SAFETY DATA SHEETIssue Date03-27-2015 Revision Date03-27-2015 Version11. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGProduct identifier Product Name BRAKE FLUID-DOT 4-PREMIUM PLUSOther means of identification Common Name: 0601UN/ID No Not RegulatedSynonyms Mixture of glycol ethers, Glycols, Polyglycols.Product Type Brake FluidRecommended use of the chemical and restrictions on use Sale and Use Restrictions Not applicableRecommended Use Restricted to professional users.Uses advised against Consumer useDetails of the supplier of the safety data sheet Emergency telephone number Company Phone Number MOC PRODUCTS CO., INC. (818) 794-3500Emergency Telephone CHEMTREC 1-800-424-93002. HAZARDS IDENTIFICATIONClassification Acute toxicity - Oral Category 4Serious eye damage/eye irritation Category 1Label elements Emergency OverviewSupplier AddressMOC PRODUCTS CO., INC.12306 Montague StreetPacoima, CA 91331DangerHazard statementsHarmful if swallowedCauses serious eye damage/eye irritation_____________________________________________________________________________________________AppearanceGlycol Ether based solutionPage1 of 10Physical stateLiquid OdorMild_____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handlingDo not eat, drink or smoke when using this productWear protective gloves/protective clothing/eye protection/face protectionPrecautionary Statements - ResponseSpecific treatment (see response statements below and Section 4 of the Safety Data Sheet)IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingImmediately call a POISON CONTROL CENTER or doctor/physicianIF SWALLOWED: Call a POISON CONTROL CENTER or doctor/physician if you feel unwellRinse mouthPrecautionary Statements - DisposalDispose of contents/container to an approved waste disposal plantHazards not otherwise classified (HNOC)Other information May be harmful in contact with skin3. COMPOSITION/INFORMATION ON INGREDIENTSSynonyms Mixture of glycol ethers, Glycols, Polyglycols.Components CAS Number Weight % Trade SecretTriethylene Glycol Monomethyl BorateEster68441-44-1 0-50 *Triethylene Glycol Monoethyl Ether 112-50-5 0-50 *Diethylene Glycol Monoethyl Ether 111-90-0 0-50 *Diethylene Glycol Monobutyl Ether 112-34-5 0-50 *Triethylene Glycol Monomethyl EtherBorate Ester71243-41-9 0-40 *Triethylene Glycol Monomethyl Ether 112-35-6 0-31 *Polyethylene Glycol Monomethyl Ether 9004-74-4 0-28 *Triethylene Glycol 112-27-6 0-25 *Tetraethylene Glycol 112-60-7 0-25 *Diethylene Glycol 111-46-6 5-10 *Triethylene Glycol Monobutyl Ether 143-22-6 0-4 *Tetraethylene Glycol Monobutyl Ether 1559-34-8 0-1.5 ** The exact percentage (concentration) of composition has been withheld as a trade secret.4. FIRST AID MEASURESFirst aid measures_____________________________________________________________________________________________General advice Take proper precautions to ensure your own health and safety before attempting rescueand providing first aid. In case of accident or unwellness, seek medical advice immediately(show directions for use or safety data sheet if possible).Skin contact:Page2 of 10Remove contaminated clothing. Wash exposed skin with soap and water. If irritation occurs,seek medical attention. Launder contaminated clothing before reuse. (Discardcontaminated shoes)._____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Inhalation: If affected remove individual to fresh air. If breathing is difficult, give oxygen. If notbreathing, give artificial respiration. Call a physician immediately.Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easyto do. Continue rinsing for 15 minutes. Seek immediate medical attention/advice.Ingestion: If swallowed, rinse mouth with water (only if the person is conscious). Call a physician orPoison Control Center immediately.Most important symptoms and effects, both acute and delayedSymptoms Eye irritation, Skin irritation, Dizziness, Drowsiness, Nausea, Visual disturbances.Indication of any immediate medical attention and special treatment neededProtection of first-aiders: Avoid skin contact with product.5. FIRE-FIGHTING MEASURESSuitable extinguishing media:Use dry chemical, CO2, water spray (fog) or alcohol resistant foam.Small Fire Alcohol resistant foam, Dry chemical or CO2.Large Fire Water spray or fog; Alcohol resistant foam.Explosive properties: Explosive when mixed with oxidizing substances. Containers may rupture if exposed toextreme heat.Specific hazards arising from the chemicalCOMBUSTIBLE MATERIAL. In the event of fire and/or explosion do not breathe fumes. Thermal decomposition can lead to releaseof irritating and toxic gases and vapors. Hazardous combustion products may include: a complex mixture of airborne solid andliquid particulates and gases (smoke), Carbon oxides, Unidentified organic and inorganic compounds.Hazardous combustion productsCarbon monoxide, Carbon dioxide (CO2).Specific methods: Sensitivity to Mechanical Impact None.Sensitivity to Static Discharge May be ignited by heat, sparks or flames.Special firefighting procedures:COMBUSTIBLE! Keep away from heat, spark and flame. Fight fire from a safe distance or use unmanned hose handlers or monitornozzles. Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well afterfire is out. Wear positive pressure self contained breathing apparatus (SCBA). Structural firefighters protective clothing will onlyprovide limited protection.6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures_____________________________________________________________________________________________Personal precautions: Contaminated surfaces will be extremely slippery. Do not walk through spilled material. Usespark-proof tools and explosion-proof equipment. Do not touch damaged containers orspilled material unless wearing appropriate protective clothing. Avoid contact with skin andeyes. Use personal protective equipment. For personal protective equipment see Section 8.For emergency respondersPage3 of 10Use personal protection recommended in Section 8. Ventilate the area. Remove all sourcesof ignition._____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Environmental precautionsEnvironmental precautions: Do not let product enter drains. Do not flush into surface water or sanitary sewer system.Water runoff can cause environmental damage. Avoid subsoil penetration. Local authoritiesshould be advised if significant spillages cannot be contained.Methods and material for containment and cleaning upMethods for containment Prevent further leakage or spillage if safe to do so. Prevent from spreading or enteringdrains, ditches, or rivers by using sand, earth, or other appropriate barriers.Methods for cleaning up: Extremely slippery when spilled. Avoid accidents, clean up immediately. Reclaim liquiddirectly or in an absorbent. Soak up residue with absorbent such as clay, and or othersuitable material and place in chemical waste container for proper disposal.Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.7. HANDLING AND STORAGEPrecautions for safe handlingHandling: Avoid contact with eyes. Avoid prolonged or repeated contact with skin and clothing. Avoidall possible sources of ignition (spark or flame). Avoid breathing vapors or mists. Storeaway from incompatible materials (See section 7 or 10 of the SDS). Protect againstphysical damage. Containers of this material may be hazardous when emptied.Sinceemptied containers retain product residues (vapor, liquid, and/or solid), all hazardprecautions given in the data sheet must be observed.Conditions for safe storage, including any incompatibilitiesTechnical measures/precautions: Use local exhaust ventilation if there is a risk of inhalation of vapors, mists or aerosols. Eyewash should be easily accessible.Materials to avoid: Oxidising agents: Acids, Strong bases, Light and/or alkaline metals; Zinc.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersExposure Guidelines .Components ACGIH TLV OSHA Exposure Limits: NIOSH IDLHTriethylene Glycol Monomethyl BorateEster 68441-44-1- Not established -Triethylene Glycol Monoethyl Ether 112-50-5- Not established -Diethylene Glycol Monoethyl Ether 111-90-0- Not established -Diethylene Glycol Monobutyl Ether 112-34-5TWA: 10 ppminhalable fractionand vaporNot established -Triethylene Glycol Monomethyl EtherBorate Ester 71243-41-9- Not established -Triethylene Glycol Monomethyl Ether 112-35-6- Not established -Polyethylene Glycol Monomethyl Ether 9004-74-4-_____________________________________________________________________________________________Not established -Triethylene Glycol 112-27-6-Page4 of 10Not established -_____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Tetraethylene Glycol 112-60-7- Not established -Diethylene Glycol 111-46-6- Not established -Triethylene Glycol Monobutyl Ether 143-22-6- Not established -Tetraethylene Glycol Monobutyl Ether 1559-34-8- Not established -Other information WEEL (Workplace Environmental Limit) 8 hr TWA AIHA: Diethylene Glycol = 10 mg/m3;Diethylene Glycol Monobutyl Ether = 25 ppm; Diethylene