CASE NO. 3089: SAMPLE NO.'S F4132, F4133, F4229 AND ...Environmental Prelection Agency. CLP Sample...

Bromofluorobenzene (BFB)

CaseNo._^&M———— Contractor ^^^

instrument in V^A Date ^ i /^. . . . . / . /

Lab ID KPF^W 7^?/9, Data Release Authorized By:

^/o$-^ T

m/« ION ABUNDANCE CRITERIA ;

Contract No. 6? 9, - <^-^&

Time__^C3________

%RELATIVE ABUNDANCE

50

,75

95

96

173

1 7 4 ~ "

175

176

177

.15.0 - 40.0% of the base peak . . .

30.0 - 60.0% of the base peak

Base peak, 100% relative abundance '..

5.0 - 9.0% o< the base peak .... ;

Less than 1.0% of the base peak

5.0 - 9.0% of mass 174

Greater than 95.0%. but less than 101.0% of mass 174

5.0 • 9.0% of mass 176

• • -^9(z? ; : . • •

- 5Z fc /- /DO. Gb

^ fc3 •0

-.-- .u,.s9' .. . . . . . . . . . -^.^7 C%^)1,

' ^'^ ^^\

• H.^ -(-fc^5-2-.

-r,

e,—,

„

Value in parenthesis is % mass 174.

^ Value in parenthesis is % mass 175.

THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWING

SAMPLES, BLANKS AND STANDARDS.

SAMPLE ID

r^i F41^r4o4-?7 - --F^SL-S 0 "P' /^2,0

/=^^S°• . . -—- . - ' '

-- • •-• • • • - • - •••—

" --—-———

LAB ID

5^%-)rf-7 -5( lS- ia

-fPS

•- - • —'^ — ----1.^- f5 A^S-if3-J^Jri5- ••

. :• -T2,b«k 7X

- - - - — - - • — - - • • • • • •

—„—--.^-,-———--••-- - • -— - . - . . - . - - • - - - • - - • - - - - - • — -

DATE OF

•B /

,. ,. ^

ANALYSIS

^^

1

/

TIME OF ANALYSIS

^•0^-

9:0^^'.of-'v <u &

:0'»-

G;o%-- . .. 4 .-,,-.—.-

..•.-..-^b.;- ..,;

4/84

80383 FORM V

MASS LIST DATA:08/19/84 2:07:00 + 35:16 CALI:SAMPLE: 50 UG/L STD, VERIFICATIONCONDS. :

EPAVOA1718 #1032EPAVOA1718 # 1

BASE M/E: 95RIC: 220416.

JW

50-51.57.61.62.63.68.69.73.74.75.76.78.80.86.88.93.94.95.96.

174.175.176.177.

50.77»SS

020404040406060606080808889694060810101000040000

3.

7.

24.6.4.5.5.4.

12.12.

6.20.59.

4.5.4.

• 4.5.4.

13.100...6.66.

5.65.4.

90

RA

969286415611443112906195327.1207657040063-59473900

0.

7. F

4.1.0.1.1.0.2.

• 2.• 1.4.

11.0.

. 1.0.

• 0.: 1.0.2.

19.1.

12.1.

12.8.

00

(1C

833494050879413818025396039181118852342888066577

0. MINIMA# 0 MAXIMAINTEN.

10640.2948.2072.23QS.2372.1750.5304.5248.2608.8864.

2540B.2112.2268.2008.1792.2456.1948.5560.

42624.2824.

28384.2332.

27872.1704.

MIN INTEN: 1662.

t 9 '• [- 0 .0

1

50

5.0iiu

MASS SPE03^19/84SAMPLE;CONDS.:

.0

1 5^01,

\M60

CTR'?

59"

68

UM;07;eUG/L

7E

1

w

38 ^STC

^.1

78

.

3.

<

8

35; 16UERIFICAT

95

;

!

3: 88.1u^0 '

ION

.1

,

104.0 117.8l., , , 1 .1 , , , . , . , . . • , - , . .100 123

DflTfl: EPAUOhll713 #1832 BASE M/CflLI; EPWOA1719 #1 RIC;

17'

<1

'

130.0 143-8

148 169

E^

..

1

; 9528416.

0

1

1 , , , ,1 . | . .

180

I- O Q

SCANS 1000 TO 1060ass; CHROMATOGRAII DATA; EPAUOAIZIS #10328/'1&/-S4 2;07;e0 ' CftLl! EPfl"Oftl71S <tlAMPLE: 50 UG/-L STO. UERIFICATIONONDS. • • • - - : • • • • . • • ! • . , . . ......flNGE! G 1,1309 LABEL: N 2, 3.9 QUAN; A 2, 2.0 J 0 'BASE: U 20, 3

• 1033'43113.490681. ;

1060 SCAN36;13 TIME

43264.

95.028± 0.509

Initial Calibration Data

Volatile HSL Compounds

Case No: - .^PS'?

Contractor: ^ S>T-e^-h'i^C

Instrument I D:

Contract No: h '?i— ^V"

Calibration Data- ?,J/c57bV- 7 T

Minimum RF for SPCC is 0.300 Maximum % RSD for CCC is 30%

/--

Laboratory )•

Compound

Chloromethane

Bromomethane

Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

Cartion Disulfide

1 . 1-Dichloroethene

1, 1-Dichloroethane

Trans-1, 2-DichloroeIheneChloroform

1. 2-Oichloroethane2-Butanone

1 . 1 . 1 -Trichloroothane

Carbon Tetrachloride - - -

Vinyl Acetate

Bromodichloromethane

1. 2-Dichloropropane

Trans-l. 3-Dichloropropene

Trichloroethene

Dibromochloromethane

1 . 1 . 2-Trichtoroethane

Beniene

cis-1, 3-Dichloropropene2-ChloroethylvmyletherBromoform

2-Hexanone

4-Melhyl-2-Penlanone

Tetrachloroelhene

1. 1 . 2, 2-Teirachloroethan<

Toluene

ChlorobenzeneElhylbeniene

SlyreneToial Xylenes

RFzo

0.^

1: /./yy

D.SWsf.W

0-/Vs./s^

&.HQ.

^•6^1.370^.«3o</

l.f-W-

c?.o/ys^-o-.y^

0.&?,fO-llSi..0--V-SO

o.'-WO.'/W

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l-f^Lrn

0, C?=,0>c>.^wO.fH

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05^

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0.337-o.SOi-

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RF100

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-?âr9.to9^>i.t^4

/,3^^^.O^W

LO/-?0. bf^

Rr

o.î.Oîf

l.aw

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1.777n.iffl-•3.7W

/.8fc.<

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CCC-SPCC"

- - •* '".k •

*

«

4 4

»

......... -

*

* *

» • » • • •

» '

• *

^} «

RF -Response Factor (subscript is itw amouni of UQ/LIR^ -Average Response Factor%RSD -Percent Relative Standard Deviation

CCC -Calibration Check Compounds (*)SPCC -System Performance Check Compounds (

Form VI

Environments) Prolecnon Agency,P.O. Box 616. Alexandria. Vtrgini

< 1 C

Lab SamplB ID No- -T T<2 •n

CLP Sample Management OMice,22313 703/557-2490

Organics Anal(Pa

-T-fs^m/ / G >-^ - J ,

, ^

. Volatile C

Concentration: (\.ow)

• ' OJ

Percent Moisture (Decan

ysisDgel)

Cas

QC

Oat

ompot

Mediu

^

^7^

led): -i-

)ata Sheet

<? Nn .:. .

Rnpnrt Nn / / -3

llrai-1 Nn- W 0 '

Jnds

m (Circle One)

/C? /^

'67'

pH

Sample Number

^ 1 1 ^

^6^Q

Ol-(c^%0

^\nî i

CASNumber

74.87-3

74-83-9

75-01-4

75-00-3

75-09-2

67-64-1

7.5-15-0

-75..35-A- . -

75-34.3

156-60-5

67-66-3

107-06-2 '

78-93-3

71.55-6

56.23-5

108-05-4

75-27-4

Chloromeihane

Bromomethane

Vinyl Chloride

Chloroelhane

Methylene Chloride

Acetone

Carbon Disultide'- ' -:

1.'!-Dichtoroethene

1. 1-Dichloroethane

Trans-1, 2-Dichlofoethene '

Chloroform

1 , 2-Dichloroethane

2-Buianone

1 , 1 . 1-Trichloroeihane

Carbon Tetrachloride

Vinyl Acetate


ug/\0fi£p(CiTCte-O-

^^• uu^

^D

•a. -,^

' •^6a©^050-^0

- 5040S.U^0^0aw

Kg,

\

1

\

v

CASNumber

79-34-5

78-87.5

10061-02-6

79-01-6

124-48-1

79-00-5

71.43-2

10061-01-5

1'10-75-8

75-25-2

591-78-6

1 0 8 - 1 0 - 1

127 -18 -4

108.88.3

108.90-7

100-41-4

100.42-5

1 , 1 . 2 . 2-Tetrachtoroelhane

1 , 2-Dichloropropane

Trans-1, 3-Oichloropropene

Thchloroethene

Oibromochloromelhane

1 . 1 . 2-Trichloroeihane -

Benzene - • • • ; •-.

cis-1. 3-Dichloroorop-ene

2-Chloroethylvinylelher

Bromoform

2-Hexanone

4-Methyl 2 "entanons

Tetrachloroeihene

Toluene

Chlorobenzene

Elhylbenzene

Styfene

Total Xylenes

ug/l or i^/l(Circleon

^0^^•.?C>1

o®.• ^Q:

'): . , : : • so-^' ^

A-/^G? ^SO50âo.^\

<9Îe)

\

1-

^

\

\\

sl/

0»ta Reporting Qu

o'EPA. ttie lollowing rfl'

Addilionit flags 0( looinoiet ••plJining results are encourBQod Mowflvei.

dfidnilion of eact) flao must be •xoliot '

Vklu* H the fBtutI ii, • value graaier tti«n or oqu«l to 1*^

d«ieciion liniil. rool lf< value -

U lndic«t«( compound •w*t •fivred lo< birt "01 detected

Repon lha mmimun' Oeiflmon limn lor ihe MfnoK wth

the U (eg.. 10<J| b«»*d on f^cetMry concflnift'ort''

dilulion •Clioni fTh«S is not necorurily th« iritlium^nl

d«iaccon limit 1 The <o<rtrwle thould ffl U-

Compourtd we •fvlvied for but noi doieci«<] The

f\urrib«r <( i e mimriurn an«irmblft d laciion limit ICK

the urnple

'This llao apD'ies 10 pesticide infrnBiers wtiere (h<

tdeniilicaiion has bflen contifiTKil bv GC/MS Single

cornooneni peslicides>10 ng/ul in the <in«l eiirJd

should bt condfmed by GC/MS

used when ihe an«lvte it (our i i" ihe tilmk

i sarnpie Imvlicatet possible/'pfobable

minanon e"d warns the d»l* UM' fo lake

aciion

Hags ar^d footnotes "iay be lequi'ed 10

e the fflsuits M uted. ihey TiutI be <ull>«iu-^) rt-s^tioi'o" aliached to ih« daia

Othai dinei speCili

piocwfiv deti

Environmental Prelection Agency. CLP Sample MJniggmem Oftic*.P.O.Box 818. Alexandrie. Virginia 22313 703/557-2490

Sample Number

" ;3Ôrganics Analysis Data Sheet

(Page 2)

Semivolatile Compounds

Concentration: •(^vi/ Medium . (Circle One)

Date Extracted/Prepared:

'dium . (Cir(

v^\s±Date Analyzed:

Conc/Dil Factor

CASNumber

62-75-9

108-95-2

62-53-3

111.44-4

95-57-8

541-73-1

106-46-7

100-51-6

95-50-1

'95-48-7

39638-32-9

106-44-5

621-64.7

67-72-1

98.95-3

78-59-1

88-75.5

105-67-9

65-85-0

1 1 1 - 9 1 - 1

120-83-2

120-82-1

91-20-3

106-47-8

87.68-3

59.50-7

91-57 -6

77-47-4

88-06-2

95-95-4

91-58.7

68-74-4

1 3 1 - 1 1 - 3

N-Nnrosodimethytamine

Phenol

Aniline

bis(-2-Chloroelhyl)Elher

2-Chlorophenol

1. 3-Dichlorobenzene


Benzyl Alcohol

1 , 2-Dichlorobenzene

2-Melhylphenol

bis(2-chloroisopropyl)Etner

4-Methylphenol :

N-Nrtroso-Di-n-Propylarnine

Hexachtocoethane

Nitrobenzene

Isophorone

2-Nitrophenot

2. 4-Dimethylphenol

Benzoic Acid

bis(-2-ChloroeihoxytMeihane

2. 4-Dichlorophenol

1 , 2, 4-Thchloroben2ene

Naphthalene

4-Chloroaniltne ;

Hexachlorobutadiene

4-Chloro-3-Methytphenol

2-Meihylnaph(halene

HeKachlorocyclopentadiene •;

2, 4. 6-Trichlorophenol :

2. 4, 5-Tnchlorophenol

2-Chloronaphihalene

2-Niuoanilme

Dimeihyl PhihalaTe

ug/lorfia^(CireieCT

T-KPOVTl!5Q•nmo-TUTO1-1 (TO1-1 (TO'ntm'nisv-nro"M3t)'MTOTPirD'nvT>/7-,rro-ncn>-runi•T-im>'TT<n)^W:-nTO-ni11^'^ff&"iro'""y&^TO-nst)111^.3?^^fcsro'no-o^ (ro-nro

^^

CASNumber

83-32-9

51-28-5

100-02-7

132-64-9

I'ZI-14-2

606-20-2

84-66-2

7005-72-3

86-73-7

100-01-6

534-52-1

86-30-6

101-55-3

118 -74 -1

87.86.5

8501-8

120-12-7

84-74.2

206-44-0

92-87.5

129-00-0

85-68-7

9)-94-1

56-55-3

1 1 7 - 8 1 - 7

218 -01 -9

117 -84 -0

205-99-2

207.08-9

50-32-8

193-39-5

53-70-3

191.24.2

Acenaphihene

2, 4-Dinitrophenol

4-Nitfophenol

Oibenzofuran

2, 4-Dinitrotoluene

2, 6-Dinitrotoluene

Oiethyfphthalate

4-Chlorophenyl-phenylether

Fluorene

4-Nitroaniline :

4, 6-Dmttro-2-MethylphenoI

N-Nnrosodiphenylamine (1)

4-Bromophenyl-phenylether

Hexachlorobcnzene

Pentach lorophenol

Phenanthrene

Anthracene

Di-n-Bmylphihalale'

Fluoranthene

Benîdine

Pyrene

Buiylbenzylphthalale

3. 3'-Dichlorobenz»dine

Ben20<alAnthracene

bis(2-Elhylhexy()Phthatale

Chrysene

Di-n-Ociyt Phlhalate

Benio(b)Fluoranlhene

BenTo(k)Fluoranthene

Banzo(alPyrene

lndeno<1, 2. 3-cd)Pyfene

Dibenz(a, h)Anthracene

Benzofg. h. itPeryiene

u

1Si:"«•

^

s^'a"^

?,

\c•,vc:^''"

g/l or(Jg^CircieT

-ITO ^

^• l

"?TO10^n^(^

hotiû

100

?FiF3R^-tB\>

"lOT)ITO

r^1-not>^113&'.IS?nini1,^L^BO ^^0^rw \n^-n^ncor^Tiro1-1 rDsT.yo'

/Kg^

t-

\

\r

Environmental Prot«cl(onAg«nCY. CLP Sample Man«g«m«nl Office.P.O. Bo* 618. AI«Mndru,Vln)inr22313 703/557-2490

Organics Analysis Data Sheet(Page 4)

Tentatively Identified Compounds

CASNumbor

1

2

3.

4.

S

fi

7.

B

9.

in1112

13

14

TS7

Ifi

17

in1 9 .

?p21.

17

23

24

25.

7fi

27

2fl

29.

in

Compound Narne

U )A^-> doJb^^''

V^-"v.,A<---v^^- /-^'-^

YM^ <-T^^< \AT^

t^v-l(AY^-\Ar>-^VA'V^rrA^Êr^rv-^——, y r'^——"T ^——-———————————

WtNJZ/n^^xrv.——r(—<—-'———————————————————^k/>s-k/i' <v^

VA -k-Tr\J<a^^v^

U -j< r &<Arv^^ • •

: • ..-....-

Fr.

U

V

etion

^

f——

RT or Sc*n.Nuinbflf

10°1^Ûiop^-s.^r?r^^03^^S^

;•

EJlimatedConcentralton

(ug/1 o^<ig/kg^

^6^0îGTDîGD\\'^Q1?)l6^\n,\6^^1CUîro

;§2

! \ 0

mu-ir-

ui

"•••"C

OC

1

-&-

J

^

^

s^

(

h-* •"

§

^g

g'^

^^^&

JJ&

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——

^ 1,5 ^

^^^^l^

^^^r

—^ '

oo

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--'I>

——

—

x ("S

^A

.)j

fl-^

-T-,9,^

~J-J

J&

en

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p

65

:1

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^—

^^-d

L>ifia

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0

Q

isi

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-7

^^

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01 u

i«t »

QUANTITATION REPORT FILE: EPAVOA1725

DATA: EPAVOA1725. TI88/19/84 9:06:00SAMPLE: 77.1.13-12

SUBMITTED BY SPA ANALYST: RJM

AMOUNT=AREA(HGHT) » REF. AMNT/(REF. AREA<HGHT)* RESP.FACT).RESP. FAC. FROM AVERAGE OF WHOLE . RL

NAME«

HSLHSL

HSLHSLHSL

HSLHSLHSLHSL

BROMOCHLORMETHANE (INTERAL STANDARD)P-DIFLUOROBENZENE (INTERNAL STANDARD)DXCHLOROBENZENE-D5 (INTERNAL STANDARD)CHLOROMETHANEBi"<OMOMETHANEVINYL CHLORIDECHLOROETHANEMETHYLENE CHLORIDEACROLEINACRYLONITRILE

1,1-DICHLOROETHYLENE1.1-DICHLOROETHANETRANS-1,2-DICHLOROETHYLENECHLOROFORM1.2-DICHLOROETHANE1, l., 1-TRICHLOROETHANEACETONECARBON DISULFIDECARBON TETRACHLORIDEBROMODICHLOROMETHANE1,2-OICHLOROPROPANETRAN5-1-3-DICHLOROPROPYLENETRICHLOROETHYLENEB£NZENE 'DIBROMOCHLOROMETHANE1, -., 2-TRICHLOROETHANECIE-1,3-DICHLOROPROPYLENE2-CHLOr.:OETHYL VINYL ETHEREROMOFORMMETHYL ETHYL KETONEVINYL ACETATEMTTHYL ISOBUTYL KETONE1,2-DICHLOROETHANE-D4 (SURROGATE)B£N2:ENE-D6 (SURROGATE)DJr^ROMOTETRAFLUOROETHANE (SURROGATE»

B-T:S ' PERFLUOROISOPROPYL > KETONE ( SURROGATE )FL'JOROBENZENE (SURROGATE)TCThACHLOROETHYLENE1.1,2,2-TETRACHLOROETHANETOLUENE

CHLOROEENZENEE-KYLBENZENE2-HEXANONES"i'RENE

0-XYLEMEM- XYLENE

M-&ROM&BENZOTRIFLUORIDE < SURROGATE)D-5 ETHYLBENZENE (SURROGATE)TOLUENE-DS (SURROGATE)P-E:ROMC'FLUOROBENZENE (SURROGATE)

SCAN3RO-W?8S7

FOUNDFOUNDFOUNDFOUNDFOUNDFOUND

TIME REF13:07 123: 53 229: 17 3

RRT METH1. 000 A BB1. 000 A BB1. 000 A BB

AREA(HGHT)39526.

387673.2666B8.

AMOUNT 7.TOT50. 000 UG/L 9. 1150. 000 UG/L 9. 1150. 000 UG/L 9. 11

M/ENOTNOTNOTNOTNOTNOTNOT58

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

436584

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT9895

SCANFOUNDFOUNDFOUND

FOUNDFOUNDFOUNDFOUND

304FOUNDFOUNDPOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

7254o7

616FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND'FOUNDFOUNDFOUNDFOUNDFOUNDFOUND

S.1510-3&

TIME

10: 23

24: 4615: 5721: 03

27: 5135: 20

REF

1

222

33

RRT

0. 792

1. 8370. 6630. 881

0. 9511. 207

METH

A BB

A BBA BBA BB

A BBA BB

AREA(HGHT)

3513.

19684.335240.672514.

742869.456286.

AMOUNT

19. 273 UG/L

12. 819 UG/L90. 726 UG/L90. 032 UG/L

98. 352 UG/L87. 898 UG/L

7.TOT

3. 51

2. 3316. 5216. 40

17. 9116. 01

DUAL MOSS SPECTRUM03/'19./84 9;0e;08 + 18:23SAMPLE: 77113-12CONDS.!ENHANCED (S 15B 2N 0T)

DATA: EPAUOA1725 #304 BASE M/E! 43/- 43CALl! EPSWOA1725 #1 RIC; 3351. / 6131.

35 45 . . y 55

DUAL MASS SPECTRUM DATA: EPWOA1725 #725 BASE M/'E; 43/- 4383/'19/84 3!06!00 + 24!46 CALI; EPftWftl725 ttl RIC; S399./ 11999.SAMPLE; 77113-12CONDS.:ENHANCED (S 15B 2N 0T;'

100.9-] r 3920.

50.0-

—i 'l111 i—|—P"1—i—r i—I—I—\—'——1—I—1—I—1—[""T—I—<—|—>—I—1—I—'—!—'—1—i—|—^

M/E 58 100 150 200

50,0- r-i iI r

^ i ^

| 0 0 1 . 7 2 : : ' " 392e-

SCANS 1 TO 2860RIC DATA: EPABN1368 #1CALI; EPABH136S ftl63/18 84 14:01:60

SAMPLE; 77113-12CONDS.:RANGE; G 1,2860 LABEL; N 2, 2.8 QUAN: A 1, 3.0 J 8 BASE; U 20,

'J\

LA

5007:55

100015;50

1500

23:45200031:40

250039:35

3UANTITATIGN REPORT

3ATA: EPABN1368.TI39/18/84 14:01:003AMPLF: 77113-123UBMITTE.D BY:

FILE: EPABN1368

ANALYST:

•\MOUNT=AREA(HGHT) * REP. A(";NT/(REF. AREA(HGHT X RESP.FACT)teSP. FAC. FROM AVERAGE OF WHOLE . RL

NO NAMfe.1 * D-4 1,4-DICHLOR03ENZENE2 * D-8 NAPHTHALENE3 » D-8 ACENAPTHENE4 » D-10 PHENANTHRENE5 » D-12 CHRYSENF6 * D-12 PERYLENE7 2-FLUOROPHENOL (SURROGATE)8 D-5 PHENOL (SURROGATE)9 D-5 NITROSENZENE (SURROGATE)10 2-FLUOROBIPHENYL (SURROGATE)11 2,4,6-TRIBROMOPHENOL (SURROGATE)12 D-14 T6.RPHENYL (SURROGATE)13 N-NITROSODIMETHYLAMINfc14 2-CHLOROPHENOL15 PHENOL16 BIS (2-CHLOROETHYL) ETHER17 I,3-DICHLOROBENZENE18 1,4-DICHLOROBENZEME19 I,2-DICHLOROBENZENE20 HSL ANILINE21 HSL BENZYL ALCOHOL2? BIS(2-CHLOROISOPROPYL)ETHER23-. - HEXACHLOROETHANE.34. N-NITROSODIPROPYLAMIN&25 NITROBENZENE26 ISOPHORONE27 2 NITROPHE.NOL28 2,4-DIMETHYLPHENOL29 BIS(2-CHLOROETHOXY»METHANE30 2,4-DICHLOROPHENOL31 I,2,4-TRICHLOROBENZENfc32 NAPHTHALENE33 HEXACHLOROBUTADIENE34 P-CHLORO-M-CRESOL35 HEXACHLOROCYCLOPENTADIENE36 2,4,6-TRICHLOROPHENOL37 HSL 2-METHVLPHENOL38 HSL 4-METHYLPHENOL39 HSL BENZOIC ACID40 HSL 4-CHLOROANILINE41 HSL 2-METHYLNAPHTHALENE42 2-CHLORONAPHTHALENE43 DIMETHYL PHTHALATE44 ACENAPHTHYLENE45 2,6-DINITROTOLUENE46 ACENAPHTHENE

NO NAME47 ' 2,4-DINrTROPHEMOL48 4-NITROPHENOL49 2,4-DINITROTOLUENE50 FLUORENE51 4-CHLOROPHENYL PHENYL ETHER52 DI ETHYL PHTHALATE53 4< 6-DINITRO-2-METHYLPHENOL54 N-NITROSODIPHENYLAKINE55 1,2-DIPHENYLHYDRAZINE56 4-BROMOPHENYL PHENYL ETHtR57 HEXACHLOROBENZENE58 PENTACHLOROPHENOL59 PHENANTHRENE60 AN1HRACENE61 DI-N-BUTYL PHTHALATE62 FLUORANTHFNE63 HSL 2,4,5-TRICHLOROPHENOL64 HSL 2-NITROANILINE65 HSL 3-NrTROANILrNE66 HSL DIBENZOFURAN67 HSL 4-NITROANILINE68 BENZIDINE69 PYRENE70 BENZYL BUTYL PHTHALATE71 BENZCK A)ANTHRACENE72 3,3'-DICHLOROBENZIDrNL73 CHRYSENE74 BIS(2-ETHYLHEXYL> PH7HALATE75 DI-N-OCTYL PHTHALATE76 BENZCK B>FLUORANTHENE77 BENZO(K>FLUORANTHENE_7S________BENZO (A > PYRENE79 INDENOd, 2, 3-CD1PYRENF80 DIBENZOCA,H>ANTHRACENE81 BENZCHGHDPERYLENE

NO M/E SCAN TIME REt- RRT KFTH AREA(HSHT) AMOUNT 7.TOT

NO123456789

10111213141516171819202122232425262728293031I?3334 -353637383940

424344454647434950515253545556

M/E'152136164188240264NOT

•NOTNOTNOTNOTNOTNOT

'NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

.NOTNOTNOT

.NOT• i ya

:NOT107-NOTNOTNOTNOTNOT•NOT

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

SCAN702942

1280155920672320

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

9A4—FOUND

-—WtWJ~FOUNDFOUNDFOUNDFOUNDFOUNDFOUND

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

T111420243236

17

IME075516414441

06

REI-123456

2

1.1.1.1.1.1.

