CCR Monitoring Closure Verification Report · closure verification groundwater data were reviewed...

4300 MarketPointe Drive, Suite 200

Minneapolis, MN 55435

952.832.2600

www.barr.com

CCR Monitoring Closure Verification Report

Black Dog Generating Plant

Burnsville, Minnesota

Prepared for

Northern States Power Company

July 31, 2019

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Monitoring\Confidential Reporting\Closure Verification\Closure Verification Report_073019.docx

i

CCR Monitoring Closure Verification Report

July 31, 2019

Contents

1.0 Introduction ........................................................................................................................................................................... 1

1.1 Background ....................................................................................................................................................................... 1

1.2 Report Organization ...................................................................................................................................................... 1

2.0 Groundwater Protection Standards .............................................................................................................................. 2

2.1 CCR Monitoring System ............................................................................................................................................... 2

2.2 Baseline Data Collection .............................................................................................................................................. 2

2.2.1 Data Quality Review ................................................................................................................................................. 3

2.3 Background Concentrations ....................................................................................................................................... 3

2.3.1 Background Data Set ............................................................................................................................................... 3

2.3.2 Background Calculation .......................................................................................................................................... 3

2.4 Establishment of Groundwater Protection Standards ...................................................................................... 4

3.0 Closure Verification ............................................................................................................................................................. 5

3.1 Groundwater Flow Direction ...................................................................................................................................... 5

3.2 Analytical Results ............................................................................................................................................................ 5

3.3 Conclusion ......................................................................................................................................................................... 5

4.0 References Cited .................................................................................................................................................................. 6

ii

List of Tables

Table 1 CCR Groundwater Protection Standards

Table 2 Closure Verification Monitoring Results

List of Figures

Figure 1 Site Location

Figure 2 Site Map

Figure 3 Water Table Map, March 11, 2019

Figure 4 Water Table Map, May 13, 2019

List of Appendices

Appendix A Baseline Data

Appendix B Data Quality Control / Quality Assurance Review

Appendix C Development of Groundwater Protection Standards

Appendix D Closure Monitoring Data

iii

Certifications

I hereby certify that I have examined the facility and, being familiar with the provisions of 40 CFR 257

Subpart D, attest that the groundwater data have been collected appropriately and that this

Groundwater Closure Report has been prepared in accordance with good engineering practice,

including consideration of applicable industry standards and the requirements of 40 CFR §257.91. I

hereby certify that the monitoring system is adequate for this facility. I further certify that I am a duly

Licensed Professional Engineer under the laws of the state of Minnesota.

July 31, 2019

Jeremy J. Gacnik, P.E.

PE #: 49292

Date

iv

Acronyms

Acronym Description

CCR coal combustion residuals

EPA United States Environmental Protection Agency

GWPS groundwater protection standards

MCL maximum containment level

NSPM Northern States Power Company

RCRA Resource Conservation and Recovery Act

SAP Sampling and Analysis Plan

SOP standard operating procedure

UPL upper prediction limit

1

1.0 Introduction

This Closure Monitoring Verification Report provides groundwater monitoring information supporting the

certification of closure of the Black Dog Generating Plant coal combustion residuals (CCR) units in

accordance with the United States Environmental Protection Agency (EPA) rule to regulate the disposal of

CCR as solid waste [CCR Rule: Subtitle D of the Resource Conservation and Recovery Act (RCRA), 40 CFR

Parts 257 and 261 (EPA, 2015a)]. Under the provision for closure by removal of CCR, §257.102(c) of the

CCR Rule states:

Closure by removal of CCR: An owner or operator may elect to close a CCR unit by removing and

decontaminating all areas affected by releases from the CCR unit. CCR removal and

decontamination of the CCR unit are complete when constituent concentrations throughout the CCR

unit and any areas affected by releases from the CCR unit have been removed and groundwater

monitoring concentrations do not exceed the groundwater protection standard established pursuant

to § 257.95(h) for constituents listed in appendix IV to this part.

1.1 Background

Northern States Power Company, a Minnesota corporation doing business as Xcel Energy (NSPM),

formerly operated three CCR units, referred to as Ash Ponds 1, 2, and 3 (collectively the Ash Ponds) at its

Black Dog Generating Plant (Plant or Site), located in Burnsville, MN (Figure 1). Coal operations ceased at

the Plant on April 16, 2015 and CCR discharges to the Ash Ponds ceased prior to October 19, 2015. The

remaining wastewater discharged from the Plant was directed to an alternate discharge system in 2016,

thereby allowing for closure of the Ash Ponds and their associated components. NSPM drained the Ash

Ponds and removed CCR in accordance with the Ash Pond Closure Plan (Barr, 2016) by December 12,

2016. The removal of CCR throughout the CCR Units is documented in the CCR Surface Impoundment

Closure Certification Report, Ash Ponds 1-3 (Barr, 2017a).

1.2 Report Organization

This report is organized into the following additional sections:

Section 2.0 of this report documents the process for establishing groundwater protection

standards (GWPS) pursuant to §257.95(h) for constituents listed in appendix IV to the CCR Rule.

Section 3.0 of this report describes hydrogeologic conditions and documents that groundwater

monitoring concentrations do not exceed the GWPS, demonstrating that the Site meets the

requirements for closure in accordance with §257.102(c).

Section 4.0 includes references.

2

2.0 Groundwater Protection Standards

As stated in the CCR Rule (as modified by Amendments to the National Minimum Criteria [Phase One, Part

One], July 30, 2018), GWPS are to be established in accordance with §257.95(h), which states:

(h) The owner or operator of the CCR unit must establish a groundwater protection standard for

each constituent in appendix IV to this part detected in the groundwater. The groundwater

protection standard shall be:

(1) For constituents for which a maximum contaminant level (MCL) has been established

under §§ 141.62 and 141.66 of this title, the MCL for that constituent;

(2) For the following constituents:

(i) Cobalt 6 micrograms per liter (µg/l);

(ii) Lead 15 µg/l;

(iii) Lithium 40 µg/l; and

(iv) Molybdenum 100 µg/l

(3) For constituents for which the background level is higher than the levels identified under

paragraphs (h)(1) and (h)(2) of this section, the background concentration.

Therefore, to develop values for GWPS, the “background concentration” needs to be determined for each

appendix IV constituent and compared to the MCL and the values in (h)(2) above. The following

subsections provide details on the baseline monitoring used to develop the background concentrations

and the development of GWPS.

2.1 CCR Monitoring System

NSPM established a multiunit groundwater monitoring system for the former CCR Units in 2017 for use in

conducting baseline monitoring to establish background conditions, and then for use in final closure

monitoring to document GWPS were met. The monitoring system included seven wells to characterize

background groundwater conditions at the Site and five wells located downgradient of the former CCR

Units for closure monitoring. The monitoring system is documented in the Groundwater Monitoring

System Certification Report (Barr, 2019a) and shown on Figure 2.

2.2 Baseline Data Collection

During the baseline groundwater monitoring period, December 2017 through October 2018, each

monitoring well was sampled a minimum of eight times. Each sampling event included measuring water

levels to evaluate the groundwater flow direction at the Site and the collection of samples for laboratory

analysis of parameters listed in Appendices III and IV of the CCR Rule. Groundwater samples were also

analyzed for additional parameters (e.g., major cations and anions) to verify the appropriateness of the

monitoring network.

3

The groundwater samples were collected and analyzed in accordance with the Sampling and Analysis Plan

(SAP; Barr, 2017b). Sampling services were provided by Pace Analytical Services of Minneapolis, Minnesota

(Pace). The samples were analyzed by the following labs using the appropriate methodologies: Xcel

Energy’s Minneapolis Testing Laboratory and Pace Analytical Services located in Greensburg,

Pennsylvania. Copies of the laboratory reports with the baseline groundwater data are included in

Appendix A.

2.2.1 Data Quality Review

The baseline groundwater data were reviewed in general accordance with Barr’s data quality review

standard operating procedures (SOPs) included in the SAP (Barr, 2017b). The data quality reviews included

a check for completeness, field quality control, and laboratory quality control. Details from the data

quality review are included in Appendix B. The baseline groundwater data were determined to be

acceptable as qualified with the exception of the following rejected data:

Well Sample Date Rationale Details

W600A May 8, 2018 Elevated turbidity (200 NTU) Analytical data from this well / sampling events were

rejected and are not included in the baseline data set. W600A June 12, 2018 Elevated turbidity (54 NTU)

W601A February 7, 2018 Elevated turbidity (320 NTU) Analytical data from this well / sampling event were

rejected and are not included in the baseline data set.

These wells were resampled on two occasions for which the data was determined to be acceptable for

use.

2.3 Background Concentrations

Background concentrations for each appendix IV parameter were determined based on results of

background well sampling during the CCR baseline monitoring period. Background concentrations were

established in accordance with the methods outlined in the CCR Groundwater Statistical Analysis Plan

(Barr, 2019c). The methods used to establish background concentrations are discussed below, and

detailed information regarding the background data assessment is provided in Appendix C.

2.3.1 Background Data Set

The background data set (Table C-1) includes monitoring results from background well sampling

completed during the baseline monitoring period. This data set was used to establish background

concentrations for the constituents listed in appendix IV of the CCR Rule. Representativeness of the data

was reviewed by performing outlier testing, as described in Appendix C. All values were retained for use in

the background data set.

2.3.2 Background Calculation

Consistent with the CCR Rule (§257.93 (f)), statistical methods were used to evaluate the background data

set and establish background concentrations (Barr, 2019c). Background concentrations for each appendix

4

IV parameter were calculated based on the upper prediction limit (UPL) of the background data set, with

95% probability and two future measurements, coinciding with the two closure monitoring events.

Prior to computing the UPL, goodness-of-fit testing was performed on the background data set for each

appendix IV parameter to assess whether the data sets fit a normal distribution. For all parameters, the

data set did not fit a normal distribution, therefore, nonparametric methods were used for the statistical

analysis. Goodness-of-fit test results are included in Table C-2 in Appendix C.

The UPL results are shown in Table C-3 in Appendix C.

2.4 Establishment of Groundwater Protection Standards

In accordance with the CCR Rule (§257.95(h)), GWPS were established to be the highest of the following

values: the MCL; the values listed for cobalt, lead, lithium, and molybdenum; or the background

concentrations (UPL), as shown in Table C-2. The GWPS are provided in Table 1.

5

3.0 Closure Verification

As defined in the CCR Rule (§257.102(c)), closure verification sampling was needed to confirm

groundwater monitoring concentrations do not exceed the GWPS. Closure verification sampling took

place in March and May 2019, and included the measurement of water levels in the monitoring wells to

verify groundwater flow directions at the Site and the collection of samples in downgradient wells for

laboratory analysis and comparison to the GWPS. Groundwater samples were also collected from the

background wells for informational purposes. The samples were analyzed for the parameters listed in

Appendices III and IV of the CCR Rule and additional parameters (e.g., major cations and anions). The

sampling, laboratory analysis, and data quality review methods were consistent with the methods used

during baseline sampling and the SAP, updated at the time of network certification (Barr, 2019b). The

closure verification groundwater data were reviewed and determined to be acceptable with qualifications,

as presented in Appendix B. Closure monitoring laboratory reports are included in Appendix D.

3.1 Groundwater Flow Direction

Maps depicting groundwater contours and flow directions during the closure monitoring events are

attached as Figures 3 and 4. The groundwater flow directions at the Site during these monitoring events

were consistent with flow patterns observed during baseline sampling and the downgradient wells were

positioned hydraulically downgradient of the former CCR units.

3.2 Analytical Results

The concentrations of parameters listed in appendix IV of the CCR rule from downgradient well sampling

during the two closure monitoring events are compared to GWPS in Table 2. No appendix IV parameters

were detected in downgradient wells at concentrations above the GWPS established pursuant to

§257.95(h).

3.3 Conclusion

Groundwater monitoring at the Site was conducted in accordance with the CCR Rule to support closure of

the CCR units. Closure monitoring results were below GWPS, therefore the Site meets the requirements

for closure of the CCR units in accordance with §257.102(c).

6

4.0 References Cited

Barr, 2019a. Groundwater Monitoring System Certification Report, Black Dog Generating Plant, Ash Ponds

1-3, Burnsville, Minnesota. Prepared for Northern States Power Company. March 2019

Barr, 2019b. Sampling and Analysis Plan, CCR Rule Groundwater Monitoring Program, Black Dog

Generating Plant. Prepared for Northern States Power Company. April 2019.

Barr, 2019c. CCR Groundwater Statistical Analysis Plan, Black Dog Generating Plant. Prepared for Northern

States Power Company. April 2019.

Barr, 2017a. CCR Surface Impoundment Closure Certification Report, Ash Ponds 1-3, Black Dog Generating

Plant. Prepared for Northern States Power Company. February 2017.

Barr, 2017b. Sampling and Analysis Plan, CCR Rule Groundwater Monitoring Program, Black Dog

Generating Plant. Prepared for Northern States Power Company. November 2017.

Barr, 2016. Ash Pond Closure Plan, Black Dog Generating Plant. Prepared for Northern States Power

Company. May 2016.

EPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities: Unified Guidance. EPA

530/R-09-007. March 2009.

EPA, 2010. National Functional Guidelines for Inorganic Superfund Data Review, US EPA Contract

Laboratory Program, United States Environmental Protection Agency. [Online] OSWER 9240.1-51.

USEPA-540-R-10-011, January 2010.

http://epa.gov/superfund/programs/clp/download/ism/ism1nfg.pdf.

EPA, 2015a. Hazardous and Solid Waste Management Systems; Management of Coal Combustion

Residuals From Electric Utility, CFR Parts 257 and 261 , Federal Register, Vol. 80, No. 74, April 17,

2015.

Tables

Table 1

CCR Groundwater Protection Standards


Burnsville, MN

Parameter Units GWPS

Appendix IV Parameters

Antimony, total ug/l 6 MCL

Arsenic, total ug/l 51 UPL

Barium, total ug/l 2000 MCL

Beryllium, total ug/l 4 MCL

Cadmium, total ug/l 5.47 UPL

Chromium, total ug/l 100 MCL

Cobalt, total ug/l 49.1 UPL

Fluoride mg/l 4 MCL

Lead, total ug/l 15 MCL

Lithium, total mg/l 0.418 UPL

Mercury, total ug/l 2 MCL

Molybdenum, total ug/l 323 UPL

Selenium, total ug/l 159 UPL

Thallium, total ug/l 2 MCL

Radium, combined (226+228), Calculation pCi/l 5 MCL

Notes:

MCL - Maximum contaminant level.

UPL -Background Upper Prediction Limit. Upper Tolerance Limit and Upper Prediction Limit are equal

because distribution is nonparametric

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Table 2

Closure Verification Monitoring Results


Burnsville, MN

W602A W602A W603A W603A W604A W604A W605A W605A W7A W7A

3/13/2019 5/15/2019 3/12/2019 5/14/2019 3/12/2019 5/14/2019 3/12/2019 5/14/2019 3/13/2019 5/15/2019

N N N N N N N N N N

Parameter Units

Xcel Black Dog

Groundwater Protection

Standards

Effective Date

Exceedance Key No Exceedances


Antimony, total ug/l 6 MCL < 0.500 < 0.500 1.21 1.04 0.845 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Arsenic, total ug/l 51 UPL 3.14 3.12 5.18 4.62 3.56 2.48 4.69 5.79 1.29 1.11

Barium, total ug/l 2000 MCL 77.4 66.5 42.8 45.0 46.1 37.7 49.8 44.5 52.8 72.4

Beryllium, total ug/l 4 MCL < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Cadmium, total ug/l 5.47 UPL < 0.100 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100 0.123 < 0.100

Chromium, total ug/l 100 MCL < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Cobalt, total ug/l 49.1 UPL 1.88 0.531 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Fluoride mg/l 4 MCL < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

Lead, total ug/l 15 MCL < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Lithium, total mg/l 0.418 UPL 0.0249 0.0181 0.109 0.0971 0.0291 0.0164 < 0.0150 < 0.0150 0.0223 < 0.0150

Mercury, total ug/l 2 MCL < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

Molybdenum, total ug/l 323 UPL 68.6 46.4 158 164 122 86.9 88.8 47.8 81.2 34.8

Selenium, total ug/l 159 UPL < 0.500 < 0.500 1.42 2.90 6.54 2.02 < 0.500 0.507 < 0.500 < 0.500

Thallium, total ug/l 2 MCL < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Radium 226 pCi/l 0.262 +/- 0.364 ND 0.495 +/- 0.371 0.571 +/- 0.563 ND 0.236 +/- 0.402 ND 0.173 +/- 0.635 ND 0.205 +/- 0.484 ND -0.216 +/- 0.425 ND 0.473 +/- 0.516 ND 0.324 +/- 0.383 ND 0.556 +/- 0.383

Radium 228 pCi/l 0.762 +/- 0.381 b 0.641 +/- 0.645 ND 0.847 +/- 0.461 b 0.150 +/- 0.780 ND 0.253 +/- 0.352 ND 0.819 +/- 0.824 ND 0.736 +/- 0.461 ND -0.504 +/- 0.635 ND 0.0840 +/- 0.381 ND 1.15 +/- 0.785 ND

Radium, combined (226+228),

Barr Calculation pCi/l 5 MCL 0.26 +/- 0.36 ND 1.14 +/- 0.74 q 0.57 +/- 0.56 ND 0.386 +/- 0.88 ND 0.43 +/- 0.73 ND 1.02 +/- 0.96 ND 0.74 +/- 0.46 ND 0.473 +/- 0.52 ND 0.41 +/- 0.54 ND 1.71 +/- 0.87 q

Location

Date

Sample Type

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Data Footnotes and Qualifiers

-- Not analyzed/Not available.

N Sample Type: Normal

NDNot detected. Radiochemical parameters are ND if the uncertainty is greater than the result or if

the MDC is greater than the result.

b

Radium 228 result is a potential false positive value based on blank data validation procedures.

Concentrations identified as potential false positive are excluded from calculations. Combined

Radium result is the same as the Radium 226 result.

q The combined radium result includes both detected and not detected values.

MCL Maximum contaminant level.

UPLBackground Upper Prediction Limit. Upper Tolerance Limit and Upper Prediction Limit are equal

because distribution is nonparametric

Barr Standard Footnotes and Qualifiers

Xcel Black Dog Groundwater Protection Standards

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Figures

SITE LOCATION

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FIGURE 3WATER TABLE MAP

March 11, 2019Black Dog Generating Plant

Xcel EnergyBurnsville, Minnesota



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FIGURE 4WATER TABLE MAP

May 13, 2019Black Dog Generating Plant

Xcel EnergyBurnsville, Minnesota



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Apparent Groundwater Flow Direction

Water Table Contour (1 ft)

Approximate Water Table Contour (1 ft)





700.04 Elevation in Feet MSL

Note: Additional contour lines along the South Margin are not shown.

Appendices

Appendix A

Baseline Data

#=CL#

January 08, 2018

LIMS USE: FR - DAVE ANDERSONLIMS OBJECT ID: 30238992

30238992Project:Pace Project No.:

RE:

Dave AndersonPace Analytical Services - Field Svcs Division1700 Elm Street, Suite 200Minneapolis, MN 55414

17-1366,Xcel Energy-Black Dog

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Carin [email protected]

Project Manager724-850-5615

Enclosures

cc: Harry S. Davis III, Xcel EnergyCharles A. Donkers, Xcel EnergyChristine M. Keefe, Xcel EnergyCiara Ruikkie, Pace Analytical Services - Field SvcsDivision

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC1638 Roseytown Road - Suites 2,3,4

Greensburg, PA 15601(724)850-5600

Page 1 of 18

#=CP#

CERTIFICATIONS

Pace Project No.:Project:


Pennsylvania Certification IDs1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601L-A-B DOD-ELAP Accreditation #: L2417Alabama Certification #: 41590Arizona Certification #: AZ0734Arkansas CertificationCalifornia Certification #: 04222CAColorado CertificationConnecticut Certification #: PH-0694Delaware CertificationFlorida/TNI Certification #: E87683Georgia Certification #: C040Guam CertificationHawaii CertificationIdaho CertificationIllinois CertificationIndiana CertificationIowa Certification #: 391Kansas/TNI Certification #: E-10358Kentucky Certification #: 90133Louisiana DHH/TNI Certification #: LA140008Louisiana DEQ/TNI Certification #: 4086Maine Certification #: PA00091Maryland Certification #: 308Massachusetts Certification #: M-PA1457Michigan/PADEP CertificationMissouri Certification #: 235

Montana Certification #: Cert 0082Nebraska Certification #: NE-05-29-14Nevada Certification #: PA014572015-1New Hampshire/TNI Certification #: 2976New Jersey/TNI Certification #: PA 051New Mexico Certification #: PA01457New York/TNI Certification #: 10888North Carolina Certification #: 42706North Dakota Certification #: R-190Oregon/TNI Certification #: PA200002Pennsylvania/TNI Certification #: 65-00282Puerto Rico Certification #: PA01457Rhode Island Certification #: 65-00282South Dakota CertificationTennessee Certification #: TN2867Texas/TNI Certification #: T104704188-14-8Utah/TNI Certification #: PA014572015-5USDA Soil Permit #: P330-14-00213Vermont Dept. of Health: ID# VT-0282Virgin Island/PADEP CertificationVirginia/VELAP Certification #: 460198Washington Certification #: C868West Virginia DEP Certification #: 143West Virginia DHHR Certification #: 9964CWisconsin CertificationWyoming Certification #: 8TMS-L




Greensburg, PA 15601(724)850-5600

Page 2 of 18

#=SS#

SAMPLE SUMMARY



Lab ID Sample ID Matrix Date Collected Date Received

30238992001 Field Blank Water 12/11/17 13:15 12/16/17 10:30

30238992002 W504A Water 12/11/17 14:10 12/16/17 10:30

30238992003 W504B Water 12/11/17 15:00 12/16/17 10:30

30238992004 W502A Water 12/12/17 09:45 12/16/17 10:30

30238992005 W502B Water 12/12/17 10:25 12/16/17 10:30

30238992006 W602A Water 12/12/17 11:30 12/16/17 10:30

30238992007 W7A Water 12/12/17 12:40 12/16/17 10:30

30238992008 W14A Water 12/12/17 13:30 12/16/17 10:30

30238992009 W511A Water 12/12/17 14:30 12/16/17 10:30

30238992010 W510A Water 12/12/17 15:40 12/16/17 10:30

30238992011 W600A Water 12/13/17 08:50 12/16/17 10:30

30238992012 W601A Water 12/13/17 10:00 12/16/17 10:30

30238992013 W603A Water 12/13/17 11:00 12/16/17 10:30

30238992014 W604A Water 12/13/17 12:30 12/16/17 10:30

30238992015 Duplicate Water 12/13/17 12:30 12/16/17 10:30

30238992016 W514A Water 12/13/17 13:30 12/16/17 10:30

30238992017 W506A Water 12/13/17 14:30 12/16/17 10:30

30238992018 W605A Water 12/13/17 15:40 12/16/17 10:30




Greensburg, PA 15601(724)850-5600

Page 3 of 18

#=SA#

SAMPLE ANALYTE COUNT



Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

30238992001 Field Blank EPA 903.1 1 PASI-PAKAC

EPA 904.0 1 PASI-PAJLW

Total Radium Calculation 1 PASI-PACMC

30238992002 W504A EPA 903.1 1 PASI-PAKAC



30238992003 W504B EPA 903.1 1 PASI-PAKAC



30238992004 W502A EPA 903.1 1 PASI-PAKAC



30238992005 W502B EPA 903.1 1 PASI-PAKAC



30238992006 W602A EPA 903.1 1 PASI-PAKAC



30238992007 W7A EPA 903.1 1 PASI-PAKAC



30238992008 W14A EPA 903.1 1 PASI-PAKAC



30238992009 W511A EPA 903.1 1 PASI-PAKAC



30238992010 W510A EPA 903.1 1 PASI-PAKAC



30238992011 W600A EPA 903.1 1 PASI-PAKAC



30238992012 W601A EPA 903.1 1 PASI-PAKAC



30238992013 W603A EPA 903.1 1 PASI-PAKAC




Greensburg, PA 15601(724)850-5600

Page 4 of 18

#=SA#







30238992014 W604A EPA 903.1 1 PASI-PAKAC



30238992015 Duplicate EPA 903.1 1 PASI-PAKAC



30238992016 W514A EPA 903.1 1 PASI-PAKAC



30238992017 W506A EPA 903.1 1 PASI-PAKAC



30238992018 W605A EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 5 of 18

#=NA#

PROJECT NARRATIVE



Method:

Client: Pace-MN Field Services Division

EPA 903.1

Date: January 08, 2018

Description: 903.1 Radium 226

General Information:18 samples were analyzed for EPA 903.1. All samples were received in acceptable condition with any exceptions noted below or on thechain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.

Hold Time:The samples were analyzed within the method required hold times with any exceptions noted below.

Method Blank:All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.

Laboratory Control Spike:All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Additional Comments:




Greensburg, PA 15601(724)850-5600

Page 6 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 18

#=NA#

PROJECT NARRATIVE



Method:


Total Radium Calculation


Description: Total Radium 228+226

General Information:18 samples were analyzed for Total Radium Calculation. All samples were received in acceptable condition with any exceptions notedbelow or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.






This data package has been reviewed for quality and completeness and is approved for release.




Greensburg, PA 15601(724)850-5600

Page 8 of 18

#=ARR#

ANALYTICAL RESULTS - RADIOCHEMISTRY



Sample: Field Blank Lab ID: 30238992001 Collected: 12/11/17 13:15 Received: 12/16/17 10:30 Matrix: Water

Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No. QualMethod

PWS: Site ID: Sample Type:

Radium-226 0.609 ± 0.379 (0.374)C:NA T:88%

pCi/L 01/08/18 11:31 13982-63-3EPA 903.1

Radium-228 -0.142 ± 0.298 (0.718)C:75% T:100%

pCi/L 01/05/18 11:33 15262-20-1EPA 904.0

Total Radium 0.609 ± 0.677 (1.09) pCi/L 01/08/18 14:09 7440-14-4Total RadiumCalculation

Sample: W504A Lab ID: 30238992002 Collected: 12/11/17 14:10 Received: 12/16/17 10:30 Matrix: Water



Radium-226 0.290 ± 0.330 (0.521)C:NA T:94%

pCi/L 01/08/18 11:31 13982-63-3EPA 903.1

Radium-228 0.123 ± 0.426 (0.964)C:71% T:77%

pCi/L 01/05/18 11:33 15262-20-1EPA 904.0


Sample: W504B Lab ID: 30238992003 Collected: 12/11/17 15:00 Received: 12/16/17 10:30 Matrix: Water



Radium-226 0.921 ± 0.473 (0.496)C:NA T:94%

pCi/L 01/08/18 11:31 13982-63-3EPA 903.1

Radium-228 0.375 ± 0.427 (0.898)C:76% T:75%

pCi/L 01/05/18 11:33 15262-20-1EPA 904.0





Radium-226 0.274 ± 0.312 (0.492)C:NA T:101%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 1.70 ± 0.608 (0.931)C:80% T:84%

pCi/L 01/05/18 11:33 15262-20-1EPA 904.0





Radium-226 0.442 ± 0.378 (0.513)C:NA T:92%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 0.519 ± 0.406 (0.801)C:75% T:86%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0




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Page 9 of 18

#=ARR#











Radium-226 0.476 ± 0.348 (0.389)C:NA T:87%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 0.790 ± 0.513 (0.977)C:71% T:73%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.107 ± 0.245 (0.394)C:NA T:83%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 0.135 ± 0.373 (0.836)C:77% T:78%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.638 ± 0.472 (0.638)C:NA T:83%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 0.506 ± 0.384 (0.755)C:76% T:86%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.143 ± 0.309 (0.571)C:NA T:91%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 0.701 ± 0.408 (0.740)C:76% T:79%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 18

#=ARR#







Radium-226 0.496 ± 0.390 (0.542)C:NA T:98%

pCi/L 01/08/18 11:50 13982-63-3EPA 903.1

Radium-228 1.55 ± 0.602 (0.947)C:70% T:84%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.245 ± 0.348 (0.589)C:NA T:94%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.140 ± 0.338 (0.752)C:78% T:82%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.639 ± 0.381 (0.362)C:NA T:92%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.399 ± 0.399 (0.826)C:76% T:84%

pCi/L 01/05/18 11:34 15262-20-1EPA 904.0





Radium-226 0.301 ± 0.342 (0.539)C:NA T:92%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.242 ± 0.357 (0.769)C:74% T:81%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0





Radium-226 0.494 ± 0.346 (0.417)C:NA T:97%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.571 ± 0.447 (0.879)C:72% T:72%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 18

#=ARR#








Sample: Duplicate Lab ID: 30238992015 Collected: 12/13/17 12:30 Received: 12/16/17 10:30 Matrix: Water



Radium-226 -0.134 ± 0.233 (0.587)C:NA T:94%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.0504 ± 0.537 (1.24)C:61% T:69%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0





Radium-226 0.180 ± 0.306 (0.540)C:NA T:96%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.310 ± 0.345 (0.721)C:71% T:88%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0





Radium-226 0.0507 ± 0.231 (0.373)C:NA T:88%

pCi/L 01/08/18 12:34 13982-63-3EPA 903.1

Radium-228 0.468 ± 0.376 (0.746)C:74% T:86%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0





Radium-226 0.214 ± 0.392 (0.700)C:NA T:83%

pCi/L 01/08/18 12:10 13982-63-3EPA 903.1

Radium-228 0.546 ± 0.451 (0.904)C:76% T:74%

pCi/L 01/05/18 11:35 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 18

#=QCR#

QUALITY CONTROL - RADIOCHEMISTRY



Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

283025EPA 904.0

EPA 904.0904.0 Radium 228

Associated Lab Samples: 30238992001, 30238992002, 30238992003, 30238992004, 30238992005, 30238992006, 30238992007,30238992008, 30238992009, 30238992010, 30238992011, 30238992012, 30238992013, 30238992014,30238992015, 30238992016, 30238992017, 30238992018

Parameter UnitsAct ± Unc (MDC) Carr Trac Qualifiers

METHOD BLANK: 1389291


Matrix: Water

Analyzed

Radium-228 pCi/L 01/05/18 11:330.0986 ± 0.329 (0.741) C:76% T:92%




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Page 13 of 18

#=QCR#







283024EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 01/08/18 11:310.295 ± 0.306 (0.456) C:NA T:91%




Greensburg, PA 15601(724)850-5600

Page 14 of 18

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Act - ActivityUnc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)(MDC) - Minimum Detectable ConcentrationTrac - Tracer Recovery (%)Carr - Carrier Recovery (%)Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - GreensburgPASI-PA


without the written consent of Pace Analytical Services, LLC.Date: 01/08/2018 03:02 PM


Greensburg, PA 15601(724)850-5600

Page 15 of 18

Minneapolis Testing Laboratory

1518 Chestnut Ave N


Certification #MN-027-053-197

WI-999071150

Christine Keefe, Supervisor (612) 630-4506

Amended ReportOriginal Report ID: MCL0153 Xcel General Report FINAL 01 05 2018

1055 01 05 2018 0110

Environmental Services-Water Minneapolis

RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager

Enclosed are the results of analyses for samples received by the laboratory on 12/14/2017 10:05. If you have

any questions concerning this report, please feel free to contact me.

I certify that this analysis report was prepared under my direction or supervision under a system designed to

assure that qualified personnel analyzed the submitted samples. All protocols for analysis were followed as

required by Minnesota Rules and the Applicable Management Plan.

Sincerely,

22 January 2018

cc: During the first baseline sampling event

additional samples will be collected and

field filtered to obtain dissolved metals

concetrations (in addition to total metals).

Re-issued with additional metals and

removed TSS. HSD 1/22/18

Project Name/Location: Black Dog CCR

Project Manager: Tedd Ronning

Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N


Certification # MN-027-053-197

WI-999071150



1055 01 05 2018 0110

ANALYTICAL REPORT FOR SAMPLES

Sample ID Laboratory IDSample Qualifier Matrix Sampled Received

MCL0153-01 Water 12/14/2017 10:0512/11/2017 13:15Field Blank

MCL0153-02 Water 12/14/2017 10:0512/11/2017 14:10W504A

MCL0153-03 Water 12/14/2017 10:0512/11/2017 15:00W504B

MCL0153-04 Water 12/14/2017 10:0512/12/2017 9:45W502A

MCL0153-05 Water 12/14/2017 10:0512/12/2017 10:25W502B

MCL0153-06 Water 12/14/2017 10:0512/12/2017 11:30W602A

MCL0153-07 Water 12/14/2017 10:0512/12/2017 12:40W7A

MCL0153-08 Water 12/14/2017 10:0512/12/2017 13:30W14A

MCL0153-09 Water 12/14/2017 10:0512/12/2017 14:30W511A

MCL0153-10 Water 12/14/2017 10:0512/12/2017 15:40W510A

MCL0153-11 Water 12/14/2017 10:0512/13/2017 8:50W600A

MCL0153-12 Water 12/14/2017 10:0512/13/2017 10:00W601A

MCL0153-13 Water 12/14/2017 10:0512/13/2017 11:00W603A

MCL0153-14 Water 12/14/2017 10:0512/13/2017 12:30W604A

MCL0153-15 Water 12/14/2017 10:0512/13/2017 12:30Duplicate

MCL0153-16 Water 12/14/2017 10:0512/13/2017 13:30W514A

MCL0153-17 Water 12/14/2017 10:0512/13/2017 14:30W506A

MCL0153-18 Water 12/14/2017 10:0512/13/2017 15:40W605A

Xcel Energy Minneapolis Testing Lab The results in this report apply to the samples analyzed in accordance with the

chain of custody document. This analytical report must be reproduced in its

entirety.

Page 1 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

ResultAnalyte Limit Batch

Reporting

Prepared Analyzed Method AnalystDilutionUnits

MCL0153-01 (Water) - Chain of Custody Number: 2125342/2125345

Field Blank

Qualifier

Analyte

Anions by Ion Chromatography

Chloride 1.00 mg/L 1 BCL0258 EPA 300.0< 1.00 CRL12/14/17 16:3212/14/17 10:46

Fluoride 0.750 mg/L 1 BCL0258 EPA 300.0< 0.750 CRL12/14/17 16:3212/14/17 10:46

Sulfate 1.00 mg/L 1 BCL0258 EPA 300.0< 1.00 CRL12/14/17 16:3212/14/17 10:46

Wet Chemistry

pH pH Units 1 BCL0257 SM 4500-H+ B6.86 CRLM_TTT 12/14/17 10:5212/14/17 10:35

Total Dissolved Solids 20.0 mg/L 1 BCL0264 SM 2540C< 20.0 HSD12/18/17 6:4212/18/17 6:42

Dissolved Metals by ICPMS

Arsenic 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Barium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Beryllium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Cadmium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Cobalt 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Chromium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Molybdenum 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Lead 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Antimony 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Selenium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Thallium 0.500 ug/L 1 BCL0361 EPA 200.8< 0.500 CRL12/20/17 8:2012/19/17 6:49

Total Metals by ICPMS


Barium 0.500 ug/L 1 BCL0324 EPA 200.8< 0.500 CRL12/19/17 8:5212/18/17 6:08












entirety.

Page 2 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



Field Blank

Qualifier

Analyte

Dissolved Metals by ICP

Boron 0.0500 mg/L 1 BCL0360 EPA 200.7< 0.0500 HRD12/27/17 12:4612/19/17 6:46

Calcium 0.500 mg/L 1 BCL0360 EPA 200.7< 0.500 HRD12/27/17 12:4412/19/17 6:46

Potassium 0.500 mg/L 1 BCL0360 EPA 200.7< 0.500 HRD12/27/17 12:4412/19/17 6:46

Lithium 0.0500 mg/L 1 BCL0360 EPA 200.7< 0.0500 HRD12/27/17 12:4412/19/17 6:46

Magnesium 0.500 mg/L 1 BCL0360 EPA 200.7< 0.500 HRD12/27/17 12:4412/19/17 6:46

Sodium 0.500 mg/L 1 BCL0360 EPA 200.7< 0.500 HRD12/27/17 12:4412/19/17 6:46

Total Metals by ICP

Boron 0.0500 mg/L 1 BCL0323 EPA 200.7< 0.0500 HRD12/21/17 12:4412/18/17 6:06

Calcium 0.500 mg/L 1 BCL0323 EPA 200.7< 0.500 HRD12/21/17 12:4212/18/17 6:06

Potassium 0.500 mg/L 1 BCL0323 EPA 200.7< 0.500 HRD12/21/17 12:4212/18/17 6:06


Magnesium 0.500 mg/L 1 BCL0323 EPA 200.7< 0.500 HRD12/21/17 12:4312/18/17 6:06

Sodium 0.500 mg/L 1 BCL0323 EPA 200.7< 0.500 HRD12/21/17 12:4212/18/17 6:06

Mercury

Mercury 0.200 ug/L 1 BDA0027 EPA 245.1, 7470A< 0.200 HRD1/3/18 14:581/3/18 9:26



entirety.

Page 3 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W504A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BCL0258 EPA 300.086.1 CRL12/14/17 16:5212/14/17 10:46


Sulfate 1.00 mg/L 1 BCL0258 EPA 300.0854 CRL12/14/17 16:5212/14/17 10:46

Wet Chemistry


Total Dissolved Solids 20.0 mg/L 1 BCL0264 SM 2540C1990 HSD12/18/17 6:4212/18/17 6:42


Arsenic 0.500 ug/L 1 BCL0361 EPA 200.81.48 CRL12/20/17 8:2412/19/17 6:49

Barium 0.500 ug/L 1 BCL0361 EPA 200.822.4 CRL12/20/17 8:2412/19/17 6:49



Cobalt 0.500 ug/L 1 BCL0361 EPA 200.80.963 CRL12/20/17 8:2412/19/17 6:49


Molybdenum 0.500 ug/L 1 BCL0361 EPA 200.866.0 CRL12/20/17 8:2412/19/17 6:49



















entirety.

Page 4 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W504A

Qualifier

Analyte


Boron 0.0500 mg/L 1 BCL0360 EPA 200.716.8 HRD12/27/17 12:5012/19/17 6:46

Calcium 0.500 mg/L 1 BCL0360 EPA 200.7337 HRD12/27/17 12:4912/19/17 6:46

Potassium 0.500 mg/L 1 BCL0360 EPA 200.73.16 HRD12/27/17 12:4912/19/17 6:46

Lithium 0.0500 mg/L 1 BCL0360 EPA 200.70.0502 HRD12/27/17 12:4912/19/17 6:46

Magnesium 0.500 mg/L 1 BCL0360 EPA 200.774.7 HRD12/27/17 12:4912/19/17 6:46

Sodium 0.500 mg/L 1 BCL0360 EPA 200.7187 HRD12/27/17 12:4912/19/17 6:46

Total Metals by ICP







Mercury




entirety.

Page 5 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BCL0258 EPA 300.019.2 CRL12/14/17 17:1312/14/17 10:46

Wet Chemistry





Barium 0.500 ug/L 1 BCL0361 EPA 200.8352 CRL12/20/17 8:3612/19/17 6:49
























entirety.

Page 6 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W504B

Qualifier

Analyte







Sodium 0.500 mg/L 1 BCL0360 EPA 200.727.1 HRD12/27/17 13:0512/19/17 6:46

Total Metals by ICP







Mercury




entirety.

Page 7 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W502A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 8 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W502A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 9 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W502B

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 10 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W502B

Qualifier

Analyte






Magnesium 0.500 mg/L 1 BCL0360 EPA 200.7123 HRD12/27/17 13:1612/19/17 6:46


Total Metals by ICP





Magnesium 0.500 mg/L 1 BCL0323 EPA 200.7125 HRD12/21/17 13:3412/18/17 6:06


Mercury




entirety.

Page 11 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W602A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BCL0258 EPA 300.0218 CRL12/14/17 19:5612/14/17 10:46



Wet Chemistry





























entirety.

Page 12 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W602A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 13 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W7A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 14 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W7A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 15 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W14A

Qualifier

Analyte





Wet Chemistry










Molybdenum 0.500 ug/L 1 BCL0361 EPA 200.8103 CRL12/20/17 8:5512/19/17 6:49



















entirety.

Page 16 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W14A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 17 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W511A

Qualifier

Analyte





Wet Chemistry









Chromium 0.500 ug/L 1 BCL0361 EPA 200.82.66 CRL12/20/17 8:5912/19/17 6:49



Antimony 0.500 ug/L 1 BCL0361 EPA 200.80.562 CRL12/20/17 8:5912/19/17 6:49

Selenium 0.500 ug/L 1 BCL0361 EPA 200.84.87 CRL12/20/17 8:5912/19/17 6:49
















entirety.

Page 18 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W511A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 19 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W510A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 20 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W510A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 21 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W600A

Qualifier

Analyte





Wet Chemistry






Beryllium 0.500 ug/L 1 BCL0361 EPA 200.80.602 CRL12/20/17 9:0712/19/17 6:49












Beryllium 0.500 ug/L 1 BCL0324 EPA 200.81.68 CRL12/19/17 9:3912/18/17 6:08

Cadmium 0.500 ug/L 1 BCL0324 EPA 200.81.97 CRL12/19/17 9:3912/18/17 6:08




Lead 0.500 ug/L 1 BCL0324 EPA 200.81.29 CRL12/19/17 9:3912/18/17 6:08



Thallium 0.500 ug/L 1 BCL0324 EPA 200.80.518 CRL12/19/17 9:3912/18/17 6:08



entirety.

Page 22 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W600A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 23 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W601A

Qualifier

Analyte





Wet Chemistry























Lead 0.500 ug/L 1 BCL0324 EPA 200.83.20 CRL12/19/17 9:4312/18/17 6:08






entirety.

Page 24 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W601A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 25 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W603A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 26 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W603A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 27 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W604A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 28 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W604A

Qualifier

Analyte



Calcium 0.500 mg/L 1 BCL0360 EPA 200.785.3 HRD12/27/17 14:1212/19/17 6:46





Total Metals by ICP







Mercury




entirety.

Page 29 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 30 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



Duplicate

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 31 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W514A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 32 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W514A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 33 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W506A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 34 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W506A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 35 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W605A

Qualifier

Analyte





Wet Chemistry





























entirety.

Page 36 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110


Reporting



W605A

Qualifier

Analyte








Total Metals by ICP







Mercury




entirety.

Page 37 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Anions by Ion Chromatography - Quality Control

Batch BCL0258 - Wet Prep

Blank (BCL0258-BLK1) Prepared & Analyzed: 12/14/2017

Chloride 1.00 mg/L<1.00

Fluoride 0.750 mg/L<0.750

Sulfate 1.00 mg/L<1.00





LCS (BCL0258-BS1) Prepared & Analyzed: 12/14/2017

Chloride 1.00 25.000 90-11099.6mg/L24.9

Fluoride 0.750 5.0000 90-110103mg/L5.14

Sulfate 1.00 100.00 90-110104mg/L104


Chloride 1.00 25.000 90-110101mg/L25.2

Fluoride 0.750 5.0000 90-110106mg/L5.31

Sulfate 1.00 100.00 90-110103mg/L103


Chloride 1.00 25.000 90-110101mg/L25.2

Fluoride 0.750 5.0000 90-110106mg/L5.28

Sulfate 1.00 100.00 90-110103mg/L103

LCS (BCL0258-BS4) Prepared: 12/14/2017 Analyzed: 12/15/2017

Chloride 1.00 25.000 90-11099.8mg/L24.9

Fluoride 0.750 5.0000 90-110106mg/L5.30

Sulfate 1.00 100.00 90-110103mg/L103



entirety.

Page 38 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Duplicate (BCL0258-DUP1) Prepared & Analyzed: 12/14/2017Source: MCL0082-01

Chloride 1.00 200.389mg/L23.6 23.7

Fluoride 0.750 202.48mg/L0.204 0.199

Sulfate 1.00 200.0718mg/L71.0 71.1


Chloride 1.00 201.23mg/L28.2 28.5

Fluoride 0.750 201.79mg/L0.222 0.226

Sulfate 1.00 200.134mg/L85.4 85.3

Matrix Spike (BCL0258-MS1) Prepared & Analyzed: 12/14/2017Source: MCL0082-01

Chloride 1.00 12.500 80-12098.2mg/L36.0 23.7

Fluoride 0.750 2.5000 80-120100mg/L2.71 0.199

Sulfate 1.00 50.000 80-12099.7mg/L121 71.1

Matrix Spike (BCL0258-MS2) Prepared & Analyzed: 12/14/2017Source: MCL0149-01

Chloride 1.00 12.500 80-12093.0mg/L40.1 28.5

Fluoride 0.750 2.5000 80-12097.6mg/L2.67 0.226

Sulfate 1.00 50.000 80-12096.5mg/L134 85.3

Matrix Spike Dup (BCL0258-MSD1) Prepared & Analyzed: 12/14/2017Source: MCL0082-01

Chloride 1.00 12.500 2080-12096.7 0.521mg/L35.8 23.7

Fluoride 0.750 2.5000 2080-12098.4 1.75mg/L2.66 0.199

Sulfate 1.00 50.000 2080-12098.5 0.523mg/L120 71.1

Matrix Spike Dup (BCL0258-MSD2) Prepared & Analyzed: 12/14/2017Source: MCL0149-01

Chloride 1.00 12.500 2080-12093.8 0.246mg/L40.2 28.5

Fluoride 0.750 2.5000 2080-12099.1 1.42mg/L2.70 0.226

Sulfate 1.00 50.000 2080-12097.3 0.322mg/L134 85.3



entirety.

Page 39 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BCL0266-BLK1) Prepared: 12/14/2017 Analyzed: 12/15/2017





Chloride 1.00 25.000 90-110102mg/L25.4

Fluoride 0.750 5.0000 90-110110mg/L5.52

Sulfate 1.00 100.00 90-110106mg/L106


Chloride 1.00 25.000 90-110101mg/L25.3

Fluoride 0.750 5.0000 90-110107mg/L5.35

Sulfate 1.00 100.00 90-110104mg/L104


Chloride 1.00 25.000 90-110100mg/L25.0

Fluoride 0.750 5.0000 90-110105mg/L5.26

Sulfate 1.00 100.00 90-110103mg/L103

Duplicate (BCL0266-DUP1) Prepared: 12/14/2017 Analyzed: 12/15/2017Source: MCL0153-15

Chloride 1.00 200.0966mg/L146 146

Fluoride 0.750 205.63mg/L0.347 0.328

Sulfate 1.00 200.427mg/L352 350

Matrix Spike (BCL0266-MS1) Prepared: 12/14/2017 Analyzed: 12/15/2017Source: MCL0153-15

Chloride 1.00 12.500 80-12090.1mg/L157 146

Fluoride 0.750 2.5000 80-120101mg/L2.85 0.328

Sulfate 1.00 50.000 80-12097.1mg/L399 350



entirety.

Page 40 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BCL0266-MSD1) Prepared: 12/14/2017 Analyzed: 12/15/2017Source: MCL0153-15

Chloride 1.00 12.500 2080-12088.0 0.170mg/L157 146

Fluoride 0.750 2.5000 2080-120103 2.01mg/L2.91 0.328

Sulfate 1.00 50.000 2080-12094.0 0.390mg/L397 350



entirety.

Page 41 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Wet Chemistry - Quality Control



pH 7.0000 90-110101pH Units7.04


pH 200.281pH Units7.12 7.14


pH 200.313pH Units6.37 6.39



Total Suspended Solids 4.00 mg/L<4.00


Total Suspended Solids 4.00 20mg/L<4.00 0.400



Total Dissolved Solids 20.0 mg/L<20.0


Total Dissolved Solids 20.0 200.401mg/L2000 1990






entirety.

Page 42 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Total Suspended Solids 5.00 209.01mg/L26.5 29.0








entirety.

Page 43 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Dissolved Metals by ICPMS - Quality Control

Batch BCL0361 - EPA 200.2, EPA 3005


Cadmium 0.500 ug/L<0.500

Lead 0.500 ug/L<0.500

Barium 0.500 ug/L<0.500

Molybdenum 0.500 ug/L<0.500

Beryllium 0.500 ug/L<0.500

Chromium 0.500 ug/L<0.500

Selenium 0.500 ug/L<0.500

Antimony 0.500 ug/L<0.500

Cobalt 0.500 ug/L<0.500

Thallium 0.500 ug/L<0.500

Arsenic 0.500 ug/L<0.500


Lead 0.500 100.00 85-11593.7ug/L93.7

Chromium 0.500 100.00 85-11597.1ug/L97.1

Barium 0.500 100.00 85-11594.7ug/L94.7

Selenium 0.500 100.00 85-11597.6ug/L97.6

Molybdenum 0.500 100.00 85-11594.4ug/L94.4

Cadmium 0.500 100.00 85-11596.0ug/L96.0

Arsenic 0.500 100.00 85-11594.1ug/L94.1

Beryllium 0.500 100.00 85-11594.4ug/L94.4

Antimony 0.500 100.00 85-11593.5ug/L93.5

Thallium 0.500 100.00 85-11594.9ug/L94.9

Cobalt 0.500 100.00 85-115101ug/L101


Molybdenum 0.500 200.808ug/L72.4 72.9

Chromium 0.500 20ug/L0.151 <0.500

Barium 0.500 201.36ug/L85.5 86.7

Arsenic 0.500 202.82ug/L35.1 34.1

Beryllium 0.500 20 M_D-RL134ug/L0.136 0.0270

Cadmium 0.500 20ug/L0.0509 <0.500

Lead 0.500 20 M_D-RL102ug/L0.0510 0.0166

Thallium 0.500 20 M_D-RL152ug/L0.0903 0.0123

Antimony 0.500 20 M_D-RL77.9ug/L0.147 0.0645

Cobalt 0.500 203.76ug/L3.17 3.30

Selenium 0.500 20ug/L<0.500 <0.500



entirety.

Page 44 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.500 2018.3ug/L0.0368 0.0442

Barium 0.500 204.11ug/L140 146

Arsenic 0.500 204.16ug/L5.02 5.23

Beryllium 0.500 20 M_D-RL33.0ug/L0.0204 0.0147

Molybdenum 0.500 206.54ug/L0.227 0.212

Chromium 0.500 20ug/L0.133 <0.500

Cobalt 0.500 206.45ug/L0.133 0.142


Lead 0.500 20ug/L<0.500 <0.500

Thallium 0.500 20 M_D-RL49.4ug/L0.0140 0.00843

Selenium 0.500 20ug/L<0.500 <0.500


Lead 0.500 100.00 70-13083.8ug/L83.8 0.0166

Beryllium 0.500 100.00 70-13087.2ug/L87.2 0.0270

Cadmium 0.500 100.00 70-13088.9ug/L88.9 <0.500

Molybdenum 0.500 100.00 70-13097.9ug/L171 72.9

Antimony 0.500 100.00 70-13096.1ug/L96.2 0.0645

Arsenic 5.00 100.00 70-130105ug/L140 34.1

Barium 0.500 100.00 70-13097.6ug/L184 86.7

Selenium 5.00 100.00 70-130107ug/L107 <5.00

Thallium 0.500 100.00 70-13088.0ug/L88.0 0.0123

Chromium 5.00 100.00 70-130105ug/L105 <5.00

Cobalt 5.00 100.00 70-130105ug/L108 3.30


Beryllium 0.500 100.00 70-13088.7ug/L88.8 0.0147

Thallium 0.500 100.00 70-13087.8ug/L87.8 0.00843

Barium 0.500 100.00 70-13099.3ug/L245 146

Lead 0.500 100.00 70-13083.8ug/L83.8 <0.500

Arsenic 0.500 100.00 70-130104ug/L109 5.23

Molybdenum 0.500 100.00 70-13099.2ug/L99.4 0.212

Antimony 0.500 100.00 70-13094.3ug/L94.4 0.0684

Cadmium 0.500 100.00 70-13087.6ug/L87.6 0.0442

Selenium 0.500 100.00 70-130104ug/L104 <0.500

Cobalt 0.500 100.00 70-130101ug/L101 0.142

Chromium 0.500 100.00 70-130103ug/L103 <0.500



entirety.

