Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated...

12
Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light Anak Bhandari, 1, * Børge Hamre, 1 Øvynd Frette, 1 Lu Zhao, 1 Jakob J. Stamnes, 1 and Morten Kildemo 2 1 Department of Physics and Technology, University of Bergen, N-5007 Bergen, Norway 2 Department of Physics, Norwegian University of Science and Technology, N-7491 Trondheim, Norway *Corresponding author: [email protected] Received 15 April 2011; accepted 19 April 2011; posted 29 April 2011 (Doc. ID 145271); published 25 May 2011 A Lambert surface would appear equally bright from all observation directions regardless of the illumi- nation direction. However, the reflection from a randomly scattering object generally has directional variation, which can be described in terms of the bidirectional reflectance distribution function (BRDF). We measured the BRDF of a Spectralon white reflectance standard for incoherent illumination at 405 and 680 nm with unpolarized and plane-polarized light from different directions of incidence. Our mea- surements show deviations of the BRDF for the Spectralon white reflectance standard from that of a Lambertian reflector that depend both on the angle of incidence and the polarization states of the incident light and detected light. The non-Lambertian reflection characteristics were found to increase more toward the direction of specular reflection as the angle of incidence gets larger. © 2011 Optical Society of America OCIS codes: 120.5410, 120.5820, 290.1483, 290.5880. 1. Introduction Spectralon white reflectance standards are the International Commission on Illumination (CIE)- recommended light diffusing surfaces that are com- mercially available from Labsphere Corporation [1]. They are made of thermoplastic materials, which are resin machined into flat, thermally stable, high- permittivity surfaces with porosity within the top layer (generally a few tenths of a millimeter thick) that randomizes the phase of the incident lightdue to internal multiple reflectionsto produce dif- fuse reflected light. Because of their stable optical properties over the ultravioletvisiblenear-infrared spectral region, Spectralon white reflectance stan- dards are widely used as reference standards for the calibration of photometric instruments on the ground as well as on-board satellites. The same materials are also used to make integrating spheres, which are reflectance accessories [2] for the creation of diffuse light sources. In the visible spectral range, the hemispherical reflectance of the Spectralon white reflectance standard is claimed to be larger than 98% [3] with Lambertian characteristics. As mentioned above, the surface of a Spectralon reflection standard is porous, implying that the dif- fusely reflected light, to a significant degree, may be due to internal multiple reflections beneath its sur- face. For that reason, a random-surface model may not be adequate for simulating the Spectralon bi- directional reflectance distribution function (BRDF). Instead, one might use a model similar to that pres- ented recently [4] to simulate radiation transport in coupled atmospheresnowiceocean systems, in which case there are contributions to the diffuse 0003-6935/11/162431-12$15.00/0 © 2011 Optical Society of America 1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2431

Transcript of Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated...

Page 1: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

Bidirectional reflectance distribution functionof Spectralon white reflectance standardilluminated by incoherent unpolarized

and plane-polarized light

Anak Bhandari,1,* Børge Hamre,1 Øvynd Frette,1 Lu Zhao,1

Jakob J. Stamnes,1 and Morten Kildemo2

1Department of Physics and Technology, University of Bergen, N-5007 Bergen, Norway2Department of Physics, Norwegian University of Science and Technology, N-7491 Trondheim, Norway

*Corresponding author: [email protected]

Received 15 April 2011; accepted 19 April 2011;posted 29 April 2011 (Doc. ID 145271); published 25 May 2011

A Lambert surface would appear equally bright from all observation directions regardless of the illumi-nation direction. However, the reflection from a randomly scattering object generally has directionalvariation, which can be described in terms of the bidirectional reflectance distribution function (BRDF).We measured the BRDF of a Spectralon white reflectance standard for incoherent illumination at 405and 680nm with unpolarized and plane-polarized light from different directions of incidence. Our mea-surements show deviations of the BRDF for the Spectralon white reflectance standard from that ofa Lambertian reflector that depend both on the angle of incidence and the polarization states of theincident light and detected light. The non-Lambertian reflection characteristics were found to increasemore toward the direction of specular reflection as the angle of incidence gets larger. © 2011 OpticalSociety of AmericaOCIS codes: 120.5410, 120.5820, 290.1483, 290.5880.

1. Introduction

Spectralon white reflectance standards are theInternational Commission on Illumination (CIE)-recommended light diffusing surfaces that are com-mercially available from Labsphere Corporation [1].They are made of thermoplastic materials, whichare resin machined into flat, thermally stable, high-permittivity surfaces with porosity within the toplayer (generally a few tenths of a millimeter thick)that randomizes the phase of the incident light—due to internal multiple reflections—to produce dif-fuse reflected light. Because of their stable opticalproperties over the ultraviolet–visible–near-infraredspectral region, Spectralon white reflectance stan-dards are widely used as reference standards for

the calibration of photometric instruments on theground as well as on-board satellites. The samematerials are also used to make integrating spheres,which are reflectance accessories [2] for the creationof diffuse light sources. In the visible spectral range,the hemispherical reflectance of the Spectralonwhite reflectance standard is claimed to be largerthan 98% [3] with Lambertian characteristics.

As mentioned above, the surface of a Spectralonreflection standard is porous, implying that the dif-fusely reflected light, to a significant degree, may bedue to internal multiple reflections beneath its sur-face. For that reason, a random-surface model maynot be adequate for simulating the Spectralon bi-directional reflectance distribution function (BRDF).Instead, one might use a model similar to that pres-ented recently [4] to simulate radiation transportin coupled atmosphere–snow–ice–ocean systems, inwhich case there are contributions to the diffuse

0003-6935/11/162431-12$15.00/0© 2011 Optical Society of America

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2431

Page 2: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

reflected light from a possible snow layer on top ofthe ice, a rough ice surface, and randomly locatedparticles (bubbles and brine pockets) within the ice.Such simulations, however, are beyond the scope ofthis paper.