1.

RRT000000000000000000

146

'146

MEAAAAAA

A

£THBBBVBBBBBBBV

T?B———

ua

AREA<H3HT2&364.72157.41305.78294.73583.52?87.

—————3Tt-.———

"——271-———

) AMOUNT40.00040. 00040.00040.00040-00040.000

————0.154-

—"0. ^04

———©-£83-

UO/MLUO/MLUO/MLUG/MLue/MLUG/ML

US/ML

-O&TfH——

-Ue^SL-

•/.TOT15. 6415. 6415. 6415. 6415. 6415. 64

—8-06———

—0—24

n 11

NO

58

60^—6263646566 .67

697e~717273747576777879 :8081

M/E

NOT

NOT

NOTNOTNOTNOTNOTNOT

NOT-*-49-NOTNOTNOT149

NOTNOTNOTNOTNOTNOT

SCAN TIME RE

FOUND

FOUND—IWt——2S-59——-AFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

FOUND—T7B7—31: 2B——5FOUNDFOUNDFOUND2106 33:21 S

•—SPly—35. 06——tFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

:F RF

t——1-0<5

1. 01

^T MET

?3——ft-Bl

sn—a-w

9 A*B^ 5 A S ^

H AREAO

B————————794

B 13057B—————- 5004

4-3HT) AMOUNT,

! 0 . c 7 5 u G /

h—————- 0. 338 W71

r:——————0. ^^6 UG/

6.896 UG/———— 1 , p7-4 UP/I

%TOT

«fc—&-+a——

HI.——U. 14——

Mt——O-O?"^" '''

/

ML 2. 70 Qt-LQ^3—— o

DUAL MASS SPECTRUM89/18/84 14:01:00 + 14:57SAMPLE; 77113-12CONDS.!ENHANCED <S 15B 2H 6T)

DATA: EPABH1368 ft944CALI: EPABN13G8 #1

BASE M/E; 128/ 136RIC: 212./ 6495.

p ' I ' M ' ' i i t u 1 \ r

DUAL MASS SPECTRUM09/18/-84 14:91:00 + 17:06SAMPLE: 77113-12CONDS.!ENHANCED <S 15B 2N 0T)

DATA! EPABN1368 #1080 BASE H/-E! 82/ 82CALI: EPABN13£8 #1 RIC; 17823./ 23551.

160

•a- <s>oo (M

,

(M

L

oo '•-C--4

•0-1

— in

UJ —

i

UJ

So-

^5

0000

LO U

id

CT

55

CQ C

O<

r<r

UJ UJ

liQ 00 —

I

UJO

CT

Cl_

•• •u"i •

- »-* in

Ln p~

i-n •i-

0^

00

••

•• LU^

S

. U

J .

1_)

co _i m

z-i-rt CL. Q

<r<r '-. •z- z

i=< cri <r o

z0

0 IT

l 0 U

J

en

3

t-n

o<s

> \

o

CT•

m

• •

CZ"

CT

G*

mo

w o

o3: 0

3>

LO C

o-

m •

s 3

(n •

• ••

oo

o

-s-

LTI

^J

LH/

. -J

>-*

Ln

^ -

fcin

»-*

—

•vw

<sm

i —

• o

^s >— 3

>

??

M W

cn e

nC

O 0

0

SC

D

^^

2§o

DUAL MASS SPECTRUM09/18/84 14:01:00 + 26:59SAMPLE: 77113-12CONDS.:ENHANCED <S 15B 2N 8T)

DATA: EPABN1368 #1704CALI; EPABN1368 #1

BASE 11/Ei 149/ 149RIC; 592./ 1327.

DUAL MASS SPECTRUM09/18/84 14:61:09 + 29:44SAMPLE: 77113-12CONDS.:ENHANCED (S 15B 2N 0T)

DATA; EPABN1368 #1878 BASE M/E: 67/ 67CALI: EPABH13G8 «1 RIC: 150527./ 221439.

r 63872.

289 256*—l—i

DUAL MASS SPECTRUM09/18/84 14:01:60 + 31:28SAMPLE; 77113-12

• CONDS.sENHANCED <S 15B 2N 6T)

DATA: EPABN1368 #1987 BASE 11/E: 149/ £7CALI; EPABN1368 #1 RIC: 467./ 7743.

~I——r

00 1

DUAL MASS SPECTRUM09/-18/-84 14:31:00 + 33:21SAMPLE; 77113-12CONDS.;ENHANCED <S 15B 2N OT)

DATA: EPABN1368 »2106 BASE 11/E: 149/- 149CALI: EPABN1368 #1 RIC: 17023./- 25183.

i I i I i

m>-•! < i 1 - 1 i i

250

DATA: EPABN1368 #2217 BASE M/E; 149/ 149CALI: EPABN13G8 ttl RIC; 4719./ 16511.

DUAL MASS SPECTRUM69/18/84 14;01:00 + 35;06SAMPLE; 77113-12CONDS.;ENHANCED (S 15B 2N 0T)

i 1 1 | i

200 250

0 0

i " : ' i. U 0 I

LIBRARY SEARCH , DATA: EPABH1368 ft 709 BASE M-'E: £609/18/84 14:01:00 + 11:14 ! CALI: EPABH1368 ft 1 RIC: 208447.SAMPLE: 77113-12CONDS.:

1233 i r ••

SAMPLE

C1U.H18.0 CYCLOHE^AHOL-1-METHYL-4-(1-MET

N NT1?^' 13 PK 6bRANK 1W 6537m 961-1 •

Cla.H12 4,7-METHAHO-1H-IHOEHE...3H..4..7;7

M m r , rB PK 66RAHK 2IN 3648FIT 957 -

C1".H12_ 1-2,4-METHEHO-1H-CYCLOBUTA[CD3

,'1 NT fs5 1B PK 66RANK 3IN 3664FIT 946' •

r'l/E 40 60 59 100 120 140

1080

SAMPLE

J S . H l U.1 m'•S PK 91WNK 1W 1441"IT 935

:.11.H14.0

.1 ^?94 1?. PK 91W. 2W 1199671T 983

;9.H10.02

• NT1?^3 FK 91W, 3I N £071^IT 88U

t-l/'E

r

3f

r

1 ,

4

LI09SACO

3

BRftRY SEARC/18/S4 14:0•1PLE: 7711;NDS.s

l l l . l , . , , , ,cy

5,

BE

, , . , , ,L,60

'€'• • •

H1:00 + It

-12

CLOPEHTEt

1, , , . , 1

3,7-1:1,2,

NZEHEPROF

, 1

S.-52

E.I

11 ,33P

l4Lw.

S0

0 0

-ETHEt

ROPAHE

ICACIC

1 1 , . . . i . 1IYL-3-METh

TRIVLBEH^

1

J

1 i

106

I h , ,^Y

I ' l , , , , , ,0

OftTA: ECALI: E

120

PABN136S #166PABN1368 »

140

5 BASE M/E: 661 RIC:. 212479.

160 180

0 0

LIBRARY SEARCH09/18/84 14:01:06 + 17;34SAMPLE: 77113-12CONDS.:

DATA: EPABN1368 ft 111 8CALI: EPABN1368 » 1

BASE t1/E! 154RIC; 62143.

1099 i

SAMPLE

C8.H4.03

t-1 HT^JS3 PK 1@4RANK 1IN 5821.-"IT 993

C.P..H6.04

n NT1!^B PK 76RANK 2IN 8447FIT 979

1,2-BEHZEHEDICftRBOCTLICAC10

C9.H8.04

.•1 MT 185E; PK 76RdNK 3IN 10402FIT 930

1 - 2-BEHZEHEDICARBOWLICACID/ NO

M./E 40 69 80 10U 120 140 160

ez.z. @e7. esi es i OI'T ezi sen e's 09 et- 3/u •————————————————^———————^————————————————————————^

• It'8 lidS,8 N1e '>fny;aI£I »d 3931 1M ^

•i -' L

aRni-('lAN3irig-3-OamH3-.3) '3N32H3a U • nH •ei3

——————————^————^————————^———^

St'S lidSZ38 MIz »nyaic i Md a931 1H U J J

OU0I2'?' -"i.'.n3Hd-1 -ciaoiH';i-e '• 3H3ina-s no • T i H • e i o

I———————————————————————^r^—————"^r^————————————[n^——————1

• ;S3 II;SSt'S HIi waISI Md ?3H Itl H

•' -' Sum3HIG-T •• I-OailtHIQ-S '3 '3H30HI-HI t'TH • 1 T::i

1———-———————————————————————.——————————r-hfJl————^——————mrfp———m————[|||"l"l'|l"|"l|-'

31dU9S

•• '• H00I: s'SONOO

zi-snz^ :3-idnys•i3i'si ^la i ft 83£ingyd3 'iiyo 3i:z? + @@!i0=t'i t'8/8T/'6993 :3/'n 3sy'a sz/Tft 83sinayd3 sylw . mms Aayaan

0 0 1 ^ -; 0

L 00

LIBRARY SEARCH39-/18/84 14:01:88 + 29:44SAMPLE: 77113-12CONDS.:

DATA: EPABN1368 «1878CALI: EPABH1368 tt 1

BASE M./E: 67RIC: 211711.

l@i3Ei ^ ,

SAMPLE

C8 .H7 .U .NIHHO -

n MT IS.S3 PK 133 .RAHK 1I N 3839 •m 911 -

BEH2EHEACETON I TR I LE, 4-H'iORU;-:Y-

CU3.HU3.0.M2.SlOyQ i '•

H NT 255B PK 133RANK 2IH 13494FIT S98 •

C8.H7.0.H

;'l NT I'S^6 PK 133RhHK 3IN 3827FIT 886 •

1H-IHDOL-5-OL

r'l/E 56 ln0 15S 258

Z ( ; 1. 0 0 : :

LIBRARY SEARCH DATA: EPABH1368 #2120 E:ASE M/E; 9109/18/84 14:01:00 + 33:34 CALI; EPABH1368 # 1 RIC : 24319.SAMPLE: 77113-12COHDS.:

1008 i

SAMPLE ^

I I ,1 | 1 . llll.l lll.ll ..ll . ., ll|l . |.. . lll| . . . I... . |. . .ll. . 1 | 1 . . , 1 1 III,____________________T-———_____________________| , , ,

U15.H14.H. I PHEHHHTHRIDINIUt1 - 5,b-DIMETHYL-

M NT 335 13 PK 287RAHK 1IH 24387-"IT 867 •

[ _ _ _ _ _ , - . , . • . . • • . . ,' . . . . .11._____,..-. , j. , ..li, . | , 1 1 . , . 1 1 1 ' , ______________________, . , .1

C22.H2^S BEHZEHE, \, \' -[:2-t'1ETH'('L-2-(PHEH

M HT ^i \B PK 129RANK 2IN 23226FIT 857 • i

C15.H13.H 1H-IHDCILE,2-HETHYL-3-PHEHYL-

,1 ^287 1 •B PK 207RANK 3I N 13732F I T 79S •

, , . , . , . , . , . , 1 1 , ,_____| . , . , i . . n| , .nil, . . . , l|il, _____^_,___________, . , . ,

M/E 50 1UU 150 200 250 3m3

0 0

LIBRARY SEARCHeo/-18/'S4 14:91:00 + 36:44SAMPLE: 77113-12COHDS. -.

DATA: EPABH1368 tt232QCALI: EPABH1368 # 1

BASE M/E: 264RIC: 41823.

1608 i

SAMPLE

C15.H24.02.H2 SPARTEIHE/14. ALPHA. -HYDROi/Y-17

M 1.JT 2£43 Pf; 264RAHK 1IH 19233HT 727

C17.H12.0.H2

. m}E; PK 26HRHHK 2IN 18957FIT 719

4 (1 H) -U.U I HftZOL I HOME.. 2-PHEHVL-1

C13.H8.U.SE

;•] HT 26.§B PK 268RANK 3IN 1 8 9 1 1FIT 694 •

I'l/E 10t3 159 200

. - . 1 0 0 , , . . .

LIBRARY SEARCH : I DATA: EPABH1368 S2453 BASE M/E; 6709/18./84 14:01:00 + 38:58 : , • ' , CALI: EPABH1368 # ' 1 RIC: 241663.SAMPLE; 77113-12 :CONDS.:

1069 Y .

SAMPLE ) I ^: I

. . j . ...^ . . . . . .

,i ,...ii. |1, .lil.k l.i,I. i.L.JI.___^______________,C8.H7.U.H BENZENEACETOHITRILE-4-HYDROW- ' !

N 1-JT 133 r :3 PK 133 'RANK 1 :W 3830r I T 901 • ! •

. 1 1 1 ! .u — i i i i , . . . , , 1 1 , , i . , i i i , . , , ,11..,.,____,, i , , . : , , , . , _ _ _ _ , , , , , , , , , , , , , , . , . , , , >Cy.H12.H2 H'('DRH2IHE,';'2-PHEH''f'LETHYL'-

nHT^r ; ' [B PK 105RANK 2IH 4161FIT 834 - :

C3. H 11. H AZ I R I D I NE. 2- (PHEHVLMETH'i'L ;• -1 FIH0 ^ r r

;1 W 133B PK 91RANK 3I N 3839FIT 877 J

I. .1 . . I . II. !.ll,.^.J__________________________^__________________________

M/'E 59 168 150 200 . : 250 300 350

EnvironmentsP. 0 Box 818.

Protection AgerAlexandria. V

' ;

ID No

n. ^

ncy. CLPSampleManagementOffice,f0inia22313 703/557-2490

Organics Analysis D(Page 1)

.^-T^S-h/^ r,.7 7 / ^ - < / z ^ .Ll————.J—————————— Cor

By. y^ • " • Dal

v , Volatile Cornpol

Concentration: ^[.ow} Med<u• — — O."

nato Analyrcri- 0 f 1^ J

Percent Moisture (Decanted): •

)ata Sheet

o Mn-

Rt.n"rt Nn /./ —'

Trad Nn- t? fc

JndsJm (Circle One)

ÎW

^1

pH .... ....

Sample Number

/^ /^3

^0^

o/-fcys^^j^?^// '

CASNumber

74-87-3

74-83-9

75-01-4

75-00-3

75-09-2

67-64-1 .

75-1'5:Q::.';,:

75-3.5-4;-.: 7.

^5-34-3: -/

156-60-5

67-66-3

107-06-2

78-93-"3'

71-55-6

56.23.5

108-05-4

75-27-4

Chloromethane

Bromomethane

Vinyl Chloride

Chloroethane

Melhylene Chloride

Acetone .

CSrtidn.Disul'ida"-' .-"" ~

.L l OichloroethBta-^^-;-

1 , 1-Dichlofoethane

Trans-1, 2-Dichloroethene '

Chloroform

1, 2-OichIordelhane

2-8uianone

1 , 1 . 1-Trichloroelhane


Vinyl Acetale


ug7(C

:!

.^

ff

•'"•'•:

lor 16Yirclft

^ i%.

(7 t )/¥,-1TrY v^^•y•^—-

QJ

t6 4

^^ î,rs

/jKg,onef/ '

f^/

V

Jh

^

CASNumber

79-34-5

78-87-5

10061-02-6

79-01-6

124-48-1

79-00-5

.71-43-2

10061 -01 -5

110-75-8

75.25-2

591-78-6

108-10-'

127-18-4

108-88-3

108-90-7

100-41-4

100-42-5

1. 1,2. 2-Telrachloroeihane

1, S-Dichloropropane

Trans-1. 3-Dichloropropene

Trichlofoeihene

Dibromochforomethane

1. I, 2-Thchloroelhane

Benzene •...,..:.:. . - ; , '.

CtS-1. 3-DfcMoropropene "

-2-Chloroethylvinylelher

Bromotorm

2-Hexanone

A.Mel^v!-2-P""t3r:cne

Tetrachloroeihene

Toluene

Chlorobenzene

Ethylbenzene

Stvrene

Total Xylenes

ug/f or w/^(CircleW

^ fu -y •q :• c? •

Q- :-r^—f

^^^^^S^ u^ ;q \^?1u

Kg^rreii

/ .

: OJU Raponiofl Qualifiefi

Addilional 11ao&or looinoiafplatning results •re en

- (l^tnit'on of eacti tlag musl tr •H{3l(C<tJraQftd How<»<' ina

f than of w^l 1rf ihe fetuh <

tffllOCIion lirr

lodicatflt compouruS was Jnalyz«d ftx but not fl«t«CHd

Rapon ih< minimum daiecrion Iwn Kx ihc Mmplawnth

<h< Utco . 10U)t>B»«lon ^^®ce..MfVCortc«nlf»^ô"rF

dilution •ctionc fThit ix noi n«c«tUfilv the iniifm"-»il

d»i»<nion limn .) The (oolnole Tioutd r»»d U-

Compound was •rv*lYtO<J for bul not d«rccd Th«

nufntKf i« ih« m.nimu<ri •na<n«b4a d«teClion lirmi <e'

tha t*mpl<

lridic«ta« •n ««nmatBd v«lu«. Thr 41«Q'rt ufted •iltwr

Kl«nm»»d compoundt wt^f • 1 1 TCSOO"M it •tuxwd

Tins (l<fl •ppl<«t 10 p«siiC<d< DflrarrmiBft »vh»re iht

•dem location has txan condfrrwd by GC/MS Singit

comporwni p<siic»des^l0 ng/ul in the Unal flmraci

Should be confirmed by GC/MS

This Hag <s uted wtten ihe •nalflo it found ni the blank

•i. wall «S a urnol« It indicales pofSible/prooable

blank coniarn<n«iion •nd wfni ih« data u4Cf 10 take

apo'op'n't aciio"

Olher tpecilic t i tos and looinoiei may be Kguirsd 10

prooerly deiine Ihe r«sultt M u**d. they mud be tul'v

d««cnt>«d •nd •uch d«&cnpliori •nuchad (o irw data

tumrnary fcpor't

Environm«nfl Protection Agency. CLP Sampte Management Office.P. 0. Box 818, Alexandria. Virginia 22313 703/S57-2490


Sample

^

i Number

5V


Concentration: • (U>y/ Medium .(Circle One)

Date Extracted/Prepared:

edium .(Circit

•pared: ^^\&4

^VBVgADate Analyzed:

Conc/Dil Factor:

CASNumber

62-75-9

108-95-2

62-53-3

1 1 1 - 4 4 - 4

95-57-8

541-73-1

106-46-7

100-51-6

95-50-1

95-48-7

39638-32-9

106-44-5

621-64-7

67-72-1

98-95-3

78.59-1

88-75-5

105-67-9

65-85-0

1 1 1 - 9 1 - 1

120-83-2

120-82-1

91-20-3 •

106-47-8

87-68-3

59-50-7

91-57-6

77-47-4

8B-06-2

95-95-4

91 .58 -7

88.74-4

1 3 1 - 1 1 . 3

208-96.8

99.09.2

N-Nitrosodimethylamine

Phenol

Aniline

bis(-2-Chlofoethyl)Elher

2-C+itorophenol i

1 . 3-Dichlorobenzene

1,4-Dichforobenzene

Benzyl Alcohol - -——— '.-'—'.'-

1,.2-Drchlorobenzene !

2-Meihylphenol ;

bis(2-chtoroisopropyl)Elher ,

4-Methylphenol ^

N-Nitroso-Di-n-Prdpylamine

Hexachtoroethane •

Nitrobenzene

Isophorone

2-Nilrophenol

2, 4-Dimethylphenol

Benzoic Acid :

bis(-2-ChloroeihoxY)Methane

2. 4-Dichlorophenol

1 , 2. 4-Trichlorobenzene .

"Naphthalene ' '

4-Chloroaniline i

Hexachlorobuiadiene :

4-Chloro-3-Meihylphenol

2-Meihylnaphthalene -

Hexachlorocyclopflniadiene ;

2. 4. 6-Tnchlorophenol i

2. 4. 5-Tcichlorophenol :

2-ChIoronaphthatene

2-Nilroaniline

Dimethyl Phihalate . !

Acenaphthylene i

3-Nitroaniline

ug/l wftg/(CircieOn

^^0^

^^0

?,<=> 0

^^0^5^0A5\0^^•Sf5^5K^fA.O

te^D t^\o^2>oIS-SO^^0

te>- o^to^5^0-1LRT>^^^^^\Q

i nAts^n^Xn^^^^0^>ÎJO

n^c?oassonLô^^3<io\->^C3-)\

K»?a)

^

\/

CASNumber

83-32-9

51-28-5

100-02-7

1J32-64-9

121-14 .2

606.20.2

84-66-2

7005-72-3

86-73-7

100-01-6

534-52-1

86.30-6

101-55-3

1 1 8 - 7 4 - 1

87-86-5

85-01-8

120-12-7

84-74-2

206-44-0

92-87-5

129-00-0

85-68-7

91-94.1

56-55-3

1 1 7 - 8 1 - 7

218-01-9

117-84-0

205-99-2

207-08-9

50-32-8

193-39-5

53.70-3

191-24 .2

Acenaphthene

2, 4-Dinitrophenol

4-Niirophenol

Dibenzofuran

2,4-Dinnrotoluene •

2. 6-Dinitrotoluene

Diethylphthalale

4-Chlorophenyl-phenyletrier

Ftuorerie"." :" '^

4-Nitroaniline - - - . - - ;

4, 6-Dinitro-2-Methylphenol

N-Nilrosodiphenylamine ( 1 )

4-Bromophenyl-phenylether

Hexachlorobenzene

Penlachlorophenol

ênanthrene

Anthracene

Oi-n-Butylphlhatale

Fluoranthene

Be mid me

Pyrene

Butylbenzylphthatate

3. 3'-0ichlorobenzidine

Ben2o(a)Anthracene .

bis(2-Ethylhexyl)Phlhalaie

Chrysene

Oi-n-Ociyl Phthalate

Benro(b|Fluoranthene

8enzo(k)F(uoranIhene

Benzo(alPyrene

lndeno(l. 2. 3-cd|Pyrene

Dibenz(a, htAnlhracene

Genzofg. h, i)Perylene

ug/lor^/Kg^(CircleCne

^^0^

ni,« \h .<=?D:SSô3 ioio

A5ô^^03%>>o -n\os&.\-lLÔ35^^^lo

rn.cDS- o^^Sssoi ô^^•y.^)F5^-'101,0 ,te^^-70^-rlo^

Â^\S5io^5^03G30^5^0Âo'SS' o^-

Envifonnwiul Protection AQ«IKY. CLPS«(npl«Maruo«fn«nt Office.P. 0. Bo» 818. Ateundni. Virgin- 22313 703/S57-2490


Sample Number

f^fl'^


CASNumtxr

l^

7

3

A.

5.

fi

7

a9

in1 1 -ii

13, .

14

1!;

16

17

m19

20

71 .

71

23

24

2?

7fi

27

7R

29

-in

Compound Nama

LUlOHU^^

^, s , - •-rr i ^-M- p^ - •///^1^.iGUJ>Y'(jl ^

U»"-(<'v\J»vi i :

..,.. -.„.-„——..^-..^-^-..^-.——— ' ^ — ^

: -.' -—-.-. •

^

'

!