Page 45 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Selenium 5.00 100.00 2070-130105 1.21ug/L105 <5.00

Cadmium 0.500 100.00 2070-13087.1 2.04ug/L87.1 <0.500

Lead 0.500 100.00 2070-13082.4 1.65ug/L82.4 0.0166

Beryllium 0.500 100.00 2070-13083.0 4.99ug/L83.0 0.0270

Chromium 5.00 100.00 2070-130101 4.16ug/L101 <5.00

Antimony 0.500 100.00 2070-13095.2 1.03ug/L95.2 0.0645

Barium 0.500 100.00 2070-13098.6 0.554ug/L185 86.7

Cobalt 5.00 100.00 2070-130102 2.27ug/L105 3.30

Molybdenum 0.500 100.00 2070-13098.7 0.510ug/L172 72.9

Thallium 0.500 100.00 2070-13086.8 1.33ug/L86.8 0.0123

Arsenic 5.00 100.00 2070-130103 1.49ug/L138 34.1


Arsenic 0.500 100.00 2070-130104 0.193ug/L109 5.23

Selenium 0.500 100.00 2070-130105 0.284ug/L105 <0.500

Beryllium 0.500 100.00 2070-13084.1 5.41ug/L84.1 0.0147

Chromium 0.500 100.00 2070-130103 0.248ug/L103 <0.500

Lead 0.500 100.00 2070-13083.1 0.735ug/L83.1 <0.500

Antimony 0.500 100.00 2070-13093.1 1.29ug/L93.2 0.0684

Thallium 0.500 100.00 2070-13087.7 0.0550ug/L87.7 0.00843

Cobalt 0.500 100.00 2070-130100 0.508ug/L101 0.142

Molybdenum 0.500 100.00 2070-13099.6 0.394ug/L99.8 0.212

Barium 0.500 100.00 2070-13099.3 0.00412ug/L245 146

Cadmium 0.500 100.00 2070-13087.2 0.470ug/L87.2 0.0442



entirety.

Page 46 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Total Metals by ICPMS - Quality Control






Lead 0.500 ug/L<0.500



Barium 0.500 ug/L<0.500


Cobalt 0.500 ug/L<0.500




Lead 0.500 100.00 85-11596.5ug/L96.5

Cobalt 0.500 100.00 85-11597.1ug/L97.1

Beryllium 0.500 100.00 85-11595.0ug/L95.0

Antimony 0.500 100.00 85-11595.0ug/L95.0

Chromium 0.500 100.00 85-11597.4ug/L97.4

Cadmium 0.500 100.00 85-11596.8ug/L96.8

Molybdenum 0.500 100.00 85-11595.8ug/L95.8

Selenium 0.500 100.00 85-11595.0ug/L95.0

Thallium 0.500 100.00 85-11596.2ug/L96.2

Barium 0.500 100.00 85-11597.5ug/L97.5

Arsenic 0.500 100.00 85-11595.2ug/L95.2


Cadmium 0.500 20ug/L<0.500 <0.500

Barium 0.500 201.21ug/L88.6 89.7

Chromium 0.500 2015.5ug/L0.158 0.135

Antimony 0.500 20ug/L0.106 <0.500

Cobalt 0.500 201.72ug/L3.08 3.02

Lead 0.500 20ug/L0.0362 <0.500

Molybdenum 0.500 200.558ug/L72.4 72.0

Beryllium 0.500 20ug/L0.0899 <0.500

Arsenic 0.500 201.95ug/L35.7 35.0

Selenium 0.500 20ug/L<0.500 <0.500

Thallium 0.500 20ug/L0.0681 <0.500



entirety.

Page 47 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.500 20ug/L<0.500 <0.500

Lead 0.500 20ug/L<0.500 <0.500

Chromium 0.500 20 M_D-RL27.4ug/L0.119 0.156

Thallium 0.500 20ug/L<0.500 <0.500

Molybdenum 0.500 207.41ug/L0.241 0.260

Arsenic 0.500 202.75ug/L4.81 4.68

Selenium 0.500 20ug/L<0.500 <0.500

Cobalt 0.500 201.55ug/L0.0811 0.0798

Barium 0.500 200.184ug/L147 147

Beryllium 0.500 20ug/L<0.500 <0.500

Antimony 0.500 20ug/L0.0359 <0.500


Chromium 0.500 100.00 70-13097.9ug/L98.1 0.135

Cadmium 0.500 100.00 70-13087.5ug/L87.5 <0.500

Selenium 0.500 100.00 70-130102ug/L102 <0.500

Molybdenum 0.500 100.00 70-13098.8ug/L171 72.0

Arsenic 5.00 100.00 70-130101ug/L136 35.0

Barium 0.500 100.00 70-130102ug/L192 89.7

Cobalt 0.500 100.00 70-13098.1ug/L101 3.02

Beryllium 0.500 100.00 70-13086.2ug/L86.2 <0.500

Lead 0.500 100.00 70-13084.6ug/L84.6 <0.500

Thallium 0.500 100.00 70-13088.0ug/L88.0 <0.500

Antimony 0.500 100.00 70-13096.1ug/L96.1 <0.500


Thallium 0.500 100.00 70-13090.1ug/L90.1 <0.500

Beryllium 0.500 100.00 70-13091.9ug/L91.9 <0.500

Molybdenum 0.500 100.00 70-13097.9ug/L98.2 0.260

Cobalt 0.500 100.00 70-13099.5ug/L99.6 0.0798

Arsenic 0.500 100.00 70-130107ug/L111 4.68

Selenium 0.500 100.00 70-130103ug/L103 <0.500

Chromium 0.500 100.00 70-13099.8ug/L100 0.156

Barium 0.500 100.00 70-130105ug/L252 147

Cadmium 0.500 100.00 70-13089.6ug/L89.6 <0.500

Lead 0.500 100.00 70-13086.8ug/L86.8 <0.500

Antimony 0.500 100.00 70-13096.4ug/L96.4 <0.500



entirety.

Page 48 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Barium 0.500 100.00 2070-130103 0.600ug/L193 89.7

Thallium 0.500 100.00 2070-13088.4 0.404ug/L88.4 <0.500

Cadmium 0.500 100.00 2070-13088.2 0.729ug/L88.2 <0.500

Lead 0.500 100.00 2070-13085.5 1.12ug/L85.5 <0.500

Molybdenum 0.500 100.00 2070-130100 0.736ug/L172 72.0

Selenium 0.500 100.00 2070-130102 0.638ug/L102 <0.500

Arsenic 5.00 100.00 2070-130102 0.948ug/L137 35.0

Beryllium 0.500 100.00 2070-13086.9 0.808ug/L86.9 <0.500

Antimony 0.500 100.00 2070-13097.1 0.975ug/L97.1 <0.500

Cobalt 0.500 100.00 2070-13097.0 1.05ug/L100 3.02

Chromium 0.500 100.00 2070-13097.0 0.949ug/L97.1 0.135


Selenium 0.500 100.00 2070-130103 0.0763ug/L103 <0.500

Molybdenum 0.500 100.00 2070-13099.8 1.90ug/L100 0.260

Cobalt 0.500 100.00 2070-13099.6 0.0794ug/L99.7 0.0798

Antimony 0.500 100.00 2070-13098.0 1.60ug/L98.0 <0.500

Beryllium 0.500 100.00 2070-13090.6 1.43ug/L90.6 <0.500

Thallium 0.500 100.00 2070-13091.6 1.59ug/L91.6 <0.500

Cadmium 0.500 100.00 2070-13087.7 2.18ug/L87.7 <0.500

Lead 0.500 100.00 2070-13087.3 0.627ug/L87.3 <0.500

Barium 0.500 100.00 2070-130112 2.54ug/L259 147

Chromium 0.500 100.00 2070-13099.5 0.271ug/L99.7 0.156

Arsenic 0.500 100.00 2070-130108 1.20ug/L113 4.68



entirety.

Page 49 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Dissolved Metals by ICP - Quality Control



Potassium 0.500 mg/L<0.500

Lithium 0.0500 mg/L<0.0500

Magnesium 0.500 mg/L<0.500

Boron 0.0500 mg/L<0.0500

Sodium 0.500 mg/L<0.500

Calcium 0.500 mg/L<0.500


Potassium 0.500 100.00 85-115105mg/L105

Lithium 0.0500 1.0000 85-115105mg/L1.05

Magnesium 0.500 100.00 85-115100mg/L100

Sodium 0.500 100.00 85-115106mg/L106

Calcium 0.500 100.00 85-115106mg/L106

Boron 0.0500 1.0000 85-11599.0mg/L0.990


Calcium 0.500 201.14mg/L341 337

Boron 0.0500 203.44mg/L16.2 16.8

Potassium 0.500 2016.4mg/L3.73 3.16

Lithium 0.0500 204.41mg/L0.0480 0.0502

Sodium 0.500 200.836mg/L189 187

Magnesium 0.500 202.56mg/L72.8 74.7


Magnesium 0.500 204.50mg/L76.8 80.3

Calcium 0.500 204.47mg/L222 232

Sodium 0.500 203.83mg/L26.1 27.1

Boron 0.0500 203.21mg/L0.468 0.483

Lithium 0.0500 20mg/L<0.0500 0.0342

Potassium 0.500 20 M_D26.8mg/L1.73 1.33



entirety.

Page 50 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Dissolved Metals by ICP - Quality Control



Potassium 0.500 100.00 70-130108mg/L111 3.16

Magnesium 0.500 100.00 70-130102mg/L177 74.7

Boron 0.0500 1.0000 M_MS70-13065.9mg/L17.5 16.8

Sodium 0.500 100.00 70-130111mg/L298 187

Lithium 0.0500 1.0000 75-125108mg/L1.13 0.0502

Calcium 0.500 100.00 70-130113mg/L450 337


Potassium 0.500 100.00 70-130105mg/L106 1.33

Calcium 0.500 100.00 70-13098.0mg/L330 232

Magnesium 0.500 100.00 70-130103mg/L183 80.3

Lithium 0.0500 1.0000 75-125104mg/L1.07 0.0342

Sodium 0.500 100.00 70-130104mg/L131 27.1

Boron 0.0500 1.0000 70-130105mg/L1.53 0.483


Boron 0.0500 1.0000 2070-130108 2.39mg/L17.9 16.8

Magnesium 0.500 100.00 2070-130108 3.19mg/L182 74.7

Calcium 0.500 100.00 2070-130121 1.85mg/L459 337

Sodium 0.500 100.00 2070-130117 1.97mg/L304 187

Lithium 0.0500 1.0000 2075-125109 0.663mg/L1.14 0.0502

Potassium 0.500 100.00 2070-130110 2.00mg/L113 3.16


Sodium 0.500 100.00 2070-130108 2.48mg/L135 27.1

Boron 0.0500 1.0000 2070-130109 2.34mg/L1.57 0.483

Potassium 0.500 100.00 2070-130107 1.97mg/L108 1.33

Magnesium 0.500 100.00 2070-130107 2.11mg/L187 80.3

Calcium 0.500 100.00 2070-130107 2.65mg/L338 232

Lithium 0.0500 1.0000 2075-125107 2.45mg/L1.10 0.0342



entirety.

Page 51 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Total Metals by ICP - Quality Control





Sodium 0.500 mg/L<0.500

Boron 0.0500 mg/L<0.0500

Lithium 0.0500 mg/L<0.0500



Boron 0.0500 1.0000 85-115102mg/L1.02

Magnesium 0.500 100.00 85-115104mg/L104

Calcium 0.500 100.00 85-115109mg/L109

Lithium 0.0500 1.0000 85-115109mg/L1.09

Sodium 0.500 100.00 85-115109mg/L109

Potassium 0.500 100.00 85-115108mg/L108


Boron 0.0500 202.64mg/L17.1 17.5

Calcium 0.500 202.28mg/L347 339

Magnesium 0.500 200.915mg/L73.6 74.3

Sodium 0.500 202.29mg/L196 191

Potassium 0.500 203.51mg/L3.74 3.61

Lithium 0.0500 204.58mg/L0.0406 0.0388


Lithium 0.0500 20mg/L<0.0500 <0.0500

Boron 0.0500 204.72mg/L0.446 0.425

Magnesium 0.500 200.583mg/L81.2 81.7

Sodium 0.500 200.809mg/L26.0 26.2

Calcium 0.500 200.950mg/L230 233

Potassium 0.500 200.184mg/L1.37 1.37



entirety.

Page 52 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Sodium 0.500 100.00 70-130113mg/L304 191

Lithium 0.0500 1.0000 75-125107mg/L1.11 0.0388

Magnesium 0.500 100.00 70-130107mg/L181 74.3

Calcium 0.500 100.00 70-130116mg/L455 339

Potassium 0.500 100.00 70-130107mg/L110 3.61

Boron 0.0500 1.0000 70-130100mg/L18.5 17.5


Boron 0.0500 1.0000 70-130110mg/L1.52 0.425

Potassium 0.500 100.00 70-130110mg/L112 1.37

Magnesium 0.500 100.00 70-130105mg/L186 81.7

Calcium 0.500 100.00 70-130120mg/L352 233

Lithium 0.0500 1.0000 75-125114mg/L1.14 <0.0500

Sodium 0.500 100.00 70-130112mg/L138 26.2


Sodium 0.500 100.00 2070-130113 0.00766mg/L304 191

Calcium 0.500 100.00 2070-130116 0.0672mg/L456 339

Lithium 0.0500 1.0000 2075-125108 0.700mg/L1.12 0.0388

Magnesium 0.500 100.00 2070-130107 0.211mg/L181 74.3

Boron 0.0500 1.0000 20 M_MS70-130139 2.06mg/L18.9 17.5

Potassium 0.500 100.00 2070-130107 0.0960mg/L110 3.61


Sodium 0.500 100.00 2070-130111 0.999mg/L137 26.2

Potassium 0.500 100.00 2070-130109 0.956mg/L111 1.37

Lithium 0.0500 1.0000 2075-125113 1.20mg/L1.13 <0.0500

Magnesium 0.500 100.00 2070-130105 0.361mg/L187 81.7

Boron 0.0500 1.0000 2070-130109 0.825mg/L1.51 0.425

Calcium 0.500 100.00 2070-130117 0.769mg/L350 233



entirety.

Page 53 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte

Mercury - Quality Control

Batch BDA0027 - EPA 245.1, EPA 7470A

Blank (BDA0027-BLK1) Prepared & Analyzed: 01/03/2018

Mercury 0.200 ug/L<0.200

LCS (BDA0027-BS1) Prepared & Analyzed: 01/03/2018

Mercury 0.200 3.0000 85-11588.9ug/L2.67

Duplicate (BDA0027-DUP1) Prepared & Analyzed: 01/03/2018Source: MCL0153-06

Mercury 0.200 20ug/L<0.200 <0.200

Duplicate (BDA0027-DUP2) Prepared & Analyzed: 01/03/2018Source: MCL0153-07

Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDA0027-MS1) Prepared & Analyzed: 01/03/2018Source: MCL0153-06

Mercury 0.200 3.0000 70-13091.9ug/L2.76 <0.200

Matrix Spike (BDA0027-MS2) Prepared & Analyzed: 01/03/2018Source: MCL0153-07

Mercury 0.200 3.0000 70-13097.0ug/L2.91 <0.200

Matrix Spike Dup (BDA0027-MSD1) Prepared & Analyzed: 01/03/2018Source: MCL0153-06

Mercury 0.200 3.0000 2070-13089.9 2.20ug/L2.70 <0.200

Matrix Spike Dup (BDA0027-MSD2) Prepared & Analyzed: 01/03/2018Source: MCL0153-07

Mercury 0.200 3.0000 2070-13090.4 7.04ug/L2.71 <0.200



entirety.

Page 54 of 55



Reported:


250 Marquette Plaza

01/22/2018 12:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1055 01 05 2018 0110

Qualifiers and Definitions

M_TTT Sample received at the lab outside of required hold time.

M_MS The percent recovery and/or RPD were outside the acceptance limits for the MS/MSD due to possible matrix interference

and/or non-homogeneous sample matrix.

M_D-RL The RPD for the sample duplicate was outside of QC acceptance limits due to<RL.

M_D The RPD for the sample duplicate was outside of QC acceptance limits possibly due to non-homogeneous matrix.

Sample results reported on a dry weight basis

Relative Percent DifferenceRPD

dry

Not ReportedNR

Analyte NOT DETECTED at or above the reporting limitND

Analyte DETECTEDDET

Z Non Accredited Analyte



entirety.

Page 55 of 55

#=CL#

March 02, 2018

514B was incorrectly labeled as W514A in the field and has been revised in EQuIS to display W514B. KAC - 08/06/2018 DAVE ANDERSON LIMS OBJECT ID: 30243373


RE:


18-00227, Xcel Energy - Blackd

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 18

#=CP#

CERTIFICATIONS



Pennsylvania Certification IDs1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601L-A-B DOD-ELAP Accreditation #: L2417Alabama Certification #: 41590Arizona Certification #: AZ0734Arkansas CertificationCalifornia Certification #: 04222CAColorado CertificationConnecticut Certification #: PH-0694Delaware CertificationFlorida/TNI Certification #: E87683Georgia Certification #: C040Guam CertificationHawaii CertificationIdaho CertificationIllinois CertificationIndiana CertificationIowa Certification #: 391Kansas/TNI Certification #: E-10358Kentucky Certification #: 90133Louisiana DHH/TNI Certification #: LA140008Louisiana DEQ/TNI Certification #: 4086Maine Certification #: PA00091Maryland Certification #: 308Massachusetts Certification #: M-PA1457Michigan/PADEP CertificationMissouri Certification #: 235

Montana Certification #: Cert 0082Nebraska Certification #: NE-05-29-14Nevada Certification #: PA014572015-1New Hampshire/TNI Certification #: 2976New Jersey/TNI Certification #: PA 051New Mexico Certification #: PA01457New York/TNI Certification #: 10888North Carolina Certification #: 42706North Dakota Certification #: R-190Oregon/TNI Certification #: PA200002Pennsylvania/TNI Certification #: 65-00282Puerto Rico Certification #: PA01457Rhode Island Certification #: 65-00282South Dakota CertificationTennessee Certification #: TN2867Texas/TNI Certification #: T104704188-14-8Utah/TNI Certification #: PA014572015-5USDA Soil Permit #: P330-14-00213Vermont Dept. of Health: ID# VT-0282Virgin Island/PADEP CertificationVirginia/VELAP Certification #: 460198Washington Certification #: C868West Virginia DEP Certification #: 143West Virginia DHHR Certification #: 9964CWisconsin CertificationWyoming Certification #: 8TMS-L




Greensburg, PA 15601(724)850-5600

Page 2 of 18

#=SS#

SAMPLE SUMMARY





30243373002 W14A Water 02/05/18 13:50 02/13/18 10:30

30243373003 W7A Water 02/05/18 14:40 02/13/18 10:30

30243373004 W602A Water 02/05/18 15:40 02/13/18 10:30

30243373005 W504A Water 02/06/18 09:50 02/13/18 10:30

30243373006 W504B Water 02/06/18 10:30 02/13/18 10:30

30243373007 W502A Water 02/06/18 11:05 02/13/18 10:30

30243373008 W502B Water 02/06/18 11:45 02/13/18 10:30

30243373009 W511A Water 02/06/18 12:30 02/13/18 10:30

30243373010 W510A Water 02/06/18 13:30 02/13/18 10:30

30243373011 W604A Water 02/06/18 14:30 02/13/18 10:30

30243373012 W600A Water 02/07/18 09:35 02/13/18 10:30

30243373013 W601A Water 02/07/18 10:30 02/13/18 10:30

30243373014 W603A Water 02/07/18 11:30 02/13/18 10:30

30243373015 Duplicate Water 02/07/18 11:03 02/13/18 10:30

30243373016 W605A Water 02/07/18 12:30 02/13/18 10:30

30243373017 W506A Water 02/07/18 13:20 02/13/18 10:30

30243373018 W514A Water 02/07/18 14:10 02/13/18 10:30




Greensburg, PA 15601(724)850-5600

Page 3 of 18

#=SA#








30243373002 W14A EPA 903.1 1 PASI-PAKAC



30243373003 W7A EPA 903.1 1 PASI-PAKAC



30243373004 W602A EPA 903.1 1 PASI-PAKAC



30243373005 W504A EPA 903.1 1 PASI-PAKAC



30243373006 W504B EPA 903.1 1 PASI-PAKAC



30243373007 W502A EPA 903.1 1 PASI-PAKAC



30243373008 W502B EPA 903.1 1 PASI-PAKAC



30243373009 W511A EPA 903.1 1 PASI-PAKAC



30243373010 W510A EPA 903.1 1 PASI-PAKAC



30243373011 W604A EPA 903.1 1 PASI-PAKAC



30243373012 W600A EPA 903.1 1 PASI-PAKAC



30243373013 W601A EPA 903.1 1 PASI-PAKAC




Greensburg, PA 15601(724)850-5600

Page 4 of 18

#=SA#







30243373014 W603A EPA 903.1 1 PASI-PAKAC






30243373016 W605A EPA 903.1 1 PASI-PAKAC



30243373017 W506A EPA 903.1 1 PASI-PAKAC



30243373018 W514A EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 5 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: March 02, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 18

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 18

#=ARR#







Radium-226 0.237 ± 0.309 (0.509)C:NA T:92%

pCi/L 03/01/18 19:05 13982-63-3EPA 903.1

Radium-228 0.673 ± 0.415 (0.785)C:76% T:85%

pCi/L 02/27/18 13:03 15262-20-1EPA 904.0





Radium-226 0.300 ± 0.280 (0.369)C:NA T:90%

pCi/L 03/01/18 19:05 13982-63-3EPA 903.1

Radium-228 0.282 ± 0.366 (0.781)C:73% T:88%

pCi/L 02/27/18 13:03 15262-20-1EPA 904.0





Radium-226 0.171 ± 0.402 (0.745)C:NA T:80%

pCi/L 03/01/18 19:05 13982-63-3EPA 903.1

Radium-228 0.442 ± 0.398 (0.810)C:70% T:83%

pCi/L 02/27/18 13:04 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.312 (0.660)C:NA T:91%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 0.898 ± 0.429 (0.750)C:78% T:86%

pCi/L 02/27/18 13:04 15262-20-1EPA 904.0





Radium-226 0.500 ± 0.350 (0.422)C:NA T:94%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 0.891 ± 0.419 (0.718)C:79% T:85%

pCi/L 02/27/18 13:04 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 18

#=ARR#











Radium-226 0.601 ± 0.380 (0.430)C:NA T:95%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 1.78 ± 0.561 (0.724)C:72% T:85%

pCi/L 02/27/18 13:04 15262-20-1EPA 904.0





Radium-226 0.381 ± 0.357 (0.506)C:NA T:84%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 1.15 ± 0.440 (0.676)C:75% T:94%

pCi/L 02/27/18 13:04 15262-20-1EPA 904.0





Radium-226 0.329 ± 0.334 (0.506)C:NA T:93%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 1.47 ± 0.593 (0.990)C:77% T:86%

pCi/L 02/27/18 16:06 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.250 (0.508)C:NA T:85%

pCi/L 03/01/18 19:18 13982-63-3EPA 903.1

Radium-228 0.527 ± 0.430 (0.865)C:77% T:82%

pCi/L 02/27/18 16:06 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 18

#=ARR#







Radium-226 -0.047 ± 0.356 (0.743)C:NA T:96%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 0.365 ± 0.488 (1.05)C:73% T:88%

pCi/L 02/27/18 16:06 15262-20-1EPA 904.0





Radium-226 0.224 ± 0.312 (0.520)C:NA T:83%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 -0.0482 ± 0.394 (0.916)C:78% T:86%

pCi/L 02/27/18 16:06 15262-20-1EPA 904.0





Radium-226 0.288 ± 0.328 (0.517)C:NA T:93%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 0.756 ± 0.394 (0.693)C:77% T:83%

pCi/L 02/27/18 15:02 15262-20-1EPA 904.0





Radium-226 0.598 ± 0.420 (0.537)C:NA T:88%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 1.14 ± 0.428 (0.636)C:81% T:87%

pCi/L 02/27/18 15:01 15262-20-1EPA 904.0





Radium-226 0.441 ± 0.408 (0.594)C:NA T:90%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 0.330 ± 0.295 (0.592)C:81% T:81%

pCi/L 02/27/18 15:01 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 18

#=ARR#











Radium-226 0.252 ± 0.462 (0.825)C:NA T:77%

pCi/L 03/01/18 19:31 13982-63-3EPA 903.1

Radium-228 0.325 ± 0.294 (0.592)C:83% T:83%

pCi/L 02/27/18 15:02 15262-20-1EPA 904.0





Radium-226 0.398 ± 0.312 (0.366)C:NA T:88%

pCi/L 03/01/18 19:57 13982-63-3EPA 903.1

Radium-228 1.45 ± 0.596 (0.993)C:75% T:83%

pCi/L 02/27/18 11:45 15262-20-1EPA 904.0





Radium-226 0.221 ± 0.267 (0.407)C:NA T:82%

pCi/L 03/01/18 19:45 13982-63-3EPA 903.1

Radium-228 0.208 ± 0.371 (0.811)C:72% T:95%

pCi/L 02/27/18 11:46 15262-20-1EPA 904.0





Radium-226 0.475 ± 0.404 (0.568)C:NA T:96%

pCi/L 03/01/18 19:45 13982-63-3EPA 903.1

Radium-228 1.26 ± 0.480 (0.722)C:75% T:86%

pCi/L 02/27/18 11:47 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 18

#=QCR#







288061EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 03/01/18 19:05-0.046 ± 0.210 (0.496) C:NA T:96%




Greensburg, PA 15601(724)850-5600

Page 13 of 18

#=QCR#







288064EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 02/27/18 11:45-0.0908 ± 0.292 (0.704) C:79% T:83%




Greensburg, PA 15601(724)850-5600

Page 14 of 18

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 15 of 18


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

21 February 2018

cc:

W514B was incorrectly labeled as W514A in the field and has been revised in EQuIS to display W514B. KAC - 08/06/2018



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDB0094-01 Water 02/08/2018 10:3002/05/2018 13:00Field Blank

MDB0094-02 Water 02/08/2018 10:3002/05/2018 13:50W14A

MDB0094-03 Water 02/08/2018 10:3002/05/2018 14:40W7A

MDB0094-04 Water 02/08/2018 10:3002/05/2018 15:40W602A

MDB0094-05 Water 02/08/2018 10:3002/06/2018 9:50W504A

MDB0094-06 Water 02/08/2018 10:3002/06/2018 10:30W504B

MDB0094-07 Water 02/08/2018 10:3002/06/2018 11:05W502A

MDB0094-08 Water 02/08/2018 10:3002/06/2018 11:45W502B

MDB0094-09 Water 02/08/2018 10:3002/06/2018 12:30W511A

MDB0094-10 Water 02/08/2018 10:3002/06/2018 13:30W510A

MDB0094-11 Water 02/08/2018 10:3002/06/2018 14:30W604A

MDB0094-12 Water 02/08/2018 10:3002/07/2018 9:35W600A

MDB0094-13 Water 02/08/2018 10:3002/07/2018 10:30W601A

MDB0094-14 Water 02/08/2018 10:3002/07/2018 11:30W603A

MDB0094-15 Water 02/08/2018 10:3002/07/2018 11:30Duplicate

MDB0094-16 Water 02/08/2018 10:3002/07/2018 12:30W605A

MDB0094-17 Water 02/08/2018 10:3002/07/2018 13:20W506A

MDB0094-18 Water 02/08/2018 10:3002/07/2018 14:10W514A



entirety.

Page 1 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDB0094-01 (Water) - Chain of Custody Number: 2201206/2201209

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDB0217 EPA 300.0< 1.00 CRL2/12/18 21:182/12/18 10:13

Fluoride 0.750 mg/L 1 BDB0217 EPA 300.0< 0.750 CRL2/12/18 21:182/12/18 10:13

Sulfate 1.00 mg/L 1 BDB0217 EPA 300.0< 1.00 CRL2/12/18 21:182/12/18 10:13

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDB0163 SM 2320B< 10.0 CRL2/8/18 15:502/8/18 14:14

pH pH Units 1 BDB0163 SM 4500-H+ B6.43 CRLM_TTT 2/8/18 15:502/8/18 14:14

Total Dissolved Solids 20.0 mg/L 1 BDB0162 SM 2540C< 20.0 HSD2/9/18 8:112/9/18 8:11


Arsenic 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Barium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Beryllium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Cadmium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Cobalt 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Chromium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Molybdenum 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Lead 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Antimony 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Selenium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Thallium 0.500 ug/L 1 BDB0214 EPA 200.8< 0.500 CRL2/15/18 10:262/12/18 8:06

Total Metals by ICP

Boron 0.0500 mg/L 1 BDB0213 EPA 200.7< 0.0500 HRD2/14/18 12:172/12/18 8:04

Calcium 0.500 mg/L 1 BDB0213 EPA 200.7< 0.500 HRD2/14/18 12:162/12/18 8:04

Potassium 0.500 mg/L 1 BDB0213 EPA 200.7< 0.500 HRD2/14/18 12:162/12/18 8:04

Lithium 0.0500 mg/L 1 BDB0213 EPA 200.7< 0.0500 HRD2/14/18 12:162/12/18 8:04

Magnesium 1.25 mg/L 1 BDB0213 EPA 200.7< 1.25 HRD2/14/18 12:162/12/18 8:04

Sodium 0.500 mg/L 1 BDB0213 EPA 200.7< 0.500 HRD2/14/18 12:162/12/18 8:04



entirety.

Page 2 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDB0221 EPA 245.1, 7470A< 0.200 HRD2/13/18 14:382/12/18 12:39



entirety.

Page 3 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDB0217 EPA 300.0132 CRL2/12/18 21:382/12/18 10:13


Sulfate 1.00 mg/L 1 BDB0217 EPA 300.0108 CRL2/12/18 21:382/12/18 10:13

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDB0163 SM 2320B325 CRL2/8/18 15:572/8/18 14:14


Total Dissolved Solids 20.0 mg/L 1 BDB0162 SM 2540C698 HSD2/9/18 8:112/9/18 8:11


Arsenic 0.500 ug/L 1 BDB0214 EPA 200.82.15 CRL2/15/18 10:302/12/18 8:06

Barium 0.500 ug/L 1 BDB0214 EPA 200.830.2 CRL2/15/18 10:302/12/18 8:06



Cobalt 0.500 ug/L 1 BDB0214 EPA 200.80.603 CRL2/15/18 10:302/12/18 8:06

Chromium 0.500 ug/L 1 BDB0214 EPA 200.80.564 CRL2/15/18 10:302/12/18 8:06

Molybdenum 0.500 ug/L 1 BDB0214 EPA 200.8108 CRL2/15/18 10:302/12/18 8:06





Total Metals by ICP

Boron 0.0500 mg/L 1 BDB0213 EPA 200.71.34 HRD2/14/18 12:222/12/18 8:04

Calcium 0.500 mg/L 1 BDB0213 EPA 200.788.1 HRD2/14/18 12:212/12/18 8:04

Potassium 0.500 mg/L 1 BDB0213 EPA 200.72.54 HRD2/14/18 12:212/12/18 8:04


Magnesium 1.25 mg/L 1 BDB0213 EPA 200.721.4 HRD2/14/18 12:212/12/18 8:04

Sodium 0.500 mg/L 1 BDB0213 EPA 200.7135 HRD2/14/18 12:212/12/18 8:04



entirety.

Page 4 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry











Molybdenum 0.500 ug/L 1 BDB0214 EPA 200.852.8 CRL2/15/18 10:422/12/18 8:06





Total Metals by ICP


Calcium 0.500 mg/L 1 BDB0213 EPA 200.7154 HRD2/14/18 12:362/12/18 8:04







entirety.

Page 6 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 8 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 10 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDB0217 EPA 300.050.7 CRL2/12/18 23:002/12/18 10:13


Sulfate 1.00 mg/L 1 BDB0217 EPA 300.09.00 CRL2/12/18 23:002/12/18 10:13

Wet Chemistry






Barium 0.500 ug/L 1 BDB0214 EPA 200.8358 CRL2/15/18 10:542/12/18 8:06










Total Metals by ICP






Sodium 0.500 mg/L 1 BDB0213 EPA 200.722.5 HRD2/14/18 12:522/12/18 8:04



entirety.

Page 12 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 13 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP




Lithium 0.0500 mg/L 1 BDB0213 EPA 200.70.0915 HRD2/14/18 12:572/12/18 8:04





entirety.

Page 14 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDB0213 EPA 200.7129 HRD2/14/18 13:022/12/18 8:04




entirety.

Page 16 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 17 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte





Wet Chemistry














Selenium 0.500 ug/L 1 BDB0214 EPA 200.80.776 CRL2/15/18 11:092/12/18 8:06


Total Metals by ICP









entirety.

Page 18 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 20 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 21 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDB0163 SM 2320B72.1 CRL2/8/18 17:102/8/18 14:14












Antimony 0.500 ug/L 1 BDB0214 EPA 200.81.29 CRL2/15/18 11:172/12/18 8:06



Total Metals by ICP









entirety.

Page 22 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 23 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 24 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 25 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L 1 BDB0214 EPA 200.84.39 CRL2/16/18 8:052/12/18 8:06

Cadmium 0.500 ug/L 1 BDB0214 EPA 200.82.77 CRL2/16/18 8:052/12/18 8:06




Lead 0.500 ug/L 1 BDB0214 EPA 200.854.3 CRL2/16/18 8:052/12/18 8:06

Antimony 0.500 ug/L 1 BDB0214 EPA 200.83.62 CRL2/16/18 8:052/12/18 8:06


Thallium 0.500 ug/L 1 BDB0214 EPA 200.83.92 CRL2/16/18 8:052/12/18 8:06

Total Metals by ICP









entirety.

Page 26 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 29 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 30 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 31 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 32 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry





Arsenic 5.00 ug/L 10 BDB0214 EPA 200.8< 5.00 CRL2/16/18 8:212/12/18 8:06



Cadmium 0.500 ug/L 1 BDB0214 EPA 200.84.42 CRL2/16/18 8:322/12/18 8:06







Thallium 0.500 ug/L 1 BDB0214 EPA 200.80.972 CRL2/16/18 8:322/12/18 8:06

Total Metals by ICP









entirety.

Page 34 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 35 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDB0217 - Wet Prep

Blank (BDB0217-BLK1) Prepared & Analyzed: 02/12/2018








LCS (BDB0217-BS1) Prepared & Analyzed: 02/12/2018

Chloride 1.00 25.000 90-11098.8mg/L24.7

Fluoride 0.750 5.0000 90-110102mg/L5.09

Sulfate 1.00 100.00 90-110100mg/L100


Chloride 1.00 25.000 90-11099.2mg/L24.8

Fluoride 0.750 5.0000 90-11098.6mg/L4.93

Sulfate 1.00 100.00 90-11099.7mg/L99.7

LCS (BDB0217-BS3) Prepared: 02/12/2018 Analyzed: 02/13/2018

Chloride 1.00 25.000 90-11099.2mg/L24.8

Fluoride 0.750 5.0000 90-11099.0mg/L4.95

Sulfate 1.00 100.00 90-11099.3mg/L99.3

Duplicate (BDB0217-DUP1) Prepared & Analyzed: 02/12/2018Source: MDB0023-01

Chloride 1.00 202.81mg/L34.4 35.4

Fluoride 0.750 201.80mg/L0.110 0.112

Sulfate 1.00 200.686mg/L51.5 51.9



entirety.

Page 38 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.0279mg/L14.3 14.3

Fluoride 0.750 20mg/L<0.750 <0.750

Sulfate 1.00 200.107mg/L11.3 11.3

Matrix Spike (BDB0217-MS1) Prepared & Analyzed: 02/12/2018Source: MDB0023-01

Chloride 1.00 12.500 80-12084.3mg/L46.0 35.4

Fluoride 0.750 2.5000 80-12089.6mg/L2.35 0.112

Sulfate 1.00 50.000 80-12093.8mg/L98.8 51.9

Matrix Spike (BDB0217-MS2) Prepared & Analyzed: 02/12/2018Source: MDB0069-01

Chloride 1.00 12.500 80-12098.4mg/L26.6 14.3

Fluoride 0.750 2.5000 80-12096.4mg/L2.41 <0.750

Sulfate 1.00 50.000 80-12099.4mg/L60.9 11.3

Matrix Spike Dup (BDB0217-MSD1) Prepared & Analyzed: 02/12/2018Source: MDB0023-01

Chloride 1.00 12.500 2080-12095.1 2.90mg/L47.3 35.4

Fluoride 0.750 2.5000 2080-12090.5 0.889mg/L2.37 0.112

Sulfate 1.00 50.000 2080-12094.0 0.100mg/L98.9 51.9

Matrix Spike Dup (BDB0217-MSD2) Prepared & Analyzed: 02/12/2018Source: MDB0069-01

Chloride 1.00 12.500 2080-12098.6 0.124mg/L26.7 14.3

Fluoride 0.750 2.5000 2080-12098.5 2.13mg/L2.46 <0.750

Sulfate 1.00 50.000 2080-12099.9 0.418mg/L61.2 11.3


Blank (BDB0288-BLK1) Prepared: 02/15/2018 Analyzed: 02/16/2018






entirety.

Page 39 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte








Chloride 1.00 25.000 90-11099.7mg/L24.9

Fluoride 0.750 5.0000 90-110101mg/L5.07

Sulfate 1.00 100.00 90-110101mg/L101


Chloride 1.00 25.000 90-110100mg/L25.0

Fluoride 0.750 5.0000 90-11098.5mg/L4.92

Sulfate 1.00 100.00 90-110100mg/L100


Chloride 1.00 25.000 90-110100mg/L25.1

Fluoride 0.750 5.0000 90-11098.5mg/L4.92

Sulfate 1.00 100.00 90-110100mg/L100

Duplicate (BDB0288-DUP1) Prepared: 02/15/2018 Analyzed: 02/16/2018Source: MDB0094-10

Chloride 1.00 200.352mg/L90.3 90.6

Fluoride 0.750 204.36mg/L0.202 0.211

Sulfate 1.00 200.370mg/L0.810 0.813


Chloride 1.00 200.425mg/L9.62 9.66

Fluoride 0.750 200.823mg/L0.121 0.122

Sulfate 1.00 2011.0mg/L0.456 0.509



entirety.

Page 40 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike (BDB0288-MS1) Prepared: 02/15/2018 Analyzed: 02/16/2018Source: MDB0094-10

Chloride 1.00 12.500 80-12085.8mg/L101 90.6

Fluoride 0.750 2.5000 80-12086.2mg/L2.37 0.211

Sulfate 1.00 50.000 80-12094.2mg/L47.9 0.813


Chloride 1.00 12.500 80-12095.1mg/L21.5 9.66

Fluoride 0.750 2.5000 80-12091.0mg/L2.40 0.122

Sulfate 1.00 50.000 80-12096.2mg/L48.6 0.509

Matrix Spike Dup (BDB0288-MSD1) Prepared: 02/15/2018 Analyzed: 02/16/2018Source: MDB0094-10

Chloride 1.00 12.500 2080-12089.3 0.431mg/L102 90.6

Fluoride 0.750 2.5000 2080-12090.4 4.38mg/L2.47 0.211

Sulfate 1.00 50.000 2080-12098.2 4.10mg/L49.9 0.813


Chloride 1.00 12.500 2080-12097.9 1.64mg/L21.9 9.66

Fluoride 0.750 2.5000 2080-12095.4 4.48mg/L2.51 0.122

Sulfate 1.00 50.000 2080-12099.0 2.84mg/L50.0 0.509



entirety.

Page 41 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte









pH 7.0000 90-110101pH Units7.05

Alkalinity, Total 100.00 90-11099.4mg/L99.4


Alkalinity, Total 10.0 201.76mg/L331 325

pH 200.939pH Units7.49 7.42


pH 200.340pH Units8.85 8.82

Alkalinity, Total 10.0 202.28mg/L73.7 72.1








entirety.

Page 42 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDB0214 - EPA 200.2, EPA 3005


Lead 0.500 ug/L<0.500




Cobalt 0.500 ug/L<0.500






Barium 0.500 ug/L<0.500


Molybdenum 0.500 100.00 85-11597.4ug/L97.4

Beryllium 0.500 100.00 85-115101ug/L101

Cobalt 0.500 100.00 85-115101ug/L101

Arsenic 0.500 100.00 85-11598.5ug/L98.5

Lead 0.500 100.00 85-11598.6ug/L98.6

Thallium 0.500 100.00 85-115101ug/L101

Barium 0.500 100.00 85-11598.1ug/L98.1

Selenium 0.500 100.00 85-11598.1ug/L98.1

Cadmium 0.500 100.00 85-11598.9ug/L98.9

Antimony 0.500 100.00 85-11595.0ug/L95.0

Chromium 0.500 100.00 85-115103ug/L103



Lead 0.500 20 M_D-RL64.7ug/L0.0686 0.0350

Molybdenum 0.500 201.29ug/L68.2 69.1

Chromium 0.500 206.60ug/L0.250 0.234

Selenium 0.500 20ug/L<0.500 <0.500

Cobalt 0.500 200.268ug/L1.98 1.99

Cadmium 0.500 20 M_D-RL32.8ug/L0.0349 0.0485

Arsenic 0.500 201.86ug/L5.97 6.09

Barium 0.500 201.66ug/L88.4 89.9





entirety.

Page 43 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte





Beryllium 0.500 2010.3ug/L0.0389 0.0431

Cadmium 0.500 2010.5ug/L0.0832 0.0924

Cobalt 0.500 202.66ug/L1.43 1.47

Selenium 0.500 20ug/L<0.500 <0.500

Chromium 0.500 208.68ug/L0.498 0.543

Molybdenum 0.500 201.89ug/L47.7 46.8

Lead 0.500 20ug/L0.0164 <0.500

Arsenic 0.500 203.18ug/L2.14 2.20

Antimony 0.500 209.33ug/L0.122 0.111

Barium 0.500 200.344ug/L24.8 24.8


Arsenic 0.500 100.00 70-130103ug/L109 6.09

Barium 0.500 100.00 70-130101ug/L190 89.9

Beryllium 0.500 100.00 70-13095.2ug/L95.2 0.0250

Cobalt 0.500 100.00 70-130102ug/L104 1.99

Antimony 0.500 100.00 70-13094.6ug/L94.6 0.0499

Lead 0.500 100.00 70-13085.9ug/L85.9 0.0350

Thallium 0.500 100.00 70-13088.5ug/L88.5 0.0107

Chromium 0.500 100.00 70-130104ug/L104 0.234

Molybdenum 0.500 100.00 70-13097.6ug/L167 69.1

Selenium 0.500 100.00 70-13095.4ug/L95.4 <0.500

Cadmium 0.500 100.00 70-13091.4ug/L91.4 0.0485


Cadmium 0.500 100.00 70-13090.4ug/L90.5 0.0924

Molybdenum 0.500 100.00 70-130101ug/L148 46.8

Beryllium 0.500 100.00 70-13093.9ug/L93.9 0.0431

Barium 0.500 100.00 70-130104ug/L129 24.8

Cobalt 0.500 100.00 70-130105ug/L107 1.47

Thallium 0.500 100.00 70-13091.0ug/L91.0 0.0137

Lead 0.500 100.00 70-13086.6ug/L86.6 <0.500

Antimony 0.500 100.00 70-13096.8ug/L96.9 0.111

Selenium 0.500 100.00 70-130101ug/L101 <0.500

Arsenic 0.500 100.00 70-130107ug/L109 2.20

Chromium 0.500 100.00 70-130108ug/L109 0.543



entirety.

Page 44 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Arsenic 0.500 100.00 2070-130106 2.11ug/L112 6.09

Antimony 0.500 100.00 2070-13096.0 1.48ug/L96.0 0.0499

Cobalt 0.500 100.00 2070-130106 4.27ug/L108 1.99

Molybdenum 0.500 100.00 2070-13097.2 0.213ug/L166 69.1

Thallium 0.500 100.00 2070-13090.6 2.34ug/L90.6 0.0107

Barium 0.500 100.00 2070-13099.5 0.584ug/L189 89.9

Lead 0.500 100.00 2070-13088.0 2.41ug/L88.0 0.0350

Selenium 0.500 100.00 2070-13094.8 0.696ug/L94.8 <0.500

Beryllium 0.500 100.00 2070-13097.4 2.37ug/L97.5 0.0250

Chromium 0.500 100.00 2070-130107 3.08ug/L107 0.234

Cadmium 0.500 100.00 2070-13093.8 2.58ug/L93.8 0.0485


Selenium 0.500 100.00 2070-130101 0.400ug/L101 <0.500

Molybdenum 0.500 100.00 2070-130101 0.251ug/L147 46.8

Beryllium 0.500 100.00 2070-13093.7 0.157ug/L93.8 0.0431

Arsenic 0.500 100.00 2070-130107 0.338ug/L110 2.20

Antimony 0.500 100.00 2070-13097.4 0.573ug/L97.5 0.111

Barium 0.500 100.00 2070-130106 1.20ug/L130 24.8

Thallium 0.500 100.00 2070-13091.5 0.512ug/L91.5 0.0137

Cadmium 0.500 100.00 2070-13089.7 0.715ug/L89.8 0.0924

Chromium 0.500 100.00 2070-130107 1.45ug/L107 0.543

Lead 0.500 100.00 2070-13086.7 0.188ug/L86.7 <0.500

Cobalt 0.500 100.00 2070-130102 3.08ug/L104 1.47



entirety.

Page 45 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Lithium 0.0500 mg/L<0.0500

Sodium 0.500 mg/L<0.500




Boron 0.0500 mg/L<0.0500


Magnesium 1.25 100.00 85-115103mg/L103

Calcium 0.500 100.00 85-115102mg/L102

Lithium 0.0500 1.0000 85-115100mg/L1.00

Boron 0.0500 1.0000 85-115101mg/L1.01

Potassium 0.500 100.00 85-115102mg/L102

Sodium 0.500 100.00 85-115103mg/L103


Potassium 0.500 207.78mg/L2.74 2.54

Boron 0.0500 200.303mg/L1.35 1.34

Calcium 0.500 200.0688mg/L88.0 88.1

Sodium 0.500 200.243mg/L135 135

Magnesium 1.25 200.543mg/L21.5 21.4

Lithium 0.0500 20mg/L<0.0500 <0.0500


Boron 0.0500 200.122mg/L1.62 1.61

Calcium 0.500 202.53mg/L158 154

Sodium 0.500 202.52mg/L110 108

Potassium 0.500 208.80mg/L3.38 3.09

Magnesium 1.25 200.0232mg/L43.9 43.9

Lithium 0.0500 20mg/L<0.0500 <0.0500



entirety.

Page 46 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Boron 0.0500 1.0000 70-130102mg/L2.36 1.34

Lithium 0.0500 1.0000 75-12599.3mg/L0.993 <0.0500

Potassium 0.500 100.00 70-130101mg/L103 2.54

Calcium 0.500 100.00 70-13099.2mg/L187 88.1

Magnesium 1.25 100.00 70-130102mg/L123 21.4

Sodium 0.500 100.00 70-13099.4mg/L234 135


Calcium 0.500 100.00 70-130108mg/L261 154

Magnesium 1.25 100.00 70-130107mg/L151 43.9

Lithium 0.0500 1.0000 75-125102mg/L1.02 <0.0500

Boron 0.0500 1.0000 70-130108mg/L2.70 1.61

Sodium 0.500 100.00 70-130107mg/L214 108

Potassium 0.500 100.00 70-130103mg/L106 3.09


Boron 0.0500 1.0000 2070-130107 2.05mg/L2.41 1.34

Sodium 0.500 100.00 2070-13086.1 5.83mg/L221 135

Magnesium 1.25 100.00 2070-13093.7 6.98mg/L115 21.4

Lithium 0.0500 1.0000 2075-12593.8 5.62mg/L0.938 <0.0500

Potassium 0.500 100.00 2070-13094.7 5.89mg/L97.2 2.54

Calcium 0.500 100.00 2070-13088.4 5.89mg/L177 88.1


Magnesium 1.25 100.00 2070-130106 0.708mg/L149 43.9

Lithium 0.0500 1.0000 2075-125102 0.0671mg/L1.02 <0.0500

Calcium 0.500 100.00 2070-130107 0.422mg/L260 154

Potassium 0.500 100.00 2070-130103 0.0561mg/L106 3.09

Boron 0.0500 1.0000 2070-130104 1.58mg/L2.66 1.61

Sodium 0.500 100.00 2070-130106 0.320mg/L213 108



entirety.

Page 47 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDB0221 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11592.4ug/L2.77


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13092.1ug/L2.76 <0.200


Mercury 0.200 3.0000 70-13091.4ug/L2.74 <0.200


Mercury 0.200 3.0000 2070-13093.8 1.75ug/L2.81 <0.200


Mercury 0.200 3.0000 2070-13094.2 2.96ug/L2.82 <0.200






entirety.

Page 48 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Mercury 0.200 3.0000 85-11592.8ug/L2.78


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13096.6ug/L2.90 <0.200


Mercury 0.200 3.0000 2070-13093.7 3.09ug/L2.81 <0.200



entirety.