For collimated incident light, Haner et al. [5] mea-sured the hemispherical reflectance from Spectralonand found its average value equal to 0:971� 0:04 forthe visible and near-infrared spectral regions. Such anonabsorbing surface should reflect the incidentlight equally in all directions with radiance propor-tional to the irradiance of the incident light. Vossand Zhang [6] found the reflectance characteris-tics of Spectralon white reflectance standards to benearly Lambertian only for illumination at normalincidence. Early et al. [7] found the BRDF of a Spec-tralon white reflectance standard to depend on theillumination and viewing directions, but their mea-surement results did not include polarization effects.Georgiev and Butler [8] studied aging effects on theSpectralon BRDF in the UV and visible spectralranges. They used polarized incident light but re-ported measurements only of unpolarized scatteredlight.

Haner et al. [9] measured the BRDF of a Spectra-lon white reflectance standard for coherent, plane-polarized illumination at four different angles ofincidence and concluded that the BRDF varied withthe observation angle, the angle of incidence, and thepolarization state of incident light. For illuminationthey used coherent laser light, which generatesspeckle [10,11] in the BRDF profile due to inter-ference effects. In contrast, we used incoherentillumination to avoid speckle effects and did mostmeasurements in a plane outside the plane of inci-dence. Also, we examined a Spectralon white reflec-tance standard (SRS-99-020) different from thatinvestigated by Haner et al. [9] (position 1 of Spectra-lon test sample number 12969). The effects on theBRDF of using polarized light from a 75W xenonlamp to illuminate a Spectralon white reflectancestandard was investigated by Georgiev and Butler[12], who found the BRDF of the Spectralon whitereflectance standard to strongly depend on the polar-ization state of the incident light.

When the incident light is polarized, the reflectedradiance will generally be partially polarized to a de-gree that depends on the nature of the random scat-tering process caused by the surface roughness aswell as by volume scattering events beneath the sur-face. As discussed by Germer [13], the scattering ofpolarized light from the Spectralon standard is likelyto be due mainly to volume scattering events.

A. BRDF

The reflectance of an object is generally quantifiedin terms of its albedo, which is the fraction of the in-cident radiative energy reflected from it. The albedois dimensionless, and it characterizes the total hemi-spherical reflectance, whereas the BRDF describeshow the reflectance varies as a function of illumina-

tion direction, observation direction, wavelength,and polarization. The BRDF ½sr−1� as defined byNicodemus [14] is the ratio of the reflected radi-ance L½W m−2 sr−1 � to the incident irradianceE½W m−2 �. It is an intrinsic optical property thatvaries from one surface to another, and it may alsovary with the position on a given surface.

Consider an angular beam of radiation of frequencyν that is incident on the surface of diffusely scatteringobject with radianceLðν; Ω0Þ ½W m−2 sr−1 �within acone of solid angle dω0 around the direction of inci-dence defined by the unit vector Ω0ðθ0;ϕ0Þ as illu-strated in Fig. 1, so that the irradiance Eðν; Ω0Þincident on the surface is given by Lðν; Ω0Þcos θ0dω0½W m−2 �. We let Lðν; Ω0; ΩÞ be the radianceof the reflected light leaving the diffusely scatteringobject in the observation direction given by the unitvector Ωðθ;ϕÞ, and we define the directional reflec-tance, or BRDF, as the ratio of the reflected radianceto the incident irradiance, i.e.,

ρðν; Ω0; ΩÞ ¼ Lðν; Ω0; ΩÞEðν; Ω0Þ

¼ Lðν; Ω0; ΩÞLðν; Ω0Þ cos θ0dω0 ½sr

−1�: ð1Þ

Note that Eq. (1) gives the scalar definition of theBRDF, which is appropriate for unpolarized illumina-tion and detection, and does not account for thepolarization states of the incident and scattered light.Adding the contributions to the reflected radiance inthe direction Ω from beams incident on the diffuselyscattering object in all directions Ω0, we obtain the re-flected radiance

Lðν; ΩÞ ¼Z2πdω0 cos θ0ρðν; Ω0; ΩÞLðν; Ω0Þ; ð2Þ

Fig. 1. Geometry and symbols for the definition of the BRDF. Thenormal to the surface area dA of a diffusely scattering object istaken to be along the z axis, and the incident beam along the unitvector Ω0ðθ0;ϕ0Þ is taken to lie in the x–z plane with azimuth angleϕ0 ¼ 0°. The observation direction is along the unit vector Ωðθ;ϕÞ,and α is the backscattering angle, which is given by α ¼ π −Θ,where cosΘ ¼ Ω0 · Ω, Θ being the scattering angle. When the azi-muth angle ϕ ¼ 0°, the scattering plane coincides with the plane ofincidence (the x–z plane).

2432 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011

Page 3: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

where the 2π underneath the integral sign indicatesintegration over the whole hemisphere of incidentdirections. If the reflected radiance from a diffuselyscattering object is the same in all directions of obser-vation Ω, regardless of the direction of incidence Ω0, itis said to be a Lambert reflector. Then the BRDFsimplifies to ρðν; Ω0; ΩÞ ¼ ρLðνÞ, where ρLðνÞ is theLambert reflectance, and the reflected radiance inEq. (2) becomes

Lðν; ΩÞ ¼ ρLðνÞZ2πdω0 cos θ0Lðν; Ω0Þ ¼ ρLðνÞEðνÞ: ð3Þ

For a collimated beam (see Fig. 2) with irradianceEsðνÞ normal to the incident beam direction Ω0, theincident radiance is given by [15]

Lsðν; Ω0Þ ¼ EsðνÞδðΩ0 − Ω0Þ¼ EsðνÞδðcos θ0 − cos θ0Þδðϕ0 − ϕ0Þ; ð4Þ

and the corresponding incident irradiance is

Eðν; Ω0Þ ¼Z2πdω0 cos θ0Lsðν; Ω0Þ ¼ EsðνÞ cos θ0: ð5Þ

From Eqs. (3) and (5), the reflected radiance from aLambert reflector due to a collimated incident beamis Lðν; ΩÞ ¼ ρLðνÞ cos θ0EsðνÞ, and the reflected hemi-spherical irradiance becomes

Eðν; Ω0Þ ¼Z2πdω cos θLðν; ΩÞ ¼ πρLðνÞEsðνÞ cos θ0:

ð6Þ

Thus, for a Lambert reflector, the ratio of the re-flected hemispherical irradiance to the irradianceof the incident collimated beam, called the irradiancereflectance or plane albedo, is given by [15]

ρðν; Ω0; 2πÞ ¼Eðν; Ω0Þ

EsðνÞ cos θ0¼ πρLðνÞ; ð7Þ

where the 2π argument emphasizes the integrationover the hemisphere. Because the irradiance reflec-tance or plane albedo in Eq. (7) must be less than orequal to unity, i.e., ρðν; Ω0; 2πÞ ≤ 1, a Lambert reflec-tance must satisfy the inequality ρLðνÞ ≤ 1=π for un-polarized light. In practice, it is difficult to realizea reflector with a BRDF that is equal to that of aLambert reflector for all illumination and observa-tion geometries.

