Chapter 7 Oxidation and Reduction Introduction to Respiration Day 2.

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Chapter 7 Oxidation and Reduction Introduction to Respiration Day 2

Transcript of Chapter 7 Oxidation and Reduction Introduction to Respiration Day 2.

Chapter 7Oxidation and Reduction

Introduction to RespirationDay 2

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Cellular respiration can best be described as

A. using energy released from breaking high-energy covalent bonds in organic molecules to make ATP.

B. taking electrons from food and giving them to oxygen to make water and using the energy released to make ATP.

C. converting higher-energy organic molecules to lower-energy organic molecules and using the energy released to make ATP.

The Principle of Redox

• Chemical reactions that transfer electrons between reactants are called oxidation-reduction reactions, or redox reactions.

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Oxidation

• In oxidation, a substance loses electrons, or is oxidized.

Redox• In reduction, a substance gains electrons, or is

reduced (the amount of positive charge is reduced).

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• The electron donor is called the reducing agent. (Na)

• The electron acceptor is called the oxidizing agent. (Cl)

becomes oxidized(loses electron)

becomes reduced(gains electron)

Figure 7.UN02

becomes oxidized

becomes reduced

• The electron donor is called the reducing agent. (X)

• The electron acceptor is called the oxidizing agent. (Y)

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Figure 7.3

Reactants Products

Methane(reducing

agent)

Oxygen(oxidizing

agent)

Carbon dioxide Water

becomes reduced

becomes oxidized

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Figure 7.UN03

becomes oxidized

becomes reduced

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Stepwise Energy Harvest via NAD+ and the Electron Transport Chain

In cellular respiration, glucose and other organic molecules are broken down in a series of steps.

Electrons from organic compounds are usually first transferred to NAD, a coenzyme.

As an electron acceptor, NAD functions as an oxidizing agent during cellular respiration.

Each NADH (the reduced form of NAD) represents stored energy that is tapped to synthesize ATP.

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Figure 7.4

NAD

Nicotinamide(oxidized form)

Nicotinamide(reduced form)

Oxidation of NADH

Reduction of NAD

DehydrogenaseNADH

2[H] (from food)

2 e− 2 H

2 e− H

H

H

Figure 7.UN04

NADH passes the electrons to the electron transport chain.

Unlike an uncontrolled reaction, the electron transport chain passes electrons in a series of steps instead of one explosive reaction.

O2 pulls electrons down the chain in an energy-yielding tumble.

The energy yielded is used to regenerate ATP.

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Figure 7.5

Explosiverelease

(a) Uncontrolled reaction (b) Cellular respiration

H2O

Fre

e en

erg

y, G

Fre

e en

erg

y, G

Electro

n tran

spo

rt

chain

Controlledrelease of

energy

H2O

2 H

2 e−

2 H 2 e−

ATP

ATP

ATP

½

½

½H2 O2 O2

O2

2 H

Zombie Ladybug

When a female Dinocampus coccinellae wasp stings a ladybug, it leaves behind a single egg. After the egg hatches, the larva begins to eat its host form the inside out. When ready, the parasite emerges and spins a cocoon between the ladybug’s legs. Though the body is now free of the tormentor, the bug remains enslaved, standing over the cocoon and protecting it form predators.