Page 49 of 50



Reported:


250 Marquette Plaza

02/21/2018 06:48Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150







dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 50 of 50

#=CL#

April 12, 2018

W514B was incorrectly labeled as W514A in the field and has been revised in EQuIS to display W514B. KAC - 08/06/2018E: FR - DAVE ANDERSON LIMS OBJECT ID: 30247121


RE:



Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on March 23, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 19

#=CP#

CERTIFICATIONS



Pennsylvania Certification IDs1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601ANAB DOD-ELAP Rad Accreditation #: L2417Alabama Certification #: 41590Arizona Certification #: AZ0734Arkansas CertificationCalifornia Certification #: 04222CAColorado Certification #: PA01547Connecticut Certification #: PH-0694Delaware CertificationEPA Region 4 DW RadFlorida/TNI Certification #: E87683Georgia Certification #: C040Guam CertificationHawaii CertificationIdaho CertificationIllinois CertificationIndiana CertificationIowa Certification #: 391Kansas/TNI Certification #: E-10358Kentucky Certification #: KY90133KY WW Permit #: KY0098221KY WW Permit #: KY0000221Louisiana DHH/TNI Certification #: LA180012Louisiana DEQ/TNI Certification #: 4086Maine Certification #: 2017020Maryland Certification #: 308Massachusetts Certification #: M-PA1457Michigan/PADEP Certification #: 9991

Missouri Certification #: 235Montana Certification #: Cert0082Nebraska Certification #: NE-OS-29-14Nevada Certification #: PA014572018-1New Hampshire/TNI Certification #: 297617New Jersey/TNI Certification #: PA051New Mexico Certification #: PA01457New York/TNI Certification #: 10888North Carolina Certification #: 42706North Dakota Certification #: R-190Ohio EPA Rad Approval: #41249Oregon/TNI Certification #: PA200002-010Pennsylvania/TNI Certification #: 65-00282Puerto Rico Certification #: PA01457Rhode Island Certification #: 65-00282South Dakota CertificationTennessee Certification #: 02867Texas/TNI Certification #: T104704188-17-3Utah/TNI Certification #: PA014572017-9USDA Soil Permit #: P330-17-00091Vermont Dept. of Health: ID# VT-0282Virgin Island/PADEP CertificationVirginia/VELAP Certification #: 9526Washington Certification #: C868West Virginia DEP Certification #: 143West Virginia DHHR Certification #: 9964CWisconsin Approve List for RadWyoming Certification #: 8TMS-L




Greensburg, PA 15601(724)850-5600

Page 2 of 19

#=SS#

SAMPLE SUMMARY





30247121002 W 511A Water 03/19/18 14:15 03/23/18 10:20

30247121003 W 510A Water 03/19/18 15:10 03/23/18 10:20

30247121004 W 604A Water 03/19/18 16:10 03/23/18 10:20

30247121005 W 603A Water 03/19/18 17:00 03/23/18 10:20

30247121006 W 504A Water 03/20/18 09:30 03/23/18 10:20

30247121007 W 504B Water 03/20/18 10:05 03/23/18 10:20

30247121008 W 502A Water 03/20/18 11:10 03/23/18 10:20

30247121009 Duplicate Water 03/20/18 11:10 03/23/18 10:20

30247121010 W 502B Water 03/20/18 11:40 03/23/18 10:20

30247121011 W 600A Water 03/20/18 12:50 03/23/18 10:20

30247121012 W 602A Water 03/20/18 13:40 03/23/18 10:20

30247121013 W 7A Water 03/20/18 14:25 03/23/18 10:20

30247121014 W 14A Water 03/20/18 15:30 03/23/18 10:20

30247121015 W 514A Water 03/21/18 09:10 03/23/18 10:20

30247121016 W 506A Water 03/21/18 09:50 03/23/18 10:20

30247121017 W 605A Water 03/21/18 10:50 03/23/18 10:20

30247121018 Pond A Water 03/21/18 11:05 03/23/18 10:20

30247121019 W 601A Water 03/21/18 12:25 03/23/18 10:20




Greensburg, PA 15601(724)850-5600

Page 3 of 19

#=SA#







Total Radium Calculation 1 PASI-PAJAL

30247121002 W 511A EPA 903.1 1 PASI-PAKAC



30247121003 W 510A EPA 903.1 1 PASI-PAKAC



30247121004 W 604A EPA 903.1 1 PASI-PAKAC



30247121005 W 603A EPA 903.1 1 PASI-PAKAC



30247121006 W 504A EPA 903.1 1 PASI-PAKAC



30247121007 W 504B EPA 903.1 1 PASI-PAKAC



30247121008 W 502A EPA 903.1 1 PASI-PAKAC






30247121010 W 502B EPA 903.1 1 PASI-PAKAC



30247121011 W 600A EPA 903.1 1 PASI-PAKAC



30247121012 W 602A EPA 903.1 1 PASI-PAKAC



30247121013 W 7A EPA 903.1 1 PASI-PAKAC




Greensburg, PA 15601(724)850-5600

Page 4 of 19

#=SA#







30247121014 W 14A EPA 903.1 1 PASI-PAKAC



30247121015 W 514A EPA 903.1 1 PASI-PAKAC



30247121016 W 506A EPA 903.1 1 PASI-PAKAC



30247121017 W 605A EPA 903.1 1 PASI-PAKAC



30247121018 Pond A EPA 903.1 1 PASI-PAKAC



30247121019 W 601A EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 5 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: April 12, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 19

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 19

#=ARR#







Radium-226 0.297 ± 0.421 (0.712)C:NA T:89%

pCi/L 04/05/18 18:50 13982-63-3EPA 903.1

Radium-228 0.128 ± 0.415 (0.927)C:77% T:90%

pCi/L 04/05/18 13:04 15262-20-1EPA 904.0


Sample: W 511A Lab ID: 30247121002 Collected: 03/19/18 14:15 Received: 03/23/18 10:20 Matrix: Water



Radium-226 0.435 ± 0.474 (0.746)C:NA T:84%

pCi/L 04/05/18 18:50 13982-63-3EPA 903.1

Radium-228 -0.103 ± 0.471 (1.11)C:67% T:76%

pCi/L 04/05/18 13:04 15262-20-1EPA 904.0





Radium-226 0.217 ± 0.453 (0.816)C:NA T:92%

pCi/L 04/05/18 18:50 13982-63-3EPA 903.1

Radium-228 -0.914 ± 0.522 (1.27)C:79% T:80%

pCi/L 04/05/18 13:04 15262-20-1EPA 904.0





Radium-226 0.336 ± 0.492 (0.840)C:NA T:87%

pCi/L 04/05/18 18:50 13982-63-3EPA 903.1

Radium-228 0.466 ± 0.413 (0.845)C:80% T:91%

pCi/L 04/05/18 13:04 15262-20-1EPA 904.0





Radium-226 0.348 ± 0.456 (0.759)C:NA T:88%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 0.377 ± 0.320 (0.644)C:79% T:93%

pCi/L 04/05/18 12:35 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 19

#=ARR#











Radium-226 0.618 ± 0.555 (0.843)C:NA T:90%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 1.08 ± 0.442 (0.693)C:75% T:89%

pCi/L 04/05/18 15:58 15262-20-1EPA 904.0


Sample: W 504B Lab ID: 30247121007 Collected: 03/20/18 10:05 Received: 03/23/18 10:20 Matrix: Water



Radium-226 0.335 ± 0.467 (0.788)C:NA T:88%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 1.21 ± 0.501 (0.790)C:73% T:81%

pCi/L 04/05/18 15:59 15262-20-1EPA 904.0





Radium-226 -0.059 ± 0.419 (0.890)C:NA T:83%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 0.588 ± 0.379 (0.713)C:76% T:83%

pCi/L 04/05/18 15:59 15262-20-1EPA 904.0





Radium-226 0.356 ± 0.521 (0.890)C:NA T:89%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 -0.0609 ± 0.525 (1.23)C:73% T:85%

pCi/L 04/05/18 19:18 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 19

#=ARR#







Radium-226 0.516 ± 0.622 (1.02)C:NA T:77%

pCi/L 04/05/18 19:06 13982-63-3EPA 903.1

Radium-228 0.854 ± 0.550 (1.04)C:76% T:85%

pCi/L 04/05/18 19:18 15262-20-1EPA 904.0





Radium-226 0.609 ± 0.525 (0.780)C:NA T:91%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.617 ± 0.567 (1.15)C:73% T:80%

pCi/L 04/05/18 19:18 15262-20-1EPA 904.0





Radium-226 -0.168 ± 0.395 (0.887)C:NA T:90%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.658 ± 0.514 (1.01)C:76% T:86%

pCi/L 04/05/18 19:19 15262-20-1EPA 904.0





Radium-226 0.329 ± 0.431 (0.719)C:NA T:93%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.307 ± 0.431 (0.925)C:75% T:87%

pCi/L 04/05/18 18:48 15262-20-1EPA 904.0





Radium-226 0.0670 ± 0.541 (1.06)C:NA T:80%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.272 ± 0.296 (0.616)C:76% T:86%

pCi/L 04/05/18 13:55 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 19

#=ARR#











Radium-226 0.248 ± 0.517 (0.931)C:NA T:90%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.265 ± 0.305 (0.640)C:77% T:87%

pCi/L 04/05/18 13:55 15262-20-1EPA 904.0





Radium-226 0.512 ± 0.438 (0.594)C:NA T:85%

pCi/L 04/05/18 19:20 13982-63-3EPA 903.1

Radium-228 0.0803 ± 0.285 (0.647)C:80% T:93%

pCi/L 04/05/18 15:41 15262-20-1EPA 904.0





Radium-226 0.290 ± 0.442 (0.761)C:NA T:94%

pCi/L 04/05/18 19:33 13982-63-3EPA 903.1

Radium-228 0.746 ± 0.364 (0.620)C:79% T:84%

pCi/L 04/05/18 13:56 15262-20-1EPA 904.0


Sample: Pond A Lab ID: 30247121018 Collected: 03/21/18 11:05 Received: 03/23/18 10:20 Matrix: Water



Radium-226 0.335 ± 0.350 (0.493)C:NA T:82%

pCi/L 04/05/18 19:33 13982-63-3EPA 903.1

Radium-228 0.351 ± 0.310 (0.622)C:79% T:80%

pCi/L 04/05/18 13:56 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 19

#=ARR#







Radium-226 -0.057 ± 0.431 (0.900)C:NA T:90%

pCi/L 04/05/18 19:33 13982-63-3EPA 903.1

Radium-228 0.307 ± 0.299 (0.610)C:78% T:83%

pCi/L 04/05/18 13:56 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 13 of 19

#=QCR#







292604EPA 903.1

EPA 903.1903.1 Radium-226

Associated Lab Samples: 30247121001, 30247121002, 30247121003, 30247121004, 30247121005, 30247121006, 30247121007,30247121008, 30247121009, 30247121010, 30247121011, 30247121012, 30247121013, 30247121014,30247121015, 30247121016, 30247121017, 30247121018, 30247121019




Matrix: Water

Analyzed

Radium-226 pCi/L 04/05/18 18:500.325 ± 0.302 (0.398) C:NA T:96%




Greensburg, PA 15601(724)850-5600

Page 14 of 19

#=QCR#







292679EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 04/05/18 12:350.0235 ± 0.293 (0.676) C:79% T:89%




Greensburg, PA 15601(724)850-5600

Page 15 of 19

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 16 of 19


1518 Chestnut Ave N



WI-999071150


Amended ReportOriginal Report ID: MDC0258 Xcel General Report FINAL 03 28 2018

1257 03 28 2018 0312


RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

06 April 2018

cc: Re-issued report with lower reporting limits

for samples: Duplicate for cobalt,

chromium and W506A for arsenic,

selenium. HSD 4/6/18.




Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312



MDC0258-01 Water 03/21/2018 13:4003/19/2018 13:40Field Blank

MDC0258-02 Water 03/21/2018 13:4003/19/2018 14:15W511A

MDC0258-03 Water 03/21/2018 13:4003/19/2018 15:10W510A

MDC0258-04 Water 03/21/2018 13:4003/19/2018 16:10W604A

MDC0258-05 Water 03/21/2018 13:4003/19/2018 17:00W603A

MDC0258-06 Water 03/21/2018 13:4003/20/2018 9:30W504A

MDC0258-07 Water 03/21/2018 13:4003/20/2018 10:05W504B

MDC0258-08 Water 03/21/2018 13:4003/20/2018 11:10W502A

MDC0258-09 Water 03/21/2018 13:4003/20/2018 11:10Duplicate

MDC0258-10 Water 03/21/2018 13:4003/20/2018 11:40W502B

MDC0258-11 Water 03/21/2018 13:4003/20/2018 12:50W600A

MDC0258-12 Water 03/21/2018 13:4003/20/2018 13:40W602A

MDC0258-13 Water 03/21/2018 13:4003/20/2018 14:25W7A

MDC0258-14 Water 03/21/2018 13:4003/20/2018 15:30W14A

MDC0258-15 Water 03/21/2018 13:4003/21/2018 9:10W514A

MDC0258-16 Water 03/21/2018 13:4003/21/2018 9:50W506A

MDC0258-17 Water 03/21/2018 13:4003/21/2018 10:50W605A

MDC0258-18 Water 03/21/2018 13:4003/21/2018 11:05Pond A

MDC0258-19 Water 03/21/2018 13:4003/21/2018 12:25W601A



entirety.

Page 1 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting


MDC0258-01 (Water) - Chain of Custody Number: 2201241/2201238

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDC0489 EPA 300.0< 1.00 CRL3/26/18 17:443/26/18 9:20

Fluoride 0.750 mg/L 1 BDC0489 EPA 300.0< 0.750 CRL3/26/18 17:443/26/18 9:20

Sulfate 1.00 mg/L 1 BDC0489 EPA 300.0< 1.00 CRL3/26/18 17:443/26/18 9:20

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDC0428 SM 2320B< 10.0 CRL3/22/18 9:473/22/18 7:27

pH pH Units 1 BDC0428 SM 4500-H+ B6.53 CRLM_TTT 3/22/18 9:473/22/18 7:27

Total Dissolved Solids 20.0 mg/L 1 BDC0425 SM 2540C< 20.0 HSD3/22/18 9:033/22/18 9:03


Arsenic 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Barium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Beryllium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Cadmium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Cobalt 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Chromium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Molybdenum 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Lead 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Antimony 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Selenium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Thallium 0.500 ug/L 1 BDC0430 EPA 200.8< 0.500 CRL3/26/18 9:043/22/18 8:00

Total Metals by ICP

Boron 0.0500 mg/L 1 BDC0429 EPA 200.7< 0.0500 HRD3/26/18 12:243/22/18 7:57

Calcium 0.500 mg/L 1 BDC0429 EPA 200.7< 0.500 HRD3/26/18 12:233/22/18 7:57

Potassium 0.500 mg/L 1 BDC0429 EPA 200.7< 0.500 HRD3/26/18 12:233/22/18 7:57

Lithium 0.0500 mg/L 1 BDC0429 EPA 200.7< 0.0500 HRD3/26/18 12:233/22/18 7:57

Magnesium 0.500 mg/L 1 BDC0429 EPA 200.7< 0.500 HRD3/26/18 12:233/22/18 7:57

Sodium 0.500 mg/L 1 BDC0429 EPA 200.7< 0.500 HRD3/26/18 12:233/22/18 7:57



entirety.

Page 2 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDC0468 EPA 245.1, 7470A< 0.200 HRD3/23/18 14:173/23/18 8:41



entirety.

Page 3 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W511A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDC0489 EPA 300.0132 CRL3/26/18 18:043/26/18 9:20


Sulfate 1.00 mg/L 1 BDC0489 EPA 300.0233 CRL3/26/18 18:043/26/18 9:20

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDC0428 SM 2320B175 CRL3/22/18 10:003/22/18 7:27


Total Dissolved Solids 20.0 mg/L 1 BDC0425 SM 2540C718 HSD3/22/18 9:033/22/18 9:03


Arsenic 0.500 ug/L 1 BDC0430 EPA 200.84.77 CRL3/26/18 9:083/22/18 8:00

Barium 0.500 ug/L 1 BDC0430 EPA 200.848.8 CRL3/26/18 9:083/22/18 8:00




Chromium 0.500 ug/L 1 BDC0430 EPA 200.816.0 CRL3/26/18 9:083/22/18 8:00

Molybdenum 0.500 ug/L 1 BDC0430 EPA 200.886.2 CRL3/26/18 9:083/22/18 8:00



Selenium 0.500 ug/L 1 BDC0430 EPA 200.81.02 CRL3/26/18 9:083/22/18 8:00


Total Metals by ICP

Boron 0.0500 mg/L 1 BDC0429 EPA 200.73.94 HRD3/26/18 12:293/22/18 7:57

Calcium 0.500 mg/L 1 BDC0429 EPA 200.7106 HRD3/26/18 12:273/22/18 7:57

Potassium 0.500 mg/L 1 BDC0429 EPA 200.75.79 HRD3/26/18 12:273/22/18 7:57


Magnesium 0.500 mg/L 1 BDC0429 EPA 200.719.4 HRD3/26/18 12:283/22/18 7:57

Sodium 0.500 mg/L 1 BDC0429 EPA 200.7108 HRD3/26/18 12:273/22/18 7:57



entirety.

Page 4 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W510A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDC0489 EPA 300.092.1 CRL3/26/18 18:243/26/18 9:20



Wet Chemistry






Barium 0.500 ug/L 1 BDC0430 EPA 200.8242 CRL3/26/18 9:203/22/18 8:00










Total Metals by ICP






Sodium 0.500 mg/L 1 BDC0429 EPA 200.763.7 HRD3/26/18 12:433/22/18 7:57



entirety.

Page 6 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W604A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDC0428 SM 2320B75.4 CRL3/22/18 10:153/22/18 7:27










Molybdenum 0.500 ug/L 1 BDC0430 EPA 200.8200 CRL3/26/18 9:243/22/18 8:00


Antimony 0.500 ug/L 1 BDC0430 EPA 200.80.941 CRL3/26/18 9:243/22/18 8:00



Total Metals by ICP


Calcium 0.500 mg/L 1 BDC0429 EPA 200.782.2 HRD3/26/18 12:483/22/18 7:57







entirety.

Page 8 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W603A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP




Lithium 0.0500 mg/L 1 BDC0429 EPA 200.70.0913 HRD3/26/18 12:543/22/18 7:57





entirety.

Page 10 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W504A

Qualifier

Analyte





Wet Chemistry









Cobalt 0.500 ug/L 1 BDC0430 EPA 200.81.71 CRL3/26/18 9:313/22/18 8:00







Total Metals by ICP









entirety.

Page 12 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDC0489 EPA 300.016.0 CRL3/26/18 19:463/26/18 9:20

Wet Chemistry
















Total Metals by ICP









entirety.

Page 14 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 15 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry














Total Metals by ICP









entirety.

Page 18 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 19 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting


MDC0258-09RE1 (Water) - Chain of Custody Number: 2201241/2201238

Duplicate

Qualifier

Analyte






entirety.

Page 20 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 0.500 mg/L 1 BDC0429 EPA 200.7114 HRD3/26/18 13:193/22/18 7:57




entirety.

Page 21 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 22 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W600A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 23 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 24 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 25 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 26 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 27 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 28 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W14A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 29 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 30 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W514A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 31 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 32 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W506A

Qualifier

Analyte





Wet Chemistry







Cadmium 0.500 ug/L 1 BDC0430 EPA 200.85.47 CRL3/26/18 10:303/22/18 8:00






Thallium 0.500 ug/L 1 BDC0430 EPA 200.80.729 CRL3/26/18 10:303/22/18 8:00

Total Metals by ICP









entirety.

Page 33 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 34 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting


MDC0258-16RE1 (Water) - Chain of Custody Number: 2201241/2201238

W506A

Qualifier

Analyte






entirety.

Page 35 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



Pond A

Qualifier

Analyte





Wet Chemistry












Lead 0.500 ug/L 1 BDC0430 EPA 200.80.529 CRL3/26/18 12:333/22/18 8:00




Total Metals by ICP









entirety.

Page 38 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



Pond A

Qualifier

Analyte

Mercury




entirety.

Page 39 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W601A

Qualifier

Analyte





Wet Chemistry












Lead 0.500 ug/L 1 BDC0430 EPA 200.80.895 CRL3/26/18 12:373/22/18 8:00

Antimony 0.500 ug/L 1 BDC0430 EPA 200.80.894 CRL3/26/18 12:373/22/18 8:00



Total Metals by ICP









entirety.

Page 40 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312


Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 41 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDC0489 - Wet Prep

Blank (BDC0489-BLK1) Prepared & Analyzed: 03/26/2018








LCS (BDC0489-BS1) Prepared & Analyzed: 03/26/2018

Chloride 1.00 25.000 90-110104mg/L26.0

Fluoride 0.750 5.0000 90-110106mg/L5.31

Sulfate 1.00 100.00 90-110105mg/L105


Chloride 1.00 25.000 90-11099.0mg/L24.8

Fluoride 0.750 5.0000 90-110101mg/L5.05

Sulfate 1.00 100.00 90-11099.7mg/L99.7


Chloride 1.00 25.000 90-11099.2mg/L24.8

Fluoride 0.750 5.0000 90-11097.7mg/L4.88

Sulfate 1.00 100.00 90-11099.8mg/L99.8

Duplicate (BDC0489-DUP1) Prepared & Analyzed: 03/26/2018Source: MDC0236-01

Chloride 1.00 203.10mg/L32.7 31.7

Fluoride 0.750 205.48mg/L0.142 0.150

Sulfate 1.00 200.594mg/L91.4 91.9



entirety.

Page 42 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.126mg/L34.9 34.9

Fluoride 0.750 208.92mg/L0.150 0.164

Sulfate 1.00 200.0117mg/L94.0 94.0

Matrix Spike (BDC0489-MS1) Prepared & Analyzed: 03/26/2018Source: MDC0236-01

Chloride 1.00 12.500 80-120105mg/L44.9 31.7

Fluoride 0.750 2.5000 80-12080.9mg/L2.17 0.150

Sulfate 1.00 50.000 80-12096.2mg/L140 91.9


Chloride 1.00 12.500 80-12092.9mg/L46.5 34.9

Fluoride 0.750 2.5000 80-12091.1mg/L2.44 0.164

Sulfate 1.00 50.000 80-12093.3mg/L141 94.0

Matrix Spike Dup (BDC0489-MSD1) Prepared & Analyzed: 03/26/2018Source: MDC0236-01

Chloride 1.00 12.500 2080-120106 0.160mg/L45.0 31.7

Fluoride 0.750 2.5000 2080-12097.1 17.1mg/L2.58 0.150

Sulfate 1.00 50.000 2080-12096.7 0.197mg/L140 91.9


Chloride 1.00 12.500 2080-12094.9 0.560mg/L46.7 34.9

Fluoride 0.750 2.5000 2080-12096.5 5.34mg/L2.58 0.164

Sulfate 1.00 50.000 2080-12095.2 0.675mg/L142 94.0








entirety.

Page 43 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte








Chloride 1.00 25.000 90-11093.9mg/L23.5

Fluoride 0.750 5.0000 90-11093.9mg/L4.70

Sulfate 1.00 100.00 90-11095.0mg/L95.0


Chloride 1.00 25.000 90-11095.5mg/L23.9

Fluoride 0.750 5.0000 90-11093.2mg/L4.66

Sulfate 1.00 100.00 90-11095.9mg/L95.9

LCS (BDC0521-BS3) Prepared: 03/27/2018 Analyzed: 03/28/2018

Chloride 1.00 25.000 90-11097.9mg/L24.5

Fluoride 0.750 5.0000 90-11093.7mg/L4.69

Sulfate 1.00 100.00 90-11098.3mg/L98.3


Chloride 1.00 200.944mg/L54.6 55.1

Fluoride 0.750 203.45mg/L0.114 0.118

Sulfate 1.00 200.977mg/L65.6 66.2


Chloride 1.00 200.0433mg/L18.5 18.5

Fluoride 0.750 200.897mg/L0.112 0.111

Sulfate 1.00 200.00544mg/L36.8 36.8



entirety.

Page 44 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 12.500 80-12087.8mg/L66.1 55.1

Fluoride 0.750 2.5000 80-12092.0mg/L2.42 0.118

Sulfate 1.00 50.000 80-12093.1mg/L113 66.2


Chloride 1.00 12.500 80-12096.5mg/L30.5 18.5

Fluoride 0.750 2.5000 80-12093.0mg/L2.44 0.111

Sulfate 1.00 50.000 80-12098.0mg/L85.7 36.8


Chloride 1.00 12.500 2080-12086.9 0.167mg/L66.0 55.1

Fluoride 0.750 2.5000 2080-12087.1 5.22mg/L2.30 0.118

Sulfate 1.00 50.000 2080-12091.5 0.726mg/L112 66.2


Chloride 1.00 12.500 2080-12097.9 0.575mg/L30.7 18.5

Fluoride 0.750 2.5000 2080-12095.7 2.67mg/L2.50 0.111

Sulfate 1.00 50.000 2080-12098.8 0.482mg/L86.2 36.8



entirety.

Page 45 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte









Alkalinity, Total 100.00 90-110102mg/L102

pH 7.0000 90-110101pH Units7.07


pH 201.46pH Units8.17 8.29




pH 200.265pH Units7.53 7.55








entirety.

Page 46 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDC0430 - EPA 200.2, EPA 3005

Blank (BDC0430-BLK1) Prepared: 03/22/2018 Analyzed: 03/26/2018






Lead 0.500 ug/L<0.500


Cobalt 0.500 ug/L<0.500


Barium 0.500 ug/L<0.500



Antimony 0.500 100.00 85-11594.1ug/L94.1

Thallium 0.500 100.00 85-11595.1ug/L95.1

Molybdenum 0.500 100.00 85-11594.4ug/L94.4

Cadmium 0.500 100.00 85-11597.3ug/L97.3

Barium 0.500 100.00 85-11594.9ug/L94.9

Lead 0.500 100.00 85-11594.6ug/L94.6

Beryllium 0.500 100.00 85-11595.0ug/L95.0

Duplicate (BDC0430-DUP1) Prepared: 03/22/2018 Analyzed: 03/26/2018Source: MDC0258-04

Cadmium 0.500 20 M_D-RL25.3ug/L0.0433 0.0558

Antimony 0.500 201.56ug/L0.956 0.941

Selenium 0.500 203.29ug/L12.4 12.8


Molybdenum 0.500 200.894ug/L199 200

Chromium 0.500 200.00531ug/L5.34 5.34

Lead 0.500 203.17ug/L0.160 0.155

Cobalt 0.500 203.04ug/L0.245 0.238

Arsenic 0.500 202.78ug/L4.01 3.90

Barium 0.500 200.857ug/L67.9 68.4




entirety.

Page 47 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Selenium 0.500 209.66ug/L0.623 0.686

Cadmium 0.500 20ug/L<0.500 0.0400


Molybdenum 0.500 200.425ug/L156 155

Thallium 0.500 20ug/L<0.500 <0.500

Antimony 0.500 207.48ug/L0.174 0.188

Beryllium 0.500 2012.7ug/L0.00630 0.00715

Lead 0.500 2012.3ug/L0.0374 0.0330

Arsenic 0.500 204.85ug/L6.88 7.23

Barium 0.500 202.73ug/L56.9 58.5

Cobalt 0.500 202.39ug/L0.262 0.268

Matrix Spike (BDC0430-MS1) Prepared: 03/22/2018 Analyzed: 03/26/2018Source: MDC0258-04

Beryllium 0.500 100.00 70-13090.7ug/L90.7 0.00957

Molybdenum 0.500 100.00 70-13098.3ug/L299 200

Antimony 0.500 100.00 70-130101ug/L102 0.941

Thallium 0.500 100.00 70-13089.6ug/L89.6 0.0415

Barium 0.500 100.00 70-130103ug/L171 68.4

Cadmium 0.500 100.00 70-13095.7ug/L95.7 0.0558

Lead 0.500 100.00 70-13088.2ug/L88.4 0.155


Antimony 0.500 100.00 70-130101ug/L101 0.188

Cadmium 0.500 100.00 70-13095.7ug/L95.7 0.0400

Beryllium 0.500 100.00 70-13089.6ug/L89.6 0.00715

Barium 0.500 100.00 70-130101ug/L160 58.5

Thallium 0.500 100.00 70-13091.0ug/L91.0 <0.500

Lead 0.500 100.00 70-13089.0ug/L89.0 0.0330

Molybdenum 0.500 100.00 70-130103ug/L259 155



entirety.

Page 48 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BDC0430-MSD1) Prepared: 03/22/2018 Analyzed: 03/26/2018Source: MDC0258-04

Molybdenum 0.500 100.00 2070-13097.7 0.198ug/L298 200

Antimony 0.500 100.00 2070-13099.5 1.22ug/L100 0.941

Barium 0.500 100.00 2070-130101 1.25ug/L169 68.4

Cobalt 0.500 100.00 2070-130102ug/L103 0.238

Thallium 0.500 100.00 2070-13090.2 0.651ug/L90.2 0.0415

Beryllium 0.500 100.00 2070-13093.4 2.88ug/L93.4 0.00957

Lead 0.500 100.00 2070-13088.4 0.161ug/L88.5 0.155

Cadmium 0.500 100.00 2070-13096.7 1.04ug/L96.7 0.0558

Arsenic 0.500 100.00 2070-130102ug/L106 3.90

Chromium 0.500 100.00 2070-130101ug/L107 5.34

Selenium 0.500 100.00 2070-13094.6ug/L107 12.8


Lead 0.500 100.00 2070-13089.2 0.247ug/L89.2 0.0330

Molybdenum 0.500 100.00 2070-130103 0.273ug/L258 155

Arsenic 0.500 100.00 2070-130101ug/L108 7.23

Selenium 0.500 100.00 2070-13093.4ug/L94.1 0.686

Cobalt 0.500 100.00 2070-13099.8ug/L100 0.268

Cadmium 0.500 100.00 2070-13095.5 0.215ug/L95.5 0.0400

Barium 0.500 100.00 2070-130101 0.0271ug/L160 58.5

Antimony 0.500 100.00 2070-130102 0.488ug/L102 0.188

Chromium 0.500 100.00 2070-13099.4ug/L99.5 0.185

Beryllium 0.500 100.00 2070-13090.0 0.450ug/L90.0 0.00715

Thallium 0.500 100.00 2070-13091.7 0.840ug/L91.7 <0.500



entirety.

Page 49 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BDC0429-BLK1) Prepared: 03/22/2018 Analyzed: 03/26/2018


Boron 0.0500 mg/L<0.0500

Sodium 0.500 mg/L<0.500


Lithium 0.0500 mg/L<0.0500



Boron 0.0500 1.0000 85-11598.1mg/L0.981

Calcium 0.500 100.00 85-115101mg/L101

Sodium 0.500 100.00 85-115102mg/L102

Potassium 0.500 100.00 85-11599.3mg/L99.3

Lithium 0.0500 1.0000 85-11597.1mg/L0.971

Magnesium 0.500 100.00 85-115100mg/L100


Sodium 0.500 203.48mg/L104 108

Potassium 0.500 203.10mg/L5.62 5.79

Lithium 0.0500 20mg/L<0.0500 <0.0500

Boron 0.0500 205.80mg/L3.72 3.94

Magnesium 0.500 201.82mg/L19.1 19.4

Calcium 0.500 203.12mg/L103 106


Boron 0.0500 200.872mg/L5.59 5.55

Calcium 0.500 200.501mg/L245 244

Potassium 0.500 203.08mg/L2.19 2.12

Lithium 0.0500 20mg/L<0.0500 <0.0500

Magnesium 0.500 200.541mg/L65.6 65.9

Sodium 0.500 200.440mg/L64.0 63.7



entirety.

Page 50 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Magnesium 0.500 100.00 70-130103mg/L122 19.4

Calcium 0.500 100.00 70-130106mg/L212 106

Lithium 0.0500 1.0000 75-12599.8mg/L0.998 <0.0500

Potassium 0.500 100.00 70-130101mg/L107 5.79

Sodium 0.500 100.00 70-130107mg/L215 108

Boron 0.0500 1.0000 70-13098.8mg/L4.92 3.94


Magnesium 0.500 100.00 70-130113mg/L179 65.9

Sodium 0.500 100.00 70-130113mg/L176 63.7

Potassium 0.500 100.00 70-130106mg/L108 2.12

Boron 0.0500 1.0000 70-130113mg/L6.68 5.55

Lithium 0.0500 1.0000 75-125104mg/L1.04 <0.0500

Calcium 0.500 100.00 70-130124mg/L369 244


Potassium 0.500 100.00 2070-130103 2.17mg/L109 5.79

Calcium 0.500 100.00 2070-130109 1.32mg/L215 106

Lithium 0.0500 1.0000 2075-125102 2.42mg/L1.02 <0.0500

Sodium 0.500 100.00 2070-130110 1.46mg/L218 108

Boron 0.0500 1.0000 2070-13092.4 1.30mg/L4.86 3.94

Magnesium 0.500 100.00 2070-130106 2.71mg/L125 19.4


Potassium 0.500 100.00 2070-130102 3.39mg/L104 2.12

Calcium 0.500 100.00 2070-130107 4.72mg/L352 244

Boron 0.0500 1.0000 20 M_MS70-130170 8.14mg/L7.25 5.55

Sodium 0.500 100.00 2070-130105 4.23mg/L169 63.7

Magnesium 0.500 100.00 2070-130105 4.36mg/L171 65.9

Lithium 0.0500 1.0000 2075-125101 2.54mg/L1.01 <0.0500



entirety.

Page 51 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDC0468 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11592.9ug/L2.79


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13070.9ug/L2.13 <0.200


Mercury 0.200 3.0000 M_MS70-13069.8ug/L2.09 <0.200


Mercury 0.200 3.0000 20 M_MS70-13069.9 1.34ug/L2.10 <0.200


Mercury 0.200 3.0000 20 M_MS70-13069.5 0.421ug/L2.08 <0.200



entirety.

Page 52 of 53



Reported:


250 Marquette Plaza

04/06/2018 10:02Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



1257 03 28 2018 0312








dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 53 of 53

#=CL#

June 04, 2018

W514B was incorrectly labeled as W514A in the field and has been revised in EQuIS to display W514B. KAC - 08/06/2018 DAVE ANDERSON LIMS OBJECT ID: 30252798


RE:


18-00584,Xcel Energy-BlackDogC

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on May 14, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 18

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 18

#=SS#

SAMPLE SUMMARY





30252798002 W 511 A Water 05/08/18 09:25 05/14/18 09:50

30252798003 W 510 A Water 05/08/18 10:10 05/14/18 09:50

30252798004 W 604 A Water 05/08/18 11:00 05/14/18 09:50

30252798005 W 603 A Water 05/08/18 11:45 05/14/18 09:50

30252798006 W 605 A Water 05/08/18 12:40 05/14/18 09:50

30252798007 W 506 A Water 05/08/18 13:30 05/14/18 09:50

30252798008 W 514 A Water 05/08/18 14:10 05/14/18 09:50

30252798009 W 601 A Water 05/08/18 15:00 05/14/18 09:50

30252798010 W 600 A Water 05/09/18 09:00 05/14/18 09:50

30252798011 W 504 A Water 05/09/18 09:45 05/14/18 09:50

30252798012 W 504 B Water 05/09/18 10:25 05/14/18 09:50

30252798013 W 502 A Water 05/09/18 11:05 05/14/18 09:50

30252798014 W 502 B Water 05/09/18 11:40 05/14/18 09:50

30252798015 Duplicate Water 05/09/18 11:40 05/14/18 09:50

30252798016 W 602 A Water 05/09/18 12:30 05/14/18 09:50

30252798017 W 7 A Water 05/09/18 13:10 05/14/18 09:50

30252798018 W 14 A Water 05/09/18 14:00 05/14/18 09:50




Greensburg, PA 15601(724)850-5600

Page 3 of 18

#=SA#







Total Radium Calculation 1 PASI-PARMK

30252798002 W 511 A EPA 903.1 1 PASI-PAKAC



30252798003 W 510 A EPA 903.1 1 PASI-PAKAC



30252798004 W 604 A EPA 903.1 1 PASI-PAKAC



30252798005 W 603 A EPA 903.1 1 PASI-PAKAC



30252798006 W 605 A EPA 903.1 1 PASI-PAKAC



30252798007 W 506 A EPA 903.1 1 PASI-PAKAC



30252798008 W 514 A EPA 903.1 1 PASI-PAKAC



30252798009 W 601 A EPA 903.1 1 PASI-PAKAC



30252798010 W 600 A EPA 903.1 1 PASI-PAKAC



30252798011 W 504 A EPA 903.1 1 PASI-PAKAC



30252798012 W 504 B EPA 903.1 1 PASI-PAKAC



30252798013 W 502 A EPA 903.1 1 PASI-PAKAC




Greensburg, PA 15601(724)850-5600

Page 4 of 18

#=SA#







30252798014 W 502 B EPA 903.1 1 PASI-PAKAC






30252798016 W 602 A EPA 903.1 1 PASI-PAKAC



30252798017 W 7 A EPA 903.1 1 PASI-PAKAC



30252798018 W 14 A EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 5 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: June 04, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0

Date: June 04, 2018











Greensburg, PA 15601(724)850-5600

Page 7 of 18

#=NA#

PROJECT NARRATIVE



Method:



Date: June 04, 2018












Greensburg, PA 15601(724)850-5600

Page 8 of 18

#=ARR#







Radium-226 0.169 ± 0.258 (0.415)C:NA T:92%

pCi/L 06/01/18 12:37 13982-63-3EPA 903.1

Radium-228 0.493 ± 0.404 (0.809)C:84% T:77%

pCi/L 05/31/18 16:10 15262-20-1EPA 904.0


Sample: W 511 A Lab ID: 30252798002 Collected: 05/08/18 09:25 Received: 05/14/18 09:50 Matrix: Water



Radium-226 0.651 ± 0.457 (0.584)C:NA T:94%

pCi/L 06/01/18 12:37 13982-63-3EPA 903.1

Radium-228 -0.225 ± 0.449 (1.06)C:85% T:79%

pCi/L 05/31/18 16:10 15262-20-1EPA 904.0





Radium-226 0.431 ± 0.438 (0.663)C:NA T:83%

pCi/L 06/01/18 12:37 13982-63-3EPA 903.1

Radium-228 0.339 ± 0.365 (0.762)C:88% T:84%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.285 (0.639)C:NA T:92%

pCi/L 06/01/18 12:43 13982-63-3EPA 903.1

Radium-228 0.353 ± 0.411 (0.865)C:85% T:73%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.262 (0.423)C:NA T:90%

pCi/L 06/01/18 12:37 13982-63-3EPA 903.1

Radium-228 0.417 ± 0.376 (0.766)C:86% T:85%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 18

#=ARR#











Radium-226 0.000 ± 0.258 (0.416)C:NA T:92%

pCi/L 06/01/18 12:37 13982-63-3EPA 903.1

Radium-228 0.261 ± 0.363 (0.778)C:80% T:84%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.303 (0.489)C:NA T:83%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 0.110 ± 0.290 (0.650)C:85% T:86%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.238 ± 0.287 (0.438)C:NA T:88%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 0.464 ± 0.424 (0.871)C:83% T:85%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.164 ± 0.250 (0.402)C:NA T:93%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 0.529 ± 0.377 (0.731)C:85% T:84%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 18

#=ARR#







Radium-226 0.351 ± 0.399 (0.629)C:NA T:87%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 1.03 ± 0.461 (0.773)C:83% T:85%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.245 ± 0.296 (0.451)C:NA T:88%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 0.107 ± 0.334 (0.752)C:80% T:82%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0


Sample: W 504 B Lab ID: 30252798012 Collected: 05/09/18 10:25 Received: 05/14/18 09:50 Matrix: Water



Radium-226 0.915 ± 0.472 (0.396)C:NA T:94%

pCi/L 06/01/18 12:54 13982-63-3EPA 903.1

Radium-228 0.777 ± 0.434 (0.788)C:82% T:79%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Radium-226 0.372 ± 0.387 (0.577)C:NA T:87%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.447 ± 0.359 (0.713)C:85% T:83%

pCi/L 05/31/18 16:12 15262-20-1EPA 904.0





Radium-226 0.612 ± 0.505 (0.730)C:NA T:95%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.913 ± 0.402 (0.648)C:79% T:90%

pCi/L 05/31/18 16:12 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 18

#=ARR#











Radium-226 0.541 ± 0.461 (0.647)C:NA T:89%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.934 ± 0.443 (0.751)C:84% T:79%

pCi/L 05/31/18 16:12 15262-20-1EPA 904.0





Radium-226 0.389 ± 0.395 (0.597)C:NA T:90%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.133 ± 0.311 (0.693)C:82% T:86%

pCi/L 05/31/18 16:12 15262-20-1EPA 904.0





Radium-226 0.181 ± 0.355 (0.648)C:NA T:91%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.567 ± 0.422 (0.828)C:83% T:76%

pCi/L 05/31/18 16:12 15262-20-1EPA 904.0





Radium-226 0.125 ± 0.285 (0.459)C:NA T:89%

pCi/L 06/01/18 13:07 13982-63-3EPA 903.1

Radium-228 0.0155 ± 0.360 (0.833)C:82% T:79%

pCi/L 05/31/18 16:11 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 18

#=QCR#







298551EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 05/31/18 16:100.409 ± 0.308 (0.595) C:84% T:89%




Greensburg, PA 15601(724)850-5600

Page 13 of 18

#=QCR#







298537EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 06/01/18 12:220.177 ± 0.269 (0.433) C:NA T:92%




Greensburg, PA 15601(724)850-5600

Page 14 of 18

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 15 of 18


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

04 June 2018

cc:




Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDE0098-01 Water 05/10/2018 10:0005/08/2018 8:50Field Blank

MDE0098-02 Water 05/10/2018 10:0005/08/2018 9:25W511A

MDE0098-03 Water 05/10/2018 10:0005/08/2018 10:10W510A

MDE0098-04 Water 05/10/2018 10:0005/08/2018 11:00W604A

MDE0098-05 Water 05/10/2018 10:0005/08/2018 11:45W603A

MDE0098-06 Water 05/10/2018 10:0005/08/2018 12:04W605A

MDE0098-07 Water 05/10/2018 10:0005/08/2018 13:30W506A

MDE0098-08 Water 05/10/2018 10:0005/08/2018 14:10W514A

MDE0098-09 Water 05/10/2018 10:0005/08/2018 15:00W601A

MDE0098-10 Water 05/10/2018 10:0005/09/2018 9:00W600A

MDE0098-11 Water 05/10/2018 10:0005/09/2018 9:45W504A

MDE0098-12 Water 05/10/2018 10:0005/09/2018 10:25W504B

MDE0098-13 Water 05/10/2018 10:0005/09/2018 11:05W502A

MDE0098-14 Water 05/10/2018 10:0005/09/2018 11:40W502B

MDE0098-15 Water 05/10/2018 10:0005/09/2018 11:40Duplicate

MDE0098-16 Water 05/10/2018 10:0005/09/2018 12:30W602A

MDE0098-17 Water 05/10/2018 10:0005/09/2018 13:10W7A

MDE0098-18 Water 05/10/2018 10:0005/09/2018 14:00W14A



entirety.

Page 1 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDE0098-01 (Water) - Chain of Custody Number: 2201253/2201254

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDE0259 EPA 300.0< 1.00 CRL5/14/18 9:235/14/18 5:46

Fluoride 0.750 mg/L 1 BDE0259 EPA 300.0< 0.750 CRL5/14/18 9:235/14/18 5:46

Sulfate 1.00 mg/L 1 BDE0259 EPA 300.0< 1.00 CRL5/14/18 9:235/14/18 5:46

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDE0218 SM 2320B< 10.0 CRL5/10/18 11:295/10/18 10:40

pH pH Units 1 BDE0218 SM 4500-H+ B6.59 CRLM_TTT 5/10/18 11:295/10/18 10:40

Total Dissolved Solids 20.0 mg/L 1 BDE0220 SM 2540C< 20.0 HSD5/11/18 8:445/11/18 8:44


Arsenic 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Barium 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Beryllium 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Cadmium 0.100 ug/L 1 BDE0264 EPA 200.8< 0.100 CRL5/15/18 9:135/14/18 7:45

Cobalt 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Chromium 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Molybdenum 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Lead 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Antimony 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Selenium 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Thallium 0.500 ug/L 1 BDE0264 EPA 200.8< 0.500 CRL5/15/18 9:135/14/18 7:45

Total Metals by ICP

Boron 0.0500 mg/L 1 BDE0263 EPA 200.7< 0.0500 HRD5/17/18 11:465/14/18 7:44

Calcium 0.500 mg/L 1 BDE0263 EPA 200.7< 0.500 HRD5/17/18 11:445/14/18 7:44

Potassium 0.500 mg/L 1 BDE0263 EPA 200.7< 0.500 HRD5/17/18 11:445/14/18 7:44

Lithium 0.0500 mg/L 1 BDE0263 EPA 200.7< 0.0500 HRD5/17/18 11:445/14/18 7:44

Magnesium 0.500 mg/L 1 BDE0263 EPA 200.7< 0.500 HRD5/17/18 11:455/14/18 7:44

Sodium 0.500 mg/L 1 BDE0263 EPA 200.7< 0.500 HRD5/17/18 11:445/14/18 7:44



entirety.

Page 2 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDE0318 EPA 245.1, 7470A< 0.200 HRD5/15/18 13:505/15/18 8:37



entirety.

Page 3 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDE0259 EPA 300.033.2 CRL5/14/18 9:445/14/18 5:46


Sulfate 10.0 mg/L 10 BDE0259 EPA 300.01240 CRL5/14/18 12:585/14/18 5:46

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDE0218 SM 2320B59.8 CRL5/10/18 11:405/10/18 10:40


Total Dissolved Solids 20.0 mg/L 1 BDE0220 SM 2540C1970 HSD5/11/18 8:445/11/18 8:44


Arsenic 0.500 ug/L 1 BDE0264 EPA 200.84.47 CRL5/15/18 9:295/14/18 7:45

Barium 0.500 ug/L 1 BDE0264 EPA 200.876.9 CRL5/15/18 9:295/14/18 7:45


Cadmium 0.100 ug/L 1 BDE0264 EPA 200.80.142 CRL5/15/18 9:295/14/18 7:45


Chromium 0.500 ug/L 1 BDE0264 EPA 200.874.0 CRL5/15/18 9:295/14/18 7:45

Molybdenum 0.500 ug/L 1 BDE0264 EPA 200.8433 CRL5/15/18 9:295/14/18 7:45


Antimony 0.500 ug/L 1 BDE0264 EPA 200.80.969 CRL5/15/18 9:295/14/18 7:45

Selenium 0.500 ug/L 1 BDE0264 EPA 200.879.8 CRL5/15/18 9:295/14/18 7:45


Total Metals by ICP

Boron 0.0500 mg/L 1 BDE0263 EPA 200.711.5 HRD5/17/18 11:515/14/18 7:44

Calcium 0.500 mg/L 1 BDE0263 EPA 200.7468 HRD5/17/18 11:505/14/18 7:44

Potassium 0.500 mg/L 1 BDE0263 EPA 200.716.9 HRD5/17/18 11:505/14/18 7:44

Lithium 0.0500 mg/L 1 BDE0263 EPA 200.70.136 HRD5/17/18 11:505/14/18 7:44

Magnesium 0.500 mg/L 1 BDE0263 EPA 200.78.21 HRD5/17/18 11:505/14/18 7:44

Sodium 0.500 mg/L 1 BDE0263 EPA 200.784.1 HRD5/17/18 11:505/14/18 7:44



entirety.

Page 4 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDE0259 EPA 300.039.6 CRL5/14/18 10:045/14/18 5:46

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDE0218 SM 2320B940 CRL5/10/18 11:515/10/18 10:40





Barium 0.500 ug/L 1 BDE0264 EPA 200.8231 CRL5/15/18 9:325/14/18 7:45





Molybdenum 0.500 ug/L 1 BDE0264 EPA 200.80.574 CRL5/15/18 9:325/14/18 7:45





Total Metals by ICP









entirety.

Page 6 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP


Calcium 0.500 mg/L 1 BDE0263 EPA 200.781.3 HRD5/17/18 12:105/14/18 7:44




Sodium 0.500 mg/L 1 BDE0263 EPA 200.7123 HRD5/17/18 12:105/14/18 7:44



entirety.

Page 8 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDE0259 EPA 300.0126 CRL5/14/18 10:455/14/18 5:46



Wet Chemistry
















Total Metals by ICP









entirety.

Page 10 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 12 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry









Cobalt 0.500 ug/L 1 BDE0264 EPA 200.814.6 CRL5/15/18 9:525/14/18 7:45






Thallium 0.500 ug/L 1 BDE0264 EPA 200.80.649 CRL5/15/18 9:525/14/18 7:45

Total Metals by ICP









entirety.

Page 14 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDE0259 EPA 300.0< 1.00 CRL5/14/18 12:065/14/18 5:46

Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 18 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L 1 BDE0264 EPA 200.811.4 CRL5/15/18 10:195/14/18 7:45





Lead 0.500 ug/L 1 BDE0264 EPA 200.818.9 CRL5/15/18 10:195/14/18 7:45



Thallium 0.500 ug/L 1 BDE0264 EPA 200.80.612 CRL5/15/18 10:195/14/18 7:45

Total Metals by ICP









entirety.

Page 20 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 21 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 22 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 23 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 24 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 25 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 26 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 0.500 mg/L 1 BDE0263 EPA 200.7115 HRD5/17/18 13:115/14/18 7:44




entirety.

Page 28 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 29 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 0.500 mg/L 1 BDE0263 EPA 200.7117 HRD5/17/18 13:175/14/18 7:44




entirety.

Page 30 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 31 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 32 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 34 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 35 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDE0259 - Wet Prep

Blank (BDE0259-BLK1) Prepared & Analyzed: 05/14/2018








LCS (BDE0259-BS1) Prepared & Analyzed: 05/14/2018

Chloride 1.00 25.076 90-11097.3mg/L24.4

Fluoride 0.750 2.5076 90-110101mg/L2.54

Sulfate 1.00 48.144 90-11099.4mg/L47.9


Chloride 1.00 25.076 90-11098.0mg/L24.6

Fluoride 0.750 2.5076 90-11094.3mg/L2.36

Sulfate 1.00 48.144 90-11098.5mg/L47.4


Chloride 1.00 25.076 90-11098.7mg/L24.8

Fluoride 0.750 2.5076 90-11094.3mg/L2.36

Sulfate 1.00 48.144 90-11099.0mg/L47.6

Duplicate (BDE0259-DUP1) Prepared & Analyzed: 05/14/2018Source: MDE0098-08

Chloride 1.00 200.257mg/L8.95 8.93

Fluoride 0.750 202.23mg/L0.136 0.133

Sulfate 1.00 20mg/L<1.00 0.474



entirety.

Page 38 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.299mg/L56.7 56.9

Fluoride 0.750 202.24mg/L0.221 0.226

Sulfate 1.00 200.668mg/L17.3 17.4

Matrix Spike (BDE0259-MS1) Prepared & Analyzed: 05/14/2018Source: MDE0098-08

Chloride 1.25 31.345 80-12096.0mg/L39.0 8.93

Fluoride 0.938 3.1345 80-12091.3mg/L2.86 <0.938

Sulfate 1.25 60.180 80-12096.8mg/L58.2 <1.25


Chloride 1.25 31.345 80-12092.9mg/L86.0 56.9

Fluoride 0.938 3.1345 80-12086.1mg/L2.93 0.226

Sulfate 1.25 60.180 80-12093.8mg/L73.8 17.4

Matrix Spike Dup (BDE0259-MSD1) Prepared & Analyzed: 05/14/2018Source: MDE0098-08

Chloride 1.25 31.345 2080-12096.5 0.435mg/L39.2 8.93

Fluoride 0.938 3.1345 2080-12095.2 4.15mg/L2.98 <0.938

Sulfate 1.25 60.180 2080-12097.5 0.746mg/L58.7 <1.25


Chloride 1.25 31.345 2080-12095.2 0.842mg/L86.8 56.9

Fluoride 0.938 3.1345 2080-12088.7 2.70mg/L3.01 0.226

Sulfate 1.25 60.180 2080-12095.9 1.73mg/L75.1 17.4



entirety.

Page 39 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




pH 7.0000 90-110101pH Units7.04



pH 201.51pH Units9.19 9.33




pH 200.139pH Units7.18 7.19













entirety.

Page 40 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDE0264 - EPA 200.2, EPA 3005

Blank (BDE0264-BLK1) Prepared: 05/14/2018 Analyzed: 05/15/2018







Barium 0.500 ug/L<0.500



Lead 0.500 ug/L<0.500

Cobalt 0.500 ug/L<0.500

LCS (BDE0264-BS1) Prepared: 05/14/2018 Analyzed: 05/15/2018

Antimony 0.500 100.00 85-115102ug/L102

Cadmium 0.100 100.00 85-11598.2ug/L98.2

Beryllium 0.500 100.00 85-11598.9ug/L98.9

Selenium 0.500 100.00 85-11597.5ug/L97.5

Thallium 0.500 100.00 85-115101ug/L101

Lead 0.500 100.00 85-115100ug/L100

Arsenic 0.500 100.00 85-11598.2ug/L98.2

Molybdenum 0.500 100.00 85-11599.6ug/L99.6

Barium 0.500 100.00 85-115102ug/L102

Cobalt 0.500 100.00 85-115101ug/L101

Chromium 0.500 100.00 85-115100ug/L100

Duplicate (BDE0264-DUP1) Prepared: 05/14/2018 Analyzed: 05/15/2018Source: MDE0098-04

Barium 0.500 204.61ug/L51.6 49.3


Cadmium 0.100 20ug/L0.0439 <0.100

Molybdenum 0.500 201.52ug/L120 118

Lead 0.500 20ug/L0.0409 <0.500

Antimony 0.500 202.91ug/L1.91 1.86


Arsenic 0.500 208.01ug/L4.34 4.01

Selenium 0.500 200.844ug/L37.7 38.0

Cobalt 0.500 200.234ug/L0.154 0.154

Chromium 0.500 202.01ug/L7.42 7.57



entirety.