Fraction

. uoft-\,/

'ftfl

RT or SonNumbor

.

-^H'W^.

3^^

•

EatirnatadConca nt ro{ia&

(ug/1 oc-tig/kgl/

^05&^0

^-l o

QUANTITATION REPORT FILE: EPABN1369

DATA: EPABN1369. TI09/18/84 15:01:00SAMPLE: 77113-13SUBMITTED BY: ANALYST:

AMOUNT°AREA(HGHT) • REF.AMNT/(REF.AREA(HQHT)» RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . R L

NO NAME1 * D-4 1,4-DICHLOROBENZENE2 •» D-8 NAPHTHALENE3 » D-8 ACENAPTHENE4 » D-10 PHENANTHRENE5 » D-12 CHRYSENE6 » D-12 PERYLENf-7 2-FLUOROPHENOL (SURROGATE)B D-5 PHENOL (SURROGATE) •9 D-5 NITROBENZENE (SURROGATE) .-.

10 2-FLUOROBIPHENYL (SURROGATE) Q11 2i4,6-TRIBROMOPHENOL (SURROGATE)12 D-14 TERPHENYL (SURROGATE.)13 N-NITROSODIMETHYLAMIN?14 2-CHLOROPHENOL :

15 PHENOL16 BIS (2-CHLOROETHYL) ETHFR17 1,3-DICHLOROBENZENE18 I,4-DICHLOROBENZENEI? 1,2-DICHLC)R6BENZENE20 HSL ANILINE21 HSL BENZYL ALCOHOL23 B.IS(2-CHLOBOISOPROPYL)ETHER , .23 ' HEXACHU3ROETHSKEr-^.::::::=::-——" - -- ;; : - . : ; . . ' . ;24 ' N-NITROSODIPROPYLAt+INe " • ' • . . . . - -- .—.^—^^^.''. ^ " • - . ^25 NITROBENZENE26 ISOPHORONE'27 2-NITROPHENOL28 2,4-DIMETHYLPHENOL "29 BIS(2-CHLOROETHOXY)METHANE30 2,4-DICHLOROPHENOL31 1,2,4-TRICHLOROBENZENE32 NAPHTHALENE33 HEXACHI-OROBUTADIENfc34 P-CHLORO-M-CRESOL35 HEXACHLOROCYCLOPENTADIENF36 2,4,6-TRICHLOROPHENOL37 HSL 2 METHYLPHENOL38 HSL 4-METHYLPHENOL .39 HSL BENZOIC A C I D ;40 HSL 4-CHLOROANILINE41 HSL 2-METHYLNAPHTHALENE42 2-CHLORONAPHTHALENE43 DIMETHYL PHTHALATE44 ACENAPHTHYLENE45 2,6-DINITROTOLUENE46 ACENAPHTHENE

I/ 0 0

SCANS 1 TO 1300RIC DATA; EPAWA1719 #1CftLI: EPAUOA1719 ftl03/13^34 3:07:60

SAMPLE; 77113-13CONDS.;RANGE: G 1-1300 LABEL: N 0, 4.0 QUAN: A 9- 1.0 J 8 BASE: I) 20- 3

725

QUANTITATION -.EPORT FILE: EPAVOA1719

DATA: EPAVOA-'l1?. "I08/19/84 3:>i7:eeSAMPLE: 7711:—1;SUBMITTED BY iPf-. ANALYST: RJM

AMOUNT»AREA -.- »£?-. AMNT/(REF. AREA>» RESP.FACT)RESP. FAC. F-tOM AVERAGE OF WHOLE . RL

NAME*«•»

HSLHSL

HSLHSLHSL

HSLHSLHSLHSL

BrtOMOCHLORMETHANE (INTERAL STANDARD)P-DIFLUOROBENZENE (INTERNAL STANDARD)DrCHLOROBENZENE-05 (INTERNAL STANDARD)CHLOROMETHANEB.TOMOMETHANEVINYL CHLORIDECuLOROETHANEM£THVLENE CHLORIDEA!:F<OLEINACRYLONITRILE1 -—D.ICHLOROETHYLENE1 i-DICHLOROETHANET'-fANS-l, 2-DICHLOROETHYLENECHl-OROFORM1 ,;-DICHLOROETHANE1. -. . .1-TRICHLOROETHANEACETONECARBON DISULFIDECWWh TETRACHLORIDEB 'OMOUICHLOROMETHANE1 £-DICHLOROPROPANETRANS-i, 3-DICHLOROPROPYLENETi^ICHLOROETHYLENEBENZENEDIBROMOCHLOROMETHANE1 1.2-TRICHLOROETHANEC1S-J., 3-DICHLOROPROPYLENE2-CHt.OROETHYL VINYL ETHERBF,OriOFORMM^TRYI- ETHYL KETONEVJ.".';'L. ACETATEM?7HV1- ISOBUTYL KETONE1, L--D-I CHLOROETHANE-D4 ( SURROGATE )BLNZENE-D6 (SURROGATE)D-LE'KOMOTETRAFLUOROETHANE (SURROGATE)BJ.;, < PERFLUOROISOPROPYL ) KETONE ( SURROGATE )FLUOROBENZENE (SURROGATE)TCTXACHLOROETHYLENE1 .., S, 2-TETRACHLOROETHANETi.Ll'^NECI--L.OKOBENZENEE1HV!.BENZENE2- :r>'ANONES'Yf<i--M£0 •:'.'(LeNEM ..Vi.i-NE

NO474B4950

N0123456789

1011121314

NAME

M/E130114117NOTNOTNOTNOT

84NOTNOTNOTNOTNOTNOT

M- ;.-<RD ••••-Tu'.. :lP - ;-;h

S C - ,3--,6-1.-B.--.t..

FOUN;:-FOUNC.FOUNnFOU^C

2.;;"FOU-.-;.FOU^"FOU.-iFOU^::FOU"i:'FOU:v.:-

OrlOBENZE.IHYLBE^Nt-DBOi'lOFLUO

IME.-:0723: 312°: 15

''•. 4B

OTRIFNZENt(SURFROBEI'

REF123

1

^LUORID; (SURR

DOGATE)>IZENE <

RRT1. 0001. 0001. 000

0. 747

E (SURROGATE)OGATE)

SURROGATE >

METH AREA BB 24A BB 10&A BB 57

A BB 24


2B. 336 UG/L 0. 94

NO151617181920212223242526272B2930313233343536.^7:

3Q—39—404142

4445 .46-47484950

M/ENOT

9758

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

436584

NOTNOTNOT-t66

NOTNOTNOT

NOTNOTNOT•NOTNOT

9895

• SCA1VFOUND

5;-3y'

FOUNDFOUNDFOUND

FOUNDFOUNDPOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

FOU.iDFOUND

7 •:••?-4s-6-c

FOU. .:-FOUNDFOUN^

/

FOUMDFOU.M^FOUM;:.

——T~"—FOUMUFOUNDFOUNDFOUNDFOUND

8-;'10:;::

TIME

'-?: 3616: 23

:-4: 46•^=••57--:-:03

- ?l::37

—S I'. 25 ~-

"'--: 51::::=: 22

REF

1 1.1 0.

2 1.2 0.2 0.

—3——07

-—3——0—

3 0.3 1.

RRT

341792

039669B83

'91 y -

?Q3—

952209

METH

A BBA BB

A BBA BBA BB

-~A-B&——

A BBA BB

AREA(HGHT)

49334.7767.

920137.97680.

191749.

374B. —

" 8 3 2 0 ;

177012.10BB53.

AMOUNT

43. 194 UG/L156. 133 UG/L

2198. 620 UG/L96- 641 UG/L93. 845 UG/L

I'-i'i - ^

24. 256~nG7I~

108. B29 UG/L97. 376 UG/L

•/.TOT

1. 445. 20

73. 023. 223. 13

——&-T4-

3. 633. 25

DUAL MASS SPECTRUM88/'13/'84 3:07; 68 + 9; 48SAMPLE! 77113-13COHDS.!ENHANCED <S 15B 2H 0T>

DATA: EPAUOA1719 #237 BASE M/'E: 49.-- 49CALIi EP'r)UOA17l3 »1 RIC: 21631./ ' 25433.

-i—i—i—|—r

159

ou83SACOEN

-^;

AL M/13/MPLENDS.HflMCE

0

ASS SPECTRUM84 3;07;e9 + 17

77113-13

ED <S 15B 2N 0T>

1 • ] i ]

50

H—————————T]

3£

6i0

•:

' 1 ' I70 8e

-rJ——————|—————1——,———L

DATA; EPAWA1Cfti-I: EPflUOAl

i•

i

• • , ' 1 1 '901 i

i i ] ' 1 |

7171

1

T

9 #515 BflSE M/'E: 97.-'9 #1 RIC; 31£73./'

' 1 ' 100 110 120

-L i i i .. i ,

9735833.

r 9'

DUAL MASS SPECTRUM DATA! EPAWA1719 #384 BASE M.-'E! 43/ 4383/19/34 3;07:00 + 10! 23 CftLIi EPWOA1719 #1 RIC,- 6967. / 18343.SAMPLE: 77113-13CONDS.!ENHANCED <S 15B 2H 0T)

100.0-1 • r 449£.

50.0-

M/E 50 108 158 200——J—————————1—————————^—————————L

^n.n -I

i i

100.9-' ' ' • : : 0 0 1 ' ('! ^ ' 4496-

DUAL MASS SPECTRUM83/19/'S4 3; 67; 00 + 24:46SAMPLE; 77113-13CONDS.;ENHANCED (S 15B 2N 0T)

DATA; EPAUOA1719 »725 BASE M-'E; 43/ 43CfiLIi EFATOA1719 ftl RIC; 410623.-' 430591.

289

OWL MASS SPECTRUM OUTA: EPWOA1719 <t773 BflSE tl/'E; 43/ 4483/19/84 3! 87; 09 + 26; 25 CALIi EPAUOA1719 «1 RIC; 802..-' 12847.SAMPLE; 77113-13CONDS.;ENHANCED <S 15B 2N 8T.''

100.0-] r- 2868.

50.0- '

M-/E 56 100 ' 150 280i 1 I - 1 l I i 1 i 1 ^ 1 . 1 i I i I i l i I i 1 i I i—1—1—I i I i I i

c.n a -i

i i

I I : ;

100.0-1 ; : 0 0 1 ' " 0 7 286e-

cs

,n0

3

(s

a

3

(Jl

••s

(0m

0

0

z L

II r~

Eo

•

m •-

> 3

m —

•"

co

x>0

A

LT]

-\J

LO

-~.

'JLT

] >—

(0

L>"

l»-

- —

"D

»--

o c

o rn

Ul

I --

1 0

ro

^ —

—

iCL

> CO

;0

r-i

o c

:

m m

•o •

nJ>

3-

•I:

•C:

0 0

X>

I>

tt <

t^

^J

-J LD

OT

l— 0

00

3>

— L

n m

co m

^ ••> e

n o-i •-,

-l——

i——

l——

i——

i——

i r,)

' '

— -

o.(0

-0.

DUAL MASS SPECTRUM DATA! EPAUOA1719 #782 BASE fl/'E: S3/' 440S/19/'S4 3!07:00 + 26;43 CftLl! EPftUOfll719 #1 RIC! 7873./ 19887.SAMPLE: 77113-13CONDS.:ENHANCED (S 15B 2N 0T>

180.0-1 r 3140.

50.0-

' i , ln, i i l i i i ,.i,., Jj.i,iiiii i , , , , , 1 , 1 , , , i , , 1 , 1 , , , , , , i , 'M/E 50 100 150 230

I I llll'illllll ' |li|'|%' Il||1' ' ' 1 ' ' | ' | i ' ' ' ' ' ' I ' l l ' ' ' " ' ' ' | 1

.n n J (-

.100.0- . . . . | i i 0 0 1 ^ ; 0 9 3l4e-

' ! i

. 0 i- ?;• 1 0 0

LIBRARY SEARCH DATA: EPAUOA1719 tt 763 BASE M/E; 5508/19/64 3;07;00 + 26:04 CALI: EPAWA1719 ft 1 RICi 20895.SAMPLE; 77113-13CONDS.:ENHANCED <S 15B 21-1 0T)

1902 i

SAMPLE

1 , 1 , 1 , . . . . i j i i , , . ii,_____L___LC8.H16_ 2-PEHTENE,2,3,4-TRIHETHYL-

11 W^i ]B PK 55RANK 1IN 1813F I T 982

;8. H 16 2-PEHTENE ,3,4,4-TR I riETHYL-

n m1B Pr<; 55WW. 2IN 1S21FIT 973

C8. H16 2-F'ENTEHE, 2 ,4 ,4-TRIMETHYL-

n m} iB PK 55RANK 3IN 1815FIT 978 •

M-'E 4n 50 60 70 80 90 lUU 110

. I I- b I- 0 0

LIBRARY SEARCH DATA: EPAUOA1719 ft 8&4 BASE M./E: 5708/19/84 3: £17:08 + 27:28 CALI: EPAUOA1719 « 1 RIC: 33215.SAMPLE; 77113-13CONDS.;ENHANCED (S 15B 2N 0T>

1088 1 r

SAMPLE

C8.H18 ' PENTANE,2,2,4-TRIMETHYL-

M W^ } \B PK 57RANK 1IN 2074FIT 987 •

1 i , I , I_______J____________________________^J;8.H18 _ - BJTANE,2,2,3,3-TETRAMETHYL-

M HT1?^ 1E; PK 57RANK 2I N 2687FIT 984 •

C8.H18 HErtAHE,2/2-OIMETHYL-10F;B 1 r

M NT H4B PK 57RW, 3IN 2084FIT 383 •

fl/E 4£t 58 be 7y 80 90 100

\ [

. ?; ;. i:. I. 0 0

LIBRARY SEARCH08/19/84 3:67:65 + 28:4£SAMPLE: 77113-13COHDS.:ENHANCED (S 15B 2H 0T>

DATA; EFAWA1719 tt 842CALI: EPWOA1719 # 1

BASE 1'1/E: 56RIC: 39231.

58 ee 78 8L1 98 1UO 119 126

1 . 0 0

SCANS 1 TO 2880DATA; EPABN1369 #1CALI; EPABN1369 #1/•1S/84 15:01:00 j

MPLE: 77113-13 ' ' 1 0NDS.: 'NGEi G 1,2808 LABEL: N 2, 2.0 QUAN: A 2, 3.0 J 0 BASE: U 20,

(S

5007:55

1800

15!50150023; 451

2000

31:40256839:35

NO NAi^ . . . . . . . . .47 2.4-DINITROPHENOL48 4-NITROPHENOL49 2,4-DINITROTOLUENE .50 FLUORENE51 4-CHLOROPHENYL PHENYL ETHER52 DIE1HYL PHTHALATE53 4,6-DINITRO-2-METHYLPHENOL54 N-NITROSODIPHENYLAMIN&55 1,2-DIPHENYLHYDRAZINE56 4-BROMOPHENYL PHENYL ETHER57 HEXACHLOROBENZENE58 PENTACHLOROPHENOL5'? PHENANTHRENE60 ANTHRACENE61 DI-M-BUTYL PHTHALATE62 FLUORANTHENE63 HSL 2.4,5-TRICHLOROPHENOL64 HSL 2 -NITROANILINE65 HSL 3-NITROANILINE66 HSL DIBENZOFURAN67 HSL 4-NITROANILINE68 BENZIDINE69 PYRENF70 BENZYL BUTYL PHTHALAT&71 BENZO(A>ANTHRACENE72 3,3 ' -DICHLOROBENZIDINF73 CHRYSENE74 BIS<2-ETHYLHEXYL> PHTHALATE75 DI-N-OCTYL PHTHALATE76 BENZO(B)FLUORANTHENE.77..,- .. BENZO<K.)FLUORANTHENE .. _ L :--;^—^-.--^- .^-.-::^-;."78'- B E N Z O < A ) P Y R E N E . : . . .. ..- . _ . . .-:7•? I N D E N O C I - 2 . 3-CDlPYRENe . . - - . - .80 DIBENZO<A,H1ANTHRACENF81 BENZCKGHDPERYLENE

NO M/E SCAN TIME REF RRT MFTH AREA(HGHT) AMOUNT 7.TOT

NO M/E SCAN TIME REF RRT METH AREA(HOHT) AMOUNT XTOT1 152 700 11 03 1 1 000 A BB 23464. 40.000 UG/ML 16.432 136 942 14 5S 2 1.000 A BB 59358. 40.000 UG/ML 16.433 164 12BO 20 16 3 1.000 A BB 37147. 40.000 UG/ML 16.434 1B8 1559 24 41 4 1.000 A BB 64255. 40.000 UG/ML 16.435 240 2065 32 42 5 1.000 A BB 24S12. 40.000 UG/ML 16.436 264 2320 36 44 6 1.000 A BB 38429. 40.000 UO/ML 16.437 NOT FOUND8 NOT FOUND9 NOT FOUND

10 NOT POUND11 NOT FOUND12 NOT FOUND ^_____ —————V3———74——Sga———3-31———1-—6-34-7——A-B&-———————S^3r.—————e-43T~UG7ML0. 1814 NOT FOUND '^15 .MOT FOUND16 NOT FOUND ,17 NOT FOUND _18 NOT FOUND _19 NOT FOUND °20 NOT FOUND 021 NOT FOUND23 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 NOT FOUND29 NOT FOUND30 NOT FOUND31 NOT FOUND

.32 NOT FOUND_.33;.. NOT FOUND

34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47. NOT FOUND48 NOT FOUND49 NOT FOUND50 NOT FOUND51 NOT FOUND52 NOT FOUND53 NOT FOUND54 NOT FOUND55 NOT FOUND56 NOT FOUND [.

\

NO5758M—606162-636465666768

707173737475767778798081

M/E'NOTNOT

NOTNOT«^u«^NOTNOTNOTNOTNOTNOT

NOTNOTNOTNOT149NOTNOTNOTNOTNOTNOTNOT

SCANFOUNDFOUND

FOUNDFOUND

—1793FOUNDFOUNDFOUNDFOUNDFOUNDFOUND

FOUNDFOUNDFOUNDFOUND2106

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

TIME

SB: Sg -

33:21

RE^

—V~

5

RRT

TTTiPT-

1. 020

METH

A UU——

A BB

AREA(i!-3HT)

6ifi>3.

1586.

AMOUNT

0.583 UG/ML

2.484 UG/ML

7.TOT

~0~34

1. 02

DUAL MASS SPECTRUM DATA; EPABH1369 'H222 BASE M/E: 45/ 4509/18/84 15:01:06 + 3:31 CALI; EPABH1369 »1 RIC; 2183./ 4599.SAMPLE! 77113-13CONDS.:ENHANCED (S 15B 2H 0T)

108.0-1 r 1632.

58.0-

M/E 56 100 150 283 250

||j|l ' i"i l j| ' j]" l" l""" l"""" l l""" l" l"""ll

50.0-

100.0-' L 1632.: ; 0 0 1 .? 1 7

DUAL MASS SPECTRUM09/18/'84 15!61:08 + 24:44SAMPLE; 77113-13COHDS.;ENHANCED <S 158 2N 6T)

DATA: EPABN1369 it 1562 BASE M/-E: 178/ 188CALI: EPABN1363 Itl RIC: 243. / 5815.

0 0 1 :' -1 8

DUAL MASS SPECTRUM09/18-'84 15:01:60 + 28:22SAMPLE; 77113-13CONDS.;ENHANCED <S 15B 2N 6T)

DATA: EPABN1369 #1792 BASE M/E: 202/ 202CALI: EPABN13G9 111 RIC; 277./ 767.

100 150J_L.

0 0 1 ° 1 ^

DUAL MASS SPECTRUM09./18/84 15:61:00 + 29:91SAMPLE: 77113-13CONOS.:ENHANCED <S 15B 2N 8T>

DATft! EPft3Hl369 #1833 BASE M/'E: 202/' 282CftLI: EPABN1369 iti RIC; 157./• 521.

_l__L158

i .1 i

0 0 1

DUAL MASS SPECTRUM09/18/84 15;61;00 + 33;21SAMPLE: 77113-13CONDS.:ENHANCED <S 15B 2N 0T>

DATA: EPABH1369 #2106CALI; EPABN1369 #1

BASE M/E: 149/ 149RIC: 2283./ 2931.

0 0

LIBRARY SEARCH09/-18/-84 15:01:00 + 37:52SAMPLE; 77113-13CONDS.!ENHANCED (S 15B 2N 0T>

DATA: EPABN1369 S2392CALI: EPABN13G9 f t ' 1

BASE r'l./E; 269RIC: 7111.

1421-1

SAMPLE

C12.H10 .U.N2

H HT1!^;B PK 198RANK 1IH 12569F I T 655

9H-PYRI DO[3.. 4-B 31NDOL-7-OL.1-11

::14.H21.C

11 NT^^B PK 2i39RANK 2IN 15552FIT G45

C7.H5.U.C,.1 mB PK 195RhNK 3It-1 14124FIT 635

t'l/E

L3

59

i

,11 , l l

BENZ&

. 11

BENZEt

"1

C, D I -TERT-BUTYLCHLCiRO-

C, 1,3,5-TRICHLuRO-2-riETH

1 i l l

10U 15t3

iL-.

: • :

4-

'.

J-i,—200

1

iL-

1

! . , , . [

250, 306

Environfnent&l ProlAclkP.O.Box8!3, Atoun

Lab Sample ID No:

on Agency.Kjria. Virgini

'.{•^^7^

CLP Sample Manage men* Office.223)3 703/557-2490

Organics Ana)(Pa

-T^s-hmn^ -/i^

i f - , - • .

. . Volatile C

Concentration: /Cow)

. . . . . . . . . : . .Q.I

Percent Moisture (Decan

ysisGgel)

Cas

QC

Cor

Oat

ompol

MediL<^S

^

^

tea):;

)ata Sheer- - -"

a Nn-

RapnrtNn . . iJ .S>

itrar-tNn- W

Linds ;

Jm (Circle One)

/Q/9^^1

pH

0a

-

Sample Number

/^^

^9

1- fc7SO^^........

0;'

•0

p

CASNumber

74-87-374-B3-975-01 -475-00-375-09-2-67-64-175-15-Q7.5,35-4-..75-34-3156-60-567-66-3107-06-278-33-371.55-656-23-5108-05-475-27-4

ChloromethaneBromomeihaneVinyl Chloride 1

ChloroethanaMethylena Chloride :Acetone-CarbonDisuUide--•- - • - • - • <1 , I-Dichforoethene1. 1-Dichloroethane •Trans-1. 2-Dichloroelhene " -Chloroform ;1.2-Dichloroethane :

2-6ulanone1 , 1 . 1-TrichlocoethaneCarbon TetrachlorideVinyl AcetateBromodichloromethane

ug/lotw/(Circle-01

^^• ^4' W

SLU't,

•^

ft^...-1.-3. b

:.l

; !•&.

