Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol...

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Carbonyl condensation reactions

Transcript of Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol...

Page 1: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Carbonyl condensation

reactions

Page 2: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Aldol reaction: step 1

Page 3: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 4: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Aldol reaction: step 2

Page 5: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 6: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Claisen reaction

Page 7: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 8: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Michael reaction

Page 9: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 10: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Robinson annulation

Page 11: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 12: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Directed aldol reaction: step 1

Page 13: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 14: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Directed aldol reaction: step 2

Page 15: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 16: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Intramolecular aldol reaction

With 1,4-dicarbonyl compounds

Page 17: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 18: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Intramolecular aldol reaction

With 1,5-dicarbonyl compounds

Page 19: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 20: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Dieckmann reaction

With 1,6-diesters

Page 21: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.
Page 22: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

Dieckmann reaction

With 1,7-diesters

Page 23: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds.

II. Special Topics IIA. Enolate Chemistry & the Aldol Reactionccc.chem.pitt.edu/wipf/Courses//2320_06-files/IIA_Aldol.pdfClaisen-Schmidt reaction. A crossed aldol condensation in which

II. Special Topics IIA. Enolate Chemistry & the Aldol Reactionccc.chem.pitt.edu/wipf/Courses//2320_06-files/IIA_Aldol.pdfClaisen-Schmidt reaction. A crossed aldol condensation in which

Titelei 210v2 1. - Thieme...and procedures used for enzymatic C-C bond formation by aldol reaction. These include the asymmetric catalytic aldol additions of dihydroxyacetone phosphate

Titelei 210v2 1. - Thieme...and procedures used for enzymatic C-C bond formation by aldol reaction. These include the asymmetric catalytic aldol additions of dihydroxyacetone phosphate

Stereoselective, Directed Aldol Reaction

Stereoselective, Directed Aldol Reaction

Myers Stereoselective, Directed Aldol Reaction Chem 115 · 2014-02-24 · Myers Stereoselective, Directed Aldol Reaction Chem 115 M. Movassaghi Evans, D. A.; Takacs, J. M.; McGee,

Myers Stereoselective, Directed Aldol Reaction Chem 115 · 2014-02-24 · Myers Stereoselective, Directed Aldol Reaction Chem 115 M. Movassaghi Evans, D. A.; Takacs, J. M.; McGee,

Mukaiyama Aldol Reaction TheMukaiyamaAldolReaction:40 ...tional aldol reactions use a Brønsted base or an acid as the promoter in protic solvents, and consequently, suffer from the

Mukaiyama Aldol Reaction TheMukaiyamaAldolReaction:40 ...tional aldol reactions use a Brønsted base or an acid as the promoter in protic solvents, and consequently, suffer from the

Recent Advances on Asymmetric Nitroso Aldol Reaction · Recent Advances on Asymmetric Nitroso Aldol Reaction Pedro Merino,*a Tomás Tejero,a Ignacio Delsoa,b and Rosa Matutec a Laboratorio

Recent Advances on Asymmetric Nitroso Aldol Reaction · Recent Advances on Asymmetric Nitroso Aldol Reaction Pedro Merino,*a Tomás Tejero,a Ignacio Delsoa,b and Rosa Matutec a Laboratorio

Aldol Reaction Time-Linechemlabs.princeton.edu/.../sites/6/Northrup_aldol.pdf2 Racemic Aldol Technology Aldol Reaction Discovered Independently By Charles Adolphe Wurtz in Germany

Aldol Reaction Time-Linechemlabs.princeton.edu/.../sites/6/Northrup_aldol.pdf2 Racemic Aldol Technology Aldol Reaction Discovered Independently By Charles Adolphe Wurtz in Germany

2. Reaction of Carbon Nucleophile with Carbonyl Group

2. Reaction of Carbon Nucleophile with Carbonyl Group

Aldol reaction & condensation project work for Presentation by EducationBhaskar.com

Aldol reaction & condensation project work for Presentation by EducationBhaskar.com

Current Organocatalysis, 2015, 2, Organocatalysis in the ......Keywords: 1,4-conjugated addition, aldol reaction, asymmetric synthesis, enamine-activation, mannich reaction, natural

