Biomass Replacing in a Pulverized Coal Utility Boiler - Final Version

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    Biomass Replacing in a Pulverized Coal Utility Boiler:

    Prediction of Performance and Pollutant Emission Using

    CFD Tools

    Antofagasta, Chile.

    Cornejo P. (1), Prez R.(2), Flores M.(3), Garca X.(2)(1) Mechanical Engineering Department, University of Concepcin

    (2) Chemical Engineering Department, University of Concepcin

    (3) Technological Development Unit, University of Concepcin

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    Conclusions

    Results

    Model Validation

    Mathematical Models

    Case to Study

    Photography : Campanil University of Concepcin

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    Photography Unit 15 . Tocopilla, Chile.

    What are the effects that will be produce by the inclusion of

    biomass in the Unit-15?

    o

    Boiler type :Pulverized Coal Boilero Location : Tocopilla, Chile.

    o Owner : E-CL, GDF-Suez

    o Power : 150 MWe

    o Number of Burners : 4 burner by level

    o Number of levels : 4 levels

    o Primary fuel : Burner Levelo Adaro coal : levels B & C

    o Hatillo coal : levels A & D

    o Secondary Fuel :

    o Pine chips : Level A

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    Adaro Hatillo Biomass

    Proximate Analysis (As received)

    Fixed Carbon (%)Volatil Matter (%)

    Moisture (%)

    Ash (%)

    34.0%36.0%

    28.0%

    2.0%

    44.9%35.3%

    14.2%

    5.6%

    11.5%62.8%

    25.4%

    0.3%

    Ultimate Analysis (Dry basis)

    C (%)

    H (%)

    O (%)N (%)

    S (%)

    72.7%

    4.8%

    21.4%0.9%

    0.2%

    79.0%

    5.4%

    13.1%1.7%

    0.8%

    48.9%

    6%

    44.99%0.1%

    0.01%

    Properties

    LHV (kJ/kg)

    Density (kg/m3)

    R-R dispersion Factor

    R-R mean dia. (mm)

    20524

    972

    0.68 / 1.42

    0.09 / 0.15

    25623

    972

    1.09 /1.01

    0.11 / 0.09

    11190

    1.09

    0.11

    Op. variable / burner level A B C D

    Coal flow rate (ton/h)

    Biomass flow rate (ton/h)

    Primary air flow (ton(/h)Secondary air flow (ton/h)

    11.6

    2.9

    2496.3

    14.5

    0

    2796.3

    14.3

    0

    2496.3

    14.5

    0

    2596.3

    Primary air temperature (K)

    Secondary air temperature (K)

    Walls temperature (K)

    Wall internal Emissivity

    Gauge Pressure Outlet (Pa)

    611

    841

    373

    0.85

    -3056

    Level A of Burners Biomass + Pulverized Coal

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    o Gas-Solid Approach : Eulerian - Lagrangian

    o Gas phase : Reynolds Averange Navier-Stokes (RANS)

    o Turbulence Model : k-epsilon

    o Fuel particle sizes : Rosin-Rammler distribution.

    o Devolatilization model : two-competing rates.

    o Heterogenous combustion: kinetic/diffussion limited

    model.

    o Radiation Model : Discrete Ordinates

    o Absorption coef.Weighted sum of gray gases model.

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    o Gas-Solid Approach : Eulerian - Lagrangian

    o Gas phase : Reynolds Averange Navier-Stokes

    o Turbulence Model : k-epsilon

    o Fuel particle sizes : Rosin-Rammler distribution.

    o Devolatilization model : two-competing rates.

    o Heterogenous combustion: kinetic/diffussion limited

    model.

    o Radiation Model : Discrete Ordinates

    o Absorption coef.Weighted sum of gray gases model.

    Conditions and parameters was presented in the past slide.

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    o Model was validated by comparing the simulated concentrations of flue

    gas with the experimental available data for operation with coal.

    o

    Errors are close 1% , 6% and 9% for concentration of O2, CO2and SO2.o The experimental and model CO concentration were found near to zero.

    Therefore were difficult to establish a relative error .

