-4-hexyne e) C H 3 C CH 3 CH 3 CH 3 C H C CH 2 CH 3 CH 3 CH 2 CH 2 CH CH 3 CH 3 C H 2 CH CH 2 CH 3 CH 2 CH 2 CH 2 CH 2 CH 3 CH 2 CH CH CH 3 A B C D E F G H 2-butene pentane CH 3 CH 2 CH CH 3 CH 3 F CH 3 CH 3 C H 3 = 2,4,6-trimethylbenzene

Transcript of Chemistry 11 Name: Organic Chemistry Unit...

Chemistry 11

Organic Chemistry Unit Review

Name: Date: Block:

Answer the questions in the space provided.

1. Of the following molecules, choose 2 that best fit each description.

a) Structural Isomers a) A&E _________ , F&G ________

b) Unsaturated Hydrocarbons b) B&F&D ______ , ____________

c) Have the general formula CnH2n+2 c) A&C&E ______ , ____________

d) When water is added, forms an alcohol d) D&F&H ______ , ____________

e) Contain alkyl groups e) A&C ________ , ____________

2. Explain what is wrong with each of the following. If a given name is incorrect, provide the correct name.

a) 2-ethylheptane b) 5-methylhexane

c) d) 2-fluoro-4-hexyne

e)

CH3 C

CH3

CH3

CH3CH C CH2 CH3 CH3 CH2 CH2 CH CH3

CH3

CH2 CH CH2 CH3CH2 CH2

CH2CH2

CH3 CH2 CH CH CH3

A B C

D E

F G

H

2-butene pentane

CH3 CH2 CH CH3

CH3

F

CH3

CH3CH3

= 2,4,6-trimethylbenzene

3. Name the following molecules. a) b) pentane 3-methylheptane c) d) 5-ethyl-3-methyloctane 2,2,4,4-tetramethylpentane e) f) 4-methyl-2-pentene 1-butyne g) h) 3,4-dibromo-2,2-dichloro-5-iodohexane 1-ethylcyclopentane i) j)

3-octene 1,3,5-trichlorobenzene

CH3CH2CH2

CH2 CH3

CH3 CH2 CH2 CH2 CH CH3CH2CH3

CH3 C CH2 C CH3

CH3

CH3

CH3

CH3

CH3 CH CH CH CH3

CH3

CH C CH2

CH3

CH3 C CH CH CH

BrCl

Cl

Br

I

CH3CH2

CH2

CH2

CH

CH2

CH2 CH3

Cl

Cl Cl

CH3 CH2 CH CH2 CH CH2 CH2 CH3

CH3 CH2CH3

CH3 CH2 CH2 CH2

C CCH2 CH3

H

H

4. Draw the structures of the following compounds. a) 3-ethyl-4-methyloctane b) 3-heptyne c) 3,3-diethylpentane d) 1-chloro-3-ethylbenzene e) tetramethylbutane f) 1-chloro-3,4-dimethyl-cyclohexane g) 3-iodo-1-propyne h) dichloromethane i) 3-heptene j) 2-pentene

5. Draw this molecule. 4,4,5-triethyl-2,3,5,6,8,8,-hexamethyl-6,7-dipropyldecane

6. Name the following compound:

CH

C C C C C C C CH3

CH

CH

CH2

CH3

CH3

FCl

Br

Cl

CH3

CH2

CH2

CH3

CH2

CH2

CH3

CH2

CH3

CH3

CH3

CH2

CH3

F

Br

Br

Br

F

7. Draw and name all of the structural isomers of C6H14.

8. Draw and name all of the structural isomers of C5H10.

9. Draw and name as many structural isomers for C4H9OH:

10. Draw and name as many structural isomers for C5H10BrOH:

11. Match the following compounds to their appropriate descriptions. There may be more than one correct answer. 1. ___D, E___ Alcohol

2. ___G___ Carboxylic acid

3. ___C___ Saturated hydrocarbon

4. ___I___ Ketone

5. ___N___ Aromatic ring

6. ___M___ Propyne

7. ___K___ Ether

8. ___L___ Ester

9. ___H___ Aldehyde

10. ___H___ 12 carbons

11. ___N___ Benzene

12. ___C___ Alkane

13. ___B, J___ Alkene

14. ___A, M___ Alkyne

15. A, B, N, M_ Has no isomers

16. ___J___ Diene

17. ___E___ Methanol

18. ___D___ Ethanol

19. ___N___ C6H6

20. ___J___ C6H8

A B C

D E F

G H

C2H2 C2H4 C2H6

CH3 CH2 OH CH3 OH CH2 C OHNH2

O

CH2 C OHCH2

O

CH3

CH2 C CH2CH2

O

CH3 CH2 CH3

CH

O

I J

K L

M N

CH2 C OCH2

O

CH3 CH3CH2 O CH2CH2CH3 CH2 CH3

H C C C H

H

H

12. Classify the following types of reactions as combustion, substitution, addition, elimination or polymerization:

a)

Substitution

b)

Addition

c)

Addition

d)

Substitution

e)

Substitution

f)

Polymerization

g)

Addition

h)

Elimination