Page 41 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.100 20ug/L<0.100 0.0276

Thallium 0.500 20ug/L<0.500 <0.500

Molybdenum 0.500 201.52ug/L132 130

Chromium 0.500 202.92ug/L0.218 0.224

Cobalt 0.500 200.682ug/L0.180 0.179

Antimony 0.500 205.69ug/L0.623 0.589

Selenium 0.500 200.373ug/L1.71 1.72

Arsenic 0.500 200.0173ug/L5.88 5.88

Barium 0.500 202.54ug/L50.4 49.2


Lead 0.500 20ug/L0.0162 <0.500

Matrix Spike (BDE0264-MS1) Prepared: 05/14/2018 Analyzed: 05/15/2018Source: MDE0098-04

Chromium 0.500 100.00 70-130101ug/L109 7.57

Beryllium 0.500 100.00 70-13096.3ug/L96.3 0.00806

Selenium 0.500 100.00 70-13097.5ug/L136 38.0

Thallium 0.500 100.00 70-13095.0ug/L95.0 0.0163

Molybdenum 0.500 100.00 70-130108ug/L226 118

Lead 0.500 100.00 70-13092.6ug/L92.6 <0.500

Cobalt 0.500 100.00 70-130101ug/L101 0.154

Cadmium 0.100 100.00 70-13095.6ug/L95.6 <0.100

Arsenic 0.500 100.00 70-130103ug/L107 4.01

Barium 0.500 100.00 70-130105ug/L155 49.3

Antimony 0.500 100.00 70-130105ug/L107 1.86


Cadmium 0.100 100.00 70-13095.4ug/L95.5 0.0276

Selenium 0.500 100.00 70-13095.7ug/L97.4 1.72

Molybdenum 0.500 100.00 70-130106ug/L236 130

Antimony 0.500 100.00 70-130106ug/L106 0.589

Beryllium 0.500 100.00 70-13092.0ug/L92.0 0.00974

Cobalt 0.500 100.00 70-13099.7ug/L99.9 0.179

Lead 0.500 100.00 70-13092.8ug/L92.8 <0.500

Chromium 0.500 100.00 70-130101ug/L101 0.224

Arsenic 0.500 100.00 70-130104ug/L110 5.88

Thallium 0.500 100.00 70-13094.6ug/L94.6 <0.500

Barium 0.500 100.00 70-130107ug/L157 49.2



entirety.

Page 42 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BDE0264-MSD1) Prepared: 05/14/2018 Analyzed: 05/15/2018Source: MDE0098-04

Selenium 0.500 100.00 2070-13097.9 0.281ug/L136 38.0

Barium 0.500 100.00 2070-130107 1.25ug/L156 49.3

Cadmium 0.100 100.00 2070-13094.5 1.12ug/L94.5 <0.100

Chromium 0.500 100.00 2070-130101 0.107ug/L109 7.57

Cobalt 0.500 100.00 2070-130102 1.42ug/L102 0.154

Thallium 0.500 100.00 2070-13094.4 0.589ug/L94.4 0.0163

Antimony 0.500 100.00 2070-130104 0.675ug/L106 1.86

Arsenic 0.500 100.00 2070-130103 0.547ug/L107 4.01

Lead 0.500 100.00 2070-13093.1 0.539ug/L93.1 <0.500

Molybdenum 0.500 100.00 2070-130105 1.23ug/L223 118

Beryllium 0.500 100.00 2070-13094.6 1.77ug/L94.6 0.00806


Antimony 0.500 100.00 2070-130104 2.10ug/L104 0.589

Cadmium 0.100 100.00 2070-13093.7 1.80ug/L93.8 0.0276

Barium 0.500 100.00 2070-130105 1.54ug/L154 49.2

Arsenic 0.500 100.00 2070-130101 2.19ug/L107 5.88

Molybdenum 0.500 100.00 2070-130107 0.420ug/L237 130

Cobalt 0.500 100.00 2070-13096.7 2.99ug/L96.9 0.179

Lead 0.500 100.00 2070-13091.0 2.03ug/L91.0 <0.500

Chromium 0.500 100.00 2070-13097.8 3.02ug/L98.0 0.224

Thallium 0.500 100.00 2070-13093.5 1.22ug/L93.5 <0.500

Selenium 0.500 100.00 2070-13094.7 0.933ug/L96.5 1.72

Beryllium 0.500 100.00 2070-13091.9 0.0151ug/L91.9 0.00974



entirety.

Page 43 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BDE0263-BLK1) Prepared: 05/14/2018 Analyzed: 05/17/2018

Boron 0.0500 mg/L<0.0500

Lithium 0.0500 mg/L<0.0500


Sodium 0.500 mg/L<0.500



LCS (BDE0263-BS1) Prepared: 05/14/2018 Analyzed: 05/17/2018

Calcium 0.500 100.00 85-115104mg/L104

Boron 0.0500 1.0000 85-115101mg/L1.01

Lithium 0.0500 1.0000 85-115100mg/L1.00

Sodium 0.500 100.00 85-115105mg/L105

Magnesium 0.500 100.00 85-115104mg/L104

Potassium 0.500 100.00 85-115104mg/L104


Potassium 0.500 200.558mg/L17.0 16.9

Calcium 0.500 200.00192mg/L468 468

Sodium 0.500 200.222mg/L84.2 84.1

Lithium 0.0500 201.06mg/L0.134 0.136

Magnesium 0.500 200.446mg/L8.17 8.21

Boron 0.0500 202.31mg/L11.3 11.5


Sodium 0.500 201.02mg/L64.6 65.3

Magnesium 0.500 201.01mg/L71.7 72.4

Lithium 0.0500 20mg/L<0.0500 <0.0500

Potassium 0.500 206.36mg/L1.93 1.81

Calcium 0.500 201.09mg/L255 257

Boron 0.0500 201.12mg/L5.37 5.43



entirety.

Page 44 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Calcium 0.500 100.00 70-130125mg/L593 468

Sodium 0.500 100.00 70-130106mg/L190 84.1

Lithium 0.0500 1.0000 75-125100mg/L1.14 0.136

Potassium 0.500 100.00 70-130104mg/L121 16.9

Boron 0.0500 1.0000 70-130113mg/L12.7 11.5

Magnesium 0.500 100.00 70-13099.7mg/L108 8.21


Sodium 0.500 100.00 70-130105mg/L171 65.3

Boron 0.0500 1.0000 70-13080.4mg/L6.24 5.43

Lithium 0.0500 1.0000 75-125102mg/L1.02 <0.0500

Calcium 0.500 100.00 70-130107mg/L364 257

Magnesium 0.500 100.00 70-130106mg/L179 72.4

Potassium 0.500 100.00 70-130105mg/L106 1.81


Sodium 0.500 100.00 2070-130109 1.91mg/L193 84.1

Calcium 0.500 100.00 20 M_MS70-130133 1.32mg/L601 468

Potassium 0.500 100.00 2070-130106 1.93mg/L123 16.9

Magnesium 0.500 100.00 2070-130102 1.93mg/L110 8.21

Lithium 0.0500 1.0000 2075-125102 2.04mg/L1.16 0.136

Boron 0.0500 1.0000 2070-130105 0.630mg/L12.6 11.5


Sodium 0.500 100.00 2070-130102 2.17mg/L167 65.3

Boron 0.0500 1.0000 2070-130119 5.98mg/L6.62 5.43

Calcium 0.500 100.00 2070-13099.4 2.13mg/L357 257

Magnesium 0.500 100.00 2070-130101 2.97mg/L173 72.4

Lithium 0.0500 1.0000 2075-125100 2.37mg/L1.00 <0.0500

Potassium 0.500 100.00 2070-130102 2.63mg/L104 1.81



entirety.

Page 45 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDE0318 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11594.2ug/L2.83


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13091.1ug/L2.73 <0.200


Mercury 0.200 3.0000 70-13090.3ug/L2.71 <0.200


Mercury 0.200 3.0000 2070-13090.1 1.16ug/L2.70 <0.200


Mercury 0.200 3.0000 2070-13087.8 2.82ug/L2.63 <0.200






entirety.

Page 46 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Mercury 0.200 3.0000 85-11594.7ug/L2.84


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13094.7ug/L2.84 <0.200


Mercury 0.200 3.0000 2070-13089.6 5.48ug/L2.69 <0.200



entirety.

Page 47 of 48



Reported:


250 Marquette Plaza

06/04/2018 09:14Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150









dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 48 of 48

#=CL#

July 09, 2018



RE:


18-00699, Xcel Energy- Black D

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on June 18, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 19

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 19

#=SS#

SAMPLE SUMMARY





30256332002 W504A Water 06/12/18 08:45 06/18/18 09:00

30256332003 W504B Water 06/12/18 09:20 06/18/18 09:00

30256332004 W502A Water 06/12/18 10:00 06/18/18 09:00

30256332005 W502B Water 06/12/18 10:35 06/18/18 09:00

30256332006 W602A Water 06/12/18 11:25 06/18/18 09:00

30256332007 W7A Water 06/12/18 12:10 06/18/18 09:00

30256332008 W14A Water 06/12/18 12:50 06/18/18 09:00

30256332009 W600A Water 06/12/18 13:30 06/18/18 09:00

30256332010 W601A Water 06/12/18 14:15 06/18/18 09:00

30256332011 W511A Water 06/13/18 08:30 06/18/18 09:00

30256332012 W510A Water 06/13/18 09:10 06/18/18 09:00

30256332013 W603A Water 06/13/18 09:50 06/18/18 09:00

30256332014 W604A Water 06/13/18 10:40 06/18/18 09:00

30256332015 W605A Water 06/13/18 11:30 06/18/18 09:00

30256332016 W506A Water 06/13/18 12:20 06/18/18 09:00

30256332017 Duplicate Water 06/13/18 12:20 06/18/18 09:00

30256332018 W514A Water 06/13/18 13:30 06/18/18 09:00

30256332019 W514B Water 06/13/18 14:10 06/18/18 09:00




Greensburg, PA 15601(724)850-5600

Page 3 of 19

#=SA#








30256332002 W504A EPA 903.1 1 PASI-PAKAC



30256332003 W504B EPA 903.1 1 PASI-PAKAC



30256332004 W502A EPA 903.1 1 PASI-PAKAC



30256332005 W502B EPA 903.1 1 PASI-PAKAC



30256332006 W602A EPA 903.1 1 PASI-PAKAC



30256332007 W7A EPA 903.1 1 PASI-PAKAC



30256332008 W14A EPA 903.1 1 PASI-PAKAC



30256332009 W600A EPA 903.1 1 PASI-PAKAC



30256332010 W601A EPA 903.1 1 PASI-PAKAC



30256332011 W511A EPA 903.1 1 PASI-PAKAC



30256332012 W510A EPA 903.1 1 PASI-PAKAC



30256332013 W603A EPA 903.1 1 PASI-PAKAC




Greensburg, PA 15601(724)850-5600

Page 4 of 19

#=SA#







30256332014 W604A EPA 903.1 1 PASI-PAKAC



30256332015 W605A EPA 903.1 1 PASI-PAKAC



30256332016 W506A EPA 903.1 1 PASI-PAKAC






30256332018 W514A EPA 903.1 1 PASI-PAKAC



30256332019 W514B EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 5 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: July 09, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0

Date: July 09, 2018











Greensburg, PA 15601(724)850-5600

Page 7 of 19

#=NA#

PROJECT NARRATIVE



Method:



Date: July 09, 2018












Greensburg, PA 15601(724)850-5600

Page 8 of 19

#=ARR#







Radium-226 0.0652 ± 0.495 (0.978)C:NA T:73%

pCi/L 07/05/18 12:26 13982-63-3EPA 903.1

Radium-228 0.512 ± 0.463 (0.940)C:71% T:85%

pCi/L 07/06/18 13:26 15262-20-1EPA 904.0





Radium-226 0.203 ± 0.245 (0.374)C:NA T:89%

pCi/L 07/05/18 12:42 13982-63-3EPA 903.1

Radium-228 -0.222 ± 0.463 (1.13)C:65% T:73%

pCi/L 07/06/18 13:26 15262-20-1EPA 904.0





Radium-226 0.882 ± 0.536 (0.691)C:NA T:95%

pCi/L 07/05/18 12:42 13982-63-3EPA 903.1

Radium-228 1.02 ± 0.505 (0.857)C:66% T:83%

pCi/L 07/06/18 13:26 15262-20-1EPA 904.0





Radium-226 0.244 ± 0.396 (0.689)C:NA T:93%

pCi/L 07/05/18 12:42 13982-63-3EPA 903.1

Radium-228 0.620 ± 0.570 (1.17)C:70% T:75%

pCi/L 07/06/18 13:26 15262-20-1EPA 904.0





Radium-226 0.489 ± 0.442 (0.652)C:NA T:80%

pCi/L 07/05/18 12:57 13982-63-3EPA 903.1

Radium-228 0.540 ± 0.485 (0.983)C:63% T:85%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 19

#=ARR#











Radium-226 0.0530 ± 0.275 (0.571)C:NA T:88%

pCi/L 07/05/18 12:43 13982-63-3EPA 903.1

Radium-228 0.502 ± 0.487 (1.00)C:66% T:84%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0





Radium-226 0.462 ± 0.338 (0.378)C:NA T:86%

pCi/L 07/05/18 12:43 13982-63-3EPA 903.1

Radium-228 -0.126 ± 0.371 (0.899)C:65% T:87%

pCi/L 07/06/18 13:28 15262-20-1EPA 904.0





Radium-226 0.107 ± 0.332 (0.643)C:NA T:89%

pCi/L 07/05/18 12:57 13982-63-3EPA 903.1

Radium-228 0.0917 ± 0.459 (1.05)C:67% T:72%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0





Radium-226 0.315 ± 0.358 (0.565)C:NA T:85%

pCi/L 07/05/18 12:57 13982-63-3EPA 903.1

Radium-228 0.344 ± 0.424 (0.896)C:71% T:79%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 19

#=ARR#







Radium-226 0.388 ± 0.383 (0.582)C:NA T:89%

pCi/L 07/05/18 12:57 13982-63-3EPA 903.1

Radium-228 0.622 ± 0.448 (0.867)C:70% T:83%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0





Radium-226 0.103 ± 0.320 (0.621)C:NA T:87%

pCi/L 07/05/18 13:14 13982-63-3EPA 903.1

Radium-228 0.166 ± 0.406 (0.903)C:64% T:93%

pCi/L 07/06/18 13:27 15262-20-1EPA 904.0





Radium-226 0.535 ± 0.398 (0.524)C:NA T:93%

pCi/L 07/05/18 13:14 13982-63-3EPA 903.1

Radium-228 1.06 ± 0.631 (1.17)C:63% T:73%

pCi/L 07/06/18 13:28 15262-20-1EPA 904.0





Radium-226 0.170 ± 0.260 (0.418)C:NA T:81%

pCi/L 07/05/18 13:14 13982-63-3EPA 903.1

Radium-228 0.246 ± 0.454 (0.994)C:63% T:81%

pCi/L 07/06/18 13:28 15262-20-1EPA 904.0





Radium-226 0.477 ± 0.373 (0.439)C:NA T:75%

pCi/L 07/05/18 13:14 13982-63-3EPA 903.1

Radium-228 0.348 ± 0.483 (1.04)C:68% T:78%

pCi/L 07/06/18 13:28 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 19

#=ARR#











Radium-226 0.419 ± 0.387 (0.563)C:NA T:81%

pCi/L 07/05/18 13:14 13982-63-3EPA 903.1

Radium-228 1.19 ± 0.680 (1.28)C:63% T:85%

pCi/L 07/06/18 13:33 15262-20-1EPA 904.0





Radium-226 -0.053 ± 0.344 (0.746)C:NA T:86%

pCi/L 07/05/18 13:30 13982-63-3EPA 903.1

Radium-228 0.328 ± 0.639 (1.40)C:67% T:68%

pCi/L 07/06/18 13:33 15262-20-1EPA 904.0





Radium-226 0.111 ± 0.254 (0.410)C:NA T:79%

pCi/L 07/05/18 13:30 13982-63-3EPA 903.1

Radium-228 1.23 ± 0.712 (1.35)C:65% T:81%

pCi/L 07/06/18 13:33 15262-20-1EPA 904.0





Radium-226 0.218 ± 0.339 (0.586)C:NA T:82%

pCi/L 07/05/18 13:30 13982-63-3EPA 903.1

Radium-228 0.845 ± 0.665 (1.34)C:63% T:81%

pCi/L 07/06/18 13:33 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 19

#=ARR#







Radium-226 -0.152 ± 0.331 (0.763)C:NA T:86%

pCi/L 07/05/18 13:51 13982-63-3EPA 903.1

Radium-228 0.127 ± 0.577 (1.30)C:68% T:87%

pCi/L 07/06/18 13:33 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 13 of 19

#=QCR#







302949EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 07/05/18 12:260.257 ± 0.303 (0.477) C:NA T:89%




Greensburg, PA 15601(724)850-5600

Page 14 of 19

#=QCR#







302934EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 07/06/18 13:260.317 ± 0.406 (0.860) C:76% T:73%




Greensburg, PA 15601(724)850-5600

Page 15 of 19

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision andbias for a specific analyte in a specific matrix.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Act - ActivityUnc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)(MDC) - Minimum Detectable ConcentrationTrac - Tracer Recovery (%)Carr - Carrier Recovery (%)Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 16 of 19


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

29 June 2018

cc:



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDF0147-01 Water 06/14/2018 9:3006/13/2018 12:40Field Blank

MDF0147-02 Water 06/14/2018 9:3006/12/2018 8:45W504A

MDF0147-03 Water 06/14/2018 9:3006/12/2018 9:20W504B

MDF0147-04 Water 06/14/2018 9:3006/12/2018 10:00W502A

MDF0147-05 Water 06/14/2018 9:3006/12/2018 10:35W502B

MDF0147-06 Water 06/14/2018 9:3006/12/2018 11:25W602A

MDF0147-07 Water 06/14/2018 9:3006/12/2018 12:10W7A

MDF0147-08 Water 06/14/2018 9:3006/12/2018 12:50W14A

MDF0147-09 Water 06/14/2018 9:3006/12/2018 13:30W600A

MDF0147-10 Water 06/14/2018 9:3006/12/2018 14:15W601A

MDF0147-11 Water 06/14/2018 9:3006/13/2018 8:30W511A

MDF0147-12 Water 06/14/2018 9:3006/13/2018 9:10W510A

MDF0147-13 Water 06/14/2018 9:3006/13/2018 9:50W603A

MDF0147-14 Water 06/14/2018 9:3006/13/2018 10:40W604A

MDF0147-15 Water 06/14/2018 9:3006/13/2018 11:30W605A

MDF0147-16 Water 06/14/2018 9:3006/13/2018 12:20W506A

MDF0147-17 Water 06/14/2018 9:3006/13/2018 12:20Duplicate

MDF0147-18 Water 06/14/2018 9:3006/13/2018 13:30W514A

MDF0147-19 Water 06/14/2018 9:3006/13/2018 14:10W514B



entirety.

Page 1 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDF0147-01 (Water) - Chain of Custody Number: 2202816/2202814

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDF0332 EPA 300.0< 1.00 CRL6/19/18 15:226/19/18 11:40

Fluoride 0.750 mg/L 1 BDF0332 EPA 300.0< 0.750 CRL6/19/18 15:226/19/18 11:40

Sulfate 1.00 mg/L 1 BDF0332 EPA 300.0< 1.00 CRL6/19/18 15:226/19/18 11:40

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDF0263 SM 2320B< 10.0 CRL6/14/18 10:426/14/18 9:52

pH pH Units 1 BDF0263 SM 4500-H+ B6.58 CRLM_TTT 6/14/18 10:426/14/18 9:52

Total Dissolved Solids 20.0 mg/L 1 BDF0288 SM 2540C< 20.0 HSD6/18/18 8:006/18/18 8:00


Arsenic 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Barium 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Beryllium 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Cadmium 0.100 ug/L 1 BDF0290 EPA 200.8< 0.100 CRL6/21/18 8:396/19/18 12:14

Cobalt 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Chromium 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Molybdenum 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Lead 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Antimony 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Selenium 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Thallium 0.500 ug/L 1 BDF0290 EPA 200.8< 0.500 CRL6/21/18 8:396/19/18 12:14

Total Metals by ICP

Boron 0.0500 mg/L 1 BDF0289 EPA 200.7< 0.0500 HRD6/21/18 12:426/19/18 12:10

Calcium 1.25 mg/L 1 BDF0289 EPA 200.7< 1.25 HRD6/21/18 12:406/19/18 12:10

Potassium 1.50 mg/L 1 BDF0289 EPA 200.7< 1.50 HRD6/21/18 12:406/19/18 12:10

Lithium 0.0500 mg/L 1 BDF0289 EPA 200.7< 0.0500 HRD6/21/18 12:406/19/18 12:10

Magnesium 1.25 mg/L 1 BDF0289 EPA 200.7< 1.25 HRD6/21/18 12:406/19/18 12:10

Sodium 1.25 mg/L 1 BDF0289 EPA 200.7< 1.25 HRD6/21/18 12:406/19/18 12:10



entirety.

Page 2 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDF0553 EPA 245.1, 7470A< 0.200 HRD6/28/18 14:286/28/18 8:52



entirety.

Page 3 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDF0332 EPA 300.089.6 CRL6/19/18 15:436/19/18 11:40


Sulfate 1.00 mg/L 1 BDF0332 EPA 300.0715 CRL6/19/18 15:436/19/18 11:40

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDF0263 SM 2320B524 CRL6/14/18 10:586/14/18 9:52


Total Dissolved Solids 20.0 mg/L 1 BDF0288 SM 2540C1950 HSD6/18/18 8:006/18/18 8:00


Arsenic 0.500 ug/L 1 BDF0290 EPA 200.84.24 CRL6/21/18 8:436/19/18 12:14

Barium 0.500 ug/L 1 BDF0290 EPA 200.827.3 CRL6/21/18 8:436/19/18 12:14


Cadmium 0.100 ug/L 1 BDF0290 EPA 200.80.120 CRL6/21/18 8:436/19/18 12:14

Cobalt 0.500 ug/L 1 BDF0290 EPA 200.82.28 CRL6/21/18 8:436/19/18 12:14


Molybdenum 0.500 ug/L 1 BDF0290 EPA 200.822.1 CRL6/21/18 8:436/19/18 12:14





Total Metals by ICP

Boron 0.0500 mg/L 1 BDF0289 EPA 200.711.4 HRD6/21/18 12:466/19/18 12:10

Calcium 1.25 mg/L 1 BDF0289 EPA 200.7330 HRD6/21/18 12:456/19/18 12:10

Potassium 1.50 mg/L 1 BDF0289 EPA 200.72.27 HRD6/21/18 12:456/19/18 12:10


Magnesium 1.25 mg/L 1 BDF0289 EPA 200.784.4 HRD6/21/18 12:456/19/18 12:10

Sodium 1.25 mg/L 1 BDF0289 EPA 200.7156 HRD6/21/18 12:456/19/18 12:10



entirety.

Page 4 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDF0332 EPA 300.012.7 CRL6/19/18 16:036/19/18 11:40

Wet Chemistry






Barium 0.500 ug/L 1 BDF0290 EPA 200.8343 CRL6/21/18 8:546/19/18 12:14










Total Metals by ICP






Sodium 1.25 mg/L 1 BDF0289 EPA 200.724.5 HRD6/21/18 13:016/19/18 12:10



entirety.

Page 6 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 7 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDF0332 EPA 300.0103 CRL6/19/18 16:446/19/18 11:40



Wet Chemistry
















Total Metals by ICP




Lithium 0.0500 mg/L 1 BDF0289 EPA 200.70.0866 HRD6/21/18 13:066/19/18 12:10





entirety.

Page 8 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDF0289 EPA 200.7117 HRD6/21/18 13:116/19/18 12:10




entirety.

Page 10 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 11 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 12 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry










Chromium 0.500 ug/L 1 BDF0290 EPA 200.80.744 CRL6/21/18 9:106/19/18 12:14






Total Metals by ICP









entirety.

Page 14 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte





Wet Chemistry











Molybdenum 0.500 ug/L 1 BDF0290 EPA 200.8105 CRL6/21/18 9:146/19/18 12:14





Total Metals by ICP


Calcium 1.25 mg/L 1 BDF0289 EPA 200.792.8 HRD6/21/18 13:266/19/18 12:10







entirety.

Page 16 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L 1 BDF0290 EPA 200.82.86 CRL6/21/18 9:186/19/18 12:14





Lead 0.500 ug/L 1 BDF0290 EPA 200.83.24 CRL6/21/18 9:186/19/18 12:14



Thallium 0.500 ug/L 1 BDF0290 EPA 200.80.513 CRL6/21/18 9:186/19/18 12:14

Total Metals by ICP









entirety.

Page 18 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDF0263 SM 2320B98.1 CRL6/14/18 11:526/14/18 9:52












Antimony 0.500 ug/L 1 BDF0290 EPA 200.81.18 CRL6/21/18 9:226/19/18 12:14

Selenium 0.500 ug/L 1 BDF0290 EPA 200.8159 CRL6/21/18 9:226/19/18 12:14


Total Metals by ICP









entirety.

Page 20 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 21 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte





Wet Chemistry














Selenium 0.500 ug/L 1 BDF0290 EPA 200.881.1 CRL6/21/18 9:266/19/18 12:14


Total Metals by ICP









entirety.

Page 22 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 23 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 24 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 25 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 26 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 29 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 30 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 31 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 32 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 34 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 35 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDF0332 EPA 300.062.5 CRL6/20/18 0:546/19/18 11:40

Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP



Potassium 1.50 mg/L 1 BDF0289 EPA 200.7< 1.50 HRD6/21/18 14:336/19/18 12:10






entirety.

Page 38 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte

Mercury




entirety.

Page 39 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDF0332 - Wet Prep

Blank (BDF0332-BLK1) Prepared & Analyzed: 06/19/2018








LCS (BDF0332-BS1) Prepared & Analyzed: 06/19/2018

Chloride 1.00 25.076 90-11092.8mg/L23.3

Fluoride 0.750 2.5076 90-110101mg/L2.52

Sulfate 1.00 48.144 90-11093.7mg/L45.1


Chloride 1.00 25.076 90-11098.3mg/L24.6

Fluoride 0.750 2.5076 90-110106mg/L2.65

Sulfate 1.00 48.144 90-11099.3mg/L47.8

LCS (BDF0332-BS3) Prepared: 06/19/2018 Analyzed: 06/20/2018

Chloride 1.00 25.076 90-11095.0mg/L23.8

Fluoride 0.750 2.5076 90-110102mg/L2.56

Sulfate 1.00 48.144 90-11095.5mg/L46.0


Chloride 1.00 25.076 90-11098.7mg/L24.8

Fluoride 0.750 2.5076 90-110102mg/L2.56

Sulfate 1.00 48.144 90-11099.8mg/L48.0



entirety.

Page 40 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Duplicate (BDF0332-DUP1) Prepared & Analyzed: 06/19/2018Source: MDF0147-03

Chloride 1.00 202.87mg/L49.8 51.3

Fluoride 0.750 203.27mg/L0.241 0.249

Sulfate 1.00 203.14mg/L12.3 12.7


Chloride 1.00 200.292mg/L43.9 43.8

Fluoride 0.750 201.61mg/L0.188 0.185

Sulfate 1.00 200.774mg/L62.0 62.5

Matrix Spike (BDF0332-MS1) Prepared & Analyzed: 06/19/2018Source: MDF0147-03

Chloride 1.25 31.345 80-12083.6mg/L77.5 51.3

Fluoride 0.938 3.1345 80-12083.6mg/L2.87 0.249

Sulfate 1.25 60.180 80-12088.4mg/L65.9 12.7


Chloride 1.25 31.345 80-12092.0mg/L72.6 43.8

Fluoride 0.938 3.1345 80-12098.7mg/L3.28 0.185

Sulfate 1.25 60.180 80-12092.2mg/L118 62.5

Matrix Spike Dup (BDF0332-MSD1) Prepared & Analyzed: 06/19/2018Source: MDF0147-03

Chloride 1.25 31.345 2080-12088.8 2.09mg/L79.1 51.3

Fluoride 0.938 3.1345 2080-12095.0 11.7mg/L3.23 0.249

Sulfate 1.25 60.180 2080-12092.0 3.25mg/L68.1 12.7


Chloride 1.25 31.345 2080-12091.9 0.0293mg/L72.6 43.8

Fluoride 0.938 3.1345 2080-120100 1.33mg/L3.32 0.185

Sulfate 1.25 60.180 2080-12092.0 0.0964mg/L118 62.5



entirety.

Page 41 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte





pH 7.0000 90-110101pH Units7.10


pH 200.421pH Units7.11 7.14




pH 200.441pH Units9.09 9.05













entirety.

Page 42 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDF0290 - EPA 200.2, EPA 3005

Blank (BDF0290-BLK1) Prepared: 06/19/2018 Analyzed: 06/21/2018

Barium 0.500 ug/L<0.500

Lead 0.500 ug/L<0.500



Cobalt 0.500 ug/L<0.500








Arsenic 0.500 100.00 85-115102ug/L102

Lead 0.500 100.00 85-11597.5ug/L97.5

Barium 0.500 100.00 85-11599.4ug/L99.4

Molybdenum 0.500 100.00 85-115103ug/L103

Cadmium 0.100 100.00 85-115102ug/L102

Selenium 0.500 100.00 85-11595.0ug/L95.0

Thallium 0.500 100.00 85-11596.9ug/L96.9

Antimony 0.500 100.00 85-11597.0ug/L97.0

Cobalt 0.500 100.00 85-115102ug/L102

Chromium 0.500 100.00 85-115102ug/L102

Beryllium 0.500 100.00 85-11596.9ug/L96.9

Duplicate (BDF0290-DUP1) Prepared: 06/19/2018 Analyzed: 06/21/2018Source: MDF0147-18

Thallium 0.500 20ug/L0.0938 <0.500

Selenium 0.500 209.54ug/L0.729 0.802


Lead 0.500 20 M_D-RL33.6ug/L0.147 0.105

Molybdenum 0.500 208.79ug/L5.64 5.17

Chromium 0.500 200.904ug/L0.830 0.837

Cobalt 0.500 2014.6ug/L0.243 0.210

Cadmium 0.100 20 M_D-RL112ug/L0.0885 0.0249


Barium 0.500 201.05ug/L96.4 95.4

Arsenic 0.500 204.90ug/L0.600 0.571



entirety.

Page 43 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Thallium 0.500 20ug/L<0.500 <0.500

Selenium 0.500 20 M_D-RL39.0ug/L0.158 0.234

Antimony 0.500 20 M_D-RL100ug/L0.264 0.0874

Lead 0.500 2016.3ug/L0.0275 0.0233

Arsenic 0.500 202.30ug/L2.33 2.28

Cobalt 0.500 2016.9ug/L0.131 0.111

Barium 0.500 203.35ug/L150 145



Cadmium 0.100 20 M_D-RL27.6ug/L0.0382 0.0289

Molybdenum 0.500 207.80ug/L1.83 1.69

Matrix Spike (BDF0290-MS1) Prepared: 06/19/2018 Analyzed: 06/21/2018Source: MDF0147-18

Molybdenum 0.500 100.00 70-130104ug/L110 5.17

Lead 0.500 100.00 70-13089.9ug/L90.1 0.105

Chromium 0.500 100.00 70-130102ug/L103 0.837

Cobalt 0.500 100.00 70-13095.0ug/L95.2 0.210

Barium 0.500 100.00 70-130108ug/L203 95.4

Arsenic 0.500 100.00 70-130106ug/L107 0.571

Thallium 0.500 100.00 70-13093.5ug/L93.5 <0.500

Cadmium 0.100 100.00 70-13098.0ug/L98.0 0.0249

Beryllium 0.500 100.00 70-13095.1ug/L95.1 0.0236

Selenium 0.500 100.00 70-13097.1ug/L97.9 0.802

Antimony 0.500 100.00 70-130102ug/L102 0.348


Lead 0.500 100.00 70-13093.0ug/L93.0 0.0233

Beryllium 0.500 100.00 70-13099.0ug/L99.0 0.0117

Arsenic 0.500 100.00 70-130104ug/L106 2.28

Barium 0.500 100.00 70-130111ug/L256 145

Cobalt 0.500 100.00 70-13096.9ug/L97.0 0.111

Chromium 0.500 100.00 70-130101ug/L102 0.196

Antimony 0.500 100.00 70-130102ug/L102 0.0874

Selenium 0.500 100.00 70-13098.2ug/L98.4 0.234

Molybdenum 0.500 100.00 70-13099.6ug/L101 1.69

Thallium 0.500 100.00 70-13094.5ug/L94.5 <0.500

Cadmium 0.100 100.00 70-13098.3ug/L98.3 0.0289



entirety.

Page 44 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BDF0290-MSD1) Prepared: 06/19/2018 Analyzed: 06/21/2018Source: MDF0147-18

Lead 0.500 100.00 2070-13089.4 0.591ug/L89.5 0.105

Molybdenum 0.500 100.00 2070-130100 3.72ug/L106 5.17

Chromium 0.500 100.00 2070-130103 1.08ug/L104 0.837

Barium 0.500 100.00 2070-13099.3 4.23ug/L195 95.4

Beryllium 0.500 100.00 2070-13094.0 1.20ug/L94.0 0.0236

Selenium 0.500 100.00 2070-13098.2 1.14ug/L99.0 0.802

Cobalt 0.500 100.00 2070-13096.3 1.41ug/L96.5 0.210

Antimony 0.500 100.00 2070-13099.2 2.88ug/L99.5 0.348

Arsenic 0.500 100.00 2070-130104 2.00ug/L104 0.571

Cadmium 0.100 100.00 2070-13096.9 1.11ug/L96.9 0.0249

Thallium 0.500 100.00 2070-13091.1 2.51ug/L91.1 <0.500


Lead 0.500 100.00 2070-13089.2 4.17ug/L89.2 0.0233

Antimony 0.500 100.00 2070-130102 0.135ug/L102 0.0874

Thallium 0.500 100.00 2070-13091.2 3.51ug/L91.2 <0.500

Arsenic 0.500 100.00 2070-130100 3.54ug/L102 2.28

Selenium 0.500 100.00 2070-13093.1 5.33ug/L93.3 0.234

Barium 0.500 100.00 2070-130109 0.552ug/L254 145

Beryllium 0.500 100.00 2070-130100 1.01ug/L100 0.0117

Cadmium 0.100 100.00 2070-130100 1.90ug/L100 0.0289

Cobalt 0.500 100.00 2070-13097.9 1.04ug/L98.0 0.111

Chromium 0.500 100.00 2070-130102 1.03ug/L103 0.196

Molybdenum 0.500 100.00 2070-13098.1 1.48ug/L99.8 1.69



entirety.

Page 45 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BDF0289-BLK1) Prepared: 06/19/2018 Analyzed: 06/21/2018


Boron 0.0500 mg/L<0.0500

Lithium 0.0500 mg/L<0.0500


Sodium 1.25 mg/L<1.25



Lithium 0.0500 1.0000 85-11598.7mg/L0.987

Calcium 1.25 100.00 85-115103mg/L103

Sodium 1.25 100.00 85-115103mg/L103

Boron 0.0500 1.0000 85-11598.1mg/L0.981

Magnesium 1.25 100.00 85-115102mg/L102

Potassium 1.50 100.00 85-11599.1mg/L99.1


Boron 0.0500 200.539mg/L2.66 2.65

Lithium 0.0500 20 M_D-RL20.2mg/L0.0191 0.0234

Potassium 1.50 203.84mg/L5.92 5.70

Calcium 1.25 203.89mg/L71.7 69.0

Magnesium 1.25 200.983mg/L16.5 16.3

Sodium 1.25 204.23mg/L108 103


Sodium 1.25 204.14mg/L59.5 57.1

Magnesium 1.25 201.82mg/L44.6 43.8

Lithium 0.0500 201.85mg/L0.0608 0.0619

Potassium 1.50 208.24mg/L9.37 8.62

Boron 0.0500 205.72mg/L1.55 1.47

Calcium 1.25 204.08mg/L511 491



entirety.

Page 46 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Magnesium 1.25 100.00 70-130102mg/L118 16.3

Sodium 1.25 100.00 70-130108mg/L211 103

Calcium 1.25 100.00 70-130106mg/L175 69.0

Boron 0.0500 1.0000 70-130100mg/L3.65 2.65

Lithium 0.0500 1.0000 75-12597.9mg/L1.00 0.0234

Potassium 1.50 100.00 70-13099.1mg/L105 5.70


Sodium 1.25 100.00 70-130108mg/L165 57.1

Lithium 0.0500 1.0000 75-125102mg/L1.08 0.0619

Magnesium 1.25 100.00 70-130104mg/L147 43.8

Boron 0.0500 1.0000 70-130107mg/L2.54 1.47

Potassium 1.50 100.00 70-130102mg/L111 8.62

Calcium 1.25 100.00 M_MS70-130138mg/L628 491


Magnesium 1.25 100.00 2070-130102 0.210mg/L118 16.3

Boron 0.0500 1.0000 2070-130103 0.828mg/L3.68 2.65

Calcium 1.25 100.00 2070-130106 0.113mg/L175 69.0

Lithium 0.0500 1.0000 2075-12597.7 0.172mg/L1.00 0.0234

Potassium 1.50 100.00 2070-13098.8 0.220mg/L105 5.70

Sodium 1.25 100.00 2070-130109 0.335mg/L212 103


Sodium 1.25 100.00 2070-130105 1.91mg/L162 57.1

Boron 0.0500 1.0000 2070-130107 0.202mg/L2.53 1.47

Magnesium 1.25 100.00 2070-130104 0.0667mg/L147 43.8

Calcium 1.25 100.00 2070-130125 2.08mg/L615 491

Potassium 1.50 100.00 2070-130101 1.64mg/L109 8.62

Lithium 0.0500 1.0000 2075-125101 1.64mg/L1.07 0.0619



entirety.

Page 47 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDF0553 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11596.8ug/L2.90


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13095.2ug/L2.86 <0.200


Mercury 0.200 3.0000 70-13089.4ug/L2.68 <0.200


Mercury 0.200 3.0000 2070-13092.4 2.96ug/L2.77 <0.200


Mercury 0.200 3.0000 2070-13092.7 3.67ug/L2.78 <0.200



entirety.

Page 48 of 49



Reported:


250 Marquette Plaza

06/29/2018 08:30Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150









dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 49 of 49

#=CL#

August 14, 2018



RE:


XCel Energy Black Dog CCR

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on July 30, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 19

#=CP#

CERTIFICATIONS


30260756XCel Energy Black Dog CCR






Greensburg, PA 15601(724)850-5600

Page 2 of 19

#=SS#

SAMPLE SUMMARY





30260756002 W 504 A Water 07/23/18 14:10 07/30/18 09:00

30260756003 W 504 B Water 07/23/18 14:40 07/30/18 09:00

30260756004 W 511 A Water 07/24/18 08:45 07/30/18 09:00

30260756005 W 510 A Water 07/24/18 09:30 07/30/18 09:00

30260756006 W 14 A Water 07/24/18 10:35 07/30/18 09:00

30260756007 W 7 A Water 07/24/18 11:30 07/30/18 09:00

30260756008 W 602 A Water 07/24/18 12:15 07/30/18 09:00

30260756009 W 502 A Water 07/24/18 13:20 07/30/18 09:00

30260756010 Duplicate Water 07/24/18 13:20 07/30/18 09:00

30260756011 W 502 B Water 07/24/18 14:00 07/30/18 09:00

30260756012 W 600 A Water 07/24/18 15:20 07/30/18 09:00

30260756013 W 603 A Water 07/25/18 09:05 07/30/18 09:00

30260756014 W 604 A Water 07/25/18 09:50 07/30/18 09:00

30260756015 W 605 A Water 07/25/18 10:35 07/30/18 09:00

30260756016 W 601 A Water 07/25/18 11:30 07/30/18 09:00

30260756017 W 506 A Water 07/25/18 12:10 07/30/18 09:00

30260756018 W 514 A Water 07/25/18 13:00 07/30/18 09:00

30260756019 W 514 B Water 07/25/18 13:45 07/30/18 09:00

30260756020 Pond A Water 07/25/18 14:05 07/30/18 09:00




Greensburg, PA 15601(724)850-5600

Page 3 of 19

#=SA#





30260756001 Field Blank EPA 903.1 1 PASI-PAMK1

EPA 904.0 1 PASI-PAVAL


30260756002 W 504 A EPA 903.1 1 PASI-PAMK1



30260756003 W 504 B EPA 903.1 1 PASI-PAMK1



30260756004 W 511 A EPA 903.1 1 PASI-PAMK1



30260756005 W 510 A EPA 903.1 1 PASI-PAMK1



30260756006 W 14 A EPA 903.1 1 PASI-PAMK1



30260756007 W 7 A EPA 903.1 1 PASI-PAMK1



30260756008 W 602 A EPA 903.1 1 PASI-PAMK1



30260756009 W 502 A EPA 903.1 1 PASI-PAMK1



30260756010 Duplicate EPA 903.1 1 PASI-PAMK1



30260756011 W 502 B EPA 903.1 1 PASI-PAMK1



30260756012 W 600 A EPA 903.1 1 PASI-PAMK1



30260756013 W 603 A EPA 903.1 1 PASI-PAMK1




Greensburg, PA 15601(724)850-5600

Page 4 of 19

#=SA#







30260756014 W 604 A EPA 903.1 1 PASI-PAMK1



30260756015 W 605 A EPA 903.1 1 PASI-PAMK1



30260756016 W 601 A EPA 903.1 1 PASI-PAMK1



30260756017 W 506 A EPA 903.1 1 PASI-PAMK1



30260756018 W 514 A EPA 903.1 1 PASI-PAMK1



30260756019 W 514 B EPA 903.1 1 PASI-PAMK1



30260756020 Pond A EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 5 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: August 14, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 19

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 19

#=ARR#







Radium-226 -0.028 ± 0.471 (0.869)C:NA T:90%

pCi/L 08/10/18 09:21 13982-63-3EPA 903.1

Radium-228 0.493 ± 0.348 (0.665)C:77% T:80%

pCi/L 08/09/18 12:56 15262-20-1EPA 904.0





Radium-226 0.232 ± 0.387 (0.625)C:NA T:88%

pCi/L 08/10/18 09:21 13982-63-3EPA 903.1

Radium-228 0.847 ± 0.367 (0.575)C:80% T:85%

pCi/L 08/09/18 12:56 15262-20-1EPA 904.0





Radium-226 0.594 ± 0.735 (1.11)C:NA T:78%

pCi/L 08/10/18 09:21 13982-63-3EPA 903.1

Radium-228 0.871 ± 0.464 (0.841)C:74% T:84%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Radium-226 0.0567 ± 0.539 (0.945)C:NA T:86%

pCi/L 08/10/18 09:21 13982-63-3EPA 903.1

Radium-228 0.542 ± 0.395 (0.775)C:78% T:82%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Radium-226 0.0310 ± 0.628 (1.10)C:NA T:86%

pCi/L 08/10/18 09:21 13982-63-3EPA 903.1

Radium-228 1.41 ± 0.530 (0.821)C:74% T:85%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 19

#=ARR#











Radium-226 -0.332 ± 0.541 (1.07)C:NA T:86%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 1.10 ± 0.466 (0.766)C:77% T:86%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Radium-226 0.441 ± 0.599 (0.919)C:NA T:88%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 0.311 ± 0.318 (0.660)C:78% T:92%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Radium-226 0.399 ± 0.691 (1.09)C:NA T:85%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 0.603 ± 0.440 (0.863)C:77% T:74%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Radium-226 0.760 ± 0.448 (0.441)C:NA T:95%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 0.598 ± 0.409 (0.795)C:78% T:88%

pCi/L 08/09/18 12:54 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 19

#=ARR#







Radium-226 0.470 ± 0.505 (0.737)C:NA T:94%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 0.860 ± 0.444 (0.791)C:79% T:80%

pCi/L 08/09/18 12:55 15262-20-1EPA 904.0





Radium-226 0.237 ± 0.358 (0.568)C:NA T:84%

pCi/L 08/10/18 09:41 13982-63-3EPA 903.1

Radium-228 0.504 ± 0.360 (0.697)C:77% T:84%

pCi/L 08/09/18 12:55 15262-20-1EPA 904.0





Radium-226 0.556 ± 0.496 (0.665)C:NA T:88%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 0.562 ± 0.394 (0.765)C:81% T:78%

pCi/L 08/09/18 12:55 15262-20-1EPA 904.0





Radium-226 0.293 ± 0.515 (0.827)C:NA T:87%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 0.360 ± 0.443 (0.941)C:75% T:77%

pCi/L 08/09/18 12:55 15262-20-1EPA 904.0





Radium-226 -0.052 ± 0.476 (0.873)C:NA T:91%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 0.171 ± 0.355 (0.785)C:77% T:72%

pCi/L 08/09/18 12:55 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 19

#=ARR#











Radium-226 0.426 ± 0.639 (1.000)C:NA T:74%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 -0.0314 ± 0.502 (1.15)C:74% T:82%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0





Radium-226 0.402 ± 0.391 (0.520)C:NA T:87%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 -0.146 ± 0.346 (0.823)C:81% T:87%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0





Radium-226 0.582 ± 0.451 (0.570)C:NA T:96%

pCi/L 08/10/18 10:00 13982-63-3EPA 903.1

Radium-228 0.935 ± 0.466 (0.831)C:78% T:85%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0





Radium-226 0.0576 ± 0.452 (0.812)C:NA T:85%

pCi/L 08/10/18 10:20 13982-63-3EPA 903.1

Radium-228 0.739 ± 0.508 (1.00)C:76% T:84%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 19

#=ARR#







Radium-226 0.0618 ± 0.485 (0.872)C:NA T:84%

pCi/L 08/10/18 10:20 13982-63-3EPA 903.1

Radium-228 0.940 ± 0.507 (0.933)C:75% T:82%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0


Sample: Pond A Lab ID: 30260756020 Collected: 07/25/18 14:05 Received: 07/30/18 09:00 Matrix: Water



Radium-226 0.562 ± 0.586 (0.876)C:NA T:92%

pCi/L 08/14/18 09:35 13982-63-3EPA 903.1

Radium-228 2.18 ± 0.728 (1.03)C:75% T:70%

pCi/L 08/09/18 12:59 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 13 of 19

#=QCR#







308023EPA 903.1

EPA 903.1903.1 Radium-226

Associated Lab Samples: 30260756001, 30260756002, 30260756003, 30260756004, 30260756005, 30260756006, 30260756007,30260756008, 30260756009, 30260756010, 30260756011, 30260756012, 30260756013, 30260756014,30260756015, 30260756016, 30260756017, 30260756018, 30260756019, 30260756020




Matrix: Water

Analyzed

Radium-226 pCi/L 08/10/18 09:210.202 ± 0.434 (0.724) C:NA T:86%




Greensburg, PA 15601(724)850-5600

Page 14 of 19

#=QCR#







308178EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 08/09/18 12:560.740 ± 0.360 (0.587) C:78% T:78%




Greensburg, PA 15601(724)850-5600

Page 15 of 19

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision andbias for a specific analyte in a specific matrix.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Act - ActivityUnc - Uncertainty: SDWA = 1.96 sigma count uncertainty, all other matrices = Expanded Uncertainty (95% confidence interval).Gamma Spec = Expanded Uncertainty (95.4% Confidence Interval)(MDC) - Minimum Detectable ConcentrationTrac - Tracer Recovery (%)Carr - Carrier Recovery (%)Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 16 of 19


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

08 August 2018

cc:



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDG0324-01 Water 07/26/2018 11:1107/23/2018 13:35Field Blank

MDG0324-02 Water 07/26/2018 11:1107/23/2018 14:10W504A

MDG0324-03 Water 07/26/2018 11:1107/23/2018 14:40W504B

MDG0324-04 Water 07/26/2018 11:1107/24/2018 8:45W511A

MDG0324-05 Water 07/26/2018 11:1107/24/2018 9:30W510A

MDG0324-06 Water 07/26/2018 11:1107/24/2018 10:35W14A

MDG0324-07 Water 07/26/2018 11:1107/24/2018 11:30W7A

MDG0324-08 Water 07/26/2018 11:1107/24/2018 12:15W602A

MDG0324-09 Water 07/26/2018 11:1107/24/2018 13:20W502A

MDG0324-10 Water 07/26/2018 11:1107/24/2018 13:20Duplicate

MDG0324-11 Water 07/26/2018 11:1107/24/2018 14:00W502B

MDG0324-12 Water 07/26/2018 11:1107/24/2018 15:20W600A

MDG0324-13 Water 07/26/2018 11:1107/25/2018 9:05W603A

MDG0324-14 Water 07/26/2018 11:1107/25/2018 9:50W604A

MDG0324-15 Water 07/26/2018 11:1107/25/2018 10:35W605A

MDG0324-16 Water 07/26/2018 11:1107/25/2018 11:30W601A

MDG0324-17 Water 07/26/2018 11:1107/25/2018 12:10W506A

MDG0324-18 Water 07/26/2018 11:1107/25/2018 13:00W514A

MDG0324-19 Water 07/26/2018 11:1107/25/2018 13:45W514B

MDG0324-20 Water 07/26/2018 11:1107/25/2018 14:05Pond A



entirety.

Page 1 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDG0324-01 (Water) - Chain of Custody Number: 2202809/2202811

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDG0562 EPA 300.0< 1.00 CRL7/26/18 14:587/26/18 11:50

Fluoride 0.750 mg/L 1 BDG0562 EPA 300.0< 0.750 CRL7/26/18 14:587/26/18 11:50

Sulfate 1.00 mg/L 1 BDG0562 EPA 300.0< 1.00 CRL7/26/18 14:587/26/18 11:50

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDG0561 SM 2320B< 10.0 CRL7/26/18 13:307/26/18 11:43

pH pH Units 1 BDG0561 SM 4500-H+ B6.69 CRLM_TTT 7/26/18 13:307/26/18 11:43

Total Dissolved Solids 20.0 mg/L 1 BDG0568 SM 2540C< 20.0 HSD7/27/18 8:307/27/18 8:30


Arsenic 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Barium 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Beryllium 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Cadmium 0.100 ug/L 1 BDG0558 EPA 200.8< 0.100 CRL7/27/18 8:387/26/18 11:47

Cobalt 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Chromium 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Molybdenum 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Lead 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Antimony 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Selenium 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Thallium 0.500 ug/L 1 BDG0558 EPA 200.8< 0.500 CRL7/27/18 8:387/26/18 11:47

Total Metals by ICP

Boron 0.0500 mg/L 1 BDG0557 EPA 200.7< 0.0500 HRD7/27/18 11:437/26/18 11:45

Calcium 1.25 mg/L 1 BDG0557 EPA 200.7< 1.25 HRD7/27/18 11:417/26/18 11:45

Potassium 1.25 mg/L 1 BDG0557 EPA 200.7< 1.25 HRD7/27/18 11:417/26/18 11:45

Lithium 0.0150 mg/L 1 BDG0557 EPA 200.7< 0.0150 HRD7/27/18 11:417/26/18 11:45

Magnesium 1.25 mg/L 1 BDG0557 EPA 200.7< 1.25 HRD7/27/18 11:417/26/18 11:45

Sodium 1.50 mg/L 1 BDG0557 EPA 200.7< 1.50 HRD7/27/18 11:417/26/18 11:45



entirety.

Page 2 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDG0638 EPA 245.1, 7470A< 0.200 HRD7/31/18 15:187/30/18 14:24



entirety.

Page 3 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDG0562 EPA 300.096.3 CRL7/26/18 15:187/26/18 11:50


Sulfate 1.00 mg/L 1 BDG0562 EPA 300.0706 CRL7/26/18 15:187/26/18 11:50

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDG0561 SM 2320B531 CRL7/26/18 13:467/26/18 11:43


Total Dissolved Solids 20.0 mg/L 1 BDG0568 SM 2540C1880 HSD7/27/18 8:307/27/18 8:30


Arsenic 0.500 ug/L 1 BDG0558 EPA 200.84.73 CRL7/27/18 8:427/26/18 11:47

Barium 0.500 ug/L 1 BDG0558 EPA 200.830.5 CRL7/27/18 8:427/26/18 11:47


Cadmium 0.100 ug/L 1 BDG0558 EPA 200.80.158 CRL7/27/18 8:427/26/18 11:47

Cobalt 0.500 ug/L 1 BDG0558 EPA 200.82.38 CRL7/27/18 8:427/26/18 11:47


Molybdenum 0.500 ug/L 1 BDG0558 EPA 200.825.5 CRL7/27/18 8:427/26/18 11:47





Total Metals by ICP

Boron 0.0500 mg/L 1 BDG0557 EPA 200.711.2 HRD7/27/18 11:487/26/18 11:45

Calcium 1.25 mg/L 1 BDG0557 EPA 200.7320 HRD7/27/18 11:467/26/18 11:45

Potassium 1.25 mg/L 1 BDG0557 EPA 200.72.16 HRD7/27/18 11:467/26/18 11:45

Lithium 0.0150 mg/L 1 BDG0557 EPA 200.70.0372 HRD7/27/18 11:467/26/18 11:45

Magnesium 1.25 mg/L 1 BDG0557 EPA 200.784.4 HRD7/27/18 11:477/26/18 11:45

Sodium 1.50 mg/L 1 BDG0557 EPA 200.7150 HRD7/27/18 11:467/26/18 11:45



entirety.

