Boiler Tube Failure Analysis
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Transcript of Boiler Tube Failure Analysis
analysis with Modified Design
1
FAILURE DETAIL CHAPTER-1
1.1) Failure Types:-
There are six reason for failure in Boiler Tube:-
1) Water-side corrosion
2) Fire-side corrosion
3) Erosion
4) Fatigue
5) Heating
6) Lack of quality control
1.2) Detail Types Of Failures :-
1.2.1) Water-Side Corrosion:-
There are five types of effect due to water impurities.
1) Caustic corrosion
2) Oxide corrosion
3) Hydrogen Damage
4) Pitting (Localized Corrosion)
5) Stress Corrosion Cracking
1.2.2) Fire-Side Corrosion:-
There are two types of corrosion due to firing.
1) Water wall
2) Flue gas
1.2.3) Erosion:-
There are two types of failure due to erosion.
1) Fly Ash
2) Coal Particle (clinker)
analysis with Modified Design
2
1.2.4) Fatigue:-
This is occurs due to following fatigue.
1.Mechanical Fatigue( carry over )
1.2.5) Heating:-
There are two types of failures.
1. Short Term Overheat
2. Long Term Overheat
1.2.6) Lack of Quality Control:-
There are three types of failures.
1. Maintenance Damage
2. Material Defects
3. Welding Defects
1.3) Feed Water Treatment & Chemical Cleaning:-
1.3.1) Objectives:-
1.3.1.1 Pretreatment Of Water
1.3.1.2 Demineralization
1.3.1.3 Chemical Conditioning of Water
1.3.2) De-aerator:-
1.3.2.1 Function
1.3.2.2 Flow Arrangement
1.3.2.3 Design & Construction
1.3.2.4 Main Parts
1.3.2.5 Accessories
analysis with Modified Design
3
DETAIL DESCRIPTION OF FAILURES Chapter-2
2.1) Water Side Corrosion:-
2.1.1) Caustic Corrosion:-
Problem: Loss on the inside diameter (ID) surface of the tube, stress and
strain in the tube wall is increases.
Causes: Caustic corrosion occurs when there is excessive deposition on ID
tube surfaces.
If pH value of water is increases, it results in a caustic condition which
corrosively attacks and breaks down protective magnetite.
Fig. 2.1.1:- Caustic Corrosion
analysis with Modified Design
4
2.1.2) Oxide Corrosion:-
Problem: Aggressive localized corrosion and loss of tube wall is near economizer
feed water inlet on operating boilers.
Causes: Oxygen corrosion occurs with the presence of excessive oxygen in boiler
water. It can occur during operation as a result of in-leakage of air at pumps, or failure
in operation of pre-boiler water treatment equipment.
This also may occur during out-of-service periods, such as outages and storage, if
proper procedures are not followed in lay-up. Non-drainable locations of boiler
circuits, such as super heater loops, re-heater tubes and supply lines, are especially
susceptible.
Wetted surfaces are subject to oxidation as the water reacts with the iron to form iron
oxide.
Fig. 2.1.2:- Oxide Damage
analysis with Modified Design
5
2.1.3) Hydrogen Damage:-
Problem: Due to Internal micro-cracking. Loss of ductility of the tube
material leading to brittle rupture in boiler tube.
Causes: Hydrogen damage is mostly occurs on inner side of tube surfaces,
coupled with a boiler water low pH excursion.
Water chemistry is upset, such as what can occur from condenser leaks,
particularly with salt water cooling medium, and leads to acidic (low pH)
contaminants that can be concentrated in the deposit.
Under-deposit corrosion releases atomic hydrogen which migrates into the
tube wall metal, reacts with carbon in the steel (decarburization) and
causes inter granular separation.
Fig.2.1.3:- Hydrogen damage
analysis with Modified Design
6
2.1.4) Pitting (Localized Corrosion) :-
Problem: Corrosive attack of the internal tube metal surfaces, resulting in an
irregular pitted or in extreme cases appearance of the tube inner diameter.
Causes: Acid attack most commonly is associated with poor control of
process during boiler chemical cleanings and/or inadequate post-cleaning
passes of residual acid.
