Chemical bonding
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Transcript of Chemical bonding
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Objectives
• Identify the stable noble gas structure.
• Explain the formation of ionic and covalent bonds.
• State the properties of ionic and covalent bonds.
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Stable Noble Gas Structure
Where can noble gas be found?
They are gases found in Group 0 of the Periodic table.
For instance, helium, neon, argon and etc.
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What are noble gases?
Stable Noble Gas Structure
• They are gases which are unreactive or stable. Indicates that they do not
react with other atoms to form compound.
+Helium Sodium
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Why are noble gases unreactive?
The valence shells of noble gases are shown here.
Each noble gas has a fully filled valence shell.
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Noble Gas
Noble gases have duplet or octet configuration. Therefore, they do not need to react to become stable.
Duplet configuration
Octet configuration
Why are noble gases unreactive?
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Noble Gas Structure
A duplet or octet configuration is also known as a noble gas structure or a noble gas configuration.
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Noble Gas Structure
• Other atoms do not have a noble gas configuration.
• Therefore, atoms react in order to have the noble gas structure.
Why are the other atoms reactive?
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Chemical Bonding
What is chemical bonding?
Chemical Bonding is the way in which atoms join together with each other.
+
sodium metal chlorine gas table salt
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Chemical Bonding
During a chemical reaction, atoms of the elements joined together to form ionic compound or covalent compound.
Ionic Compound Covalent Compound
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Two types of chemical bonding:1. Ionic bonding- between metals
and non- metals2. Covalent bonding – between
non-metals
Chemical Bonding
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Ionic bonding
What is ionic bonding?
Ionic bonding involves transferring of electrons from metal to non-metal.
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Ionic Bonding
During bonding• Metallic atoms give away (lose)
electrons and change into positive ions or cations.
NaNa NaNa++ + e + e--
CationMetallic atom
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Formation of a Sodium Ion
To attain an octet configuration, a sodium atom (Na) loses 1 valence electron.
It forms a sodium ion (Na+) and has a noble gas structure.
sodium atom, Na
Lose 1 electron
sodium ion, Na+
++
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Formation of a Sodium Ion
11 p11 e12 n
sodium atom, Na
Lose one electron
sodium ion, Na+
++
11 p10 e12 n
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Ionic Bonding
During bonding• Non-metallic atoms take in
(accept) electrons and change into negative ions or anions.
Cl - Cl + e-
Non-metallic atom
Anion
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Formation of Chlorine ion
A chlorine atom (Cl) gains an electron to form a
chloride ion (Cl-).
The chloride ion has an octet configuration.
gains one
electron
Chlorine ion, Cl-
--
Chlorine atom, Cl
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Formation of Chlorine ion
gains one
electron
Chlorine ion, Cl-
--
17 p17 e18 n
17 p18 e18 n
Chlorine atom
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Ionic Bonding
By taking in and giving out electrons, both the metallic and non-metallic atoms achieve a completely filled outermost shell. Indicates they attain a stable noble gas structure.
--++
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• The electrostatic force of attraction between the positive and negative ions is called an ionic bond.
Ionic Bonding
Ionic bond
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How do we show ionic bonding?
We show it through the ‘dot and cross’ diagram.
The diagram here shows the formation of an ionic bond in sodium chloride.
ClNa
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Examples
• Magnesium oxide• Calcium fluoride• Lithium oxide
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Structure of Ionic Compounds
• All ionic compounds are solids with giant lattice structure.
• They consist of positive ions of metals and negative ions of non-metals.
E.g. sodium chloride
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In a crystal of sodium chloride, Na+ and Cl- are held in fixed position by strong electrostatic force of attractions (ionic bonds)
Example: Sodium chloride
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Characteristics of ionic compounds
1. High melting and boiling point
Ions are held firmly to their position by strong electrostatic force of attraction.
A great amount of energy is needed to break these forces for the ions to move out of its fixed position to become a liquid.
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Characteristics of ionic compounds
2. Solubility
Soluble in water
Insoluble in organic solvent (e.g. oil, ethanol, petrol)
Ethanol
(Insoluble)
Salt
Water
(soluble)
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Characteristics of ionic compounds
3. Conducts electricity when molten (melted) or aqueous (dissolved in water) but not in solid state
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Electrical Conductivity – in solid sodium chloride
Bulb does not light up.
In solid, the ions are held in fixed position. They cannot move freely.
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Electrical Conductivity – in molten sodium
chlorideHowever, if NaCl is heated until it melts…
Bulb lights up.
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Electrical Conductivity – in aqueous sodium
chloride
Bulb lights up.
In molten or aqueous, ions are free to move about, thus carry charges to conduct electricity.
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Covalent bondingWhat is covalent bonding?
Covalent bonding involves sharing of electrons between non-metallic atoms.
H H
Sharing of electrons Transferring of electrons
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Covalent bondingDuring bonding,
• The non-metallic atoms share electrons to achieve noble gas configuration.
H2 molecule
H H
2H atoms
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Covalent Bonding
Rule 1:• Each atom must contribute an equal
number of electrons for sharing.
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Covalent Bonding
Y Y Y Y
A B
Which of the following diagrams obey the rule?
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Covalent Bonding
Rule 2:• A shared pair of electrons forms a single
covalent bond.• 1 pair of electrons a single bond is
formed.• 2 pairs of electrons a double bond is
formed.• 3 pairs of electrons a triple bond is
formed.
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Covalent Bonding
Y Y
Structural formula
‘Dot and cross’ diagram
(Electronic Structure)
Y Y
• A shared pair of electrons forms a single covalent bond.
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Covalent Bonding
Y Y
Structural formula
‘Dot and cross’ diagram
(Electronic Structure)
Y Y
• Two shared pair of electrons forms a double covalent bond.
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How do we show covalent bonding?• Through ‘Dot and Cross’ Diagram
or• Structural formula
Covalent Bonding
Structural formula
‘Dot and cross’ diagram
(Electronic Structure)
Y Y Y Y
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Covalent BondingExamples:
1.Hydrogen molecule
2.Oxygen molecule
3.Nitrogen molecule
4.Methane (CH4)
5.Carbon dioxide
6.Water
7.Ammonia (NH3)
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Characteristics of Covalent Compounds
1. Low melting and boiling point
( high volatility)
Molecules are held together by very weak intermolecular forces.
Little energy is required to overcome the forces of attraction.
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Characteristics of Covalent compounds
2. Solubility
Soluble in organic solvent
Insoluble in water.
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Characteristics of ionic compounds
3. Does not conduct electricity in any state.
• Molecules in covalent compounds do not carry charges.
• No ions to carry electric current.