Chapter I. Basic Concepts

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    CHAPTER I

    BASIC CONCEPTS1.1 Definitions1.2 Generating agents

    1.3 Types of soils and characteristics

    1.4 Structure of clay minerals

    1.5 Structure of soils

    Professors: A.Zepeda y E Rojas

    January 17, 2011

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    1.1 DEFINITIONS

    Soil

    Soils are formed with sediments and other solid particles that can be

    separated in single particles with the force of your hand when

    saturated regardless of whether or not they have content of organic

    matter (Karl Terzaghi).

    Sediments are produced by mechanical break down or chemicaldecomposition of rocks.

    Soil Mechanics.

    Soil mechanics is the application of the laws of mechanics andhydraulics to engineering problems dealing with soils.

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    People use the land to live on, and build all sort of structures:

    houses, roads, bridges, etcetera. It is the task of the geotechnical

    engineer to predict the behavior of the soil as a result of these

    human activities.

    The problems that arise are, for instance, the settlement of a

    road or a railway under the influence of its own weight and the

    traffic load, the margin of safety of an earth retaining structure(a dike, a quay wall or a sheet pile wall), the earth pressure

    acting upon a tunnel or a sluice, or the allowable loads and the

    settlements of the foundation of a building.

    For all these problems soil mechanics provides the basic

    knowledge.

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    Soil mechanics is the science of equilibrium and motion of soil bodies. Here

    soil is understood to be the weathered material in the upper layers of the

    earthscrust.

    The non-weathered material in this crust is denoted as rock, and itsmechanics is the discipline of rock mechanics.

    In general the difference between soil and rock is roughly that in soils it is

    possible to dig a trench with simple tools such as a shovel or even by hand.

    In rock this is impossible, it must first be splintered with heavy equipmentsuch as a chisel, a hammer or a mechanical drilling device.

    The natural weathering process on a mass of rock produced by rain, ice

    wind, gravity and temperature gradually reduce the rock in smaller

    particles. This process starts by the fracturing of rock bodies during the

    freezing and thawing of the water inside the fissures in the rock.

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    n

    t

    n

    Real soils have two types of structures; a

    macrostructure consisting of large particlesand large pores and a microstructure

    composed by packets of very small pores.

    1.4 Air, water and solid phases

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    WATER IN THE SOIL

    Soil grain

    Adsorbed water

    Gas (Air)

    Capillary

    waterSaturated soil

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    air

    water

    soil

    solids

    Weigth

    Wa0

    Ww

    Ws

    Wm

    Volume

    Va

    Vw

    Vs

    Vm

    Vv

    TRADITIONAL THREE

    PHASES DIAGRAM FOR

    SATURATED SOIL

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    1.2 GENERATING AGENTS

    The Earths crust is mainly attacked by air , water and temperature. Soils

    are formed by the weathering of rocks and minerals. The surface rocks

    break down into smaller pieces through a process of weathering

    All attacking mechanisms can be divided in two groups:Mechanical disintegration (mechanical weathering) and

    Chemical decomposition (chemical weathering).

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    Mechanical weathering : Refers to the weathering of the rocks by physical

    agents such as periodic changes of temperature, the freezing of water in

    the joints and cracks in the rocks, effects of living organisms such as plants

    or animals.

    Because of these phenomena rocks degrade into sands, in extreme cases

    can produce silts and rarely clay.

    Chemical weathering (decomposition): The action of agents who attack

    the rocks by modifying its mineralogical or chemical structure.The principal agent is the water and the most important attack

    mechanisms are oxidation, hydration and carbonation.

    Chemical effects of vegetation also have influence on the process of

    weathering. These mechanisms generate clay as final product.

    The formation of soils has occurred through the geological eras.

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    1.3 TYPES OF SOILS

    Residual and Transported Soils

    Residual soils: The material attacked by weathering agents

    remains in the same place, directly above their parent rock.

    There is a number of important characteristics of the parent

    rock inherited by residual soils. These are the weathering profile

    and the set of structures such as fissures, failure planes and

    joints.

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    Transported soils: These soils are removed from the parent

    rock by the weathering agents. Different deposits of transportedsoil can be found in the same horizon without a direct

    relationship between them.

