Chem class(22apr)

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H He Little Belly Boy Come Near Oreo F or Nutrition Naughty Man And Silly P eople Should Consume A lot of Kentucky Combo

Transcript of Chem class(22apr)

Page 1: Chem class(22apr)

H He

Little Belly Boy Come Near Oreo For Nutrition

Naughty Man And Silly People Should Consume A lot of

Kentucky Combo

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GROUP 1 ELEMENTS:

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Group 1 elements are alkaline,

Call them as Alkali metals.

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Physical properties of group 1 elements

soft metals

silvery and shiny surfaces

low melting and boiling points

good conductors of heat and electricity

low density

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When down the group 1….1. Hardness

2. Atomic size the number of atomic shell ↑

3. melting point and boiling point atomic size ↑ distance between the nucleus and the valance electron shell ↑ metallic bond between atoms ↓

4. Density Size ↑ mass more than increase in volume atoms are closer

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Element Radius M.p B.p HardnessDensity Electro-

positivity

Li

Na

K

Rb

Cs

Fr

decrease increase

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Chemical propertiesR

eact

ivit

y in

crea

se

Down the group

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xx

x

x

x

3 P

3 e

3 P

2 e

3 +

2 -

1 +

Duplet (stable)

Li - 1e → Li+

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x

xx

xxx

x

xxxx

xx

xxx

x

xxxx

11 P

11 e 11 P

10 e

11 +

10 -

Na - 1e → Na+

Octet (stable)

1 +

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K - 1e → K+

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Electropositivity

Increase(↑) down the group.

The tendency to donate electrons to form positive ions

x

xx

xxx

x

xxxx

x

x

Li Na

x

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Down the group 1, Reactivity ↑

Atomic size ↑

The 1 valence electron become far from the nucleus.

The force of attraction of nucleus on the valence ↓

The single electron becomes easier to be release.

Reactivity ↑

Li < Na < K < Rb < Cs < Fr

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3 reactions in group 1

With Oxygen

With water

With halogens

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Reaction with oxygen

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Reaction with oxygenAlkali metals + oxygen alkali metal oxides

Ex:

4 Li(s) + O2(g) 2Li2O(s)

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metal reaction Phenolphthalein indicator

LiBurn with a red flame.

Turns pink

NaBurn with a brightyellow flame.

Turns pink

K Burn violently with a

very bright purplish flame.

Turns pink

Reactivity

↑down the group

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Reaction with water

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Reaction with waterAlkali metals + water alkaline metals hydroxide + hydrogen gas

Ex:

2Na(s) + 2H2O(l) 2NaOH(aq) + H2(g)

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metal

reaction Phenolphthalein indicator

Li Move slowly on the water surface. Turns pink

Na Move at a fast speed on water

surface with a “hissing” sound, burn

with yellow flame.

Turns pink

K Move very fast speed and burn

with a purple flame.

Turns pink

Reactivity

↑down the group

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Reaction with Halogen

Chlorine gas

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Reaction with Halogen

Alkali metals + halide alkali metals halide

Ex:

2K(s) + Cl2(g) 2KCl(s)

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metal reaction product

Li Burn slowly with a

reddish flame.

White solid is obtained

Na Burn brightly with a

yellowish flame.

White solid is obtained

K Burn very brightly with purplish flame.

White solid is obtained

Reactivity

↑down the group

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Safety Precautions Alkali metals are highly reactive to water and air.

Kept under non-reactive oil (eg. Paraffin oil)

Never handle with your fingers.

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Summary:

Physical

• Shiny and silvery surface

• conductors of heat and electricity

• Hardness

• Atomic size

• Mp

• Bp

• density

Chemical

• Electropositivity

• Reactivity:

• Reaction with oxygen

• Reaction with water

• Reaction with chlorine