^^

- 19-,

^^S^^-Sl

lAu^1^

Kg.

u,

A;

/

=

CASNumber

79-34.578-87-510061-02-6:79-01 -61124.48.1r79-00-5 -31-43-210061-01-5-110-75-8.75-25-2591-78-6 .,.108-10-1127-18-4

108-88-3108-90-7100-41-4

100-42-5

1.1.2. 2-TeirachloroeIhane1. 2-DichloropropaneTrans-1, 3-DichloropropeneTrichloroetheneDibromochtoromethanelTl^-2-TrichlQroeihaneBeriene- - - . . - • -.--•-

cis-1. 3-Oichloropropene—2-ChloroeihYlvinylelher 'Bromoform

2-Henanone4-MB!hy|-3-Pontano.,^

TetrachloroeiheneTolueneChlorobenieneElhytbenzeneSlyreneTotal Xylenes -

ug/1 orufl^(CircleTO

3-

^

1^•»aIS

.- l^• ••-.•(p4

" fa i,^

ft^'6^^-

i$L

^,C1

/A... .J.^

1-al'>

KB/ne)

t

rt

'

?•

>

-•^^

)

--

L

D«t» Rtportinc Qualifiers

Fof raporiiofl resulti to EPA. V^e (o<low<r>o rasvlis quxliliers afe uted

Addilional (lags or fooinoiftiflKOCining recullfTe encouragad However, (he

Oflltnmon of each flag rtiust fae axolic't

H ir»« rexull r J v«lu« gra«(«r Trvan or •qua! to Tr%«

do(»Ct<on lirrnl. rooort Ihfl vlue, ;

(ndicaiec compound was «nalvi«d for bui not o«t«ct«d

flvpOfl tha minimum d«l»C1ton limit for lh» Mmpte inlh

th« u <« g.. 10U) bJfcod on nflce«&arv conceniranon/

dilution •ctions. |Thi» IB nol n»ca«—rilvthe iritKunwn

d«l6ctt0i limit .) The (ootnole fhould raad U-

Cornpgurtd w«t «riJilyi«d lor but not dflt«ci«d Tt-K

number r thfl minimum •riBirroi» o«tecnon I'mn <ot

me sample

Ttiis flag .ipolxs 10 pcsitCide (Mramalert wtietB ihe

td«nr1ication hai b«n confirfn^d bv GC/MS Siniil<

lnd)c«l«« •

whamlir

i ••(imafd vlufl Th»t fl«g j| u««d •KrMf

>Bling « co<*c»ntranon <0t lflnt«tiv«ly

Should be confirmed by GC/MS

This (lag <& uwd wtxin th< enalvie is found in me blank

•& wflll as • lamptc. t1 <r»d«CB;»» poisiblc/pfobable

bl<oh coriiaminaiio" •r>d warnt iho dan ut«! 10 latie

•ppropnalC •Cl-O"

Olher soecitic 11«g» •"d fooinoiai •"*V b< f<iuir»d 10

pfQp«f(Y dfldnc ttt r<tul1t M Li»*d, t^flY mull tx lul ly

d«scnb«d •nd tucfi detcuption «n«ch«d to tr»fl dar

Environmental ProfctionAgancv, CLP Stmpit Managanwnt Oftic*.P. 0 Box 81 a. Al«un4ri«. Virginr 22313 703/557-2490

Sample Number

^^c5°|Organics Analysis Data Sheet

(Page 2)


Concentration: (Gw^ MedJUJn (Circle One)

Date Extracted/Prepared: __,_&t^2

Dale Analyzed: ^^^V^M

Cone/Oil Factor: "S^—î.Â.'Ô^ O^X

CASNumber

62-75-9

108-95-2

62-53-3

111-44-4

95-57-8

541-73-1

106-46-7

100-51.6-

95-50-1

95-48-7

39638-32-9

106-44-5

621-64-7

67-72-1

98-95-3

78-59-1

88-75-5

105-67-9

65-85-0

1 1 1 - 9 1 - 1

120-83-2

120-82.1

91-20-3

106-47-8

87.68-3

59-50-7

91-57-6

77-47-4

88-06-2

95-95-4

91-58-7

88-74-4

1 3 1 - 1 1 - 3

208-96.8

N-Nncosodtmethylamine

Phenol

Aniline

bis(-2.Chloroethyi)Ether

2-Chlorophenol '•

1, 3-Dichlorobenrene

1, 4-Dichlorobenzene

Benzyl Alcohol '""' •-'•""""

1 , 2-Drchlofobenzene

2-Methylphenol

bis(2-ch)oroisopropyllEther

4-Meihylphenol

N-Nitroso-Di-n-Propylaminie"

Hexachloroethane ~ •'

Nitrobenzene

Isophorone

2-Nitrophenol

2, 4-Ormelhyfphenol

Benzoic Acid

bis(-2-Chloroethoxy)Melhane

2. 4-Dichlorophenol

1. 2. 4-Trichlor-obenzene

Naphthalene •

4-Chloroanitine i

Hexachlorobuladiene

4-Chloro-3-Meihyiphenol '.

2-Meihyfnaphihalene

Hexachlorocyclopentadiene;

2. 4, 6-Trichlorophenol '.

2. 4, 5-Tfichlorophenol :

2-Ch)oronaphlhalene

2-Nitroaniline

Dimethyl Phlhalale

Acenaphthyfene

ug

J

4••«.ti.L

»,<,

V.\,

\.viLL1L^

^L

LT

III.I

L

t.

1L

{

/lordg/(Circie-Or

rl^L1^

-11^-IITO

-IS^

nyo1(TO-Wiro^FD"UTti-»roh(ro-nn)iro16^-IGT)1^

^Krer>-)SD

1TO-|0^-1TOiro•1TO

'7W-1(n>l[n6\)160^C%0HffV'550

\~\^^

K^w)

^

^

; CASNumb«r

83-32-9

51-28-5

100-02-7

32-64-9

121 -14 -2

606-20-2

84-66-2

7005-72-3

86-73-7

100-01-6

534-52-1

86-30-6

101-55-3

'18-74-1

87-86-5

85-01-8

120-12-7

84-74-2

206-44-0

92.87-5

129-00-0

85-68-7

91-94-1

56-55-3

1 1 7 - 8 1 - 7

218-01-9

117-84-0

205-99-2

207-08-9

50.32-8

193-39-5

53-70-3

191-24-2

Acenaphthene

2.4-Dinitrophen6l

4-Nnrophenol

Dibeniofuran

2. 4-Dinitrotoluene

2, 6-Dinitrotoluene

Oiethvlphthalate

4-Chloropnenyl-phenYle(her

^luorane.

4-Nitroaniline :

4. 6-Dinitro-Z-Methylphenol

N-Nnrosodiphenvlamine ( 1 )

4-BromophenYl-phenylether

Hexach lorobenzene

Pentachlorophenol

Phenanlhrene

Anthracene

Di-n-ButYlpMhalare'

Fluoranthene

Benzidine

Pyrene

Butyl be nrylphihalate

3. 3'-Dichlocoben2idine

Ben2o{a lAnthracene

bis(2-E>hylhexYl)Phthalale

Chrysene

Di-n-Octyl Phthalate

Ben20(b)Fluofanlhene

Ben20<k)Fluoranthene

8enzo(atPyfene

(ndenoO, 2. 3-cd|Pyrene

Dibenria, h)Anihracene

Benro<g. h, i)Perylene

"

^V

I

L

^T\

Lij

?

l-I.L

>.

II

L

^\\

1.

^

^^

L

I

1.

I^

L

g/1 or^g(CircieC

-|6t?»J\^

>^'1ÎSt)Ib^•)eo .ISb•^ •^W».?7P1601ft>16D

&SCT»-16^")6\>tCT)•-iro^^ '16t>-1^>

^^?,,nTOoÔ-^-(p?U

OroITO>1^>-ISTi'CD"ro

iy-)\roS

/Kg;me

(

\

t

En».rootT>«nnlProtectw<Afl»ncY. CLPS«n(>l«M*(ug«>n«nlOflic«.P_0_B»818. AlwindfHi, Virginii 22313 703/SS7-2490


Sample Number

T'^?q


CASNumbar

l

?

1

-1

K

K

7

B

0

in

1 1

if

ia , - - •, ••M. • •-•- :-IS • ' "

Ifi

17

1R

19

70

?1.

2?

71

?a

2S

26

77

2R

29

.-in

Compound Nona

(Lv^^sc^n^- '•LA^A'k>v\S>\J^t^-—

V^v4 iAJ»^ -i

vL^LLrt»-»- </->-,

.

• • • - - ^ .- .;• ... .--.--^

Fractioo

. i/orv^.

(<\6^^

RT or ScanNumber

;W

^o<r

\n\\<»\^^

•,i • •"

- ^

EitimatodConcontratjaa

(ug/lo^Cg/kg^

^0%0

•bS,(WoH Hrr)

1/1 0

~Z

. IN

<xa =

in®?j-

VtV

C.

—1

G)G

) o

tM C

Mr^

r^

-rt33 :

oo

o

<r CTQ

- Q-

<rL

U U

J

0

<s

/-,

-

•T

^^t-77^^^^

(' -\^^; ^^yp

Qi^ip

p^

f ^>

<

( S 0

''^^^^

syv^3^^-

-O

W)

§

0^r..

o"—

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§A

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»-i•»r —r^^•1

\- o

01 .. ..

3UANTITATION -REPORT FILE: EPAVOA1720

3ATA: EPAVOA172C'. -I3B/19/B4 4:••.)?: 0C-SAMPLE: 7 7 1 1 — - TSUBMITTED BY -?i- ANALYST: RJ1.)

AMOUNT=AREA (-iGH'? : « REF. AMNT/(REF. AREA(HGHT)» RESP. FACT)^EBP. FAC. F--'OM AVERAGE OF WHOLE . RL

NAME«««

HSLHSL

HSLHSLHSL

HSLHSLHSLHSL

Bn-OMOCHLORMETHANE (INTERAL. STANDARD)'P-OIFL'JOROBENZENE (INTERNAL STANDARD)D;CHLOR;OBENZENE-D5 (INTERNAL STANDARD)CHLOROfiETHANEB-^OMOMETHANEVINYL CHLORIDECHL ORO^THANEMeTHYi.-ENE CHLORIDEA':;?(OLE=NACKVLONITRILE1 --OICHLOROETHYLENE1 i-OTCHLOROETHANETi;'AN&-_. a-DICHLOROETHYLENEC-LOROrORM1 —DICHLOROETHANE1 .. --"'RICHLOROETHANEA::S:TONE:CARBON'DISULFIDECARBON TETRACHLORIDEB-tOMOD ICHLOROMETHANE1 r-a^CHLOROPROPANETSAMS-4- 3-DICHLOROPROPYLENETSICH'-^ROETHYLENEB^NZEN^D JTBROMOC HLOROMETHANE1 L. ^-"RICHLOROETHANEC:=-_.;-DICHLOROPROPYLENE2-C:-iLOF:OETHYL VINYL ETHERBSOMOF'^RMM£THYL. ETHYL KETONEV:NYL ACETATEM'ET-iyL ISOBUTYL KETONE1 r-^'ICHLOROETHANE-DA (SURROGATE)B€N2ENE:-D6 (SURROGATE)D ZBROMCTETRAFLUOROETHANE (SURROGATE)BIS i PEF:FLUOROISOPROPYL) KETONE ( SURROGATE)F-UOROEENZENE (SURROGATE)T-£";RACHLOROETHYLENE1 _, 1. 1-TETRACHLOROETHANET::-LL»ENEC-LOR05ENZENEE'^YLBENZENE2—EXANONES'YRENS:0-yYLElvEM-yVLS'YE

NO47484950

N01234 -

67B9

10111213141516171B

NAM1

M/E130114117

NOTNOT84

NOTNOTNOTNOTNOTNOTNOT

9759

NOT

M-SRD-5TOi-UP-SR

SC-w33;fc-^ar"

FOU. CFOUNC

2S-FOUNCFOU-'JCFOU-MCFOUM!:FOUMCFOUNDFOUNC

5-..C3-?^

FOU'-'J!:'

OMOBENZ'ETHYLBEIENE-D8OMOFLUOI

'~II"1E^:09£3:333'?: 17

-•:49

-,7:38-v:23

DTRINZEN(SURROBE

REF.123

1

11

FH.E 1ROCNZE

1.1.1.

0.

1.0.

;ORIDi;SURR(;ATE);NE (!

RRT000

000000

745

340790

E (SURRO3GATE)

3URROGAT

METHA BBA BBA BB

A BB

A BBA BB

GATE)

E)

AREA(HGK135492.

1&23B7.83833.

45154.

167183.9474.

r) AMOUNT50. 000 UG/L50. 000 UC/L50.000 UG/LI. aa? \\^/\

J 1 1 7^ L' 1^4—

35. B00 UG/L

100. 76& UG/L131.106 UG/L

•/.TOT1. 521. 521. 52

—e-ts-"

1. 09 ; ,^v-

—•

0

0

3. 074. 00

NO19202122232425262728293031323334353637

39404142

44454647484950

M/ENOTNOTNOTNOTNOT-78-NOTNOTNOTNOTNOT

72NOT

436584

NOTNOTNOT

NOT91

NOTNOT

NOTNOTNOTNOTNOT9895

SCAN

FOLMCFOU.-MCFOUNCFOUNCFOUNC

——-A^-.FOUNCFOUNCFOUMCFOUMCFOUMt

4^'FOUMC

7:;;43;

6--FOUMCFOUMCFOU-J;

FOU--H:8;-

FOUM:FOU-JC

FOU-JCFOU";:FOU^CFOU'lCFOU'^- 8-fi07^

•'ZME

-H'. 13 -

IS: S7

S4: 46LS':59£-:05

2E.: 03

S-'-.Si' "2£:;-22:

REF

2

222

3

"33

RRT

0. DDO

0. 66S

1. 0370. 6700. 883

0. 958

0. 9511. 208

METH

—fit-SB——

A BB

A BBA BBA BB

A BB

A BBA BB

AREA(HGHT)

——Brew:—-

10984.

1459700.13904S.285592.

23334.

278347.157623.

AMOUNT

—1 S6. 7S6'—ULi/l-

121.S7S UG/L

2269. 420 UG/L89. 835 UG/L91. 276 UG/L

[S. 602 UG/L

8.195 UG/L

117. 231 UG/L96.594 UG/L

7.TOT

57827

--/6t

3. 71

69. 1B2. 74 c\i

2. 78—

0

-0. 17 Qt 0

y^~—e. 25

3. 572. 94

DUAL MASS SPECTRUM DATA: EPAUOA1720 #83 BASE M/-E! 50/ 4408/19/84 4:83!e8 + 2:50 CALl! EPAWA1728 ftl RIC; 737. / 4047.SAMPLE; 77113-14CONDS.;ENHANCED (S 15B 2N 0T)

100.6-1 r 2536.

58.0-

\—,—,—,———,—,——————,————l—,—i———————————UM/E 35 49 45 50

SO,Q- , , . . . . . . . . . . . . . . 1 . . : . . . . . . . . . . . . .

100.0J ''• Q 0 1 .' ;' 0 l- 2536.

DUAL MASS SPECTRUM DATA; EPAUOA1728 #143 BASE H/Ei 45/ 4499/19/W 4S08S08 + 4:53 CftLI; EPAUOfll726 ftl RIC: 4647.•/ 9919.SAMPLE:!77113-14CONDS.:ENHANCED (S 15B 2N 0T)

109.0-1 (- 3048.

50.0-

————l—————F^-.——[J———^—————,—————^—————i—————^—————,————L^J————,—————^——I I i I I

M/E 40 50 60 70 80 90

"w»,a-l

100.0-1 0 0 1 ; ? 'I 3048-

DUAL MASS SPECTRUM08/19-'84 4; 08; 00 + 9 ; 48SAMPLE; 77113-14CONOS.:ENHANCED <S 15B 2N 0T>

DATA; EPAUOA1729 #287CALI; EPAUOA1729 «1

BASE fl/E; 49/ 49RIC; 38271,/ 44479.

40 60 70 80

0 0 1

: . \ : \ li

DUAL MASS SPECTRUM ! ; DATA:- EPAUOA1720 #725 BASE M/E: 43/ 43; 98/19^84 4!@8;80 + 24:46 : CALIs EPAUOA1720 #1 RICi 686079./ 736559.

SAMPLE: 77113-14 ; ;

CONDS.;' ' •ENHANCED <S 15B 2N 0T) ' i ;

180.0-1 : ; ! r 232966.

59.8- : ; ; !:

M/E 50 108 |; 150 208

TO Q-i S . I . . . . . i. : . . ' .'.. . . . . .

•• ; i • •

100.0-' ; ; 0 0 1 ^ 33 L 232960.

DUAL MASS SPECTRUM DATA; EPAUOA1728 #516 BASE M/E: 97/ 97QQ/l9''Q4 4;0.°;8a + 17!.38 CALl! EPAUOA1720 #1 RIC; 1818S7,/ 18S799,

, ., SAMPLEl,77U3-.14 „. , „ . . . . , , . , . . . . , ; . , , . , .CONDS.;' • : i • • .ENHANCED <S'15B 2H 9T)

100.e-| [- 31680.

50.0-

l 1 " . • • '••|——---N-1———————r^————M^—.—————Ll^.11/E 40 50 68 70 80^ 90 100 110 120

— — — j p , l . . , , | i . , ' — — — ' i l n r - — — — — — — — ' • 1: i ; : . 1 ——————t- iMi i , '———————^Lr

^ft^n-1

100.8-' | • 0 0 1 ' 3 'A 31680.

DUAL MASS SPECTRUM08/19/34 4!08;09 + 10:23SAMPLE: 77113-14CONDS.;ENHANCED <S 15B 2N 0T)

DATA: EPAUOA1720 #304 BASE M/E; 43/ 43CALI; EPAUOA1720 #1 RIC; G553.-' 11583.

100

l i

DUAL MASS SPECTRUM3S/-19/S4 4; 68; 38 + 21; 13SAMPLE: 77113-14CONDS.:ENHANCED <S 15B 2N 0T)

DATA: EPAUOA1720 #621CALI; EPAWA1720 #1

BASE ri/'E; 78.'' 78RIC: 30847./ 5S623.

40 60 70

0 0 •!

DATA: EPAUOA1720 #467 BASE M/'E: 65/ 65CALl! EPAUDA1728 #1 RIC; 62911./ 69887,

r 21760.

DUAL MASS SPECTRUM08-/19''S4 4:98; 08 + 15; 57SAMPLE; 77113-14CONDS.;ENHANCED <S 15B 2H 0T>

-i————i————i————|————r

70 ; 86 9068 193

l- 21760.

c-n

CDC

O

CD

en

CD

DUAL mSS SPECTRUM : DATA; EPAUOA1720 #821 BASE M/'E; 91/ 9188/'19^84 4;08;e9 + 2S;63 CALIs EPAUOA1720 #1 RICi 3QQ7,/ 32543.SAMPLE: 77113-14 :CONDS.iENHANCED (S 15B 2N 0T) :

100.8-1 r 4604.

50.0- : -

—r^i—i j1 i I11!—l—i—I—1 'I" i—[—1—1—i—|—r—i—i—|—i—)—i—\—i—|—i—|—i—r~i—1—"^

n/E 50 190 150 200' i i l i i i i i 1 ^ | l l l | ^ l l l ' ' l l l l ^ l l l ' l l | l ' ' ' " i i ' r i i i ' ' 1 1 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ic;n,0 -' ! . . . . -

100.0- ! 0 0 1 3 ' 4084-

DUAL MASS SPECTRUM , DATA; EPAUOA1720 #768 BASE M/E: 44/ 4408-/19/'84 4iB8!00 + 26! 14 : !. ' CALIs EPWOA1729 #1 RIC; 1425. / 17599.SAMPLE: 77113-14 ; .CONDS.; !

ENHANCED <S 15B 2N 0T) . !

100.0-]1 ; I . r 3166.

50.8-

II/'E 59 160 : 150 200

. ' )hn|| l|Him1 l|il||'ii|' ^ ' i i ' j l • i \ < 1 • 1 • ' ' 1 ' ' ' ' ' l ' ' • 1 ' 1 1

w^a -1 - . . . . . .. • . ; • • • • •

i :

100.0-1 ; ' 0 0 1 ' 4 0 L- 3160.

. i. I7 ( • i- 0 0

LIBRARY SEARCH DATA; EPAUOA1720 ft 763 BASE tl/E: 5508/-19/84 4:68:60 + 26:84 CALI; EPAUOA1720 # 1 RIC: 36931.SAMPLE; 77113-14CONDS.:ENHANCED <S 15B 2N 9T)

1005 i

SAMPLE

• I i l l I . .———————I. I I I . . ,————,,J |————————^———————————————L———————————^LC8.H16 • 2-PENTENE/2,4-4-TRIHETHYL-

ri NT 1 1 2 }B PK 55RANK 1IN 1815FIT 997 • :

n',i, 1 . , . . . , , i i . i , , . ,,,.i__________L^___JLJ38.H16 2-PENTENE-2-3-4-TRiriETHYL-

1R85 i rt1 W 1 1 2B PK 55RANK 2 . . . • •IN 1819FIT 9S6 • • : .

____________________________________C8.H16 2-PEHTENE/3<4,4-TRir€THYL- :

1005 i i • ; rt1 MT 1 1 2B P K : 97 . . . . . . .. ! . . . . . . . . . . • • • • •R A N K : 3 i ! i ;

F^jji- h ' ! : ? 1

-Lu——^uJ———1^——^————J-^——J^M/'E 40 \ 50 60 :70 ; : 80 90 1@0 110

• 6 ' : I. 0 0

LIBRARY SEARCH ' DATA; EPAIX)A1720 « 8@5 BASE N.-'E: 5708^19/'84 4:08:00 + 27:30 CALI; EPAWA1720 # I RIC; 58175.SAMPLE; 77113-14CONDS.;ENHANCED <S 15B 2N 0T> ;

1688 i ' ; :

SAMPLE ,

i 1111,1,,————J-L—————————————————^C8.H18 BUTANE, 2,2/3- 3-TETRAMETWL-

M WT1?^ 1B PK' 57 • :RANK 1 .IN 2087FIT 989 • : •

1 i , I ' . i———————M-^————————————————————————^;8.H18 PENTANE-2-2,4-TRINETHYL-

N MT1?^ "]B PK 57RAHK 2 . . ^ .IN 2674 : • . ;FIT ;983 • ; : :

I '

C8.H18 ; HEXAHE/2,2-DIMETHYL- : :

M^4] ! I : : [B PK: 57 . . , . . . . . . . . . . . . . ..! . . .-..-... . . . . . . . .RANK 3 ! , ! :IN 2084 ! . :

FIT 987 • ; . •

M/E 49 50 60 79 80 96 100

!- 0 0

SCANS 1 TO 2808RIC DATA: EPABM1370 #1CALI; EPABN1370 #169/18/84 15;51;08

SAMPLE; 77113-14 ABN 1/-10CONDS.:RANGE; G 1/2&00 LABEL; N 1, 2.0 QUAN; A 2^ 3.0 J 0: BASE: U 20- 3

lA

M^

500,7:55

\'

!

\

J100015:50

>

;

^J^; 1500

23:4

1

^

1

J^

1<

A

^"^w^

200031:46

^ • 1

„

UJ

3

^ .

^^^^,——i——(——i——i——i

250039:35

OUANTITATION REPORT FILE: EPABN1370

DATA: EPABN1370. TI09/18/84 13:51:00SAMPLE: 77113-14 ABNSUBMITTED By:

1/10ANALYST:

AMOUNT-AREA(HOHT) «REF. AMNT/(REI-. AREA(HGHT)* RESP. FACT)RESP. FAC. FROM AVERAGE OF WHOLE . RL

NO NAME

20 HSL21 HSL

37 HSL38 HSL39 HSL40 HSL41 HSL

-D-4"l;4-DrCHLORaBENZENE ' "D-8 NAPHTHALENED-8 ACENAPTHENED-10 PHENANTHRENED-12 CHRYSENFD-12 PERYLENF2-FLUOROPHENOL (SURROGATE)D-5 PHENOL (SURROOATE)D-5 NITROBENZENE (SURROGATE)2-FLUOROBIPHENYL (SURROGATE)2.4,6-TRIBROMOPHENOL < SURROGATE.)D-14 TERPHENYL (SURROGATE)N-NITROSODIMETHYLAMINE2-CHLOROPHENOLPHENOLBIS (2-CHLOROETHYL) ETHER1.3-DICHLOROBENZENE1.4-DICHLOROBENZENE1,2-DICHLOROBENZENEANILINfcBENZYL ALCOHOLSIS(a-CHLOROISOPROPYL)ETHERHEXACHLOROETHAME - . . -H-NITROSODI PROP YLAMINFNITROBENZENEISOPHQRONE2-NITROPHENOL2,4-DIMETHYLPHENOLBIS(2-CHLOROETHOXY)METHANE2,4-DICHLOROPHENQL1< 2.4-TRICHLOROBENZENENAPHTHALENEHEXACHLOROBUTADIENfcP-CHLORO-M-CRESOL

HEXACH1OROCYCLOPENTADIENE2,4,6-TRICHI. OROPHENOL2-METHYLPHENOL4-METHYLPHENOLBENZOI-C ACID4-CHLOROANILINE2-METHYLNAPHTHALENE2-CHLORONAPHTHALENEDIMETHYL PHTHALATEACENAPHTHYLENE2, 6-DINITROTOLU6.NEACENAPHTHENE

NO NAMF •47 2,4-DINITROPHENOL48 4 NITROPHEMOL49 2,4-DINITROTOLUENE50 FLUORENE51 4-CHLOROPHENYL PHENYL E1HER52 DIETHYL PHTHALATE53 4,6-DINITRO-2-METHYLPHENaL54 N-NITROSODIPHENYLAMINE.35 1,2-DIPHENYLHYDRAZINE

..56 - - 4-BR0110PHENYL PHENYL ETHFR"- "57 HEXACHLOROBENZENE58 PENrACHLOROPHENOL59 PHENANTHRENE60 ANTHRACENE61 DI-N-BUTYL PHTHALATE62 FLUORANTHENE63 HSL 2, 4, 5-TRICHLOROPIIENOL64 HSL 2-NITROANILINE63 HSL 3-NrTROANILINE66 HSL DIBENZOFURAN67 HSL 4-NITROANrLINE68 BENZIDINE69 PYRENE70 BENZYL BUTYL PHTHALATE71 BENZO(A)ANTHRACENE72 3,3'-DICHLOROBENZIDINE73 CHRYSENE . . . . - . . -74 BISC2-ETHYLHEXYL) FHTHALATE75 DI-N-OCTYL PHTHALATE76 BENZO(B)FLUORANTHENE77 . BENZO(K)FLUORANTHENE78 . .BENZO(A»PYRENE•79; • INbENO(1.2,3-CD>PYRENe'80 DrBENZO(A,H>ANTHRACEN£81 BENZO (GH I»PER YLE-NE

NO M/E SCAN TIKE REF RRT M&TH AREA(HGHT) AMOUNT 7.TOT

,N0 M/E SCAN . TIME REI- RRT KE.TH AREA<HCHT) AMOUNT . XTOTI 132 699 11 04 1 1.000 A BV 31080. 40.000 UG/ML 1-6. 022 136 939 14 52 2 1.000 A BV 7S560. 40.000 UG/ML 16 023 164. 1277 20 13 3 1.000 A BB 47012. 40.000 UG/ML 16.024 188 1337 24 39 4 1.000 A BV 73911. 40.000 UG/ML 16.023 240 2066 32 43 3 1 . 000 A BB 39317. 40. 000 UG/ML 16. 026 264 2322 36 46 6 1.000 A BB 117837. 40.000 UG/ML 16.027 NOT FOUND8 NOT FOUND9 NOT FOUND

10-WIT-FOUNT* •— —— •11 NOT FOUND -•12 NOT FOUND13 NOT FOUND. - . . .:14 "NOT FOUND VJJ

15 NOT FOUND .-• - . :16 NOT FOUND17 NOT FOUND -*8 t46——-?04—-1-1—06———1——1. 003——A-&B——•—~——S9S-.——————0. C3T UQ/ML——6-1-6-- Q19 NOT FOUND20 NOT FOUND °21 NOT FOUND22 NOT FOUND23 NOT FOUND24 NOT FOUND23 NOT FOUNDVtr——-BE;——U63 13: 4U 2 0. 919 A BB 416^————"——0-337 OS/ML -& -L3—27 NOT FOUND . • • . . , . . . - . . - - — — • -.28 NOT FOUND29 NOT FOUND30 NOT FOUND31—-NOT-TDUND - - ";

32 NOT-FOUND . - . • • • - • • -33 NOT FOUND34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND19 1?=' 9^9 —t-S—H-——•?——1 0?1——ft»fiB———————-6>OS^—— 1.270 UG/ML 051-^40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT.FOUND48 NOT.FOUND49 NOT FOUND50 NOT FOUND51 NOT FOUNDSa—-Wf T38'? 2 ? r 0 0 3 1.08S A BE 708. 0.075 UG/ML ~0~03—-53 NOT FOUND54——1-69——T4TS——2e" 23——4——0—709——A—Bfl————————&6-4-——————F^&^—LlC.^m n 1755 NOT FOUND56 NOT FOUND

N357585960

6263646366676869•TO-71.727374

767778798081

M/ENOTNOTNOTNOT

NOTNOTNOTNOTNOTNOTNOTNOT14<?