Glycol Monoethyl Ether = 25 ppm.Appropriate engineering controlsEngineering measures: Use local exhaust ventilation if there is a risk of inhalation of vapors, mists or aerosols. Eyewash and safety shower should be easily accessible.Individual protection measures, such as personal protective equipmentEye/face protection Wear safety glasses with side shields (or goggles). If splashes are likely to occur, wear:Face protection shield.Skin and body protection Wear normal work clothing including long pants, long-sleeved shirts and foot covering toprevent direct contact of the product with the skin. Launder clothing before reuse. If skinirritation develops, contact your facility health and safety professional or your local safetyequipment supplier to determine the proper personal protective equipment for your use.Wear chemical resistant gloves (consult your safety equipment supplier). PVC, neoprene,or nitrile rubber gloves are recommended.Respiratory protection Respiratory protection is not required under normal conditions of use. If workplaceexposure limit(s) of product or any component is exceeded, a NIOSH-approved air purifyingrespirator used in accordance with the OSHA Respiratory Protection Standard [29 CFR1910.134] is recommended in the absence of adequate ventilation during normal use (seeyour industrial hygienist). Emergency response/release cleanup may require additionalrespiratory protection, including SCBAs. Administrative or engineering controls should beimplemented to reduce exposure.General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. When using do noteat, drink or smoke. Wear suitable gloves and eye/face protection. Avoid contact with eyes,skin and clothing. Avoid breathing vapors or mists. Wash face, hands and any exposed skinthoroughly after handling. Take off all contaminated clothing and wash it before reuse.9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesPhysical state LiquidAppearance Glycol Ether based solution Odor MildColor Light yellow to Yellow Odor threshold No information isavailablePropertyValues Remarks: MethodpH 8.0-8.6 (25%) Aqueous SolutionMelting point/freezing point 230C/446F @760 mm HgFlash point >95C/203F Pensky-Martens Closed Cup (PMCC)Evaporation rateFlammability (solid, gas) No information is available OSHA/NFPA Class IIIB Combustible LiquidFlammability Limits in Air_____________________________________________________________________________________________Upper flammability limits No data availablePage5 of 10_____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Explosive properties No data availableOxidizing properties No data availableOther informationSoftening point No data availableMolecular weight No data availableDensity 1.05 - 1.06 g/ccBulk density No data available10. STABILITY AND REACTIVITYReactivityChemical stabilityPossibility of Hazardous ReactionsMay form peroxides of unknown stability.Hazardous polymerization Hazardous polymerization does not occur.Conditions to avoidHeat, flames and sparks.Incompatible materialsMaterials to avoid:Oxidising agents: Acids, Strong bases, Light and/or alkaline metals; Zinc.Hazardous Decomposition ProductsHazardous Decomposition Products Carbon monoxide, Carbon dioxide (CO2).11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposureProduct information May be harmful if swallowed. Causes serious eye damage/eye irritation. May be absorbedthrough skin in toxic amounts.Inhalation Not an expected route of exposure: May cause irritation.Eye contact Causes serious eye damage/eye irritation. Not expected to cause permanent damage. Maycause pain, redness, stinging and tearing.Skin Contact Repeated or prolonged contact may cause slight skin irritation. May be absorbed throughskin in toxic amounts.Lower flammability limit No data availableVapor pressure > 0.013 kPaVapor density Heavier than airSpecific Gravity 1.05 -1.06Water solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient No data availableAutoignition temperature >300C/572FDecomposition temperature No data availableKinematic viscosity No information is availableDynamic viscosity No data available_____________________________________________________________________________________________VOC Content (%) No data availableReactivityPage6 of 10Stable under normal conditions. Hygroscopic._____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Ingestion May produce symptoms of central nervous system depression including headache,dizziness, nausea, loss of sense of balance; drowsiness, and