    Transported soils show a number of important characteristics

    such as the stratigraphic profile and the thickness of eachstratum. We can have several strata without direct relationship

    among them.

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    A Horizonor vertical washing area: is the mostsuperficial and it has roots and vegetation. Its

    color is usually dark due to the abundance of

    decomposed organic matter or humus,

    determining the passage of water that drag

    downward fragments of fine size and soluble

    compounds. Highly leached materials (Lixiviation

    or eluviation zone).

    B Horizon or precipitation area: it lacks of

    organic material, so its color is lighter, In the B

    horizon materials drawn from above are

    deposited, mainly clay materials, oxides and

    metal hydroxides, carbonates, etc. (eIuviation

    zone).C Horizon or parent rock: is made up to top of in

    situ rocky material. Soil rests on horizon C, more

    or less fragmented by mechanical and chemical

    action, but it still recognizes it's original

    characteristics.

    Horizons of Soil.

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    Transported Soils

    There is a number of transport agents in nature, the

    main ones are:

    Glaciers

    Wind

    Rivers

    FloodingsSeas

    Gravity

    These agents frequently work combined.

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    Types of soil deposits

    a)Glacial deposits

    b) Moraine or Gravity deposits

    c) Alluvial deposits

    d) Fluvial deposits

    e) Lacustrine deposits

    f) Eolian deposits

    g) Marine deposits

    h) Organic Soil

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    Western slopes of theSouthern Alps, South

    Island, New Zealand

    (G.R. Roberts, Nelson,

    New Zealand).

    Glacial deposits: The glaciers, in

    their movement, generate big

    pressures and abrasive effect on

    rocks. The eroding action of the

    glacial ice crushes and pulverizesthe parent bedrock and transforms it

    into silt, sand, and gravel. This could

    be accomplished due to the great

    depths and enormous pressure of

    glacier ice. There are several kinds

    of glacial deposits, the main aremoraines.

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    Moraine deposits

    http://en.wikipedia.org/wiki/File:Moraines_Surlej.jpg
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    A moraine

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    The most recent glaciation on the North American continent

    is the Laurentide (or Wisconsian) glaciation, which

    dissappeared some 10 000 to 13 000 years ago.

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    Fluvioglacial soil

    Glacial deposits in the

    Bicentenario Bridge,

    Quertaro

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    Gravity deposits: Moraine deposits, are sediments that accumulate at

    the foot of mountain slopes because of avalanches, slides or instability of

    the material on the slopes.

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    Alluvium deposits: Sediment deposited by flowing water as in a flood plain

    or delta. It is also called alluvium. Their grain size varies from large rock

    fragments, gravel, sand, silt and some clay.

    The term "alluvium" is not typically used in situations where the formation of

    the sediment can clearly be attributed to another geologic process that is

    well described. This includes (but is not limited to): lake sediments

    (lacustrine), river sediments (fluvial), or glacially-derived sediments (glacial

    till).

    Alluvial plaine in Red Rock Canyon Park

    http://en.wikipedia.org/wiki/File:AlluvialPlain.JPG
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    Alluvial Soil

    Alluvial soil deposit in Quertaro

    El t i i f

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    Slickensides, the glossy (shiny and smooth) surfaces seen in

    this picture are an obligatory requirement for vertisols

    (USDA).

    Electronic microscopy of sweep

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    Picture of a soil layer in Bulgaria. There are carbonate

    concretions.

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    Fluvial Soil in a Delta

    River deposits (fluvial): Coarse particles are graved dawn stream during

    flooding and deposited when a decrease in the water velocity occurs. Fine

    particles remain in suspension to be deposited in quieter waters. Thus, river

    deposits are segregated according to size.

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    The coarse stones that are created close to the mountains are

    transported downstream by gravity water flow.

    The stones are gradually reduced in size, so that the material becomes

    finer: gravel, sand and eventually silt.

    The material is deposited by flooding or flowing rivers. The coarsest

    material at high velocities, but the finer material only at very small

    velocities. This means that gravel will be found in the upper reaches ofa river bed, and finer material such as sand and silt in the lower

    reaches (Arnold Verruijt, Delft University of Technology, 2001).

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    Lacustrine material

    Lacustrine deposits: Fine and very fine sediments like silts and clays are

    deposited when running water comes to rest, like in lakes or deltas

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    Wind deposit: Sand dunes in the Sahara, Morocco.