Page 4 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDG0562 EPA 300.019.3 CRL7/26/18 15:387/26/18 11:50

Wet Chemistry






Barium 0.500 ug/L 1 BDG0558 EPA 200.8364 CRL7/27/18 8:547/26/18 11:47










Total Metals by ICP






Sodium 1.50 mg/L 1 BDG0557 EPA 200.725.0 HRD7/27/18 12:027/26/18 11:45



entirety.

Page 6 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 7 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDG0561 SM 2320B60.0 CRL7/26/18 14:017/26/18 11:43









Chromium 0.500 ug/L 1 BDG0558 EPA 200.82.21 CRL7/27/18 8:587/26/18 11:47

Molybdenum 0.500 ug/L 1 BDG0558 EPA 200.8391 CRL7/27/18 8:587/26/18 11:47


Antimony 0.500 ug/L 1 BDG0558 EPA 200.82.85 CRL7/27/18 8:587/26/18 11:47

Selenium 0.500 ug/L 1 BDG0558 EPA 200.829.7 CRL7/27/18 8:587/26/18 11:47


Total Metals by ICP









entirety.

Page 8 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 10 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 12 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 14 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDG0562 EPA 300.0200 CRL7/26/18 17:417/26/18 11:50



Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 18 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 20 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 21 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDG0557 EPA 200.7112 HRD7/27/18 12:437/26/18 11:45




entirety.

Page 22 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 23 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L 1 BDG0558 EPA 200.80.717 CRL7/27/18 9:297/26/18 11:47









Total Metals by ICP









entirety.

Page 24 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 25 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP


Calcium 1.25 mg/L 1 BDG0557 EPA 200.764.5 HRD7/27/18 13:047/26/18 11:45







entirety.

Page 26 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDH0190 EPA 245.1, 7470A< 0.200 HRD8/7/18 14:338/7/18 9:46



entirety.

Page 29 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 30 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 31 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDG0557 EPA 200.7< 1.25 HRD7/27/18 13:197/26/18 11:45




entirety.

Page 32 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry















Thallium 0.500 ug/L 1 BDG0558 EPA 200.80.974 CRL7/27/18 9:567/26/18 11:47

Total Metals by ICP









entirety.

Page 34 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 35 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDG0562 EPA 300.0< 1.00 CRL7/27/18 1:107/26/18 11:50

Wet Chemistry
















Total Metals by ICP









entirety.

Page 38 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte

Mercury




entirety.

Page 39 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Pond A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 40 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Pond A

Qualifier

Analyte

Mercury




entirety.

Page 41 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDG0562 - Wet Prep

Blank (BDG0562-BLK1) Prepared & Analyzed: 07/26/2018








LCS (BDG0562-BS1) Prepared & Analyzed: 07/26/2018

Chloride 1.00 25.076 90-11094.7mg/L23.8

Fluoride 0.750 2.5076 90-11098.8mg/L2.48

Sulfate 1.00 48.144 90-11095.6mg/L46.0


Chloride 1.00 25.076 90-11095.8mg/L24.0

Fluoride 0.750 2.5076 90-110101mg/L2.53

Sulfate 1.00 48.144 90-11096.6mg/L46.5

LCS (BDG0562-BS3) Prepared: 07/26/2018 Analyzed: 07/27/2018

Chloride 1.00 25.076 90-11096.5mg/L24.2

Fluoride 0.750 2.5076 90-110101mg/L2.54

Sulfate 1.00 48.144 90-11097.1mg/L46.7

Duplicate (BDG0562-DUP1) Prepared & Analyzed: 07/26/2018Source: MDG0324-18

Chloride 1.00 201.04mg/L42.6 43.0

Fluoride 0.750 200.519mg/L0.192 0.193

Sulfate 1.00 200.934mg/L67.0 67.6



entirety.

Page 42 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.762mg/L8.90 8.96

Fluoride 0.750 203.10mg/L0.159 0.164

Sulfate 1.00 20mg/L<1.00 <1.00

Matrix Spike (BDG0562-MS1) Prepared & Analyzed: 07/26/2018Source: MDG0324-18

Chloride 1.25 31.345 80-12094.1mg/L72.5 43.0

Fluoride 0.938 3.1345 80-12094.0mg/L3.14 0.193

Sulfate 1.25 60.180 80-12094.6mg/L125 67.6

Matrix Spike (BDG0562-MS2) Prepared & Analyzed: 07/26/2018Source: MDG0324-19

Chloride 1.25 31.345 80-12095.1mg/L38.8 8.96

Fluoride 0.938 3.1345 80-12094.5mg/L3.13 0.164

Sulfate 1.25 60.180 80-12095.5mg/L57.5 <1.25

Matrix Spike Dup (BDG0562-MSD1) Prepared & Analyzed: 07/26/2018Source: MDG0324-18

Chloride 1.25 31.345 2080-12093.5 0.274mg/L72.3 43.0

Fluoride 0.938 3.1345 2080-12097.3 3.25mg/L3.24 0.193

Sulfate 1.25 60.180 2080-12094.1 0.228mg/L124 67.6

Matrix Spike Dup (BDG0562-MSD2) Prepared & Analyzed: 07/26/2018Source: MDG0324-19

Chloride 1.25 31.345 2080-12096.8 1.33mg/L39.3 8.96

Fluoride 0.938 3.1345 2080-12099.9 5.30mg/L3.30 0.164

Sulfate 1.25 60.180 2080-12097.5 2.12mg/L58.7 <1.25



entirety.

Page 43 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte





pH 7.0000 90-110101pH Units7.06



pH 7.0000 90-110101pH Units7.06



pH 200.559pH Units7.14 7.18



pH 200.137pH Units7.32 7.31











entirety.

Page 44 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte







entirety.

Page 45 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDG0558 - EPA 200.2, EPA 3005

Blank (BDG0558-BLK1) Prepared: 07/26/2018 Analyzed: 07/27/2018




Lead 0.500 ug/L<0.500



Cobalt 0.500 ug/L<0.500


Barium 0.500 ug/L<0.500




Lead 0.500 100.00 85-11597.0ug/L97.0

Arsenic 0.500 100.00 85-11597.8ug/L97.8

Antimony 0.500 100.00 85-11595.6ug/L95.6

Chromium 0.500 100.00 85-115100ug/L100

Barium 0.500 100.00 85-11597.0ug/L97.0

Cobalt 0.500 100.00 85-11598.5ug/L98.5

Molybdenum 0.500 100.00 85-11597.7ug/L97.7

Cadmium 0.100 100.00 85-11597.5ug/L97.5

Thallium 0.500 100.00 85-11597.6ug/L97.6

Beryllium 0.500 100.00 85-11598.8ug/L98.8

Selenium 0.500 100.00 85-11597.2ug/L97.2

Duplicate (BDG0558-DUP1) Prepared: 07/26/2018 Analyzed: 07/27/2018Source: MDG0324-04

Arsenic 0.500 204.28ug/L5.61 5.38

Selenium 0.500 200.550ug/L29.8 29.7

Lead 0.500 20 M_D-RL88.0ug/L0.0584 0.0227


Barium 0.500 203.65ug/L67.6 65.1


Molybdenum 0.500 203.17ug/L403 391

Chromium 0.500 206.73ug/L2.36 2.21

Cadmium 0.100 20 M_D27.5ug/L0.165 0.125

Cobalt 0.500 203.01ug/L0.248 0.241

Antimony 0.500 209.77ug/L2.59 2.85



entirety.

Page 46 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Molybdenum 0.500 205.15ug/L0.848 0.893

Selenium 0.500 20ug/L<0.500 <0.500

Cadmium 0.100 20 M_D-RL69.4ug/L0.0704 0.0341

Cobalt 0.500 207.20ug/L0.386 0.415

Chromium 0.500 201.66ug/L0.486 0.478

Beryllium 0.500 202.83ug/L0.0319 0.0310

Barium 0.500 200.588ug/L334 332

Arsenic 0.500 200.451ug/L39.8 40.0

Lead 0.500 206.97ug/L0.0965 0.103


Thallium 0.500 20ug/L<0.500 <0.500

Matrix Spike (BDG0558-MS1) Prepared: 07/26/2018 Analyzed: 07/27/2018Source: MDG0324-04

Barium 0.500 100.00 70-130101ug/L166 65.1

Beryllium 0.500 100.00 70-13085.4ug/L85.5 0.0365

Arsenic 0.500 100.00 70-130106ug/L112 5.38

Antimony 0.500 100.00 70-13095.9ug/L98.8 2.85

Molybdenum 0.500 100.00 70-130103ug/L494 391

Selenium 0.500 100.00 70-13099.0ug/L129 29.7

Cobalt 0.500 100.00 70-130102ug/L102 0.241

Cadmium 0.100 100.00 70-13094.4ug/L94.6 0.125

Lead 0.500 100.00 70-13083.3ug/L83.4 0.0227

Thallium 0.500 100.00 70-13086.6ug/L86.7 0.105

Chromium 0.500 100.00 70-130103ug/L105 2.21


Barium 0.500 100.00 70-130104ug/L436 332

Lead 0.500 100.00 70-13083.6ug/L83.8 0.103

Beryllium 0.500 100.00 70-13091.7ug/L91.8 0.0310

Chromium 0.500 100.00 70-130110ug/L110 0.478

Arsenic 0.500 100.00 70-130103ug/L143 40.0

Molybdenum 0.500 100.00 70-130103ug/L104 0.893

Thallium 0.500 100.00 70-13087.3ug/L87.3 <0.500

Selenium 0.500 100.00 70-13096.0ug/L96.0 <0.500

Cobalt 0.500 100.00 70-130105ug/L105 0.415

Antimony 0.500 100.00 70-13097.7ug/L97.8 0.0544

Cadmium 0.100 100.00 70-13096.9ug/L96.9 0.0341



entirety.

Page 47 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BDG0558-MSD1) Prepared: 07/26/2018 Analyzed: 07/27/2018Source: MDG0324-04

Lead 0.500 100.00 2070-13084.0 0.797ug/L84.0 0.0227

Antimony 0.500 100.00 2070-13096.7 0.788ug/L99.6 2.85

Thallium 0.500 100.00 2070-13087.7 1.29ug/L87.8 0.105

Molybdenum 0.500 100.00 2070-130125 4.29ug/L516 391

Selenium 0.500 100.00 2070-13099.7 0.550ug/L129 29.7

Cadmium 0.100 100.00 2070-13094.4 0.0695ug/L94.5 0.125

Beryllium 0.500 100.00 2070-13085.9 0.595ug/L86.0 0.0365

Chromium 0.500 100.00 2070-130108 4.90ug/L111 2.21

Arsenic 0.500 100.00 2070-130110 3.27ug/L115 5.38

Barium 0.500 100.00 2070-130105 2.82ug/L170 65.1

Cobalt 0.500 100.00 2070-130105 2.46ug/L105 0.241


Arsenic 0.500 100.00 2070-130105 1.62ug/L145 40.0

Lead 0.500 100.00 2070-13084.0 0.388ug/L84.1 0.103

Beryllium 0.500 100.00 2070-13096.3 4.82ug/L96.3 0.0310

Antimony 0.500 100.00 2070-13096.4 1.33ug/L96.5 0.0544

Cadmium 0.100 100.00 2070-13095.6 1.35ug/L95.6 0.0341

Barium 0.500 100.00 2070-130109 1.08ug/L441 332

Molybdenum 0.500 100.00 2070-130101 2.04ug/L102 0.893

Selenium 0.500 100.00 2070-13097.8 1.80ug/L97.8 <0.500

Chromium 0.500 100.00 2070-130110 0.593ug/L111 0.478

Thallium 0.500 100.00 2070-13087.7 0.473ug/L87.7 <0.500

Cobalt 0.500 100.00 2070-130106 1.12ug/L106 0.415



entirety.

Page 48 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte





Lithium 0.0150 mg/L<0.0150



Boron 0.0500 mg/L<0.0500



Boron 0.0500 1.0000 85-115101mg/L1.01

Calcium 1.25 100.00 85-115102mg/L102

Sodium 1.50 100.00 85-115101mg/L101

Lithium 0.0150 1.0000 85-11597.5mg/L0.975

Magnesium 1.25 100.00 85-115101mg/L101

Potassium 1.25 100.00 85-11599.3mg/L99.3


Boron 0.0500 201.80mg/L11.4 11.2

Magnesium 1.25 200.614mg/L83.9 84.4

Sodium 1.50 200.686mg/L151 150

Calcium 1.25 200.612mg/L322 320

Lithium 0.0150 202.67mg/L0.0362 0.0372

Potassium 1.25 207.62mg/L2.34 2.16


Sodium 1.50 200.803mg/L24.8 25.0

Lithium 0.0150 200.900mg/L0.0240 0.0237

Potassium 1.25 205.04mg/L1.59 1.52

Calcium 1.25 201.03mg/L214 216

Boron 0.0500 202.10mg/L0.377 0.369

Magnesium 1.25 200.585mg/L78.5 79.0



entirety.

Page 49 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Magnesium 1.25 100.00 70-130104mg/L189 84.4

Sodium 1.50 100.00 70-130108mg/L258 150

Boron 0.0500 1.0000 70-130113mg/L12.3 11.2

Calcium 1.25 100.00 70-130114mg/L434 320

Lithium 0.0150 1.0000 75-125101mg/L1.04 0.0372

Potassium 1.25 100.00 70-130103mg/L105 2.16


Sodium 1.50 100.00 70-130101mg/L126 25.0

Calcium 1.25 100.00 70-130101mg/L317 216

Magnesium 1.25 100.00 70-130103mg/L182 79.0

Lithium 0.0150 1.0000 75-12598.9mg/L1.01 0.0237

Potassium 1.25 100.00 70-130100mg/L102 1.52

Boron 0.0500 1.0000 70-130107mg/L1.44 0.369


Sodium 1.50 100.00 2070-130107 0.481mg/L256 150

Boron 0.0500 1.0000 2070-130100 1.05mg/L12.2 11.2

Potassium 1.25 100.00 2070-130102 0.136mg/L105 2.16

Magnesium 1.25 100.00 2070-130102 1.56mg/L186 84.4

Calcium 1.25 100.00 2070-130111 0.712mg/L431 320

Lithium 0.0150 1.0000 2075-125101 0.0478mg/L1.04 0.0372


Calcium 1.25 100.00 2070-13095.7 1.79mg/L312 216

Magnesium 1.25 100.00 2070-130101 0.838mg/L180 79.0

Sodium 1.50 100.00 2070-13099.5 1.21mg/L124 25.0

Lithium 0.0150 1.0000 2075-12597.9 0.970mg/L1.00 0.0237

Potassium 1.25 100.00 2070-13099.8 0.697mg/L101 1.52

Boron 0.0500 1.0000 2070-130106 0.610mg/L1.43 0.369



entirety.

Page 50 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDG0638 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11594.2ug/L2.83


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13092.0ug/L2.76 <0.200


Mercury 0.200 3.0000 70-13090.6ug/L2.72 <0.200


Mercury 0.200 3.0000 2070-13089.6 2.66ug/L2.69 <0.200


Mercury 0.200 3.0000 2070-13088.5 2.34ug/L2.66 <0.200

Batch BDH0190 - EPA 245.1, EPA 7470A

Blank (BDH0190-BLK1) Prepared & Analyzed: 08/07/2018




entirety.

Page 51 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDH0190 - EPA 245.1, EPA 7470A

LCS (BDH0190-BS1) Prepared & Analyzed: 08/07/2018

Mercury 0.200 3.0000 85-11589.7ug/L2.69

Duplicate (BDH0190-DUP1) Prepared & Analyzed: 08/07/2018Source: MDG0324-14

Mercury 0.200 20ug/L<0.200 <0.200

Duplicate (BDH0190-DUP2) Prepared & Analyzed: 08/07/2018Source: MDG0324-15

Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDH0190-MS1) Prepared & Analyzed: 08/07/2018Source: MDG0324-14

Mercury 0.200 3.0000 70-13088.9ug/L2.67 <0.200

Matrix Spike (BDH0190-MS2) Prepared & Analyzed: 08/07/2018Source: MDG0324-15

Mercury 0.200 3.0000 70-13088.8ug/L2.66 <0.200

Matrix Spike Dup (BDH0190-MSD1) Prepared & Analyzed: 08/07/2018Source: MDG0324-14

Mercury 0.200 3.0000 2070-13086.9 2.23ug/L2.61 <0.200

Matrix Spike Dup (BDH0190-MSD2) Prepared & Analyzed: 08/07/2018Source: MDG0324-15

Mercury 0.200 3.0000 2070-13091.7 3.24ug/L2.75 <0.200



entirety.

Page 52 of 53



Reported:


250 Marquette Plaza

08/08/2018 10:04Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150





M_D The RPD for the sample duplicate was outside of QC acceptance limits possibly due to non-homogeneous matrix.



dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 53 of 53

#=CL#

September 28, 2018



RE:


18-01019, Xcel Energy-BD CCR

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on September 17, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 19

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 19

#=SS#

SAMPLE SUMMARY





30265295002 W504 A Water 09/10/18 13:40 09/17/18 09:00

30265295003 W504 B Water 09/10/18 14:25 09/17/18 09:00

30265295004 W510 A Water 09/11/18 09:10 09/17/18 09:00

30265295005 W511 A Water 09/11/18 10:05 09/17/18 09:00

30265295006 W14 A Water 09/11/18 11:30 09/17/18 09:00

30265295007 W7A Water 09/11/18 12:20 09/17/18 09:00

30265295008 W602 A Water 09/11/18 13:10 09/17/18 09:00

30265295009 W502 A Water 09/11/18 13:50 09/17/18 09:00

30265295010 W502 B Water 09/11/18 14:35 09/17/18 09:00

30265295011 Duplicate Water 09/11/18 14:35 09/17/18 09:00

30265295012 W603 A Water 09/12/18 09:30 09/17/18 09:00

30265295013 W604 A Water 09/12/18 10:25 09/17/18 09:00

30265295014 W605 A Water 09/12/18 11:10 09/17/18 09:00

30265295015 W601 A Water 09/12/18 12:30 09/17/18 09:00

30265295016 W506 A Water 09/12/18 13:15 09/17/18 09:00

30265295017 W514 A Water 09/12/18 14:05 09/17/18 09:00

30265295018 W514 B Water 09/12/18 14:45 09/17/18 09:00

30265295019 W600 A Water 09/12/18 15:35 09/17/18 09:00




Greensburg, PA 15601(724)850-5600

Page 3 of 19

#=SA#








30265295002 W504 A EPA 903.1 1 PASI-PAMK1



30265295003 W504 B EPA 903.1 1 PASI-PAMK1



30265295004 W510 A EPA 903.1 1 PASI-PAMK1



30265295005 W511 A EPA 903.1 1 PASI-PAMK1



30265295006 W14 A EPA 903.1 1 PASI-PAMK1



30265295007 W7A EPA 903.1 1 PASI-PAMK1



30265295008 W602 A EPA 903.1 1 PASI-PAMK1



30265295009 W502 A EPA 903.1 1 PASI-PAMK1



30265295010 W502 B EPA 903.1 1 PASI-PAMK1






30265295012 W603 A EPA 903.1 1 PASI-PAMK1



30265295013 W604 A EPA 903.1 1 PASI-PAMK1




Greensburg, PA 15601(724)850-5600

Page 4 of 19

#=SA#







30265295014 W605 A EPA 903.1 1 PASI-PAMK1



30265295015 W601 A EPA 903.1 1 PASI-PAMK1



30265295016 W506 A EPA 903.1 1 PASI-PAMK1



30265295017 W514 A EPA 903.1 1 PASI-PAMK1



30265295018 W514 B EPA 903.1 1 PASI-PAMK1



30265295019 W600 A EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 5 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: September 28, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 19

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 19

#=ARR#







Radium-226 0.438 ± 0.710 (1.24)C:NA T:67%

pCi/L 09/27/18 18:55 13982-63-3EPA 903.1

Radium-228 0.544 ± 0.348 (0.633)C:72% T:74%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0


Sample: W504 A Lab ID: 30265295002 Collected: 09/10/18 13:40 Received: 09/17/18 09:00 Matrix: Water



Radium-226 0.0611 ± 0.397 (0.801)C:NA T:90%

pCi/L 09/27/18 18:55 13982-63-3EPA 903.1

Radium-228 0.553 ± 0.359 (0.668)C:68% T:82%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0


Sample: W504 B Lab ID: 30265295003 Collected: 09/10/18 14:25 Received: 09/17/18 09:00 Matrix: Water



Radium-226 0.535 ± 0.621 (1.00)C:NA T:72%

pCi/L 09/27/18 18:55 13982-63-3EPA 903.1

Radium-228 0.469 ± 0.366 (0.719)C:71% T:80%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0





Radium-226 0.369 ± 0.523 (0.885)C:NA T:83%

pCi/L 09/27/18 18:55 13982-63-3EPA 903.1

Radium-228 0.561 ± 0.380 (0.726)C:70% T:85%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0





Radium-226 0.329 ± 0.559 (0.987)C:NA T:78%

pCi/L 09/27/18 18:55 13982-63-3EPA 903.1

Radium-228 0.520 ± 0.360 (0.689)C:71% T:84%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 19

#=ARR#











Radium-226 0.000 ± 0.479 (0.980)C:NA T:84%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 0.445 ± 0.321 (0.614)C:71% T:84%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 -0.071 ± 0.459 (0.995)C:NA T:75%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 0.312 ± 0.371 (0.782)C:72% T:79%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.215 ± 0.545 (1.01)C:NA T:76%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 0.381 ± 0.327 (0.654)C:70% T:85%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.377 ± 0.524 (0.885)C:NA T:88%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 0.427 ± 0.272 (0.492)C:76% T:88%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 19

#=ARR#







Radium-226 0.134 ± 0.491 (0.943)C:NA T:86%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 1.22 ± 0.422 (0.557)C:74% T:86%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.448 ± 0.550 (0.897)C:NA T:71%

pCi/L 09/27/18 19:08 13982-63-3EPA 903.1

Radium-228 0.577 ± 0.385 (0.726)C:69% T:79%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.0652 ± 0.424 (0.854)C:NA T:82%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 0.643 ± 0.385 (0.715)C:73% T:85%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0





Radium-226 0.188 ± 0.476 (0.883)C:NA T:88%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 0.466 ± 0.419 (0.855)C:71% T:81%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0





Radium-226 0.294 ± 0.540 (0.964)C:NA T:85%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 1.37 ± 0.492 (0.721)C:72% T:87%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 19

#=ARR#











Radium-226 0.000 ± 0.458 (0.968)C:NA T:78%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 0.645 ± 0.433 (0.832)C:74% T:76%

pCi/L 09/25/18 12:27 15262-20-1EPA 904.0





Radium-226 0.433 ± 0.568 (0.946)C:NA T:78%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 0.555 ± 0.404 (0.794)C:72% T:85%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.631 ± 0.584 (0.889)C:NA T:84%

pCi/L 09/27/18 19:22 13982-63-3EPA 903.1

Radium-228 0.650 ± 0.405 (0.759)C:70% T:81%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Radium-226 0.316 ± 0.481 (0.827)C:NA T:85%

pCi/L 09/27/18 19:35 13982-63-3EPA 903.1

Radium-228 0.655 ± 0.413 (0.781)C:68% T:86%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 19

#=ARR#







Radium-226 0.217 ± 0.550 (1.02)C:NA T:76%

pCi/L 09/27/18 19:35 13982-63-3EPA 903.1

Radium-228 1.72 ± 0.566 (0.765)C:71% T:81%

pCi/L 09/25/18 12:28 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 13 of 19

#=QCR#







313426EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 09/25/18 12:280.435 ± 0.289 (0.543) C:81% T:88%




Greensburg, PA 15601(724)850-5600

Page 14 of 19

#=QCR#







313424EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 09/27/18 18:550.412 ± 0.384 (0.506) C:NA T:80%




Greensburg, PA 15601(724)850-5600

Page 15 of 19

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision andbias for a specific analyte in a specific matrix.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Act - ActivityUnc - Uncertainty: For Safe Drinking Water Act (SDWA) analyses, the reported Unc. Is the calculated Count Uncertainty (95%confidence interval) using a coverage factor of 1.96. For all other matrices (non-SDWA), the reported Unc. is the calculatedExpanded Uncertainty (aka Combined Standard Uncertainty, CSU), reported at the 95% confidence interval using a coverage factorof 1.96.Gamma Spec: The Unc. reported for all gamma-spectroscopy analyses (EPA 901.1), is the calculated Expanded Uncertainty (CSU)at the 95.4% confidence interval, using a coverage factor of 2.0.(MDC) - Minimum Detectable ConcentrationTrac - Tracer Recovery (%)Carr - Carrier Recovery (%)Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 16 of 19


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

26 September 2018

cc:



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDI0152-01 Water 09/13/2018 10:4009/10/2018 13:00Field Blank

MDI0152-02 Water 09/13/2018 10:4009/10/2018 13:40W504A

MDI0152-03 Water 09/13/2018 10:4009/10/2018 14:25W504B

MDI0152-04 Water 09/13/2018 10:4009/11/2018 9:10W510A

MDI0152-05 Water 09/13/2018 10:4009/11/2018 10:05W511A

MDI0152-06 Water 09/13/2018 10:4009/11/2018 11:30W14A

MDI0152-07 Water 09/13/2018 10:4009/11/2018 12:20W7A

MDI0152-08 Water 09/13/2018 10:4009/11/2018 13:10W602A

MDI0152-09 Water 09/13/2018 10:4009/11/2018 13:50W502A

MDI0152-10 Water 09/13/2018 10:4009/11/2018 14:35W502B

MDI0152-11 Water 09/13/2018 10:4009/11/2018 14:35Duplicate

MDI0152-12 Water 09/13/2018 10:4009/12/2018 9:30W603A

MDI0152-13 Water 09/13/2018 10:4009/12/2018 10:25W604A

MDI0152-14 Water 09/13/2018 10:4009/12/2018 11:10W605A

MDI0152-15 Water 09/13/2018 10:4009/12/2018 12:30W601A

MDI0152-16 Water 09/13/2018 10:4009/12/2018 13:15W506A

MDI0152-17 Water 09/13/2018 10:4009/12/2018 14:05W514A

MDI0152-18 Water 09/13/2018 10:4009/12/2018 14:45W514B

MDI0152-19 Water 09/13/2018 10:4009/12/2018 15:35W600A



entirety.

Page 1 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDI0152-01 (Water) - Chain of Custody Number: 2299802/2299803

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDI0313 EPA 300.0< 1.00 CRL9/18/18 10:259/17/18 12:39

Fluoride 0.750 mg/L 1 BDI0313 EPA 300.0< 0.750 CRL9/18/18 10:259/17/18 12:39

Sulfate 1.00 mg/L 1 BDI0313 EPA 300.0< 1.00 CRL9/18/18 10:259/17/18 12:39

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDI0259 SM 2320B< 10.0 CRL9/13/18 13:349/13/18 11:57

pH pH Units 1 BDI0259 SM 4500-H+ B7.35 CRLM_TTT 9/13/18 13:349/13/18 11:57

Total Dissolved Solids 20.0 mg/L 1 BDI0261 SM 2540C< 20.0 HSD9/14/18 8:569/14/18 8:56


Arsenic 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Barium 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Beryllium 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/18/18 8:139/13/18 11:54

Cadmium 0.100 ug/L 1 BDI0258 EPA 200.8< 0.100 CRL9/17/18 9:129/13/18 11:54

Cobalt 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Chromium 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Molybdenum 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Lead 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Antimony 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Selenium 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Thallium 0.500 ug/L 1 BDI0258 EPA 200.8< 0.500 CRL9/17/18 9:129/13/18 11:54

Total Metals by ICP

Boron 0.0500 mg/L 1 BDI0257 EPA 200.7< 0.0500 HRD9/14/18 11:489/13/18 11:51

Calcium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 11:469/13/18 11:51

Potassium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 11:469/13/18 11:51

Lithium 0.0150 mg/L 1 BDI0257 EPA 200.7< 0.0150 HRD9/14/18 11:469/13/18 11:51

Magnesium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 11:479/13/18 11:51

Sodium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 11:469/13/18 11:51



entirety.

Page 2 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDI0298 EPA 245.1, 7470A< 0.200 HRD9/17/18 14:089/17/18 9:21



entirety.

Page 3 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDI0313 EPA 300.058.2 CRL9/18/18 10:459/17/18 12:39


Sulfate 1.00 mg/L 1 BDI0313 EPA 300.0785 CRL9/18/18 10:459/17/18 12:39

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDI0259 SM 2320B378 CRL9/13/18 13:499/13/18 11:57


Total Dissolved Solids 20.0 mg/L 1 BDI0261 SM 2540C1820 HSD9/14/18 8:569/14/18 8:56


Arsenic 0.500 ug/L 1 BDI0258 EPA 200.82.96 CRL9/17/18 9:169/13/18 11:54

Barium 0.500 ug/L 1 BDI0258 EPA 200.826.9 CRL9/17/18 9:169/13/18 11:54



Cobalt 0.500 ug/L 1 BDI0258 EPA 200.81.54 CRL9/17/18 9:169/13/18 11:54


Molybdenum 0.500 ug/L 1 BDI0258 EPA 200.857.6 CRL9/17/18 9:169/13/18 11:54





Total Metals by ICP

Boron 0.0500 mg/L 1 BDI0257 EPA 200.714.8 HRD9/14/18 11:539/13/18 11:51

Calcium 1.25 mg/L 1 BDI0257 EPA 200.7327 HRD9/14/18 11:519/13/18 11:51

Potassium 1.25 mg/L 1 BDI0257 EPA 200.73.81 HRD9/14/18 11:529/13/18 11:51

Lithium 0.0150 mg/L 1 BDI0257 EPA 200.70.0414 HRD9/14/18 11:529/13/18 11:51

Magnesium 1.25 mg/L 1 BDI0257 EPA 200.776.5 HRD9/14/18 11:529/13/18 11:51

Sodium 1.25 mg/L 1 BDI0257 EPA 200.7177 HRD9/14/18 11:519/13/18 11:51



entirety.

Page 4 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDI0313 EPA 300.014.0 CRL9/18/18 11:069/17/18 12:39

Wet Chemistry






Barium 0.500 ug/L 1 BDI0258 EPA 200.8349 CRL9/17/18 9:289/13/18 11:54










Total Metals by ICP






Sodium 1.25 mg/L 1 BDI0257 EPA 200.726.0 HRD9/14/18 12:079/13/18 11:51



entirety.

Page 6 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 7 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte





Wet Chemistry










Chromium 0.500 ug/L 1 BDI0258 EPA 200.80.721 CRL9/17/18 9:329/13/18 11:54






Total Metals by ICP









entirety.

Page 8 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDI0313 EPA 300.0122 CRL9/18/18 12:079/17/18 12:39



Wet Chemistry











Molybdenum 0.500 ug/L 1 BDI0258 EPA 200.8161 CRL9/17/18 9:369/13/18 11:54


Antimony 0.500 ug/L 1 BDI0258 EPA 200.80.629 CRL9/17/18 9:369/13/18 11:54

Selenium 0.500 ug/L 1 BDI0258 EPA 200.81.23 CRL9/17/18 9:369/13/18 11:54


Total Metals by ICP









entirety.

Page 10 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 12 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 14 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 18 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDI0257 EPA 200.7121 HRD9/14/18 12:439/13/18 11:51




entirety.

Page 20 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 21 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDI0257 EPA 200.7122 HRD9/14/18 12:489/13/18 11:51




entirety.

Page 22 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 23 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDI0259 SM 2320B77.4 CRL9/13/18 15:129/13/18 11:57















Total Metals by ICP


Calcium 1.25 mg/L 1 BDI0257 EPA 200.785.4 HRD9/14/18 12:529/13/18 11:51







entirety.

Page 24 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 25 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 26 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 29 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry














Selenium 0.500 ug/L 1 BDI0258 EPA 200.8127 CRL9/17/18 10:239/13/18 11:54


Total Metals by ICP





Magnesium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 13:199/13/18 11:51




entirety.

Page 30 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 31 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry








Cadmium 0.100 ug/L 1 BDI0258 EPA 200.85.37 CRL9/17/18 10:279/13/18 11:54







Thallium 0.500 ug/L 1 BDI0258 EPA 200.81.05 CRL9/17/18 10:279/13/18 11:54

Total Metals by ICP









entirety.

Page 32 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 34 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 35 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDI0313 EPA 300.0< 1.00 CRL9/18/18 19:569/17/18 12:39

Wet Chemistry
















Total Metals by ICP



Potassium 1.25 mg/L 1 BDI0257 EPA 200.7< 1.25 HRD9/14/18 13:339/13/18 11:51






entirety.

Page 36 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte

Mercury




entirety.

Page 37 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry








Cadmium 0.100 ug/L 1 BDI0258 EPA 200.80.635 CRL9/17/18 10:399/13/18 11:54








Total Metals by ICP









entirety.

Page 38 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 39 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDI0313 - Wet Prep

Blank (BDI0313-BLK1) Prepared: 09/17/2018 Analyzed: 09/18/2018








LCS (BDI0313-BS1) Prepared: 09/17/2018 Analyzed: 09/18/2018

Chloride 1.00 25.076 90-11094.7mg/L23.7

Fluoride 0.750 2.5076 90-11091.1mg/L2.29

Sulfate 1.00 48.144 90-11094.1mg/L45.3


Chloride 1.00 25.076 90-11097.1mg/L24.3

Fluoride 0.750 2.5076 90-11098.3mg/L2.47

Sulfate 1.00 48.144 90-11096.7mg/L46.6


Chloride 1.00 25.076 90-11096.8mg/L24.3

Fluoride 0.750 2.5076 90-11095.5mg/L2.39

Sulfate 1.00 48.144 90-11095.6mg/L46.0

Duplicate (BDI0313-DUP1) Prepared: 09/17/2018 Analyzed: 09/18/2018Source: MDI0152-17

Chloride 1.00 201.78mg/L37.6 38.2

Fluoride 0.750 208.59mg/L0.156 0.170

Sulfate 1.00 202.10mg/L58.4 59.6



entirety.

Page 40 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 201.39mg/L8.80 8.92

Fluoride 0.750 201.61mg/L0.125 0.123

Sulfate 1.00 201.39mg/L0.500 0.507

Matrix Spike (BDI0313-MS1) Prepared: 09/17/2018 Analyzed: 09/18/2018Source: MDI0152-17

Chloride 1.25 31.345 80-12094.7mg/L67.9 38.2

Fluoride 0.938 3.1345 80-12086.9mg/L2.90 0.170

Sulfate 1.25 60.180 80-12093.6mg/L116 59.6


Chloride 1.25 31.345 80-12096.2mg/L39.1 8.92

Fluoride 0.938 3.1345 80-12096.6mg/L3.03 <0.938

Sulfate 1.25 60.180 80-12095.4mg/L57.4 <1.25

Matrix Spike Dup (BDI0313-MSD1) Prepared: 09/17/2018 Analyzed: 09/18/2018Source: MDI0152-17

Chloride 1.25 31.345 2080-12094.6 0.0497mg/L67.9 38.2

Fluoride 0.938 3.1345 2080-12095.7 9.07mg/L3.17 0.170

Sulfate 1.25 60.180 2080-12093.6 0.00103mg/L116 59.6


Chloride 1.25 31.345 2080-12096.5 0.294mg/L39.2 8.92

Fluoride 0.938 3.1345 2080-12099.9 3.37mg/L3.13 <0.938

Sulfate 1.25 60.180 2080-12095.9 0.619mg/L57.7 <1.25



entirety.

Page 41 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



LCS (BDI0259-BS1) Prepared & Analyzed: 09/13/2018

pH 7.0000 90-110102pH Units7.11



pH 7.0000 90-110101pH Units7.10


Duplicate (BDI0259-DUP1) Prepared & Analyzed: 09/13/2018Source: MDI0145-01

pH 201.92pH Units7.72 7.87



pH 200.280pH Units7.14 7.16




pH 200.275pH Units7.26 7.28


Blank (BDI0261-BLK1) Prepared & Analyzed: 09/14/2018






entirety.

Page 42 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte









entirety.

Page 43 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDI0258 - EPA 200.2, EPA 3005



Cobalt 0.500 ug/L<0.500



Lead 0.500 ug/L<0.500





Barium 0.500 ug/L<0.500




Arsenic 0.500 100.00 85-11598.3ug/L98.3

Cadmium 0.100 100.00 85-11597.6ug/L97.6

Barium 0.500 100.00 85-11598.4ug/L98.4

Cobalt 0.500 100.00 85-11598.4ug/L98.4

Thallium 0.500 100.00 85-115100ug/L100

Selenium 0.500 100.00 85-11597.9ug/L97.9

Antimony 0.500 100.00 85-11597.7ug/L97.7

Lead 0.500 100.00 85-11599.4ug/L99.4

Molybdenum 0.500 100.00 85-11599.3ug/L99.3

Chromium 0.500 100.00 85-115101ug/L101


Beryllium 0.500 100.00 85-115100ug/L100



entirety.

Page 44 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Selenium 0.500 20ug/L<0.500 <0.500

Thallium 0.500 20ug/L<0.500 <0.500


Lead 0.500 20 M_D-RL29.0ug/L0.0583 0.0435

Molybdenum 0.500 2011.5ug/L0.340 0.303

Chromium 0.500 2014.5ug/L0.623 0.721

Cobalt 0.500 2012.3ug/L0.421 0.373

Barium 0.500 200.541ug/L342 344

Cadmium 0.100 20ug/L<0.100 <0.100

Arsenic 0.500 200.262ug/L53.4 53.3


Lead 0.500 205.44ug/L0.0580 0.0550

Barium 0.500 201.87ug/L47.8 46.9

Arsenic 0.500 201.85ug/L3.41 3.35

Chromium 0.500 206.76ug/L2.48 2.32

Cobalt 0.500 2011.8ug/L0.0993 0.0882

Antimony 0.500 207.80ug/L0.680 0.629

Selenium 0.500 207.61ug/L1.14 1.23

Thallium 0.500 2012.4ug/L0.0691 0.0611

Cadmium 0.100 20 M_D-RL22.7ug/L0.0308 0.0245

Molybdenum 0.500 203.60ug/L155 161




Beryllium 0.500 2013.8ug/L0.0220 0.0191



entirety.

Page 45 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.100 100.00 70-13090.4ug/L90.4 <0.100

Selenium 0.500 100.00 70-13091.9ug/L91.9 <0.500

Barium 0.500 100.00 70-13092.6ug/L437 344

Antimony 0.500 100.00 70-13095.8ug/L95.8 0.0324

Arsenic 0.500 100.00 70-13097.9ug/L151 53.3

Lead 0.500 100.00 70-13086.3ug/L86.3 0.0435

Thallium 0.500 100.00 70-13088.7ug/L88.7 <0.500

Cobalt 0.500 100.00 70-13099.5ug/L99.9 0.373

Molybdenum 0.500 100.00 70-13098.5ug/L98.8 0.303

Chromium 0.500 100.00 70-130103ug/L104 0.721


Barium 0.500 100.00 70-130101ug/L148 46.9

Selenium 0.500 100.00 70-13096.8ug/L98.1 1.23

Antimony 0.500 100.00 70-130101ug/L101 0.629

Arsenic 0.500 100.00 70-130102ug/L105 3.35

Lead 0.500 100.00 70-13088.9ug/L89.0 0.0550

Cadmium 0.100 100.00 70-13095.8ug/L95.8 0.0245

Thallium 0.500 100.00 70-13091.4ug/L91.5 0.0611

Chromium 0.500 100.00 70-13099.9ug/L102 2.32

Molybdenum 0.500 100.00 70-13098.6ug/L260 161

Cobalt 0.500 100.00 70-13097.6ug/L97.7 0.0882


Beryllium 0.500 100.00 70-13094.1ug/L94.1 0.0331


Beryllium 0.500 100.00 70-13093.2ug/L93.2 0.0191



entirety.

Page 46 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Molybdenum 0.500 100.00 2070-130103 4.12ug/L103 0.303

Lead 0.500 100.00 2070-13089.2 3.31ug/L89.2 0.0435

Cobalt 0.500 100.00 2070-130103 3.31ug/L103 0.373

Selenium 0.500 100.00 2070-13094.7 3.00ug/L94.7 <0.500

Thallium 0.500 100.00 2070-13092.1 3.81ug/L92.1 <0.500

Arsenic 0.500 100.00 2070-130101 1.81ug/L154 53.3

Chromium 0.500 100.00 2070-130107 3.54ug/L108 0.721

Barium 0.500 100.00 2070-130108 3.55ug/L452 344

Cadmium 0.100 100.00 2070-13096.2 6.26ug/L96.2 <0.100

Antimony 0.500 100.00 2070-13098.7 3.04ug/L98.8 0.0324


Thallium 0.500 100.00 2070-13092.1 0.726ug/L92.2 0.0611

Chromium 0.500 100.00 2070-130102 1.57ug/L104 2.32

Cobalt 0.500 100.00 2070-130100 2.62ug/L100 0.0882

Antimony 0.500 100.00 2070-130101 0.777ug/L102 0.629

Arsenic 0.500 100.00 2070-130104 2.06ug/L107 3.35

Cadmium 0.100 100.00 2070-13096.9 1.09ug/L96.9 0.0245

Molybdenum 0.500 100.00 2070-13097.3 0.536ug/L258 161

Barium 0.500 100.00 2070-130102 0.894ug/L149 46.9

Lead 0.500 100.00 2070-13088.8 0.202ug/L88.8 0.0550

Selenium 0.500 100.00 2070-13096.8 0.00195ug/L98.1 1.23


Beryllium 0.500 100.00 2070-13098.1 4.23ug/L98.2 0.0331


Beryllium 0.500 100.00 2070-13092.8 0.466ug/L92.8 0.0191



entirety.

Page 47 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte






Lithium 0.0150 mg/L<0.0150

Boron 0.0500 mg/L<0.0500




Boron 0.0500 1.0000 85-115103mg/L1.03

Calcium 1.25 100.00 85-115110mg/L110

Potassium 1.25 100.00 85-115109mg/L109

Magnesium 1.25 100.00 85-115108mg/L108

Sodium 1.25 100.00 85-115110mg/L110

Lithium 0.0150 1.0000 85-115105mg/L1.05


Sodium 1.25 202.72mg/L172 177

Magnesium 1.25 204.02mg/L73.5 76.5

Boron 0.0500 200.737mg/L14.7 14.8

Calcium 1.25 202.75mg/L318 327

Potassium 1.25 205.90mg/L3.59 3.81

Lithium 0.0150 203.29mg/L0.0401 0.0414


Sodium 1.25 202.60mg/L26.7 26.0

Magnesium 1.25 200.900mg/L82.4 83.2

Lithium 0.0150 200.986mg/L0.0180 0.0182

Potassium 1.25 205.07mg/L1.26 1.32

Calcium 1.25 202.54mg/L234 229

Boron 0.0500 201.50mg/L0.387 0.393



entirety.

Page 48 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Calcium 1.25 100.00 70-130115mg/L442 327

Magnesium 1.25 100.00 70-130112mg/L188 76.5

Sodium 1.25 100.00 70-130113mg/L290 177

Lithium 0.0150 1.0000 75-125110mg/L1.14 0.0414

Potassium 1.25 100.00 70-130115mg/L119 3.81

Boron 0.0500 1.0000 M_MS70-130139mg/L16.2 14.8


Potassium 1.25 100.00 70-130113mg/L114 1.32

Sodium 1.25 100.00 70-130110mg/L136 26.0

Magnesium 1.25 100.00 70-130110mg/L193 83.2

Lithium 0.0150 1.0000 75-125108mg/L1.10 0.0182

Boron 0.0500 1.0000 70-130103mg/L1.42 0.393

Calcium 1.25 100.00 70-130110mg/L338 229


Sodium 1.25 100.00 2070-130109 1.33mg/L286 177

Magnesium 1.25 100.00 2070-130108 1.83mg/L185 76.5

Lithium 0.0150 1.0000 2075-125108 0.973mg/L1.13 0.0414

Calcium 1.25 100.00 2070-130108 1.61mg/L435 327

Potassium 1.25 100.00 2070-130114 1.30mg/L118 3.81

Boron 0.0500 1.0000 2070-130122 1.02mg/L16.0 14.8


Potassium 1.25 100.00 2070-130122 7.33mg/L123 1.32

Magnesium 1.25 100.00 2070-130125 7.33mg/L208 83.2

Calcium 1.25 100.00 20 M_MS70-130135 7.11mg/L363 229

Sodium 1.25 100.00 2070-130119 6.76mg/L145 26.0

Boron 0.0500 1.0000 2070-130109 4.38mg/L1.49 0.393

Lithium 0.0150 1.0000 2075-125116 6.97mg/L1.18 0.0182



entirety.

Page 49 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDI0298 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11591.5ug/L2.75


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDI0298-MS1) Prepared & Analyzed: 09/17/2018Source: MDI0145-01

Mercury 0.200 3.0000 70-13090.1ug/L2.70 <0.200


Mercury 0.200 3.0000 70-13085.5ug/L2.57 <0.200

Matrix Spike Dup (BDI0298-MSD1) Prepared & Analyzed: 09/17/2018Source: MDI0145-01

Mercury 0.200 3.0000 2070-13086.6 3.96ug/L2.60 <0.200


Mercury 0.200 3.0000 2070-13087.5 2.31ug/L2.63 <0.200






entirety.

Page 50 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Mercury 0.200 3.0000 85-11590.2ug/L2.71


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13090.0ug/L2.70 <0.200


Mercury 0.200 3.0000 2070-13087.6 2.72ug/L2.63 <0.200



entirety.

Page 51 of 52



Reported:


250 Marquette Plaza

09/26/2018 13:57Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150









dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 52 of 52

#=CL#

October 17, 2018



RE:


18-01178, XcelEnergy-BlackDog

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on October 04, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 13

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 13

#=SS#

SAMPLE SUMMARY




30267075001 W 600A Water 10/01/18 13:15 10/04/18 09:20

30267075002 W 601A Water 10/01/18 14:00 10/04/18 09:20




Greensburg, PA 15601(724)850-5600

Page 3 of 13

#=SA#





30267075001 W 600A EPA 903.1 1 PASI-PAKAC



30267075002 W 601A EPA 903.1 1 PASI-PAKAC






Greensburg, PA 15601(724)850-5600

Page 4 of 13

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: October 17, 2018











Greensburg, PA 15601(724)850-5600

Page 5 of 13

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 6 of 13

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 7 of 13

#=ARR#







Radium-226 0.210 ± 0.357 (0.630)C:NA T:94%

pCi/L 10/16/18 20:23 13982-63-3EPA 903.1

Radium-228 1.09 ± 0.587 (1.09)C:72% T:77%

pCi/L 10/12/18 11:03 15262-20-1EPA 904.0





Radium-226 0.503 ± 0.496 (0.755)C:NA T:83%

pCi/L 10/16/18 20:23 13982-63-3EPA 903.1

Radium-228 0.129 ± 0.368 (0.823)C:78% T:82%

pCi/L 10/12/18 11:04 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 8 of 13

#=QCR#







315727EPA 903.1

EPA 903.1903.1 Radium-226

Associated Lab Samples: 30267075001, 30267075002




Matrix: Water

Analyzed

Radium-226 pCi/L 10/16/18 19:510.113 ± 0.351 (0.679) C:NA T:85%




Greensburg, PA 15601(724)850-5600

Page 9 of 13

#=QCR#







315728EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 10/12/18 11:030.473 ± 0.381 (0.757) C:73% T:81%




Greensburg, PA 15601(724)850-5600

Page 10 of 13

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 11 of 13


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

19 October 2018

cc:



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDJ0014-01 Water 10/02/2018 12:3010/01/2018 13:15W600A

MDJ0014-02 Water 10/02/2018 12:3010/01/2018 14:00W601A



entirety.

Page 1 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDJ0014-01 (Water) - Chain of Custody Number: 1845923

W600A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDJ0198 EPA 300.030.6 CRL10/9/18 14:4410/9/18 6:01

Fluoride 0.750 mg/L 1 BDJ0198 EPA 300.0< 0.750 CRL10/9/18 14:4410/9/18 6:01

Sulfate 10.0 mg/L 10 BDJ0198 EPA 300.01510 CRL10/9/18 14:2310/9/18 6:01

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDJ0049 SM 2320B153 CRL10/2/18 14:0710/2/18 12:53

pH pH Units 1 BDJ0049 SM 4500-H+ B6.57 CRLM_TTT 10/2/18 14:0710/2/18 12:53

Total Dissolved Solids 20.0 mg/L 1 BDJ0146 SM 2540C2410 HSD10/5/18 8:4110/5/18 8:41


Arsenic 0.500 ug/L 1 BDJ0201 EPA 200.851.0 CRL10/13/18 10:0410/9/18 7:42

Barium 0.500 ug/L 1 BDJ0201 EPA 200.823.9 CRL10/13/18 10:0410/9/18 7:42

Beryllium 0.500 ug/L 1 BDJ0201 EPA 200.80.595 CRL10/13/18 10:0410/9/18 7:42

Cadmium 0.100 ug/L 1 BDJ0201 EPA 200.80.181 CRL10/13/18 10:0410/9/18 7:42

Cobalt 0.500 ug/L 1 BDJ0201 EPA 200.840.1 CRL10/13/18 10:0410/9/18 7:42

Chromium 0.500 ug/L 1 BDJ0201 EPA 200.82.45 CRL10/13/18 10:0410/9/18 7:42

Molybdenum 0.500 ug/L 1 BDJ0201 EPA 200.821.5 CRL10/13/18 10:0410/9/18 7:42

Lead 0.500 ug/L 1 BDJ0201 EPA 200.8< 0.500 CRL10/13/18 10:0410/9/18 7:42

Antimony 0.500 ug/L 1 BDJ0201 EPA 200.8< 0.500 CRL10/13/18 10:0410/9/18 7:42

Selenium 0.500 ug/L 1 BDJ0201 EPA 200.8< 0.500 CRL10/13/18 10:0410/9/18 7:42

Thallium 0.500 ug/L 1 BDJ0201 EPA 200.80.790 CRL10/13/18 10:0410/9/18 7:42

Total Metals by ICP

Boron 0.0500 mg/L 1 BDJ0200 EPA 200.74.26 HRD10/17/18 13:5910/9/18 7:38

Calcium 1.25 mg/L 1 BDJ0200 EPA 200.7518 HRD10/17/18 13:5710/9/18 7:38

Potassium 1.25 mg/L 1 BDJ0200 EPA 200.710.8 HRD10/17/18 13:5810/9/18 7:38

Lithium 0.0150 mg/L 1 BDJ0200 EPA 200.70.0839 HRD10/17/18 13:5810/9/18 7:38

Magnesium 1.25 mg/L 1 BDJ0200 EPA 200.739.0 HRD10/17/18 13:5810/9/18 7:38

Sodium 1.25 mg/L 1 BDJ0200 EPA 200.748.8 HRD10/17/18 13:5710/9/18 7:38



entirety.

Page 2 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDJ0079 EPA 245.1, 7470A< 0.200 HRD10/3/18 15:2910/3/18 9:07



entirety.

Page 3 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDJ0198 EPA 300.0148 CRL10/9/18 17:0710/9/18 6:01



Wet Chemistry







Beryllium 0.500 ug/L 1 BDJ0201 EPA 200.8< 0.500 CRL10/13/18 10:0810/9/18 7:42

Cadmium 1.00 ug/L 10 BDJ0201 EPA 200.8< 1.00 CRL10/13/18 10:3210/9/18 7:42

Cobalt 5.00 ug/L 10 BDJ0201 EPA 200.8< 5.00 CRL10/13/18 10:3210/9/18 7:42

Chromium 5.00 ug/L 10 BDJ0201 EPA 200.8< 5.00 CRL10/13/18 10:3210/9/18 7:42

Molybdenum 0.500 ug/L 1 BDJ0201 EPA 200.8243 CRL10/13/18 10:0810/9/18 7:42


Antimony 0.500 ug/L 1 BDJ0201 EPA 200.80.878 CRL10/13/18 10:0810/9/18 7:42

Selenium 0.500 ug/L 1 BDJ0201 EPA 200.831.1 CRL10/13/18 10:0810/9/18 7:42

Thallium 0.500 ug/L 1 BDJ0201 EPA 200.8< 0.500 CRL10/13/18 10:0810/9/18 7:42

Total Metals by ICP





Magnesium 1.25 mg/L 1 BDJ0200 EPA 200.7< 1.25 HRD10/17/18 14:0310/9/18 7:38

Sodium 1.25 mg/L 1 BDJ0200 EPA 200.7290 HRD10/17/18 14:0310/9/18 7:38



entirety.