Fig.2.1.4:- Localized Corrosion
analysis with Modified Design
7
2.1.5) Stress Corrosion Cracking(SCC):-
Problem: Failures from SCC is brittle-type crack. May be found at locations
of higher external stresses, such as near attachments.
Causes: SCC most commonly is associated with austenitic (stainless steel)
super heater materials and can lead to inter granular crack propagation in the
tube wall.
It occurs where a combination of high-tensile stresses and a corrosive fluid are
present. The damage results from cracks that propagate from the inner
diameter.
The source of corrosive fluid may be carryover into the super heater from the
steam drum or from contamination during boiler acid cleaning if the super
heater is not properly protected.
Fig.2.1.5:- Stress Corrosion Cracking
2.2) Fire Side Corrosion :-
analysis with Modified Design
8
2.2.1) Water Wall:-
Problem: External tube metal loss (wastage) leading to thinning and
increasing tube strain.
Causes: Corrosion occurs on external surfaces of water wall tubes when
the combustion process produces a reducing atmosphere.
For conventional fossil fuel boilers, corrosion in the burner zone usually is
associated with coal firing.
Boilers operating with staged air zones to control combustion can be more
susceptible to larger local regions possessing a reducing atmosphere,
resulting in increased corrosion rates.
Fig.2.2.1:- Water wall side corrosion
2.2.2) Flue Gases:-
analysis with Modified Design
9
Problem: It most commonly seen as a series of circumferential cracks.
Usually found on furnace wall tubes of coal-fired once-through boiler
designs, but also has occurred on tubes in drum-type boilers.
Causes: Damage initiation and propagation result from corrosion in
combination with thermal fatigue.
Thermal cycling, in addition to subjecting the material to cyclic stress can
initiate cracking of the less elastic external tube scales and expose the tube
base material to repeated corrosion.
Fig.2.2.2:- Flue gases effect
2.3) Erosion :-
analysis with Modified Design
10
2.3.1) Fly ash:-
Problem: External tube wall loss and increasing tube strain.
Causes: It usually is associated with coal firing, but also can occur for certain types of
oil firing.
Ash characteristics are considered in the boiler design when establishing the size,
geometry and materials used in the boiler. Combustion gas and metal temperatures in
the convection passes are important considerations.
Damage occurs when certain coal ash constituents remain in a molten state on the
super heater tube surfaces. This molten ash can be highly corrosive.
Fig.2.3.1:- Fly Ash
2.3.2) Erosion In Tube:-
analysis with Modified Design
11
Problem: Damage will be occurs on inner side of the tube. Ultimate failure results
from rupture due to increasing strain as tube material erodes away.
Causes: Erosion of tube surfaces occurs from impingement on the external surfaces.
The erosion medium can be any abrasive in the combustion gas flow stream, but most
commonly is associated with impingement of fly ash or soot blowing steam.
Fig.2.3.2:- Erosion in tube
2.4) Fatigues:-
analysis with Modified Design
12
2.4.1) Mechanical Fatigue:-
Problem: Damage most often results in an outer diameter (OD) initiated crack. Tends
to be localized to the area of high stress or constraint.
Causes: Fatigue is the result of cyclical stresses in the component. Distinct from
thermal fatigue effects.
Mechanical fatigue damage is associated with externally applied stresses. Stresses
may be associated with vibration due to flue gas flow or soot blowers (high-frequency
low-amplitude stresses), or they may be associated with boiler cycling (low-
frequency, high-amplitude, stress mechanism).
Fatigue failure most often occurs at areas of constraint, such as tube penetrations,
welds, attachments or supports.
Fig.:2.4.1:- Mechanical fatigue
2.5) Heating:-
analysis with Modified Design
13
2.5.1) Short Term Heating:-
Problem: Failure results in a ductile rupture of the tube metal and is normally
characterized by the classic “fish mouth” opening in the tube where the fracture
surface is a thin edge.
Causes: Short-term overheat failures are most common during boiler start up.
Failures result when the tube metal temperature is extremely elevated from a lack
of cooling steam or water flow.
Tube metal temperatures reach combustion gas temperatures of 1600°F or greater
which lead to tube failure.
