ch 8 covalent 1.notebook - Perry Local Schools – Massillon...
Transcript of ch 8 covalent 1.notebook - Perry Local Schools – Massillon...
ch 8 covalent 1.notebook
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December 09, 2014
Dec 33:56 PM
CHEMICALBONDING
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CHEMICAL BOND:A MUTUAL ELECTRICAL ATTRACTION BETWEEN THE NUCLEI AND VALENCE ELECTRONS OF DIFFERENT ATOMS THAT BINDS THE ATOMS TOGETHER.
Types of Bonds:
Ionic Covalent
e-
e-
Cl
e-e-
e- e-
e-
e-
e-
Cl
e-e-
e- e-
e-
e-
-Na
+
NaCl = sodium chloride
Nae-
Sodium atom Chlorine atom
H
HC
H
H
CH4
methane
electron sharing by overlap of orbitals
electron transfer
Nov 178:09 AM
A chemical bond:the force that holds 2 atoms together
COVALENTIONIC
*sharing valence electronsto have a full octet
* electrostatic attractionbetween + and - ions* occurs between a metal and a nonmetal* occurs between monatomic and/or polyatomic ions
Dec 33:58 PM
How do you know what type of bond will form?
Dec 33:50 PM
Atoms gain stability when they share electrons:
* lower energy
* stable electron configuration (octet rule)
Why would a covalent bond even form?
Dec 34:43 PM
Bond formation is EXOTHERMIC!
ch 8 covalent 1.notebook
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December 09, 2014
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Covalent Bond:
ATTRACTIONS:* nucleus of hydrogen a attracted to hydrogen b's e -
* hydrogen a's e - attracted to hydrogen b's nucleusREPULSIONS:* both nuclei repel each other* both electrons repel each other
WHEN THE FORCES ARE BALANCED = STABLE COVALENT BOND
e- e-
Hydrogen atom a Hydrogen atom b
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Covalent bonds *always* involve the VALENCE electrons.
F = 1s2 2s2 2p5
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Types of Covalent Bonds:
* single
* double
* triple N N ::
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Sigma and pi bonds:
Sigma bonds occur in ALL covalent bonds. They are the result of cloud overlap.
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Pi bonds:
* only occur in double and triple bonds * forms when parallel orbitals overlap
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Sigma and pi bonding in a double bond:
ch 8 covalent 1.notebook
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December 09, 2014
Dec 34:27 PM
Sigma and 2 pi bonds in a triple bond:
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Bond length decreases from a double to a triple bond.
Bond energy increases.
(Inverse relationship)
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Molecule Bond type Bond lengthBond dissociation
energy(pm) (kJ/mol)
single 143 159
double 121 498
triple 110 945
Dec 34:40 PM
Bond dissociation energy:
amount of energy required to break a bond
endothermic
Dec 34:45 PM