c 002 Solvent

May 30,2014Product Name：C-002 SOLVENT Update Date： 21900302Number：

Mar 01,2014

Solvent for printing ink

Material Safety Data SheetMay 30,2014Update date：

Create Date：

1.PRODUCT AND COMPANY IDENTIFICATION

C-002 SOLVENTPRODUCT NAME

Teikoku printing Inks Mfg.Co.,Ltd.COMPANY IDENTIFICATION

8-43-2 Nishi-Ogu,Arakawa-Ku,Tokyo 116-0011,Japan ADDRESS

THE LABORATORY OFFICE. MANUFACTURER'S NAME

＋81-3-3800-9911 TELEPHONE NUMBER FORINFORMATION

＋81-3-3800-9919 FAX NUMBER FOR INFORMATION

[email protected] MAIL ADDRESS

+81-3-3800-6760（THE LABORATORY OFFICE.) EMERGENCY TELEPHONE NUMBER

Solvent for printing ink.RECOMMENDED USES ANDRESTRICTIONS ON USE

21900302NUMBER

2.HAZARDS IDENTIFICATION(GHS CLASSIFICATION)

Category 4PHYSICAL HAZARD FLAMMABLELIQUID

Category 5 ACUTE TOXICITY(Oral)

Category 5 ACUTE TOXICITY（Dermal)

Category 2 SKIN CORROSION/IRRITATION

Category 2B SERIOUS EYE DAMAGE/EYEIRRITATIONGHS LABEL ELEMENTS SYMBOL

Warning SIGNAL WORD

H227 Combustible liquid. HAZARD STATEMENT

H303 May be harmful if swallowed.

H313 May be harmful in contact with skin.

H315 Causes skin irritation.

H320 Causes eye irritation.

P210 Keep away from heat/sparks/open flames/hot surfaces. Nosmoking.

PRECAUTIONARY STATEMENTS【SAFETY PRECAUTIONARYSTATEMENTS】

P264 Wash hands thoroughly after handling.

P280 Wear protective gloves/protective clothing/eyeprotection/face protection.P312 Call a doctor if you feel unwell.【FIRST-AID PRECAUTIONARY

STATEMENTS】P302＋P352 IF ON SKIN: Wash with plenty of water.

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P304＋P340 IF INHALED: Remove person to fresh air and keepcomfortable for breathing.P305＋P351＋P338 IF IN EYES: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy todo. Continue rinsing.P332＋P313 If skin irritation occurs: Get medicaladvice/attention.P337＋P313 If eye irritation persists: Get medicaladvice/attention.P362＋P364 Take off contaminated clothing and wash it beforereuse.P370＋P378 In case of fire: Use proper fire-extinguishers toextinguish.P403＋P235 Store in a well-ventilated place. Keep cool.【STORAGE PRECAUTIONARY

STATEMENTS】P501 Dispose of contents/container in according withlocal/regional/national/international regulation.

【DISPOSAL PRECAUTIONARYSTATEMENTS】

3.COMPOSITION/INFORMATION ON INGREDIENTS

MIXTURE.SINGLE OR MIXTURE

Chemical Name Wt％ Cas No. Application of Law

Polyhydric alcohol 90.0-100.0 -

☆：Korea "Toxic Chemicals Control Law" applicable to the observational chemicals※：Industrial Safety and Health Law　Dangerous and Harmful Substances Subject to Indicate＃：Industrial Safety and Health Law　Dangerous and Harmful Substances Subject to Notify▼：Ordinance on Prevention of Organic Solvent Poisoning　First-class organic solvent▲：Ordinance on Prevention of Organic Solvent Poisoning　Second-class organic solvent△：Ordinance on Prevention of Organic Solvent Poisoning　Third-class organic solvent■：Law concerning Pollutant Release and Transfer Register Class 1 Designated ChemicalSubstances□：Law concerning Pollutant Release and Transfer Register Class 2 Designated ChemicalSubstances＊：Poisonous and Deleterious Substances Control Act Chemical Substances Subject

4.FIRST-AID MEASURES

Remove person immediately to fresh air. Keep warm andcomfortable for breathing. Immediately call a doctor.

