Castor oil polyol for polyurethane resin material URIC · 2018. 8. 15. · Floor coating of Japan...

1

Castor oil polyol for polyurethane resin material

URIC

ITOH OIL CHEMICALS CO LTD

2

Polyisocyante Aromatic type (TDI MDI)

Polyol

Polyether polyol (PPG PTMG)

Aliphatic type (HDI IPDI)

Polyester type (Adipate Sebacate)

Acrylic polyol

Hydrocarbon type polyol

Castor oil polyol

Polyurethane raw materials

Other

URIC

Catalyst Extender Flame retardant etc

3

Technology trends of environment-friendly

polyurethane

Transition to environment friendliness

Environmental regulation VOC regulation Solvent free

Energy savings Thin film Long-term use

Biomass resource Castor oil based materials

4

Bio polyol

URIC series

Floor coating

Anticorrosion coating

Electric insulator

Foam

photosynthesis

H2O

CO2

太陽光

Carbon neutral castor oil-based polyurethane resin

5

Water Resistance

0

05

1

15

2

25

3

35

4

CO Poly-bd Polyester Polyether

Th

e r

ati

o o

f w

eig

ht

ga

in o

n e

ach

PU

(w

t)

23 for 30 days

60 for 30 days

100 for 1 hour

3 aq NaCl23 for 30 days

Curing agent Polymeric MDI

Curing agent Polymeric MDI(NCO INDEX=105)

Poly-bd Polybutadiene polyol (MW=1200 F=22)

Polyester AA type(MW= 1000 F=3) Polyether PPG(MW=1000 F=3)

6

Variation of hardness in PCT pressure cooker test(Moisture and heat-resistance acceleration test)

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd


PCT condition 121 100wt 02MPa

Hydrolysis resistance

7

Electrical characteristics

10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16

CO Polyether Polyester Poly-bd

Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance


Condition 150 in air

40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9

Performance Comparison

Castor

Oil

PPG PErsquos Poly-bd

Water G P F G

Boiling water G P P G

10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P

Ethyl Acetate P P P P

Paraffin oil G G G P

G Good

F Fair

P Poor


Solvent dipping condition 23 for 10 days

10

resistancerarr Water Oil Cold Heat P Strength Price

PPG times times

Polyester times

Acrylic times

Hydrocarbon times times

Castor oil - - -

Polyurethane Polyols (Characteristics)

11

12

URIC castor oil polyurethane systems

General purpose grade

Lower viscosity with hydrocarbon

polyols

Castor oil mod polyols which have

aromatic structure

For floor coating materials

Eco friendly polyester polyol

For urethane gel

For flexible amp rigid foam etc

13

Solvent-free 2KPU systems using URIC

USE FEATURE

Floor coating materials Low foaming at applying

Electric sealants Excellent insulation Water proof Good combination with others

Anti-corrosive paints amp Flexibility Impact resistance and

Adhesives Excellent adhesive properties to metal plastics etc

Foams Environmental friendly low elastic

(flexible amp rigid) high heat insulating properties

14

Floor coating of Japan market

Epoxy Urethane

Polyester

Water PU

Features of urethane floor coatings

15

Urethane Epoxy

Feature 2K solvent free 2K solvent free

Construction period 18hours times 48hours

Smell

Toughness times

Hot water resistance times times

Advantage Anti cracking Cheap

Disadvantages times Humid construction

cracking Bad odor

times Low temp construction

Future Gradually expanding Downside

)Japan market share 2013 15 34

16

Changes in thick film floor coating

appearance

hardness

times cracking times hot water times Abrasion

Epoxy

anticracking strength

elongation

times hot water

Hardness

urethane

hot water resistance

High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17

Strong urethane floor coating in impact

Epoxy

Hardness urethane

18

Polyurethane Resin

Polyurethane resins consist of Polyols and Polyisocyanates

OCN－－NCO HO－－OH

H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon

Polyisocyanate and water or moisture forms carbon dioxide

after reacting

OCN－－NCO HOH

Polyisocyanate Water or Moisture

Amine

OCN－－NH2 ＋ＣＯ2 uarr

Carbon dioxide

Castor oil is lower water-absorbing capacity

20

Other A

Other B

Comparison of PU floor coatings

URIC F-15

Condition

Coating condition 35 90

Curing agent Crude MDI

(Polymeric MDI)