Page 4 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDJ0114 EPA 245.1, 7470A< 0.200 HRD10/4/18 10:3510/4/18 5:47



entirety.

Page 5 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDJ0198 - Wet Prep

Blank (BDJ0198-BLK1) Prepared & Analyzed: 10/09/2018








LCS (BDJ0198-BS1) Prepared & Analyzed: 10/09/2018

Chloride 1.00 25.076 90-11098.1mg/L24.6

Fluoride 0.750 2.5076 90-110107mg/L2.68

Sulfate 1.00 48.144 90-11099.3mg/L47.8


Chloride 1.00 25.076 90-11095.9mg/L24.0

Fluoride 0.750 2.5076 90-110108mg/L2.70

Sulfate 1.00 48.144 90-11096.6mg/L46.5


Chloride 1.00 25.076 90-11095.3mg/L23.9

Fluoride 0.750 2.5076 90-110103mg/L2.59

Sulfate 1.00 48.144 90-11096.3mg/L46.3

Duplicate (BDJ0198-DUP1) Prepared & Analyzed: 10/09/2018Source: MDJ0037-01

Chloride 1.00 201.65mg/L13.7 13.9

Fluoride 0.750 201.71mg/L0.118 0.116

Sulfate 1.00 200.818mg/L44.3 44.7



entirety.

Page 6 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.239mg/L28.0 28.0

Fluoride 0.750 203.01mg/L0.229 0.236

Sulfate 1.00 200.298mg/L41.6 41.5

Matrix Spike (BDJ0198-MS1) Prepared & Analyzed: 10/09/2018Source: MDJ0037-01

Chloride 1.25 31.345 80-12096.5mg/L44.2 13.9

Fluoride 0.938 3.1345 80-120107mg/L3.35 <0.938

Sulfate 1.25 60.180 80-12097.1mg/L103 44.7


Chloride 1.25 31.345 80-12097.9mg/L58.6 28.0

Fluoride 0.938 3.1345 80-120108mg/L3.62 0.236

Sulfate 1.25 60.180 80-12098.8mg/L101 41.5

Matrix Spike Dup (BDJ0198-MSD1) Prepared & Analyzed: 10/09/2018Source: MDJ0037-01

Chloride 1.25 31.345 2080-12097.3 0.578mg/L44.4 13.9

Fluoride 0.938 3.1345 2080-120111 3.37mg/L3.47 <0.938

Sulfate 1.25 60.180 2080-12098.1 0.571mg/L104 44.7


Chloride 1.25 31.345 2080-12097.5 0.207mg/L58.5 28.0

Fluoride 0.938 3.1345 2080-120109 0.997mg/L3.65 0.236

Sulfate 1.25 60.180 2080-12098.3 0.264mg/L101 41.5



entirety.

Page 7 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




pH 7.0000 90-110101pH Units7.08




pH 7.0000 90-110102pH Units7.13

LCS (BDJ0049-BS3) Prepared: 10/02/2018 Analyzed: 10/03/2018



pH 200.785pH Units7.61 7.67









entirety.

Page 8 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDJ0201 - EPA 200.2, EPA 3005

Blank (BDJ0201-BLK1) Prepared: 10/09/2018 Analyzed: 10/13/2018



Cobalt 0.500 ug/L<0.500






Barium 0.500 ug/L<0.500


Lead 0.500 ug/L<0.500


Thallium 0.500 100.00 85-11596.0ug/L96.0

Selenium 0.500 100.00 85-115101ug/L101

Molybdenum 0.500 100.00 85-115102ug/L102

Cobalt 0.500 100.00 85-115104ug/L104

Arsenic 0.500 100.00 85-115101ug/L101

Chromium 0.500 100.00 85-115104ug/L104

Beryllium 0.500 100.00 85-11599.3ug/L99.3

Cadmium 0.100 100.00 85-115105ug/L105

Barium 0.500 100.00 85-11599.5ug/L99.5

Lead 0.500 100.00 85-11597.2ug/L97.2

Antimony 0.500 100.00 85-11597.8ug/L97.8

Duplicate (BDJ0201-DUP1) Prepared: 10/09/2018 Analyzed: 10/13/2018Source: MDJ0014-01

Lead 0.500 201.83ug/L0.0959 0.0941

Arsenic 0.500 206.13ug/L54.2 51.0

Barium 0.500 203.55ug/L24.7 23.9

Thallium 0.500 200.0515ug/L0.789 0.790

Selenium 0.500 20ug/L<0.500 <0.500


Molybdenum 0.500 203.20ug/L22.2 21.5

Chromium 0.500 207.18ug/L2.64 2.45

Cobalt 0.500 2011.0ug/L44.8 40.1

Cadmium 0.100 2011.6ug/L0.161 0.181

Beryllium 0.500 203.32ug/L0.615 0.595



entirety.

Page 9 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike (BDJ0201-MS1) Prepared: 10/09/2018 Analyzed: 10/13/2018Source: MDJ0014-01

Cobalt 0.500 100.00 70-130101ug/L141 40.1

Molybdenum 0.500 100.00 70-13099.6ug/L121 21.5

Cadmium 0.100 100.00 70-13096.2ug/L96.3 0.181

Lead 0.500 100.00 70-13084.3ug/L84.4 0.0941

Antimony 0.500 100.00 70-13095.6ug/L95.7 0.110

Barium 0.500 100.00 70-130106ug/L130 23.9

Chromium 0.500 100.00 70-13098.6ug/L101 2.45

Arsenic 0.500 100.00 70-130101ug/L152 51.0

Beryllium 0.500 100.00 70-13085.4ug/L85.9 0.595

Thallium 0.500 100.00 70-13088.4ug/L89.2 0.790

Selenium 0.500 100.00 70-130100ug/L100 <0.500

Matrix Spike Dup (BDJ0201-MSD1) Prepared: 10/09/2018 Analyzed: 10/13/2018Source: MDJ0014-01

Antimony 0.500 100.00 2070-13099.2 3.73ug/L99.3 0.110

Lead 0.500 100.00 2070-13086.7 2.87ug/L86.8 0.0941

Molybdenum 0.500 100.00 2070-130100 0.382ug/L122 21.5

Selenium 0.500 100.00 2070-13099.6 0.360ug/L99.6 <0.500

Chromium 0.500 100.00 2070-13095.5 3.09ug/L98.0 2.45

Cobalt 0.500 100.00 2070-13095.4 3.96ug/L136 40.1

Cadmium 0.100 100.00 2070-13097.7 1.58ug/L97.9 0.181

Beryllium 0.500 100.00 2070-13085.0 0.460ug/L85.6 0.595

Barium 0.500 100.00 2070-130107 1.04ug/L131 23.9

Arsenic 0.500 100.00 2070-130104 1.99ug/L155 51.0

Thallium 0.500 100.00 2070-13091.6 3.56ug/L92.4 0.790



entirety.

Page 10 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Boron 0.0500 mg/L<0.0500




Lithium 0.0150 mg/L<0.0150



Sodium 1.25 100.00 85-115104mg/L104

Lithium 0.0150 1.0000 85-11599.1mg/L0.991

Magnesium 1.25 100.00 85-115105mg/L105

Boron 0.0500 1.0000 85-115102mg/L1.02

Calcium 1.25 100.00 85-115104mg/L104

Potassium 1.25 100.00 85-115102mg/L102


Lithium 0.0150 204.02mg/L0.0291 0.0279

Magnesium 1.25 205.47mg/L34.7 32.8

Potassium 1.25 206.11mg/L4.23 3.98

Sodium 1.25 204.41mg/L12.0 11.5

Calcium 1.25 204.65mg/L90.9 86.7

Boron 0.0500 2019.9mg/L0.0855 0.104


Sodium 1.25 200.127mg/L12.4 12.4

Calcium 1.25 200.0703mg/L109 109

Lithium 0.0150 200.738mg/L0.0404 0.0407

Boron 0.0500 2010.4mg/L0.0846 0.0939

Magnesium 1.25 200.591mg/L42.3 42.0

Potassium 1.25 201.32mg/L4.54 4.48



entirety.

Page 11 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Sodium 1.25 100.00 70-130105mg/L117 11.5

Lithium 0.0150 1.0000 75-125100mg/L1.03 0.0279

Magnesium 1.25 100.00 70-130109mg/L142 32.8

Calcium 1.25 100.00 70-130111mg/L198 86.7

Potassium 1.25 100.00 70-130104mg/L108 3.98

Boron 0.0500 1.0000 70-130101mg/L1.11 0.104


Lithium 0.0150 1.0000 75-12599.5mg/L1.04 0.0407

Sodium 1.25 100.00 70-130104mg/L116 12.4

Calcium 1.25 100.00 70-130108mg/L217 109

Magnesium 1.25 100.00 70-130107mg/L149 42.0

Boron 0.0500 1.0000 70-130103mg/L1.13 0.0939

Potassium 1.25 100.00 70-130103mg/L108 4.48


Lithium 0.0150 1.0000 2075-125101 0.770mg/L1.04 0.0279

Magnesium 1.25 100.00 2070-130109 0.395mg/L142 32.8

Sodium 1.25 100.00 2070-130106 0.538mg/L118 11.5

Boron 0.0500 1.0000 2070-130104 3.02mg/L1.15 0.104

Calcium 1.25 100.00 2070-130112 0.497mg/L199 86.7

Potassium 1.25 100.00 2070-130105 0.533mg/L109 3.98


Magnesium 1.25 100.00 2070-130108 0.347mg/L150 42.0

Boron 0.0500 1.0000 2070-130104 0.850mg/L1.14 0.0939

Calcium 1.25 100.00 2070-130108 0.309mg/L217 109

Potassium 1.25 100.00 2070-130103 0.381mg/L107 4.48

Sodium 1.25 100.00 2070-130104 0.287mg/L116 12.4

Lithium 0.0150 1.0000 2075-12599.2 0.363mg/L1.03 0.0407



entirety.

Page 12 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDJ0079 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11591.5ug/L2.74

Duplicate (BDJ0079-DUP1) Prepared & Analyzed: 10/03/2018Source: MDI0346-07

Mercury 0.200 20ug/L<0.200 <0.200

Duplicate (BDJ0079-DUP2) Prepared & Analyzed: 10/03/2018Source: MDI0346-08

Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDJ0079-MS1) Prepared & Analyzed: 10/03/2018Source: MDI0346-07

Mercury 0.200 3.0000 70-13094.2ug/L2.82 <0.200

Matrix Spike (BDJ0079-MS2) Prepared & Analyzed: 10/03/2018Source: MDI0346-08

Mercury 0.200 3.0000 70-13090.2ug/L2.71 <0.200

Matrix Spike Dup (BDJ0079-MSD1) Prepared & Analyzed: 10/03/2018Source: MDI0346-07

Mercury 0.200 3.0000 2070-13095.0 0.860ug/L2.85 <0.200

Matrix Spike Dup (BDJ0079-MSD2) Prepared & Analyzed: 10/03/2018Source: MDI0346-08

Mercury 0.200 3.0000 2070-13093.8 3.98ug/L2.82 <0.200






entirety.

Page 13 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Mercury 0.200 3.0000 85-11587.3ug/L2.62


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0000 70-13089.6ug/L2.69 <0.200


Mercury 0.200 3.0000 70-13086.8ug/L2.60 <0.200


Mercury 0.200 3.0000 2070-13090.5 1.03ug/L2.72 <0.200


Mercury 0.200 3.0000 2070-13089.7 3.25ug/L2.69 <0.200



entirety.

Page 14 of 15



Reported:


250 Marquette Plaza

10/19/2018 07:47Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150







dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 15 of 15

#=CL#

November 13, 2018



RE:


18-01305, Xcel Energy-BlackDog

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on October 29, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 19

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 19

#=SS#

SAMPLE SUMMARY





30269834002 W510A Water 10/23/18 09:30 10/29/18 09:35

30269834003 W511A Water 10/23/18 10:15 10/29/18 09:35

30269834004 W14A Water 10/23/18 11:10 10/29/18 09:35

30269834005 W7A Water 10/23/18 11:50 10/29/18 09:35

30269834006 W602A Water 10/23/18 12:40 10/29/18 09:35

30269834007 W502A Water 10/23/18 13:40 10/29/18 09:35

30269834008 W502B Water 10/23/18 14:15 10/29/18 09:35

30269834009 W504A Water 10/23/18 15:00 10/29/18 09:35

30269834010 W504B Water 10/23/18 15:35 10/29/18 09:35

30269834011 W514A Water 10/24/18 09:10 10/29/18 09:35

30269834012 W514B Water 10/24/18 09:50 10/29/18 09:35

30269834013 W506A Water 10/24/18 10:50 10/29/18 09:35

30269834014 Duplicate Water 10/24/18 10:50 10/29/18 09:35

30269834015 W603A Water 10/24/18 12:00 10/29/18 09:35

30269834016 W604A Water 10/24/18 12:50 10/29/18 09:35

30269834017 W605A Water 10/24/18 13:40 10/29/18 09:35

30269834018 W601A Water 10/24/18 14:40 10/29/18 09:35

30269834019 W600A Water 10/24/18 15:30 10/29/18 09:35




Greensburg, PA 15601(724)850-5600

Page 3 of 19

#=SA#








30269834002 W510A EPA 903.1 1 PASI-PAMK1



30269834003 W511A EPA 903.1 1 PASI-PAMK1



30269834004 W14A EPA 903.1 1 PASI-PAMK1



30269834005 W7A EPA 903.1 1 PASI-PAMK1



30269834006 W602A EPA 903.1 1 PASI-PAMK1



30269834007 W502A EPA 903.1 1 PASI-PAMK1



30269834008 W502B EPA 903.1 1 PASI-PAMK1



30269834009 W504A EPA 903.1 1 PASI-PAMK1



30269834010 W504B EPA 903.1 1 PASI-PAMK1



30269834011 W514A EPA 903.1 1 PASI-PAMK1



30269834012 W514B EPA 903.1 1 PASI-PAMK1



30269834013 W506A EPA 903.1 1 PASI-PAMK1




Greensburg, PA 15601(724)850-5600

Page 4 of 19

#=SA#










30269834015 W603A EPA 903.1 1 PASI-PAMK1



30269834016 W604A EPA 903.1 1 PASI-PAMK1



30269834017 W605A EPA 903.1 1 PASI-PAMK1



30269834018 W601A EPA 903.1 1 PASI-PAMK1



30269834019 W600A EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 5 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: November 13, 2018











Greensburg, PA 15601(724)850-5600

Page 6 of 19

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 19

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 19

#=ARR#







Radium-226 0.242 ± 0.369 (0.594)C:NA T:89%

pCi/L 11/09/18 20:38 13982-63-3EPA 903.1

Radium-228 0.210 ± 0.309 (0.664)C:79% T:85%

pCi/L 11/07/18 11:57 15262-20-1EPA 904.0



Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No. Qual

• Upon receipt at the laboratory, 2.5 mls of nitric acid were added to the sample to meet the sample preservation requirement of pH<2 for radiochemistry analysis.

Comments:

Method


Radium-226 0.785 ± 0.616 (0.857)C:NA T:95%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1

Radium-228 0.560 ± 0.384 (0.733)C:76% T:87%

pCi/L 11/07/18 11:57 15262-20-1EPA 904.0





Radium-226 0.586 ± 0.816 (1.38)C:NA T:75%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1

Radium-228 0.179 ± 0.329 (0.722)C:73% T:78%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 -0.079 ± 0.464 (1.03)C:NA T:89%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1

Radium-228 0.449 ± 0.324 (0.618)C:71% T:90%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 0.304 ± 0.517 (0.913)C:NA T:92%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1




Greensburg, PA 15601(724)850-5600

Page 9 of 19

#=ARR#







Radium-228 0.427 ± 0.384 (0.777)C:73% T:81%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 0.300 ± 0.551 (0.982)C:NA T:92%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1

Radium-228 0.385 ± 0.345 (0.696)C:74% T:85%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 0.609 ± 0.707 (1.14)C:NA T:77%

pCi/L 11/09/18 20:54 13982-63-3EPA 903.1

Radium-228 0.588 ± 0.358 (0.640)C:73% T:78%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 0.818 ± 0.723 (1.07)C:NA T:91%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.395 ± 0.336 (0.671)C:80% T:83%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 0.663 ± 0.693 (1.09)C:NA T:86%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.441 ± 0.357 (0.707)C:77% T:84%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 19

#=ARR#







Radium-226 0.650 ± 0.680 (1.07)C:NA T:88%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.764 ± 0.343 (0.538)C:77% T:90%

pCi/L 11/07/18 11:58 15262-20-1EPA 904.0





Radium-226 -0.087 ± 0.453 (1.05)C:NA T:79%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.392 ± 0.368 (0.748)C:77% T:76%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 1.36 ± 0.800 (0.961)C:NA T:92%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.0688 ± 0.310 (0.707)C:79% T:85%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 0.560 ± 0.650 (1.05)C:NA T:89%

pCi/L 11/09/18 21:09 13982-63-3EPA 903.1

Radium-228 0.543 ± 0.344 (0.639)C:79% T:81%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.546 (1.13)C:NA T:90%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.511 ± 0.329 (0.607)C:79% T:81%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 19

#=ARR#











Radium-226 0.230 ± 0.713 (1.38)C:NA T:64%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.154 ± 0.349 (0.775)C:78% T:74%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 0.000 ± 0.480 (1.01)C:NA T:93%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.0665 ± 0.314 (0.719)C:80% T:75%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 0.630 ± 0.582 (0.848)C:NA T:88%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.867 ± 0.358 (0.529)C:77% T:88%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Radium-226 0.698 ± 0.645 (0.939)C:NA T:83%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.452 ± 0.359 (0.707)C:74% T:84%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 12 of 19

#=ARR#







Radium-226 0.373 ± 0.449 (0.686)C:NA T:74%

pCi/L 11/09/18 21:24 13982-63-3EPA 903.1

Radium-228 0.423 ± 0.381 (0.770)C:79% T:73%

pCi/L 11/07/18 15:25 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 13 of 19

#=QCR#







318789EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 11/09/18 20:380.288 ± 0.448 (0.776) C:NA T:94%




Greensburg, PA 15601(724)850-5600

Page 14 of 19

#=QCR#







318798EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 11/07/18 11:57-0.0498 ± 0.295 (0.700) C:82% T:88%




Greensburg, PA 15601(724)850-5600

Page 15 of 19

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 16 of 19


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

09 November 2018

cc:



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDJ0313-01 Water 10/25/2018 10:5510/23/2018 8:45Field Blank

MDJ0313-02 Water 10/25/2018 10:5510/23/2018 9:30W510A

MDJ0313-03 Water 10/25/2018 10:5510/23/2018 10:15W511A

MDJ0313-04 Water 10/25/2018 10:5510/23/2018 11:10W14A

MDJ0313-05 Water 10/25/2018 10:5510/23/2018 11:50W7A

MDJ0313-06 Water 10/25/2018 10:5510/23/2018 12:40W602A

MDJ0313-07 Water 10/25/2018 10:5510/23/2018 13:40W502A

MDJ0313-08 Water 10/25/2018 10:5510/23/2018 14:15W502B

MDJ0313-09 Water 10/25/2018 10:5510/23/2018 15:00W504A

MDJ0313-10 Water 10/25/2018 10:5510/23/2018 15:35W504B

MDJ0313-11 Water 10/25/2018 10:5510/24/2018 9:10W514A

MDJ0313-12 Water 10/25/2018 10:5510/24/2018 9:50W514B

MDJ0313-13 Water 10/25/2018 10:5510/24/2018 10:50W506A

MDJ0313-14 Water 10/25/2018 10:5510/24/2018 10:50Duplicate

MDJ0313-15 Water 10/25/2018 10:5510/24/2018 12:00W603A

MDJ0313-16 Water 10/25/2018 10:5510/24/2018 12:50W604A

MDJ0313-17 Water 10/25/2018 10:5510/24/2018 13:40W605A

MDJ0313-18 Water 10/25/2018 10:5510/24/2018 14:40W601A

MDJ0313-19 Water 10/25/2018 10:5510/24/2018 15:30W600A



entirety.

Page 1 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDJ0313-01 (Water) - Chain of Custody Number: 1845916/1845915

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDJ0730 EPA 300.0< 1.00 CRL10/29/18 14:5210/29/18 11:38


Sulfate 1.00 mg/L 1 BDJ0730 EPA 300.0< 1.00 CRL10/29/18 14:5210/29/18 11:38

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDJ0660 SM 2320B< 10.0 CRL10/25/18 14:0110/25/18 13:03


Total Dissolved Solids 20.0 mg/L 1 BDJ0689 SM 2540C< 20.0 HSD10/26/18 9:0110/26/18 9:01


Arsenic 0.500 ug/L 1 BDJ0659 EPA 200.8< 0.500 CRL10/30/18 8:3210/25/18 12:52

Barium 1.00 ug/L 1 BDJ0659 EPA 200.8< 1.00 CRL10/30/18 8:3210/25/18 12:52





Molybdenum 0.500 ug/L 1 BDJ0659 EPA 200.8< 0.500 CRL10/30/18 8:3210/25/18 12:52





Total Metals by ICP

Boron 0.0500 mg/L 1 BDJ0658 EPA 200.7< 0.0500 HRD10/30/18 12:3410/25/18 12:50

Calcium 1.25 mg/L 1 BDJ0658 EPA 200.7< 1.25 HRD10/30/18 12:3310/25/18 12:50

Potassium 1.25 mg/L 1 BDJ0658 EPA 200.7< 1.25 HRD10/30/18 12:3310/25/18 12:50

Lithium 0.0150 mg/L 1 BDJ0658 EPA 200.7< 0.0150 HRD10/30/18 12:3310/25/18 12:50


Sodium 1.25 mg/L 1 BDJ0658 EPA 200.7< 1.25 HRD10/30/18 12:3310/25/18 12:50



entirety.

Page 2 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L 1 BDK0160 EPA 245.1, 7470A< 0.200 HRD11/7/18 15:2411/7/18 8:55



entirety.

Page 3 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte




Sulfate 1.00 mg/L 1 BDJ0730 EPA 300.022.2 CRL10/29/18 15:1210/29/18 11:38

Wet Chemistry






Barium 1.00 ug/L 1 BDJ0659 EPA 200.8391 CRL10/30/18 8:3610/25/18 12:52










Total Metals by ICP









entirety.

Page 4 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W510A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 6 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W511A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 8 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W14A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 10 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 12 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 14 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L 1 BDJ0658 EPA 200.7113 HRD10/30/18 13:1910/25/18 12:50




entirety.

Page 16 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 17 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 18 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 20 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 21 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP


Calcium 1.25 mg/L 1 BDJ0658 EPA 200.786.4 HRD10/30/18 13:3410/25/18 12:50







entirety.

Page 22 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514A

Qualifier

Analyte

Mercury




entirety.

Page 23 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 24 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W514B

Qualifier

Analyte

Mercury




entirety.

Page 25 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 26 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 29 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDJ0660 SM 2320B51.0 CRL10/25/18 16:0410/25/18 13:03















Total Metals by ICP









entirety.

Page 30 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 31 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 32 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 33 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 34 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 35 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 36 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 37 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L 1 BDJ0659 EPA 200.80.543 CRL10/30/18 9:5810/25/18 12:52









Total Metals by ICP









entirety.

Page 38 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 39 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte












Chloride 1.00 25.000 90-11098.3mg/L24.6

Fluoride 0.750 2.5000 90-110107mg/L2.67

Sulfate 1.00 48.000 90-11099.1mg/L47.6


Chloride 1.00 25.000 90-11099.5mg/L24.9

Fluoride 0.750 2.5000 90-110109mg/L2.72

Sulfate 1.00 48.000 90-110100mg/L48.2


Chloride 1.00 25.000 90-110100mg/L25.0

Fluoride 0.750 2.5000 90-110104mg/L2.61

Sulfate 1.00 48.000 90-110100mg/L48.2


Chloride 1.00 201.84mg/L35.9 36.6

Fluoride 0.750 209.05mg/L0.190 0.208

Sulfate 1.00 201.68mg/L88.1 89.6



entirety.

Page 40 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.0727mg/L11.0 11.0

Fluoride 0.750 200.519mg/L0.192 0.193

Sulfate 1.00 200.322mg/L6.85 6.83


Chloride 1.25 31.250 80-12094.9mg/L66.3 36.6

Fluoride 0.938 3.1250 80-12091.1mg/L3.05 0.208

Sulfate 1.25 60.000 80-12094.4mg/L146 89.6


Chloride 1.25 31.250 80-12099.0mg/L41.9 11.0

Fluoride 0.938 3.1250 80-120105mg/L3.46 0.193

Sulfate 1.25 60.000 80-12099.8mg/L66.7 6.83


Chloride 1.25 31.250 2080-12096.2 0.574mg/L66.6 36.6

Fluoride 0.938 3.1250 2080-120106 14.4mg/L3.53 0.208

Sulfate 1.25 60.000 2080-12095.7 0.517mg/L147 89.6


Chloride 1.25 31.250 2080-12099.7 0.535mg/L42.2 11.0

Fluoride 0.938 3.1250 2080-120104 0.253mg/L3.45 0.193

Sulfate 1.25 60.000 2080-120100 0.443mg/L67.0 6.83



entirety.

Page 41 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte





pH 7.0000 90-110101pH Units7.08



pH 7.0000 90-110101pH Units7.07



pH 200.397pH Units7.55 7.58


pH 200.132pH Units7.57 7.58












entirety.

Page 42 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte







entirety.

Page 43 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte








Lead 0.500 ug/L<0.500



Cobalt 0.500 ug/L<0.500



Barium 1.00 ug/L<1.00


Molybdenum 0.500 100.00 85-11593.6ug/L93.6

Cadmium 0.100 100.00 85-11595.7ug/L95.7

Lead 0.500 100.00 85-11597.2ug/L97.2

Beryllium 0.500 100.00 85-115100ug/L100

Barium 1.00 100.00 85-115105ug/L105

Arsenic 0.500 100.00 85-11594.5ug/L94.5

Selenium 0.500 100.00 85-115101ug/L101

Chromium 0.500 100.00 85-115101ug/L101

Thallium 0.500 100.00 85-11597.5ug/L97.5

Antimony 0.500 100.00 85-11597.9ug/L97.9

Cobalt 0.500 100.00 85-11596.1ug/L96.1


Barium 1.00 206.00ug/L45.8 48.7

Selenium 0.500 200.637ug/L0.350 0.347

Thallium 0.500 20ug/L0.0660 <0.500


Arsenic 0.500 202.39ug/L1.92 1.96

Beryllium 0.500 20ug/L0.109 <0.500

Cadmium 0.100 207.21ug/L0.0486 0.0452

Chromium 0.500 207.44ug/L0.258 0.278

Lead 0.500 20 M_D-RL92.3ug/L0.0487 0.0180

Molybdenum 0.500 202.25ug/L65.6 67.1

Cobalt 0.500 205.72ug/L0.220 0.208



entirety.

Page 44 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Selenium 0.500 201.44ug/L0.241 0.245

Thallium 0.500 20ug/L<0.500 <0.500

Arsenic 0.500 207.70ug/L0.825 0.764

Beryllium 0.500 20ug/L0.0103 <0.500

Cadmium 0.100 20 M_D-RL36.5ug/L0.0380 0.0550

Cobalt 0.500 201.40ug/L0.273 0.277

Lead 0.500 2014.5ug/L0.0440 0.0380

Chromium 0.500 201.30ug/L0.615 0.607

Molybdenum 0.500 203.48ug/L23.2 24.0

Antimony 0.500 2015.7ug/L0.152 0.130

Barium 1.00 203.90ug/L141 135


Barium 1.00 100.00 70-130105ug/L154 48.7

Antimony 0.500 100.00 70-13097.0ug/L97.2 0.151

Beryllium 0.500 100.00 70-13095.9ug/L95.9 <0.500

Selenium 0.500 100.00 70-13098.6ug/L98.9 0.347

Cobalt 0.500 100.00 70-130102ug/L102 0.208

Cadmium 0.100 100.00 70-13094.1ug/L94.1 0.0452

Molybdenum 0.500 100.00 70-13094.3ug/L161 67.1

Lead 0.500 100.00 70-13085.3ug/L85.4 0.0180

Chromium 0.500 100.00 70-130105ug/L105 0.278

Thallium 0.500 100.00 70-13088.2ug/L88.2 <0.500

Arsenic 0.500 100.00 70-13099.2ug/L101 1.96


Barium 1.00 100.00 70-130105ug/L240 135

Arsenic 0.500 100.00 70-130104ug/L105 0.764

Thallium 0.500 100.00 70-13091.0ug/L91.0 <0.500

Chromium 0.500 100.00 70-130106ug/L107 0.607

Selenium 0.500 100.00 70-130102ug/L102 0.245

Cobalt 0.500 100.00 70-130102ug/L102 0.277

Antimony 0.500 100.00 70-13095.0ug/L95.1 0.130

Beryllium 0.500 100.00 70-13089.9ug/L89.9 <0.500

Molybdenum 0.500 100.00 70-130100ug/L124 24.0

Lead 0.500 100.00 70-13087.8ug/L87.9 0.0380

Cadmium 0.100 100.00 70-13093.7ug/L93.7 0.0550



entirety.

Page 45 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.100 100.00 2070-13095.3 1.33ug/L95.4 0.0452

Chromium 0.500 100.00 2070-130104 0.764ug/L104 0.278

Thallium 0.500 100.00 2070-13086.3 2.18ug/L86.3 <0.500

Barium 1.00 100.00 2070-130101 2.90ug/L150 48.7

Cobalt 0.500 100.00 2070-130102 0.443ug/L102 0.208

Selenium 0.500 100.00 2070-13099.1 0.528ug/L99.4 0.347

Molybdenum 0.500 100.00 2070-130103 5.48ug/L171 67.1

Arsenic 0.500 100.00 2070-130101 2.03ug/L103 1.96

Antimony 0.500 100.00 2070-13097.8 0.797ug/L97.9 0.151

Lead 0.500 100.00 2070-13083.9 1.74ug/L83.9 0.0180

Beryllium 0.500 100.00 2070-13094.8 1.09ug/L94.8 <0.500


Chromium 0.500 100.00 2070-130105 1.33ug/L105 0.607

Barium 1.00 100.00 2070-130104 0.236ug/L239 135

Antimony 0.500 100.00 2070-13093.1 2.03ug/L93.2 0.130

Thallium 0.500 100.00 2070-13086.8 4.71ug/L86.8 <0.500

Selenium 0.500 100.00 2070-13098.3 3.76ug/L98.5 0.245

Cadmium 0.100 100.00 2070-13093.7 0.0170ug/L93.7 0.0550

Cobalt 0.500 100.00 2070-130102 0.0432ug/L102 0.277

Beryllium 0.500 100.00 2070-13092.6 2.90ug/L92.6 <0.500

Lead 0.500 100.00 2070-13084.1 4.35ug/L84.1 0.0380

Molybdenum 0.500 100.00 2070-130100 0.184ug/L124 24.0

Arsenic 0.500 100.00 2070-130102 2.03ug/L103 0.764



entirety.

Page 46 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte







Boron 0.0500 mg/L<0.0500


Lithium 0.0150 mg/L<0.0150


Calcium 1.25 100.00 85-115102mg/L102

Boron 0.0500 1.0000 85-11599.1mg/L0.991

Sodium 1.25 100.00 85-115102mg/L102

Lithium 0.0150 1.0000 85-11599.6mg/L0.996

Magnesium 1.25 100.00 85-115103mg/L103

Potassium 1.25 100.00 85-115100mg/L100


Magnesium 1.25 200.270mg/L84.3 84.1

Calcium 1.25 200.414mg/L304 305

Sodium 1.25 200.455mg/L77.4 77.8

Boron 0.0500 200.675mg/L6.48 6.52

Lithium 0.0150 20 M_D-RL36.1mg/L0.0127 0.00883

Potassium 1.25 202.01mg/L2.95 2.89


Magnesium 1.25 201.07mg/L34.5 34.1

Calcium 1.25 200.932mg/L144 142

Boron 0.0500 201.38mg/L6.98 6.89

Potassium 1.25 201.11mg/L12.9 12.8

Lithium 0.0150 202.77mg/L0.0442 0.0454

Sodium 1.25 200.875mg/L158 157



entirety.

Page 47 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Boron 0.0500 1.0000 70-13098.2mg/L7.50 6.52

Calcium 1.25 100.00 70-130109mg/L414 305

Potassium 1.25 100.00 70-130103mg/L105 2.89

Lithium 0.0150 1.0000 70-130102mg/L1.03 0.00883

Magnesium 1.25 100.00 70-130107mg/L191 84.1

Sodium 1.25 100.00 70-130106mg/L184 77.8


Boron 0.0500 1.0000 70-130129mg/L8.18 6.89

Calcium 1.25 100.00 70-130110mg/L252 142

Potassium 1.25 100.00 70-130102mg/L115 12.8

Magnesium 1.25 100.00 70-130105mg/L139 34.1

Lithium 0.0150 1.0000 70-130101mg/L1.05 0.0454

Sodium 1.25 100.00 70-130111mg/L268 157


Lithium 0.0150 1.0000 2070-130103 0.270mg/L1.04 0.00883

Sodium 1.25 100.00 2070-130107 0.187mg/L185 77.8

Magnesium 1.25 100.00 2070-130108 0.756mg/L192 84.1

Potassium 1.25 100.00 2070-130103 0.379mg/L106 2.89

Calcium 1.25 100.00 2070-130110 0.222mg/L415 305

Boron 0.0500 1.0000 2070-130109 1.45mg/L7.61 6.52


Boron 0.0500 1.0000 20 M_MS70-130146 2.07mg/L8.35 6.89

Calcium 1.25 100.00 2070-130114 1.76mg/L257 142

Lithium 0.0150 1.0000 2070-130102 1.46mg/L1.07 0.0454

Magnesium 1.25 100.00 2070-130108 2.34mg/L142 34.1

Sodium 1.25 100.00 2070-130115 1.69mg/L272 157

Potassium 1.25 100.00 2070-130104 1.31mg/L117 12.8



entirety.

Page 48 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDK0160 - EPA 245.1, EPA 7470A

Blank (BDK0160-BLK1) Prepared & Analyzed: 11/07/2018


LCS (BDK0160-BS1) Prepared & Analyzed: 11/07/2018

Mercury 0.200 3.0000 85-11589.8ug/L2.69

Duplicate (BDK0160-DUP1) Prepared & Analyzed: 11/07/2018Source: MDJ0313-06

Mercury 0.200 20ug/L<0.200 <0.200

Duplicate (BDK0160-DUP2) Prepared & Analyzed: 11/07/2018Source: MDJ0313-07

Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDK0160-MS1) Prepared & Analyzed: 11/07/2018Source: MDJ0313-06

Mercury 0.200 3.0000 70-13086.0ug/L2.58 <0.200

Matrix Spike (BDK0160-MS2) Prepared & Analyzed: 11/07/2018Source: MDJ0313-07

Mercury 0.200 3.0000 70-13084.8ug/L2.54 <0.200

Matrix Spike Dup (BDK0160-MSD1) Prepared & Analyzed: 11/07/2018Source: MDJ0313-06

Mercury 0.200 3.0000 2070-13082.6 4.02ug/L2.48 <0.200

Matrix Spike Dup (BDK0160-MSD2) Prepared & Analyzed: 11/07/2018Source: MDJ0313-07

Mercury 0.200 3.0000 2070-13086.4 1.90ug/L2.59 <0.200



entirety.

Page 49 of 50



Reported:


250 Marquette Plaza

11/09/2018 08:33Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150









dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 50 of 50

#=CL#

December 07, 2018



RE:



Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on November 15, 2018.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 13

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 13

#=SS#

SAMPLE SUMMARY




30271771001 W 601 A Water 11/12/18 14:10 11/15/18 10:15

30271771002 W 600 A Water 11/12/18 15:00 11/15/18 10:15




Greensburg, PA 15601(724)850-5600

Page 3 of 13

#=SA#





30271771001 W 601 A EPA 903.1 1 PASI-PAMK1



30271771002 W 600 A EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 4 of 13

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: December 07, 2018











Greensburg, PA 15601(724)850-5600

Page 5 of 13

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 6 of 13

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 7 of 13

#=ARR#







Radium-226 0.326 ± 0.453 (0.766)C:NA T:91%

pCi/L 12/06/18 20:58 13982-63-3EPA 903.1

Radium-228 0.225 ± 0.371 (0.808)C:82% T:91%

pCi/L 12/05/18 16:22 15262-20-1EPA 904.0



Parameters Act ± Unc (MDC) Carr Trac Units Analyzed CAS No. Qual

• Sample collection dates and times were not present on the sample containers.Comments:

Method


Radium-226 0.462 ± 0.484 (0.757)C:NA T:92%

pCi/L 12/06/18 20:58 13982-63-3EPA 903.1

Radium-228 0.592 ± 0.428 (0.837)C:82% T:80%

pCi/L 12/05/18 16:22 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 8 of 13

#=QCR#







321151EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 12/05/18 16:220.710 ± 0.426 (0.787) C:77% T:82%




Greensburg, PA 15601(724)850-5600

Page 9 of 13

#=QCR#







321138EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 12/06/18 20:580.119 ± 0.271 (0.437) C:NA T:88%




Greensburg, PA 15601(724)850-5600

Page 10 of 13

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 11 of 13


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Tedd Ronning

Steve Davis

Project Manager






Sincerely,

27 November 2018

cc:



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MDK0180-01 Water 11/14/2018 14:3011/12/2018 14:10W601A

MDK0180-02 Water 11/14/2018 14:3011/12/2018 15:00W600A



entirety.

Page 1 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MDK0180-01 (Water) - Chain of Custody Number: 1845959

W601A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDK0443 EPA 300.0126 CRL11/19/18 15:3911/19/18 11:52

Fluoride 0.750 mg/L 1 BDK0443 EPA 300.0< 0.750 CRL11/19/18 15:3911/19/18 11:52

Sulfate 10.0 mg/L 10 BDK0443 EPA 300.01180 CRL11/19/18 15:1911/19/18 11:52

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDK0367 SM 2320B114 CRL11/15/18 14:4811/15/18 10:30

pH pH Units 1 BDK0367 SM 4500-H+ B10.3 CRLM_TTT 11/15/18 14:4811/15/18 10:30

Total Dissolved Solids 20.0 mg/L 1 BDK0383 SM 2540C2180 HSD11/16/18 8:3111/16/18 8:31


Arsenic 5.00 ug/L 10 BDK0437 EPA 200.811.8 CRL11/20/18 8:2411/19/18 9:27

Barium 0.500 ug/L 1 BDK0437 EPA 200.874.2 CRL11/20/18 7:5111/19/18 9:27

Beryllium 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5111/19/18 9:27

Cadmium 0.100 ug/L 1 BDK0437 EPA 200.8< 0.100 CRL11/20/18 7:5111/19/18 9:27

Cobalt 5.00 ug/L 10 BDK0437 EPA 200.8< 5.00 CRLM_DIL 11/20/18 8:2411/19/18 9:27

Chromium 5.00 ug/L 10 BDK0437 EPA 200.8< 5.00 CRLM_DIL 11/20/18 8:2411/19/18 9:27

Molybdenum 0.500 ug/L 1 BDK0437 EPA 200.8255 CRL11/20/18 7:5111/19/18 9:27

Lead 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5111/19/18 9:27

Antimony 0.500 ug/L 1 BDK0437 EPA 200.81.16 CRL11/20/18 7:5111/19/18 9:27

Selenium 0.500 ug/L 1 BDK0437 EPA 200.870.9 CRL11/20/18 7:5111/19/18 9:27

Thallium 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5111/19/18 9:27

Total Metals by ICP

Boron 0.0500 mg/L 1 BDK0436 EPA 200.715.7 HRD11/26/18 14:0011/19/18 9:24

Calcium 1.25 mg/L 1 BDK0436 EPA 200.7385 HRD11/26/18 13:5811/19/18 9:24

Potassium 1.25 mg/L 1 BDK0436 EPA 200.751.3 HRD11/26/18 13:5811/19/18 9:24

Lithium 0.0150 mg/L 1 BDK0436 EPA 200.70.349 HRD11/26/18 13:5811/19/18 9:24

Magnesium 1.25 mg/L 1 BDK0436 EPA 200.71.59 HRD11/26/18 13:5911/19/18 9:24

Sodium 1.25 mg/L 1 BDK0436 EPA 200.7272 HRD11/26/18 13:5811/19/18 9:24



entirety.

Page 2 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 3 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte


Chloride 1.00 mg/L 1 BDK0443 EPA 300.022.8 CRL11/19/18 16:2011/19/18 11:52

Fluoride 0.750 mg/L 1 BDK0443 EPA 300.0< 0.750 CRL11/19/18 16:2011/19/18 11:52

Sulfate 10.0 mg/L 10 BDK0443 EPA 300.01610 CRL11/19/18 16:0011/19/18 11:52

Wet Chemistry

Alkalinity, Total 10.0 mg/L 1 BDK0367 SM 2320B90.7 CRL11/15/18 14:5411/15/18 10:30

pH pH Units 1 BDK0367 SM 4500-H+ B6.53 CRLM_TTT 11/15/18 14:5411/15/18 10:30

Total Dissolved Solids 20.0 mg/L 1 BDK0383 SM 2540C2590 HSD11/16/18 8:3111/16/18 8:31


Arsenic 0.500 ug/L 1 BDK0437 EPA 200.837.4 CRL11/20/18 7:5511/19/18 9:27

Barium 0.500 ug/L 1 BDK0437 EPA 200.824.6 CRL11/20/18 7:5511/19/18 9:27

Beryllium 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5511/19/18 9:27

Cadmium 0.100 ug/L 1 BDK0437 EPA 200.80.515 CRL11/20/18 7:5511/19/18 9:27

Cobalt 0.500 ug/L 1 BDK0437 EPA 200.834.6 CRL11/20/18 7:5511/19/18 9:27

Chromium 0.500 ug/L 1 BDK0437 EPA 200.83.21 CRL11/20/18 7:5511/19/18 9:27

Molybdenum 0.500 ug/L 1 BDK0437 EPA 200.829.9 CRL11/20/18 7:5511/19/18 9:27

Lead 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5511/19/18 9:27

Antimony 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5511/19/18 9:27

Selenium 0.500 ug/L 1 BDK0437 EPA 200.8< 0.500 CRL11/20/18 7:5511/19/18 9:27

Thallium 0.500 ug/L 1 BDK0437 EPA 200.80.725 CRL11/20/18 7:5511/19/18 9:27

Total Metals by ICP

Boron 0.0500 mg/L 1 BDK0436 EPA 200.78.18 HRD11/26/18 14:0511/19/18 9:24

Calcium 1.25 mg/L 1 BDK0436 EPA 200.7575 HRD11/26/18 14:0311/19/18 9:24

Potassium 1.25 mg/L 1 BDK0436 EPA 200.713.0 HRD11/26/18 14:0411/19/18 9:24

Lithium 0.0150 mg/L 1 BDK0436 EPA 200.70.0990 HRD11/26/18 14:0411/19/18 9:24

Magnesium 1.25 mg/L 1 BDK0436 EPA 200.747.6 HRD11/26/18 14:0411/19/18 9:24

Sodium 1.25 mg/L 1 BDK0436 EPA 200.756.4 HRD11/26/18 14:0311/19/18 9:24



entirety.

Page 4 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDK0443 - Wet Prep






Chloride 1.00 25.000 90-11096.6mg/L24.2

Fluoride 0.750 2.5000 90-11097.2mg/L2.43

Sulfate 1.00 48.000 90-11096.7mg/L46.4


Chloride 1.00 25.000 90-11097.4mg/L24.3

Fluoride 0.750 2.5000 90-110104mg/L2.60

Sulfate 1.00 48.000 90-11097.1mg/L46.6

Duplicate (BDK0443-DUP1) Prepared & Analyzed: 11/19/2018Source: MDK0211-05

Chloride 1.00 201.66mg/L8.37 8.51

Fluoride 0.750 20mg/L<0.750 <0.750

Sulfate 1.00 200.844mg/L309 312

Matrix Spike (BDK0443-MS1) Prepared & Analyzed: 11/19/2018Source: MDK0211-05

Chloride 1.25 31.250 80-12094.9mg/L38.2 8.51

Fluoride 0.938 3.1250 80-12090.2mg/L2.82 <0.938

Sulfate 1.25 60.000 80-12089.7mg/L366 312

Matrix Spike Dup (BDK0443-MSD1) Prepared & Analyzed: 11/19/2018Source: MDK0211-05

Chloride 1.25 31.250 2080-12094.9 0.0197mg/L38.2 8.51

Fluoride 0.938 3.1250 2080-12098.3 8.57mg/L3.07 <0.938

Sulfate 1.25 60.000 2080-12090.0 0.0458mg/L366 312



entirety.

Page 6 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




pH 4.0000 90-110177pH Units7.06



pH 4.0000 90-110177pH Units7.06



pH 200.269pH Units7.42 7.44




pH 200.268pH Units7.46 7.48








entirety.

Page 7 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDK0437 - EPA 200.2, EPA 3005

Blank (BDK0437-BLK1) Prepared: 11/19/2018 Analyzed: 11/20/2018

Barium 0.500 ug/L<0.500

Cobalt 0.500 ug/L<0.500



Lead 0.500 ug/L<0.500







LCS (BDK0437-BS1) Prepared: 11/19/2018 Analyzed: 11/20/2018

Lead 0.500 100.00 85-11593.1ug/L93.1

Cadmium 0.100 100.00 85-115102ug/L102

Beryllium 0.500 100.00 85-11596.2ug/L96.2

Chromium 0.500 100.00 85-11597.9ug/L97.9

Cobalt 0.500 100.00 85-11597.5ug/L97.5

Barium 0.500 100.00 85-11599.8ug/L99.8

Molybdenum 0.500 100.00 85-11597.3ug/L97.3

Selenium 0.500 100.00 85-11595.4ug/L95.4

Thallium 0.500 100.00 85-11593.5ug/L93.5

Antimony 0.500 100.00 85-11599.9ug/L99.9

Arsenic 0.500 100.00 85-11597.4ug/L97.4

Duplicate (BDK0437-DUP1) Prepared: 11/19/2018 Analyzed: 11/20/2018Source: MDK0154-01

Chromium 0.500 2012.3ug/L0.952 0.842

Thallium 0.500 20ug/L0.0943 <0.500

Molybdenum 0.500 20 M_D-RL53.4ug/L0.280 0.162

Cadmium 0.100 20ug/L<0.100 <0.100


Arsenic 0.500 200.626ug/L0.678 0.674

Lead 0.500 20 M_D-RL26.4ug/L0.307 0.235

Antimony 0.500 20 M_D-RL125ug/L0.103 0.0240


Barium 0.500 206.20ug/L18.0 16.9

Cobalt 0.500 205.77ug/L0.249 0.235



entirety.

Page 8 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cadmium 0.100 20 M_D-RL30.5ug/L0.0230 0.0313


Cobalt 0.500 200.896ug/L0.244 0.246

Chromium 0.500 205.56ug/L2.00 1.89

Arsenic 0.500 205.62ug/L1.06 1.12

Thallium 0.500 20ug/L<0.500 <0.500

Antimony 0.500 201.96ug/L0.377 0.384

Lead 0.500 201.06ug/L12.5 12.4

Molybdenum 0.500 200.531ug/L0.835 0.840


Barium 0.500 202.31ug/L48.2 49.3

Matrix Spike (BDK0437-MS1) Prepared: 11/19/2018 Analyzed: 11/20/2018Source: MDK0154-01

Cadmium 0.100 100.00 70-13096.5ug/L96.5 <0.100

Arsenic 0.500 100.00 70-13095.4ug/L96.1 0.674

Barium 0.500 100.00 70-13098.2ug/L115 16.9

Cobalt 0.500 100.00 70-13097.2ug/L97.5 0.235

Antimony 0.500 100.00 70-13097.8ug/L97.9 0.0240

Chromium 0.500 100.00 70-13096.2ug/L97.0 0.842

Thallium 0.500 100.00 70-13093.9ug/L93.9 <0.500

Selenium 0.500 100.00 70-13095.5ug/L95.7 0.245

Molybdenum 0.500 100.00 70-13095.1ug/L95.3 0.162

Lead 0.500 100.00 70-13092.5ug/L92.8 0.235

Beryllium 0.500 100.00 70-13097.3ug/L97.3 0.0119


Cadmium 0.100 100.00 70-130103ug/L103 0.0313

Selenium 0.500 100.00 70-13098.8ug/L99.0 0.262

Thallium 0.500 100.00 70-13094.0ug/L94.0 <0.500

Antimony 0.500 100.00 70-13099.6ug/L100 0.384

Arsenic 0.500 100.00 70-130102ug/L103 1.12

Lead 0.500 100.00 70-13092.0ug/L104 12.4

Barium 0.500 100.00 70-13096.3ug/L146 49.3

Molybdenum 0.500 100.00 70-13096.1ug/L97.0 0.840

Cobalt 0.500 100.00 70-13097.0ug/L97.2 0.246

Chromium 0.500 100.00 70-13098.4ug/L100 1.89

Beryllium 0.500 100.00 70-13095.7ug/L95.7 0.0219



entirety.

Page 9 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BDK0437-MSD1) Prepared: 11/19/2018 Analyzed: 11/20/2018Source: MDK0154-01

Cobalt 0.500 100.00 2070-13097.8 0.569ug/L98.0 0.235

Thallium 0.500 100.00 2070-13095.7 1.88ug/L95.7 <0.500

Arsenic 0.500 100.00 2070-13099.1 3.76ug/L99.7 0.674

Molybdenum 0.500 100.00 2070-13097.1 2.05ug/L97.3 0.162

Selenium 0.500 100.00 2070-13099.2 3.81ug/L99.5 0.245

Antimony 0.500 100.00 2070-13097.7 0.124ug/L97.7 0.0240

Barium 0.500 100.00 2070-13099.4 1.03ug/L116 16.9

Chromium 0.500 100.00 2070-13097.4 1.29ug/L98.3 0.842

Cadmium 0.100 100.00 2070-130101 4.75ug/L101 <0.100

Beryllium 0.500 100.00 2070-13094.5 2.93ug/L94.5 0.0119

Lead 0.500 100.00 2070-13095.7 3.34ug/L95.9 0.235


Selenium 0.500 100.00 2070-13097.4 1.42ug/L97.6 0.262

Antimony 0.500 100.00 2070-13097.7 1.89ug/L98.1 0.384

Cobalt 0.500 100.00 2070-130102 4.73ug/L102 0.246

Barium 0.500 100.00 2070-13098.1 1.25ug/L147 49.3

Chromium 0.500 100.00 2070-13098.6 0.166ug/L100 1.89

Beryllium 0.500 100.00 2070-13094.1 1.66ug/L94.2 0.0219

Molybdenum 0.500 100.00 2070-13096.4 0.239ug/L97.2 0.840

Cadmium 0.100 100.00 2070-13098.6 3.90ug/L98.7 0.0313

Arsenic 0.500 100.00 2070-13099.9 2.27ug/L101 1.12

Lead 0.500 100.00 2070-13095.4 3.28ug/L108 12.4

Thallium 0.500 100.00 2070-13095.2 1.30ug/L95.2 <0.500



entirety.