    Wind deposits (Aeolin or Eolian): Loess and dune sands. This

    sediments are typical of arid regions, and the water table is encountered at

    great depth from the ground surface.

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    Organic material

    Marsh in Coatazacoalcos Ver.

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    Marine soil

    Marine deposits: They are related to the characteristics of the

    rock formations eroded by sea water

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    COARSE GRAINED SOIL MINERALS

    Silicates of aluminium: Feldespar (of potassium,

    sodium or calcium), micas, olivine and serpentine.

    Oxides: Quartz, limonite, magnetite and corundum.

    Carbonates: Calcite and dolomite.

    Sulphates: Anhidrite and gypsum

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    1.4 STRUCTURE OF CLAY MINERALS

    Clay minerals are predominately hydrated silicates of aluminum and/or

    iron and magnesium or other metals. These minerals are

    predominantly crystalline in that the atoms composing them are

    arranged in definite geometrical patterns.

    Most of the clays minerals have sheet or layered structures.

    Soil masses generally contain a mixture of several clay minerals.

    Clay minerals are very small (less than 0.002 mm) and very

    electrochemically active particles which can be seen using an electron

    microscope.

    There are two fundamental units (building blocks) for the clay mineral

    structure:

    Silica unit (Tetrahedron unit)

    Aluminum unit (Octahedral unit)

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    Oxygen

    Silicon

    Silica tetrahedron unit,

    approximately 4.6 Ahigh

    Block equivalent=

    Angstrom unit A= 10-10m

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    AluminumOxygen

    Octahedral unit,

    about 5.05 Ahigh

    Octahedron

    = Block equivalentG or B

    G= Gibbsite (Al)

    B= Brucite (Mg)

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    According to the mineral structure of clay, some of the most common clay

    minerals are the following

    Kaolinite: Its structure is very stable in the presence of water.

    Montmorillonite: Its structure is very unstable in the presence of

    water. When the water content increases it swells.

    Illite: Its behavior is intermediate between kaolinite and

    montomorillonite

    Kaolin is used in ceramics, medicine, coated paper, as a food additive,

    in toothpaste, as a light diffusing material in white incandescent light

    bulbs, and in cosmetics. It is generally the main component in porcelain.

    Kaolin clay is widely used as an intestinal absorbent to combat intestinalinfections, in antidiarrheal medicines and for digestive disorders.

    Kaolinite and halloysite clays are widely used for chinaware and

    ceramic, due to absence of iron and subsequent iron decoloration at

    high tempertures.

    http://en.wikipedia.org/wiki/Light_bulbshttp://en.wikipedia.org/wiki/Light_bulbs
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    7 ASi

    Al

    Kaolinite,

    schema of the

    basic unit

    Al

    Si

    Si

    Schema of the

    Montmorillonite

    9.6 A

    Schema of the Illite

    Al

    Si

    Si

    10 A

    K, Potassium

    Angstrom unit A= 10-10m

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    > 9.6

    Cationes de cambio n H2O

    Oxgeno

    Hidroxilo, OH

    Al, Fe, Mg

    Si, a veces Al

    Chemical structure of the montmorillonite

    Oxygen

    Silicon

    Aluminium

    Angstrom unit A= 10-10m

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    agua capilar

    agua

    adsorbida

    The phenomenon of capillarity in addition to the ionsin adsorbed water layer produce suction on

    unsaturated soils (matric and osmotic suction).

    Adsorbed

    water

    Capillary water

    Clay particles

    Negative electrical forces on the

    surface of the mineral particles

    attract water molecules and ions.

    These forces decrease as the water

    molecules and ions are farther

    away from the surface of the grain.

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    Floculated and dipersive clays depend on their mineralogy

    and the environmental conditions in which they were formed

    Distance

    Attractio

    n

    Rep

    ulsion

    Floculated clay

    Dispersive clay

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    The specific surface is the sum of all the external area ofthe particles of soil per gram of material. A fine sand has

    around 0.04 m2 of specific surface. A caolinite has 10 m2,

    ilite has 100 m2 and montmorillonite has up to 800 m2.

    The atoms of oxigen of the alluminate sheets are located atthe top and bottom of the clay particles in the illite and

    montmorillonite. This produces a negative charge on the

    flat surface of the particles.