B. Determination of the Incident Irradiance UsingReciprocity

At normal incidence (Ω0 ¼ −z), the reflected radiancefrom a Spectralon reflectance standard is the samefor all azimuthal directions so that the reflectedhemispherical irradiance becomes

Eðν;−zÞ ¼ 2πZ π=2

0Lmeasðν;−z; θÞ cos θ sin θdθ; ð8Þ

where Lmeasðν;−z; θÞ is the reflected radiance mea-sured at 5° intervals within the range of observationangles −90° ≤ θ ≤ 90°. We determined Eðν;−zÞ byusing the measured values of Lmeasðν;−z; θÞ for nor-mal incidence and performing the integration inEq. (8) numerically by approximating the integral bya sum in accordance with the trapezoidal rule.

The irradiance reflectance or plane albedo is givenas the ratio of the reflected hemispherical irradi-ance Eðν;−zÞ to the incident irradiance EsðνÞ [seeEq. (7)], i.e.,

ρðν;−z; 2πÞ ¼ Eðν;−zÞEsðνÞ ¼ 0:98; ð9Þ

where the final result in Eq. (9) is in accordance withthe manufacturer’s specification for the SRS-99-020Spectralon being examined. Thus, the incident irra-diance becomes EsðνÞ ¼ Eðν;−zÞ=0:98.

At normal incidence (Ω0 ¼ −z), the BRDF, which,as just mentioned, is independent of the azimuthangle ϕ, is given by

ρðν;−z; ΩÞ ¼ Lðν;−z; θ;ϕÞEsðνÞ ¼ 0:98

Lmeasðν;−z; θÞEðν;−zÞ : ð10Þ

The reciprocity principle implies that

ρðν; Ω0; ΩÞ ¼ ρðν;−Ω;−Ω0Þ: ð11Þ

Fig. 2. Schematic of collimated beam scattering geometry. Thesurface of a diffusely reflecting object lies in the vertical x–y plane,the incident beam is along the unit vector Ω0ðθ0;ϕ0 ¼ 0Þ, and theangle of incidence is θ0½0 ≤ θ0 ≤ 90°�. The observation direction isalong the unit vector Ωðθ;ϕÞ, and the polar angle of observationis θ½−90° ≤ θ ≤ 90°�. When the azimuth angle of observationϕ ¼ 0, the observation direction lies in the plane of incidence(the x–z plane). Note that θ ¼ α − θ0 ¼ π −Θ − θ0, where Θ is thescattering angle and α is the backscattering angle. The unit vectorse∥ and the e⊥ are parallel and perpendicular, respectively, to theplane of incidence.

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2433

Page 4: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

At non-normal incidence, we have

ρðν; Ω0;þzÞ ¼ ρðν;−z;−Ω0Þ ¼ ρðν;−z; θ0Þ

¼ 0:98Lmeasðν;−z; θ0Þ

Eðν;−zÞ ; ð12Þ

where the first equality sign follows from reciprocity,the second from the azimuth independence of theBRDF at normal incidence, and the third fromEq. (10), which is based on azimuth independenceof the BRDF at normal incidence plus the require-ment that the plane albedo be 98%.

From Eq. (1) it follows that the BRDF at non-normal incidence becomes

ρðν; Ω0; ΩÞ ¼ρðν; Ω0;þzÞ

Lmeasðν; Ω0; zÞþ Lmeasðν; Ω0; ΩÞ; ð13Þ

where the ratio ρðν; Ω0;þzÞ=Lmeasðν; Ω0; zÞ ensuresthat the correct value is obtained for Ω ¼ z. Substitut-ing in Eq. (13) from Eq. (12), we finally have

ρðν; Ω0; ΩÞ ¼ 0:98Lmeasðν;−z; θ0Þ

Eðν;−zÞLmeasðν; Ω0; ΩÞLmeasðν; Ω0; zÞ

;

ð14Þ

where Eðν;−zÞ is given in Eq. (8).

C. Polarization Effects

For a polarized collimated beam, we write the BRDFin the following way:

ρjkðΩ0; Ω; νÞ ¼LkðΩ0; ΩÞEs

j cos θ0½sr−1�; ð15Þ

where LkðΩ0; ΩÞ is the reflected spectral radiancefor k polarization in the direction Ω and Es

j is theincident irradiance normal to the incident beam di-rection Ω0 for j polarization. The subscripts j and krepresent the polarization states of the incidentand reflected light, respectively. When j ¼ u, the in-cident light is unpolarized, when j ¼ s or j ¼ p, theincident light is polarized perpendicular or parallelto the plane of incidence, which is spanned by Ω0and z. For example, when both the incident lightand the reflected light are unpolarized, then j ¼ k ¼u, and the BRDF is denoted by ρuu.