visual disturbances.Components Oral LD50 Dermal LD50 Inhalation LC50Triethylene Glycol Monomethyl Borate Ester 68441-44-1- - -Triethylene Glycol Monoethyl Ether 112-50-5- - -Diethylene Glycol Monoethyl Ether 111-90-0= 1920 mg/kg( Rat ) =9143 mg/kg (rabbit) > 200 mg/l( Rat ) 4 hDiethylene Glycol Monobutyl Ether 112-34-5= 3384 mg/kg( Rat ) = 2700 mg/kg( Rabbit ) -Triethylene Glycol Monomethyl Ether Borate Ester 71243-41-9>2000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 200 mg/L ( Rat ) 1 hTriethylene Glycol Monomethyl Ether 112-35-6= 11800 mg/kg ( Rat ) = 7400 mg/kg ( Rabbit ) -Polyethylene Glycol Monomethyl Ether 9004-74-4=39800 mg/kg ( Rat ) >20000 mg/kg ( Rabbit ) -Triethylene Glycol 112-27-6= 15000 mg/kg( Rat ) > 20 mL/kg( Rabbit ) -Tetraethylene Glycol 112-60-7=32484 mg/kg ( Rat ) > 20 g/kg( Rabbit ) -Diethylene Glycol 111-46-6= 12565 mg/kg( Rat ) = 11890 mg/kg( Rabbit ) -Triethylene Glycol Monobutyl Ether 143-22-6= 5300 mg/kg( Rat ) = 3480 mg/kg( Rabbit ) -Tetraethylene Glycol Monobutyl Ether 1559-34-8= 5175 mg/kg( Rat ) > 4000 mg/kg( Rat ) -Information on toxicological effectsDelayed and immediate effects as well as chronic effects from short and long-term exposureSensitization Not expected to cause skin sensitization. Not classified as a respiratory sensitizer.Mutagenic effects: No data available to indicate product or any components present at or greater than 0.1%are mutagenic or genotoxic.Carcinogenicity No component of this product present at levels greater than or equal to 0.1% is identified asa known or anticipated carcinogen by IARC, NTP, or OSHA.Reproductive toxicity No information is available.STOT - single exposure This product is not classified as STOT single exposure.STOT - repeated exposure This product is not classified as STOT repeated exposure.Chronic toxicity Prolonged skin contact may defat the skin and produce dermatitis.Subchronic toxicity No information is available.Target Organ Effects Skin, Eyes, Reproductive System.Neurological effects Repeated exposure affects the central nervous system.Other adverse effects Exposure to components of this product has caused the following effects in humans:Stomach irregularities, (CAS#112-34-5) Diethylene Glycol Monobutyl ether,(CAS#9004-77-7) Polyethylene Glycol Monobutyl Ether; Liver irregularities,(CAS#111-46-6) Diethylene Glycol. Exposure to (CAS#143-22-6) Triethylene GlycolMonobutyl Ether caused peripheral nerve, sensation effects (aneasthesia, neuromuscularblockage) and altered sleep time in rats.Aspiration hazard Swallowing large amounts of product may be harmful.This material can get into the lungsduring swallowing or vomiting, which may result in lung inflammation and/or lung injury.Numerical measures of toxicity- Product informationThe following values are calculated based on chapter 3.1 of the GHS document.ATEmix (oral) 1578mg/kg_____________________________________________________________________________________________ATEmix (dermal) 4323mg/kgPage7 of 10ATEmix (inhalation-vapor) 10480mg/l_____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-201512. ECOLOGICAL INFORMATIONEcotoxicity Although toxicity data for the components of this product indicate that the product is not significantly toxic to fish and aquaticinvertebrates, amphibians may be more sensitive. Wildlife species may be more susceptible since mammals and birds do notreadily metabolize this material. The odor and flavor of this material may attract some wildlife and cause them to consume spilledmaterial.Diethylene Glycol Monoethyl Ether 111-90-0Fish 11400 - 15700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 11600 - 16700: 96 h Pimephalespromelas mg/L LC50 flow-through 19100 - 23900: 96 h Lepomis macrochirus mg/L LC50 flow-through10000: 96 h Lepomis macrochirus mg/L LC50 static 13400: 96 h Salmo gairdneri mg/L LC50flow-throughCrustacea 3940 - 4670: 48 h Daphnia magna mg/L EC50Diethylene Glycol Monobutyl Ether 112-34-5Algae/aquatic plants 100: 96 h Desmodesmus subspicatus mg/L EC50Fish 1300: 96 h Lepomis macrochirus mg/L LC50 staticCrustacea 2850: 24 h Daphnia magna mg/L EC50 100: 48 h Daphnia magna mg/L EC50Triethylene Glycol Monomethyl Ether 112-35-6Algae/aquatic plants 500: 72 h Desmodesmus subspicatus mg/L EC50Fish 10000: 96 h Leuciscus idus mg/L LC50 static 10000: 96 h Pimephales promelas mg/L LC50 static5000: 96 h Brachydanio rerio mg/L LC50 staticCrustacea 500: 48 h Daphnia magna mg/L EC50Triethylene Glycol 112-27-6Fish 56200 - 63700: 96 h Pimephales promelas mg/L