BONDERITE L-.pdf
Transcript of BONDERITE L-.pdf
Safety Data Sheet according to (EC) No 1907/2006Page 1 of 9
sds no. : 115282V010.1
Revision: 20.11.2012printing date: 12.05.2014
BONDERITE L-AD P known as MULTAN P
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifierBONDERITE L-AD P known as MULTAN P
1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended use:Water Soluble Cooling Lubricants for Metal [email protected]
1.4. Emergency telephone numberThe Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0)211-797-3350 forexceptional cases.
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (CLP):No data available.
Classification (DPD):N - Dangerous for theenvironmentR50 Very toxic to aquatic organisms.Xi - IrritantR36/38 Irritating to eyes and skin.
2.2. Label elements
Label elements (CLP):No data available.
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Label elements (DPD):
N - Dangerous for theenvironment
Xi - Irritant
Risk phrases:R50 Very toxic to aquatic organisms.R36/38 Irritating to eyes and skin.
Safety phrases:S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S37 Wear suitable gloves.
2.3. Other hazardsNone if used properly.
SECTION 3: Composition/information on ingredients
Declaration of the ingredients according to CLP (EC) No 1272/2008:
Hazardous componentsCAS-No.
EC NumberREACH-Reg No.
content Classification
3-Iodo-2-propynyl butylcarbamate55406-53-6
259-627-5 5- 10 % Acute toxicity 4; OralH302
Serious eye damage/eye irritation 1H318
Acute toxicity 4; InhalationH332
Acute hazards to the aquatic environment 1H400
For full text of the H - statements and other abbreviations see section 16 "Other information".Substances without classification may have community workplace exposure limits available.
Declaration of ingredients according to DPD (EC) No 1999/45:
Hazardous componentsCAS-No.
EC NumberREACH-Reg No.
content Classification
3-Iodo-2-propynyl butylcarbamate55406-53-6
259-627-5 5 - 10 % Xn - Harmful; R20/22Xi - Irritant; R41
N - Dangerous for the environment; R50
For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:Move to fresh air.In case of adverse health effects seek medical advice.
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Skin contact:Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing.In case of adverse health effects seek medical advice.
Eye contact:Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting,sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital.
Ingestion:Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.
4.2. Most important symptoms and effects, both acute and delayedEYE: Irritation, conjunctivitis.
SKIN: Redness, inflammation.
4.3. Indication of any immediate medical attention and special treatment neededSee section: Description of first aid measures
SECTION 5: Firefighting measures
5.1. Extinguishing mediaSuitable extinguishing media:
Carbon dioxide, foam, powderFine water spray
Extinguishing media which must not be used for safety reasons:Water jet (solvent-containing product).
5.2. Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in fires.
5.3. Advice for firefightersWear self-contained breathing apparatus.
Additional information:Cool endangered containers with water spray jet.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency proceduresAvoid contact with skin and eyes.
6.2. Environmental precautionsDo not empty into drains / surface water / ground water.
6.3. Methods and material for containment and cleaning upRemove with liquid-absorbing material (sand, peat, sawdust).Dispose of contaminated material as waste according to Chapter 13.
6.4. Reference to other sectionsSee advice in chapter 8
SECTION 7: Handling and storage
7.1. Precautions for safe handlingAvoid skin and eye contact.Ensure that workrooms are adequately ventilated.Avoid spraying/aerosol generation.See advice in chapter 8Take measures to prevent the build-up of electrostatic charges.
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Hygiene measures:Wash hands before work breaks and after finishing work.Do not eat, drink or smoke while working.
7.2. Conditions for safe storage, including any incompatibilitiesStore in sealed original container.Store frost-free.Store in sealed original container.Do not store together with oxidants.
7.3. Specific end use(s)Water Soluble Cooling Lubricants for Metal Working
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational Exposure Limits
Valid forGermany
Ingredient ppm mg/m3 Type Category RemarksOxydipropanol25265-71-8
67 AGW: 8If the AGW and BGW valuesare complied with, thereshould be no risk ofreproductive damage (seeNumber 2.7).
TRGS 900
Oxydipropanol25265-71-8
Short Term ExposureClassification:
Category II: substances with aresorptive effect.
TRGS 900
Biological Exposure Indices:None
8.2. Exposure controls:
Engineering controls:Ensure good ventilation/suction at the workplace.
Respiratory protection:In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter. This recommendation should be matched to local conditions.
Hand protection:Chemical-resistant protective gloves (EN 374).Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30minutes permeation time as per EN 374):nitrile rubber (NBR; >= 0.4 mm thickness)Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeationtime as per EN 374):nitrile rubber (NBR; >= 0.4 mm thickness)This information is based on literature references and on information provided by glove manufacturers, or is derived byanalogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may beconsiderably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencingfactors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.