The BRDF due to an electromagnetic beam thatilluminates a rough surface [16] depends on the po-larization states of both the incident radiation andthe observed radiation, each being described by afour element quantity called the Stokes vectorI ¼ ½L∥;L⊥;U;V �T , where the superscript T denotesthe transpose. Here L∥ and L⊥ are the radiances ofthe radiation components that are respectively par-allel (i.e., along the unit vector e∥) and perpendicular(i.e., along the unit vector e⊥) to the plane of inci-dence, U is the degree of linear polarization in the

45°=135° plane, and V is the degree of circularpolarization. The unit vector e⊥ along the normalto the plane of incidence and the unit vector e∥, whichlies in the plane of incidence but normal to the unitvector s along the propagation direction, are definedsuch that e⊥ × e∥ ¼ s. This Stokes vector represen-tation is related to the more common one Is ¼½L;Q;U;V�T by L ¼ L∥ þ L⊥ and Q ¼ L∥ − L⊥. Whenlight is scattered by a rough surface, or by a collectionof particles, a four-by-four matrix, called the Muellermatrix, provides the linear transformation connect-ing the Stokes vector of the scattered radiation tothat of the incident radiation in the scattering plane,which is spanned by Ω0 and Ω. The elements of theMueller matrix contain information related to thesize, shape, and optical properties of the scatteringmedium. A complete description of the polarizedBRDF requires all elements of the Mueller matrix.However, the orthogonal states of plane-polarizedlight, which form a 2 × 2 submatrix in the upper-leftcorner of the Mueller matrix, determines the polar-izance [the degree to which incident unpolarizedlight becomes polarized into the parallel (p) andperpendicular (s) states].

We have taken a simplified approach to electro-magnetic scattering by a diffusely reflecting objectin which we considered the radiation incident uponthe object to contain (i) only parallel polarizationrepresented by the component Li

∥, (ii) only perpendi-cular polarization represented by the component Li

⊥,

and (iii) unpolarized light represented by half thesum of Li

∥ and Li⊥. In each of these cases, we detected

both Lsc∥ and Lsc

⊥, where Lsc

∥ and Lsc⊥stand for the par-

allel (p ¼ ∥) and the perpendicular (s ¼ ⊥) radiancecomponents of the scattered light. To characterizethe polarization state of the scattered light, we em-ployed the degree of reduced linear polarization P ofthe scattered light, which is obtained by neglectingthe U component of the Stokes vector, i.e.,

P ¼ jQscjLsc ¼ jLsc

∥ − Lsc⊥j

Lsc∥ þ Lsc

; ð16Þ

where the superscript sc stands for scattered light.If P ¼ 1, the scattered light is completely polarized,and if P ¼ 0, the scattered light is unpolarized.Therefore, P is bounded within the interval 0 ≤

P ≤ 1 for partially polarized light. The measure-ment of the degree of polarization defined as P ¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi

ðQscÞ2 þ ðUscÞ2 þ ðVscÞ2Þp

=L, is beyond the scope ofthis paper.

The change of polarization due to rough-surfacescattering was studied by Torrance et al. [17] usinga microfacet surface model. They showed experimen-tally that the angular distribution of plane-polarizedincident light reflected from a rough surface variedwith the angle of incidence, and that a Lambertiantype of reflector was obtained only for normal inci-dence, as predicted by the microfacet model. Debooet al. [18] measured the degree of polarization P

2434 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011

Page 5: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

for scattering of polarized light by artificial roughsurfaces and showed that it varied with the obser-vation direction and had a maximum value near thenormal direction of observation. Haner et al. [9]measured the BRDF of Spectralon white reflectancestandards using coherent, polarized laser light, andshowed that the BRDF as well as P increased as theobservation angle increased toward that of the spec-ular direction in the plane of incidence. Enhance-ment of backscattering from rough surfaces has beenstudied both numerically [19] and experimentally[20–22]. Recently, Simonsen et al. [23] simulated thescattering of p-polarized light from metallic and di-electric rough surfaces and showed that the back-scattered light intensity in the plane of incidencewas enhanced compared to that in a plane normalto the plane of incidence. These simulations includedonly rough-surface scattering, whereas the Spectra-lon standard is expected to behave mainly as a vo-lume scatterer [9] due to multiple-scattering eventstaking place beneath its surface.

2. Experimental Setup

A. Light Source and Detector

A quasi-monochromatic incoherent beam of light, ata wavelength of 405nm or 680nm, was generatedfrom a LQX 1000 xenon lamp (LINOS PhotonicsGmbH, Munich, Germany) by using an interferencebandpass filter (IF in Fig. 3) (Andover Corporation,Salem, N.H.) with a bandwidth of 10nm. As illu-strated in Fig. 3, the beam of light was collimatedby lens L and reflected from mirror M in order to il-luminate the Spectralon surface at a given angle ofincidence. The beam of light from the xenon lampwas unpolarized, but to account for possible polar-ization effects due to its transmission through var-ious optical components, we measured the p and spolarization components of the collimated beam bypolarizer P (see Fig. 3) and evaluated the degree ofreduced linear polarization P using the definitionin Eq. (16). It was found that the polarization of

the collimated beam was about 10% and 15% at680 and 405nm, respectively. We used a xenon lampin order to avoid speckles in the BRDF profiles.Figure 4 shows the Spectralon BRDF measured atnormal incidence (θ0 ¼ 0; see Fig. 2) using both a670nm diode laser (LDM145G, Imatronics, GwentUK) and a xenon lamp with a bandpass filter cen-tered at 670nm. The speckle effects due to coherentlaser light are seen to give a BRDF that can deviateby as much as 2.5% from that measured using an in-coherent xenon lamp for observation angles θ withinthe range −60° ≤ θ ≤ 60° (see Fig. 2). The speckle ef-fects can vary depending on the observation angleand the angle of incidence [10].

The detector was a silicon-based photodiodepower optometer (S370 Graseby Optics). It had anactive sensing area of 1 cm2 giving 0.14 to 0:40Aper watt absolute responsivity in the visible range.The detector was mounted on a computer-controlledgoniometer arm at a distance of 300mm from thecenter of the goniometer circle. The scattered lightfrom the illuminated surface area was focused ontothe detector using a lens (not shown in Fig. 3) witha 26mm effective diameter and 30mm focal lengththrough a 2mm circular aperture immediately infront of the detector. We assumed the beam diver-gence to be negligible. The detector aperture sub-tended a solid angle at the lens larger than thatsubtended by the illuminated surface area (of dia-meter ≤10mm) so that the light reflected back fromthe illuminated Spectralon sample to the lens wascollected by the sensing area of the detector.