INHALATION

Take off immediately all contaminated clothing.Wash with plentywater. Continue rinsing. If skin irritation or rash occurs: Getmedical advice/attention.

SKIN CONTACT

Immediately rinse with plenty water or warm water for 15minutes. Get medical advice/attention.

EYE CONTACT

Rinse mouth. Do NOT induce vomiting. Immediately call a doctor.INGESTION

No information is available.MOST IMPORTANTSYMPTOMS/EFFECTS

No information is available.PROTECTION OF FIRST-AIDERS

No information is available.SPECIAL NOTES TO AN ATTENDINGPHYSICIAN

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5.FIRE-FIGHTING MEASURES

Combustible liquid.SPECIFIC HAZARDS

Since combustion gas contain toxic gases such as carbonmonoxide, avoid smoke inhalation at the time of fire fighting.Use Form , Dry chemical , CO2 , proper fire-extinguishers. Donot use straight stream of water for the extinguishing media.

EXTINGUISHING METHODS ANDEXTINGUISHING MEDIA

Extinguish a fire from the windward.In case of fire in the periphery, move movable container to thesafe place immediately.Prohibit unauthorized person's entry to the periphery of thefire site.Lead unauthorized persons to the safe place.Use fire-extinguishing powder, fire-extinguishing foam, carbondioxide (CO2), and sand for fire fighting.Spray water for cooling the container.Be sure to wear suitable protective equipment (protectivegloves/eye protection/face protection, etc.) at fire fighting .

FIRE EXTINGUISHING NOTES ANDFIRE FIGHTING MEASURES

6.ACCIDENTAL RELEASE MEASURES

Evacuate personnel to safe area. Evacuate non-essentialpersonnel. Shut off all sources of ignition. No flares, smokingor flame in area. Wear proper protective equipment.

PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT, ANDEMERGENCY PROCEDURES

Do not wash away spills into sewer, watercourse or river.ENVIRONMENTAL PRECAUTIONS

For small spill, absorb spills with inert materials( e.g. drysand or earth), then place in a chemical waste containers.For large spill, dike for later disposal, cover spills withfoam, then place in a chemical waste container usingnon-sparking tools.Wipe off residual spill by using paper.

METHODS AND MATERIALS FORCONTAINMENT AND METHODS ANDMATERIALS FOR CLEANING UP

7.HANDLING AND STORAGE PRECAUTIONS

Use only outdoors or in a well-ventilated area.Do not handleuntil all safety precautions have been read and understood.Wearprotective gloves/protective clothing/eye protection/faceprotection.Keep away from heat/sparks/open flames/hot surfaces.No smoking.Use explosion-proof electrical/ventilating/lightingequipment.Use only non-sparking tools.Do not get in eyes, onskin, or on clothing. Avoid breathingdust/fume/gas/mist/vapours/spray. Wash hands thoroughly afterhandling.

HANDLING

Store locked up.Store in a well-ventilated place. Keep cool.Keepcontainer tightly closed.

STORAGE

8.EXPOSURE CONTROLS AND PERSONAL PROTECTION

Not established.CONTROL PARAMETERS

Use this product only in a totally enclosed systems or localexhaust ventilation. Make available in the work area withemergency shower and eyes washer. Ground/bond container andreceiving equipment.Use explosion-prooflectrical/ventilating/lighting equipment.Use only non-sparkingtools.Take precautionary measures against static discharge.

ENGINEERING MEASURE

Wear respiratory protection.RESPIRATORY PROTECTION

Wear eye protection/face protection.EYE PROTECTION

Wear protective gloves/protective clothing/eye protection/faceprotection.

SKIN AND BODY PROTECTION

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Wear protective gloves.HAND PROTECTION

The adsorption in the masks is exchanged at regularity or eachuse.

