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    Copyright 2005 Pearson Education, Inc. publishing as Benjamin Cummings

    PowerPoint Lectures forBiology, Seventh Edition

    Neil Campbell and Jane Reece

    Lectures by Chris Romero

    Chapter 3

    ater and the !itness o"

    the En#ironment

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    Overview: The Molecule That Supports All of

    Life$ Water is the biological medium here on arth

    $ All living organisms re!uire water more than

    an" other substance

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    Three#!uarters of the arth$s surface is

    submerged in water The abundance of water is the main reason the

    arth is habitable

    Figure 3.1

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    %oncept &'(: The polarity of water molecules

    results in hydrogen bonding The water molecule is a polar molecule

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    The polarit" of water molecules

    $ Allows them to form h"drogen bonds with eachother

    $ %ontributes to the various properties water

    e)hibits

    *"drogen

    bonds

    +

    +

    *

    *+

    +

    ,

    ,

    ,,

    Figure 3.2

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    %oncept &'-: .our emergent propertiesof water

    contribute to arth$s fitness for life

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    Cohesion (1)

    Water molecules e)hibit cohesion

    %ohesion

    $ /s the bonding of a high percentage of the

    molecules to neighboring molecules

    $ /s due to h"drogen bonding

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    %ohesion

    $ *elps pull water up through the microscopicvessels of plants

    Water conducting cells

    (00 mFigure 3.3

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    Surface tension

    $ /s a measure of how hard it is to brea1 thesurface of a li!uid

    $ /s related to cohesion

    Figure 3.4

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    Moderation of Temperature (2)

    Water moderates air temperature

    $ 2" absorbing heat from air that is warmer andreleasing the stored heat to air that is cooler

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    Heat and Temperature

    3inetic energ"

    $ /s the energ" of motion

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    *eat

    $ /s a measure of the total amount of 1ineticenerg" due to molecular motion

    Temperature

    $ Measures the intensit" of heat

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    Waters High pecific Heat

    The specific heatof a substance

    $ /s the amount of heat that must be absorbed orlost for 1 gram of that substance to change its

    temperature by 1C

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    Water has a high specific heat4 which allows it

    to minimi5e temperature fluctuations to withinlimits that permit life

    $ *eat is absorbed when h"drogen bonds brea1

    $ *eat is released when h"drogen bonds form

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    !"aporati"e Coo#ing

    vaporation

    $ /s the transformation of a substance from ali!uid to a gas

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    Heat of vaporization

    $ /s the quantity of heat a liquid must absorb for 1gram of it to be converted from a liquid to a gas

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    vaporative cooling

    $ /s due to water$s high heat of vapori5ation

    $ Allows water to cool a surface

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    $nsu#ation of %odies of Water by oating $ce

    Solid water4 or ice e)pands upon cooling 6&7

    $ /s less dense than li!uid water

    $ .loats in li!uid water

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    The h"drogen bonds in ice

    $ Are more 8ordered9 than in li!uid water4 ma1ingice less dense

    i!uid water

    *"drogen bondsconstantl" brea1 and re#form

    "ce

    *"drogen bonds are stable

    *"drogenbond

    Figure 3.#

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    Since ice floats in water

    $ Life can e)ist under the fro5en surfaces ofla1es and polar seas

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    The o#"ent of Life (')

    Water is a versatile solvent due to its polarit"

    /t can form a!ueous solutions

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    The different regions of the polar water

    molecule can interact with ionic compoundscalled solutes and dissolve themegative

    o)"gen regions

    of polar water molecules

    are attracted to sodium

    cations 6a+7'

    +

    +

    +

    +%l ,

    ,

    ,

    ,

    ,

    a+Positive

    h"drogen regions

    of water molecules

    cling to chloride anions

    6%l,7'

    +

    +

    +

    +

    ,

    ,

    ,

    ,

    ,

    ,

    a+

    %l,

    Figure 3.$

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    Water can also interact with polar molecules

    such as proteins

    This o)"gen is

    attracted to a slight

    positive charge on

    the l"so5"me

    molecule'This o)"gen is attracted to a slight

    negative charge on the l"so5"me

    molecule'%a&L"so5"me molecule

    in a nona!ueous

    environment

    %b& L"so5"me molecule 6purple7

    in an a!ueous environment

    such as tears or saliva

    %c& /onic and polar regions on the protein$s

    Surface attract water molecules'

    +

    ,

    Figure 3.'

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    Hydrophi#ic and Hydrophobic ubstances

    A h"drophilic substance

    $ *as an affinit" for water

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    A h"drophobic substance

    $ ;oes not have an affinit" for water

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    o#ute Concentration in ueous o#utions

    Since most biochemical reactions occur in

    water$ /t is important to learn to calculate the

    concentration of solutes in an a!ueous solution

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    A mole

    $

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    %oncept &'&: ;issociation of water molecules

    leads to acidic and basic conditions that affect

    living organisms

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    Water can dissociate

    $ /nto h"dronium ions and h"dro)ide ions

    %hanges in the concentration of these ions

    $ %an have a great affect on living organisms

    *

    *"droniumion 6*&O

    +7

    *

    *"dro)ideion 6O*,7

    *

    *

    *

    *

    *

    *

    + ,

    +

    Figure on p. #3 of water

    dissociating

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    cids and %ases

    An acid

    $ /s an" substance that increases the h"drogenion concentration of a solution

    A base

    $ /s an" substance that reduces the h"drogen

    ion concentration of a solution

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    The pH ca#e

    The p* of a solution

    $ /s determined b" the relative concentration ofh"drogen ions

    $ p* is low in an acid 6high *+ concentration7

    $ p* is high in a base 6low *+ concentration7

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    The p* scale and p* values of various

    a!ueous solutions

    /ncreasingl"(cidic

    =*+>

    ?=O*,>

    /ncreasingl")a

    sic

    =*+>@=O*,>

    *eutral

    =*+> =O*,>

    Oven cleaner

    0

    (

    -

    &

    B

    C

    D

    E

    F

    G(0

    ((

    (-

    (&

    (B

    pH +cale

    2atter" acid

    ;igestive 6stomach7Huice4 lemon HuiceIinegar4 beer4 wine4

    colaTomato Huice

    2lac1 coffee

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    %uffers

    The internal p* of most living cells

    $ Must remain close to p* E

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    2uffers

    $ Are substances that minimi5e changes in theconcentrations of h"drogen and h"dro)ide ions

    in a solution

    $ %onsist of an acid#base pair that reversibl"combines with h"drogen ions