Fig.2.5.1:- Short Term Heating
2.5.2) Long Term Heating:-
analysis with Modified Design
14
Problem: Tube metal often has heavy external scale build-up and secondary
cracking. Results in tube failure.
Causes: Long-term overheat occurs over a period of months or years. Super
heater and reheat super heater tubes commonly fail as a result of creep.
Furnace water wall tubes also can fail from long-term overheat. In the case of
water wall tubes, the tube temperature increases abnormally, most commonly
from waterside problems such as deposits, scale or restricted flow.
Fig.2.5.2:- Long term Heating
2.6) Lack Of Quality Control:-
analysis with Modified Design
15
2.6.1) Maintenance Damage & Metallurgy Defects:-
Problem: Maintenance damage & Material defect are occurs due to methods &
materials used in analysis of boiler tube.
Cause: If proper methods & material not used in it , then it cause in boiler. High
quality methods & material to be used in boiler tube failure are more expensive.
Insufficient methods & material cause heavy damage in boiler.
2.6.2) Welding Defects:-
Problem: Failure is occurs due to dissimilar metals in welding process.
Causes: Failures at dissimilar metal welding locations occur on the ferrite side of
the butt weld.
These failures are attributed to several factors: high stresses at the austenitic to
ferrites interface due to differences in expansion properties of the two materials,
excessive external loading stresses, and creep of the ferrites material.
Fig.2.6.2:- Welding Defects
Feed Water Treatment & Chemical Cleaning CHAPTER 3
analysis with Modified Design
16
3.1) Objectives of Treatment:-
Treatment and further conditioning of water are necessary for the following
objectives:
To prevent scaling internals of pressure vessels due to dissolved and suspended
impurities,
To prevent corrosion of metallic parts of the boiler, with which water / steam
come in direct contact,
To establish protective coating over metallic surfaces to prevent corrosion attack.
To avoid salt deposits over turbine blades,
To ensure better utilization of heat energy and to improve on efficiency,
In order to ensure to achieve above objectives, following processes of water
treatment are adopted:
1. Pre treatment
2. Demineralization
3. Chemical conditioning
Following are the impurities in the natural water which are to be cleaned.
1) Dissolved impurities:-
Mainly the dissolved solids found in water are mineral salts. These
contaminants in water exist as salts of calcium, magnesium and sodium.
To a lesser extent, potassium and iron salts are also present. Nitrates and
silicates of such substances are also found to a small degree. Very rarely,
Phosphates and a few heavy metals are also found in natural water.
The quantity and composition of the solids present depend upon the soil and
strata details and the origin of water.
Various gases, mainly Oxygen, and others like Carbon dioxide and Hydrogen
Sulfide are normally present in dissolved form and the presence of such
dissolved gases alter the composition and concentration of certain salts.
analysis with Modified Design
17
2) Dissolved Oxygen:-
Dissolved oxygen plays significant role in boiler feed water. The oxygen
accelerates corrosion of water tube material. Mainly oxygen is removed only
in De-aerator. Hence performance of De-aerator is very important.
De-aerator performance has to be maintained limiting dissolved oxygen to less
than 0.01 ppm level. A figure < 0.007 ppm is considered to be very ideal.
3) Total Solids:-
The basic idea is to restrict impurities in feed water as low as possible in order
to avoid rise in boiler water concentration and deposition of metal oxides in
the boiler.
4) Organic Matter:-
It is very difficult to eliminate organic matter totally from water. Presence of
organic matter is due to poor pretreatment practice, ineffective D.M. plant
performance, resin leaking or condenser leakage.
Quality of raw water at intake point is a deciding factor. Seasonal changes
play a vital role.
5) Chlorides:-
Presence of chloride in feed water is harmful to the system as whole. Hence it
is very advisable to limit chloride concentration in feed water, keeping in
mind, limit prescribed for boiler water and restriction as per drum pressure
ratings.
Leak proof condenser and efficient demineralization are essential prerequisites
to avoid contamination due to chloride.
Dosing chemicals fed to the drum can contribute in sizeable proportion to
chloride contamination if the chemicals are not of adequate quality. Very low
level chloride should be tested by selective ion electrode for accuracy.
analysis with Modified Design
18
6) Suspended and colloidal impurities:-
Clay and sand particles constitute a major portion of the suspended matter.