    10

    9

    9.4

    9.1

    CO2 O2

    8.4

    8.6

    8.8

    9

    9.2

    9.4

    9.6

    9.8

    10

    10.2

    Percentage(%)

    Experimental

    Model

    20

    550

    0

    599

    CO SO2

    0

    100

    200

    300

    400

    500

    600

    700

    Concentration[m

    g/Nm3] Experimental

    Model

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    o

    The simulation reveals for co-firing case, a decreaseof the zones of burnouts particles compared to

    normal operation.

    o The major reactivity of the biomass than the coal,

    allowing to the biomass particles burning faster than

    coal, and collaborating with the coal particleignition.

    Co-firing 95% coal5% biomass

    Normal Operation100% coal

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    o The lower LHV of biomass than coal, provides zones

    with lower temperatures than those obtained for

    coal operation.

    o The maximum temperature achieved is 1820K for

    coal combustion and 1710 K for co-firing, leading to

    a decrease in the formation of thermal-NOx.

    o The mean temperature has slightly decrease < 0,5%.

    Co-firing 95% coal5% biomass

    Tmean = 1460 [K]

    Normal Operation100% coal

    Tmean= 1476 [K]

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    o The velocity field has not greattly affected by the

    inclusion of the biomass into the process,

    considering the flame vortex is maintaing far away

    from the boiler walls.

    o

    For the co-firing case, it is observed a reduction inthe flue gas mean velocity at the burner level A

    close to 3%, associated to fast combustion of the

    biomass particles, near to the burner zone, leading

    an increase in the diameter of the flame vortex.

    Co-firing 95% coal5% biomass

    Vmean = 11,3 [m/s]

    Normal Operation100% coal

    Vmean= 11,7 [m/s]

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    o The mean turbulence intensity for coal combustion is

    15.8% and 20.1% for co-firing conditions.

    o The values are agree with the turbulence intensity

    reported by Baxter et alfor pulverized coal combustion

    (10% typical, 30% maximum).

    o Tangential distribution of burners generating highlevels of turbulence, optimazing fuel-air mixture and

    improving the combustion efficiency.

    Baxter L. Ash deposit formation and deposit propertiesA comprehensive

    Summary of Reasearch conducted atSandias

    Combustion Research Facility. Sandia

    Report. SAND2000-8253.

    Co-firing 95% coal

    5% biomassTImean = 20,1%

    Normal Operation100% coal

    TImean= 15,8%

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    0.000

    0.001

    0.002

    0.0030.004

    0.005

    0.006

    0.007

    0.008

    0 4 8 12 16 20 24 28 32 36 40CO

    Conc.perp

    owerunit

    (mg/Nm3M

    WT)

    Axial Position (m)

    CO - Co-firing

    CO - Coal comb.

    0.60

    0.80

    1.00

    1.20

    1.40

    1.60

    1.80

    0 4 8 12 16 20 24 28 32 36 40

    SO2Conc.perpowerunit

    (mg/Nm3MWT)

    Axial Position (m)

    SO2 - Co-firing

    SO2 - Coal comb.

    5.0

    6.0

    7.0

    8.0

    9.0

    10.0

    0 4 8 12 16 20 24 28 32 36 40

    Percentageo

    fCO2(%)

    Axial Position (m)

    %CO2 - Co-firing

    CO2 - Coal Comb.

    600

    800

    1000

    1200

    1400

    1600

    0 4 8 12 16 20 24 28 32 36 40

    MeanTemperature(K

    )

    Axial Position (m)

    T - Co-firing

    T - Coal Comb.

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    0.000

    0.001

    0.002

    0.0030.004

    0.005

    0.006

    0.007

    0.008

    0 4 8 12 16 20 24 28 32 36 40CO

    Conc.perp

    owerunit

    (mg/Nm3M

    WT)

    Axial Position (m)

    CO - Co-firing

    CO - Coal comb.

    0.60

    0.80

    1.00

    1.20

    1.40

    1.60

    1.80

    0 4 8 12 16 20 24 28 32 36 40

    SO2Conc.perpowerunit

    (mg/Nm3MWT)

    Axial Position (m)

    SO2 - Co-firing

    SO2 - Coal comb.