    Plasticity is the ability of soils to absorb water and todeform without fissuring. Clean sands have no plasticity

    and montmorilonites are the most plastic of soils.

    Specific surface and plasticity

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    Water is strongly attracted by minerals. In the case of clays

    plasticity is generated by the viscous water layer.

    Coarse materials have much smaller specific surface andless affinity to water (the viscous layer is almost non

    existent) and therefore do not develop significant

    plasticity.

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    Visc

    osity

    Distance from the particle surface, d

    IIII II

    -

    -

    -

    -

    -

    -

    -

    -

    -

    -

    -

    -

    -

    --

    +

    +

    Solid particle

    Solid water layer (I)

    Viscous water layer (II)

    d

    I

    II

    Free water (III)

    The electromagnetic forces reduce as the molecules of water move away from the

    surface of the clay particle

    particle

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    Cation Exchange Capacity (CEC)

    Cations are positively charged ions.

    Cation exchange capacity (CEC) represents the quantity of

    negative charges existing on the surfaces of clay particles. The

    negative charges attract the cations, hence the name cationexchange capacity.

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    Diagram of a particle of clay with negative charges

    on the surface attracting different cations.

    Different types of clays have different CECs

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    The most common soil cations, (including their chemical symbol and charge)

    are: calcium (Ca++), magnesium (Mg++), potassium (K+), ammonium (NH4+),

    hydrogen (H+), sodium (Na+), aluminum (Al+++), iron (Fe++), zinc (Zn++) and

    copper (Cu++). Notice that some cations have more than one positive charge.

    The capacity of the soil to hold on these cations is called the cation exchangecapacity (CEC).

    The quantity of positively charged ions (cations) that a clay mineral or similar

    material can accommodate on its negatively charged surface is expressed as

    milliion equivalent per 100 g, or more commonly as milliequivalent (meq) per

    100 g or cmol/kg.(10 cmolc/kg = 10 meq/100 g).

    Clays are aluminosilicates in which some of the aluminum and silica ions

    have been replaced by elements with different charge. For example,

    aluminum (Al3+) may be replaced by iron (Fe2+) or magnesium (Mg2+), leading

    to a net negative charge.

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    The CEC of the soil will depend on the pH of the soil. A neutral soil (pH ~7)

    will have a higher CEC than a soil with for example pH 5. Or in other words,the CEC of a soil with pH-dependent charge will increase with an increase in

    pH.

    This principle applies to increasing pH by the presence of lime for the

    stabilization of expansive clays.

    Expansive clayis a soil that is susceptible to large volume changes directlyrelated to changes in water content. Mitigation of the effects of expansive

    clay on structures remains a major challenge in geotechnical engineering.

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    Clay Exchange capacity, meq/100gr

    Kaolinite 3-15

    Halloysite 10-40

    Illite 10-40

    Vermiculite 100-150

    Montmorillonite 80-150

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    Identification of Clay Minerals

    X Ray Diffraction: Each diffracted path is the image of different atomic

    planes.

    Electron microscope.

    Differential Thermal Analysis (DTA): consists of simultaneously heating a

    test sample and a thermally inert substance at constant rate (usually about

    10C/min) to over 1000C and contiunuously measuring differences in

    temperature between the sample and the inert material.

    Chemical Analysis

    Thermogravimetric Analysis

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    x ray diffractometer . Equipped for qualitative and quantitative analysis of

    crystalline compounds

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    x ray difraction results

    Difraction angle

    Frequency

    Al Mg Si

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    Thermal analysis Temperature range is -100 to 1600C for simultaneous

    DSC/DTA/TG, room temperature to 1600C for dilatometry

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    TD

    TD

    Exothermic

    Reaction

    Endothermic

    Reaction

    Typical thermogram for soil minerals

    a

    a is the amplitude (cm);Ais the area (cm2)

    A

    1000C0

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    Particle diameter (mm)

    Gravel 4.75 76.2

    Sand 0.075 4.75

    Silt 0.005 0.075Clay 0.002 - 0.005

    Colloid < 0.002Flat/Needle

    Particles

    Granular

    Particles

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    Shape of Granular Soil Particles

    Angular: Short transported distance

    Round: Large transported distance

    ifi i f i i l

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    Specific gravity of important minerals

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    a) Soil Structure of coarse particles (simple structure): mainly

    gravity forces are involved.