Current Organocatalysis, 2015, 2, Organocatalysis in the ......Keywords: 1,4-conjugated addition, aldol reaction, asymmetric synthesis, enamine-activation, mannich reaction, natural

The Aldol Reaction - Chemistry | A&S | SUchemistry.syr.edu/totah/che676/support/3b1/8-1.Aldol.pdfThe Aldol Reaction General Principles ! !! - Reaction can be effected under acidic

The Aldol Reaction - Chemistry | A&S | SUchemistry.syr.edu/totah/che676/support/3b1/8-1.Aldol.pdfThe Aldol Reaction General Principles ! !! - Reaction can be effected under acidic

14.3 Aldol Reaction and Claisen Condensation in Biology Enol – Keto Tautomerization Aldol Reaction Claisen Condensation Main Menu.

14.3 Aldol Reaction and Claisen Condensation in Biology Enol – Keto Tautomerization Aldol Reaction Claisen Condensation Main Menu.

An efficient catalyst-free Mukaiyama-aldol reaction …1 An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin Fu-Min Liao,† Yun-Lin

An efficient catalyst-free Mukaiyama-aldol reaction …1 An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin Fu-Min Liao,† Yun-Lin

Carboligation using the aldol reaction - uu.diva-portal.orguu.diva-portal.org/smash/get/diva2:1255080/FULLTEXT01.pdf · Aldol compounds can be produced either synthetically or in

Carboligation using the aldol reaction - uu.diva-portal.orguu.diva-portal.org/smash/get/diva2:1255080/FULLTEXT01.pdf · Aldol compounds can be produced either synthetically or in

Copper(I)-Catalyzed Enatio- and Diastereoselctive Tandem Reductive Aldol Reaction

Copper(I)-Catalyzed Enatio- and Diastereoselctive Tandem Reductive Aldol Reaction

A Tripeptide-like Prolinamide-Thiourea as an Aldol ... · A Tripeptide-like Prolinamide-Thiourea as an Aldol Reaction Catalyst S. Fotaras, C. G. Kokotos and G. Kokotos* Laboratory

A Tripeptide-like Prolinamide-Thiourea as an Aldol ... · A Tripeptide-like Prolinamide-Thiourea as an Aldol Reaction Catalyst S. Fotaras, C. G. Kokotos and G. Kokotos* Laboratory

Chiral Benzimidazoles as Hydrogen Bonding Organocatalysts · organocatalysts in aldol and amination reactions of carbonyl compounds. 1. Introduction Benzimidazole, firstly described

Chiral Benzimidazoles as Hydrogen Bonding Organocatalysts · organocatalysts in aldol and amination reactions of carbonyl compounds. 1. Introduction Benzimidazole, firstly described

Application of Oxazolines in Asymmetric Aldol Reaction …shodhganga.inflibnet.ac.in/bitstream/10603/36788/10/10_chepter 3.pdf · Application of Oxazolines in Asymmetric Aldol Reaction

Application of Oxazolines in Asymmetric Aldol Reaction …shodhganga.inflibnet.ac.in/bitstream/10603/36788/10/10_chepter 3.pdf · Application of Oxazolines in Asymmetric Aldol Reaction

α-Carbonyl Nucleophilesstaffnew.uny.ac.id/upload/132162017/pendidikan/KO+II.+Kondensasi+aldol.pdf1 α-Carbonyl Nucleophiles Michael and Stork reactions Aldol condensation Claisen

α-Carbonyl Nucleophilesstaffnew.uny.ac.id/upload/132162017/pendidikan/KO+II.+Kondensasi+aldol.pdf1 α-Carbonyl Nucleophiles Michael and Stork reactions Aldol condensation Claisen

CARBONYL COMPOUNDS€¦ · • Carbonyl compounds react with alcohols. The product of this reaction is known as a hemiacetal, because it is halfway to an acetal. This reaction is

CARBONYL COMPOUNDS€¦ · • Carbonyl compounds react with alcohols. The product of this reaction is known as a hemiacetal, because it is halfway to an acetal. This reaction is