.NOTNOTNOT149

NOTNOTNOTNOTNOTNOT

SCANFOUNDFOUNDFOUNDFOUND

1703FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

—X987-FOUNDFOUNDFOUND

2105

FOUNDFOUNDFOUNDFOUNDFOUNDFOUND

TIME

-- - • •

-31.3.B

33:20

REF

5

RRT

I. 019

MFTH

. - - ,.

A»BB———

A VB

AREA(«GHT)

9002.531.

AMOUNT

0. 8Q<? \ia/w

—U. W^. UU/HL"

5.878 UG/ML

. XTOT

/2. 35-

DATA: EPABH1370 #701CALI; EPABN1370 ttl

BASE n/'E: 146/- 156RIC; 327. / 16695.

DUAL MASS SPECTRUMB9/-18/84 15;51;08 + 11:86SAMPLE: 77113-14 ABN 1/10CONDS.:ENHANCED <S 15B 2N 0T)

0 0 1

DUAL MASS SPECTRUM09/18/84 15:51;00 + 13:40SAMPLE; 77113-14 ABN 1/18CONDS.;ENHANCED <S 15B 2N 0T)

DATA; EPABN1370 #863CALI; EPABH1370 #1

BASE 1-1/E; 82/RIC: 165./

81 82

DUAL MASS SPECTRUM89/18/84 15:51:09 + 15;11SAMPLE: 77113-14 ABN 1/18CONDS.:ENHANCED <S 158 2N 0T)

DATA: EPABH1370 »959 BASE H/E: 41/ 122CALI; EPABN1370 #1 RIC: 42./ 366.

-r——\———r

120 130i- 1 -

60 70 80 90 100 110

i I '-

0 0 1 - 5 0

DUAL MASS SPECTRUM DATA: EPABN1370 #1389 BASE V\/i: 149/ 149I 69/18/'84:15:51;00 + 22:00 CALI; EPABN1370 #1 RICi 395./ 1205.I SAMPLE; 77113-14 ABN 1/10. CONOS.! ;;

ENHANCED:<S 15B 2N 0T) i100.0-| : ; ; j :. I r- 364.

50.04 '

t1/E '; 50 160

50.0- | '.

100.0-' 1- 304.; . 0 0 1 ° t-' 1

DUAL MASS SPLCTRUM i : DATA; EPABN1370 #1416 BASE M/-E; 169/ 4109/18^84 15!51;09 + 22:25 CALI; EPABN1370 #1 RIC: 510./ 1667.

! SAMPLE; 77113-14 ABN 1/-10COMDS.! I ;ENHANCED <S 15B 2N 8T) ;

1B0.0)-] I r 231.I : , : _

59.0^- ' ' . • !

' t ! . ! ! . ' :

1 , '

M/E 50 iee 150- - t 1 ^ I I -I • -I- I I I 1 I 1 • I I , 1 I I I 1 • I I -

50.0- I

100.0-^ i L 231.I I . ; • • • 0 0 1 ^ 5 2

DUAL MASS:SPECTRUM09/18/84 15:51:00 + 26:58SAMPLE; 77113-14 ABN 1/18CONDS.;ENHANCED <S 15B 2N 0T)

DATA: EPABN1370 )fl703CALI: EPABN1370 #1

BASE M/E: 59/ 43RIC; 888. / 56639.

150 256i I

! DUAL HA5S SPECTRUM ' DATA; EPABN1370 #1987 BASE M/E: 121/- 43i Q9/IQ/Q4 15;51;00 + 31:28 CALI: EPABN1370 #1 RIC; 829./ 7527.I SAMPLE; 77113-14 ABN 1./10; CONDS.;' ENHANCED <S 15B 2N 0T>

106.0-| ; [- 637.

50,8" . \ ' \ '.

[ | ; • ' .'

;1-L,—^———| r ' \—i—)—i—i—r^-^—S—|—\J-Y—r—|—I—i—i—y—\—\—I—i—i—i—i—r

n/E ! 50 100 : 150;—i 1 4 — 1 , 1 — 1 - i - ,4 . . -^ ' i T t . T T 4 T V T ^ T 1 '77T 1 t ' ' TT ' ' t ' ' 1 ' 1 i

50.0- ' ^

100.0-1 ' L 637.' , \ • • 0 0 1 ^.' 5 4

DUAL MASS SPECTRUM DATA: EPABN1370 #2105 BASE H/E: 149/ 14909/18/84;15;51;00 + 33:20 CALI: EPABN1370 #1 RIC: 11503./ 21119.SAMPLE; 77113-14 ABN 1/10CONDS.i :ENHANCED;<S 15B 2N 0T)

100.0-1 ' : r 3456.

I ' • ' ; ' : , ' ' ' "; ' '! I ; , ; .' i

1 ' ' , ' ' . ' ' . ! •'.': \

56.9- ' '. '^ . ;

M/E 59 100 1 0 200 250' ti ft |t ' jtt '^^ i , . , . . ^ , . 1 1 1 1 . 1 . i , , . i , 1 , 1 , 1 , , . ,

50.6 - !

100.0- \ ' ' . L 3456.^ . : i ; 0 0 1 " 3 5

•^

f

DUAL09/1SAMPCONDENHA

11 r-"

MASS8/84 1LE; 77S.i: •NCED <

1 :

,1 ,lll

' " I

SPEC75:51:113-1

5 15B

i

I I I

RU064

3 2

ll11

11

JI1i + 3

ABN

?N 8T

0

F

5:121/1

)

IIIilLT-J^-

r

0

4^4-

^}]\

\ i • \

: ; , :

1 1 1 ' 1

1. 1 1 1 1 1

DATA; EPABH1370 #2223 BASE M^E: 57/CALI; EPABN1370 »1 RIC: 10319./

' 1 ' | ' 1 ' 1 ' 1 ' 1 ' | ' 1 ' l i l200 250

i .1 » 1 i . l • 1 < 1 i 1 < 1 i 1 » 1 . 1.

| ;

5717599.

- IS

•

10

I. ^ 0 0

LIBRARY. SEARCH03/-18/84 15:51:00 + 27:18SAMPLE; 77113-14 ABN 1/18CONDS,^;' ... - .•,. .ENHANCED (S 15B 2H 0T)

DATA; EPABN1370 #1716 BASE M/-E; 43CALI; EPABH1370 tt 1 RIC; 68991.

1394 i

SAMPLE

C16.H32.02

11 NT125(1B PK 43RANK 1IN 1S616FIT 986

HEXADECANOICACIO

:18.H26.02

M m 1B PK 66RANK' 2IN: 9172FIT: 975 •

C9.H18.02: 1394 ^

t1 HT 158B PK 66RANK . 3IN '73S4FIT, 963 •

M/E

1 1 , 1

56

-L L

:

; !

,1

1

, , 1 1 , , 1

DECANOICACID

ll 1NONANOICACIO

1 1 1.

i

;

S———^

~i—'—'—"00 i|50.; 208 259

0 0

LIBRARY SEARCH ,B9/18/84 15;51 see + 29:19SAMPLE;; 77113-14 ABN 1/16CONDS.?. • . ;'. . i •

DftTA: :EPflBN1379 #1852CALI: -EPftBN1370 # 1

BASE M/E: 43RIC: 45867.

DECANOICftCID

NONAMOICACID

(56'

; " ' ' "1

• " ^ • 1 . 1 • ,.'—————————————.————————————-——————^————————————r-:iee 150 ! 288 250 ; 38i3 350 480 . 450 500

Environmental Proieciion Agency, CLP Sample Management OHice.P. 0. Box Bl 8. Alomndra, Virginr 2231.3.703/557-2490

Sample Number

^^36Organics Analysis Data Sheet

(Page1)

.^^•fs-n-^Laboratory Name: Case No:

QC Report No:

Contract No:

Lab Sample ID No:

Sample Matrix: ~-y)

nate~Sa-m-pleReceive-d:"-Z l-Z3-iS^_

rids

n (Circle One)

fl W •

^1 '.

Data Release Authorized By:

^ ;;y.o.la.tiJe Compounds

Concentration: ('tow) Medium (Circle One)•"•'' '-' '• " ::- r\c-—^— -Q"Date Extracted/Prepared: 0

Date Analyzed::——,0-^—1—1

Conc/0-iLEacloc- .-

Percent Moisture:

-PH.

Percent Moisture (Decanted):

CASNumber

74-87-3

74-83-9

75-OT-4

75-00-3

76-09-2

67-64-1

75-15-0' "

75-35-4

75-34-3

156-60-5

67-66-3

107-06-2

78-93-3

71-55-6

56-23-5

108-05-4

75-27-4

Chloromethane

BroiTio methane

Vinyl Chloride

Chldroathane

Melhytene Chloride

Acetone , - . . - . - . . -

Carbon Bisulfide

1;"1-OichT6roflthsne" ~ •-—

1 , 1 -Dichloroeihane

Trans-1. 2-Oichloroethene '

Chloroform

1. 2-Dichloroelhane " " ' •

2-Bmanone

1 . 1 . 1-Trichloroethane

Carbon Tetrachlonde

Vinyl Acetale

Bromodichloromeihane

. ufl/l of^Jla/(CircleTB'

• -H .i/'/

•:-#; / 4 s

. , p.,:.;;a-••-!^-.

., .5.., ; :•?• ^ 7

, .-. 7-. ^ ,- bS• : 7 -^—^• • -/- ^.

Kg<fs8,

<

/

A,

....

,

^

y

>

-.—

CASNumber

79-34-5

78.87.5

10061.02-6

79-01-6

124-48-1

79-00-5 .

71-43-2 • -

10061-OK-'

110-75-8

75-25-2

591-78-6

t08-10-l ,

127-18-4

(08.88-3

108-90-7

t00-41-4

100-42-5

-i——————————

1 . 1 .2 . 2-Tetrachloroethane

1, 2-Dichloropropane

Trans-1. 3-Dichloropropene

Trichloroeihene

Otbromochtoromelhane

1 , 1 , 2-Tnchloroethane,

•Bentene - • - • — : - - — • •- •;

cis^: 3-Dichloropropehe'" "

2-Chtoroelhvlvinytether

•Brornoform

2-HftKanone

4-Melhy! -2-Pentanonc

Telrachforoelhene

Toluene

Chlorobenzene

Elhylbenzene

Slyrene

Toial Xylenes

ug/lori^(Circlen

J, ^

?-?

- 7 ••. ? .-.•-2, !

• • • - ? " • ---^-;

-^" i' 'VL\f^^

^ry-^^-f?-?>

me}

{——

/ -

.f

/

'. D«u Reporting Qualffien

For reponin^ rexditt 10 EPA. th« following rflsuht OUJ

cfflfiniHon ol aach" tlag musi be txolicil p

<f<ers •re used

Vclu« tf the raiufi i« « v«lue graarr lh«n or equfll to the

(tBiwnon limn. repon the vlue

U IndiCJios cornpound wat •nalyiBti *&r hul "ol d<t»c«ad

Rflport the minimum d«t«ci<on hfnil (or ihe umple with

lh» U (a o . 10U)bJt«d on fi«CBtMrYCOOcentr«lK>r»/

dilution •c1ion« (This is not i-xcesfcirity me iniirum«nt

d«l«ctton limit .[The (ootr>ot« xhould r««d U-

Cowpound wt Tflyied (of but nol d«rct«d. Th«

riumtxr ic 1rr« minii ufri •naifvbia d«(«cii0fi I'mn (o*

ihe Mmple

•J l<^diCJl«& •n etiirm«d vlo«. The fl«g r u—d •ittf

when •«tim«t4ng • conc»nir»lKXi (or mni«li<Mlv

»d«niifi*d compoundi •vt^re • 1 : 1 f«ippn«« <« •*su»TVt»d

of when the man Bp»cir«( dar indicatfi« 11- rvi-.»"^-

C Thit <lag •[Kilies to p«stic*d« p«ram«rrs where the

identiftcation h«s t»en confirrrwi by GC/MS Sinflle

component pecrcioes^l 0 ng •'ul m ihfl final eKHaci

Shoutd be confirmed DY GC/'MS

B This 1\»g if uKd when ih« «nJilyie is found in the blank

•s well <i J Mmpiff h >nd»caies pos&ible/protiable

bl«nk coni«mination and wwrns the daU u&er 10 lake

•op«op*me •ci'on

OthT Olher specific (lag* «nd toolnolat may tK raqyired to

properlv dedne the retullt tl utftd. they mult be fully

oe»cnb«d •od «uch deicnpiion •n«ched lo ihe d«f

HJmmarv rapon

EnvifonintnttlPtofeclionAflOTcv. ClPS»np(«Mln*g«in«<itOff>c«.P.O..Bo«8»8; Aleyndn>.VIreinr22313 703/'S57-1490

Organics Analysis Data Sheot(Page 4)


CASNumber

1

2 ' ' • ^ ' - ' • •

3

d -

s6

7.

R

9.

in.

11

17

it14.

IS

Ifi

17

1R.

1 9

20.

71..

22

23

24

2!,

?S

27

28

29

30

Compound Nama ' ..

Uol/OK\^ C^i^Jf

. • • ' ' '

. .. ..- -..-...-...

• . — . - - ' • •

. .. . .. . . .. - , . . . - - . . . .

; . ; • . - . ..-.-.

• • . 1

• 1'

; '. [ .

• ~i :., •

r

• • T

Fr»etior).

.-•..-.-.—-..--.:

... . ..

RT or Scan; Mumbar

.;:'.•; :. . . . •

- ;-., . -.

CttimatedConcartttation

(ug/1 OffigTkg^.

r

£

. . . — , . ; .

-^ô

tiY

eaô

CT1

X> 0

3>

CO '-'

•Z.-

Z.-

3. \

<-

)C

T C

l "0

-

mL

nr-

m" .

m s

.. ..

co"

^^.

^"

^"

Co

.-

( -^

(MÛ

^

• -

: ••

-g B

^>^^(^

^^^^^_^^^^y

/^ A

Â

^Â

^^

i^^

C^^

^-I

'/•

00 ^

^-.-^--M

^-tÂ

^^..C

S^^V

. )


DATA: EPAVOA1721. TI08/19/84 5:07:00SAMPLE: 77113-15SUBMITTED BY: EPA ANALYST: RJW

AMOUNT=AREA(HGHT) * REF. AMNT/(REF. AREA(HGHT)* RESP.FACT)RESP, FAC. FROM AVERAGE OF WHOLE . RL

MO NAME1 *2--.B.--

3 »

H3LHSL

HSLHSLHSL

HSLHSLHSLHSL

BROMOCHLORMETHANE^ (INTERAL STANDARD)P-DIFLUOROBEN2ENE ^INTERNAL'STANDARD)D.ICHLOROBENZEIME-D5: < INTERNAL STANDARD)CHLOROMETHANE ;BROMOMETHANEVINYL CHLORIDE : •CHLOROETHANE , .METHYLENE CHLORIDEACROLEINACRYLONITRILE1, -L-DICHLOROETHYLENE1. -L-DICHLOROETHANETRANS-1,2-DICHLOROETHYLENECHLOROFORM :1, a-OICHLOROETHANE'1, 1, 1-TRICHLOROETHANEACETONE :

CARBON DISULFIDE • " 'CftRBON TETRACHLORIDEBROMODICHLOROMETHANE1,2-DICHLOROPROPANETRANS-l.^-DICHLOROPROP-YLENE " - '-TRICHLOROETHYLEN^BSNZENEDIBROMOCHLOROMETHANE1, -L, 2-TRICHLOROETHANECIS-i. 3-DICHLOROPROPYLENE2-CHLOROETHYL VINYL ETHER8ROMOFORMMETHYL ETHYL KETONEVJN'YL ACETATEMETHYL ISOBSJTYL KETONE1. 2-OICHLOROETHANE-D4 (SURROGATE)BENZENE-DA (SURROGATE)D1EROMOTETRAFLUOROETHANE (SURROGATE)Brs'PERFLUOROISOPROPYL)KETONE (SURROGATE)Fi.L'OROEENZENE (SURROGATE)TSTRACHLOROETHYLENE1,1,2,2-TETRACHLOROETHANETOLUENE ' ^ '/ 'CHLOROBENZENEErHYLBENZENE2-:-!EXANONESrYRENE

0-^YLENEM-:<YLENE

NO47484950

NAMEM-eROl-IOBENZOTRIFLUORIDE (SURROGATE >D-5 ETHYLBENZENE (SURROGATE) .TOLUENE-DB (SURROGATE)P-BROMOFLUOROSENZENE (SURROGATE)

NO--1

234567B9

1011

M/E SCAN-130 - 385114 699117 BS8NOT'FOUNDNOT FOUNDNOT FOUNDNOT FOUND

B4 237NOT FOUNDNOT FOUNDNOT FOUND

T313:23:29;

9:

:ME09S319

45

REF123

1

: RRT1.-0001. 0001. 000

0. 745

MlAAA

A

:THBBBBBB

BB

AREA(HGHT)14133.64337,39B14.

14343.

AMOUNTS0. 000 UG/L30. 000 UG/LS0..00e :UG/L

•/.TOT4. 344. 344. 34

38. 357 .UG/L 2. 59

NO121314151617i a

1920212223a425262728293031323334353637'10

394041424344454647484950

- M/ENOTNOTNOTNOT97

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT436584

NOTNOTNOT

- 3AA

NOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

9B95

SCANFOUNDFOUNDFOUNDFOUND

516FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND'FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

726468617

FOUNDFOUNDFOUND- 7RPfFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

8151036

TIME

17: 3B

24: 4815:5921: 05

27:5135: 24

REF

1

222

—3—

33

; RR

1.. 34

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:.:^

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9 A?• A

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BB

SBBBBB

-DD—

BBBB

; AREA<HGHT»

30551.

125202.61726.

114230.

——38BB.'

116166.65834.

AMOUNT

46. 243,

491. 155100. 627

92. 11B

ia

103. 01984. 949

: • •-^; -

UG/L

UG/LUG/LUG/L

UG/LUG/L

•'XTOT •

4. 20 «

44. 62 •-"9. 148. 37

- 44-

9. 367. 72

DUAL MASS SPECTRUM83/19^84 5!07!00 + 9:48SAMPLE: 77113-15CONDS.:ENHANCED <S 15B 2N 0T)

DATA; EPAUOA1721 #287 BASE M/'E: 49/- 49CALIi EPAUOA1721 #1 RIC; 13103./' 14927,

49 60 70 80

DATA: EPAUOA1721 #515 BASE M/E; 97/- 97CALI; EPAUOA1721 #1 RICi 17343./ 18697.

DUAL MASS SPECTRUM ;

98/19/34 5i07!00 + 17S3SSAMPLE:'77113-15CONDS.:; IENHANCED <S'15B 2N 6T)

80 90 190 110 1201

40

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i DUAL MASS SPECTRUM DATA; EPAWA1721 #780 BASE M/E: 166/- 4498/19/84 5;07;00 + 26:39 ! CALI; EPAWA1721 #1 RIC: 3967./ 11327.SAMPLE:|77113-15 ' . , :CONOS.sl IENHANCED <S 158 2N 0T>

100.0-1 : : r 1374.

50.0- . , , . . , . . . .

—I—i—r1-]—I' 'l I J I ;i | "i ; 1 ! 'i' | •• i |—i—|—r- '^—|—f—|—i i ' i 1 'I———I 1 I 1—|—r-1

M/E 50 . S ; '. \ . \ 100 . i Ui 150 ' 200| I I I I I • ] ' • j l j • I . 1 . 1 , 1 . ! 1 ll I i 1 i I i I l I I 1 i 1 i

59,9- ' ; : • ;' , •. : ' .

100.0- : • ; L 1374.: ; 0 0 •i •' 6 S

Environmental Protecnon Agency.P.O.Bo«8l8. Alexandria.Virgin!

1 1 ^

lab Sample in No- 1 T<7 •n

CLP Sample Management OMice., 22313 703/S57-2490

Organics Anal(Pa

.^s4im^ -;5^Y.

. yL . . .U Volatile C<

Concentration: (Vow)

. . . . ... 0 . 1

Percent Moisture (Oecan

ysis Dgel)

Gas

(?C

Cor

Oat

omROL»

Mediu

^ 1

Q'tted):'.

)ata Sheet

H Nn

RBport Nn 7 7 —'

•ilrarl Nn V o

Jnds

m (Circle One)

i^W^i

r

Sample Number

/^w

^Q

OJ-^~7?,D^]nt-W

l i

D

CASNumber

74-87-3

74.83-9

75-01-4

75-00-3

75-09-2

67-64-1

75-15-0

75-35-4

75-34-3

156-60.5

67-66-3

107-06--2

78-93-3

71-55-6

56-23-5

108-05-4

75-27-4

Chloromethane

Bromomethane

Vinyl Chloride

Chloroethane

Methylene Chloride

Acetone

.Carbon Disulfide ;

1 , 1-Dichloroethene

^.-l-Dichloroethane

Trans-1, 2-Dichloroelhene

Chloroform ;

1 : 2-Dichloroeihane

2-Bulanone

1 , 1 , 1 -Trichloroelhane

Carbon Telrachloride

Vinyl Aceiate


ug/lori^(CircleTS

^l.. .