    Assemblage of individual particles

    Bulky particles

    Dense Bulky SoilLoose Bulky Soil

    Voids (Vv)

    Bulky particle (Vs)

    e=0.91 e=0.35

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    Granular Loose Soil

    Honeycomb soil structure

    in granular soil

    Loess (wind) deposit

    Good compressive

    Strength

    Unstable if loaded

    (collapse)

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    Most soils contain a variety of particle sizes

    Granular Soils Packing

    In general, the greater the range of the size of soil

    particles, the lower the void ratio because small particles

    fill the voids of larger particles

    Soil strength also depends on particle interlockGreater interlock higher shear strength

    Interlock is a function of: particle shape and

    amount of inter-particle contact

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    Granular Soil Volumetric weigth

    Very looseLoose

    Mediun compact

    Dense or compact

    Very dense or very compact

    High void ratio (e)Low strength, compressible

    Low void ratio (e)

    High strength, incompressible

    Granular Dense Soil

    Dense soil:

    Low Vv, high Vs, therefore low e

    Lower the soil void ratio the more dense,

    Less settlement and higher strength

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    minmax

    max

    ee

    eeDr n

    A measure of the structure of coarse soils is given by

    the relative density parameter , Dr

    minmax ,ee Are the laboratory values of themaximun and minimum void reatios

    s

    v

    n

    V

    Ve Is the natural value of void reatio

    The densest state, ,is obtained by vibrating a

    confined weight of sand and measuring the volume.

    The loosest state, is obtained by carefully placing

    the material in a mould.

    mine

    maxe

    Vv= volume of voids, Vs= volume of solids

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    Flat clay particles

    Flat thin particles of clays and colloids

    cohesive soils

    Large surface area with small mass

    Specific surface = surface area/mass

    Electrical forces dominate their behavior

    Negligible gravity forces

    Sand = 0.001 to 0.4 m2/gram

    Silt = 0.4 to 1.0 m2/gram

    Clay = 5 to 800 m2

    /gram

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    Dispersed

    structure

    d) Dispersed - particles repel each other

    (negative to negative charge).

    c) Flocculated clay or cardhouse structure: particles attract to each

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    Plate particles: Flaky or mica shape

    Edge to face contact. It is

    called flocculated or

    cardhouse strcture

    Due to electrical forces and deposition in very low energy

    environments, clays develop structures with large voids ratio

    ) y p

    other in lakes or quiet rivers in edge to face contacts then settle

    dawn due to gravity

    Clay Structure

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    a) Honeycomb structure: particles deposit due

    to gravity forces. During this process they areattracted and attached to others

    Clay Structure(particles equal or smaller than 0.002 mm in size).

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    Floculated structure or superior order honeycomb

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    b) Composite structure: Clay particles are aggregated or flocculated

    together in submicroscopc fabrics units which are called domains. Domains

    form groups called clusters and clusters form peds and group of peds of

    macroscopic size.

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    Composite structure

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    Typical Kaolinite

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    Electronic microscopy of sweep, natural soil

    of Queretaro (Lpez-Lara, 2001).

    Chemical analysis, Tejeda clay

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    2.13Non soluble

    material

    0.06K2O

    0.72Na2O

    5.36MgO

    66.52CaO

    21.75%Lost by

    calcination

    3.663.94Potassium

    1.791.79Sodium

    35.6733.95Calcium

    8.538.48Magnesium

    Interchangeable cations

    (meq/100g)

    7.78.2Ph

    48.86

    me/100g

    49.96

    me/100g

    Cation Exchange capacity

    (CEC)

    1.631.73Organic material

    0.400.47MgO

    1.131.36K2O

    3.634.34CaO

    6.716.74Fe2O3

    19.9319.58AL2O3

    55.76%54.13%SiO

    21

    SampleSubstance

    Lime used in the

    stabilization

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    MONTMORILLONITE

    2

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    SILTSIZE FRACTION OF MEXICO CITY CLAY SHOWING FRAGMENTS OF SHELLS

    (DIATOMS). (DIATOMSARE A MAJOR GROUP OF ALGAE MOST DIATOMSARE

    UNICELLULAR, ALTHOUGH THEY CAN EXIST AS COLONIES).