Film thickness 500 micron with applicator

Typical Formulation

Polyol 630

Extender pigment 260

Dehydrating agent 70

Coloring agent 35

Defoamer 05

Crosslinker (P MDI) 250

Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22

Application field of URIC

F-15 F-25 F-40 PU floor coating materials

23


USE FEATURE







24

Comparison between CO-PU and PEsrsquo one

Before PCT

After PCT

CO polyurethane

Polyester polyurethane

25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30

PCT (Presser cooker test) (Moisture amp Heat resistance acceleration test)

26


H-30 Y-403

H-420 H-1824

AC-005

Insulation sealant for home electric

appliance such as washing machines and

dishwaters which can easily become wet In

addition these are used in electronic parts

for automobiles

27


PH Series Urethane gel like insulation sealant for the

electronic parts for automobiles and buffer

mold for building etc

28


USE FEATURE







29

Tensile shear strength of PU adhesive

NCO index13 AC-009 5蓖麻油AC-009=955 AC-006 50蓖麻油AC-006=5050

180 deg peel strength of PU adhesive

Interfacial

failure Cohesive

failure

30

Interfacial

failure

アルミニウム Comparison of the impact resistance

31

Weight height

Contact radius(mm)

Castor oil AC-009 5 AC-006 50

AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG

URIC H-30 URIC H-52 URIC H-102 URIC AC-006 URIC AC-009

URIC AC-009

URIC AC series for Adhesive

URIC H-368

FRP-FRP adhesive Fracture surface after the tensile shear test

URIC AC-006

33

2KPU anti-corrosive paints for water amp gas

pipes steel stakes etc


H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006

2KPU adhesives for automotive

architectural parts and materials for

waterproofing etc

Filter

34

0

100

200

300

400

500

600

URIC H-30 ( ITOH OIL

CHEMICALS)

Commercial Grade

μgg

Volatilization amount

35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール

URIC F-40 URIC F-97 URIC SE-975

光沢保持率

()

デュラネート TSE-100

500h

1000h

2000h

Weather resistance of URIC

Gloss retention

Acryl polyol F-40 F-97 SE-975

VS HDI NCO index 105

36

Weather resistance of URIC 2

品名水酸基価 mgKOHg

粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20

Building exterior coating

highway

bridge

Application

37


USE FEATURE







38


HF Series

Polyurethane flexible or rigid foam

39

40

Typical Properties of H Series

OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15

Crosslinked with polymeric MDI NCO content 31 NCO Index105 at 25

1 Time its viscosity reaches 50000 mPas at 25 after mixing polyol and polymeric MDI

42


Properties and Applications

H-30 Refined castor oil for 2KPU elastomers amp coatings

H-31 Reactive diluent for PU polyols epoxy and acrylic resin etc

H-52 Castor oil polyol for 2KPU system

H-56 Castor oil polyol for 1KPU system except electric sealants


H-62 Castor oil polyol for 2KPU elastomers and coatings

H-73X Great anti-hydrolysis and physical properties for 2KPU elastomers

and coatings H-81

H-420 Great physical property and heat resistance for 2KPU coatings

adhesives and sealants

H-854 Great anti-hydrolysis and adhesive properties for 2KPU heavy duty

coatings

43

Typical Properties of Y Series

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25

F1 Properties amp Applications

Y-202 120 10 003 650 2 Good water resistance and

anti-foaming property In

addition great reactive

diluents for polybutadiene

polyols for 2KPU sealants

adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22

Y-332 123 05 003 1250 2 Good weather ability for

2KPU systems Great

reactive diluents for isoprene

polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14

Urethane Properties of Y Series


In case of Y-332 it is crossliked with HDI isocyanurate NCO content 21 at 25)


45

Blank 1 eg 1 e g 2 eg 3

Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750

Hardness [shore A] 46 46 50 58

Elongation [] 160 190 640 720

Tensile Strength [MPa] 14 19 37 52

Formulation Example

1 Polybutadiene polyol (OHV 466 Functionality 22)

46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25


AC-005 210 15 003 1200 2 BPA modified castor oil

polyols for 2KPU adhesives

and coatings Great adhesive

for metals and good anti-

corrosive properties

AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)

