Chem-Group 4
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Transcript of Chem-Group 4
5.10 Covalent CompoundsAnd Their Solutions
5.11 Protecting Our Drinking Water:
Federal Legislation
5.12 Treatment of Municipal Drinking Water
A covalent compound is a compound in which the atoms
that are bonded share electrons
rather than transfer electrons from one to the other.
We know for a fact that water and oil don’t mix and the reason for that is they are very different structurally. Water molecules are highly polar while oil consists of
nonpolar hydrocarbon molecules. These molecules stick with their own when they come in contact.
sucrose (table sugar), ethylene glycol (the main ingredient of
antifreeze),
ethanol (which is usually found in
alcoholic beverages)
The ethanol (C2H5OH) molecule’s –OH group can form hydrogen bonds
with H2O molecules and it’s the reason why water and ethanol have
great affinity for each other.
Another alcohol is the ethylene glycol which has two –OH
groups for hydrogen bonding with H2O which makes
ethylene glycol highly water-soluble.
And then we have sucrose which contains eight –OH
groups and three additional oxygen atoms that can participate in hydrogen
bonding. This explains the high solubility of sugar in
water.
Protecting Our Drinking Water:Federal Legislation
We all need clean drinking water to survive. Keeping our water supplies safe has long been recognized as an
important public health issue.
The Safe Drinking Water Act (SDWA) was passed To provide public health protection to all
Americans who get their water from community water
supplies (over 250 million people).
Contaminants that may be health risks are regulated by EPA that sets legal limits for
such contaminants according to their levels of adverse risk
as required by SDWA.
For each contaminant, the EPA has established a maximum contaminant level goal or the MCLG, which is the maximum level of contaminant in drinking water at which no known or anticipated adverse effect on the health of persons would
occur.Each MCLG includes built-in safety factors accounting for uncertainties in collection data and for how different people might
react to each contaminant.
The concentration of an impurity must exceed the maximum contaminant level or the MCL, which sets the legal limit for the concentration of a contaminant, before any regulatory action is taken against a water utility.
POLLUTANT MCLG MCL
Cadmium 0.005 0.005
Chromium 0.1 0.1
Lead 0 0.015
Mercury 0.002 0.002
Nitrate 10 10
Benzene 0 0.005
Trihalomethanes 0 0.080
For each contaminant, the EPA has established a maximum contaminant level goal (MLCG).
Lower limits for MCL values have been established as more accurate risk information, improved detection and quantitative analytical
methods has become available.
As of now, more than 80 contaminants are regulated which fall into several major categories:
a. Metals (cadmium, chromium, copper, mercury, and lead)b. A few nonmetallic elements (fluorine, and arsenic)c. Pesticidesd. Industrial solventse. Compounds associated with plastics manufacturing, and radioactive materials
These contaminants pose chronic health problems even when consumed in tiny doses.
Other laws have also been passed like the Clean Water Act or the CWA to provide the foundation for dramatic progress in reducing surface water pollution over the past three decades. This act establishes limits on the amounts of pollutants that industries can discharge into surface waters.
Improvements in surface water quality have at least two major beneficial effects:
They reduce the amount of clean-up needed for public drinking water supplies, andThey result in a more healthful natural environment for aquatic organizations.
In turn, a more healthful aquatic ecosystem
has many indirect benefits for humans.
STEP 1. Water is passed through a screen that separates it from
other objects. (Ex. Sticks, fishes, tires, and beverage cans)
STEP 2. Two chemicals are added to the water : Aluminium Sulphate
(Al2(SO4)3+) and Calcium Hydroxide (Ca(OH)2). These chemicals are known
as flocculating agents. When mixed together, they react to form
Aluminum Hydroxide (Al(OH)3+)
which is a gel that collects suspended clay and dirt
particles. The gel settles with all the collected particles in a
separate settling tank.
STEP 4. Chlorine is then added to the water. This is
the most crucial step as chlorine kills disease carrying organisms, making the water
safe for drinking.
STEP 5. An optional step, Sodium Fluoride (NaF) is
added to the water to help protect against tooth decay.
The chlorine added to the water usually comes in one of three forms :
1. Chlorine gas (Cl2)2. Sodium Hypochlorite (NaClO)3. Calcium Hypochlorite (Ca(ClO)2)
These generate an antibacterial agent called Hypochlorous Acid (HClO). Only
a very low concentration of this solution is added to the water
(between 0.075ppm and 0.600ppm) to protect it against further
contamination as it travels through the pipes to the user.
CASE 1. In a classic study, John Snow was able to
trace a mid-1800s cholera epidemic in London to
water contaminated with the excretions of victims of
the disease.
CASE 2. In 1991, a cholera epidemic in Peru was traced to bacteria in shellfish growing in estuaries with untreated fecal matter. The bacteria found its
way into the water supply where they continued to multiply because of the absence of
chlorination.
DRAWBACKS OF CHLORINATION1. The taste and odor of residual chlorine is objectionable. This is often the reason why people prefer to drink bottled water or use filters to remove residual chlorine at the tap.
2. Residual chlorine reacts with other substances in the water forming by-products with potentially toxic levels. (Ex. Trihalomethanes (THMs) such as Chloroform (ChCl3-))
1.Ozone (O3)Used in many European and a few US cities, the toxic property of ozone is used for a beneficial purpose. Ozone is more effective than chlorine against water borne viruses, and disinfection can be achieved with a smaller concentration. However, ozonation is more expensive and it decomposes quickly, thus leaving it unable to protect water from contamination after it leaves the treatment plant.
2. Ultraviolet (UV) RadiationUV disinfection is very fast, leaves no residual by-products, and is economical for small installations. However, like ozone, UV disinfection does not protect the water from contamination after it leaves the treatment plant.
Depending on local conditions, one or more additional purification steps may be carried
out at the water treatment facility after disinfection.
1. Water is sprayed into the air to remove volatile chemicals that create objectional
odors and tastes.
2. Calcium oxide (lime) is added to water to neutralize its acidity should it cause problems such as corrosion of pipes.