    20

    Needle particles

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    Halloysite nanotubes imaged at

    Cornell University

    A bundle of NaturalNanohalloysite nanotubes

    compared to the width

    of a human hair

    Sensitivity and Thixotropic

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    y p

    Properties of Clays

    Sensitivity, St: The ratio of peak undisturbedstrength to remolded

    strength, as determined by unconfined compression test, was used

    initially as a quantitative measure of sensitivity (Terzaghi, 1944).

    St = qu/ qr

    Thixotropy: Is defined as an isothermal, reversible, time- dependentprocess occurring in a material under conditions of constant volume

    whereby it stiffens while at rest and softens or liquefies upon

    remolding.

    The remoulding of thixotropic clays causes an abrupt drop in pore

    water tension (increase in pore water pressure) generating an

    important reduction of its strength followed by a slow regain instrength during periods at rest.

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    Thixotropic properties of clays

    Strength

    Time

    Agedstrength

    Remolded

    Remolded

    Remolded Strength

    Sa

    Sr

    Sa/Sr = Thixotropic Strength Ratio

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    Extremely sensitive clays losse

    strength and become fluid when

    remoulded. They are called quick

    clays. (Photograph courtesy of

    Haley and Aldrich, Inc.)

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    St

    Insensitive ~ 1.0

    Slightly sensitive clays 1-2

    Medium sensitive

    clays

    2-4

    Very sensitive clays 4-8

    Slightly quick clays 8-16

    Medium quick clays 16-32

    Very quick clays 32-64Extra quick clays >64

    Classification of Sensitivity Values

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    CAUSES OF SENSITYVITY

    At least six differente phenomena may

    contribuite to the develpment of sensitivity:

    1. Metastable fabric;2. Cementation;

    3. Weathering;

    4. Thixotropic hardening;

    5. Leaching, ion exchange;

    6. Formation or addition of dispersing

    agents.

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    Honeycomb structure

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    Colloidal particles: Grain size less than 0.0002 mm:If the colloidal particles are in a water suspension, there is

    no effect of the gravity forces, they are in Brownian

    movement, it is no possible the sedimentation. There is

    repulsion force among the particles, caused by the negative

    electrical charge on the surface of the grains.

    Only with the addition of a electrolyte to the suspension for

    neutralize the negative charge is possible the fluccullation

    of particles and then the deposition

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    Apparatus

    Apparatus for DTA consists of a:

    Sampler holder, usually ceramic, nickel, or platinum.

    Furnace.

    Temperature controller to provide a constant rate of heating.

    Thermocouples for measurements of temperature and thedifference in temperature between the sample and the inert

    reference material.

    The recorder for the thermocouple output.

    The amount of sample required is about 1 gr.

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    Typical Kaolinite

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    Element Weight% Atomic%

    O K 14.83 26.83Na K 0.75 0.94

    Mg K 2.25 2.68

    Al K 2.75 2.95

    Si K 46.61 48.04

    K K 2.31 1.71

    Ca K 5.01 3.62

    Fe K 25.50 13.22

    Totals 100.00

    Spectrum processing:

    Peaks possibly omitted: 2.149, 8.036, 8.475, 8.900, 9.706, 11.501, 13.367 keV

    Processing option: All elements analyzed (Normalised)

    Number of iterations = 2. Jurica Clay, Queretaro city. Mexico. Alicia Del Real L

    JU100-2 sitio 1 espectro2

    1 3 Characteristics and structure of soils

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    1.3 Characteristics and structure of soilsMercury porosimeter measures pore size distribution in the range of pore diameters

    between 300m and 3 nm. Samples can be in the form of granular powders or monoliths.

    Nitrogen adsorption the pore size distributions in the range of pore diameters between 100

    nm and 1.7 nm, the specific surface area, micropore volume and area, and total porevolume.

    Mercury intrusion

    Nitrogen adsorption

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    Element Weight% Atomic%

    O K 18.71 31.06

    Na K 0.68 0.79

    Mg K 1.75 1.92

    Al K 10.36 10.20

    Si K 46.95 44.40

    K K 2.59 1.76

    Ca K 4.57 3.03

    Fe K 14.38 6.84

    Totals 100.00

    Spectrum processing :

    Peaks possibly omitted : 2.149, 8.036, 8.515, 8.905, 9.706, 11.486, 13.350 keV

    Processing option : All elements analyzed (Normalised)

    Number of iterations = 3. Jurica Clay, Queretaro city. Mexico. Alicia Del Real L.