Very fine clay remains in colloidal state. Colloidal suspension of dye material
and certain organic contents, give color to water, in most cases.
7) General nature of dissolved contents:-
Normally the mineral salts dissolved in water are found to exist in the ionized
form. Generally there is no uniformity in quantity and proportion of such
dissolved salts, since their presence is mainly dependent on the sources of the
water.
However fair representations of composition of mineral salts, as widely found
in nature are brought out below:
CATION (Basic Radical) ANION (Acidic Radical)
Ca ++ (Calcium) HCO3- (Bicarbonate)
Mg++ (Magnesium) CO3-- (Carbonate)
Na+ (Sodium) SO4-- (Sulphate)
Fe++ (Iron) Cl- (Chloride)
Al+++ (Aluminium) NO3- (Nitrate)
PO4--- (Phosphate)
SiO2 (Silica)
3.1.1) Pre-Treatment of Water :-
analysis with Modified Design
19
Fig 3.1 Feed Water Treatment
3.1.1.1) Clarification:-
Pre- treatment to raw water is mainly to make it suitable for further processing of
water by Deionization units.
The water entering De-mineralizer plant should be free from suspended, colloidal
and organic impurities and the process of pretreatment plays a vital role in
ensuring proper feed input is made to Deionization units.
Presence of such suspended impurities adversely affects the deionization
properties of the resins, which will affect the end quality of Demineralized water.
analysis with Modified Design
20
Suspended & colloidal particles are removed by clarifying the water in a
clariflocator aided by suitable coagulating agents. It is further chlorinated to
achieve effective oxidation to combat organic contamination.
3.1.1.2) Precipitator Clarifier Section:-
A precipitator inlet flow control valve controls the raw water inlet flow into the
clarified water basin, through a level controller.
A manual by-pass valve is also provided to the level control valve, so that in case of
problem in the level control valve, manual operation can be done to maintain the
level.
The raw water enters the inner mixing zone through an open channel from the top and
flows downward into the inner conical tank.
The chemicals are let into the open channel to get mixed thoroughly with the raw
water flowing along the open channel into the mixing chamber. A water flow
indicating mechanism is fitted in the open channel to indicate the raw water flow.
Ferrous sulphate solution is delivered into the “Precipitator” by means of twin head
proportional feed 5% solution dosing pump.
The following chemical equations illustrates the chemical reaction of lime with the
calcium and magnesium bicarbonates:
Ca ( OH ) 2 + CO2 CaCO3↓ + H2O
Ca ( OH )2 + Ca ( HCO3 )2 2CaCO3↓ + 2H2O
2Ca ( OH )2 + Mg ( HCO3 )2 MgCO3 + CaCO3↓ + 2H2O
analysis with Modified Design
21
Ca ( OH )2 + MgCO3 Mg( OH )2↓ + 2CaCO3↓
The chemical reaction of Ferrous Sulphate with calcium bicarbonate is as
illustrated below:
4FeSo4 + 4Ca (HCo3) 2 + O2 4Fe ( OH )3 + 4CaSo4 + 8 Co2 + 12 H2O
(Insoluble)
The colloidal produced by Ferric Hydroxide in this reaction is negatively charged,
and is an effective coagulant of the positively charged, colloidal precipitates
formed in the reaction of Lime with salts causing temporary hardness.
The precipitated chemical in this reaction with the Calcium and Magnesium salts,
form an effective sludge in layers, which can be easily removed by blowing down.
Whatever the residual calcium, magnesium and sodium salts and silica still
present in the clarified water are removed by the successive ion exchange process
with the resin beds in the water de-mineralizing plant.
3.1.1.3) Filtration:-
Water filtration is the process of separating suspended and colloidal impurities
from water by passage through a porous medium. A bed of granular filter material
or media is used in most plant application.
A filter may be defined simply as a device consisting of a tank, suitable filter
media and necessary piping, valves and controls.
Filters are designed for the following:
analysis with Modified Design
22
Gravity flow: with natural head of water above the filter bed and low point of
discharge at the filter bottom, providing the pressure differential needed to move
the water through the filter bed.