B. Measurements and Analyses

A schematic of the optical setup of the goniometersystem is shown in Fig. 3, and a detailed descriptionof this goniometer setup is given in Zhao et al. [24].During the measurements we placed the Spectralonreflecting surface in the vertical plane (the x–y plane

Fig. 3. Sketch of optical setup in the experiment: IF, interferencefilter; L, lens; P, polarizer; CA, circular aperture; M, plane mirror;A0, temporary analyzer; A, analyzer; D, detector. Note that theSpectralon scattering surface is aligned parallel to the verticalplane.

Fig. 4. Spectralon BRDF curves (ρuu) measured at 670nm forunpolarized illumination from a xenon lamp (•−) and for illumina-tion from a 670nm diode laser (�−) at θ0 ¼ 0° [see Figure 2]. Thecurves are normalized to 1 at θ ¼ 0°.

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2435

Page 6: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

in Fig. 2) at the center of the goniometer ring to makeit possible for the detector to measure reflected lightfor observation angles in the range −90° ≤ θ ≤ 90°(see Fig. 2). Some of the measurements were madein the plane of incidence (ϕ ¼ ϕ0 ¼ 0°), but most ofthem were made by lifting the detector tube 6° abovethe plane of incidence (the x–z plane in Fig. 2) so thatthe lifted detector could detect the scattered lightwithin the entire range of observation polar anglesby avoiding the obscurity due to the position of mir-ror. However, in this lifted observation plane, it wasnot possible to detect the scattered light in the direc-tion of specular reflection (θ ¼ θ0, ϕ ¼ ϕ0 ¼ 0°). Onthe other hand, with measurements in the plane ofincidence, it was not possible to detect the backscat-tered light in directions close to that opposite to thedirection of incidence (θ ¼ −θ0, ϕ ¼ ϕ0 ¼ 0°) due tothe shadow of the mirror.

To obtain the reflected radiance L for an incidentirradiance E, the power ½W m−2 � of the reflectedlight was measured for different angular positionsof the detector and divided by the solid angle sub-tended by the detector to obtain L½W m−2 sr−1 �.The solid angle subtended by the detector was givenby ðr=RÞ2π cos θ, where r is the radius of the apertureof the lens mounted in front of the detector, R is thedistance from the illuminated area on the Spectralonsurface at the center of the goniometer to the lens,and θ represents the angular position of the detector.

Our analyses relied on the assumptions that theSpectralon reflection standard had 98% irradiancereflectance, as given by the manufacturer, and thatthe reflected radiance was azimuth independent fornormal incidence. In contrast to the latter assump-tion, the measurements for normally incident polar-ized light with the detector lifted 6° above the planeof incidence were not perfectly symmetrical aboutθ ¼ 0. At 405nm, the maximum asymmetry for ss po-larization was found to occur for the measured valueat θ ¼ −50°, which was 6% higher than at θ ¼ þ50°.At 680nm, the maximum asymmetry was 7% for sspolarization, but less than 5% for pp polarization. Inorder to compensate for this asymmetry, which wasassumed to be due to measurement errors, the mea-sured radiance values for normal incidence weresymmetrized by setting LsymðθÞ ¼ Lsymð−θÞ ¼ 1

2 ½Lsymð−θÞ þ LsymðθÞ�. This symmetrized LsymðθÞ functionwas assumed to be azimuth independent, and itwas therefore used to calculate E as explained inSubsection 1.B. For normal incidence, the BRDF,which is equal to Lsym=E½sr−1�, was calculated as de-scribed in Eq. (1). All measurements of the BRDF fornon-normal incidence were normalized by use of thereciprocity theorem, as explained in Subsection 1.B.

For measurements made when the detector tubewas lifted 6° above the x–z plane in Fig. 2, the angles(θg;ϕg) in the goniometer coordinate system and theangles (θ;ϕ) in the Spectralon reflection standardcoordinate system are related by

θ ¼�

arccosðcos θg cosϕgÞ for θg ≥ 0− arccosðcos θg cosϕgÞ for θg < 0 ; ð17Þ

ϕ ¼

8><>:

arcsinh

sinϕg

½1−ðcos θg cosϕgÞ2�1=2i

for θg ≥ 0

π þ arcsinh−

sinϕg

½1−ðcos θg cosϕgÞ2�1=2i

for θg < 0:ð18Þ

Thus, the measured power of the reflected lightwas corrected through division by cos θ, with θ asgiven in Eq. (17), but for cosϕg ¼ cos 6° ¼ 0:995, thedifference between cos θ ¼ cos θg cosϕg and cos θg isnegligible.

1. Alignment and Repeatability

To align the optical setup, we let a collimated unpo-larized beam at a wavelength of 680nm be normallyincident on the central area of the Spectralon sur-face, so that θ0 ¼ 0 in Fig. 2. Next, we carefullyaligned the Spectralon surface so as to obtain a sym-metrical angular distribution of the reflected lightabout the surface normal, i.e., to obtain the same re-flected radiance for θ ¼ −θ0 and θ ¼ þθ0, which istrue for normally incident light.

Measurements were made at observation angles θat every 5° interval. In each measurement, the detec-tor recorded 10 raw data sets, each for an integrationtime of 100ms, and the median value, which had arelative standard deviation ≤1:3%, was used to ob-tain the BRDF. The background noise due to theambient light and the detector dark current wasmeasured to be in the order of 10−12 W. In order tocheck the measurement repeatability, we repeatedfive measurements at normal incidence (θ0 ¼ 0°in Fig. 2) without altering the setup and comparedthese measurements as shown in Fig. 5. The goni-ometer system showed repeatable results with rootmean square (rms) values that were less than 1%for observation angles θ in the range −80° ≤ θ ≤ þ80°.

2. Homogeneity of Spectralon Surface

The selected Spectralon white reflectance standardSRS-99-020 (Labsphere, Inc., North Sutton, N.H.)had a flat circular reflecting surface with a diameterof 50:8mm (the total dimensions were 60:45mm indiameter and 15:24mm in height). We checked thehomogeneity of the surface by measuring reflectedlight from five different equally large neighboringpatches (each about 8mm in diameter) that were il-luminated at normal incidence (θ0 ¼ 0° in Fig. 2).First we measured reflected light from the centralarea for observation angles θ in the range−85° ≤ θ ≤ þ85°, and then we translated the Spectra-lon surface about 10mm vertically (up and down)and horizontally (left and right) to measure reflectedlight from four additional surface patches. Thesemeasurements, which are compared in Fig. 6,showed that the variations in reflected light fromthe five different surface patches were fairly close

2436 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011

Page 7: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

to the rms value, i.e., less than 1% for observationangles θ in the range −65° ≤ θ ≤ þ65°. However, atlarger observation angles, the rms value increased,which may be due to a decreasing signal-to-noise ratio.