• ^

• •eJV,

~^t~^\

~"T'"• •l-• ^^

-^^^ iM '^

^-J

^

J-

,

^

/

CASNumber

79-34-5

•78-87-5

'10061-02-6

'79.01 -6

124-48-1

79-00-5

71-43-2 ; •

10061-01-5

110-75-8

75-25-2

591-78-6

.108-10-1

127 -18 -4

108-88-3

108-90-7

100-41-4

•100-42-5

1 . 1 .2 . 2-Teirachloroethane

1 , 2-Dichl.oropropane •

Trans-1, 3-D(chloropropene

Trichloroethene

Dibromochloromethane

1 , 1 . 2-Trichloroelhane

Benzene '- :;

cis-1. 3-Dichioropropene

2-ChIoroethylvinylether

Bromoform

2-Hexanone

4-Methyl-2-Penianone

Tetrachforoelhene

Toluene

Chlorobenzene

Elhyl benzene

Slyrene

Total Xylenes

ug/l orw/(CircleW

^ 1-s-•T

?3 •

? .? i

3 •

• =? -

'.y-•- 7"H^H^ ^~}

•4

?-J - ^

Kg/^ne|

y

\

D«ta R«E>oning Qualifiers

< reponiitfl rosults lo EPA, th« following resiflis aualifiei

definition O* BBCh tiflfl rnust t>B •KpltCll '

V«lu« H the fetuti K • vlu« gr««taf than or equal \o lh«

<tci®ct*o" (<mn. r«oon thfl value

U indicatet compound w«s analyzed for.but "01 o<itec(«d

Rapon ilw mir>imum d«(flciion fimil <(K lha umpl«wrth

tn< U (fl .g,. I OU| ba*«d 0" nacit—rY CO"CBnn*HKm/

dilution •ctions. (Th»t is noi n«c«furily the inurunwnl

<*B(BCI'O I limit .1 Th« fooinof xnould r«ad U-

C(xnpound Wt •n«lyi«<J (or but noi (»«(«ci«d Th«

numbflr i« in« minimum TUinJbl* dataction limit to*

the Mmpic

J lndic*l«k •n «»(imal«d vlu« Th<« fl«g i« u*«d edhf

w+ien ttumating e co"cflmr«non for iBntfllivflly

This flag •ppties to pesliCtde par»fTKier$ •vhere the

idennficaiion has baari condrmcd Oy GC/MS S»ngle

coniponeni p^tticid^s^l 0 nfl/ul in the linnl aKtraci

snouki be confirmed Ov GC/MS

This (lag is ui»d wtwn ih< •nal^e 11 found in th« blank

as w<ll as J sample H indtcates polt'ole/protxble

«ppro<in«ie action

Ot"«» Olh<r loeciltC Hags and (oolnows m*Y t>e requi(e0 to

proo«rlv delinfl the reculif M usftd, tt'<Y fnuti tx tulli

d«u:nb«d and BUC" dfltcftption •nach»d 10 (hfl dar

turnmAry feport

Environmental Protection Agency. CLP Sample Management Office.P. O.Box818. Alexandria. Virginia 22313 703/557-2490

Sample Number

H^nO^SOrganics Analysis Data Sheet

(Page 2)

Semivolatiie Compounds

Concentration: (to / Medium i (Circle One)

Date Extracted/Prepared: IJ l^-5

Date Analyzed: c \ \^n•^~\

CASNumber

62-75-9

108-95-2

62-53-3

111.44-4

95-57-8

541-73-1

106-46-7

100-51-6

95-50-1

95-48-7

39638-32-9

106-44-5

621-64-7

67.72-1

98-95-3

78-59.1

88-75-5

105-67-9

65-85-0

1 1 1 - 9 1 - 1

120-83-2

120-82-1

91-20-3 .

•106.47.8

87.68-3

59-50-7

91-57-6

77-47-4

88-06-2

95-95-4

91.58-7

88.74.4

1 3 1 - 1 1 - 3

208-96-8on f-in i

N-Nilrosodimelhylamine

Phenol

Aniline

bis(-2-Chloroelhyt)Elher

2-Chlorophenol

1. 3-Dicntorobenzftne


Benzyl Alcohol.

1; 2-DichIorobenzene

2-Methylphenol

bis(2-chlorotsopropvl}£tner

4-Methyiphenof

N-Nitfoso-Di-n-Propylamine

Hexachforoeihano

Nitrobenrene

Isophorone

2-Nilrophenol

2, 4-DimethY)phenol

Benzoic Acid

bis(-2-Chforoethoxy)Methane

2, 4-DtChlorophenol

1 , 2. 4-Trichloroben2ene

Naphthalene

4-ChIoroaniline

Heitachlorobyladiene

4-Chloro-3-Melhylphenol

2-Methylnaphthatene

HexachlorocYclopentadiene

2.4. 6-Trichlorophenol

2, 4, 5-Trichlorophenot

2-Chforonaphihalene

2-Nitroaniline

DtmelhYl Phihatate

Acenaphihylene" .,

iia/lorCa/Kg?(CircieOne)

CASNumbef

83-32-9

51-28-5

100-02-7

•I.32-64-9

^21-14-2

606-20-2

84-66-2

7005-72-3

86-73-7

100.01-6

534-52-1

86-30-6

101-55-3

1:18-74-1

87-86-5

35-01-8

120-12-7

84-74-2

206-44-0

S(2-87.5

r29-00-0

85-68-7

31-94-1

36-55-3

1;17-81.7

2'18-01-9

1,17-84-0

205-99-2

207-08-9

SO-32-8

1.93.39-5

53-70-3

1'9I-24-2

Acenaphthene

2. 4-Oinitrophenol

4-Niirophenol

)ibenzofuran

2. 4-Dinitrotoluene

2, 6-Dinitrotoluene

Diethylphthatate

4-Chforophenyl-p'henyfethef

Fluorene

4-Nitro3niline

4, 6-Dinitro-2-Meihyiphenol

N-Nitrosodiphenytamine ( 1 )

4-Bromophenyl-pheny<ethet"

Hexachlorobenzene

Pentachlorophenol

Phenanihrene

Anthracene

Di-n-Butylphthalale"

Fluoranthene

Benzidine

Pyrene

Buiylbenzylphthaiate

3. 3'-Dichlorobenzidine'

Benzo(atAnthracene '

bis(2-Ethy(hexyl)Phihalaie

Chrysene

Oi-n-Odyl Phlhalale

Benzo(b)Fluoranthene

Benzo(klFluoranthene

Benzo(a>Pyrene

lndeno(1. 2. 3-cd)Pyrene

Diben^a, h)Anthracene

Benzo(g. h, i)Perylene

ug/lor^g/Kg^(CircieOn?

EnvKonnKfual Promotion Agency, CLPSafnp(«MJn«gam«nlOnic«.P.O.BoxSIS. AlnxirKlru.VirB.no 22313 703/557.2490


Sample Number


CASNumb«r

l

•>

1

a

•i

fi

7

R

l

in

n

17

n

1 A

Ti

1 R

17

in

19

?0

21

77

23

24

7fi

3B

27

2B

29

in

Compound Name

-

. ; .. ..-...„

FractionRT or Scan

NumberEstimated

Concentration(ug/1 o^tiO/kgL

0

0

0 0

RIC08/19/-84 7:67:09SAMPLE; 77113-15 MSDCOHDS.:RANGE; G 1,1330 LABEL; N

DATA;CALI:

EPAWA1723 #1EPAUOA1723 #1

0, 4.0 QUAN; A 0, 1,0 J 0

SCANS

BASE: U 20,815

1 TO 1300


DATA: EPAVOA1723. TI8B/19/84 7:07:00SAMPLE: 77113-15 MSDSUBMITTED BY EPA ANALYST: RJM

AMOUNT=AREA(HGHT) « REF. AMNT/(REF. AREA<HGHT)* RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . RL

MO NAME1 »2 »3 »

HSLHSL

30 HSL31 HSL32 HSL

HSLHSLHSLHSL

BROMOCHLORMETHANE (INTERAL STANDARD)P-DIFLUOROBENZENE (INTERNAL STANDARD)DICHLOROBENZENE-D5 (INTERNAL STANDARD)CHLOROMETHANEBROMOMETHANEVINYL CHLORIDECHLOROETHANEMETtiYLENE CHLORIDEACROLEINACRYLONITRILE1,1-DICHLOROETHYLENE1, 1-DICHLOROETHANETRANS-1,2-DICHLOROETHYLENECHLOROFORM1, 2-DICHLOROETHANE1,1,1-TRICHLOROETHANEACETONECARBON DISULFIDECARBON TETRACHLORIDEBROMODICHLOROMETHANE1, 2-DICHLOROPROPANETRANS-1, 3-DICHLOROPROPYLENETRICHLOROETHYLENEBENZENEDXERGMOCHLOROMETHANE1,1,2-TRICHLOROETHANEC;S-1,3-DICHLOROPROPYLENE2-CHLOROETHYL VINYL ETHERBROIIOFORMMETHYL ETHYL KETONEVINYL ACETATEMCTHVL ISOBUTYL KETONE1,2-OICHLOROETHANE-D4 (SURROGATE)B£N2ENE-D6 (SURROGATE)DIBPOMOTETRAFLUOROETHANE < SURROGATE)B1E(FERFLUOROISOPROPYL)KETONE (SURROGATE)F^UOROE.ENZENE (SURROGATE)TETRACHLOROETHYLENE1, - , £ , 2-TETRACHLOROETHANETOLUENECHLOROBENZENEETriYLBENZENE2-HE;'A^ONESTYREME0-XYLEMEM-<YLENE

NO474B4950

N0123456789

1011

1213141516

NAMI


84NOTNOT

61NOTNOTNOTNOT

97

M-BID-5TOUP-SI

SCAN384

698857


287FOUNDFOUND

369


515

M-BROMOBENZOTRIFLUORIDE (SURROGATE)D-5 ETHYLBENZENE (SURROGATE)TOLUENE-DS (SURROGATE)P-SROMOFLUOROBENZENE (SURROGATE)

TIME REF RRT METH AREA(HGHT)51590.

268497.159081.

13: 07 1 1. 000 A BB

23: 51 2 1. 000 A BB29; 17 3 1. 000 A BB

9: 48 1 0. 747 A BB 34. 137 UG/L 4. 09 62586.

12: 36 1 0. 961 A BB 57. 746 UG/L 6. 93 111121.

17: 36 1 1. 341 A BB 49. 385 UG/L 5. 92 119099.

AMOUNT 7.TOT50. 000 UG/L 6.0050. 000 UG/L 6. 0050, 000 UG/L 6. 00

NO1718192021222324252627282930313233343536373B394041424344454647484950

M/ENOTNOTNOTNOTNOTNOT

9578

NOTNOTNOTNOTNOTNOTNOT436584

NOTNOTNOT166NOT

91112NOTNOTNOTNOTNOTNOTNOT

9895

SCANFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

605621


72546861&

FOUNDFOUNDFOUND

780FOUND

821861


8151036

TIME

20: 4821: 13

24: 4615: 5921: 03

26: 39

28:0329:25

27: 5135: 24

REF

22

222

3

33

33

RRT

0. 8670. 890

1. 0390. 6700. 883

0. 910

0. 9581. 005

0. 9511. 209

METH

A BBA BB

A VBA BBA VB

A BB

A BBA BB

A BBA BB

AREA<HGHT)

87953.181042.

31812.211691.469033.

24796.

199880.138976.

475220.269712.

AMOUNT

33.165 UG/L33. 352 UG/L

29. 912 UG/L82. 719 UG/L90. 662 UG/L

9. 94S UG/L

36. 991 UG/L33. 426 UG/L

105.475 UG/L87.102 UG/L

•/.TOT

3. 984. 00

!r',

3. 599. 92 '~

10. 87 0

0

1. 19

4. 444. 01

12. 6510. 45

DUAL MASS SPECTRUM08/19/84 7;07s68 + 9:48SAMPLE; 77113-15 MSDCONDS.!ENHANCED (S 15B 2N 6T)

DATA; EPAUOA1723 #287CALI; EPAUOA1723 Sl

BASE N./E: 49/ 49RIC: 5S255./ 53263.

40 60 79 80

0

DUAL MASS SPECTRUM08/13/84 7;07!00 + 12:3£SAMPLE: 77113-15 USDCONDS.!ENHANCED (S 15B 2N 0-0

DATA; EPAWA1723 tt369CALI; EPAUOA1723 <tl

BASE M/E; 61/ 61RIC; 62713.-' 66047.

40 60

-T"

78 89 30 100

0 0 1 :1 "/ 7

DUAL MASS SPECTRUM03/19/84 7;87;09 + 17;36SAMPLE: 77113-15 MSDCOHDS.:ENHANCED <S 15B 2N 9D

DATA: EPAUDA1723 #515CALI; EPAUOA1723 #1

BASE M/'E: 97•/ 97RIC; 74379./ 78335.

40 60 70 80 S6 110 129

'- 21888.

DUAL MASS SPECTRUM08/19/84 7:07:88 + 28;48SAMPLE; 77113-15 MSDCOHOS.;ENHANCED <S 15B 2N 0T)

DATA; EPAUOA1723 TO5CALIs EPAUOA1723 ftl

BASE n/-E; 95/ 35RIC; 34531./ 97731.

0 0 1

DATA: EPAUOA1723 #621CALI; EPA1JOA1723 »1

BASE ri/E: 78/ 78RIC: 675S3./ 184S31.

DUAL MASS SPECTRUM88/19/34 7:07:00 + 21;13SAMPLE: 77113-15 MSDCONDS.:ENHANCED <S 15B 2N 0T)

60 70

0 0

49

DUAL MASS SPECTRUM03/'19/84 7; 07; 88 + 24:46SAMPLE: 77113-15 MSDCONDS.: .ENHANCED <S 15B 2H 0T)

DATA; EPAWA1723 #725CALI; EPIWOA1723 Dl

BASE ri/'Ei 43/ 43RICi S335./ 13E63.

40 68 70 30 90

0 0

DUAL MASS SPECTRUM DATA: EPAWA1723 <t78@ BASE M.-'E; 166/ 16683/'13/84 7:07!00 + 26!39 CALI! EPAUOA1723 #1 P^IC! 32415./ 39743.SAMPLE: 77113-15 MSDCONDS.:ENHANCED <S 15B 2N 0T>

100.8-1 r 4G88.

59.0-

tl/E 50 100 150 200

j ||||[|])|| ||j))'| • | 1 | | 1 ' j l ^ l ' j ' j l 1 1 1 ' ' • | ' ] ] 1 ' • ' ' ' j ' ) j | ' ' ' ' ' ' ' I

50, 0 -

100.0-^ , \- 4688.0 0 1 ' • ; 2

DUAL MASS SPECTRUM DATA: EPAUOA1723 #321 BASE M/E; 91/ 9188/13/'84 7!e7!00 + 28;83 CALI; EPWOfllPSS til RIC; 73993./ 113£63.SAMPLE: 77113-15 MSDCONDS.:ENHANCED (S 15B 2M eT)

199.0-1 r 34432.

50.0-

—r i—I—•L-I—^U—| "I ' |—I--11111"!—j—i—\—v—|—i—|—i—|—i—|—i—|—i—|—i—|—i—|———|—T^

M/E ^0 ^0 1^8 2^0

, ',|i|i|||^L..I.irlTji1r.l-^ I •^I'j,'^. < I———' • ' • ' • ' ' ' • ' •———^-^-J———|

50.3-

109.0-^ '- 34432.0 0 1 ' n ?

DUAL MASS SPECTRUM03/19/S4 ?!e7:00 + 29;25SAMPLE; 77113-15 MSDCONDS.:ENHANCED <S 15B 2N 8T>

DATA; EPAWA1723 #861 BASE M/E; 112/' 112CALI; EPWOftl723 #1 RIC; £2331./' 118655.

1 1| , " 1C

-^hh. ,„ J||

0i| | l | . H i . ' , . l . i j j

' ' I T 1 • • I ' I 1100

- 1—t 1 I 1 1 -I 'llli 'Tiiii—^~~——-

1 |

—1——

^

1 i I i 1 i | i 1 i 1 i I i 1 i i

153 230-1 i 1 < 1 i 1 i 1 i 1 i 1 i 1 i 1 i

t-

00

SCANS 1 TO 2800RIC DATA: EPABN1361 #1CALI; EPABN1361 ttl09/17/84 19:16:00

SAMPLE: 77113-7 1/10 ABNCONDS.:RANGE: G 1,2808 LABEL: H 2, 2.0 QUAN: A 2, 3.0 J 0 BASE; U 20, 3

i5

5007:55

1009l5;50

150023:45

2000

31:40250039:35

QUANTITATICN REPORT FILE: EPABN1361

DATA: EPABN1361.TI09/17/84 19:16:00SAMPLE: 77113-7 1/10 ABNSUBMITTED BY: A?<1ALYST:

AMOUNT-AREA<HQHT) » REF.AMNT/(REF.AREA(HGHT)* RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . R L

MO NAME1 »2 •»3 »4 *5 »6 »

20 HSL21 HSL

HSLHSLHSLHSLHSL

D-4 1,4-DICHLOROBENZENED-8 NAPHTHALENED-8 ACENAPTHENED-10 PHENANTHRENED-12 CHRYSENFD-12 PERYLENF2-FLUOROPHENOL < SURROGATE. >D-5 PHENOL (SURROGATE)D-5 NITROBENZENE (SURROGATE)2-FLUOROBIPHENYL (SURROGATE)2.4,6-TRIBROMOPHENOL (SURROGATE)D-14 TE.RPHENYL (SURROGATE)N-NITR OSODIMETHYLAMINE2-CHLOROPHENOLPHENOLBIS (2-CHLOROETHYL) ETH6.R1,3-DICHLOROBENZENE1<4-DICHLOROBENZENEI,2-DICHLOROBENZENEANILINEBENZYL ALCOHOLBIS(2-CHLOROISOPROPYL)ETHERHEXACHLOROETHANEN- NITROSODIPROPYLAMIN6NITROBENZENEISOPHORONE2-NITROPHENOL2,4-DIMETHYLPHENOLBIS(2-CHLOROETHOXY)Mm HANE2,4-DICHLOROPHENOL1,2,4-TRICHLOROBENZENE-NAPHTHALENEHEXACHLOROBUTADIENEP-CHLORO-M-CRESOLHEXACHLOROCYCLOPENTADI EN?2,4.6-TRICHLOROPHENOL2-MFTHYLPHENOL4-METHYLPHENOLBENZOIC ACID4-CHLOROANILINE2-METHYLNAPHTHALENE2-CHLORONAPHTHALENEDIMETHYL PHTHALATEACENAPHTHYLENE2,6-DINITROTOLUENEACENAPHTH£NE

/

//'

NO NAME2,4-DINITROPHENOL4-NITROPHENOL2.4-DINITROTOLUENEFLUORENE4-CHLOROPHENYL PIIENYL ETHERDI ETHYL PHTHALATE4, 6-DINITRO-2-METHYLPHENOLN-NITROSODIPHENYLAMINF1. 2-DIPHENYLHYDRAZINE4-BROHOPHENYL PHENYL ETH6.RHEXAC.HLOROBENZENE .PENTACHLOROPHENOLPKENANTHRENEANTHRACENEDI-N-BUTYL PHTHALATEFLUORANTHENE

HSL 2,4,5-TRICHLOROPHENOLHSL 2-NITROANILINEHSL 3-NITROANILINEHSL DIBENZOFURANHSL 4-NITROANILINE

BENZIDINEPYRENEBENZYL BUTYL PHTHALATE.BENZOCA)ANTHRACENE3.3'-DICHLaROBENZIDINfcCHRYSENEBIS<2-ETHYLH£XYL) PHTHALATEDI-N-OCTYL PHTHALATEBENZO(B > FLUORANTHENEBENZQ(K»FLUORANTHENEBENZO<A)PYRENEINDENO(I. 2,3-CD)PYRENFDIBENZO<A.H>ANTHRACENEBENZO<GHI )PERYLF:NE

M/E SCAN TIME REF RRT METH AREA(H5MT) AMOUNT 7.TOT

NO1234S6789

1011121314151617181920212?23242526272829303132333435363738394041424344454647484950515253545556

M/E1S2136164188240264NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

SCAN699942

1280133820632320

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDPOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

T111420243236

IME043316404244

REF1234S6

RRT1. 0001. 0001. 0001. 0001. 0001. 000

MEAAAAAA

:THBVBBBVBBBBBB

AREAd-iSHT21323.30/18.33937.32489.30900.39094.

) AMOUNT40.00040.00040.00040. 00040.00040.000

UG/MLUC/MLUG/MLUS/MLus/Mi-ne/ML

7.TOT16. 7116. 7116. 7116. 7116. 7116. 71

NO M/E SCAN TIME. REf- RRT METH AREA(HSHT) AMOUNT y.TOT57 NOT FOUND58 NOT FOUND59 NOT FOUND60 NOT FOUND61 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND65 NOT FOUND66 NOT FOUND67 NOT FOUND68 NOT FOUND69 NOT FOUND70 NOT FOUND71 NOT FOUND72 NOT FOUND73 NOT FOUND "'74 NOT FOUND75 NOT FOUND ~-76 NOT FOUND Q77 NOT FOUND _78 NOT FOUND79 NOT FOUND80 NOT FOUND81 NOT FOUND

Environmental Protection Aflency, CLP Sample Management OHice,P. 0.80x618. Alexandria. Virginia 22313 703/557-2490

Sample Number

P'H^D^

Laboratory Name:

Lab Sample ID No:

Sample Matrix:

Organics Analysis Data Sheet(PageD

'.{.^•^S^m case No:

^îl^lÂ^ QC Report No:

Contract No:

Date Sample Received: 6j'/~f'l'h^Data Release Authorized By:

~D Volatile Compounds

Concentration: /Cow) Medium _ (Circle One)

Date Extracted/Prepared: 0,

Dale Analyzed: ——,° 1 , 1

Conc/Dil Factor: ————(_

Percent Moisture: ——d

Percent Moisture (Decanted): .

^1^

<2,iy/ .

-PH-

CASNumber

74-87-3

74-83-9

75-01.4

75-00-3

75-09-2

67-64.1

75-15-0' "

75-35-4

75-34-3 •

156.60.5

67-66-3

107-06-2

78.93-3

71-55-6

56-23-5

108-05-4

75-27.4

Cnloromethane

Bromomethane

Vinyl Chloride

Chloroethane

Methytene Chloride

Acetone

Gaboon Drsulfide;

T. 1-Oichloroethene

1, 1-DtChloroelhane

Trans-1, 2-Dichloroethene

Chloroform

1 . 2-Dichloroeihane

2-Bulanone

1 . 1 , 1-Trichloroethane


Vinyl Acetate

Bromodichloromelhane

ug/lortijTK(CireleTrfl

IK 1

1<4

- i n: ^ Y /

^5—. —i

' • ^?-

.: ... ...•T -

N\?11-.^.

——^7. 1 4 1^^

aT

^

^

CASNumb«r

7.9-34-5

78-87-5

10061-02-6

7S-01-6

124-48-1

79-00-5

;7'1 -43-2 .

1D061-01-5

110-75-8

75.25-2

S91-78-6, .

108.10-1

127.18-4

108.88.3

108-90-7

100-41-4

100-42-5;

1 , 1 , 2 . 2-Teirachloroeihane

1, 2-Dichloropropane

Trans-1, 3-DichlofOpropene

Trichforoethene

Oibfoinochloromelhane

1. 1 . 2-Trich(orbethane

SenTene : - •': -• - •"- ••;

cis-1-. 3-Oichloropropene

-2-C+doroethylvinYlether

Bromoform

2-Hexanone

4-Me!hYl-2-Pentano^^':

Telrachloroeihene

Toluene

Chlorobenzene

Elhylbenzene

Styrene

Total Xylenes

ug/l or m/(CircleU?

-? 1

-?

^

'?^••

7..... ^ .