180 15 003 1600 25 Improved the existing AC

series which are stricken a

balance between handling amp

adhesive property not

mention chemical resistance

AC-009 (NEW)

225 15 003 1500 25

Typical Properties of AC Series

1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14

Urethane Properties of AC Series

Crosslinked with polymeric MDI NCO content 31 NCO Index105 at 85 for 16 hours


48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)

1000g 635 Good Good Good Good Good Good

318 Good Good Good Good Good Bad


Impact Resistance

1)Falling height 500 mm

Test film is coated on 3mm in thickness on the sand blast surface carbon steel (SIS Sa 2 frac12)

2)Epoxy resin EPYCOAT 828 crosslinked with polyamine VERSAMID 115

Du Pont test 1)

49

Urethane Properties (Crosslinked with polymeric MDI NCO 31 INDEX 105)

F-15 F-25 F-40

OHV [mgKOHg] 167 188 236

AV [mgKOHg] 15 06 15

Viscosity [mPas 25] 3000 2600 3900

Hardness [Shore D] 67 70 80

Elongation [] 122 96 85

Tensile Strength [MPa] 26 28 43

Tear Strength [Nmm] 58 86 170

Feature General purpose

grade

General amp

refinish use

High hardness

impact resistance

50

SE Series Environmental friendly polyester polyol better water

resistance and excellent performance in lower temperature crosslinked

with pure MDI)

SE-2003 SE-2606

Appearance White solid White solid

Acid Value [mgKOHg] 03 01 or less

Hydroxyl Value [mgKOHg] 56 43

Melting Point [] 54 66

Composition SAPDO SAHG

Molecular weight 2000 2600

Hardness [shore A D] 94A 49D

Modulus at 100 [MPa] 44 -


Elongation [] gt700 -

SA Sebacic acid PDO 13-Propanediol HG Hexylene glycol

51

Urethane Properties (crosslinked with liquid MDI NCO content 29 NCO index 105)

PH-5001 PH-5002 PH-6000

OHV [mgKOHg] 45 43 46

Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2

Hardness [shore C] 18 21 17


Feature General

purpose use

Excellent

elongation

Excellent heat

resistance

PH Series Special modified castor oil polyols for urethane gel

52

Thank you for your attention


53

54

Variation of the addition of DBTDL()

100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005

The influence of catalyst upon the gel time of castor oil polyurethane

reference

55

Polyisocyanate

Polyol

Others

Foam Flexible Semi-rigid Rigid foam

Elastomer Thermoplastic amp Thermosetting

Paint Both 1 amp 2 Component

Adhesive Both 1 amp 2 Component

waterproofing sealant 2 Component

Artificial leather

Elastic fiber

Polyurethane application reference

56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()

Tensile strength (Mpa)

Hardener Pure MDI

Castor Oil (Physical properties)

reference

57

Castor Oil (Chemical resistance)

0

05

1

15

2

25

3

35

4

H-30 Poly-bd Polyester PPG Epoxy resin

Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4

Dipping test (at 25 for 10 days) Hardener Crude MDI

reference

58

Comparison of hydrolysis resistance

Variation of acid value on each polyol

(Emusion solution polyolwatersurfactant=1001001 at 40)

00

05

10

15

20

25

30

35

40

0 after 30 days at 40

AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59

PU floor coating market in Japan

0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA

Wb urethane concrete

PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40

Tensile strength [Mpa]

Elongation []

Tg(）

Physical properties of F series

Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]

Hardness after 1 day

Hardness after 10 days

Variation of hardness after coating reference

Hardener Crude MDI

62 Application of PU flexible foam 141200 tons(FY07）

Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible

PU foam market in Japan

Flexible foam (Technical trend)

Lightening (Low density)

Low elasticity (flexible at low temp)

Shock absorbent

Acoustic

Rigid foam (Technical trend)

Flame retarding

Foaming agent water only

reference

63

Flexible foam Rigid foam

Method Slab (general purpose

use) Mold Slab or Mold

State of cell Linking-cell Non-linking-cell

Functionality 3 3 - 8

Epoxide POEOPOEO PO(EO)

