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SUMMARY OF AMMONIUM-NITROGEN MEASUREMENTS MADE DURING

SIX COOPERATIVE U. S.-U. S. S. R. MARr~p SURVEYS

by

Ruth Waldhauer, Albert Matte, and J. E. O'Reilly

U. S. Department of CommerceNational Oceanic and Atmospheric Administration

National Marine Fisheries ServiceNortheast Fisheries Center. Sandy Hook Laboratory

Highlands, New Jersey 07732 USA

Report No. SHL 80-16 (August 1980)

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Introducti on

During six cooperative U. S.-U. S. S. R. surveys from August 1979 to

June 1980, seawater collections were made on the continental shelf of the

U. S. from Cape Hatteras to the Gulf of Maine to determine concentrations

of nutrients, rates of primary productivity, phytoplankton biomass

(chlorophyll a), phytoplankton community structure, and other physical-

biological variables. Reported here are ammonium-nitrogen concentrations

from samples collected during these cruises. When sample processing is

completed, reports will be published describing nitrate, nitrite, urea,

ammonium, silicate, and orthophosphate distributions, interrelationships,

and their association with various physical-biological factors.

Methods

Samples for ammonium-nitrogen (NH4-N) analysis were pressure filtered

immediately after collection through glass fiber filters (Whatman GF/F,

retention D.7p) and preserved by the addition of phenol-alcohol (Degobbis,

1973) and freezing; Analyses were completed at the Sandy Hook Laboratory

within a week or two of cruise termination following the procedures of

Liddicoat et al. (1975).

Resul ts

Presented here are cruise tracks and data listings of NH4-N concentrations

for stations and depths sampled during six cooperative U. S.-U. S. S. R.

surveys:Belogorsk 79-01 .•••.••..•..• 11 August to 2 September 1979Belogorsk 79-03, Part 1.•••. 12 September to 19 September 1979

Part 11 .••. 29 September to 9 October 1979Belogorsk 79-05 ..•••...•.•.. 22 November to 28 November 1979Evrika 80-02 .....•.•.•.•.•.. 18 May to 28 May 1980Delaware 80-03 ....•.••••••.. 23 May to 12 June 1980Evrika 80-04 ..•.•.•.•••••••• 25 June to 29 June 1980

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The intent of this program is to establish seasonal nutrient baselines

which will provide the basis for a better understanding of factors

influencing the productivity of the waters of the U. S. continental shelf

from Cape Hatteras to the Gulf of Maine.

The Evrika 80-02 survey departs from the others reported here in that

it is more site-specific. Its experimental design was to make as complete

a series of physical-biological observations at as frequent intervals as

possible in waters on Georges Bank known to contain high members of larval

gadids, in order to study factors which ,contribute to larval survival and

year class success. The first four stations sampled for nutrients (12, 17,

32, and 35) were within 70.8 km. Stations 42 through 89 were located as

close as possible in a geographically fixed position from 20 to 28 May 1980.

Water sample collections for nutrient analysis were made at these last

stations twice daily at 0600 and 1100 EST. The difference between the

0600 and 1100 observations over the period sampled will be examined to

correlations with other physical and biological data concurrently collected.

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References

Degobbis, D. 1973. On the storage of seawater samples for ammonia

determination. Limno. and Oceano. 18: 146.

Liddicoat, M. I., S. Tibbits and E. I. Butler. 1975. The determination

of ammonia in seawater. Limno. and Oceano. 20: 131.

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Cruise track and station locations sampled during Belogorsk 79-01

·1·;

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i~' ""'\• ,( ,< T1.\

123

" ~.

118w

"" 117

116

115

114N

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11. AIJClJST 197~1'O 2 S[r'T[M8E:~ 1979

( AM~ONIUM CONCENTRATIONS

STATION S,'\MPI._E DEPTH CONCE~~TF::ATION(M) (u~1/l..)

1 U301 1 0.5:1.

( 1 1803 10 L ll)1 HlO[, 25

., 7"'1~._ .. ,.} ,...

2 1806 1 0 .. 852 1808 20 0.782 U310 52 inD/'4 1811 1 L 60

(.£, 1813 10 L 12I) 1815 -)', ..... :I. ;,":'• .:.0 ~'•• H5 lB16 1 0.565 18lf:J 1.1. 0 .. 825 1820 2A 0.927 1826 1 16. 6~1.., 182.8 1. ~,~ -I 77, .I. '" >oJ I7 1820,' 2:1. 0 .. 92.., 18:01 38 0.56,

11. 1837 I 1 .. 081.:1. 183') 10 B1.1. IB·4:l.

