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vi, mol

C2H4(g) -1 52510 -52510

H2O(g) -1 -241818 241818

C2H6O(g) 1 -235100 -235100

-45792  ∆A =

∆rH°m R( J/Mol!) ∆H°/R " (°!) l# " - ∆$(")

-45792 8%314 -5507%8181380804 298%15 5%6975967156 410%2544

vi, mol

C2H4(g) -1 68460 -68460

H2O(g) -1 -228572 228572

C2H6O(g) 1 -168490 -168490

-8378

∆r&°m R( J/Mol!) " (°!) R" - ∆$(l#") - (∆'")/2

-8378 8%314 298%15 2478%8191 7%8398930806 -0%619704775

(-)J/R R( J/Mol!) " (°!) R" ∆$(l#") (∆'")/2

17%8054292502 8%314 298%15 2478%8191 -7%8398930806 0%619704775

" (°!) l# ! ! ∆r&°m ∆rH°m ξ

330 1%5950183336 4%9284194268 -4376%1242003259 -45885%295270893 0%9078921578

338%7 1%1649798249 3%205858204 -3280%527034892 -45904%139937224 0%8650784859

347%3 0%7608920075 2%1401844298 -2197%0393009305 -45920%474371391 0%8106192907

356 0%3718365357 1%450395874 -1100%5558290742 -45934%747647363 0%7436417875

358%1 0%2804858165 1%3237727668 -835%0745460355 -45937%098250822 0%7258430386

360%3 0%1859362056 1%2043454274 -556%9782628495 -45939%469562353 0%7066322402

C2H

4(g) H

2O(g)

∆* H°m JMol-1 vi ∆

* H°m JMol-1

  ∆r H°(298%15°!,(g)) +

∆* &°m JMol-1 vi ∆

* &°m JMol-1

  ∆r &°(298%15°!,(g)) +

325 330 335 340 345 350 355 360 3

0.6

0.65

0.7

0.75

0.8

0.85

0.9

0.95

 

ξ

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T (°K)

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$

1%424 0%014394 -0%000004392

3%47 0%00145 0

3%518 0%020001 -0%000006002

-1%376 ∆' + 0%004157 ∆C + -0%00000161

 - (∆'"2)/2 - (∆C"3)/3 ∆/" J/R J

-184%7649786663 14%2235846695 -40%5835988596 -5308%6887309367 -44136%438109008

.0 mol/ 163

C0 !mol/m3 9%3

1(-1) 0%004

"1 (!) 600

(J/mol) 12141

 - (∆C"2)/6 -∆/(2"2) J (-∆r&°m J)/R"

0%0238530684 0%0680590288 -44136%4381090078 -14%4255940698 -7%113493667

 (∆C"2)/6 ∆/(2"2 - J l# !  

-0%0238530684 -0%0680590288 44136%4381090078 -7%113493667 3%3798351804

k (h^-1)   (-r) mol/m .0/-r (m3) C"R (m3)

0%0005460555 0 0%0050783164 32097%2518286625 0

0%0006117892 0%1 0%0049431989 32974%59857799 3297%459857799

0%0006807201 0%2 0%0044729547 36441%2362940714 7288%2472588143

0%0007543886 0%3 0%0034599183 47110%9386528966 14133%281595869

0%0007727556 0%4 0%0021404172 76153%3778735309 30461%3511494124

0%0007922388 0%5 0%0006250617 260774%25055332 130387%12527666

C2H

6O(g)

' (10-3) C (10-6)

5

Discución:Ls si!ui"n#"s $%#s ns &"'i#"n s%c%' %s si!ui"n#"s cncusin"s

1. *s un% '"%cción +u" s" $"s&%,% % s &'$uc#s % +u" "n"'!i% $" '"

n"!%#i%2.L% '"%cción &'"s"n#" "s un% '"%cción "#"'ic% % +u" "n#%&i% $" '3. n'" %u"n#% % #"&"'%#u'% % cns#%n#" c $isinu" (" "+u'"%c#is).4.- n% % $" c&'/%' +u" % '"%cción "s "#"'ic% "s i"n$ %&'"s"n#".5.- Ls %'"s /#"ni$s &%'% k % 600 u"'n /#"ni$s "$i%n#" "h##&:"%hch"is#'.c+u"s#ins$"#"'in"-'%#"-%-in#"!'%#"$-'%#"cns#%n#-$"h$'%#in-"#h%n

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4 2 (-)R" R( J/Mol!) ∆$(")

116%8709498918 11%8568388535 -2743%62 8%314 -454%08

53%9335401139 8%4117164081 -2815%9518 8%314 -466%0512

26%8822952934 6%2803688596 -2887%4522 8%314 -477%8848

14%2161762615 4%900791748 -2959%784 8%314 -489%856

12%3045884201 4%6475455337 -2977%2434 8%314 -492%7456

10%6191733438 4%4086908548 -2995%5342 8%314 -495%7728

H/3 3/8H .()

0%05 65071%8504066525

0%0333333333 200436%882434694

0%0375 287455%695097743

0%0333333333 501475%251213883

0%0333333333 838402%879640734

0.4 0.5

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 (∆'"2)/2 (∆C"3)/3 (-)∆/" J J/R    ∆A

226%34865 -19%28619 36%6666666667 -44136%43811 -5308%6887310561 -1%376

238%440718665 -20%8521197936 35%7248302332 -44135%43811 -5308%5684520087 -1%376

250%703037265 -22%4811731851 34%8401957961 -44134%43811 -5308%4481729613 -1%376

263%420776 -24%2133352533 33%9887640449 -44133%43811 -5308%3278939139 -1%376

266%537715385 -24%644362275 33%7894442893 -44132%43811 -5308%2076148665 -1%376

269%822743065 -25%1013689785 33%5831251735 -44131%43811 -5308%0873358191 -1%376

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 ∆ ∆ ∆D ∆$(l#") (∆'")/2 (∆C"2)/6

0%004157 -0%00000161 -12100 -7%9795514925 0%685905 -0%0292215

0%004157 -0%00000161 -12100 -8%0153579095 0%70398795 -0%0307825802

0%004157 -0%00000161 -12100 -8%0498600086 0%72186305 -0%0323656395

0%004157 -0%00000161 -12100 -8%0839046857 0%739946 -0%0340074933

0%004157 -0%00000161 -12100 -8%0919976932 0%74431085 -0%0344098887

0%004157 -0%00000161 -12100 -8%1004253364 0%74888355 -0%0348339842

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 ∆/(2"2) R" :M$

-0%0555555556 -7%113493667 2743%62 -14%4919172151

-0%052738161 -7%113493667 2815%9518 -14%5083843676

-0%0501586464 -7%113493667 2887%4522 -14%5240149115

-0%0477370282 -7%113493667 2959%784 -14%5391968741

-0%0471787829 -7%113493667 2977%2434 -14%5427691817

-0%0466043924 -7%113493667 2995%5342 -14%54647383

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