ChemInform Abstract: (NH4)15 [H3Mo57V6(NO)6 O189(H2O)12(VO)6] ×≈60H2O: New Nanocompound Obtained...
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2000 molybdenum, Mo molybdenum, Mo I 5600 40 - 014 (NH 4 ) 15 [H 3 Mo 57 V 6 (NO) 6 O 189 (H 2 O) 12 (VO) 6 ] ·≈60H 2 O: New Nanocompound Obtained by Chemical Embellishment of {M 57 V 6 }. — The title compound is prepared from an acidified (HCl) aq. solution of Na 2 MoO 4 ·H 2 O, (NH 4 ) 2 MoS 4 , and NH 4 VO 3 (75 ◦ C, 12 h, 33% yield). The nanocompound is characterized by IR, VIS/NIR, solid-state 51 V NMR, ESR spectroscopy, and single crystal XRD (hexagonal, space group P6 3 /mmc, Z = 2). The structure of the torus-like shaped nanoanion [H 3 Mo 57 V 6 (NO) 6 O 189 (H 2 O) 12 (VO) 6 ] 15- , which contains six (VO) 3+ units with tetrahedral coordi- nation environments, is discussed. — (YANG, WENBIN; LIN, XIANG; LU, CANZHONG; ZHUANG, HONGHUI; HUANG, JINSHUN; Inorg. Chem. 39 (2000) 13, 2706-2707; State Key Lab. Struct. Chem., Fujian Inst. Res. Struct. Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop. Rep. China; EN) 1
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Transcript of ChemInform Abstract: (NH4)15 [H3Mo57V6(NO)6 O189(H2O)12(VO)6] ×≈60H2O: New Nanocompound Obtained...
![Page 1: ChemInform Abstract: (NH4)15 [H3Mo57V6(NO)6 O189(H2O)12(VO)6] ×≈60H2O: New Nanocompound Obtained by Chemical Embellishment of {M57V6}.](https://reader031.fdocuments.in/reader031/viewer/2022020508/575003761a28ab11489948fc/html5/thumbnails/1.jpg)
2000 molybdenum, Mo
molybdenum, MoI 5600
40 - 014(NH4)15 [H3Mo57V6(NO)6 O189(H2O)12(VO)6] ·≈60H2O: NewNanocompound Obtained by Chemical Embellishment of {M57V6}.— The title compound is prepared from an acidified (HCl) aq. solution ofNa2MoO4·H2O, (NH4)2MoS4, and NH4VO3 (75 ◦C, 12 h, 33% yield). Thenanocompound is characterized by IR, VIS/NIR, solid-state 51V NMR, ESRspectroscopy, and single crystal XRD (hexagonal, space group P63/mmc, Z =2). The structure of the torus-like shaped nanoanion [H3Mo57V6(NO)6O189
(H2O)12(VO)6]15−, which contains six (VO)3+ units with tetrahedral coordi-nation environments, is discussed. — (YANG, WENBIN; LIN, XIANG; LU,CANZHONG; ZHUANG, HONGHUI; HUANG, JINSHUN; Inorg. Chem. 39(2000) 13, 2706-2707; State Key Lab. Struct. Chem., Fujian Inst. Res. Struct.Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop. Rep. China; EN)
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