OHV 56 28 - 36 380 - 550

Viscosity lt 2000 lt 2000

MW 3000 4600 - 6000 305 - 1100

Functionality 3 or more 3 or more

OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000

Polymer-polyol No use Use No use

Foaming agent water Water HFC-245fa

HFC-365mfc etc

Polyisocyanate TDI TDI Polymeric MDI

TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol

Polymer-polyol Combination between PPG amp vinyl modified polyol

Comparison reference

64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive

Adhesive for glass fiber

Paint

Others

Inside 1990

Outside 2002 (15000 t)

Domestic Market of PU Dispersion reference

65

PU rigid foam (Chemical resistance)

Seawater G MEK S

Soapy water G Acetone S

Benzene G Ethyl acetate S

Toluene G Styrene monomer S

Xylene G Concentrated sulfuric acid D

Gasoline G Concentrated nitric acid D

Paraffin oil G Concentrated hydrochloric acid S

Methyl chloride S Concentrated NaOH aq solution G

Alcohol S Vegetable oil G

Carbon tetrachloride S Animal oil G

G Not attacked S Swelling D Dissolved

reference

66

Hydrocarbon based polyols

Poly-bd (Polybutadiene polyol)

Polyisoprene polyol)

reference

67

reference

Chemical structure of PTMG or PCL

68

DU PONT TYPE FALLING

IMPACT TESTER

reference

69

Castor Oil (compatibility)

Castor oilother polyol=11

PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000

Phthalic acid type polyester

Polycarbonate

Polycaprolactone

Polybutadiene

times times

25

transparence opacity (haze) times separation

reference

70

Mechanism of solar heat-shielding

Special modified TiO2 effectively reflects this

infrared rays area (780-2100nm) which makes the

person feel that it is hot

reference

71

Retort pouches for food

Thickness 01 mm (100μm)

reference

2

Polyisocyante Aromatic type (TDI MDI)

Polyol

Polyether polyol (PPG PTMG)

Aliphatic type (HDI IPDI)

Polyester type (Adipate Sebacate)

Acrylic polyol

Hydrocarbon type polyol

Castor oil polyol

Polyurethane raw materials

Other

URIC

Catalyst Extender Flame retardant etc

3


polyurethane





4

Bio polyol

URIC series

Floor coating


Electric insulator

Foam

photosynthesis

H2O

CO2

太陽光


5

Water Resistance

0

05

1

15

2

25

3

35

4


Th

e r

ati

o o

f w

eig

ht

ga

in o

n e

ach

PU

(w

t)

23 for 30 days

60 for 30 days

100 for 1 hour






6


0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd




7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

3


polyurethane





4

Bio polyol

URIC series

Floor coating


Electric insulator

Foam

photosynthesis

H2O

CO2

太陽光


5

Water Resistance

0

05

1

15

2

25

3

35

4


Th

e r

ati

o o

f w

eig

ht

ga

in o

n e

ach

PU

(w

t)

23 for 30 days

60 for 30 days

100 for 1 hour






6


0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd




7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

4

Bio polyol

URIC series

Floor coating


Electric insulator

Foam

photosynthesis

H2O

CO2

太陽光


5

Water Resistance

0

05

1

15

2

25

3

35

4


Th

e r

ati

o o

f w

eig

ht

ga

in o

n e

ach

PU

(w

t)

23 for 30 days

60 for 30 days

100 for 1 hour






6


0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd




7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

5

Water Resistance

0

05

1

15

2

25

3

35

4


Th

e r

ati

o o

f w

eig

ht

ga

in o

n e

ach

PU

(w

t)

23 for 30 days

60 for 30 days

100 for 1 hour






6


0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd




7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

6


0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

time(h)

Ha

rd

ness

(sh

ore A

)

CO

Polyether

Polyester

Poly-bd




7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

7


10E+10

10E+11

10E+12

10E+13

10E+14

10E+15

10E+16


Volu

me

resi

stiv

ity (Ω

cm)


8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

8

Heat Resistance



40

45

50

55

60

65

70

75

80

85

0 7 14Time(day)

Hard

ness

[sh

ore

A]

CO

PPG

PEs

PBD

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

9


Castor

Oil


Water G P F G


10 aq NaOH G P F G

10 aq H2SO4 G P F G

Methanol G P F G

Acetone P P P P



G Good

F Fair

P Poor



10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

10


PPG times times

Polyester times

Acrylic times


Castor oil - - -


11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

11

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

12




polyols


aromatic structure



For urethane gel


13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

13


USE FEATURE







14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

14


Epoxy Urethane

Polyester

Water PU


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference


15

Urethane Epoxy



Smell

Toughness times




cracking Bad odor




16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

16


appearance

hardness


Epoxy


elongation

times hot water

Hardness

urethane


High durability

Concrete foundation

treatment

Water PU

2015年 2005年 1995年 1960年

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

17


Epoxy

Hardness urethane

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

18

Polyurethane Resin



H O

｜ ∥

－N－C－O－

O H

∥ ｜

－O－C－N－

O H

∥ ｜

－O－C－N－

ISOCYANATE POLYOL

URETHANE BOND

H O

｜ ∥

－N－C－O－

POLYURETHANE

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

19

Foaming phenomenon


after reacting

OCN－－NCO HOH


Amine


Carbon dioxide


20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

20

Other A

Other B


URIC F-15

Condition



(Polymeric MDI)


Typical Formulation

Polyol 630



Coloring agent 35

Defoamer 05


Formation rate31

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

21

Example 1

URIC F-15 F-25 F-40

PU floor coating

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

22



23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

23


USE FEATURE







24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

24


Before PCT

After PCT

CO polyurethane


25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

25

0

10

20

30

40

50

60

70

0 50 100 150 200

時間(hr)

A硬度

H-1823 H-1824 H-30


26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

26


H-30 Y-403

H-420 H-1824

AC-005





for automobiles

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

27





28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

28


USE FEATURE







29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

29




Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference


Interfacial

failure Cohesive

failure

30

Interfacial

failure


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference


31

Weight height

Contact radius(mm)


AC-006 100

EpoxyAmine

1000g 10m

635 OK OK OK OK OK

318 OK OK OK OK NG

159 OK OK OK OK NG


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference


URIC AC-009


URIC H-368


URIC AC-006

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

33




H-30 H-368

H-854 H-870

H-30 H-368

H-420 AC-006



waterproofing etc

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

Filter

34

0

100

200

300

400

500

600


CHEMICALS)

Commercial Grade

μgg


35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

35

0

10

20

30

40

50

60

70

80

90

100

他社アクリル

ポリオール


光沢保持率

()


500h

1000h

2000h


Gloss retention



36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

36



粘度 mPas25

官能基数 Tg

F-97 330 4630 25 97

F-40 236 3900 3 77

Ref) H-30 160 690 27 20


highway

bridge

Application

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

37


USE FEATURE







38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

38


HF Series


39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

39

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

40


OHV [mgKOHG]

AV

[mgKOHG]

Water

content [wt]

Viscosity [mPss 25]

Functionality

H-30 160 02 003 690 27

H-31 164 10 003 30 1

H-52 200 05 003 630 3

H-56 90 20 003 230 2

H-57 100 20 003 460 3

H-62 260 25 003 265 2

H-73X 270 20 003 1000 3

H-81 340 20 003 1200 3

H-420 320 10 010 800 3

H-854 215 10 005 800 3

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

41


Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

H-30 7423 62 132 8 25 20E+14

H-31 - - - - - - -

H-52 9138 58 100 10 27 40E+14

H-56 30 5 - 120 05 2 20E+11

H-57 44 9 200 480 09 3 20E+12

H-62 - 55 30 81 6 51 22E+14

H-73X - 70 24 39 28 55 95E+14

H-81 - 68 17 35 23 87 11E+15

H-420 - 80 41 10 48 25 30E+15

H-854 - 60 57 172 13 28 50E+15



42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

42










and coatings H-81




coatings

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

43


OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







adhesives etc

Y-403 160 10 003 220 2

Y-406 165 15 003 250 22


2KPU systems Great


polyols

1 Functionality

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

44

Hardness Shore AD

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear st [Nmm]

VR

[Ωcm]

Y-202 5510 344 87 25 40 70E+13

Y-403 334 - 109 06 30 140E+14

Y-406 5912 48 110 30 60 140E+14

Y-332 5312 - 107 24 50 160E+14





45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

45


Poly-bd 1 100 50 50 50

Y-202 50

Y-403 50

Y-406 50

Viscosity [mPas 25] 7000 3200 1600 1750


Elongation [] 160 190 640 720


Formulation Example


46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

46

OHV

mgKOHg

AV

mgKOHg

Mois

()

