ChemInform Abstract: Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via...

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ChemInform 2011, 42, issue 25 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Enantioselective syntheses O 0031 DOI: 10.1002/chin.201125028 Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetri- zation of 2,2-Disubstituted 1,3-Propanediols. — The asymmetric monobenzoylation of symmetric diols is achieved with high enantioselectivities by use of the copper-cat- alyst derived from Pybox-ligand PBO. — (LEE, J. Y.; YOU, Y. S.; KANG*, S. H.; J. Am. Chem. Soc. 133 (2011) 6, 1772-1774, http://dx.doi.org/10.1021/ja1103102 ; Dep. Chem., Korea Adv. Inst. Sci. Technol., Daejeon 305-701, S. Korea; Eng.) — Klein 25- 028

Transcript of ChemInform Abstract: Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via...

Page 1: ChemInform Abstract: Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetrization of 2,2-Disubstituted 1,3-Propanediols.

Enantioselective synthesesO 0031 DOI: 10.1002/chin.201125028

Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetri-zation of 2,2-Disubstituted 1,3-Propanediols. — The asymmetric monobenzoylation of symmetric diols is achieved with high enantioselectivities by use of the copper-cat-alyst derived from Pybox-ligand PBO. — (LEE, J. Y.; YOU, Y. S.; KANG*, S. H.; J. Am. Chem. Soc. 133 (2011) 6, 1772-1774, http://dx.doi.org/10.1021/ja1103102 ; Dep. Chem., Korea Adv. Inst. Sci. Technol., Daejeon 305-701, S. Korea; Eng.) — Klein

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ChemInform 2011, 42, issue 25 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim