ChemInform Abstract: Epimerization of Carbohydrates and Cyclitols. Part 16. D-Tagatose Derivatives...

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1999 carbohydrates carbohydrates U 0500 51 - 200 Epimerization of Carbohydrates and Cyclitols. Part 16. D-Tagatose Derivatives from D-Fructose by a Facile Epimerization Procedure. The D-fructose derivative (I) is directly converted into the D-tagatose derivative (IV) by heating with dicyclohexylcarbodiimide (II) and chloral (III). (IV) is deprotected stepwise yielding D-tagatose (VIII) in good yield. — (FRANK, MICHAEL; MIETHCHEN, RALF; DEGENRING, DANIELA; Carbohydr. Res. 318 (1999) 1-4, 167-170; Lehrstuhl Org. Chem., Fachber. Chem., Univ. Rostock, D-18051 Rostock, Germany; EN) 1

Transcript of ChemInform Abstract: Epimerization of Carbohydrates and Cyclitols. Part 16. D-Tagatose Derivatives...

Page 1: ChemInform Abstract: Epimerization of Carbohydrates and Cyclitols. Part 16. D-Tagatose Derivatives from D-Fructose by a Facile Epimerization Procedure.

1999 carbohydrates

carbohydratesU 0500

51 - 200Epimerization of Carbohydrates and Cyclitols. Part 16. D-TagatoseDerivatives from D-Fructose by a Facile Epimerization Procedure.— The D-fructose derivative (I) is directly converted into the D-tagatosederivative (IV) by heating with dicyclohexylcarbodiimide (II) and chloral(III). (IV) is deprotected stepwise yielding D-tagatose (VIII) in good yield.— (FRANK, MICHAEL; MIETHCHEN, RALF; DEGENRING, DANIELA;Carbohydr. Res. 318 (1999) 1-4, 167-170; Lehrstuhl Org. Chem., Fachber.Chem., Univ. Rostock, D-18051 Rostock, Germany; EN)

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