^.- -r-^^^

-^^?^\

Kgîs)

1

-\

/Dau Reporting Qualifaers

For faporting refuitt io;EPA. the following resists Qualifiers «re usod

Ad<liii(n-ial 41*gs Of (ootnotet «xolinni"g fsutts rfie' <rtcou<'*i3»d Howev<f.

d«1infi<on of ««ch flag mull be expl.cil \

M th« r««uh it a wlu« gr««t«r t^<" or »qual lo tê

cf4l«ciion limit, fport lh« v«tu«

li-idiCaK- compound wi anJtyred lor bui noi d«!eci<d

Rtpon lh» rninifnum dflteciiO" limn Iw the sJmDiawnih

tho U (B.B . 10U) b.isod on Mceswn/ conccntfinon/

diluiion Jict*on«. (Th)* it not necaKUtily (he iniirufneni

d«teciion limit .) The footnor should read U-

Compound w«( analyzed lor bul f>o< d«l«ct»d Th«

numbflf it the mintmyrn «rfirâb>e oelection limit (of

the umole

lndic«l«f •n ••ti'rrfd wlu«. Thi< (t«o <• u»9d •ith—'

wh«n cilirming a cooc«r»tf«HKKl f(K Knuiiîly

This (l«g T>pl<«s 10 peSUCKit par«m<taft whar® (he

•dent ideation h»s t>*<n confiffrwd by GC/MS Single

componcni petttCtd«t£10ng/u) in the final axifCt

should be confirmed by GC/MS

B This {lag if u(«d wh<in IMC •rutyte it found in (h« bl»i

•s ovall «t • umpl« H <ndicaics poisible/pfobabi*

tilank contamination •nd wrns ih« datJ us«f to t«ke

•Dpioome •ciion

OTh»f Olh<r ipecidc llagi •wl k*o«noie» mav b< r«<iuif»d <o

(KQp«irlv d«tin« lha rsulis rf uwJ, thav mu»i tx luH^

ooicnb*d and «uch deicupiion «nach»d lo the dar

Environmental Protection Ag«ncY. CLP Sample Management Office.P.O Bo«B18. Alexandria. Virginia 21313 703/557-2490

Sample Number

Hm-hsOrganics Analysis Data Sheet

(Page 2)


Concentration: (to / Medium i (Circle One)

Date Extracted/Prepared: ^ ) 3 \ ~\

Dale Analyzed: 4 ^ ^ ^•\ ________

Conc/Dil F . ~>\^.^ \0^d^-

CASNumber

62-75-9

108-95-2

62-53-3

1 1 1 -44-4

95-57-8

541-73-1

106-46-7

100-51-6

95-50-1

95-48-7

39638-32-9

106-44-5

621-64-7

67-72-1

98.95-3

78-59-1

88.75-5

105-67.9

65.85-0

1 1 1 - 9 1 - 1

120-83-2

120-82-1

91-20-3

106-47-8

87-68-3

59.50-7

91-57-6

77-47-A

88-06.2

95-95-A

91-58-7

88-74.4

1 3 1 - 1 1 - 3

208.96-8

N-Niirosodimethylamine

Phenol

Aniline

bis(-2-Ch,oroethyl)Elher

2-Chlorophenol



Benzyl Alcohol

1.-2.Dich!orobenzene

2-Melhyiphenol

bis(2-chloroisopropvl)Elher

4-Methylphenol

N-Nitroso-Di-n-Propylamine

Hexachloroethane

Nitrobenzene

Isophorone

2-Nitrophenol

2, 4-Dimethvfphenol

Benzoic Acid

bis(-2-Ch)oroethoxy)Methane

2, 4-Dichlorophenol

1 , 2. 4-Trichtorobenzene

Naphthalene

4-Chloroaniline

Hexachlorobutadiene

4-Chtoro-3-Melhylphenol

2 -Methyl naphthalene

Hexachforocyclopentadiene

2. 4. 6-Trichlorophenol

2. 4. 5-Trichlorophenol

2 -Chloconaphthalene

2-Nilroanitine

Dimelhyl Phthalate

Acenaphihvlene

ug/l ortfd/Ka^(CircieDne)

CASNumber

83-32-9

51-28-5

100-02-7

132-64-9

121-14-2

606-20-2

84-66-2

7005-72-3

86-73-7

100-01-6

534-52-1

86-30-6

101-55-3

118-74-1

87-86-5

85-01-B

120-12-7

84.74-2

206-44-0

92-87-5

129-00-0

85-68-7

91-94-1

56-55-3

1 1 7 - 8 1 - 7

218-01-9

117-84-0

205-99-2

207-08-9

50-32-8

193-39-5

53.70-3

191-24.2

Acenaphthene

2, 4-Dinnrophenol

4-Nitrophenol

Dibenrofuran

2, 4-Oinitrotdluene :

2,G-Dinilrotoluene

Diethylphthalate

4-Chlorophenyl -phehylether

Fluorene

4-Nitroaniline

4. 6-Dinitro-2-Methylphenol

N-Nilrosodiphenyfamine 0)

4-Bromophenyl-phenyleiher

Hexachlorobenzene

Pemachlorophenol

Phenanihrene

Anthracene

Di-n-Butylphihalate-

Fluoranihene

Benzidine

Pyrene

BuTylbenzytph^halate

3, S'-Dichlorobenzidine

Benzo{a|Anthracene

bis(2-Elhy(hexy()Phihalaie

Chrysene

Di-n-Octyl Phihalale

Benzo(b)Ffuoranihene

Benzo(k)Fluoramhene

Benzo(a)Pyrene

lndeno<1. 2. 3-cd)Pyrene

Dibenz(a. h)An[hracene

Benzo(g. h. i)Perylene

ug/1 or(tfg/Kg^(Circleune

Environm«nul Prot«ctionAQ«ncv. CLP S«mpl« M«n«g«m4nl Office.P O.Bo.eiB. Ataundri*. Virgin.* 22313 703/557-2490

Organics Analysis Data Sheet(Page 4»

Sample Numbar


CASNumb«r

1

2

3

4

S.

e7

aain1113

13, ,

14 •

1 R

16

17

1R.

1 9

2C-

.?!

27

23

24

2S

26

27

2S

29.

in

Compound Name

.

'•

;

- ' • . . . t.-

:. •': --•-'.

'•

'. ". 1

•

•;

r

FractionRT or Scan

NumberEstimatad

ConcentrBtiQA(ug/1o^Og/kg),

<M

0

0

.... -

I- 0 0

SCANS 1 TO 1300RIC DATA: EPAUOA1722 ftlCALl! EPAUOA1722 #1eg/-19/84 6:08:00

SAMPLE; 77113-15 MSCONDS.;RANGE; G 1,1308 LABEL: N 0, 4.0 QUAN: A 0, 1.8 J 0 BASE: U 20, 3

817

37

2£

.

1 •

\ 96 178 .V-—'"—————•""—"J

' 12806:50

3737

-\^J'

04£

..„.„..

40013;40

5

39

U'

6

6

|

•w- J60

20!

18

6S

l^J^J

933

33

7(

|UU

OJ

ai

^i

80627:2

f

8E

J-/•'3>0

;1

10

.J^J

100034:10

132512

36

}

\J0^7^206^^

i | i1200 SCAN41:00 TIME


DATA: EPAVOA1722. TI08/19/84 6:08:00SAMPLE: 77113-15 MSSUBMITTED BY USTCO ANALYST: RJM

AMOUNT=AREA(HGHT) » REF. AMNT/(REF. AREA<HGHT)« RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . RL

NAME«•*•••

17 HSL18 HSL

30 HSL31 HSL32 HSL

HSLHSLHSLHSL

BROMOCHLORMETHANE (INTERAL STANDARD)P-DIFLUOROBENZENE (INTERNAL STANDARD)DICHLOROBENZENE-D5 (INTERNAL STANDARD)CHLOROMETHANEBROMOMETHANEVINYL CHLORIDECHLOROETHANEMETHYLENE CHLORIDEACROLEINACRYLONITRILE1, l-DICHLOROETHYLENE1, J.-DICHLOROETHANETRANS-1, 2-DICHLOROETHYLENECHLOROFORM1,2-DICHLOROETHANE1.li1-TRICHLOROETHANEACETONECARBON DISULFIDECARBON'TETRACHLORIDEBROMODICHLOROMETHANE1,2-DICHLOROPROPANETRANS-iL, 3-&ICHLOROPROPYLENETRICHLOROETHYLENEBENZENEDZBROMOCHLOROMETHANE1,1,2-TRICHLOROETHANEC;S-1,S-DICHLOROPROPYLENE2-CHLOROETHYL VINYL ETHERBSOMOF&RMM£THVL ETHYL KETONEVINYL ACETATEM.TTHYL ISOBUTYL KETONE1.2-DICHLOROETHANE-D4 (SURROGATE)BENZENE-D6 (SURROGATE)

D-IPROMOTETRAFLUOROETHANE (SURROGATE)B.rS(PERFLUOROISOPROPYL)KETONE (SURROGATE)FL-UOROEENZENE (SURROGATE)TS'-'RACHLOROETHYLENE1, J-, 2, 2-TETRACHLOROETHANETOLUENECl-iLOROKENZENE

•Er!-!YLBENZENE2-HE:XAN.ONESn'RENE;'

0-^VLElvEM'-XYLENE

M-SROMOBENZOTRIFLUORIDE (SURROGATE)D-5 ETHYLBENZENE (SURROGATE)TOLUENE-OB (SURROGATE)P-SROMOFLUOROBENZENE (SURROGATE)

SCAN335699858

FOUNDFOUNDFOUNDFOUND287

FOUNDFOUND370


511.

TIME REF RRT METH13: 09 1 1. 000 A BB23: 53 2 1, 000 A BB29: 19 3 1. 000 A BB

V: 48 1 0, 745 A BB

12: 38 1 0. 961 A BB

17: 38 1 1. 340 A BB

AREA(HGHT)S0103.

330407.100748.

95372.

116910.

231014.


53. 5&4 UG/L 5. 28

62. 557 UG/L 6. 17

98. 634 UG/L 9. 73

<-

NO

171819202122232425262728293031323334353637383940414243

44454647484958

M/ENOTNOT

NOTNOTNOTNOT9578

NOTNOTNOTNOTNOTNOTNOT

436584

NOTNOTNOT166NOT

91112NOTNOTNOTNOTNOTNOTNOT

9895

SCANFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

60&632


725469617

FOUNDFOUNDFOUND

731FOUND

822B&3

FOUNDFOUNDFOUNDPOUNDFOUNDFOUNDFOUND

Bl.t,1026

T3:ME REF

20:42 2 0.21:13 2 0.

24: 46 2 1.•1&:01 2 0.21:05 2 0.

26:41 3 0.

2B: 05 3 0.2T: 29 3 1.

27: 53 3 0.35:24 3 1.

RRT

867890

037671883

910

958806

951207

METH

A BBf\ BB

A BBA BBA VB

A BB

A BBA BB

A BBA BB

AREA(HGHT)

97014.207121.

41561.189218.419548.

52173.

197572.110880.

359064.151348.

AMOUNT

42. 629 UG/L44. 464 UG/L

45. 540 UG/L86. 160 UG/L94. 504 UG/L

33. 025 UG/L

57. 735 UG/L42. 110 UG/L

125. 837 UG/L77. 176 UG/L

7.TOT

4. 214. 39

\'^

4. 498. 509. 32 0

0

3. 26 "•

5. 704. 15

12. 417. 61

DUAL MASS SPECTRUMe8^19/-84 6!98;0@ + 9; 48SAMPLE: 77113-15 MSCONDS.:ENHANCED (5 15B 2N OT)

DATA; EPAUOA1722 #237CALI; EPAUOA1722 #1

BASE M/E: 49/ 49RIC; 81919./' 86527,

48 60 70 80

0 0

DUAL MASS SPECTRUM08 19/84 6;08:80 + 12i38SAMPLE; 77113-15 MSCONDS.:ENHANCED <S 15B 2N BT)

DATA: EPAWA1722 #378CALI; EPAWA1722 #1

BASE n/'E: 61/ 61RIC; 89471./' 93823.

-i—'-J-^———i———• | ' • • • i————i————r

40 50 68 70 80 90 100

0 0 1 '

DUAL MASS SPECTRUMBS/19^84 G!08;00 + 17;38SAMPLE: 77113-15 MSCONDS.;ENHANCED <S 15B 2N 0T)

DATA; EPAUOA1722 #516 BASE n/E: 97/' 97CALl! EPAWA1722 #1 RICi 146637. / 151807.

48 60 79 80 90 100 110 129

1

DUAL MASS SPECTRUM DATA: EPAUOA1722 tt606 BASE M/Ei 95/- 95eS/19/SA 6s08s00 + 29S42 CALI; EPAUOA1722 #1 RICi 103887./ 187519.SAMPLE: 77113-15 fISCOMDS.;ENHANCED <S 15B 2N UT)

198.0-1 r 16496.

50.9-

M/E 53 190

|———1|| ' ' • | 1 | | |1———' |t|| I———I——————L-^^———I lt|TT|1———————————————————ITTTT^

50.9- . . - •

100.0-^ - 18496.^ • 0 0 2 - 0 0

DUAL MASS SPECTRUM DATA; EPAWA1722 #622 BASE M.-'E; 78/ 7803/19784 6!3.S!09 + 2l!l5 CALI!! EPAUOA1722 #1 RICi S3327./ 114175.SAMPLE: 77113-15 MSCONDS.:ENHANCED (S 15B 2N eT)

186.0-1 r 36672.

58.9-

M/E 48 58 63 • 79 88

TO.a-

0 0 2 - 0 1

DUAL MASS SPECTRUM DATA: EPAUOA1722 #725 BASE M/E: 43/- 4303/'19-'84 6!0?.s0e + 24!46 CALl! EPAWA1722 «l RIC! 14431,/ 19263.SAMPLE; 77113-15 MSCONDS.;ENHANCED (S 15B 2N 0T>

109.0-1 r- 6976.

- I

561.0-

————,——' ' | I I '—i————j————l ' ' ! ' |————i—'—h————i————I————I——'—1————i————J

M/E 49 53 69 70 80 93 100————• ,,|,y,|————3————^-1————-^—————————————^————————^

59.9-1

-!

100.0-' i - 6976.| O 0 2 ' ) ' i ^

DUAL MASS SPECTRUM38---19/84 6; 98s 30 + 26; 41SAMPLE: 77113-15 MSCONDS.:ENHANCED (S 15B 2N @T)

DATA; EPAWA1722 #781 BASE M/'E; 166/ 166CALI; EPAWA1722 #1 RICi 66943,/' 74239.

__i—i—,- i i~i—1—r" "i—I—r

109 150 200

0 0 2 " u :"

DUAL MASS SPECTRUM08/'19/84 6;08i00 + 28s 85SAMPLE: 77113-15 t1SCONDS.!ENHANCED <S 15B 2N 0T>

DATA: EPAUOA1722 #822CALl! EPAWA1722 #1

BASE M/E: 91.-- 91RIC; S93S3./ 107135.

109 150

DUAL MASS SPECTRUMQ8/19/S4 6108;60 + 29!29SAMPLE; 77113-15 MSCONDS.sENHANCED (S 15B 2N 8T)

DATA: EPAUOA1722 #863CALI; EPAUOA1722 #1

BASE M/'E: 112/ 112RIC! 55167./- 81919.

199i I ' —I., 7

0 0 2 • 1 .' :'

'. "6 0 0

SCANS 1 TO 2800RIC DATA: EPABN1360 »1CALI: EPABN1360 #109/17/84 18:18:00

SAMPLE; 77113-7 1/10CONDS.;RANGE; G 1,2800 LABEL: N 2, 2.0 QUAN: A 2, 3.0 J 0 BASE: U 20- 3

IS

5007:55

100015:50

150023:45

200031:40

250939:35

QUANTITATION REPORT FILE: EPABN1360

DATA: EPABN1360-'TI — — — — — — -09/17/84 18:18:00SAMPLE: 77113-7 1/10SUBMITTED BY: ANALYST:

AMOUNT°AREA(HOHT) * REf-. AMNT/(REF, AREA(HGHT)* RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . R L

NAME•»»•»«•

20 HSL21 HSL

HSLHSLHSLHSLHSL

D-4 1-4-DICHl.OROBENZENED-8 NAPHTHALENED-8 ACENAPTHENED-10 PHENANTHRENED-12 CHRYSENED-12 PERYLENt-2-FLUOROPHENOL <SURROSATE»D-5 PHENOL (SURROGATE)D-S NITROBENZENE (SURROGATE)2-FLUOROB IPi-tFNYL (SURROGATE >2,4.6-TRIBROMOPHENOL (SURROGATfc)D-14 TERPHENYL (SURROGATE)N-NITROSODIMETHYLAMIN62-CHLQROPHENOLPHENOLBIS (2-CHLOROE1HYL) ETHER1.3-DICHLOROBENZENF1.4-DICHLOROBENZENE1.2-DICHLOROBENZENEANILINEBENZYL ALCOHOLBIS(2-CHLOROISOPROPYL)ETHERHEXACHLOROETHANEN-NITROSODIPROPYLAMINENITROBENZENEISOPHORONE2-NITROPHENOL2,4-DIMETHYLPHENOLBIS(2-C HLOROETHO X Y)ME IHANE2.4-DICHLOROPHENOL1.2.4-TRICHLOROBENZEMENAPHTHALENEHEXACHLOROBUTADIENEP-C HLORO-M-C RESOLHEXACHLOROCYCLOPENTADIENF2,4,6-TRICHLOROPHENOL2-METHYLPHENOL4-METHYLPHENOLBENZOIC ACID4-CHLOROANILINE2-METHYLNAPHTHALENE2-CHLORONAPHTHALENEDIMETHYL PHTHALATEACENAPHTHYLENE2,6-DINITROTOLUENEACENAPHTHENE

NO NAME47 2, 4-DINITROPHENOL48 4-NITROPHENOL49 3.4-DINITROTOLUENE50 FLUORENE51 4-CHLOROPHENYL PHENYL ETHER52 DIE1HYL PHTHALATE53 4.6-DrNITRO-2-METHYLPHENOL54 N-NITROSODIPHENYLAMINE55 1,2-DIPHENYLHYDRAZINF56 4-BROMOPHENYL PHENYL ETHFR57 HEXACHLORQBENZENE58 PENTACHLOROPHENOL59 PHENANTHRENE60 ANTHRACENE61 DI-N-BUTVL PHTHALATE62 FLUORANTHENE63 HSL 2.4,5-TRICHLOROPHENOL64 HSL 2-NITROANILINE65 HSL 3-NITROANILINE66 HSL DIBENZOFURAN67 HSL 4-NITROANILINE68 BENZIDINE69 PYRENE70 BENZYL BUTYL PHTHALATE71 BENZO(A>ANTHRACENE72 3,3'-DICHLOROBENZIDINF73 CHRYSENE74 BIS<2-ETHYLHEXYL) PHTHALATE75 DI -N-OCTYL PHTHALATE76 BENZO < S »FLUORANTHENE77 BENZO(K>FLUORANTHENE78 BENZO(A)PYRENE79 INDENOd, 2, 3-CD)PYRENF80 DIBENZO(A.H)ANTHRACEN&81 BENZO(GHI)PERYLFNE

NO M/E SCAN TIME REF RRT METH AREA(!-!5HT> AMOUNT 7.TOT

NO123456789

1011121314151617181920212723242526272829303132333435363738394041424344454647484950515253545556

M/E152136164188240264NOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

SCAN699942

1280135920662320

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

TIME11: 0414; 3520: 1624: 4132:4336:44

REF1 1.2 1.3 1.4 1.3 1.6 1,

RRT000000000000000000

METHA BVA SBA BVA SBA BVA SB

AREA<«8HT»16491.34717.23606.39260.24930.38459.

AMOUNT40.000 UO/ML40.000 UG/ML40.000 UG/ML40.000 UG/ML40.000 UG/ML40.000 UG/ML

XTOT16. 7216. 7216. 7216. 7216. 7216. 72

NO M/E SCAN TIME REF RRT KETH AREA(HSHT) AMOUNT 7.TOT57 NOT FOUND - - -58 NOT FOUND :

59 NOT FOUND60 NOT FOUND61 NOT FOUND62 NOT FOUND63 NOT FOUND64 NOT FOUND65 NOT FOUND66 NOT FOUND67 NOT FOUND68 NOT FOUND :69 NOT FOUND ;-.70 NOT FOUND ' ";71 NOT FOUND "•_73 NOT FOUND ;-73 NOT FOUND C\!74 NOT FOUND ' C75 NOT FOUND 076 NOT FOUND77 NOT FOUND78 NOT FOUND79 NOT FOUND80 NOT FOUND81 NOT FOUND

Sample NumberEnvifonmenlfitProleciion Agency. CLP Sample Management OMicc.P.O B0..818. Aleundna. Virginia 22313 703/557.2490

Orgaoics.AnalysisOata Sheet(Page 1 )

'^^s4imLaboratory Name:

Lab Sample ID No,<2_^ •g

Sample Mairix: —30 \. X

Oa(a Release Aulhorired By: Dale Sample Re<

u^^,<&-o/-WS^

.oi^. î/m^V Volatile Compounds

Concentration: /'Low) Medium (Circle One)

Percent Moistur<

0 ,

^

>•

i(0e

l/^^ • /

/ ' PH

i-anlflril

7.0

CASNumber

74-87-3

74.83-9

75-01.4

75-00-3

75-09-2

67-64-1

75-15-0

75-35-4

75-34-3

156-60.5

67-66-3

107.06-2

78-93.3

71-55-6

56-23.5

108-05-4

75-27-4

Chtoromethane

Bromomelhane

Vinyl Chloride

Chtocoelhane

Methylene Chloride

Acetone

Carbon Oisulfide

1 , 1 -Dichtoroethene "

1, 1-Oichloroeihane

Trans-1. 2-Oichlofoelhene '

Chloroform

1 , 2-Dichloroeihane

2-Butanone

1 , 1 . 1 •TrichloroeThane

Carbon Telrachloride

Vinyl Aceiale

Bcomodichloromelhane

ug/loiulg(CirdaT:

/ o u-'o/to

/O.</o.5

-- 6"5"

-ir-5'/&2^ -/O.5'

^

\i1

*-/

CASNumber

79-34-5

78-87-5

10061-02-6

79-01.6

124-48-1

79-00-5

71.43-2

tOOfil.01.5

110-75-8

75-25-2

591-78-6

1 0 8 - 1 0 - 1

1 2 7 - 1 8 - 4

108-88.3

108.90-7

100 -41 -4 ,

100.42-5

1 , 1 , 2 . 2-Tetrachtoroethane

1 , 2-0tch(oropropane

Trans-1, 3-Dichloropropene

Trichloroethene

O'bromochloromelhane

1 , \. 2-Trichloroclhane

Benzene

C f S - 1 . 3-OichlofOpropene

2-Chloroeihv(vinyte(her

Bromoform

2-Hexanone

4-MelhY(-2-Penianone

Telrachloroelhene

Toluene

Chlorobenzene

Eihylbenzene

Styrene

Total Xylenes

ug/l or i q^(CircleÔ

^6 \/^'

6<5',1;^( 0A"" /

/O 1

/Â^£'S- i3~ 1s-\/

Kg^mel

/

D«U R«poning Quilifie's

F.or i«poriir>B <flt"llt lo EPA. t < <ol(£>»vir fl results gu^

Addition*! <Ugs o» (ooirtoi<>»<iu>l*i"if\g r««ulls a«e Bf

dflfinHion of •«Ch 11«Q musl tr •«fllic<;

c a'aJi«f ;h«n ex •qu«l 10 (ric

lr*d«CalBl compound «VJS •(^•lyrftd (or t)u1 "01 d«1«0«d

Report th« minimum d«<9C1<on IITMI (<K ir»« Mfnpt<w1h

lh« U <« o . 10U] bJi*d on n«ce«urv cooc«nif«l>on^

dilution action* {This <s no( ri«c«turilv (FM? irMCfu'n«n(

dawction limn | The (001001® «houtd i»*a U-COTipourtd w( »n«lYi*<} lot but noi dfltacied Th«

nurritxir if ih« fninimum T(*irL«bâ d«l*cti0« lirnrltor

l"< K/npio

•«rs •re uwd

>UfJQ«d Mo'"^Cv<f. the

C Tnn fl«g •ppiies lo peilicidc pT«"tfltef» iwnare ir>«

id<r>ii(ic*('o" hai t>«n co"Hrmw3 bv GC/MS S>ftfl(«

corr>po"trtl p<tticxlet?10 "g I'ul i" ine linal oiract

should &e co"*'*"'«3 by GC/MS

B Ttiit <1<B ls "*w3 wtên ih» «rulYifl it (ouwJ '" ' bl<"k

•s bv«tl «> • MfTiDH- li ind<cai«i poa.s-ble/rKOtMbk

bifh comamimiion artd v/a'nt if* <l»r ut« 10 laht

JC>p<aoriJI« •CtiO"

Ot»x' Ol"tt IpocifiC <rg» <fid (ootnolti mflY b< *equif*<3 lo

prcuwrlv Afifin? Ihr mt.irn H 11*-^ "'--• •"• •" K- (' •"•

Env«ronm«ntal Protect«on Agency. CLP Sample Management OfftCfl.P. 0 Bo« 818.- Ate«aniffi»: Virginia 22313 703/557-2490



Concentration: (toy^ Medium > (Circle One)

Date Extracied/Preparedi <j|o-^ ^ y"\

Date Analyzed: \ \ \ 1 6\____

Conc/Dil Facior: \ "^ \1^~^—-

Sample Number

^LAÂL/^

CASNumber

62-75-9

108-95-2

62-53-3

111-44 .4

95-57-8

541-73-1

106-46-7

100-51-6 -

95-50-1

95-48-7

39638-32-9

106-44-5

621-64-7

67.72-1

98.95-3

78.59-1

88-75-5

105-67-9

65-85-0

1 1 1 - 9 1 - 1

120-83-2

120-82-1

91-20-3

106-47-8

B7-68-3

59.50-7

91 -57 -6

77-47-4

88-06-2

95.95-4

9 1 - 5 8 - 7

88.74-4

1 3 1 - 1 1 . 3

^-Nilrosodimelhytamine

Phenol

Aniline

bis(.2-Chtofoeihy()Elher

2-Chloropheno!