3. Polarization States

Wemeasured the BRDF in the plane of incidence and6° above it for various combinations of polarization

states for the incident and detected light for sixdifferent angles of incidence: θ0 ¼ 0°, 20°, 30°, 38°,45°, and 60°. The orthogonal polarization states L∥

and L⊥ are denoted by p and s, respectively, and un-polarized light is denoted by u. Seven different com-binations of polarization states for the incident anddetected light were investigated. These are denotedby uu, ss, sp, pp, ps, su, pu, where the first and lastletter of each combination indicate the polarizationstate of the incident and detected light, respectively.The s- and p-polarization components of the incidentlight were carefully checked in each measurementwith an analyzer temporarily placed between the re-flectingmirror and the Spectralon surface (see Fig. 3).As explained in Section 1, the Spectralon surface isnonabsorbing and does not produce fluorescence ef-fects in the visible and near-infrared spectral ranges,so that the scattering is conservative, and the re-flected radiance is nearly Lambertian at normal in-cidence for which θ0 ¼ 0° Fig. 2.

3. Results and Discussion

In this section, we compare measured SpectralonBRDF curves with the Lambertian BRDF for variousangles of incidence and various combinations ofpolarization states of the incident and detected light.For each angle of incidence θ0, we plot the measuredBRDF and the corresponding degree of linear polar-ization P [see Eq. (16)] against the observation angleθ in the range −90° ≤ θ ≤ þ90°.

The BRDF curves in Figs. 7 and 8 are for a wave-length of 680nm, measured in the plane of incidence(Fig. 7) and in an observation plane that was 6° abovethe plane of incidence (Fig. 8), while those in Fig. 9are for a wavelength of 405nmmeasured in an obser-vation plane that was 6° above the plane of incidence.In Fig. 7 there are four panels (a)–(d) correspondingto angles of incidence of θ0 ¼ 0°,30°, 45°, and 60°, re-spectively, whereas Figs. 8 and 9 contain six panels(a)–(f) corresponding to angles of incidence of θ0 ¼ 0°,20°, 30°, 38°, 45°, and 60°, respectively. Each panel inFigs. 7–9 contains seven BRDF curves, each curve re-presenting a particular combination of polarizationstates for the incident and detected light, i.e., uu,ss, sp, pp, ps, su, and pu, where the first and last let-ter of each combination indicate the polarizationstates of the incident and detected light, respectively.The color codes used in Figs. 7–9 are as follows:(black −curve) →uu=2, (blue −curve) →ss, (blue− • curve) →sp, (red −curve) →pp, (red − • curve)→ps, (green −curve) →su=2, and (green − • curve)→pu=2. Note that each of the uu BRDF curves, whichis equal to 1=π for a Lambert reflector, has been di-vided by 2 for comparison with the polarized BRDFcurves, each of which having the value 1=2π (repre-sented by the symbols × in Figs. 7–9) for a Lambertreflector.

The BRDF curves measured in the plane of inci-dence (Fig. 7) did not reveal any specular reflectioncomponent at any of the four different angles of

Fig. 6. Raw data averages and rms values for measurements atnormal incidence (θ0 ¼ 0°) on the Spectralon test material at fivedifferent areas.Bullets (•) and crosses (×) indicatemeasuredvaluesbetweenwhich there is linear interpolation, except between the va-lues for θ ¼ −20° and θ ¼ þ20°, in which case spline interpolationwas used. The units on the left vertical axis represent the percen-tage rms values and the detected output power in nanowatts.

Fig. 5. Raw data averages and rms values obtained from testmeasurements at normal incidence (θ0 ¼ 0° in Fig. 2) to examinethe repeatability of measured results. Bullets (•) and crosses (×)indicate measured values between which there is linear interpola-tion, except between the values for θ ¼ −20° and θ ¼ þ20°, inwhich case spline interpolation was used. The units on the leftvertical axis represent the percentage rms values and the detectedaverage output power in nanowatts.

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2437

Page 8: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

incidence, but revealed a gradual increase of scatter-ing for θ > 0 as the angle of incidence θ0 got larger.

We expected the Spectralon reflectance standardto have a nearly Lambertian BRDF at normal inci-dence (θ0 ¼ 0°). But Fig. 7 (pertaining to the planeof incidence) as well as Figs. 8(a) and 9(a) (pertainingto an observation plane that was 6° above the planeof incidence) show deviations from Lambertian beha-vior even for small absolute values of the observationangle θ. The deviation from Lambertian behaviorvaries with jθj, both for θ < 0 and θ > 0. In the caseof normal incidence and unpolarized incident and de-tected light [see black − curve in Fig. 7(a)], the mea-sured BRDF is found to be ≃5% higher than theLambertian BRDF when jθj ≤ 50°, but to be 20% be-low the Lambertian BRDF when jθj > 60°. Similarly,at normal incidence, the relative difference betweenthe uu BRDF values measured in the plane of inci-dence and in an observation plane that was 6° abovethe plane of incidence was found to be about 3% forobservation angles in the range −60° ≤ θ ≤ 60°, but tobe more than 3% for θ > 60°.

The dashed curves in Fig. 7 are BRDF curves forpolarized light measured by Haner et al. [9] from po-sition 1 of Spectralon test sample number 12,969.These curves show that the measured BRDF for po-larized incident light is generally higher than theLambertian BRDF value of 1=2π for polarized light.For small absolute values of the observation angle θ,the copolarized BRDF curves of Haner et al. [9] areseen to be 15% higher than the Lambertian BRDF,whereas the corresponding difference found from

our measurements is about 10%. Moreover, suchdifferences are seen to increase more for θ > 0 as theangle of incidence θ0 increases. The difference ofabout 5% between our measurements and those ofHaner et al. [9] may be due to difference in surfacefinish between the Spectralon samples.