Pressure units: which, as their name implies, are operated on line, under service
pressure, filtering the water as it flows the tank on its way to service or storage
Backwashing:-
When differential head between inlet and outlet increases, the filters must be taken
out of service and backwashed for removing accumulated dirt and sludge
materials.
For back wash the flow direction is reversed that is the inlet is given at the bottom
and water from the top is delivered out to open canal.
When the water flows in reverse direction it carries all the accumulated dirt and
sediments and throws out along with the water. The back washing is to be done
until the out flowing water is perfectly clear of all accumulated sediments.
Chlorine removal:-
To avoid algae formation chlorine is dosed into raw water, before the process of
clarification in the clariflocator.
Presence of chlorine is harmful to the Ion Exchange Resin and it is essential to
ensure that even the traces of chlorine are not present in the clarified and filtered
water, before admission to deionizing unit.
Hence before admission to cation vessel, the water is once again filtered treated in
a vessel containing a bed of Activated Carbon. Activated Carbon Bed absorbs left
over chlorine and the organic matters and feeds clear water to the ion exchange
vessels.
3.1.2) De-mineralization:-
analysis with Modified Design
23
Demineralization is the removal of dissolved ionic impurities that are present in
water. Demineralized water is commonly produced by one or a combination of the
following processes:
1. Ion exchange
2. Membrane desalination
3. Thermal desalination
The method selected to produce demineralized water depends on the quality of the
influent water, the required quality of the effluent water, the availability of resources
such as regenerant chemicals and waste water treatment and disposal requirements.
The economics of the processes that produce acceptable effluent quality must be
evaluated to determine the most cost-effective method for a specific application.
3.1.2.1) Ion Exchange Process:-
Basically the minerals present in water are in ionized condition. Ion exchange
demineralization therefore is one of the most important and widely applied
processes for the production of high-purity water for power plant services, and
it is accomplished using resins that exchange one ion for another.
Cation resins are solid spherical beads with fixed negatively charged sites and
exchangeable positively charged sites. Anion resins are solid spherical beads
that have fixed negatively charged sites and exchangeable negatively charged
sites.
In their regenerated state for demineralization applications, Cation resins are
in the hydrogen form and anion resins are in the hydroxide form. The reactions
of the resin beads with the dissolved impurities in the water are represented by
the following:
Cation resin: R-H+ + C+ ↔ R-C+ + H+
analysis with Modified Design
24
2R-H+ + C2+ ↔ R2-C2 + 2H+
Anion resin: R+OH- + A- ↔ R+A- + OH-
2R+OH- + A2- ↔ R2+A2 + 2OH-
Where, R = resin matrix and fixed charge site;
C = cations such as Ca2+, Mg2+, and Na+; and
A = anions such as HCO3-, Cl-, and SO4
-2
The hydrogen ions (H+) displaced from the cation resin react with the
hydroxide ions (OH-) displaced form the anion resin. The net effect is the
dissolved ions are removed from the water and replaced by pure water (H2O).
The ion exchange resins are contained in ion exchange pressure vessels. The
ion exchange resin in the vessels is referred to as the resin bed. This process of
exchanging dissolved impurities is cyclic.
When a resin bed site is exchanged with a dissolved ion, the site becomes
“exhausted” and cannot remove other impurities without releasing an
impurity.
Exhausted resins must be regenerated to return the resin beads to the original
hydrogen form for cations and hydroxide form for anions before further ion
exchange can take place.
Cation resins are commonly regenerated with a strong acid solution of either
sulfuric or hydrochloric acid.
Sulfuric acid does not present the fuming problems associated with
concentrated hydrochloric acid and is easier to handle (material selection).
Consequently, sulfuric acid is frequently the recommended regenerant for
cation resins.
analysis with Modified Design
25
Anion resins are commonly regenerated with a sodium hydroxide solution. As
can be seen from the regeneration reactions listed below, regeneration is the
reverse reaction to the impurity exchange reactions.