Page 10 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BDK0436-BLK1) Prepared: 11/19/2018 Analyzed: 11/26/2018


Lithium 0.0150 mg/L<0.0150



Boron 0.0500 mg/L<0.0500


LCS (BDK0436-BS1) Prepared: 11/19/2018 Analyzed: 11/26/2018

Calcium 1.25 100.00 85-115114mg/L114

Potassium 1.25 100.00 85-115113mg/L113

Boron 0.0500 1.0000 85-115109mg/L1.09

Lithium 0.0150 1.0000 85-115110mg/L1.10

Magnesium 1.25 100.00 85-115113mg/L113

Sodium 1.25 100.00 85-115115mg/L115


Potassium 1.25 200.360mg/L4.23 4.25

Sodium 1.25 200.354mg/L24.0 23.9

Lithium 0.0150 201.82mg/L0.0574 0.0585

Calcium 1.25 200.902mg/L142 141

Boron 0.0500 200.0184mg/L0.0997 0.0997

Magnesium 1.25 201.14mg/L65.5 64.8


Boron 0.0500 204.63mg/L0.0585 0.0558

Potassium 1.25 203.51mg/L3.35 3.23

Calcium 1.25 201.27mg/L96.0 94.8

Magnesium 1.25 201.59mg/L45.5 44.8

Sodium 1.25 201.12mg/L253 250

Lithium 0.0150 200.710mg/L0.0266 0.0264



entirety.

Page 11 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Sodium 1.25 100.00 70-130113mg/L137 23.9

Magnesium 1.25 100.00 70-130115mg/L180 64.8

Boron 0.0500 1.0000 70-130112mg/L1.22 0.0997

Potassium 1.25 100.00 70-130112mg/L116 4.25

Lithium 0.0150 1.0000 70-130108mg/L1.14 0.0585

Calcium 1.25 100.00 70-130118mg/L259 141


Calcium 1.25 100.00 70-130111mg/L206 94.8

Lithium 0.0150 1.0000 70-130107mg/L1.10 0.0264

Sodium 1.25 100.00 70-130113mg/L364 250

Potassium 1.25 100.00 70-130111mg/L114 3.23

Boron 0.0500 1.0000 70-130111mg/L1.16 0.0558

Magnesium 1.25 100.00 70-130114mg/L159 44.8


Magnesium 1.25 100.00 2070-130113 1.32mg/L178 64.8

Sodium 1.25 100.00 2070-130111 1.79mg/L135 23.9

Potassium 1.25 100.00 2070-130110 1.56mg/L114 4.25

Calcium 1.25 100.00 2070-130114 1.91mg/L254 141

Boron 0.0500 1.0000 2070-130111 0.748mg/L1.21 0.0997

Lithium 0.0150 1.0000 2070-130107 1.72mg/L1.12 0.0585


Potassium 1.25 100.00 2070-130109 2.00mg/L112 3.23

Calcium 1.25 100.00 2070-130106 2.57mg/L201 94.8

Boron 0.0500 1.0000 2070-130107 2.79mg/L1.13 0.0558

Lithium 0.0150 1.0000 2070-130105 2.31mg/L1.08 0.0264

Sodium 1.25 100.00 2070-130104 2.59mg/L354 250

Magnesium 1.25 100.00 2070-130108 3.75mg/L153 44.8



entirety.

Page 12 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BDK0547 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0000 85-11586.7ug/L2.60


Mercury 0.200 20ug/L<0.200 <0.200

Matrix Spike (BDK0547-MS1) Prepared & Analyzed: 11/26/2018Source: MDK0180-01

Mercury 0.200 3.0000 70-13088.3ug/L2.65 <0.200

Matrix Spike Dup (BDK0547-MSD1) Prepared & Analyzed: 11/26/2018Source: MDK0180-01

Mercury 0.200 3.0000 2070-13089.0 0.775ug/L2.67 <0.200



entirety.

Page 13 of 14



Reported:


250 Marquette Plaza

11/27/2018 12:41Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150





M_DIL Sample was diluted. The MDL and MRL were raised due to the dilution.



dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 14 of 14

Appendix B

Data Quality Control / Quality Assurance Review

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Verification\Appendices\B-QAQC\Appendix B QAQC Memo_071519.doc

Appendix B: Data Quality Assurance / Quality Control Review

A review of the quality control data was conducted to assess the validity of the analytical results for the

groundwater samples collected during the CCR baseline monitoring (2017-2018) and closure verification

events (2019) at the Black Dog Generating Plant (Plant or Site) located in Burnsville, Minnesota. The samples

were collected and analyzed for the parameters listed in Appendices III and IV of the CCR Rule. Groundwater

samples were also analyzed for additional parameters (e.g., major cations and anions) to verify the

appropriateness of the monitoring network. This review was performed in accordance with Barr Engineering’s

Standard Operating Procedures (SOPs) for data evaluation, which are based on The National Functional

Guidelines for Organic and Inorganic Data Review (USEPA, 2008 and 2010). The majority of the analyses were

performed by Xcel Energy’s Minneapolis Testing Laboratory (Xcel Minneapolis) located in Minneapolis,

Minnesota with the radium analysis performed by Pace located in Greensburg, Pennsylvania.

Both field sampling and laboratory analytical procedures were examined in the review of the sampling event.

Field sampling procedures were examined utilizing field blank samples and field (masked) duplicate sample

analyses. Laboratory procedures were evaluated utilizing technical holding times, preservation, method blank

samples, accuracy data, precision data, and data package completeness.

Field sampling procedures

A field blank sample was collected during each of the eight baseline monitoring and two closure verification

events. The field blank collected with the samples for the December 11th, 2017 event had a detection of radium

226 and the following sample detections were qualified (b) as potential false positive detections: W504B,

W602A, W14A, W601A, and W604A. No other target compounds were detected above the reporting limits

(RLs) in the field blank samples.

Field (masked) duplicate sample results were evaluated by calculating the Relative Percent Difference (RPD)

values for compounds where both the native and field duplicate sample had concentrations reported above

the RL. The RPD formula is as follows:

1002/)(

DS

DSRPD

Where: RPD = relative percent difference

S = original sample result

D = duplicate sample result



A field duplicate pair was collected during each of the eight baseline monitoring and two closure verification

events and the data is shown in Table B-1. The acceptance criteria used for the field duplicate samples data

precision (30% RPD) was based on Barr’s SOPs for routine data evaluation. The field duplicate data met the

RPD criteria for precision.

The field parameters were also reviewed for each event. There were three instances where the turbidity was

significantly elevated (< 50 NTU) and the associated sample data (W600A - May 8 and June 12, 2018 and

W601A - February 7, 2018) was rejected (**) based on this. As discussed in the report, these sample locations

were resampled in order to have a complete baseline dataset.

Laboratory Procedures

Technical holding times and preservation were evaluated for each sample and target parameter based on

United States Environmental Protection Agency (USEPA) and method recommendations. The technical holding

times were within these recommendations for all of the analyses, and the groundwater samples arrived at the

laboratory at the correct temperatures and with the correct chemical preservatives.

Method blanks were analyzed by the laboratory for each parameter. The method blank tested with the

samples for the July 23-25, 2018 event had a detection of radium 228 and the following sample detections

were qualified (b) as potential false positive detections: W504A, W504B, W14A, W510A, and the W50A Field

Duplicate. No other target compounds were detected above the RL in the method blank samples.

The accuracy and precision data review included evaluation of laboratory control spike (LCS), matrix spike (MS),

matrix spike duplicate (MSD), and laboratory duplicate samples. Accuracy was evaluated by comparing

laboratory percent recoveries from LCS, MS, and MSD samples to laboratory acceptance criteria. Precision was

evaluated by calculating the RPD of the MS/MSD and laboratory duplicate sample pairs.

The LCS samples displayed acceptable accuracy when compared to the laboratory acceptance criteria in the

majority of instances. The LCS tested for laboratory pH with the samples included in laboratory work order

MDK0180, had a percent recovery that exceeded the laboratory acceptance criteria and the associated samples

results taken on November 12, 2018 (W600A and W601A) were qualified (*) as estimated. Also, an LCS

associated with the closure work order MEE0179 analysis of fluoride had an LCS that was only slightly above

acceptance recovery (by one percent) and no data was qualified based on this slight deviation. The remaining

LCS samples displayed accuracy within laboratory acceptance limits.

The laboratory included MS/MSD samples tested from project and non-project samples in each work order.

Only the MS/MSD samples taken from project samples were evaluated compared to project data. In instances



where a duplicate accuracy sample was analyzed (MSD), the associated sample data results were not qualified

if only the RPD or one of the percent recoveries were outside acceptance criteria. In addition, where MS

recoveries failed acceptance criteria and the native sample concentration was significantly greater than the

spike added (greater than four times), the spike recovery could not be accurately evaluated, therefore the

criteria did not apply and acceptance of the sample results were based on the acceptable LCS data. The

MS/MSDs displayed accuracy and/or precision within laboratory acceptance criteria or the deviation was

considered minor (less than five percent).

The laboratory included laboratory duplicate samples tested from project and non-project samples in each

work order. Only the duplicate samples taken from project samples were evaluated compared to project data.

The calculated RPD was compared against the laboratory criteria. Only duplicate pairs that were detected

significantly above the RL (greater than five times) were evaluated as the RPD is exaggerated from results close

to the RL. All of the evaluated laboratory duplicate data met the RPD criteria for precision.

Data completeness was evaluated by comparing the analyses requested with the data package as received.

There were multiple events where the sample location was labeled incorrectly as W514A on the COCs and

associated laboratory reports when the correct location should have been W514B; the laboratory reports have

been revised to note the correction and the EQuIS database and associated tables reflect the correct sample

location of W514B. Neither of these wells are in the monitoring network and the project result were

unaffected.

Conclusion

The data are deemed acceptable for the purposes of this project with the qualifications assigned during the

data evaluation process.

References

United States Environmental Protection Agency (USEPA), 2008. USEPA Contract Laboratory Program

National Functional Guidelines for Superfund Organic Methods Data Review. EPA QA/R-5. 2008

United States Environmental Protection Agency (USEPA), 2010. USEPA Contract Laboratory Program

National Functional Guidelines for Superfund Inorganic Methods Data Review. EPA QA/R-5. 2010

Table B-1

2017-2019 CCR Groundwater Data- Duplicate Comparison


Burnsville, MN

N FD RPD N FD RPD N FD RPDParameter Units Parameter List

Field ParametersDissolved oxygen mg/l Field 0.2 -- NA 0.1 -- NA 0.7 -- NApH pH units Field 7.2 -- NA 7.0 -- NA 7.2 -- NARedox (oxidation potential) mV Field -68 -- NA -61 -- NA -83 -- NASpecific conductance @ 25 ºC umhos/cm Field 3020 -- NA 3020 -- NA 2740 -- NATemperature deg C Field 9.5 -- NA 13.0 -- NA 8.5 -- NATurbidity NTU Field 1.4 -- NA 3.5 -- NA 2.1 -- NA

Cations/AnionsAlkalinity, total, as CaCO3 mg/l Cations/Anions 309 315 1.9 % 297 305 2.7 % 331 322 2.8 %Magnesium mg/l Cations/Anions 70.0 70.7 1.0% 72.5 72.0 0.69 % 70.0 69.6 0.57 %Potassium mg/l Cations/Anions 15.4 16.0 3.8 % 16.3 16.5 1.2 % 15.0 14.7 2.0 %Sodium mg/l Cations/Anions 161 166 3.1 % 160 160 0.0% 142 141 0.71 %

Chloride mg/l Appendix III, Cations/Anions 101 101 0.0% 107 106 0.94 % 94.8 94.9 0.11 %

Fluoride mg/l Appendix III, Appendix IV < 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

Sulfate, as SO4 mg/l Appendix III, Cations/Anions 1410 1410 0.0% 1440 1430 0.70 % 1470 1480 0.68 %

Appendix III ParametersBoron mg/l Appendix III 7.87 8.09 2.8 % 8.01 8.00 0.12 % 8.34 8.39 0.60 %Calcium mg/l Appendix III 482 496 2.9 % 508 507 0.20 % 490 486 0.82 %pH pH units Field 7.45 7.45 0.0% 7.38 7.40 0.27 % 7.43 7.45 0.27 %Solids, total dissolved mg/l Appendix III 2620 2600 0.77 % 2720 2690 1.1 % 2630 2610 0.76 %


Chloride mg/l Appendix III, Cations/Anions 101 101 0.0% 107 106 0.94 % 94.8 94.9 0.11 %

Sulfate, as SO4 mg/l Appendix III, Cations/Anions 1410 1410 0.0% 1440 1430 0.70 % 1470 1480 0.68 %


Antimony ug/l Appendix IV < 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NAArsenic ug/l Appendix IV 30.4 33.8 11 % 31.2 33.5 7.1 % 37.3 37.5 0.53 %Barium ug/l Appendix IV 79.8 80.2 0.50 % 76.7 75.6 1.4 % 80.4 80.2 0.25 %Beryllium ug/l Appendix IV < 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NACadmium ug/l Appendix IV < 0.500 < 0.500 NA < 0.100 < 0.100 NA < 0.100 < 0.100 NAChromium ug/l Appendix IV < 0.500 < 0.500 NA < 5.00 < 5.00 NA < 0.500 < 0.500 NACobalt ug/l Appendix IV 3.53 3.87 9.2 % < 5.00 < 5.00 NA 3.89 4.02 3.3 %


Lead ug/l Appendix IV < 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NALithium mg/l Appendix IV 0.0887 0.0919 3.5 % 0.0889 0.0889 0.0% 0.0797 0.0777 2.5 %Mercury ug/l Appendix IV < 0.200 < 0.200 NA < 0.200 < 0.200 NA < 0.200 < 0.200 NAMolybdenum ug/l Appendix IV 65.9 66.6 1.1 % 67.9 66.6 1.9 % 63.9 63.6 0.47 %Selenium ug/l Appendix IV < 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NAThallium ug/l Appendix IV < 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NARadium 226 pCi/l -0.059 +/- 0.419 ND 0.356 +/- 0.521 ND NA 0.760 +/- 0.448 0.470 +/- 0.505 ND NA 0.610 +/- 0.446 0.352 +/- 0.547 ND NARadium 228 pCi/l 0.588 +/- 0.379 ND -0.0609 +/- 0.525 ND NA 0.598 +/- 0.409 ND 0.860 +/- 0.444 NA 1.80 +/- 0.658 b 0.666 +/- 0.513 ND NARadium, combined (226+228), Barr Calculation pCi/l Appendix IV 0.588 +/- 0.380 ND 0.356 +/- 0.520 ND NA 1.36 +/- 0.610 q 1.33 +/- 0.670 q 2.2% 0.610 +/- 0.45 1.02 +/- 0.75 ND NA

Location W502AW502A W502A

Sample TypeSample Date 03/13/201903/20/2018 07/24/2018

%RPD = | (N ‐ FD) / (N + FD) / 2 | X 100Where: N = 1st ValueFD = 2nd Value

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Table B-1



Burnsville, MN

Parameter Units Parameter ListField Parameters

Dissolved oxygen mg/l FieldpH pH units FieldRedox (oxidation potential) mV FieldSpecific conductance @ 25 ºC umhos/cm FieldTemperature deg C FieldTurbidity NTU Field

Cations/AnionsAlkalinity, total, as CaCO3 mg/l Cations/AnionsMagnesium mg/l Cations/AnionsPotassium mg/l Cations/AnionsSodium mg/l Cations/Anions

Chloride mg/l Appendix III, Cations/Anions

Fluoride mg/l Appendix III, Appendix IV

Sulfate, as SO4 mg/l Appendix III, Cations/Anions

Appendix III ParametersBoron mg/l Appendix IIICalcium mg/l Appendix IIIpH pH units FieldSolids, total dissolved mg/l Appendix III





Antimony ug/l Appendix IVArsenic ug/l Appendix IVBarium ug/l Appendix IVBeryllium ug/l Appendix IVCadmium ug/l Appendix IVChromium ug/l Appendix IVCobalt ug/l Appendix IV


Lead ug/l Appendix IVLithium mg/l Appendix IVMercury ug/l Appendix IVMolybdenum ug/l Appendix IVSelenium ug/l Appendix IVThallium ug/l Appendix IVRadium 226 pCi/lRadium 228 pCi/lRadium, combined (226+228), Barr Calculation pCi/l Appendix IV

Location

Sample TypeSample Date

N FD RPD N FD RPD N FD RPD

0.2 -- NA 0.3 -- NA 0.3 -- NA7.4 -- NA 7.6 -- NA 7.3 -- NA

-167 -- NA -53 -- NA -178 -- NA2710 -- NA 2330 -- NA 2100 -- NA11.0 -- NA 13.5 -- NA 11.0 -- NA5.8 -- NA 4.4 -- NA 5.7 -- NA

359 390 8.3 % 376 385 2.4 % 394 396 0.51 %115 117 1.7 % 121 122 0.82 % 107 108 0.93 %1.90 1.88 1.1 % 2.03 2.02 0.49 % 1.88 1.90 1.1 %62.0 62.3 0.48 % 65.6 65.8 0.30 % 57.8 58.0 0.35 %

84.1 83.8 0.36 % 81.8 82.3 0.61 % 83.2 83.6 0.48 %

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

1190 1200 0.84 % 1160 1160 0.0% 1150 1150 0.0%

3.67 3.78 3.0 % 3.65 3.64 0.27 % 3.51 3.54 0.85 %445 447 0.45 % 468 470 0.43 % 412 412 0.0%7.31 7.31 0.0% 7.26 7.28 0.28 % 7.31 7.32 0.14 %2270 2330 2.6 % 2400 2260 6.0 % 2200 2200 0.0%

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

84.1 83.8 0.36 % 81.8 82.3 0.61 % 83.2 83.6 0.48 %

1190 1200 0.84 % 1160 1160 0.0% 1150 1150 0.0%

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA4.61 4.68 1.5 % 4.27 4.37 2.3 % 4.80 4.93 2.7 %148 147 0.68 % 133 133 0.0% 141 146 3.5 %

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA< 0.100 < 0.100 NA < 0.100 < 0.100 NA < 0.100 < 0.100 NA< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA< 0.0500 < 0.0500 NA 0.0259 0.0264 1.9 % 0.0247 0.0239 3.3 %< 0.200 < 0.200 NA < 0.200 < 0.200 NA < 0.200 < 0.200 NA< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA

0.612 +/- 0.505 ND 0.541 +/- 0.461 ND NA 0.134 +/- 0.491 ND 0.448 +/- 0.550 ND NA 0.463 +/- 0.428 ND 0.631 +/- 0.435 NA0.913 +/- 0.402 0.934 +/- 0.443 2.3% 1.22 +/- 0.422 0.577 +/- 0.385 ND NA 0.409 +/- 0.622 ND 0.792 +/- 0.653 ND NA

1.53 +/- 0.650 1.48 +/- 0.640 3.3% 1.35 +/- 0.650 q 1.03 +/- 0.670 ND NA 0.872 +/- 0.76 ND 1.42 +/- 0.78 q NA

W502B W502B W502B05/15/201909/11/201805/09/2018


Page 2 of 47/16/2019


Table B-1



Burnsville, MN















Location


N FD RPD N FD RPD N FD RPD

1.6 -- NA 0.2 -- NA 0.3 -- NA6.6 -- NA 7.0 -- NA 7.8 -- NA-5 -- NA 236 -- NA 120 -- NA

2420 -- NA 1820 -- NA 1420 -- NA9.5 -- NA 15.0 -- NA 10.0 -- NA3.3 -- NA 4.8 -- NA 1.5 -- NA

209 204 2.4 % 226 227 0.44 % 153 150 2.0 %43.8 43.2 1.4 % 41.5 41.0 1.2 % 21.9 22.4 2.3 %8.62 8.67 0.58 % 7.78 7.94 2.0 % 10.8 10.9 0.92 %57.1 58.1 1.7 % 42.6 42.8 0.47 % 147 150 2.0 %

86.8 90.5 4.2 % 36.3 35.7 1.7 % 203 203 0.0%

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

1190 1220 2.5 % 858 840 2.1 % 240 238 0.84 %

1.47 1.50 2.0 % 1.78 1.77 0.56 % 7.84 8.15 3.9 %491 494 0.61 % 342 343 0.29 % 101 103 2.0 %7.06 7.07 0.14 % 6.96 6.95 0.14 % 8.40 8.31 1.1 %2270 2290 0.88 % 1690 1660 1.8 % 856 880 2.8 %

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

86.8 90.5 4.2 % 36.3 35.7 1.7 % 203 203 0.0%

1190 1220 2.5 % 858 840 2.1 % 240 238 0.84 %

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA4.76 4.86 2.1 % 1.42 1.31 8.1 % 8.58 8.70 1.4 %18.9 18.8 0.53 % 20.4 20.4 0.0% 61.6 62.3 1.1 %

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA3.60 3.50 2.8 % 3.92 3.96 1.0 % < 0.500 < 0.500 NA

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA20.6 19.2 7.0 % 10.9 10.6 2.8 % < 0.500 < 0.500 NA

< 0.750 < 0.750 NA < 0.750 < 0.750 NA < 0.750 < 0.750 NA

< 0.500 < 0.500 NA < 0.500 < 0.500 NA < 0.500 < 0.500 NA0.0619 0.0624 0.80 % 0.0553 0.0527 4.8 % 0.0954 0.0963 0.94 %< 0.200 < 0.200 NA < 0.200 < 0.200 NA < 0.200 < 0.200 NA

20.6 20.5 0.49 % 18.7 19.0 1.6 % 108 110 1.8 %0.653 0.556 16 % 0.564 0.555 1.6 % < 0.500 < 0.500 NA0.703 0.696 1.0 % 0.982 1.02 3.8 % < 0.500 < 0.500 NA

-0.053 +/- 0.344 ND 0.111 +/- 0.254 ND NA 0.560 +/- 0.650 ND 0 +/- 0.546 ND NA 0.441 +/- 0.408 ND 0.252 +/- 0.462 ND NA0.328 +/- 0.639 ND 1.23 +/- 0.712 ND NA 0.543 +/- 0.344 ND 0.511 +/- 0.329 ND NA 0.330 +/- 0.295 ND 0.325 +/- 0.294 ND NA

0.328 +/- 0.640 ND 1.34 +/- 0.760 ND NA 1.10 +/- 0.740 ND 0.511 +/- 0.640 ND NA 0.577 +/- 0.550 ND 0.771 +/- 0.500 ND NA

06/13/2018 10/24/2018 02/07/2018W506A W506A W603A


Page 3 of 47/16/2019


Table B-1



Burnsville, MN















Location


N FD RPD

1.3 -- NA7.6 -- NA-52 -- NA

1340 -- NA11.5 -- NA9.8 -- NA

-- -- NA21.7 20.7 4.7 %6.81 6.51 4.5 %175 168 4.1 %

147 146 0.68 %

< 0.750 < 0.750 NA

350 350 0.0%

3.99 3.85 3.6 %87.3 84.2 3.6 %8.75 8.78 0.34 %832 824 0.97 %

< 0.750 < 0.750 NA

147 146 0.68 %

350 350 0.0%

1.78 1.86 4.4 %6.29 6.37 1.3 %82.7 84.2 1.8 %

< 0.500 < 0.500 NA< 0.500 < 0.500 NA

1.77 1.67 5.8 %< 0.500 < 0.500 NA

< 0.750 < 0.750 NA

< 0.500 < 0.500 NA< 0.0500 < 0.0500 NA< 0.200 < 0.200 NA

177 177 0.0%4.03 4.10 1.7 %

< 0.500 < 0.500 NA0.494 +/- 0.346 b -0.134 +/- 0.233 349%0.571 +/- 0.447 0.0504 +/- 0.537 170 %

1.07 +/- 0.570 q 0.0504 +/- 0.540 ND NA

12/13/2017W604A


Page 4 of 47/16/2019



-- Not analyzed/Not available.N Sample Type: Normal

FD Sample Type: Field DuplicateNA NA (not applicable) indicates that the RPD calculation is not applicableND Not detected.

b Potential false positive value based on blank data validation procedures. Concentrations identified as potential false positive are excluded from calculations.



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Appendix C

Development of Groundwater Protection Standards

Barr Engineering Co. 4300 MarketPointe Drive, Suite 200, Minneapolis, MN 55435 952.832.2600 www.barr.com

Technical Memorandum

To: Project File

From: Denise Levitan and Jennifer Brekken

Subject: Development of Groundwater Protection Standards

Date: July 2019

Project: Black Dog Generating Plant, Burnsville, Minnesota

Statistical analyses were conducted using the Sanitas software package (version 9.6, produced by Sanitas

Technologies of Loveland, CO). The Sanitas software is set up to conduct statistical analyses according to

the U.S. Environmental Protection Agency (EPA)’s 2009 Statistical Analysis of Groundwater Monitoring Data

at RCRA Facilities: Unified Guidance (Unified Guidance; EPA 530/R-09-007). The statistical analyses also

followed the CCR Groundwater Statistical Analysis Plan (Barr, 2019c).

The background data (Table C-1) were loaded into Sanitas for statistical analyses. Unless otherwise

specified, an alpha of 0.05 was used in statistical tests.

The normality of the pooled data from the seven background wells was assessed by the Shapiro-Francia

test (Unified Guidance, Chapter 10). The results of the normality testing in combination with the fraction

of data below analytical reporting limits (Table C-2) were used to determine whether parametric or non-

parametric methods would be used. None of the pooled background datasets were determined to fit a

normal distribution, so non-parametric methods were used for subsequent statistical analysis.

Outlier testing was conducted on pooled data from the seven background wells using the Tukey hinge

screening method with an interquartile range multiplier of 3 (Unified Guidance, Chapter 12). Values less

than three times the median and values below analytical reporting limits were not included as outliers. For

suspected outliers identified in the pooled background data, individual well-parameter datasets were then

evaluated using Dixon’s test (for normally distributed datasets, based on the Shapiro-Wilk test) or the

Tukey screening method (for non-normally distributed datasets). Values that were identified as outliers in

both the pooled data screening and the well-parameter pair datasets were individually evaluated using

professional judgement to determine whether the values should remain in the background dataset. Values

that were identified as outliers in both the pooled data screening and the well-parameter pair datasets

were individually evaluated for data quality issues and shifts in groundwater population (Barr 2019c). The

values included two chromium samples from W600A (43.1 µg/L on July 24, 2018, and 8.37 µg/L on

September 12, 2018). No data quality issues were identified for these samples, and no trend or shift was

identified in the data. Therefore, consistent with the CCR Groundwater Statistical Analysis Plan (Barr,

2019c), no statistical outliers were removed from the background dataset.

To: Project File

From: Denise Levitan and Jennifer Brekken

Subject: Development of Groundwater Protection Standards

Date: July 2019

Page: 2

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Interwell prediction limits were used to calculate background concentrations. Prediction limits were

calculated assuming two statistical evaluations per year with 15 appendix IV constituents in 5

downgradient wells to yield an annual false positive rate of 0.1 or a per-event false positive rate of 0.05

(40 CFR 257.93(g)(2)).

For datasets with less than 15% of observations below laboratory reporting limits, one-half the detection

limit was substituted for non-detect values. For datasets with between 15% and 50% of observations

below laboratory reporting limits, the Kaplan-Meier method was used for non-detect values. For datasets

with greater than 50% of observations below laboratory reporting limits, non-parametric statistical

methods were used (Unified Guidance, Chapter 15). No evaluation or correction for seasonality was done

because the dataset included less than three years of data (Unified Guidance, Chapter 14).

None of the pooled background datasets follow a normal or log-normal distribution, so the non-

parametric prediction limit of the highest value from the pooled background data was used (Unified

Guidance, Chapter 18).

The upper prediction limit of the pooled background data for each appendix IV constituent was compared

to the maximum contaminant level (MCL) or the levels listed in §257.95(h)(2) (regional screening level,

RSL). The higher of the background concentration and the MCL or RSL was set as the Groundwater

Protection Standard (Table C-3).

The statistical outliers described above are below the upper prediction limits, MCL, and/or RSLs and do

not affect the GWPS.

Tables:

Table C-1: Background Data

Table C-2: Normality Test Results

Table C-3: CCR Groundwater Protection Standard Development

Table C-1

CCR Baseline Groundwater Data - Background Wells


Burnsville, MN

W502A W502A W502A W502A W502A W502A W502A W502A

12/12/2017 2/06/2018 3/20/2018 5/09/2018 6/12/2018 7/24/2018 9/11/2018 10/23/2018

N N N N N N N N

Parameter Units


Antimony ug/l < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Arsenic ug/l 35.0 34.2 30.4 32.1 32.7 31.2 34.6 36.8

Barium ug/l 89.7 82.1 79.8 75.7 74.9 76.7 77.0 81.2

Beryllium ug/l < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Cadmium ug/l < 0.500 < 0.500 < 0.500 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100

Chromium ug/l < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 5.00 < 5.00 < 0.500

Cobalt ug/l 3.02 3.35 3.53 3.68 3.46 < 5.00 < 5.00 3.75

Fluoride mg/l < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

Lead ug/l < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Lithium mg/l 0.0938 0.0915 0.0887 0.0900 0.0866 0.0889 0.0900 0.0848

Mercury ug/l < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

Molybdenum ug/l 72.0 67.8 65.9 63.6 63.8 67.9 68.5 67.8

Selenium ug/l < 0.500 < 5.00 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Thallium ug/l < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

Radium 226 pCi/l 0.274 +/- 0.312 0.381 +/- 0.357 ND -0.059 +/- 0.419 ND 0.372 +/- 0.387 ND 0.244 +/- 0.396 ND 0.760 +/- 0.448 0.377 +/- 0.524 ND 0.609 +/- 0.707 ND

Radium 228 pCi/l 1.70 +/- 0.608 1.15 +/- 0.440 0.588 +/- 0.379 ND 0.447 +/- 0.359 ND 0.620 +/- 0.570 ND 0.598 +/- 0.409 ND 0.427 +/- 0.272 ND 0.588 +/- 0.358 ND


CalculationpCi/l 1.97 +/- 0.680 q 1.53 +/- 0.570 q 0.588 +/- 0.380 ND 0.819 +/- 0.530 ND 0.864 +/- 0.690 ND 1.36 +/- 0.610 q 0.804 +/- 0.590 ND 1.20 +/- 0.790 ND

Sample Type

Date

Location

Page 1 of 9

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P:\Mpls\23 MN\19\23191085 Black Dog Site Environment\23191085.17 Black Dog Remediation\WorkFiles\10-CCR-GW Monitoring\Confidential Reporting\Closure Verification\Appendices\C-

GWPS Development\Table C-1_CCR_Background Data.xlsx

Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date

Location W502B W502B W502B W502B W502B W502B W502B W502B

12/12/2017 2/06/2018 3/20/2018 5/09/2018 6/12/2018 7/24/2018 9/11/2018 10/23/2018

N N N N N N N N

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

4.68 4.92 3.64 4.61 4.40 4.30 4.27 4.49

147 153 112 148 142 137 133 146

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 0.718

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.0500 < 0.0500 < 0.0500 < 0.0500 < 0.0500 0.0275 0.0259 0.0240

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.442 +/- 0.378 0.329 +/- 0.334 ND 0.516 +/- 0.622 ND 0.612 +/- 0.505 ND 0.489 +/- 0.442 ND 0.237 +/- 0.358 ND 0.134 +/- 0.491 ND 0.818 +/- 0.723 ND

0.519 +/- 0.406 1.47 +/- 0.593 0.854 +/- 0.550 ND 0.913 +/- 0.402 0.540 +/- 0.485 ND 0.504 +/- 0.360 ND 1.22 +/- 0.422 0.395 +/- 0.336 ND

0.961 +/- 0.550 ND 1.80 +/- 0.680 q 1.37 +/- 0.830 ND 1.53 +/- 0.650 1.03 +/- 0.660 ND 0.741 +/- 0.510 ND 1.35 +/- 0.650 q 1.21 +/- 0.800 ND

Page 2 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date

Location W504A W504A W504A W504A W504A W504A W504A W504A

12/11/2017 2/06/2018 3/20/2018 5/09/2018 6/12/2018 7/23/2018 9/10/2018 10/23/2018

N N N N N N N N

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

1.16 2.20 3.03 2.97 4.24 4.73 2.96 6.06

24.5 24.8 25.0 26.7 27.3 30.5 26.9 31.0

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.100 0.120 0.158 < 0.100 < 0.100

< 0.500 0.543 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.850 1.47 1.71 1.45 2.28 2.38 1.54 2.29

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.0500 < 0.0500 < 0.0500 < 0.0500 < 0.0500 0.0372 0.0414 0.0358

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

72.1 46.8 29.1 24.4 22.1 25.5 57.6 35.9

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.290 +/- 0.330 0.500 +/- 0.350 0.618 +/- 0.555 ND 0.245 +/- 0.296 ND 0.203 +/- 0.245 ND 0.232 +/- 0.387 ND 0.0611 +/- 0.397 ND 0.663 +/- 0.693 ND

0.123 +/- 0.426 0.891 +/- 0.419 1.08 +/- 0.442 0.107 +/- 0.334 ND -0.222 +/- 0.463 ND 0.847 +/- 0.367 0.553 +/- 0.359 ND 0.441 +/- 0.357 ND

0.413 +/- 0.540 ND 1.39 +/- 0.550 1.70 +/- 0.710 q 0.352 +/- 0.450 ND 0.203 +/- 0.250 ND 1.08 +/- 0.530 q 0.614 +/- 0.540 ND 1.10 +/- 0.780 ND

Page 3 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date

Location W504B W504B W504B W504B W504B W504B W504B W504B

12/11/2017 2/06/2018 3/20/2018 5/09/2018 6/12/2018 7/23/2018 9/10/2018 10/23/2018

N N N N N N N N

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

4.53 5.09 4.12 4.34 4.60 4.67 4.09 3.48

372 358 359 367 343 364 349 367

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.100 < 0.100 < 0.100 < 0.100 < 0.100

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.0500 < 0.0500 < 0.0500 < 0.0500 < 0.0500 0.0237 0.0182 0.0209

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.921 +/- 0.473 b 0.601 +/- 0.380 0.335 +/- 0.467 ND 0.915 +/- 0.472 0.882 +/- 0.536 0.594 +/- 0.735 ND 0.535 +/- 0.621 ND 0.650 +/- 0.680 ND

0.375 +/- 0.427 1.78 +/- 0.561 1.21 +/- 0.501 0.777 +/- 0.434 ND 1.02 +/- 0.505 0.871 +/- 0.464 0.469 +/- 0.366 ND 0.764 +/- 0.343

1.30 +/- 0.640 q 2.38 +/- 0.680 1.55 +/- 0.680 q 1.69 +/- 0.640 1.90 +/- 0.740 1.46 +/- 0.870 q 1.00 +/- 0.720 ND 1.41 +/- 0.760 q

Page 4 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date


12/13/2017 2/07/2018 3/21/2018 5/08/2018 6/13/2018 7/25/2018 9/12/2018 10/24/2018

N N N N N N N N

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

2.88 < 5.00 2.81 2.36 4.76 2.68 1.83 1.42

25.1 19.3 16.9 14.8 18.9 19.4 21.9 20.4

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

3.58 4.42 5.47 3.54 3.60 4.08 5.37 3.92

< 0.500 < 5.00 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

8.20 18.1 25.4 14.6 20.6 19.2 21.4 10.9

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.105 0.0855 0.0763 0.0537 0.0619 0.0617 0.0820 0.0553

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

32.1 41.4 36.6 22.5 20.6 20.8 22.9 18.7

1.18 < 5.00 < 0.500 1.09 0.653 0.705 0.549 0.564

1.26 0.972 0.729 0.649 0.703 0.974 1.05 0.982

0.0507 +/- 0.231 0.221 +/- 0.267 ND 0.512 +/- 0.438 ND 0 +/- 0.303 ND -0.053 +/- 0.344 ND 0.582 +/- 0.451 0.433 +/- 0.568 ND 0.560 +/- 0.650 ND

0.468 +/- 0.376 0.208 +/- 0.371 ND 0.0803 +/- 0.285 ND 0.110 +/- 0.290 ND 0.328 +/- 0.639 ND 0.935 +/- 0.466 0.555 +/- 0.404 ND 0.543 +/- 0.344 ND

0.519 +/- 0.440 ND 0.429 +/- 0.460 ND 0.592 +/- 0.520 ND 0.110 +/- 0.420 ND 0.328 +/- 0.640 ND 1.52 +/- 0.650 0.988 +/- 0.700 ND 1.10 +/- 0.740 ND

Page 5 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date


12/13/2017 2/07/2018 3/20/2018 7/24/2018 9/12/2018 10/01/2018 10/24/2018 11/12/2018

N N N N N N N N

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

9.48 11.1 13.1 40.6 39.1 51.0 22.7 37.4

32.4 26.5 22.2 23.7 26.6 23.9 20.0 24.6

1.68 < 0.500 < 0.500 0.717 < 0.500 0.595 0.543 < 0.500

1.97 < 0.500 < 0.500 1.01 0.635 0.181 0.347 0.515

0.773 < 0.500 < 0.500 43.1 8.37 2.45 2.36 3.21

49.1 1.19 < 0.500 39.9 23.5 40.1 40.0 34.6

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

1.29 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.134 0.124 0.0875 0.147 0.170 0.0839 0.0250 0.0990

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

71.8 162 148 66.5 84.1 21.5 2.01 29.9

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.518 < 0.500 < 0.500 < 0.500 < 0.500 0.790 0.670 0.725

0.245 +/- 0.348 0.288 +/- 0.328 ND 0.609 +/- 0.525 ND 0.556 +/- 0.496 ND 0.217 +/- 0.550 ND 0.210 +/- 0.357 ND 0.373 +/- 0.449 ND 0.462 +/- 0.484 ND

0.140 +/- 0.338 0.756 +/- 0.394 0.617 +/- 0.567 ND 0.562 +/- 0.394 ND 1.72 +/- 0.566 1.09 +/- 0.587 0.423 +/- 0.381 ND 0.592 +/- 0.428 ND

0.385 +/- 0.490 ND 1.04 +/- 0.510 q 1.23 +/- 0.770 ND 1.12 +/- 0.630 ND 1.94 +/- 0.790 q 1.30 +/- 0.690 q 0.796 +/- 0.590 ND 1.05 +/- 0.650 ND

Page 6 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date


12/13/2017 3/21/2018 5/08/2018 6/12/2018 7/25/2018 9/12/2018 10/01/2018 10/24/2018

N N N N N N N N

1.39 0.894 0.739 1.18 0.889 0.885 0.878 0.940

12.5 11.9 13.3 6.66 9.44 7.70 10.9 9.30

88.2 74.3 64.3 71.1 72.7 85.6 77.8 78.9

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

< 0.500 < 0.500 < 0.100 0.144 < 0.100 < 0.100 < 1.00 < 0.100

4.49 1.71 0.806 2.33 0.804 0.919 < 5.00 < 0.500

0.789 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 5.00 < 0.500

< 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750 < 0.750

3.20 0.895 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.262 0.348 0.230 0.310 0.384 0.418 0.362 0.356

< 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200 < 0.200

295 243 222 323 255 307 243 220

90.2 43.7 49.0 159 41.8 127 31.1 30.6

< 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500 < 0.500

0.639 +/- 0.381 b -0.057 +/- 0.431 ND 0.164 +/- 0.250 ND 0.388 +/- 0.383 ND 0.402 +/- 0.391 ND 0 +/- 0.458 ND 0.503 +/- 0.496 ND 0.698 +/- 0.645 ND

0.399 +/- 0.399 0.307 +/- 0.299 ND 0.529 +/- 0.377 ND 0.622 +/- 0.448 ND -0.146 +/- 0.346 ND 0.645 +/- 0.433 ND 0.129 +/- 0.368 ND 0.452 +/- 0.359 ND

1.04 +/- 0.550 q 0.307 +/- 0.300 ND 0.693 +/- 0.450 ND 1.01 +/- 0.590 ND 0.402 +/- 0.390 ND 0.645 +/- 0.630 ND 0.632 +/- 0.620 ND 1.15 +/- 0.740 ND

Page 7 of 9

7/26/2019



Table C-1



Burnsville, MN

Parameter Units


Antimony ug/l

Arsenic ug/l

Barium ug/l

Beryllium ug/l

Cadmium ug/l

Chromium ug/l

Cobalt ug/l

Fluoride mg/l

Lead ug/l

Lithium mg/l

Mercury ug/l

Molybdenum ug/l

Selenium ug/l

Thallium ug/l

Radium 226 pCi/l

Radium 228 pCi/l


CalculationpCi/l

Sample Type

Date

Location W601A

11/12/2018

N

1.16

11.8

74.2

< 0.500

< 0.100

< 5.00

< 5.00

< 0.750

< 0.500

0.349

< 0.200

255

70.9

< 0.500

0.326 +/- 0.453 ND

0.225 +/- 0.371 ND

0.551 +/- 0.590 ND

Page 8 of 9

7/26/2019




-- Not analyzed/Not available.

N Sample Type: Normal

FD Sample Type: Field Duplicate

ND Not detected.

* Estimated value, QA/QC criteria not met.

b

Radium 228 result is a potential false positive value based on blank data

validation procedures. Concentrations identified as potential false positive are

excluded from calculations. Combined Radium result is the same as the

Radium 226 result.



Page 9 of 9

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Monitoring\Confidential Reporting\Closure Verification\Appendices\C-GWPS Development\Table C-1_CCR_Background

Data.xlsx

Table C-2

CCR Background Groundwater Goodness-of-Fit


Burnsville, MN

Appendix IV

Parameters%ND Calculated W Critical W Normal Calculated W Critical W Log-Normal

Antimony 84.2 n/a n/a n/a n/a n/a n/a

Arsenic 1.754 0.7416 0.961 No 0.9314 0.961 No

Barium 0 0.7118 0.961 No 0.9189 0.961 No

Beryllium 92.98 n/a n/a n/a n/a n/a n/a

Cadmium 70.18 n/a n/a n/a n/a n/a n/a

Chromium 75.44 n/a n/a n/a n/a n/a n/a

Cobalt 47.37 0.6344 0.961 No 0.8596 0.961 No

Fluoride 100 n/a n/a n/a n/a n/a n/a

Lead 94.74 n/a n/a n/a n/a n/a n/a

Lithium 26.32 0.7054 0.961 No 0.9348 0.961 No

Mercury 100 n/a n/a n/a n/a n/a n/a

Molybdenum 28.07 0.7427 0.961 No 0.8386 0.961 No

Selenium 73.68 n/a n/a n/a n/a n/a n/a

Thallium 78.95 n/a n/a n/a n/a n/a n/a

Radium, combined

(226+228), Barr

Calculation

63.16 n/a n/a n/a n/a n/a n/a

Notes:

ND: Non-Detect

W: Shapiro-Francia test statistic

n/a: normality not assessed for data with >50% NDs

Page 1 of 1

7/12/2019


Monitoring\Confidential Reporting\Closure Verification\Appendices\C-GWPS Development\Table C-2_Norm.xlsx

Table C-3

CCR Groundwater Protection Standard Development


Burnsville, MN

Parameter Units

EPA Maximum

Contaminant

Levels

RSLUpper Prediction

Limit

Groundwater

Protection

Standard


Antimony ug/l 6 1.39 6 MCL

Arsenic ug/l 10 51 51 UPL

Barium ug/l 2000 372 2000 MCL

Beryllium ug/l 4 1.68 4 MCL

Cadmium ug/l 5 5.47 5.47 UPL

Chromium ug/l 100 43.1 100 MCL

Cobalt ug/l 6 49.1 49.1 UPL

Fluoride mg/l 4 0.75 4 MCL

Lead ug/l 15 TT(12) 15 3.2 15 MCL

Lithium mg/l 0.04 0.418 0.418 UPL

Mercury ug/l 2 0.2 2 MCL

Molybdenum ug/l 100 323 323 UPL

Selenium ug/l 50 159 159 UPL

Thallium ug/l 2 1.26 2 MCL

Radium 226 pCi/l 5 (13) -- --

Radium 228 pCi/l 5 (13) -- --

Radium, combined (226+228), Barr

CalculationpCi/l 5 2.38 5 MCL

Notes:

MCL

UPL

RSL

TT(12)

(13)

Maximum contaminant level

Background Upper Prediction Limit. Upper Tolerance Limit and Upper Prediction Limit are

equal because distribution is nonparametric

Based on the criteria for combined radium 226 and 228.

EPA Regional Screening Level, health based standard to be used per CCR Rule

(§257.95(h) as modified by Amendments to the National Minimum Criteria (Phase One, Part

One), July 30, 2018).

MCL is based on a treatment technique; lead action level 0.015 mg/l.

Page 1 of 1

7/26/2019


Monitoring\Confidential Reporting\Closure Verification\Appendices\C-GWPS Development\Table C-3_GWPS.xlsx

Appendix D

Closure Monitoring Data

#=CL#

April 03, 2019



RE:



Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on March 15, 2019. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures





Greensburg, PA 15601(724)850-5600

Page 1 of 18

#=CP#

CERTIFICATIONS








Greensburg, PA 15601(724)850-5600

Page 2 of 18

#=SS#

SAMPLE SUMMARY





30284353002 W 603A Water 03/12/19 09:35 03/15/19 09:30

30284353003 W 604A Water 03/12/19 10:15 03/15/19 09:30

30284353004 W 605A Water 03/12/19 11:15 03/15/19 09:30

30284353005 W 506A Water 03/12/19 12:00 03/15/19 09:30

30284353006 W 601A Water 03/12/19 13:30 03/15/19 09:30

30284353007 W 600A Water 03/12/19 14:35 03/15/19 09:30

30284353008 W 7A Water 03/13/19 09:40 03/15/19 09:30

30284353009 W 602A Water 03/13/19 10:30 03/15/19 09:30

30284353010 W 502A Water 03/13/19 11:30 03/15/19 09:30

30284353011 Duplicate Water 03/13/19 11:30 03/15/19 09:30

30284353012 W502B Water 03/13/19 12:10 03/15/19 09:30

30284353013 W 504A Water 03/13/19 13:10 03/15/19 09:30

30284353014 W 504B Water 03/13/19 13:45 03/15/19 09:30




Greensburg, PA 15601(724)850-5600

Page 3 of 18

#=SA#








30284353002 W 603A EPA 903.1 1 PASI-PAMK1



30284353003 W 604A EPA 903.1 1 PASI-PAMK1



30284353004 W 605A EPA 903.1 1 PASI-PAMK1



30284353005 W 506A EPA 903.1 1 PASI-PAMK1



30284353006 W 601A EPA 903.1 1 PASI-PAMK1



30284353007 W 600A EPA 903.1 1 PASI-PAMK1



30284353008 W 7A EPA 903.1 1 PASI-PAMK1



30284353009 W 602A EPA 903.1 1 PASI-PAMK1



30284353010 W 502A EPA 903.1 1 PASI-PAMK1






30284353012 W502B EPA 903.1 1 PASI-PAMK1



30284353013 W 504A EPA 903.1 1 PASI-PAMK1




Greensburg, PA 15601(724)850-5600

Page 4 of 18

#=SA#







30284353014 W 504B EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 5 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1












Greensburg, PA 15601(724)850-5600

Page 6 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0












Greensburg, PA 15601(724)850-5600

Page 7 of 18

#=NA#

PROJECT NARRATIVE



Method:















Greensburg, PA 15601(724)850-5600

Page 8 of 18

#=ARR#







Radium-226 0.0648 ± 0.421 (0.849)C:NA T:97%

pCi/L 03/28/19 20:37 13982-63-3EPA 903.1

Radium-228 0.991 ± 0.434 (0.719)C:76% T:94%

pCi/L 04/02/19 16:03 15262-20-1EPA 904.0





Radium-226 0.571 ± 0.563 (0.857)C:NA T:86%

pCi/L 03/28/19 20:37 13982-63-3EPA 903.1

Radium-228 0.847 ± 0.461 (0.843)C:76% T:86%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 0.173 ± 0.635 (1.22)C:NA T:79%

pCi/L 03/28/19 20:37 13982-63-3EPA 903.1

Radium-228 0.253 ± 0.352 (0.756)C:74% T:94%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 -0.216 ± 0.425 (1.02)C:NA T:89%

pCi/L 03/28/19 20:37 13982-63-3EPA 903.1

Radium-228 0.736 ± 0.461 (0.862)C:74% T:73%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 0.274 ± 0.315 (0.186)C:NA T:86%

pCi/L 03/28/19 20:37 13982-63-3EPA 903.1

Radium-228 0.547 ± 0.418 (0.832)C:76% T:87%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 18

#=ARR#











Radium-226 0.0680 ± 0.442 (0.891)C:NA T:89%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 0.456 ± 0.392 (0.793)C:72% T:93%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 -0.077 ± 0.402 (0.930)C:NA T:77%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 1.08 ± 0.494 (0.835)C:73% T:84%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 0.324 ± 0.383 (0.602)C:NA T:92%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 0.0840 ± 0.381 (0.866)C:73% T:81%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Radium-226 0.262 ± 0.364 (0.608)C:NA T:95%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 0.762 ± 0.381 (0.670)C:74% T:105%

pCi/L 04/02/19 16:04 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 18

#=ARR#







Radium-226 0.610 ± 0.446 (0.498)C:NA T:91%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 1.80 ± 0.658 (1.04)C:75% T:86%

pCi/L 04/02/19 15:59 15262-20-1EPA 904.0





Radium-226 0.352 ± 0.547 (0.947)C:NA T:73%

pCi/L 03/28/19 20:50 13982-63-3EPA 903.1

Radium-228 0.666 ± 0.513 (1.03)C:73% T:80%

pCi/L 04/02/19 15:59 15262-20-1EPA 904.0





Radium-226 0.291 ± 0.572 (1.03)C:NA T:87%

pCi/L 03/28/19 21:02 13982-63-3EPA 903.1

Radium-228 1.06 ± 0.574 (1.06)C:72% T:80%

pCi/L 04/02/19 15:59 15262-20-1EPA 904.0





Radium-226 -0.222 ± 0.481 (1.11)C:NA T:89%

pCi/L 03/28/19 21:02 13982-63-3EPA 903.1

Radium-228 0.341 ± 0.489 (1.05)C:70% T:85%

pCi/L 04/02/19 15:59 15262-20-1EPA 904.0





Radium-226 0.807 ± 0.539 (0.668)C:NA T:98%

pCi/L 03/28/19 21:02 13982-63-3EPA 903.1

Radium-228 0.604 ± 0.489 (0.995)C:75% T:93%

pCi/L 04/02/19 15:59 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 18

#=ARR#











Greensburg, PA 15601(724)850-5600

Page 12 of 18

#=QCR#







334212EPA 904.0

EPA 904.0904.0 Radium 228

Associated Lab Samples: 30284353001, 30284353002, 30284353003, 30284353004, 30284353005, 30284353006, 30284353007,30284353008, 30284353009, 30284353010, 30284353011, 30284353012, 30284353013, 30284353014




Matrix: Water

Analyzed

Radium-228 pCi/L 04/02/19 16:070.447 ± 0.341 (0.671) C:78% T:92%




Greensburg, PA 15601(724)850-5600

Page 13 of 18

#=QCR#







334202EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 03/28/19 20:37-0.137 ± 0.381 (0.899) C:NA T:88%




Greensburg, PA 15601(724)850-5600

Page 14 of 18

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 15 of 18


1518 Chestnut Ave N



WI-999071150

Christine Keefe, Manager (612) 630-4506

Amended ReportOriginal Report ID: MEC0098 Xcel General Report FINAL 03 28 2019

0851


RE: Black Dog CCR


250 Marquette Plaza

Eric Ealy

Steve Davis

Project Manager






Sincerely,

15 May 2019

cc: Removed analysis per client request. HSD

5/15/19


Project Manager: Eric Ealy

Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851



MEC0098-01 Water 03/14/2019 10:5003/12/2019 9:00Field Blank

MEC0098-02 Water 03/14/2019 10:5003/12/2019 9:35W603A

MEC0098-03 Water 03/14/2019 10:5003/12/2019 10:15W604A

MEC0098-04 Water 03/14/2019 10:5003/12/2019 11:15W605A

MEC0098-05 Water 03/14/2019 10:5003/12/2019 12:00W506A

MEC0098-06 Water 03/14/2019 10:5003/12/2019 13:30W601A

MEC0098-07 Water 03/14/2019 10:5003/12/2019 14:35W600A

MEC0098-08 Water 03/14/2019 10:5003/13/2019 9:40W7A

MEC0098-09 Water 03/14/2019 10:5003/13/2019 10:30W602A

MEC0098-10 Water 03/14/2019 10:5003/13/2019 11:30W502A

MEC0098-11 Water 03/14/2019 10:5003/13/2019 11:30Duplicate

MEC0098-12 Water 03/14/2019 10:5003/13/2019 12:10W502B

MEC0098-13 Water 03/14/2019 10:5003/13/2019 13:10W504A

MEC0098-14 Water 03/14/2019 10:5003/13/2019 13:45W504B



entirety.

