ChemInform Abstract: N-Methylanilines from Benzylic Azides.
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1999 amines amines (benzene compounds) Q 0120 25 - 079 N-Methylanilines from Benzylic Azides. — The title transformation to amines (II) is investigated in more detail. Instead of SnCl 4 TFA gives similar results. Other acids are less effective. Additional experiments to understand the mechanism are made and discussed. The reaction gives complex mixtures or decomposition products in the case of a p-methoxy, p-nitro, and m-nitro substituent α-branched benzylic azides. Aliphatic azides give the reduced amines. — (LOPEZ, FRANCISCO J.; NITZAN, DOV; Tetrahedron Lett. 40 (1999) 11, 2071-2074; Neurobiol. Unit, Roche Biosci., Palo Alto, CA 94304, USA; EN) 1
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Transcript of ChemInform Abstract: N-Methylanilines from Benzylic Azides.
1999 amines
amines (benzene compounds)Q 0120
25 - 079N-Methylanilines from Benzylic Azides. — The title transformationto amines (II) is investigated in more detail. Instead of SnCl4 TFA gives similarresults. Other acids are less effective. Additional experiments to understandthe mechanism are made and discussed. The reaction gives complex mixturesor decomposition products in the case of a p-methoxy, p-nitro, and m-nitrosubstituent α-branched benzylic azides. Aliphatic azides give the reducedamines. — (LOPEZ, FRANCISCO J.; NITZAN, DOV; Tetrahedron Lett. 40(1999) 11, 2071-2074; Neurobiol. Unit, Roche Biosci., Palo Alto, CA 94304,USA; EN)
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