Eye protection:Protective goggles
Skin protection:Suitable protective clothing
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SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical propertiesAppearance liquid
clearAmber
Odor characteristic
pH not applicableInitial boiling point No data available / Not applicableFlash point > 100 °C (> 212 °F); Flash Point, Pensky-Martens
No flash point up to 100 °CDecomposition temperature No data available / Not applicableVapour pressure No data available / Not applicableDensity
(20 °C (68 °F)) 1,025 - 1,065 g/cm3
Bulk density No data available / Not applicableViscosity No data available / Not applicableViscosity (kinematic) No data available / Not applicableExplosive properties No data available / Not applicableSolubility (qualitative)
(Solvent: Water) of high solubility
Solidification temperature No data available / Not applicableMelting point No data available / Not applicableFlammability No data available / Not applicableAuto-ignition temperature No data available / Not applicableExplosive limits No data available / Not applicablePartition coefficient: n-octanol/water No data available / Not applicableEvaporation rate No data available / Not applicableVapor density No data available / Not applicableOxidising properties No data available / Not applicable
9.2. Other information
No data available / Not applicable
SECTION 10: Stability and reactivity
10.1. ReactivityReaction with oxidants.
10.2. Chemical stabilityStable under recommended storage conditions.
10.3. Possibility of hazardous reactionsSee section reactivity
10.4. Conditions to avoidNo decomposition if used according to specifications.
10.5. Incompatible materialsNone if used properly.
10.6. Hazardous decomposition productsNone if used for intended purpose.In case of fire toxic gases can be released.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
General toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.
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Skin irritation:Irritating to the skin.OECD 404
Eye irritation:Irritating to eyes.OECD 405
Sensitizing:Sensibilization test: no findings (not sensitizing).OECD 406
SECTION 12: Ecological information
General ecological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Do not empty into drains / surface water / ground water.
Ecotoxicity:Very toxic to aquatic organisms.
Persistence and degradability:Ultimate biodegradation:
The product contains both "readily biodegradable" components as well as compounds which do not fulfil the OECD's criteriafor "ready biodegradability".
12.1. Toxicity
Hazardous componentsCAS-No.
Valuetype
Value AcuteToxicity
Study
Exposuretime
Species Method
3-Iodo-2-propynylbutylcarbamate
55406-53-6
LC50 0,067 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline203 (Fish, Acute
Toxicity Test)NOEC 0,0084 mg/l Fish 35 d Pimephales promelas
3-Iodo-2-propynylbutylcarbamate
55406-53-6
EC50 0,65 mg/l Daphnia 48 h Daphnia magna OECD Guideline202 (Daphnia sp.
AcuteImmobilisation
Test)3-Iodo-2-propynyl
butylcarbamate55406-53-6
EC50 0,053 mg/l Algae 72 h Scenedesmus subspicatus (newname: Desmodesmus
subspicatus)
OECD Guideline201 (Alga, Growth
Inhibition Test)
12.2. Persistence and degradability
Hazardous componentsCAS-No.
Result Route ofapplication
Degradability Method
3-Iodo-2-propynylbutylcarbamate
55406-53-6
25 % OECD Guideline 301 F (ReadyBiodegradability: ManometricRespirometry Test)
12.3. Bioaccumulative potential / 12.4. Mobility in soil
Hazardous componentsCAS-No.
LogKow Bioconcentrationfactor (BCF)
Exposuretime
Species Temperature Method
3-Iodo-2-propynylbutylcarbamate
55406-53-6
3,3 - 4,5 Carassius sp.
3-Iodo-2-propynylbutylcarbamate
55406-53-6
2,81
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SECTION 13: Disposal considerations
13.1. Waste treatment methodsProduct disposal:
In consultation with the responsible local authority, must be subjected to special treatment.
Recommended cleaning agentsWater, if necessary with added cleaning agent.
Waste code120108The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codesfor the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. Wewill be happy to advise you.
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SECTION 14: Transport information
14.1. UN number
ADR 3082RID 3082ADNR 3082IMDG 3082IATA 3082
14.2. UN proper shipping name
ADR ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodinecarbamate)
RID ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodinecarbamate)
ADNR ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodinecarbamate)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Iodinecarbamate)
IATA Environmentally hazardous substance, liquid, n.o.s. (Iodine carbamate)
14.3. Transport hazard class(es)
ADR 99
RID 99
ADNR 99
IMDG 99
IATA 99
14.4. Packaging group
ADR IIIRID IIIADNR IIIIMDG IIIIATA III
14.5. Environmental hazards
ADR not applicableRID not applicableADNR not applicableIMDG Marine pollutantIATA not applicable
14.6. Special precautions for user
ADR not applicableTunnelcode: (E)
RID not applicableADNR not applicableIMDG not applicableIATA not applicable
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable
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SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixtureVOC content
(1999/13/EC)0 %
15.2. Chemical safety assessmentA chemical safety assessment has not been carried out.
National regulations/information (Germany):
WGK: WGK = 3, highly water endangering product. Classification according to themixture rules in German VwVwS regulation annex 4 from 27 July 2005.
Storage class according to TRGS 510: 10
SECTION 16: Other information
The labelling of the product is indicated in Section 2. The full textof all abbreviations indicated by codes in this safety data sheet are as follows:
R20/22 Harmful by inhalation and if swallowed.R41 Risk of serious damage to eyes.R50 Very toxic to aquatic organisms.H302 Harmful if swallowed.H318 Causes serious eye damage.H332 Harmful if inhaled.H400 Very toxic to aquatic life.
Further information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee anyparticular properties.