Vis mPas 25







AC-006 178 30 003 4000 2

H-368 195 10 003 1300 25

AC-008 (NEW)






AC-009 (NEW)

225 15 003 1500 25


1 Functionality

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

47

Hardness Shore D

Pot life 1

[min]

Elongation []

Tensile

strength [MPa]

Tear

strength [Nmm]

Volume

resistance

[Ωcm]

AC-005 73 52 25 39 136 12E+15

AC-006 78 74 17 51 34 30E+15

H-368 68 53 120 23 112 18E+15

AC-008 47 73 95 15 50 55E+16

AC-009 69 37 100 30 30 18E+16

H-30

(CO)

23 62 132 8 25 20E+14




48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

48

Falling

weight

Contact (radius mm)

AC-005 AC-006 H-368 AC-008 (NEW)

AC-009 (NEW)

Epoxy

Resin 2)




Impact Resistance




Du Pont test 1)

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

49


F-15 F-25 F-40

OHV [mgKOHg] 167 188 236


Viscosity [mPas 25] 3000 2600 3900






grade

General amp

refinish use

High hardness

impact resistance

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

50



with pure MDI)

SE-2003 SE-2606












51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

51


PH-5001 PH-5002 PH-6000


Viscosity [25 mPas] 5400 8300 5800

Functionality 2 2 2



Feature General

purpose use

Excellent

elongation

Excellent heat

resistance


52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

52



53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

53

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

54


100

1000

10000

100000

0 5 10 15 20 25 30 35 40 45 50 55

Time [min]

Vis

cosi

ty [

mP

as] 0

001

002

003

005


reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

55

Polyisocyanate

Polyol

Others






Artificial leather

Elastic fiber


56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

56

0

50

100

150

200

250

300

H-30 PPG PEs PBD

Hard

ness(s

ho

re A

) o

r E

lon

gati

on

()

0

2

4

6

8

10

12

14

Ten

sil

e s

tren

gth（

MP

a）

Hardness (shore A)

Elongation ()


Hardener Pure MDI


reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

57


0

05

1

15

2

25

3

35

4


Varia

tio

n r

ate

of w

eig

h（）

Water

10 aq NaOH

10 aq H2SO4


reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

58




00

05

10

15

20

25

30

35

40


AV

H-30

H-854

Y-403

PH-5001

AC-006

Adipate

reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

59


0

5000

10000

15000

20000

25000

30000

35000

40000

1995 2000 2005 2006 2007

Fiscal year

Sales volume (ton)

Wb acrylic resin

Sb acrylic resin

Polyester resin

MMA


PU resin

Epoxy resin

reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

60

0

20

40

60

80

100

120

140

F-15 F-25 F-40


Elongation []

Tg(）


Hardener Crude MDI

reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

61

50

55

60

65

70

75

80

85

90

95

100

F-15 F-25 F-40

Hae

dn

ess

[sh

ore

D]




Hardener Crude MDI


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference


Others 16200

11

Furniture 6300

4

Bedclothes 9400

7

Vehicle 108800

73

0

100000

200000

300000

400000

20032004

20052006

20072008

Volu

me （

ton）

Rigid

Flexible





Shock absorbent

Acoustic


Flame retarding


reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

63







OHV 56 28 - 36 380 - 550


MW 3000 4600 - 6000 305 - 1100


OHV 45 - 70 350 - 400

AV lt 2 lt 2

Viscosity 10000 - 20000 2000～3000



HFC-365mfc etc


TDI P MDI＝8 2

Po

lye

the

r p

oly

ol

Po

lye

ste

r p

oly

ol



64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

64

6015

15

55

15

10

28

17

30

Fiber treatment

Adhesive


Paint

Others

Inside 1990

Outside 2002 (15000 t)


65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

65


Seawater G MEK S











reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

66




reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

67

reference


68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

68


IMPACT TESTER

reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

69



PPG MW3000

PTMG MW3000

AABG MW1000

AADEG MW1000


Polycarbonate

Polycaprolactone

Polybutadiene

times times

25


reference

70





reference

71



reference

70





reference

71



reference

71



reference

Castor oil polyol for polyurethane resin material URIC · 2018. 8. 15. · Floor coating of Japan...

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Transcript of Castor oil polyol for polyurethane resin material URIC · 2018. 8. 15. · Floor coating of Japan...