Cation resin regeneration: 2R-C+ + H2SO4 ↔ 2R-H + C2+SO4
2-
R2-C2+ + H2SO4 ↔ 2R-H+ + C2+SO4
2-
Anion resin regeneration: R+A- + NaOH ↔ R+OH- + Na+A-
R2+A2- + 2NaOH ↔ 2R+OH- + Na2
+A2-
3.1.3) Chemical conditioning of Boiler water:-
Demineralization of water renders raw water fit for use as make up and feed to a
boiler. Just feeding a boiler with Demineralize water, which is free of all
impurities, alone, will not suffice in reality due to the following reasons.
a) When the steam is continuously being generated and released for process,
the water inside the drum gets more and more concentrated, even with the
very little and negligible level of impurity in feed water.
b) Further the pH of Demineralized water normally remains to be close to
neutral and will induce low pH corrosion of tube and pipe materials.
c) Demineralized water when under storage absorbs atmospheric air and the
level of dissolved Oxygen in water increases. Presence of Oxygen in feed
water again renders it corrosive.
Chemical treatment is done at various stages for feed and boiled water, steam and
return condensate, in order to ensure adequate protection is established over the
entire system, to help prevention of direct attack on parent metal by the corrosive
elements present in water / steam cycle.
analysis with Modified Design
26
The chemical treatment technique is based on several factors. While the overall
conditioning concept remains the same, there would be variations in the methods
adopted and the residual levels optimized, it depends mainly on:
a) Deferent grades of ferrous and alloy metals which are deployed in the
design and manufacturing of various pressure part components, such as,
water wall tubes, headers, raiser tubes, economizers, super heaters,
reheaters etc. and so many other equipment down the line such as turbines,
condensers, various stages of regenerative system heaters and the pumps,
b) Working temperature and pressure at which the steam is generated for
supply to end users,
c) The type of fuel used and the firing system adopted,
d) Release of heat flux density, depending on the fuel fired and the design
and size of the furnace,
e) Capacity of boiler for steam generation and the level of steam purity
expected,
f) Quality and quantity of condensate recirculated within the system.
The condensate extracted from the Condenser is passed through a De-aerator to
get rid of dissolved oxygen, by mechanical stripping action.
The feed water is then chemically conditioned further with dosing of chemicals to
ensure that the dissolved oxygen content of the water is reduced to the minimum.
Hydrazine hydrate is normally employed for this purpose.
analysis with Modified Design
27
3.2) De-Aerator:-
3.2.1) Function Of De-Aerator:-
• To remove the oxygen from feed water to be fed to Boiler.
• It is a direct contact type heater and is located between LP heater and Boiler feed
pump in feed water cycle.
• The steam from suitable turbine stage is drawn to heat the condensate which is broken
in fine particles for effective heating and mass transfer on non-condensable gases.
3.2.1) Flow Arrangement :-
The condensate to be de aerated enters the chamber at a top and is sprayed by variable
orifice spray valves. The water then falls through perforated tray stack or spill over
tray track by gravity.
The condensate is divided in to fine droplets and comes in the contact with the steam
resulting in release of non-condensable gases carried by steam moving up wards.
The condensate leaving the de aerator enters and collected to feed storage tank and
goes to Boiler feed pump
3.2.2) Design And Construction:-
The De-aerator removes the non-condensable gases by heating the condensate which
reduces the solubility of non-condensable gases and then allow mass transfer time to
reduce non condensable further.
The steam flowing upward provides the atmosphere for mass transfer and condensate
droplets while carrying away non condensable gases. The trays divide the condensate
in to fine droplets so that heating and mass transfer is achieved quickly.
The steam admittance in storage tank provides steam blanket over stored condensate
and thus eliminate sub cooling and re absorption of gases.
analysis with Modified Design
28
Fig 3.2 De-aerator
3.2.3) Main Parts Of De Aerating Header:-
1) Shell:-
It is fabricated from steel plate of boiler quality closed with dished end. The shell
is mounted over the feed storage tank. It contains steel trays. The distribution
chamber is located at the top in which spray valves are provided for spraying
condensate.
2) Spray Valves And Trays:-
• Spray valves are spring loaded disc. The variable opening is controlled by flow.
analysis with Modified Design
29
• The tray design is of two type (1) Perforated trays and
(2) Spill over trays.