Page 1 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting


MEC0098-01 (Water) - Chain of Custody Number: 2286822/2286820

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L BEC0244 EPA 300.0< 1.00 CRL3/15/19 10:433/15/19 5:541

Fluoride 0.750 mg/L BEC0244 EPA 300.0< 0.750 CRL3/15/19 10:433/15/19 5:541

Sulfate 1.00 mg/L BEC0244 EPA 300.0< 1.00 CRL3/15/19 10:433/15/19 5:541

Wet Chemistry

Alkalinity, Total 10.0 mg/L BEC0230 SM 2320B< 10.0 CRL3/14/19 14:483/14/19 11:491

pH pH Units BEC0230 SM 4500-H+ B6.69 CRLM_TTT 3/14/19 14:483/14/19 11:491

Total Dissolved Solids 20.0 mg/L BEC0246 SM 2540C< 20.0 HSD3/15/19 8:363/15/19 8:361


Arsenic 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Barium 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Beryllium 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Cadmium 0.100 ug/L BEC0319 EPA 200.8< 0.100 CRL3/20/19 8:183/19/19 10:521

Cobalt 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Chromium 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Molybdenum 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Lead 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Antimony 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Selenium 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Thallium 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 8:183/19/19 10:521

Total Metals by ICP

Boron 0.0500 mg/L BEC0318 EPA 200.7< 0.0500 HRD3/20/19 14:243/19/19 10:461

Calcium 1.50 mg/L BEC0318 EPA 200.7< 1.50 HRD3/20/19 14:223/19/19 10:461

Potassium 1.50 mg/L BEC0318 EPA 200.7< 1.50 HRD3/20/19 14:223/19/19 10:461

Lithium 0.0150 mg/L BEC0318 EPA 200.7< 0.0150 HRD3/20/19 14:223/19/19 10:461

Magnesium 1.50 mg/L BEC0318 EPA 200.7< 1.50 HRD3/20/19 14:233/19/19 10:461

Sodium 1.50 mg/L BEC0318 EPA 200.7< 1.50 HRD3/20/19 14:223/19/19 10:461



entirety.

Page 2 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L BEC0342 EPA 245.1, 7470A< 0.200 HRD3/20/19 14:053/20/19 8:391



entirety.

Page 3 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W603A

Qualifier

Analyte


Chloride 1.00 mg/L BEC0244 EPA 300.069.6 CRL3/15/19 11:043/15/19 5:541


Sulfate 1.00 mg/L BEC0244 EPA 300.0261 CRL3/15/19 11:043/15/19 5:541

Wet Chemistry

Alkalinity, Total 10.0 mg/L BEC0230 SM 2320B40.5 CRL3/14/19 14:543/14/19 11:491


Total Dissolved Solids 20.0 mg/L BEC0246 SM 2540C542 HSD3/15/19 8:363/15/19 8:361


Arsenic 0.500 ug/L BEC0319 EPA 200.85.18 CRL3/20/19 8:303/19/19 10:521

Barium 0.500 ug/L BEC0319 EPA 200.842.8 CRL3/20/19 8:303/19/19 10:521





Molybdenum 0.500 ug/L BEC0319 EPA 200.8158 CRL3/20/19 8:303/19/19 10:521


Antimony 0.500 ug/L BEC0319 EPA 200.81.21 CRL3/20/19 8:303/19/19 10:521

Selenium 0.500 ug/L BEC0319 EPA 200.81.42 CRL3/20/19 8:303/19/19 10:521


Total Metals by ICP

Boron 0.0500 mg/L BEC0318 EPA 200.75.30 HRD3/20/19 14:393/19/19 10:461

Calcium 1.50 mg/L BEC0318 EPA 200.757.5 HRD3/20/19 14:383/19/19 10:461

Potassium 1.50 mg/L BEC0318 EPA 200.713.5 HRD3/20/19 14:383/19/19 10:461

Lithium 0.0150 mg/L BEC0318 EPA 200.70.109 HRD3/20/19 14:383/19/19 10:461

Magnesium 1.50 mg/L BEC0318 EPA 200.77.61 HRD3/20/19 14:383/19/19 10:461

Sodium 1.50 mg/L BEC0318 EPA 200.790.4 HRD3/20/19 14:383/19/19 10:461



entirety.

Page 4 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W604A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 6 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W605A

Qualifier

Analyte





Wet Chemistry











Molybdenum 0.500 ug/L BEC0319 EPA 200.888.8 CRL3/20/19 8:383/19/19 10:521





Total Metals by ICP




Lithium 0.0150 mg/L BEC0318 EPA 200.7< 0.0150 HRD3/20/19 14:483/19/19 10:461





entirety.

Page 8 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W506A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L BEC0230 SM 2320B132 CRL3/14/19 15:173/14/19 11:491







Cadmium 0.100 ug/L BEC0319 EPA 200.81.98 CRL3/20/19 8:413/19/19 10:521

Cobalt 0.500 ug/L BEC0319 EPA 200.85.20 CRL3/20/19 8:413/19/19 10:521







Total Metals by ICP


Calcium 1.50 mg/L BEC0318 EPA 200.7223 HRD3/20/19 14:533/19/19 10:461







entirety.

Page 10 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W601A

Qualifier

Analyte


Chloride 1.00 mg/L BEC0244 EPA 300.0139 CRL3/15/19 13:063/15/19 5:541



Wet Chemistry










Chromium 0.500 ug/L BEC0319 EPA 200.80.638 CRL3/20/19 8:453/19/19 10:521






Total Metals by ICP





Magnesium 1.50 mg/L BEC0318 EPA 200.7< 1.50 HRD3/20/19 14:593/19/19 10:461

Sodium 1.50 mg/L BEC0318 EPA 200.7269 HRD3/20/19 14:583/19/19 10:461



entirety.

Page 12 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W600A

Qualifier

Analyte





Wet Chemistry










Chromium 0.500 ug/L BEC0319 EPA 200.80.631 CRL3/20/19 8:493/19/19 10:521






Total Metals by ICP









entirety.

Page 14 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 18 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 19 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 20 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 21 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 22 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 23 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W502B

Qualifier

Analyte





Wet Chemistry






Barium 0.500 ug/L BEC0319 EPA 200.8143 CRL3/20/19 9:173/19/19 10:521





Molybdenum 0.500 ug/L BEC0319 EPA 200.8< 0.500 CRL3/20/19 9:173/19/19 10:521





Total Metals by ICP





Magnesium 1.25 mg/L BEC0318 EPA 200.7117 HRD3/25/19 12:303/19/19 10:461




entirety.

Page 24 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 25 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W504A

Qualifier

Analyte





Wet Chemistry












Lead 0.500 ug/L BEC0319 EPA 200.81.47 CRL3/20/19 9:213/19/19 10:521




Total Metals by ICP









entirety.

Page 26 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L BEC0244 EPA 300.03.23 CRL3/15/19 18:533/15/19 5:541

Wet Chemistry






Barium 0.500 ug/L BEC0319 EPA 200.8350 CRL3/20/19 9:253/19/19 10:521










Total Metals by ICP









entirety.

Page 28 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851


Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 29 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEC0244 - Wet Prep

Blank (BEC0244-BLK1) Prepared & Analyzed: 03/15/2019








LCS (BEC0244-BS1) Prepared & Analyzed: 03/15/2019

Chloride 1.00 25.000 90-11099.1mg/L24.8

Fluoride 0.750 2.5000 90-110105mg/L2.64

Sulfate 1.00 48.000 90-110101mg/L48.4


Chloride 1.00 25.000 90-110101mg/L25.2

Fluoride 0.750 2.5000 90-110109mg/L2.74

Sulfate 1.00 48.000 90-110104mg/L49.7


Chloride 1.00 25.000 90-110100mg/L25.0

Fluoride 0.750 2.5000 90-110110mg/L2.74

Sulfate 1.00 48.000 90-110103mg/L49.4

Duplicate (BEC0244-DUP1) Prepared & Analyzed: 03/15/2019Source: MEC0098-02

Chloride 1.00 201.32mg/L68.6 69.6

Fluoride 0.750 206.98mg/L0.318 0.341

Sulfate 1.00 201.10mg/L258 261



entirety.

Page 30 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 201.01mg/L42.6 43.0

Fluoride 0.750 206.47mg/L0.367 0.344

Sulfate 1.00 201.88mg/L3.17 3.23

Matrix Spike (BEC0244-MS1) Prepared & Analyzed: 03/15/2019Source: MEC0098-02

Chloride 1.25 31.250 80-12099.2mg/L101 69.6

Fluoride 0.938 3.1250 80-120108mg/L3.37 <0.938

Sulfate 1.25 60.000 80-12098.5mg/L320 261


Chloride 1.25 31.250 80-120102mg/L74.8 43.0

Fluoride 0.938 3.1250 80-120113mg/L3.52 <0.938

Sulfate 1.25 60.000 80-120105mg/L66.5 3.23

Matrix Spike Dup (BEC0244-MSD1) Prepared & Analyzed: 03/15/2019Source: MEC0098-02

Chloride 1.25 31.250 2080-12099.6 0.134mg/L101 69.6

Fluoride 0.938 3.1250 2080-120118 8.72mg/L3.68 <0.938

Sulfate 1.25 60.000 2080-12098.7 0.0359mg/L320 261


Chloride 1.25 31.250 2080-120103 0.557mg/L75.2 43.0

Fluoride 0.938 3.1250 2080-120118 4.20mg/L3.67 <0.938

Sulfate 1.25 60.000 2080-120106 0.817mg/L67.0 3.23



entirety.

Page 31 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




pH 7.0000 90-110101pH Units7.08




pH 7.0000 90-110101pH Units7.08


pH 201.53pH Units9.21 9.07



pH 200.134pH Units7.44 7.45






Total Suspended Solids 4.00 202.15mg/L18.8 18.4






entirety.

Page 32 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte









Total Suspended Solids 4.00 20 M_D-RL22.2mg/L4.00 3.20








entirety.

Page 33 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEC0319 - EPA 200.2, EPA 3005

Blank (BEC0319-BLK1) Prepared: 03/19/2019 Analyzed: 03/20/2019




Cobalt 0.500 ug/L<0.500



Lead 0.500 ug/L<0.500




Barium 0.500 ug/L<0.500

LCS (BEC0319-BS1) Prepared: 03/19/2019 Analyzed: 03/20/2019

Beryllium 0.500 100.00 85-11593.2ug/L93.2

Cadmium 0.100 100.00 85-11596.4ug/L96.4

Cobalt 0.500 100.00 85-115100ug/L100

Thallium 0.500 100.00 85-115100ug/L100

Arsenic 0.500 100.00 85-115102ug/L102

Chromium 0.500 100.00 85-115101ug/L101

Molybdenum 0.500 100.00 85-11597.2ug/L97.2

Selenium 0.500 100.00 85-115101ug/L101

Antimony 0.500 100.00 85-115102ug/L102

Barium 0.500 100.00 85-115102ug/L102

Lead 0.500 100.00 85-11599.7ug/L99.7

Duplicate (BEC0319-DUP1) Prepared: 03/19/2019 Analyzed: 03/20/2019Source: MEC0098-04

Chromium 0.500 201.24ug/L0.209 0.206


Arsenic 0.500 209.97ug/L4.24 4.69

Barium 0.500 200.0989ug/L49.8 49.8

Cadmium 0.100 20ug/L<0.100 <0.100

Molybdenum 0.500 200.426ug/L88.4 88.8

Cobalt 0.500 2019.4ug/L0.143 0.118

Lead 0.500 20 M_D-RL25.7ug/L0.0483 0.0373

Antimony 0.500 2012.0ug/L0.229 0.203


Thallium 0.500 20ug/L0.0186 <0.500



entirety.

Page 34 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Cobalt 0.500 201.67ug/L5.12 5.20

Arsenic 0.500 202.03ug/L2.43 2.38

Barium 0.500 201.44ug/L11.2 11.1

Beryllium 0.500 201.49ug/L0.0348 0.0343

Thallium 0.500 202.23ug/L0.404 0.395

Cadmium 0.100 200.558ug/L1.99 1.98


Molybdenum 0.500 200.820ug/L30.8 30.6

Lead 0.500 201.35ug/L0.0322 0.0318


Selenium 0.500 20ug/L<0.500 0.0898

Matrix Spike (BEC0319-MS1) Prepared: 03/19/2019 Analyzed: 03/20/2019Source: MEC0098-04

Cobalt 0.500 100.00 70-13097.7ug/L97.9 0.118

Thallium 0.500 100.00 70-13094.0ug/L94.0 <0.500

Lead 0.500 100.00 70-13091.3ug/L91.3 0.0373

Arsenic 0.500 100.00 70-130105ug/L109 4.69

Selenium 0.500 100.00 70-13098.5ug/L98.8 0.352

Cadmium 0.100 100.00 70-13094.9ug/L94.9 <0.100

Antimony 0.500 100.00 70-130101ug/L101 0.203

Beryllium 0.500 100.00 70-13094.8ug/L94.9 0.0197

Molybdenum 0.500 100.00 70-130108ug/L197 88.8

Barium 0.500 100.00 70-130103ug/L152 49.8

Chromium 0.500 100.00 70-130100ug/L101 0.206


Selenium 0.500 100.00 70-130102ug/L102 0.0898

Cadmium 0.100 100.00 70-13094.1ug/L96.1 1.98

Chromium 0.500 100.00 70-13099.7ug/L99.8 0.0724

Cobalt 0.500 100.00 70-13099.4ug/L105 5.20

Thallium 0.500 100.00 70-13093.4ug/L93.8 0.395

Arsenic 0.500 100.00 70-130110ug/L112 2.38

Molybdenum 0.500 100.00 70-13097.9ug/L129 30.6

Barium 0.500 100.00 70-130101ug/L112 11.1

Beryllium 0.500 100.00 70-13088.9ug/L89.0 0.0343

Antimony 0.500 100.00 70-13098.9ug/L99.0 0.0816

Lead 0.500 100.00 70-13088.9ug/L89.0 0.0318



entirety.

Page 35 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BEC0319-MSD1) Prepared: 03/19/2019 Analyzed: 03/20/2019Source: MEC0098-04

Beryllium 0.500 100.00 2070-13094.3 0.563ug/L94.3 0.0197

Arsenic 0.500 100.00 2070-130104 0.417ug/L109 4.69

Chromium 0.500 100.00 2070-130101 0.575ug/L101 0.206

Barium 0.500 100.00 2070-130100 1.48ug/L150 49.8

Selenium 0.500 100.00 2070-13099.2 0.753ug/L99.6 0.352

Cobalt 0.500 100.00 2070-13098.6 0.870ug/L98.7 0.118

Antimony 0.500 100.00 2070-130102 0.815ug/L102 0.203

Cadmium 0.100 100.00 2070-13096.4 1.63ug/L96.4 <0.100

Molybdenum 0.500 100.00 2070-130103 2.87ug/L192 88.8

Thallium 0.500 100.00 2070-13092.4 1.71ug/L92.4 <0.500

Lead 0.500 100.00 2070-13092.2 0.997ug/L92.2 0.0373


Molybdenum 0.500 100.00 2070-130101 2.31ug/L132 30.6

Selenium 0.500 100.00 2070-130102 0.0869ug/L102 0.0898

Cobalt 0.500 100.00 2070-13098.7 0.704ug/L104 5.20

Cadmium 0.100 100.00 2070-13092.5 1.61ug/L94.5 1.98

Beryllium 0.500 100.00 2070-13090.6 1.86ug/L90.6 0.0343

Thallium 0.500 100.00 2070-13094.5 1.18ug/L94.9 0.395

Lead 0.500 100.00 2070-13089.1 0.230ug/L89.2 0.0318

Arsenic 0.500 100.00 2070-130111 0.954ug/L113 2.38

Chromium 0.500 100.00 2070-130101 0.971ug/L101 0.0724

Antimony 0.500 100.00 2070-130100 1.47ug/L100 0.0816

Barium 0.500 100.00 2070-130103 2.29ug/L114 11.1



entirety.

Page 36 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Blank (BEC0318-BLK1) Prepared: 03/19/2019 Analyzed: 03/20/2019

Boron 0.0500 mg/L<0.0500




Lithium 0.0150 mg/L<0.0150


LCS (BEC0318-BS1) Prepared: 03/19/2019 Analyzed: 03/20/2019

Potassium 1.50 100.00 85-11598.7mg/L98.7

Boron 0.0500 1.0000 85-11597.9mg/L0.979

Lithium 0.0150 1.0000 85-11599.2mg/L0.992

Magnesium 1.50 100.00 85-115101mg/L101

Calcium 1.50 100.00 85-115102mg/L102

Sodium 1.50 100.00 85-115103mg/L103


Potassium 1.50 206.78mg/L14.5 13.5

Calcium 1.50 204.97mg/L60.5 57.5

Boron 0.0500 203.45mg/L5.48 5.30

Sodium 1.50 204.72mg/L94.8 90.4

Magnesium 1.50 204.63mg/L7.98 7.61

Lithium 0.0150 204.86mg/L0.114 0.109


Sodium 1.50 200.836mg/L83.4 82.7

Potassium 1.50 201.61mg/L5.42 5.33

Calcium 1.50 200.928mg/L68.0 67.4

Magnesium 1.50 200.518mg/L12.8 12.7

Boron 0.0500 201.97mg/L3.46 3.39

Lithium 0.0150 200.322mg/L0.0292 0.0291



entirety.

Page 37 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Calcium 1.50 100.00 70-130103mg/L161 57.5

Boron 0.0500 1.0000 70-130129mg/L6.58 5.30

Lithium 0.0150 1.0000 70-13099.2mg/L1.10 0.109

Sodium 1.50 100.00 70-130106mg/L196 90.4

Magnesium 1.50 100.00 70-130101mg/L109 7.61

Potassium 1.50 100.00 70-13098.8mg/L112 13.5


Lithium 0.0150 1.0000 70-13099.3mg/L1.02 0.0291

Sodium 1.50 100.00 70-130107mg/L190 82.7

Potassium 1.50 100.00 70-13098.8mg/L104 5.33

Calcium 1.50 100.00 70-130105mg/L173 67.4

Boron 0.0500 1.0000 70-130117mg/L4.56 3.39

Magnesium 1.50 100.00 70-130102mg/L115 12.7


Sodium 1.50 100.00 2070-130111 2.81mg/L202 90.4

Magnesium 1.50 100.00 2070-130103 1.39mg/L110 7.61

Lithium 0.0150 1.0000 2070-130100 1.00mg/L1.11 0.109

Potassium 1.50 100.00 2070-130100 1.26mg/L114 13.5

Calcium 1.50 100.00 2070-130107 2.40mg/L165 57.5

Boron 0.0500 1.0000 20 M_MS70-130136 1.05mg/L6.65 5.30


Lithium 0.0150 1.0000 2070-13097.2 2.09mg/L1.00 0.0291

Boron 0.0500 1.0000 2070-130119 0.383mg/L4.58 3.39

Sodium 1.50 100.00 2070-130104 1.50mg/L187 82.7

Calcium 1.50 100.00 2070-130103 1.44mg/L170 67.4

Magnesium 1.50 100.00 2070-130100 1.82mg/L113 12.7

Potassium 1.50 100.00 2070-13096.5 2.19mg/L102 5.33



entirety.

Page 38 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEC0342 - EPA 245.1, EPA 7470A




Mercury 0.200 3.0030 85-11590.7ug/L2.73


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 3.0030 70-13097.0ug/L2.91 <0.200


Mercury 0.200 3.0030 70-13094.2ug/L2.83 <0.200


Mercury 0.200 3.0030 2070-13093.1 4.07ug/L2.80 <0.200


Mercury 0.200 3.0030 2070-13094.9 0.701ug/L2.85 <0.200



entirety.

Page 39 of 40



Reported:


250 Marquette Plaza

05/15/2019 11:44Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



0851








dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 40 of 40

#=CL#

June 07, 2019



RE:


19-01923,XCEL ENERGY Black Dog

Dear Dave Anderson:Enclosed are the analytical results for sample(s) received by the laboratory on May 17, 2019. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures

cc: Eric Ealy, Xcel EnergyChristine M. Keefe, Xcel EnergyCiara Ruikkie, Pace Analytical Services - Field SvcsDivision




Greensburg, PA 15601(724)850-5600

Page 1 of 18

#=CP#

CERTIFICATIONS



Pennsylvania Certification IDs1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601ANAB DOD-ELAP Rad Accreditation #: L2417Alabama Certification #: 41590Arizona Certification #: AZ0734Arkansas CertificationCalifornia Certification #: 04222CAColorado Certification #: PA01547Connecticut Certification #: PH-0694Delaware CertificationEPA Region 4 DW RadFlorida/TNI Certification #: E87683Georgia Certification #: C040Florida: Cert E871149 SEKS WETGuam CertificationHawaii CertificationIdaho CertificationIllinois CertificationIndiana CertificationIowa Certification #: 391Kansas/TNI Certification #: E-10358Kentucky Certification #: KY90133KY WW Permit #: KY0098221KY WW Permit #: KY0000221Louisiana DHH/TNI Certification #: LA180012Louisiana DEQ/TNI Certification #: 4086Maine Certification #: 2017020Maryland Certification #: 308Massachusetts Certification #: M-PA1457Michigan/PADEP Certification #: 9991





Greensburg, PA 15601(724)850-5600

Page 2 of 18

#=SS#

SAMPLE SUMMARY





30295102002 W 603A Water 05/14/19 08:50 05/17/19 09:30

30295102003 W 604A Water 05/14/19 09:50 05/17/19 09:30

30295102004 W 605A Water 05/14/19 10:50 05/17/19 09:30

30295102005 W 506A Water 05/14/19 11:40 05/17/19 09:30

30295102006 W 601A Water 05/14/19 12:30 05/17/19 09:30

30295102007 W 600A Water 05/14/19 13:25 05/17/19 09:30

30295102008 W 504A Water 05/14/19 14:10 05/17/19 09:30

30295102009 W 504B Water 05/14/19 14:40 05/17/19 09:30

30295102010 W 502A Water 05/15/19 09:10 05/17/19 09:30

30295102011 W 502B Water 05/15/19 10:00 05/17/19 09:30

30295102012 Duplicate Water 05/15/19 10:00 05/17/19 09:30

30295102013 W 602A Water 05/15/19 10:50 05/17/19 09:30

30295102014 W 7A Water 05/15/19 11:40 05/17/19 09:30




Greensburg, PA 15601(724)850-5600

Page 3 of 18

#=SA#








30295102002 W 603A EPA 903.1 1 PASI-PAMK1



30295102003 W 604A EPA 903.1 1 PASI-PAMK1



30295102004 W 605A EPA 903.1 1 PASI-PAMK1



30295102005 W 506A EPA 903.1 1 PASI-PAMK1



30295102006 W 601A EPA 903.1 1 PASI-PAMK1



30295102007 W 600A EPA 903.1 1 PASI-PAMK1



30295102008 W 504A EPA 903.1 1 PASI-PAMK1



30295102009 W 504B EPA 903.1 1 PASI-PAMK1



30295102010 W 502A EPA 903.1 1 PASI-PAMK1



30295102011 W 502B EPA 903.1 1 PASI-PAMK1






30295102013 W 602A EPA 903.1 1 PASI-PAMK1




Greensburg, PA 15601(724)850-5600

Page 4 of 18

#=SA#







30295102014 W 7A EPA 903.1 1 PASI-PAMK1






Greensburg, PA 15601(724)850-5600

Page 5 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 903.1

Date: June 07, 2019











Greensburg, PA 15601(724)850-5600

Page 6 of 18

#=NA#

PROJECT NARRATIVE



Method:


EPA 904.0

Date: June 07, 2019











Greensburg, PA 15601(724)850-5600

Page 7 of 18

#=NA#

PROJECT NARRATIVE



Method:



Date: June 07, 2019












Greensburg, PA 15601(724)850-5600

Page 8 of 18

#=ARR#







Radium-226 0.937 ± 0.678 (0.944)C:NA T:82%

pCi/L 06/06/19 10:43 13982-63-3EPA 903.1

Radium-228 0.0219 ± 0.764 (1.75)C:79% T:79%

pCi/L 06/03/19 21:03 15262-20-1EPA 904.0





Radium-226 0.236 ± 0.402 (0.709)C:NA T:95%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.150 ± 0.780 (1.77)C:79% T:69%

pCi/L 06/03/19 21:03 15262-20-1EPA 904.0





Radium-226 0.205 ± 0.484 (0.897)C:NA T:88%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.819 ± 0.824 (1.71)C:69% T:80%

pCi/L 06/03/19 21:03 15262-20-1EPA 904.0





Radium-226 0.473 ± 0.516 (0.811)C:NA T:83%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 -0.504 ± 0.635 (1.54)C:74% T:89%

pCi/L 06/03/19 21:03 15262-20-1EPA 904.0





Radium-226 0.126 ± 0.463 (0.890)C:NA T:87%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.0718 ± 0.709 (1.61)C:76% T:89%

pCi/L 06/03/19 21:03 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 9 of 18

#=ARR#











Radium-226 0.919 ± 0.547 (0.520)C:NA T:76%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.327 ± 0.586 (1.28)C:78% T:72%

pCi/L 06/03/19 19:45 15262-20-1EPA 904.0





Radium-226 0.516 ± 0.540 (0.845)C:NA T:87%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.278 ± 0.527 (1.16)C:73% T:91%

pCi/L 06/03/19 19:45 15262-20-1EPA 904.0





Radium-226 0.172 ± 0.373 (0.689)C:NA T:87%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 0.427 ± 0.376 (0.765)C:84% T:79%

pCi/L 06/06/19 12:50 15262-20-1EPA 904.0





Radium-226 0.957 ± 0.624 (0.845)C:NA T:90%

pCi/L 06/06/19 10:56 13982-63-3EPA 903.1

Radium-228 1.12 ± 0.651 (1.20)C:76% T:83%

pCi/L 06/03/19 19:46 15262-20-1EPA 904.0





Greensburg, PA 15601(724)850-5600

Page 10 of 18

#=ARR#







Radium-226 0.674 ± 0.471 (0.569)C:NA T:89%

pCi/L 06/06/19 11:19 13982-63-3EPA 903.1

Radium-228 0.458 ± 0.598 (1.27)C:75% T:76%

pCi/L 06/03/19 20:30 15262-20-1EPA 904.0





Radium-226 0.463 ± 0.428 (0.623)C:NA T:93%

pCi/L 06/06/19 11:19 13982-63-3EPA 903.1

Radium-228 0.409 ± 0.622 (1.35)C:71% T:88%

pCi/L 06/03/19 20:30 15262-20-1EPA 904.0





Radium-226 0.631 ± 0.435 (0.465)C:NA T:89%

pCi/L 06/06/19 11:19 13982-63-3EPA 903.1

Radium-228 0.792 ± 0.653 (1.31)C:70% T:83%

pCi/L 06/03/19 20:30 15262-20-1EPA 904.0





Radium-226 0.495 ± 0.371 (0.192)C:NA T:82%

pCi/L 06/06/19 11:19 13982-63-3EPA 903.1

Radium-228 0.641 ± 0.645 (1.34)C:70% T:83%

pCi/L 06/03/19 20:30 15262-20-1EPA 904.0





Radium-226 0.556 ± 0.383 (0.409)C:NA T:93%

pCi/L 06/06/19 11:19 13982-63-3EPA 903.1

Radium-228 1.15 ± 0.785 (1.52)C:75% T:72%

pCi/L 06/03/19 20:30 15262-20-1EPA 904.0




Greensburg, PA 15601(724)850-5600

Page 11 of 18

#=ARR#











Greensburg, PA 15601(724)850-5600

Page 12 of 18

#=QCR#







343316EPA 903.1

EPA 903.1903.1 Radium-226





Matrix: Water

Analyzed

Radium-226 pCi/L 06/06/19 10:430.350 ± 0.406 (0.655) C:NA T:89%




Greensburg, PA 15601(724)850-5600

Page 13 of 18

#=QCR#







343326EPA 904.0

EPA 904.0904.0 Radium 228





Matrix: Water

Analyzed

Radium-228 pCi/L 06/03/19 13:380.718 ± 0.345 (0.576) C:84% T:80%




Greensburg, PA 15601(724)850-5600

Page 14 of 18

#=QL#

QUALIFIERS



DEFINITIONS


LABORATORIES





Greensburg, PA 15601(724)850-5600

Page 15 of 18


1518 Chestnut Ave N



WI-999071150



RE: Black Dog CCR


250 Marquette Plaza

Eric Ealy

Steve Davis

Project Manager






Sincerely,

28 May 2019

cc:



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




MEE0179-01 Water 05/15/2019 12:4505/14/2019 8:10Field Blank

MEE0179-02 Water 05/15/2019 12:4505/14/2019 8:50W603A

MEE0179-03 Water 05/15/2019 12:4505/14/2019 9:50W604A

MEE0179-04 Water 05/15/2019 12:4505/14/2019 10:50W605A

MEE0179-05 Water 05/15/2019 12:4505/14/2019 11:40W506A

MEE0179-06 Water 05/15/2019 12:4505/14/2019 12:30W601A

MEE0179-07 Water 05/15/2019 12:4505/14/2019 13:25W600A

MEE0179-08 Water 05/15/2019 12:4505/14/2019 14:10W504A

MEE0179-09 Water 05/15/2019 12:4505/14/2019 14:40W504B

MEE0179-10 Water 05/15/2019 12:4505/15/2019 9:10W502A

MEE0179-11 Water 05/15/2019 12:4505/15/2019 10:00W502B

MEE0179-12 Water 05/15/2019 12:4505/15/2019 10:00Duplicate

MEE0179-13 Water 05/15/2019 12:4505/15/2019 10:50W602A

MEE0179-14 Water 05/15/2019 12:4505/15/2019 11:40W7A



entirety.

Page 1 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting


MEE0179-01 (Water) - Chain of Custody Number: 2273477/2273471

Field Blank

Qualifier

Analyte


Chloride 1.00 mg/L BEE0412 EPA 300.0< 1.00 CRL5/17/19 12:165/17/19 6:061

Fluoride 0.750 mg/L BEE0412 EPA 300.0< 0.750 CRL5/17/19 12:165/17/19 6:061

Sulfate 1.00 mg/L BEE0412 EPA 300.0< 1.00 CRL5/17/19 12:165/17/19 6:061

Wet Chemistry

Alkalinity, Total 10.0 mg/L BEE0361 SM 2320B< 10.0 CRL5/15/19 14:355/15/19 13:091

pH pH Units BEE0361 SM 4500-H+ B7.04 CRLM_TTT 5/15/19 14:355/15/19 13:091

Total Dissolved Solids 20.0 mg/L BEE0382 SM 2540C< 20.0 HSD5/16/19 8:505/16/19 8:501


Arsenic 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Barium 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Beryllium 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Cadmium 0.100 ug/L BEE0386 EPA 200.8< 0.100 CRL5/20/19 8:545/16/19 7:321

Cobalt 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Chromium 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Molybdenum 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Lead 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Antimony 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Selenium 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Thallium 0.500 ug/L BEE0386 EPA 200.8< 0.500 CRL5/20/19 8:545/16/19 7:321

Total Metals by ICP

Boron 0.0500 mg/L BEE0385 EPA 200.7< 0.0500 HRD5/20/19 14:395/16/19 7:281

Calcium 1.25 mg/L BEE0385 EPA 200.7< 1.25 HRD5/20/19 14:375/16/19 7:281

Potassium 1.25 mg/L BEE0385 EPA 200.7< 1.25 HRD5/20/19 14:375/16/19 7:281

Lithium 0.0150 mg/L BEE0385 EPA 200.7< 0.0150 HRD5/20/19 14:375/16/19 7:281

Magnesium 1.25 mg/L BEE0385 EPA 200.7< 1.25 HRD5/20/19 14:375/16/19 7:281

Sodium 1.25 mg/L BEE0385 EPA 200.7< 1.25 HRD5/20/19 14:375/16/19 7:281



entirety.

Page 2 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Field Blank

Qualifier

Analyte

Mercury

Mercury 0.200 ug/L BEE0560 EPA 245.1, 7470A< 0.200 HRD5/23/19 13:305/22/19 14:001



entirety.

Page 3 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte


Chloride 1.00 mg/L BEE0412 EPA 300.077.5 CRL5/17/19 12:365/17/19 6:061


Sulfate 1.00 mg/L BEE0412 EPA 300.0294 CRL5/17/19 12:365/17/19 6:061

Wet Chemistry

Alkalinity, Total 10.0 mg/L BEE0361 SM 2320B47.5 CRL5/15/19 14:485/15/19 13:091


Total Dissolved Solids 20.0 mg/L BEE0382 SM 2540C610 HSD5/16/19 8:505/16/19 8:501


Arsenic 0.500 ug/L BEE0386 EPA 200.84.62 CRL5/20/19 8:575/16/19 7:321

Barium 0.500 ug/L BEE0386 EPA 200.845.0 CRL5/20/19 8:575/16/19 7:321





Molybdenum 0.500 ug/L BEE0386 EPA 200.8164 CRL5/20/19 8:575/16/19 7:321


Antimony 0.500 ug/L BEE0386 EPA 200.81.04 CRL5/20/19 8:575/16/19 7:321

Selenium 0.500 ug/L BEE0386 EPA 200.82.90 CRL5/20/19 8:575/16/19 7:321


Total Metals by ICP

Boron 0.0500 mg/L BEE0385 EPA 200.75.06 HRD5/20/19 14:435/16/19 7:281

Calcium 1.25 mg/L BEE0385 EPA 200.767.0 HRD5/20/19 14:425/16/19 7:281

Potassium 1.25 mg/L BEE0385 EPA 200.712.7 HRD5/20/19 14:425/16/19 7:281

Lithium 0.0150 mg/L BEE0385 EPA 200.70.0971 HRD5/20/19 14:425/16/19 7:281

Magnesium 1.25 mg/L BEE0385 EPA 200.79.10 HRD5/20/19 14:425/16/19 7:281

Sodium 1.25 mg/L BEE0385 EPA 200.7108 HRD5/20/19 14:425/16/19 7:281



entirety.

Page 4 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W603A

Qualifier

Analyte

Mercury




entirety.

Page 5 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte





Wet Chemistry











Molybdenum 0.500 ug/L BEE0386 EPA 200.886.9 CRL5/20/19 9:095/16/19 7:321





Total Metals by ICP






Sodium 1.25 mg/L BEE0385 EPA 200.763.1 HRD5/20/19 14:585/16/19 7:281



entirety.

Page 6 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W604A

Qualifier

Analyte

Mercury




entirety.

Page 7 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte





Wet Chemistry

Alkalinity, Total 10.0 mg/L BEE0361 SM 2320B131 CRL5/15/19 15:005/15/19 13:091















Total Metals by ICP









entirety.

Page 8 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W605A

Qualifier

Analyte

Mercury




entirety.

Page 9 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte





Wet Chemistry








Cadmium 0.100 ug/L BEE0386 EPA 200.82.06 CRL5/20/19 9:175/16/19 7:321

Cobalt 0.500 ug/L BEE0386 EPA 200.84.26 CRL5/20/19 9:175/16/19 7:321







Total Metals by ICP


Calcium 1.25 mg/L BEE0385 EPA 200.7239 HRD5/20/19 15:085/16/19 7:281







entirety.

Page 10 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W506A

Qualifier

Analyte

Mercury




entirety.

Page 11 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte


Chloride 1.00 mg/L BEE0412 EPA 300.0131 CRL5/17/19 14:395/17/19 6:061



Wet Chemistry









Cobalt 5.00 ug/L BEE0386 EPA 200.8< 5.00 CRLM_DIL 5/20/19 9:215/16/19 7:3210

Chromium 5.00 ug/L BEE0386 EPA 200.8< 5.00 CRLM_DIL 5/20/19 9:215/16/19 7:3210

Molybdenum 0.500 ug/L BEE0386 EPA 200.8258 CRL5/20/19 9:255/16/19 7:321


Antimony 0.500 ug/L BEE0386 EPA 200.81.86 CRL5/20/19 9:255/16/19 7:321



Total Metals by ICP









entirety.

Page 12 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W601A

Qualifier

Analyte

Mercury




entirety.

Page 13 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte





Wet Chemistry







Beryllium 0.500 ug/L BEE0386 EPA 200.80.839 CRL5/20/19 9:295/16/19 7:321

Cadmium 0.100 ug/L BEE0386 EPA 200.81.52 CRL5/20/19 9:295/16/19 7:321


Chromium 0.500 ug/L BEE0386 EPA 200.81.77 CRL5/20/19 9:295/16/19 7:321


Lead 0.500 ug/L BEE0386 EPA 200.80.529 CRL5/20/19 9:295/16/19 7:321



Thallium 0.500 ug/L BEE0386 EPA 200.80.709 CRL5/20/19 9:295/16/19 7:321

Total Metals by ICP









entirety.

Page 14 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W600A

Qualifier

Analyte

Mercury




entirety.

Page 15 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 16 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504A

Qualifier

Analyte

Mercury




entirety.

Page 17 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte




Sulfate 1.00 mg/L BEE0412 EPA 300.014.4 CRL5/17/19 17:425/17/19 6:061

Wet Chemistry






Barium 0.500 ug/L BEE0386 EPA 200.8374 CRL5/20/19 9:375/16/19 7:321










Total Metals by ICP









entirety.

Page 18 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W504B

Qualifier

Analyte

Mercury




entirety.

Page 19 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 20 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502A

Qualifier

Analyte

Mercury




entirety.

Page 21 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L BEE0385 EPA 200.7107 HRD5/20/19 15:395/16/19 7:281




entirety.

Page 22 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W502B

Qualifier

Analyte

Mercury




entirety.

Page 23 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP





Magnesium 1.25 mg/L BEE0385 EPA 200.7108 HRD5/20/19 15:445/16/19 7:281




entirety.

Page 24 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



Duplicate

Qualifier

Analyte

Mercury




entirety.

Page 25 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 26 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W602A

Qualifier

Analyte

Mercury




entirety.

Page 27 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte





Wet Chemistry
















Total Metals by ICP









entirety.

Page 28 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150



Reporting



W7A

Qualifier

Analyte

Mercury




entirety.

Page 29 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEE0412 - Wet Prep

Blank (BEE0412-BLK1) Prepared & Analyzed: 05/17/2019








LCS (BEE0412-BS1) Prepared & Analyzed: 05/17/2019

Chloride 1.00 25.026 90-11099.0mg/L24.8

Fluoride 0.750 2.5000 M_LCS-H90-110111mg/L2.77

Sulfate 1.00 50.150 90-110100mg/L50.3


Chloride 1.00 25.026 90-11096.3mg/L24.1

Fluoride 0.750 2.5000 90-11099.1mg/L2.48

Sulfate 1.00 50.150 90-11097.8mg/L49.1


Chloride 1.00 25.026 90-11095.5mg/L23.9

Fluoride 0.750 2.5000 90-11099.8mg/L2.50

Sulfate 1.00 50.150 90-11096.9mg/L48.6

Duplicate (BEE0412-DUP1) Prepared & Analyzed: 05/17/2019Source: MEE0157-01

Chloride 1.00 200.556mg/L17.9 18.0

Fluoride 0.750 203.99mg/L0.307 0.295

Sulfate 1.00 200.150mg/L91.2 91.4



entirety.

Page 30 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chloride 1.00 200.192mg/L18.2 18.3

Fluoride 0.750 20mg/L0.320 <0.750

Sulfate 1.00 200.480mg/L91.9 91.5

Matrix Spike (BEE0412-MS1) Prepared & Analyzed: 05/17/2019Source: MEE0157-01

Chloride 1.25 31.283 80-12096.1mg/L48.1 18.0

Fluoride 0.938 3.1250 80-120111mg/L3.46 <0.938

Sulfate 1.25 62.688 80-12095.8mg/L151 91.4

Matrix Spike (BEE0412-MS2) Prepared & Analyzed: 05/17/2019Source: MEE0157-02

Chloride 1.25 31.283 80-12097.5mg/L48.8 18.3

Fluoride 0.938 3.1250 80-120113mg/L3.54 <0.938

Sulfate 1.25 62.688 80-12097.0mg/L152 91.5

Matrix Spike Dup (BEE0412-MSD1) Prepared & Analyzed: 05/17/2019Source: MEE0157-01

Chloride 1.25 31.283 2080-12096.5 0.202mg/L48.2 18.0

Fluoride 0.938 3.1250 2080-120119 6.91mg/L3.70 <0.938

Sulfate 1.25 62.688 2080-12095.9 0.0462mg/L151 91.4

Matrix Spike Dup (BEE0412-MSD2) Prepared & Analyzed: 05/17/2019Source: MEE0157-02

Chloride 1.25 31.283 2080-12097.1 0.277mg/L48.6 18.3

Fluoride 0.938 3.1250 2080-120116 2.30mg/L3.62 <0.938

Sulfate 1.25 62.688 2080-12096.7 0.154mg/L152 91.5



entirety.

Page 31 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




pH 7.0000 90-110101pH Units7.06




pH 7.0000 90-110101pH Units7.08



pH 200.761pH Units9.16 9.23


pH 200.137pH Units7.32 7.31



pH 200.810pH Units7.44 7.38









entirety.

Page 32 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte








Total Dissolved Solids 1000 200.460mg/L65400 65100



entirety.

Page 33 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEE0386 - EPA 200.2, EPA 3005

Blank (BEE0386-BLK1) Prepared: 05/16/2019 Analyzed: 05/20/2019



Lead 0.500 ug/L<0.500

Barium 0.500 ug/L<0.500




Cobalt 0.500 ug/L<0.500




LCS (BEE0386-BS1) Prepared: 05/16/2019 Analyzed: 05/20/2019

Antimony 0.500 100.00 85-115100ug/L100

Barium 0.500 100.00 85-115103ug/L103

Selenium 0.500 100.00 85-11595.2ug/L95.2

Chromium 0.500 100.00 85-11597.3ug/L97.3

Molybdenum 0.500 100.00 85-115101ug/L101

Beryllium 0.500 100.00 85-11598.4ug/L98.4

Thallium 0.500 100.00 85-115103ug/L103

Cobalt 0.500 100.00 85-115100ug/L100

Cadmium 0.100 100.00 85-115101ug/L101

Arsenic 0.500 100.00 85-115101ug/L101

Lead 0.500 100.00 85-115103ug/L103

Duplicate (BEE0386-DUP1) Prepared: 05/16/2019 Analyzed: 05/20/2019Source: MEE0179-04




Arsenic 0.500 201.68ug/L5.69 5.79

Beryllium 0.500 20ug/L0.148 <0.500

Barium 0.500 202.99ug/L45.9 44.5

Lead 0.500 20 M_D-RL68.0ug/L0.0834 0.0410

Cobalt 0.500 20 M_D-RL21.0ug/L0.122 0.0991

Chromium 0.500 200.783ug/L0.157 0.158

Molybdenum 0.500 203.95ug/L49.7 47.8

Cadmium 0.100 20ug/L<0.100 <0.100



entirety.

Page 34 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Chromium 0.500 2017.3ug/L0.105 0.0883

Arsenic 0.500 203.43ug/L1.01 1.04


Cobalt 0.500 202.69ug/L4.15 4.26

Barium 0.500 201.76ug/L14.7 14.9

Molybdenum 0.500 202.30ug/L12.6 12.3

Lead 0.500 20ug/L<0.500 <0.500


Selenium 0.500 203.71ug/L1.78 1.85

Thallium 0.500 203.83ug/L0.464 0.447

Cadmium 0.100 203.66ug/L1.99 2.06

Matrix Spike (BEE0386-MS1) Prepared: 05/16/2019 Analyzed: 05/20/2019Source: MEE0179-04

Lead 0.500 100.00 70-13091.8ug/L91.9 0.0410

Molybdenum 0.500 100.00 70-130104ug/L152 47.8

Selenium 0.500 100.00 70-13093.3ug/L93.9 0.507

Barium 0.500 100.00 70-130105ug/L149 44.5

Antimony 0.500 100.00 70-130102ug/L102 0.128

Cobalt 0.500 100.00 70-13095.7ug/L95.8 0.0991

Thallium 0.500 100.00 70-13093.5ug/L93.5 0.0127

Arsenic 0.500 100.00 70-130101ug/L107 5.79

Chromium 0.500 100.00 70-13097.1ug/L97.3 0.158

Cadmium 0.100 100.00 70-13094.8ug/L94.8 <0.100

Beryllium 0.500 100.00 70-13096.4ug/L96.4 <0.500


Chromium 0.500 100.00 70-13098.9ug/L99.0 0.0883

Beryllium 0.500 100.00 70-13095.8ug/L95.8 0.0274

Antimony 0.500 100.00 70-130102ug/L102 0.200

Lead 0.500 100.00 70-13090.9ug/L90.9 <0.500

Selenium 0.500 100.00 70-13099.6ug/L101 1.85

Cadmium 0.100 100.00 70-13093.9ug/L96.0 2.06

Thallium 0.500 100.00 70-13092.5ug/L93.0 0.447

Molybdenum 0.500 100.00 70-130101ug/L113 12.3

Arsenic 0.500 100.00 70-130106ug/L107 1.04

Cobalt 0.500 100.00 70-13097.6ug/L102 4.26

Barium 0.500 100.00 70-130106ug/L121 14.9



entirety.

Page 35 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte



Matrix Spike Dup (BEE0386-MSD1) Prepared: 05/16/2019 Analyzed: 05/20/2019Source: MEE0179-04

Cobalt 0.500 100.00 2070-13097.1 1.47ug/L97.2 0.0991

Lead 0.500 100.00 2070-13091.9 0.0449ug/L91.9 0.0410

Selenium 0.500 100.00 2070-13093.7 0.340ug/L94.2 0.507

Thallium 0.500 100.00 2070-13094.9 1.48ug/L94.9 0.0127

Cadmium 0.100 100.00 2070-13098.2 3.56ug/L98.2 <0.100

Antimony 0.500 100.00 2070-130103 0.827ug/L103 0.128

Barium 0.500 100.00 2070-130105 0.0796ug/L149 44.5

Chromium 0.500 100.00 2070-130100 3.10ug/L100 0.158

Molybdenum 0.500 100.00 2070-130105 0.766ug/L153 47.8

Arsenic 0.500 100.00 2070-130102 0.701ug/L108 5.79

Beryllium 0.500 100.00 2070-13098.8 2.49ug/L98.8 <0.500


Antimony 0.500 100.00 2070-13097.9 3.82ug/L98.1 0.200

Barium 0.500 100.00 2070-130100 4.68ug/L115 14.9

Chromium 0.500 100.00 2070-130103 3.71ug/L103 0.0883

Beryllium 0.500 100.00 2070-13093.0 2.92ug/L93.0 0.0274

Molybdenum 0.500 100.00 2070-130101 0.146ug/L113 12.3

Arsenic 0.500 100.00 2070-130105 1.09ug/L106 1.04

Cadmium 0.100 100.00 2070-13093.7 0.249ug/L95.7 2.06

Thallium 0.500 100.00 2070-13093.4 0.931ug/L93.9 0.447

Lead 0.500 100.00 2070-13090.8 0.158ug/L90.8 <0.500

Selenium 0.500 100.00 2070-130101 1.38ug/L103 1.85

Cobalt 0.500 100.00 2070-130101 3.06ug/L105 4.26



entirety.

Page 36 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte






Boron 0.0500 mg/L<0.0500


Lithium 0.0150 mg/L<0.0150



Magnesium 1.25 100.00 85-115105mg/L105

Sodium 1.25 100.00 85-115106mg/L106

Boron 0.0500 1.0000 85-11599.6mg/L0.996

Calcium 1.25 100.00 85-115106mg/L106

Potassium 1.25 100.00 85-115100mg/L100

Lithium 0.0150 1.0000 85-115101mg/L1.01


Sodium 1.25 200.373mg/L107 108

Lithium 0.0150 200.145mg/L0.0970 0.0971

Magnesium 1.25 201.40mg/L8.98 9.10

Calcium 1.25 200.325mg/L66.8 67.0

Boron 0.0500 201.38mg/L5.13 5.06

Potassium 1.25 202.30mg/L12.4 12.7


Potassium 1.25 209.96mg/L4.33 3.91

Calcium 1.25 208.29mg/L50.9 46.8

Boron 0.0500 206.77mg/L3.27 3.06

Lithium 0.0150 203.09mg/L0.0159 0.0164

Magnesium 1.25 208.13mg/L12.4 11.5

Sodium 1.25 208.25mg/L68.5 63.1



entirety.

Page 37 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte




Potassium 1.25 100.00 70-13094.6mg/L107 12.7

Lithium 0.0150 1.0000 70-13095.1mg/L1.05 0.0971

Calcium 1.25 100.00 70-130101mg/L168 67.0

Magnesium 1.25 100.00 70-13098.6mg/L108 9.10

Boron 0.0500 1.0000 70-130105mg/L6.11 5.06

Sodium 1.25 100.00 70-130102mg/L210 108


Potassium 1.25 100.00 70-13094.2mg/L98.1 3.91

Calcium 1.25 100.00 70-130102mg/L149 46.8

Magnesium 1.25 100.00 70-13098.9mg/L110 11.5

Sodium 1.25 100.00 70-130103mg/L166 63.1

Lithium 0.0150 1.0000 70-13094.2mg/L0.958 0.0164

Boron 0.0500 1.0000 70-130102mg/L4.08 3.06


Lithium 0.0150 1.0000 2070-13094.8 0.262mg/L1.05 0.0971

Calcium 1.25 100.00 2070-130102 0.128mg/L169 67.0

Magnesium 1.25 100.00 2070-13098.4 0.190mg/L108 9.10

Boron 0.0500 1.0000 2070-130111 0.893mg/L6.17 5.06

Potassium 1.25 100.00 2070-13094.1 0.397mg/L107 12.7

Sodium 1.25 100.00 2070-130102 0.0429mg/L210 108


Lithium 0.0150 1.0000 2070-13097.1 2.99mg/L0.987 0.0164

Potassium 1.25 100.00 2070-13096.5 2.36mg/L100 3.91

Boron 0.0500 1.0000 2070-130110 1.84mg/L4.15 3.06

Calcium 1.25 100.00 2070-130106 2.35mg/L152 46.8

Sodium 1.25 100.00 2070-130107 2.36mg/L170 63.1

Magnesium 1.25 100.00 2070-130102 3.08mg/L114 11.5



entirety.

Page 38 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEE0560 - EPA 245.1, EPA 7470A






Mercury 0.200 3.0030 85-11593.3ug/L2.80


Mercury 0.200 3.0030 85-11598.4ug/L2.96


Mercury 0.200 20ug/L0.0330 <0.200


Mercury 0.200 20ug/L<0.200 <0.200


Mercury 0.200 20ug/L0.0325 <0.200


Mercury 0.200 3.0030 70-13099.3ug/L2.98 <0.200


Mercury 0.200 3.0030 70-13099.1ug/L2.98 <0.200


Mercury 0.200 3.0030 70-13077.1ug/L2.32 <0.200



entirety.

Page 39 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150


Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

Limit Notes Analyte


Batch BEE0560 - EPA 245.1, EPA 7470A


Mercury 0.200 3.0030 2070-13095.7 3.64ug/L2.87 <0.200


Mercury 0.200 3.0030 2070-13097.3 1.82ug/L2.92 <0.200


Mercury 0.200 3.0030 2070-13077.0 0.182ug/L2.31 <0.200



entirety.

Page 40 of 41



Reported:


250 Marquette Plaza

05/28/2019 06:05Minneapolis MN, 55401


1518 Chestnut Ave N



WI-999071150




M_LCS-H The recovery of this analyte in the LCS was above the control limits. The sample result may be biased high.


M_DIL Sample was diluted. The MDL and MRL were raised due to the dilution.



dry

Not ReportedNR


Analyte DETECTEDDET




entirety.

Page 41 of 41

CCR Monitoring Closure Verification Report · closure verification groundwater data were reviewed...

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