OTHER PROTECTION

9.PHYSICAL AND CHEMICAL PROPERTIES

Liquid.APPEARANCE (Form)

Transparent.APPEARANCE (color)

Odour of Organic Solvent.ODOUR

No information is available.pH

No information is available.MELTING POINT（℃）

No information is available.BOILING POINT(℃)

68.0FLASHPOINT(℃)

1.2-13.1 (Polyhydric Alcohol)UPPER/LOWER FLAMMABILITY OREXPLOSIVE LIMITS

No information is available.VAPOUR PRESSURE

No information is available.VAPOUR DENSITY

0.9-1.0SPECIFIC GRAVITY (RelativeDensity)

Not soluble in water.SOLUBILITY

Soluble in organic solvents.

No information is available.n-OCTANOL/WATER PARTITIONCOEFFICIENT

No information is available.AUTO-IGNITION TEMPERATURE(℃)

No information is available.DECOMPOSITION TEMPERATURE(℃)

10.STABILITY AND REACTIVITY

It stabilizes under the normal temperature.STABILITY

Strong oxidizing agents.INCOMPATIBLE MATERIALS

Heat, flames and sparks.High temperature and humidity.CONDITIONS TO AVOID

No information is available.HAZARDOUS REACTIONSOCCURRINGUNDER SPECIFIC CONDITIONS

The harmful gases such as CO and NOx.HAZARDOUS DECOMPOSITIONPRODUCTS

11.HAZARD INFORMATION

No information is available.

12.ECOLOGICAL INFORMATION

No information is available.ECOTOXICITY

No information is available.PERSISTENCE AND DEGRADABILITY

No information is available.BIOACCUMULATIVE POTENTIAL

No information is available.MOBILITY IN SOIL

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No information is available.HAZARD TO THE OZONE LAYER

13.NOTES ON DISPOSAL

Do processing such as detoxification, stabilization, andneutralization to lower hazard level as much as possible beforedisposal.

WASTE FROM RESIDUES

Disposal of container and contents must be entrusted to wastedisposer authorized by local authorities.Clean the container for recycling or appropriately dispose underthe related laws and regulations and the standard of localgovernment.

CONTAMINATED CONTAINER ANDCONTAMINATED PACKAGING

In case of disposal of empty container, remove the contentscompletely.

14.TRANSPORT INFORMATION

It is not classified in the definition.UN NUMBER

It is not classified by definition.NAME OF PRODUCT (UN PROPERSHIPPING NAME)

This product is not classified in the definition.UN CLASSIFICATION (TRANSPORTHAZARD CLASS)

It is not classified by definition.PACKING GROUP

NoMARINE POLLUTANT (Y/N)

129INDICATION NUMBER FOREXTINCTION IN JAPAN

It is necessary to retain "yellow card" at the time of transport.Do not transport with food and feed.For transportation, avoid direct sunlight, load withoutcontainer damage, corrosion, and leakage and ensure preventionof load shift.Do not load heavy goods on top of it.

PRECAUTIONS

15.REGULATORY INFORMATION

Please refers national measures that may be relevant.All materials for this product are registered in the CAS, TSCA,EINECS(ELINCS).

REGULATIONS RULE

Road Act (dangerous articles transportation on the tunnels underthe water,long tunnels and else for loading limitation)Dangerous article ship transportation and storing rule

4th group Dangerous Substance 2nd group petroleum under theJapanese Fire Defense Law.

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16.OTHER INFORMATION

1)ACGIH（2010)2)Japan society for occupational health.(2012-2013)3)ICSC CARD http//:nihs.go.jp/ICSC4)Kanagawa environmental research center date base.5)Nite incorporated administrative agency national institute oftechnology and evaluation.6)Raw material safety data sheet.7)Guideline of GHS(Japan Chemical Industry Association)8)JIS Z 7252-20099)JIS Z 7253-201210)IARC（vol.1～ 85)

REFERENCE

This information is furnished without warranty, express orimplied, except that it is accurate to the best knowledge ofTeikoku Printing Inks Mfg. Co., Ltd. It relates only to thespecific material designated herein, does not relate to use incombination with any other material or in any process. TeikokuPrinting Inks Mfg. Co., Ltd. assumes no legal responsibility foruse of or reliance upon this information.

CHANGE IN CONTENTS OFDESCRIPTION, ETC.

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c 002 Solvent

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