ChemInform Abstract: Disordered Structure of ZrW1.8V0.2O7.9 from a Combined X-Ray and Neutron Powder...
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ChemInform 2009, 40, issue 52 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Tungsten I 5700 Disordered Structure of ZrW1.8V0.2O7.9 from a Combined X-Ray and Neutron Powder Diffraction Study at 530 K. — A yellow crystalline powder of the title com- pound is prepared by an acidic steam hydrothermal route starting with ZrOCl2, W7O24, NH4VO3, and 6M HCl (autoclave, 473 K, 20 h; annealing at 873 K, 2 h). ZrW1.8V0.2O7.9 crystallizes in the cubic space group Pa3 with Z = 4. The average structure is similar to that of β-ZrW2O8 with substitution occurring only at one of the W sites. — (CHEN, X.; TAO, J.; MA, H.; ZHAO*, X.; Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 65 (2009) 10, i74-i76; Coll. Chem., Beijing Norm. Univ., Beijing 100875, Peop. Rep. China; Eng.) — Schramke 52- 020
Transcript of ChemInform Abstract: Disordered Structure of ZrW1.8V0.2O7.9 from a Combined X-Ray and Neutron Powder...
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TungstenI 5700 Disordered Structure of ZrW1.8V0.2O7.9 from a Combined X-Ray and Neutron
Powder Diffraction Study at 530 K. — A yellow crystalline powder of the title com-pound is prepared by an acidic steam hydrothermal route starting with ZrOCl2, W7O24, NH4VO3, and 6M HCl (autoclave, 473 K, 20 h; annealing at 873 K, 2 h). ZrW1.8V0.2O7.9 crystallizes in the cubic space group Pa3 with Z = 4. The average structure is similar to that of β-ZrW2O8 with substitution occurring only at one of the W sites. — (CHEN, X.; TAO, J.; MA, H.; ZHAO*, X.; Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 65 (2009) 10, i74-i76; Coll. Chem., Beijing Norm. Univ., Beijing 100875, Peop. Rep. China; Eng.) — Schramke
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ChemInform 2009, 40, issue 52 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