At an angle of incidence of θ0 ¼ 20°, all BRDF com-ponents in Figs. 8(b) and 9(b) are slightly enhancedfor θ > 0, and when θ0 ¼ 30°, all copolarized compo-nents of the BRDF are further enhanced for θ > 0,while the uu component is found to lie between thecopolarized and the cross-polarized components.Enhanced scattering for θ > 0 is seen to occur forθ0 > 38°. At an angle of incidence of θ0 ¼ 38°, the co-polarized BRDF components in Figs. 8 and 9 as wellas the uu component exceed the Lambertian BRDFin observation directions with θ > 0. Furthermore,the ss component of the BRDF is seen to be the lar-gest of all BRDF components in observation direc-tions with θ < 0. For θ0 ≥ 45°, enhanced scattering forθ < 0 of the pp component is seen both at 680nm(Fig. 8) and at 405nm (Fig. 9), but more pronouncedin the former case. At θ0 ¼ 60°, the copolarized andunpolarized BRDF components exceed the Lamber-tian BRDF for θ > 0. Also for θ0 ≥ 20°, the ss compo-nents of the BRDF [blue − curves in panels (b)–(f) inFigs. 7–9] are seen to have stronger enhanced scat-tering for θ > 0 than the pp components (red − curvesin the same figures). For larger θ0, the differencebetween the two cross-polarized components(blue − •→sp and red − •→ps) increases as the

Fig. 7. Spectralon BRDF curves measured in the plane of incidence at a wavelength of 680nm for angles of incidence θ0 as indicated ineach of parts (a)–(d). Curves with blue or red color represent s or p polarization, respectively, of the incident light. For each polarizationstate of the incident light, both the copolarized component (indicated by −) and the cross-polarized component (indicated by −•) are pre-sented. The green curves represent unpolarized detected light, i.e., measurements in which there was no analyzer in front of the detector,and in this case the symbols − and −• are used to indicate s and p polarization, respectively, of the incident light. The black symbols × alongthe horizontal axis show the Lambertian BRDF, and the black − curves show the BRDF for the case uu of unpolarized incident and detectedlight. Thus, [− → uu=2 (black)], [− → ss (blue)], [−• → sp (blue)], [− → pp (red)], [−• → ps (red)], [− → su=2 (green)], and [−• → pu=2 (green)].For comparison, BRDF curves at 632:8nm, measured by Haner et al. [9] are represented by [−− → ss (blue)], [− • − → sp (blue)], [−− → pp(red)], [− • − → ps (red)]. Note that the test sample of Haner et al. [9] was different from ours.

2438 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011

Page 9: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

observation angle θ increases for θ > 0. Such differ-ences are seen to be larger at 405nm than at 680nm.

The ratio of BRDF components for polarized lightat 680nm measured in the plane of incidence (Fig. 7)to those measured in an observation plane that was6° above the plane of incidence (Fig. 8) was examinedfor four different angles of incidence θ0 (not shownhere). This ratio should be equal to 1, if the Spectra-lon surface were a perfect Lambert surface, but wasfound to deviate from 1 as jθj increased, and the de-viation was found to be larger for the copolarizedcomponents than for the cross-polarized components.Within the range of observation angles −60° ≤ θ ≤

60°, the difference between the BRDF componentsfor polarized light at 680nm measured in the planeof incidence and in an observation plane that was 6°above the plane of incidence was found to be ≤5%,which is close to the corresponding difference foundin the uu case of unpolarized illumination anddetection.

Figures 7–9, which show the variation of theBRDF components with the observation angle θ,indicate that the anisotropic characteristics of thescattering increase with the angle of incidence θ0.For largeangles of incidence, all BRDF curves showenhanced scattering in observation directions with

θ > 0. Also, slightly enhanced scattering is ob-served for θ < 0 for p-polarized incident light forθ0 ≥ 38°. Such scattering events may be related to thegeometric self-shadowing and self-masking [25]caused by the surface topography as well as multiple-scattering effects [13,23] that occur on the surfaceas well as in the region below it.

If the structure of the Spectralon standard weresuch as to scatter the incident light uniformly in alldirections, the hemispherical distribution of thescattered light would follow the Lambert cosine law.In practice, Lambertian reflectors do not exist, butthe Spectralon standard, which has the most super-ior diffuse reflectance of any known light-diffusingmaterial, is assumed to behave nearly Lambertian[1] in the UV, visible, and near-infrared spectralranges, covering wavelengths from 0.257 to 10:6 μm.If it were so, the measured BRDF curves would bealmost independent of the viewing direction.However, The BRDF curves in Figs. 7–9 for the Spec-tralon standard show deviations from the idealLambertian BRDF values as a function of the obser-vation angle θ for various angles of incidence θ0, andthese deviations also depend on the polarizationstates of the incident and detected light.

Fig. 8. Spectralon BRDF curves measured in an observation plane that was 6° above the plane of incidence at a wavelength of 680nm forangles of incidence θ0 as indicated in each of parts (a)–(f). Curves with blue or red color represent s or p polarization, respectively, of theincident light. For each of these polarization states of the incident light, both the copolarized component (indicated by −) and the cross-polarized component (indicated by −•) are presented. The green curves represent unpolarized detected light, i.e., measurements in whichthere was no polarizer in front of the detector, and in this case the symbols − and −• are used to indicate s and p polarization, respectively,of the incident light. The black symbols × along the horizontal axis show the Lambertian BRDF, and the black − curves show the BRDF forthe uu case of unpolarized incident and detected light. Thus, [− → uu=2 (black)], [− → ss (blue)], [−• → sp (blue)], [− → pp (red)], [−• → ps(red)], [− → su=2 (green)], and [−• → pu=2 (green)].

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2439

Page 10: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

In our measurements as well as in those of Haneret al. [9], the s-polarized BRDF is always greaterthan the p-polarized BRDF for θ > 0, whereas forlarge angles of incidence [see Figs. 8(e), 8(f), 9(e),and 9(f)], the opposite is seen to be true for θ < 0.Comparison of BRDF curves for polarized light mea-sured in the plane of incidence (Fig. 7) and 6° above it(Fig. 8) indicates that enhanced scattering for θ < 0occurs more in the plane of incidence than in otherobservation planes. However, as pointed out pre-viously, scattering for θ < 0 in directions close tothe direction opposite to that of incidence was notpossible to detect due to obscuration by the detector.