    5.0

    6.0

    7.0

    8.0

    9.0

    10.0

    0 4 8 12 16 20 24 28 32 36 40

    Percentageo

    fCO2(%)

    Axial Position (m)

    %CO2 - Co-firing

    CO2 - Coal Comb.

    600

    800

    1000

    1200

    1400

    1600

    0 4 8 12 16 20 24 28 32 36 40

    MeanTemperature(K

    )

    Axial Position (m)

    T - Co-firing

    T - Coal Comb.

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    0.000

    0.001

    0.002

    0.0030.004

    0.005

    0.006

    0.007

    0.008

    0 4 8 12 16 20 24 28 32 36 40CO

    Conc.perp

    owerunit

    (mg/Nm3M

    WT)

    Axial Position (m)

    CO - Co-firing

    CO - Coal comb.

    0.60

    0.80

    1.00

    1.20

    1.40

    1.60

    1.80

    0 4 8 12 16 20 24 28 32 36 40

    SO2Conc.perpowerunit

    (mg/Nm3MWT)

    Axial Position (m)

    SO2 - Co-firing

    SO2 - Coal comb.

    5.0

    6.0

    7.0

    8.0

    9.0

    10.0

    0 4 8 12 16 20 24 28 32 36 40

    PercentageofCO2(%)

    Axial Position (m)

    %CO2 - Co-firing

    CO2 - Coal Comb.

    600

    800

    1000

    1200

    1400

    1600

    0 4 8 12 16 20 24 28 32 36 40

    MeanTemperature(K

    )

    Axial Position (m)

    T - Co-firing

    T - Coal Comb.

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    Co-firing 95% coal5% biomass

    RHFmean= 165,3 [MW]

    100% coal

    RHFmean= 166,3 [MW]

    Co-firing 95% coal5% biomass

    THFmean= 198,1 [MW]

    100% coal

    THFmean= 199,2 [MW]

    Total Heat FluxRadiation Heat Flux

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    o A CFD model was developed and validated using field concentration of

    the flue gas with a low relative error.

    o It was found that a 5% mass replacement of coal by feeding biomass into

    level A reduces the SO2and O

    2concentrations in a 5% and 1.1%

    respectively. On the other hand, the concentration of CO is maintained

    near zero and CO2(9.4%) is kept similar to the reference condition.

    Meanwhile, flue gas mean temperature it decrease by 2% for co-firing

    case.

    o

    The inclusion of biomass into the coal combustion process, presentscomparatives advantages, allowing a decreasing of pollutant emissions

    concentrations, without greatly affecting the vorticity, residence time of

    the fuel particles, radiate and convective heat flux and flue gas

    temperature inside the boiler.

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    o E-CL company and his workers for their support in providing key

    boundary conditions and measurements validations for the study.

    o

    FONDEF Project D09I1173 for financial Support of this work.o CONICYT for give me a scholarship support.

    o Mechanical Engineering Department of University of Concepcin, for

    the possibility to use his computational facilities.

    o Technological Development Unit for his financial support and guide.

    o Chemical Engineering Department of University of Concepcin for

    giving me the opportunity to perform my PhD studies.

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    o Pulverized Coal Combustion

    o Study the effects to incorporate biomass in others levels of

    burners (B,C and D) and other types of biomass, into a

    pulverized coal combustion boiler.o We expect the power plant provide experimental data

    from his co-firing test at industrial scale.

    o Fluidized Bed Combustion

    o Develop co-firing experiences with several types of biomass

    in a pilot scale Fluidized Bed Combustor to study the effectto incoporate biomass into a pilot scale combustor.

    o Study and modelling the ash deposition at pilot scale, using

    cfd tools and the develop of co-firing tests into a fluidized

    bed combustor.

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    Thank You Very much for your attention

    Questions?

    Dr (c). Ing. Rubn A. Prez J.

    [email protected]

    Antofagasta, Chile.

    mailto:[email protected]:[email protected]