• Perforated trays have no of small size holes through condensate falls down. The
annual and central opening is for flow velocity of steam, non-condensable and
pressure equalization.
• In case of spill over tray a series of channel type trays are arranged such that,
condensate spills over from one layer to other layer.
3.2.4) Accessories:-
1) Safety relief valve
2) Orifice plate
3) Vacuum breaker valve
4) Vent and drain valve
5) Stand pipe
6) Isolation valves for stand pipe and instruments
7) Level gauge
8) Level switch
9) Pressure gauge
10) Temperature gauge
analysis with Modified Design
30
3.3) Quality of feed water to boiler:-
Quality requirement for feed water is very much dependent on drum operating
pressure. Hence recommended feed water quality is always expressed for a
particular range of boiler operating pressure.
Table No. 3.3.1 :- Quality of feed water
Drum operating Pressure Kg/Cm2 60 80 100 120 130 &
above
pH at 25 °C 8.5~9.
0
8.5 ~
9.0
8.7 ~ 9.0 8.8 ~ 9.2 8.8~ 9.2
Electrical conductivity at 25 °C in
micro mhos/cm
< 0.5 < 0.5 < 0.4 < 0.3 < 0.2
Economizer inlet < 0.01 < 0.01 < 0.005 < 0.005 < 0.005
Total iron ( Fe ppm ) < 0.03 < 0.01 < 0.01 < 0.01 < 0.01
Total copper ( Cu ppm ) <
0.005
< 0.005 < 0.003 < 0.003 < 0.003
Total iron copper & nickel ppm < 0.03 < 0.02 < 0.02 < 0.02 < 0.01
Total silica ( SiO2 ppm ) < 0.02 < 0.02 < 0.02 < 0.02 < 0.01
Carbonic acid (CO2 ppm ) Nil Nil Nil Nil Nil
Organic matter mg KmnO4/Litre Less than 0.1 ppm is considered tolerable
Oil ppm Nil Nil Nil Nil Nil
Hydrazine N2H4 ppm ) < 0.1 < 0.05 < 0.05 < 0.02 ~
0.05
< 0.02
analysis with Modified Design
31
MODIFIED DESIGN Chapter-4
4.1) Types of Modified Design
There are six types of modified design
1) Boiler feed pump and feed control design
2) Arrangement of Orifice Meter
3) Re-heater design
4) Piping Design
5) Design of Cooling Water Sump
6) Air Instrument design
4.2) Detail Description Of Designs:-
4.2.1) Boiler feed pump and feed control design:-
Fig 4.2.1(A), (B) and (C) shows the present & modified design of feed control
valve arrangement.
In fig. 4.2.1 (a) drum level controlled by the feed control valve by 60-70 percent
open and the differential pressure across the feed control valve is 15 kg per square
senti-meter by boiler feed pump scoop.
Fig.4.2.1 (b) shows the signal flow arrangement of feed water flow, drum level
and steam flow.
Fig.4.2.1 (c) shows the new modified arrangement of the whole control system.
So, the new drum level controlled by boiler feed pump scoop and feed control
valve 1 and 2 keeps fully open.
Now in modified design the differential pressure across the control valve is 0 to
0.5 kg per square senti-meter.
analysis with Modified Design
32
Fig 4.2.1(a) Feed Control Valve
Fig 4.2.1(b) Signal Flow
analysis with Modified Design
33
Fig. 4.2.1(c) Modified Boiler Feed Pump & Feed Control Valve
4.2.2) Arrangement of Orifice Meter :-
Fig. 4.2.2 (a) and (b) shows the piping arrangement of water flow form boiler
feed pump to the super heater with control valve arrangement.
In fig.4.2.2 (a), when the inlet pressure is 165 kg per senti-meter square then at
outlet the orifice meter gives the pressure reading is 160 kg per senti-meter
square. That means there is loss of pressure between inlet and outlet by the
control valve.
In fig. 4.2.2 (b) show the rearrangement of orifice meter to solve this pressure
drop across the boiler feed pump and super heater.
analysis with Modified Design
34
Fig. 4.2.2(a) Arrangement of Orifice Meter
Fig. 4.2.2 (b) New Arrangement Of Orifice Meter
analysis with Modified Design
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4.2.3) Re-Heater design:-
Fig.4.2.3 shows the water flow from boiler feed pump to the re-heater.