1.4-Dichtorobenzene

-Benryl-Alco+iot

1, 2-Oichlorobenzeoe

2-Meihylphenol

bis(2-chloroisopropyllEther

4-Methylphenoi . -

N-Niuoso-Di-n-Propylamioe

Hexachloroethane

Nitrobenzene

Isophorone - .————.- . —

2-Nitcophenot

2. 4-0ime(hy(phenol

Benzoic Acid

bis<-2-ChloroethoKy)Melhane

2, 4-Dichlorophenol

1. 2. 4-Trichlorobenzene

Naphthalene

4-Ch(oroaoi)«ne

Hexachlorobutadiene

4-Chlofo-3-Meihylpheno<

2-Meihylnaphihalene

HeKachlorocyclopeniadiene

2. 4. 6-TrichlorophenoI

2. 4. S-Trichlorophenol

2-Chloronaphlhalene

2-Nitcoan<line

Dimethyl Phthalale

ug/lortfg/(CirclaCT

; OU

) \

$uSO^0

MO^2^0<W>A^^rU^( ~0

^^0r OiTD

oÔiS rt)5^0\BTS^)?WDr O^sn^s-o^^0^CTS?U-05J5D5^T>^r0\t^~^codcô^-ro

^ne)

\,

t

CASNumber

83-32-9

51-28-5

100-02-7

132-64-9

1 2 1 - 1 4 - 2

606-20-2

84-66-2

7005-72-3

86-73-7

100-01-6

534-52-1

86-30-6

101-55-3

118-74-1

87-86-5

85-01-8

1 2 0 - 1 2 - 7

84.74-2

206-44-0

92-87-5

129-00-0

85-68-7

91.94-1

56.55-3

1 1 7 - 8 1 - 7 •

218 -01 -9

117 -84 -0

205.99-2

207-08-9

50.32-8

193-39.5

53-70-3

1 9 1 . 2 4 - 2

Acenaphlhene

2. 4-Dinitrophenol

4-Nitrophenol

Dibenzofuran

2. 4-Dinitroioluane

2, 6-OinitroMfuene

Oiethylphthalate

4-Chloropheny(-phenylether

Fluorene

4-N.iroaniline

4, 6-Oinitro-2-Methylphenol

N-Nnrosodiphenylamine ( 1 )

4-Bromophenyl-phenylelher

Hexachtorobenzene

Pentachlorophenot

Phenanihrene

Anthracene

Oi-n-ButylphthalaTe

Fluoranlhene

Benzidine

Pyrene

Bulylbenzylphthalate

3. 3'-0ichlorobenzidme

Benzo<a)Anihracene

bis<2-6thylhexy,}Phthatate

Chrysene

DJ-n-Ociyl Phihalale

Benzo<b)Ftuoranihene

Benzo^Huoranihene

Benzo<a)Pyrene

lndeno<1, 2. 3-cd|Pyrene

Oibenz(a. h)Anthraccne

Benro/n h ilPo'-"!"""

ug/l orîg/(CirciSui

SJ£O u-

L^JS?\6^ba-eo^0O^^C>

^>rWS

5^0

\^0

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^SD\^^yn>^0$JSt>pÔ^^y^>"0u^

^>STi^^^1?^SD^^0^nêo^S?ô;u?o »,-^ ^-?-' \

KQ^ne

iA

£nvtfonm«m«l Proi«ctiof\A^anCY. CLPS«mp(aMJnaga<nantOrftca,P.0.8o«818. Al«undri«. Virginia 22313 703/SS7-2490



CASNumber

l

••>

3

d - ...

S.

K

7

R

1

m

11

17

TI

14

1';

Ifi

17

in

iq

7f

71 .

77

71

74

7R

7fi

77

7fl

7<)

in

Compound Nama

• : --.---

FractionRT or Scan

NumbarEalimatod

Concentration<ug/l o^iflg/kg^

§

^-Y

V7<

)^^-

01|

^ (^S

/')-^ -irp'^^a^y^Tv

s-

mr~-1\- o

^ g

___

v^^^^^^-'

L<! <c0- Q-

<I

LU LD

<C "

<

II—

_J

=3

gs

y^^^ry^^T

/^ ^

// s-

m ( /s/7~^^ l^ cy7

:?^' \^7yc

) • :s n^<^^g s-

0 <

X

®C

T^ ^

?3A -:

—i—

——

——

——

——

F0

WANT I TAT I ON REPORT FILE: EPAVOA1717

^ATA: EPAVOA17:7.TI)8/18/84 21:23:00iAMPLE: 77113-BLANKSUBMITTED BY: USTCO ANALYST: RJH

•.MOUNT=AREA(HGHT) •» REF. AMNT/(REF. AREA(HGHT)•» RESP.FACT)•;ESP. FAC. FROM AVERAGE OF WHOLE .RL

NAME•»»»

HSLHSL

HSLHSLHSL

HSLHSLHSLHSL

BROMOCHLORMETHANE (INTERAL STANDARD)P-D:FHJOROBENZENE (INTERNAL STANDARD)DICHLOROBENZENE-D5 (INTERNAL STANDARD)CHLOROMETHANEBROMOMETHANEVINYL CHLORIDECHLOROETHANEME1HYLENE CHLORIDEACROLEINACRYLGNITRILE1,1-DICHLOROETHYLENE1.1-DICHLOROETHANETRANS-1,2-DICHLOROETHYLENECHLOROFORM1.2-DICHLOROETHANEI,1,I-TRICHLOROETHANEACE I ONECARBON DISULFIDECARBON TETRACHLORIDEBROMODICHLOROMETHANE1 , 2-DICHLOROPROPAIMETRANS-1,3-DICHLOROPROPYLENETRICHLOROETHYLENEBENZENEDIBROKOCHLOROMETHANE1,1,2-TRICHLOROETHANECIS-1,3-DICHLOROPROPYLENE2-CHLOROETHYL VINYL ETHERBROMOFORMMETHYL ETHYL KETONEVINYL ACETATEMETHYL .ISOBUTYL KETONE1,2-DICHLOROETHANE-D4 (SURROGATE)QENZENE-D6 (SURROGATE)DIBROMOTETRAFLUOROETHANE (SURROGATE)BIS(PERFLUOROISOPROPYL)KETONE (SURROGATE)FLUOROBENZENE (SURROGATE)TETRACHLOROETHYLENE1,1,2,2-TETRACHLOROETHANETOLUENECHLOROBENZENE .ETHYLBENZENE2-HEXANONESTYRENE0-XYLENEM-XYLENE

NO47484950

NO .1234567

NAM


E • •:- - M-BF

D-5TOU.P-BF

SCAN384699857


TOMOETH

JENEWHO

T132329

BENZYLBE-D8FLUO

I ME075317

OTRIFNZENE(SURRROBEN

REFI23

LUORI(SUR

OGATEZ.ENE

RRT1. 0001. 0001. 000

DEROG>(SU

MAAA

(SUFtROGAATE)

RROGATE)

ETHBBBBBB

TE)

AREA(HGHT)107878.440907.284791.

AMOUNT 7.TOT50.000 UG/L 9.6650.000 UG/L 9.6650.000 UG/L 9. 66

NO89

101112131415161718192021222324252627282930313233343536373839WU1-3435.4-5-6:7•'BW;0

M/ENOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

6584


SCANFOUND-FOUNDFOUNDFOUNDFOUNDFOUNDPOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

468617

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

8151036

TIME

15: 5921.05

27: 5135:24

REF

22

33

RRT

0. 6700.883.

0. 9511. 209

METH

A SBA BB

A BEA BB

A R E A ( H G H T )

379961.748701.

808970.491932.

AMOUNT

90.413 UG/L88.130 UG/L

100.295 UG/L88.741 UG/L

7.TOT

17. 4717. 03

19. 3817. 15

i. ; • 2 0 0

SCANS 1 TO 2809RIC DATA; EPABN1352 #1CALI: EPABN1352 #109/16/-84 22:36:08

SAMPLE; BLANK ABNCONDS.;RANGE; G 1-2800 LABEL; N 2, 2.0 QUAN: A 2- 3.0 J 8 BASE: U 26- 3

s S

5007:55

100015:50

150023:45

200031:40

250039:35

QUANTiTATION REPORT FILE: EPABN1352

DATA: EPABN1352.TI09/16/84 22:36:00SAMPLE: BLANK ABNSUBMITTED BY: ANALYST:

AMOUNT-AREA(HQHT) ». REF. AMNT/<REF.AREA(HGKT>» RESP.FACT)RESP. FAC. FROM AVERAGE OF WHOLE . R L

40 NAME1 •2 »3 »4 »5 •6 •

HSLHSL

37 HSL38 HSL39 HSL40 HSL41 HSL

D-4 1.4-DICHLOROBENZENED-8 NAPHTHALENE . . . . . . . . .6-8 ACENAPTHENED-10 PHENAN1HRENED-12 CHRYSENED-12 PERYLENF2-FLUOROPHENOL (SURROGATE)D-5 PHENOL (SURROGATE)D-5 NITROBENZENE (SURROGATE)2-FLUOROBIPHENYL (SURROGATE)2,4,6-TRIBROMOPHENOL (SURROGATt)D-14 TERPHENYL (SURROGATfc.)N-NITROSODIMETHYLAMINb2-CHLOROPHENOLPHENOLBIS (2-CHLOROETHYL) ElH£R1.3-DICHLOROBENZENE1.4-DICHLOROBENZENE1,2-DICHLOROBENZENEANILINE.BENZYL ALCOHOLBIS(2-CHLOROISOPROPYL)ETHERHEXACHI. OROETHANEN-NITROSODIPROPYLAMINENITROBENZENEISOPHORONE2-NITROPHENOL2.4-DIMETHYLPHENOLBIS(2-CHLOROETHOXY)METHANE2,4-DICHLOROPHENOL1,2,4-TRICHLOROBENZEN&NAPHTHALENEHEXACHLOROBUTADIENEP-CHLORO-M-CRESOL

HEXACHLOROCYCLOPENTADIENfc2,4,6-TRICHLOROPHENOL2-METHYLPHENOL4-METHYLPHENOLBENZOIC ACID4-C HLOR OANILINE2-METHYLNAPH1HALENE2-CHLORONAPHTHALENEDIMETHYL PHTHALATEACENAPHTHYLENE2,6-DINITROTOLUENEACENAPHTHENE

NO NAME47 2, 4-DINITROPHENOL48 4-NITROPHENOL49 2,4-DINITROTOLUENE50 FLUORENE

.51 - „ - ...4-CHLOROPHENYLPHENYL ETHER52 DIETHYL PHTHALATE53 4,6-DINITRO-2-METHYLPHENOL54 N-NITROSODIPHENYLAMIME55 1,2-DIPHENYLHYDRAZINE-56 4-BROMOPHENYL PHENYL ETH6R57 HEXACHLOROBENZENE .58 PENTACHLOROPHENOL59 PHENANTHRENE60 ANTHRACENE61 Dr-N-BUTYL PHTHALATE62 FLUORANTHENE63 HSL 2-4, 5-TRrCHLOROPHENOL .64 HSL 2 NITROANILINE65 HSL 3-NITROANILINE66 HSL DIBENZOFURAN67-HSL---4-^^•TROAI]<^LINE68 BENZIDINE69 PYRENE70 BENZYL BUTYL PHTHALATE71 BENZOCA)ANTHRACENE72 3.3'-DICHLOROBENZIDIN£73 CHRYSENE74 -B-IS-C2-ETHYLHEXYL) PHTHALATE75 DI-N-OCTYL PHTHALATE76 BENZO < B > FLUORANTHENE77 BENZO(K)FLUORANTHENE78 BENZO<A)PYRENE79 INDENOd. 2, 3-CD?PYRENF80 DIBENZO<A,H»ANTHRACENE81 BENZO<GHI>PERYLENE

NO M/E SCAN TIME REF RRT KFTH AREA(HSHT) AMOUNT 7.TOT

NO M/E SCAN TIME REF RRT MFTH AREA(HSHT) AMOUNT XTOT1 152 702 11 07 I 1.000 A BB 29547. 40.000 US/MI. 4.602 136 942 14 55 2 1.000 A BB 68417. 40.000 UG/ML 4.603 164 1279 20 15 3 1.000 A BB 8248. 40.000 UG/ML 4.604 188 1558 24 40 4 1.000 A BB 63272. 40.000 US/ML 4.605 240 2064 .32 41 5 1.000 A B B 31?97. 40.000 UG/ML 4.606 264 2318 36 42 6 1.000 A BB 19608. 40. 000 UQ/ML 4.607 112 483 7 39 1 0.688 A BV 71371. 89.408 U8/ML 10.278 99 675 10 41 1 0.962 A BB 73400. 77. 941 UG/ML 8.959 82 819 12 58 2 0.869 A SB 91124. 97.434 UG/ML 11.19

10 172 1162 18 24 3 0.909 A BB 157194. 112.693 UG/ML 12.9511 330 1434 S3 42 3 1.121 A BV 6864; 92. 135 UG/ML 10.5912 241 1877 29 43 5 0.909 A 3B 77955. 62.312 UG/ML 7.1613 NOT FOUND . . . .—14 NOT FOUND CV15 NOT FOUND16 NOT FOUND ,,17 NOT FOUND ••Ifl 1/IA •7ns 1-1 • i n 1 1 r^La—-ff--Pff————————-372-——————0. 240 UG/l-iL——0-OT~~ "-19 NOT FOUND 020 NOT FOUND21 NOT FOUND — — - - — -22 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND ________________ ______26-——83-——S6^——fJ: 4 5 2 0 . 923——ff»VB——————-4190.——————i—OSa- UG/I'lL:——0. 12——•—27 NOT FOUND28 NOT FOUND ..29 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND" '34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND43 NOT FOUND .49 NOT FOUND50 NOT FOUND51 NOT FOUND52 NOT FOUND53 NOT FOUND54 NOT FOUND55 NOT FOUND56 NOT FOUND

t

NO M/E SCAN TIME REf- RRT METH AREA(HSHT) AMOUNT 7.TOT57 NOT FOUND58 NOT FOUND59 NOT FOUND60 NOT FOUND61 NOT FOUND :62 NOT FOUND63 NOT POUND64 NOT FOUND65 NOT FOUND66 NOT FOUND

69 NOT FOUND i"i i70 NOT FOUND71 NOT FOUND • ' . . "72 NOT FOUND73 NOT FOUND '-\;74 NOT FOUND C-75 NOT FOUND 076 NOT FOUND77 NOT FOUND78 NOT FOUND79 NOT FOUNDSO NOT FOUND81 NOT FOUND

^

DUAL MASS SPECTRUM09/-16/'84 22; 35; 08 + 11:16SAMPLE! BLANK ABNCONDS.!ENHANCED (S 15B 2N 0T>

OftTA; EPABN1352 ft705CALI; EPABN1352 #1

BASE n/E: 57/ 150RIC: 30e..'- 15983.

0 0 2

DUAL MASS SPECTRUM09/16/-84 22s 36:00 + 13:4SSAMPLE; BLANK ABNCONDS.:ENHANCED <S 158 2N 0T>

DATA! £PABN1352 #869 BASE ri/E; 54/ 82CALI; EPABN1352 til RIC; 22. / 253.

55 6@ £5 78 75 80- I , , , . 1 , . , . I , . , , I , , , , I . , , . 1

DUAL MASS SPECTRUM09/16/84 22;3£:00 + 29-.43SAMPLE:. BLW ABN ,.CONDS.; 'ENHANCED <S 15B 2N 8T>

DATA; EPABN1352 i»1877 BASE M/E: 244/ 244CALI: EPABH1352 #1 RIC; 83S39./ 101563.

r 23008.

i l• , r ^ - 1' 'i "100

r^U^^ ^..^t ,T»J7l . 'i, ^f^it ^j -.<^^

Environments! Proleclion Agency. ' CLP Sample Management Office.P.0.fio«8)8. Alexandria. Virginia 22313 703/557-2490

Organics Analysis Data Sheet.(Pagel)

Sample Number

Û^-vJi-'P^^

Laboraiory Name: f^ ' ' -n rY>

Lab Sample ID No: _ "7 7 f I a) - &1 .1^

Sample Matrix:.

CaseNo: ^-(^-(^0

SmTQC Repon No:

Contract No:

. Data Release Authorized By: Date Sample Received: 6 I 1 ^ ! m

Volatile Compounds

Concentration: (Low) Medium (Circle One)

Date Arialyrpri- ..?i,/n, j

1 1 '

Percfnt Moisture' -

^• . /

pH 7.0

Percent Moisture (Decanted):

CASNumber

74-87-3

74-83-9

75-01-4

75-00-3

75-09-2

67-64-1

75-15-0

75-35-4

75-34-3

156-60-5

67-66-3

107-06-2

78-93-3

71-55-6

56-23-5

108-05-4

75-27-4

Chloromethane

Bromomethane

Vinyl Chloride

Chloroelhane

Mathylene Chloride

Acetone

Carbon Oisuldde

1, 1-Dichloroethene

1, 1-Dichloroeihane

Trans-1. 2-Oichloroeihene '

Chloroform

1 , 2-Dichloroflthane

2-Butanone

1 . 1 . 1-Trichloroelhane


Vinyl Acelate


ug/lori^r(CirdaC

/ O LA.

/o/o/o-</os<,5"

-HGi b5^/OS' >

/Kg

li/

CASNumber

79-34-5

78-87-5

10061-02-6

79-01-6

124.48-1

79-00-5

71,43-2..

10061-01-5

110-75-8

75.25-2

591-78-6

1 0 8 - 1 0 - 1

1 2 7 - 1 8 - 4

108-88.3

108-90-7

100-41-4

100-42-5

1 , 1 . 2 , 2-Teirachloroethane

\. 2-Dichloropropane

Trans-l, 3-Dichloropropene

Trichloroethene

Dibforriochloromelhane

1 , 1 . 2-Trichtoroethane

Benzene

cis -1 , 3-Dichloroprop^ne

2-ChloroethylvinYlelher

Bromoform

2-Hexanone

4-Melhyl-2-Penianone

Tetrachloroelhene

Toluene

Chlorobenzene

Ethyl benzene

Slyrene

Toâl Xylenes

ug/t or iw(Circlet

'S'^t—

'^\

- ^ - -&

•S

^

-^-

/ 0

£'/O!Â^^S-5S-^

/^We)

/

D«t* flflporting Qua liters

Fof repoflinQ reiuitt 10 EPA, tha following results qualif'ers •r<

Addmonal flags or fooinoies«Kpl«ining fesi

dflfindion of •«ch flag must t— axJilioi

Valu* rt Ihe resurt it • value gr««ter irrn or ftqual 10 t^«

detection limil. r«po<1 irr vlu«

U Irtdicfllci cofTipound wat •nalyred for but nol d«i«cted

R«oo<i iht minimum d<l<cnon tifrni (r>f the w-npK wiih

(n» U <e.o.. 10U) txi»«l on rmcctwry concen (ration/

dilution •Cttoni, fThit 1C noi necetunly ih« incirufn«ni

d«tl«K:lion limit .) The (ootno(« »ho<Jk3 read. U-

Compound «v«C •nalyfd for but noi d«i»ci«d The

"umfaflf i« Irw minimum an«in«bl« 0«i«ction limit «o*

lit* &«mpl«

iitirnaied v«lu« Thif flag n LIndicitf •nwti^n »T..^

C In's tlao npplies 10 pesnc<d« p*ifam«><ar» w+^fe lh«

ideniidcaiion ITS b«an cor'firm<d bv GC/MS Singit

comporient pesiiCidti^lO ng/ul m the final Brtraci

should tK conl.ffTiBd by GC/MS

6 this 1iag is uiw3 wtien lha analvie i» found in ihfl blank

as well «s J tamole H indicales Dossible/pfobabit

blank coniamrnaiion aod wtfris Ihe data user to take

Bpp(ociiaie action

Oth«r 0<htr sptCifiC flags arKi looinolfls may be fffq"11'®^ 'o

piope'-'y delinc ir>e rsuttS M UWKJ. <h»v muH b« fully

Ocsct'fawd and such oetcnpiion BnachaO 10 th« ABta

EnvKonJn«nu( Protection Agency, CLP Sflmple M«nagern«nt On>c«.P.O.B«818. AI«K<ndrn.Virg>nr22313 703/557.2490



CASNumbar

1

7

3

4.

*>

6

7

a1

10

n

17

13. ,

14

15

1 6

17

1 R

19

20

7-1-

22

23

24

2S

2fi

27

?R

71)

30

Compound Name

. ; ... ..-..-

FractionRT or Scan

NumborEstimated

Concentration^(ug/1 opCg/kgi^

0>'

(.V;

0

i'Y-^

-W -w

m^L

CO

-, /^^-^

f^^^l^

w^©

•-W^^^

o \

'

^

.^pT

rT-'ir^^si

-4^3

1 'T

n^J

'--

"—'/,

enI

1 L

Cl-

^^

(y^

ir ^

1 ^n

/,

''~r

-<p^^?^

©S

C

O0

—I

CT

• .. CD

nr^.

i T-4

G) n

•• T

^

f-<

CO •rt1

-r^-

oS

...."\

LJ

• ..

(n —i in

UJ

•^o

-o

o

Q^

<S* L

t'l O Q

^

iUANTITATION REPORT FILE: EPAVOA1724

WTA: EPAVOA1724.TI :^8/19/84 8:07:00iAMPLE: 77113-BLANKiUBMITTEn BY^. USTCO ANALYST: RJM . . . . .

»MOUNT=AREA * REF.AMNT/(REF.AREA)* RESP.FACT);ESP. FAC. FROM AVERAGE OF WHOLE .RL

NO NAME1 * BROMOCHLORtlETHANE (INTERAL STANDARD)2 * P-DIFLUOROSENZENE (INTERNAL STANDARD)3 * DICHLOROBENZENE-D5 (INTERNAL STANDARD)4 CHLOROMETHANE5 BROMOMETHANE6 VINYL CHLORIDE7 CHLOROETHANE8 METHYLENE CHLORIDE9 ACROLEIN

10 ACRYLONITRILE

1 1 1,1-DICHLOROETHYLENE12 1,1-DICHLOROETHANE13 TRANS-1,2-DICHLOROETHYLE^E14 CHLOROFORM15 1,2-DICHLOROETHANE16 1,I,1-TRICHLOROETHANE17 HSL ACETONE18 HSL CARBON DISULFIDE.19 CARBON TETRACHLORIDE20 BROMODICHLOROMETHANE21 1,2-DICHLOROPROPANE22 TRANS-1,3-DICHLOROPROPYLENE23 ' TRICHLOROETHYLENE24 BENZENE25 DIBROMOCHLOROMETHANE26 1,I,2-TRICHLOROETHANE27 CIS-1,3-DICHLOROPROPYLENE28 2-CHLOROETHYL VINYL ETHER29 BROMOFORK30 HSL METHYL ETHYL KE'l ONE31 HSL VINYL ACE1ATE32 •HSL • METHYL -ISOBUTYL KETONE"33 I,2-DICHLOROETHANE-D4 (SURROGATE)34 BENZENE-D6 (SURROGATE)35 DIBROMOTETRAFLUOROETHANE (SURROGATE)36 BIS(PERFLUOROISOPROPYL)KETONE (SURROGATE)37 FLUOROBENZENE (SURROGATE)38 TETRACHLOROETHYLENE39 1,1,2,2-TETRACHLOROETHANE40 TOLUENE

41 CHLOROEENZENE42 ETHYLEENZENE43 HSL 2-HEXANONE44 HSL STYRENE45 HSL 0-XYLENEt& HSL M-XYLENE

NO47484950

N01334567

NAM(


M-BRD-5TOLUP-BR

SCAN384&99858


OMOBENZETHYLBEENE-D8OMO.FLUC

TIME13 0733 5329 19

^OTRI:NZEN

(5UR1ROBE

REF123

FLLE (ROGNZE

1.1.1.

JORIDESURRC

;ATE >:NE .(S

PRT000000000

E (SURROGATE)3GATE)

SURROGATE)

METH AREA(HGHT)A BB 97489.A BB 412319.A BE 370291.

AMOUNT50. 00050.00050.000

UG/LUG/LUQ/L

7.T9.9.9.

roT616161

NU

89

101112131415161718'192021222324252637282930313233343536373839404142tS4445^6\7485.950

M/ENOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOTNOT

6584


.- a<;AN- - T-IM&-FOUND .FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

469 16:01618 21:07

FOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUNDFOUND

816 27:531035 35:22

REF-

22 .

33

——RRT-

0. 6710,884

0. 9511. 206

—M&t+t-———

A BBA BB ..

A BBA BB

—ARtAt H G H T 1 ~ '

362227..718271.

763931.463798.

AMOUNT

92.170 UG/L90-.4.10 UG/L

99. 792 UG/L88.154 UG/L

Y.TOJ

17. 711-7. 37

19. 1716;. 94

CASE NO. 3089: SAMPLE NO.'S F4132, F4133, F4229 AND ...Environmental Prelection Agency. CLP Sample...

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Transcript of CASE NO. 3089: SAMPLE NO.'S F4132, F4133, F4229 AND ...Environmental Prelection Agency. CLP Sample...