..,.., 1 .. 27~.. ..:...( 12 18-4;.~ I

0 .. 8812 IBA3 5 0.8512 18.£,4 10 1 .. 37lC' 184S 15 0,,9"714 1846 1 I.OOJ.l) IB/~8 1.2 :I." 2:1.111 1849 f7 --

- --1 .. 87

{14 18.50 24 1 .. 8716 18.51 1 0.6616 lB52 10 0,,5616 1853 20 0,,8016 18511 30 0 .. 53

( :1.6 1855 480.91

17 1856 1 0.7017 18.58 19 0.9517 18LIO A,b 0 .. 3·l }.17 lB61 93 0.031.7 1862 140 0.18

l 1.7 18632D·f.} 0.06

17 1864 496 0.1117 1865 ?nO 0.0520 1872 1 0.1220 1874 9 0.1220 1876 20 0.26

L 22 1877 I0.13

22 1879 1.:1. .0.1622 1880 llJ 0.3028 1891 I 0.11.>28 lD(?2 -'-i 0,,1528 1G?3 L'i 0 .. 17

L 2B:l.es).!.) 1'7 0,,33

28 18{?S 2A 0 .. 13

n""MJf:c'I~~G ANALy:nS, Sf.lt1F'LE TUDE Bf::DI

((, .I. '..,":0:)·:\ .I o. SO,~} :t 200f; :I. ~:) 2" s::.~,~) 1 '?OOc; 3.1 0" DA'.:1 l ::,~::--: '!. r SS 1 HZ I." ,.!\ •.'61 :,-:: ;:~: 1. "j 100

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.., 38.....63 ~r',..) ... ) 20 0. 96( ~:.. ,I':.. ":"6/· 202 1+ SO .r. "44,63 2026 100

.., 17..'- ..b3 2027 135 1·605[;) 202C 1 1 " lj r:;\~S 2030 20 0. 91

( bS 203250 0. 99

6S 2033 65 II" 56'7 2040 1 6" E70,{)7 2() f.) 2 :t2 .I · 6267 20/1,';:, 26 4. 006? 20.lt5 1

.., 21~"b? 20·';:;·:7 20 .I " 806 'i' 20·{:·(? 39 5" -4271 2050 :I. 0 .. .,~~ 7

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?{/ :?O{).!) 30 {' 83,J"79 2058 75 0. A3~n 20'70 200 o. 51+I "X8t 205.5 1 1. A18:1. ? (; .~::,? 20 2. lB81 20E·? 50

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80 20~?S 50 o. 4380 2077 100 o. '1" C)..... ')86 208A l. l. ·3386 ?Of:l6 1. 1 1 " :088i~ :~onn 30 1 " O(?

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Cruise track and station locations sampled during Belogorsk 79-03Part I, September 12-19, 1979.

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AMMONIlJM CONC[:NTRATIONS

STATION ::; (I ~1 F' L. [:. D[F:'TH CfJhl cr~ UTr::I:~'1 TIC) 1,1( ~i ) ( ur1/L )

1 2.1+00 1,.v, 19..... A'_ ..

1 2A06 SO 1·21( 1 21+08 100 0 .. ()D

1 2 '10'1 :1.77 l·ft ..r,\.),.1

2 2Al0 1 1 .. 062 2At7 SO 0" it .I.:.2 24:1. (? 100 1

,\ r".. Vd'"> 2420 "1''''1:: o. 39"- ..:.. ...:. ..)C ::.~A21 :L 1 ?l,0 ..5 242(:} 30 1 ·Si-S 2A3() 100 L 08S 2"-:;3:1. 2~E 1 "..'· '•../ 60.(- "15 2·'H~B 20 'I ..

(', ..,(:) "

15 2·1.)93 100 0. r~o15 2-494 180 23. 2710, 24(?E, 1 1

I ,.).. ....,..( 16 24SHi 19 1. i~ ::.~

16 2503 J.OO O. 5616 250·4 185 O. 6B18 2505 1 7. 5.tf1.8 2508 7 A. T'", .'18 2511 21.> 1·51

L 18 2513 68 6. 8419 2S14 1 1. ·3219 2!jlB 1. n 1. 20, ..19 2[,20 35 '"> 90~'- ..:I. n 2~:}?:?