LC50 flow-through 10000: 96 h Lepomis macrochirusmg/L LC50 static 61000: 96 h Lepomis macrochirus mg/L LC50 flow-throughCrustacea 42426: 48 h Daphnia magna mg/L EC50Tetraethylene Glycol 112-60-7Algae/aquatic plants 1000: 96 h Pseudokirchneriella subcapitata mg/L EC50Fish 1000: 96 h Oncorhynchus mykiss mg/L LC50 staticCrustacea 1000: 48 h Daphnia magna mg/L EC50Diethylene Glycol 111-46-6Fish 75200: 96 h Pimephales promelas mg/L LC50 flow-throughCrustacea 84000: 48 h Daphnia magna mg/L EC50Triethylene Glycol Monobutyl Ether 143-22-6Algae/aquatic plants 500: 72 h Desmodesmus subspicatus mg/L EC50Fish 2200 - 4600: 96 h Leuciscus idus mg/L LC50 static 2400: 96 h Pimephales promelas mg/L LC50 2400:96 h Pimephales promelas mg/L LC50 staticCrustacea 500: 48 h Daphnia magna mg/L EC50Tetraethylene Glycol Monobutyl Ether 1559-34-8Algae/aquatic plants 1000: 96 h Pseudokirchneriella subcapitata mg/L EC50Fish 1000: 96 h Salmo gairdneri mg/L LC50_____________________________________________________________________________________________Crustacea 1000: 48 h Daphnia magna mg/L EC50Page8 of 10Persistence and degradabilityThis product will biodegrade rapidly in both soil and water, and will not persist in the environment. Due care should be taken toavoid accidental releases to aquatic or terrestrial systems. Vapor phase of this product is degraded in the atmosphere by reactionwith photochemically produced hydroxyl radicals and ozone. This product contains components which may be persistent in theenvironment._____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015BioaccumulationThis material is highly soluble in water and should not bioaccumulate in aquatic or terrestrial life.MobilitySoluble in water. If product enters soil, one or more constituents will be mobile and may contaminate ground water.Components Partition coefficientDiethylene Glycol Monobutyl Ether 112-34-51Triethylene Glycol Monomethyl Ether 112-35-6-1.12Triethylene Glycol Monobutyl Ether 143-22-60.5113. DISPOSAL CONSIDERATIONSWaste treatment methodsDisposal of wastes Dispose of in accordance with federal, state and local regulations.Contaminated packaging Do not reuse container. Dispose of in accordance with federal, state and local regulations.14. TRANSPORT INFORMATIONDOTNot regulatedIATANot regulatedIMDGNot regulated15. REGULATORY INFORMATIONInternational Inventories Legend:TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListFederal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) -This product contains a chemicalor chemicals which is/are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part372:Components CAS Number Weight % SARA 313 - Threshold Values%Triethylene Glycol Monoethyl Ether 112-50-5 0-50 1.0 % de minimis concentrationDiethylene Glycol Monoethyl Ether 111-90-0_____________________________________________________________________________________________0-50 1.0 % de minimis concentrationDiethylene Glycol Monobutyl Ether 112-34-5Page9 of 100-50 1.0 % de minimis concentration_____________________________________________________________________________________________0601 BRAKE FLUID-DOT4-PREMIUM PLUSRevision Date03-27-2015Triethylene Glycol Monomethyl Ether 112-35-6 0-31 1.0 % de minimis concentrationTriethylene Glycol Monobutyl Ether 143-22-6 0-4 1.0 % de minimis concentrationSARA 311/312 Hazard Categories Acute health hazard YesChronic Health Hazard YesFire hazard YesSudden release of pressure hazard NoReactive Hazard NoCWA (Clean Water Act)This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42).CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355).There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material.State Regulations (RTK) California Proposition 65This product does not contain any Proposition 65 chemicals.U.S. State Right-to-Know RegulationsU.S. EPA Label InformationEPA Pesticide Registration Number Not applicable16. OTHER INFORMATIONNFPA rating:Health hazards1Flammability1Instability0Physical and Chemical Properties-HMIS health rating:Health hazards2*Flammability1Physical hazards0Personal protectionBChronic Hazard Star Legend * = Chronic Health HazardPrepared By Environmental Health and Safety DepartmentIssue Date 03-27-2015Revision Date 03-27-2015_____________________________________________________________________________________________Revision NoteDisclaimerThe information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and beliefat the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.Page 10 of 10End of Safety Data Sheet