Present pressure in boiler feed pump is 150 kg per senti-meter square. Due to this high
pressure the damage occurs in the spray nozzle.
To prevent this damage put the pressure control valve ahead of spray control valve
and also make one reservoir tank between the controller and spray control valve.
By this the pressure is reduced up to 50 kg per senti-meter square in reservoir tank.
So, in controller the pressure up to 0 to 100 kg per senti-meter square is maintained.
Fig 4.2.3 Re- heater Design
4.2.4) Piping Design:-
Fig. 4.2.4 (a) and (b) shows the piping arrangement of boiler feed pump line.
As shown in fig.4.2.4 (a) the pressure difference between boiler feed pump & header
pressure is 10 kg per senti-meter square. This pressure difference is occurs due to “T”
joint of the pipe line.
analysis with Modified Design
36
This pressure difference can be reduced by changing “ T ” type arrangement into “ C
” or “ Y ” type arrangement as shown in fig. 4.2.4 (b).
Due to “C” or “Y” type arrangement smooth flow of water is made.
Fig. 4.2.4(a) Piping Design
analysis with Modified Design
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Fig. 4.2.4(b) New Piping Design
4.2.5) Design of Cooling Water Sump:-
The simple design is shown in fig. 4.2.5.
In cooling water sump house, make the simple spray type arrangement. By this the
natural air passes through the spray and natural cooling is occurs.
Due to this the temperature of the water can be reduced. So, cooling process can be
made easily in cooling water sump house.
analysis with Modified Design
38
Fig. 4.2.6 Cooling Water Sump Design
4.2.6) Air Instrument Design:-
Due to continuous use of air operated instrument (vacuum pressure operated), amount
of water and silica particles are increases which cause to stop the working of
instruments.
So, to solve this problem make one reservoir tank near the main valve. Due to this
silica and water particles fed in bottom of the tank and fresh air can be made and life
of the instrument can be increases.
Fig. 6 (a) and (b) shows arrangement of reservoir tank with control valve.
analysis with Modified Design
39
Fig. 4.2.6(a) Air Instrument Design
Fig. 4.2.6 (b) New Air Instrument Design
analysis with Modified Design
40
4.2.7) ADVANTAGES OF MODIFICATION:-
Followings are the advantages of Modified Design.
Ampere loading of Boiler Feed Pumps reduced by 40 A per Boiler Feed Pump.
Reduction in differential pressure up to 15 kg/cm2.
Reduction in feed control valve maintenance.
Reduction in generation cost.
Reduction in load on boiler master controller
Increases plant efficiency.
Reduction in instrument damages.
Easy handling of flow.
Better cooling of water in cooling water sump.
Increases instruments life.
Smooth flow is made.
Smooth control of Boiler Drum Level
Minimum movement of Boiler Feed Pump Scoop.
analysis with Modified Design
41
CONCLUSION (WASTE DOCUMENTATION) Chapter-5
4.1) Types of Waste:- Solid & Liquid
4.2) Quantity of Waste: - As Per Defect.
4.3) Detailed Description:-
Waste of material is subjected to defect occurs in the Boiler. If problem
caused in it is large than amount of waste material is more.
But when boiler tube is fail then 1000 kiloliter water is waste. The water
used in it is distilling water and it cost is 8 Rs. Per liter. As per market rate.
So, minimum wastage of money is 80 lakhs per 1 times of failure. If the
failure is small or big. This is minimum cost in industry for wastage in
distilling water.
Another loss is Generation loss which occurs due to starting of Boiler. And
that cost is Rs.1.5 cr.
4.4) Modified Design:-
The modified design is very useful to industry to reduce the generation
cost and maintenance of control system.
analysis with Modified Design
42
-: REFERENCES:-
Books:-
1) Reduced Boiler Tube Failure Analysis,
B & W (Babcock & Wilcox) power generation Group.
2) Power plant engineering, by Arora Domkundwar, Dhanpat
Rai & co.
Websites:-
www.swcc.gov.sa
www.PDHcenter.com