Ch5_WS1

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Cambridge International AS and A Level Chemistry Original material © Cambridge University Press 2011 1 Worksheet 5.1 Kinetic theory and the general gas equation 1 a Describe the changes that occur in the closeness and motion of the particles when: i a gas changes to a liquid [4] ii a solid changes to a liquid. [4] b State the name given to each of the changes in part a. [2] c What energy change occurs when: i a gas changes to a liquid? [1] ii a liquid changes to a gas at a temperature below the boiling point of the liquid? [1] 2 a Under what conditions do the properties of an ideal gas differ from those of a real gas? [2] b For the conditions you stated in part a, explain how an ideal gas would behave. [4] c Explain why the properties of ideal gases differ from those of real gases. [5] In questions 3 and 4 you will need to use the gas constant, R. You will find this value in Data sheet 1. 3 The relative molecular mass of a volatile liquid can be found by vaporising the liquid in a gas syringe. 0.0750 g of a hydrocarbon vapour occupies 25.0 cm 3 at 77.0 °C. Atmospheric pressure is 101.3 kPa. a What is the value of the temperature in kelvins? [1] b What is the atmospheric pressure in pascals? [1] c What is the volume of the hydrocarbon vapour in m 3 ? [1] d Use the general gas equation to calculate the relative molecular mass of the hydrocarbon. [3] 4 A hydrocarbon with relative molecular mass 58.0 exists as a vapour at 100 °C and atmospheric pressure 101 kPa. Under these conditions, 0.100 g of this hydrocarbon was present as vapour. a Calculate the number of moles of the hydrocarbon. Give your answer to 3 significant figures. [1] b What is the value of the temperature in kelvins? [1] c What is the atmospheric pressure in pascals? [1] d What volume, in cm 3 , does this hydrocarbon occupy under these conditions? [4]

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KINETIC ENERGY AND GASES

Transcript of Ch5_WS1

Page 1: Ch5_WS1

Cambridge International AS and A Level Chemistry  Original material © Cambridge University Press 2011  1 

Worksheet 5.1 

Kinetic theory and the general gas equation 

1  a  Describe the changes that occur in the closeness and motion of the particles when: i  a gas changes to a liquid  [4] ii  a solid changes to a liquid.  [4] 

b  State the name given to each of the changes in part a.  [2] c  What energy change occurs when: 

i  a gas changes to a liquid?  [1] ii  a liquid changes to a gas at a temperature below the boiling point of the liquid?  [1] 

2  a  Under what conditions do the properties of an ideal gas differ from those of a real gas?  [2] b  For the conditions you stated in part a, explain how an ideal gas would behave.  [4] c  Explain why the properties of ideal gases differ from those of real gases.  [5] 

In questions 3 and 4 you will need to use the gas constant, R. You will find this value in Data sheet 1. 

3  The relative molecular mass of a volatile liquid can be found by vaporising the liquid in a gas syringe. 0.0750 g of a hydrocarbon vapour occupies 25.0 cm 3 at 77.0 °C. Atmospheric pressure is 101.3 kPa. a  What is the value of the temperature in kelvins?  [1] b  What is the atmospheric pressure in pascals?  [1] c  What is the volume of the hydrocarbon vapour in m 3 ?  [1] d  Use the general gas equation to calculate the relative molecular mass of the hydrocarbon.  [3] 

4  A hydrocarbon with relative molecular mass 58.0 exists as a vapour at 100 °C and atmospheric pressure 101 kPa. Under these conditions, 0.100 g of this hydrocarbon was present as vapour. a  Calculate the number of moles of the hydrocarbon. Give your answer to 3 significant 

figures.  [1] b  What is the value of the temperature in kelvins?  [1] c  What is the atmospheric pressure in pascals?  [1] d  What volume, in cm 3 , does this hydrocarbon occupy under these conditions?  [4]