    Sample: JU100 2 espectro4. Site of Interest 2 Type: Default. JU100-2 sitio 2

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    Element Weight% Atomic%

    O K 18.71 31.06

    Na K 0.68 0.79

    Mg K 1.75 1.92

    Al K 10.36 10.20

    Si K 46.95 44.40

    K K 2.59 1.76

    Ca K 4.57 3.03

    Fe K 14.38 6.84

    Totals 100.00

    Spectrum processing :

    Peaks possibly omitted : 2.149, 8.036, 8.515, 8.905, 9.706, 11.486, 13.350 keV

    Processing option : All elements analyzed (Normalised)

    Number of iterations = 3. Jurica Clay, Queretaro city. Mexico. Alicia Del Real L.

    Sample: JU100 2 espectro4. Site of Interest 2 Type: Default. JU100-2 sitio 2

    BENTONITE

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    BENTONITE

    Bentonite usually forms from weathering of volcanic ash, most often in the

    presence of water. For industrial purposes, two main classes of bentonite exist:

    sodium and calcium bentonite.

    Sodium bentonite expands when wet, possibly absorbing several times its dry

    mass in water. Because of its excellent properties it is often used in drilling mud

    for oil and gas wells and for geotechnical and environmental investigations.

    The property of swelling also makes sodium bentonite useful as a sealant,especially for the sealing of subsurface disposal systems for spent nuclear fuel

    and for quarantining metal pollutants of groundwater. Similar uses include

    making slurry walls, waterproofing of below-grade walls and forming other

    impermeable barriers: e.g., to seal off the annulus of a water well, to plug old

    wells, or as a liner in the base of landfills to prevent migration of leachate.

    Sodium bentonite can also be "sandwiched" between synthetic materials tocreate geo-synthetic clay liners (GLC) for the aforementioned purposes. This

    technique allows for more convenient transport and installation and it greatly

    reduces the volume of sodium bentonite required.

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    A slurry wallis a technique used to build reinforced-concrete walls

    in areas of soft earth close to open water or with a high ground

    water table.

    A trench is excavated to create a form for each wall. The trench is

    kept full of slurry at all times. The slurry prevents the trench from

    collapsing by providing outward pressure which balances the

    inward hydraulic forces and prevents water flow into the trench.Reinforcement is then lowered in and the trench is filled with

    concrete, which displaces the slurry.

    Slurry walls are typically constructed by starting with a set of guide

    walls, typically 1 meter deep and 0.8 meter thick. The guide wallsare constructed on the ground surface to outline the desired slurry

    trench and guide excavation.

    http://upload.wikimedia.org/wikipedia/commons/2/29/SlurrywallEquipment.jpg
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    Slurry wall excavator

    Excavation is done using a special clamshell-

    shaped digger or a hydromill trench cutter.

    The excavator digs down to the required

    depth, or bedrock, for the first cut. Theexcavator is then lifted and moved along the

    trench guide walls to continue the trench with

    successive cuts as needed. The trench is kept

    filled with slurry (usually a mixture of bentonite

    and water) at all times to prevent collapse.

    Once a particular length is reached, a

    reinforcing cage is lowered into the slurry-

    filled pit and then the pit is filled with concrete

    from the bottom up using tremie pipes. The

    concrete displaces the bentonite slurry, whichis pumped out and recycled.

    http://upload.wikimedia.org/wikipedia/commons/2/29/SlurrywallEquipment.jpg
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    Schema of the process of building a Milan Wall: Excavation,

    placement of joints between panels, placement of steel

    reinforcement, filled with concrete from the bottom up using

    tremie pipe.

    Characteristics:

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    Steel reinforcement for Milan Wall 27 m

    deep, Metro, line B.Extraction of metalic joints.

    Metro . Mexico City.

    Characteristics:

    Width: 60 cm (standard) 80 cm

    Depth: up to 45 m

    Mud: Bentontic polymer

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    Completed Milan Walls.

    Metro, Mexico City

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