1··' () .. ~?c/./ \,J_.I."., 2S23 1 1,8 • 04"·fi ~·fil 22 ::'~S2b :l !:l O. M

-, - "~'"-'.:-"-

( r) '"";...... ,.. ")n T" )' '!-1 ..,_.... .... ~-:_ -.. l .;.. \.) ,.. ,,-' " .::'., r, ,., [" r) r"',

.t~ ~? 1 1 0 t..;:. ...•. ,:~ ..... ) " '".'r) .., ~ r-,":.:'O l ~:) 3 ~.).... ,.~ A'•• ":::~3

r) r; .., "j r, '3 .f:•. .:.' •. .".: ",., -. '} r:' -r f, ") l () -, )...~. ,) ..... ,j ,.J ", -,', " , ...,.,.,2b~3[, 2D n " ...~. ,:) " A',•

r 2\>::, 2 !?) :5 , 1 r, 0 :5u o. ",., 6 ,., 5·40 20 l F! E\•. .{- "26 25'+" 1 00

., 1 ..,0- " ,::.26 25.1+ [) 20 [;) 1 " 6 :I.

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48

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Cruise track and station locations sampledPart II, September 29-0ctober 9, 1979.

during Belogorsk 79-03,

(.•• - ,. ,t-·,Io

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AtlMO~Jlt!M CONCEN'rR~'r'[[)NS

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26Hi2.:)212b2:32625262t>2fJ2?2bZ326342{,3S264026./+ 1264226432,Slt62M?2bS126532bEA2bSS

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2 .. 0?7.77o u 8{}3 .. '?E:.0 .. E'i9"7 O~,..''' .' ....'

0 .. 63:3 .. 82

3:l." 8::.~2 .. 20

:1.6 .. 3/j0 .. 76:I." Sb1 .. 7'':::.1 .. ~;:LAu 2·,+1 .. 63l .. ?10 .. 550" 3"j

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0 .. 600 .. ·490,,770" S"70 .. 770" 7t;O"B60 .. 520" ('!":.10 .. .if,(.)0" (:,00 .. 600., S~;::0 .. 50

0" :.':).f.)0 .. 3S0,,340.37O~3?

0 .. .1+3O.. bO()., :I. :10.120.1+1.O. IIIOhSBO.. b:l.0 .. 580.630 .. 3r~0.160" 2[~o h if ::.~O.. 7?(). ",0

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0" 16() .. :~:lf0 .. l{j0,,070.380,,170 .. i\")0.030 .. 480.14

0 .. 3~20"370,,200,,:1.00,,2GO"l?0.370"200.330 • .1.60.070.080.:1.4

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33

34

42°

40°

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Crulse track and station locations sampled during Evrika 80-02

(

"'8 MAY 1980 Tf] 2El MAY :L9~:IO

( AMMONIUM CONCENTRATIONS

~:;HITIDN "ANF'LE DEPTH C[Jij c: EJ.flT: i'l TID H( M) ( un/I... )

1. ~.~ 1 1. 1. ·20( 1. ~~ 2 12 :i. ·01

1.:< 3 1.9r, " ,..':." ',J ".,

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229

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11121

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1" ~::,,..1. ...,:, ('.

2,,0:1.1 .. 691 .. ?2:I,,, GS0,,910 .. 9?1.,,[>9L l,5L58:l... 731 .. 121.21.\ .." ,-:..1." C'.,~.

1" 2[3:L., --~-;1" A~';~1 .. .It 3

I" :I.,c.1." l·:·}1,,2A:1..1 ?L 19:I. .. 2{,O"A-',!

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1 .. 581." ()20 .. Sfo}0 .. ~1.;?0 .. 760" 9S}0.970 .. 971." 200 .. [:00 .. 720,,(;30 .. '~l:l.0.1.,70 .. 680.4 /,0,,971..661.52L7S'2.0fj

131" .It ~:;

13

8=MISSING ANALYSIS, SAMrLE TilDE BROKEN IN TRANSIT

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126

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StartPart I

800523

40°

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Cruise track and station locations sampled during Delaware 80-03 (Part Iand Part II) and Evrika 80-04 (Part III).

(

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(AMl10NIlJM CONC[NTI~~T:I:ONS•

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0 .. 02O.()';'

0.0'70 .. l~?0 .. 070.12:) .. l,S0" :?nO. :1.10 .. :L70.230" 3~:)0.20.0 .. 270.370 .. 390.260 .. :1. /.0. ·"AO.. A?0 .. :31.

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