Figure 10 shows the degree of reduced linear polar-ization P versus observation angle θ for six differentangles of incidence, computed from Eq. (16) based onthe results shown in Figs. 8 and 9. Our measured re-sults in Fig. 10 show that polarized incident lightgets more depolarized due to scattering by the Spec-tralon at small angles of incidence θ0 than at largevalues of θ0. At normal incidence, Fig. 10(a) showsthat 680nm s-polarized incident light gives higherP values (≃5%) than for p-polarized incident light.For θ0 ≥ 30°, the P values for s-polarized incidentlight are found to increase with θ for θ > 0, whilethe P value for p-polarized incident light decreasesto a minimum close to the direction of normal obser-vation (θ ¼ 0°), and then it increases with θ for θ > 0more than it does for θ < 0. This behavior suggeststhat the randomization due to scattering of the inci-dent light from Spectralon is polarization dependent,so that p-polarized incident light becomesmore depo-

larized by scattering from the Spectralon standardthan s-polarized light.

By comparing the P values at 405 and 680nm inFig. 10, we see that for s-polarized incident light theyare larger at 680nm than at 405nm when θ0 ≤ 45°,while they are found to be close to each other inthe range of observation angles −50° ≤ θ ≤ 25° whenθ0 ¼ 60°. For p-polarized incident light, the P valuesare smaller at 680 than at 405nm for small anglesof incidence (θ0 ¼ 0°–20°), are about the same at thetwo wavelengths for intermediate angles of incidence(θ0 ¼ 30°–38°), and are larger at 680nm than at405nm for large angles of incidence (θ0 ¼ 60°) [seeFig. 10(f)]. Thus, the depolarization of polarized inci-dent light due to scattering from the Spectralonstandard depends on the wavelength of the incidentlight and the angle of incidence.

The influence of the wavelength of the incidentlight on the BRDF due to rough-surface scatteringcan be related to a Rayleigh criterion [26], accordingto which a rough surface will reflect specularly if thewavelength of the incident light is large compared tothe surface roughness. Similarly, the strong scatter-ing in directions with θ > 0 [see Figs. 8(f) and 9(f)]can be intuitively explained in terms of anotherRayleigh criterion [27,28], according to which a sur-face will behave smoother for small grazing anglesβ ¼ π=2 − θ0 (θ0 is the angle of incidence) than forlarge grazing angles. These criteria are based on sur-face topography and do not take into account that theincident light undergoes multiple reflections under-neath the Spectralon surface. Also, neither of these

Fig. 9. Symbols and legends are the same as in Fig. 8 except that the wavelength of the incident light was 405nm for the results shown inthis figure.

2440 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011

Page 11: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

two Rayleigh criteria refers to the polarization stateof the incident light.

Our results show that the difference between scat-tering at 405 and at 680nm is larger for s-polarizedincident light than for p-polarized incident light.At normal incidence, both s- and p-polarized lighthave electric field vectors that are parallel to the flatsurface plane. However, at oblique incidence, self-shadowing masking effects [17,25] due to surface mi-crotopography may reduce the amount of scatteredlight and the direction of the electric field vectorfor p-polarized light relative to the flat surface plane,and more importantly, relative to the plane of arough-surface facet, depends on the angle of inci-dence, resulting in a partial conversion from p- tos-polarized incident light with respect to reflectionfrom the facets. In contrast, the orientation of theelectric field vector for s-polarized incident light willremain the same relative to the flat surface plane orthe rough-surface facet planes at all angles of inci-dence. This conversion may contribute to explain ourobservation noted above that as the angle of inci-dence gets sufficiently large (θ0 ≥ 45°), the magni-tudes of the different BRDF components are foundto be such that ss > pp > su > uu > pu > sp > psfor θ > 0.

Light scattering from a Spectralon standard isprobably dominated by volume scattering occurringbeneath its surface, whose complete description re-quires the use of Mueller matrices [13,29], whichis beyond the scope of this paper. In the case of singlescattering within the volume, the reflected light may

retain its original state of polarization, but in thecase of multiple scattering within the volume, thereflected light is likely to have a different state of po-larization than the incident light. Therefore, mea-surements of copolarized light, which include bothsingly scattered and multiply scattered light, havehigher BRDF values than measurements of cross-polarized light.

4. Conclusions

We have measured the BRDF for a Spectralon whitereflectance standard in the plane of incidence andin an observation plane 6° above the plane of the in-cidence by illuminating it at different angles of inci-dence with unpolarized and plane-polarized light at680 and 405nm. At normal incidence, the differencebetween the BRDF measured in the plane of inci-dence and in an observation plane 6° above it wasfound to be about ≤5% for observation angles θ in therange −60° ≤ θ ≤ 60°. At large angles of incidence,this difference was found to be larger.

The BRDF of the Spectralon white reflectancestandard was found to deviate considerably from theLambertian BRDF. Thus, all polarization compo-nents of the measured BRDFwere found to vary withthe angle of observation, and the anisotropic angularscattering characteristics were found to vary withboth the angle of incidence and the states of polari-zation of the incident and detected light. Therefore,for the purpose of calibration, the Spectralon BRDFshould be measured at all relevant angles of

Fig. 10. Degree of reduced linear polarization P (in percent) versus observation angle θ for different angles of incidence θ0 as indicated inpanels (a)–(f). The blue and red curves represent incident light at 405 and 680nm, respectively, and the degree of reduced linear polar-ization P is represented by the symbol − for s-polarized incident light and by −• for p-polarized incident light. Thus, − → s-polarizedincident light at 405nm, −• → p-polarized incident light at 405nm, − → s-polarized incident light of 680nm, and −• → p-polarized incidentlight at 680nm.

1 June 2011 / Vol. 50, No. 16 / APPLIED OPTICS 2441

Page 12: Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light

incidence and for all relevant combinations of thepolarization states of the incident and detected light.

This work was financially supported by the Norwe-gian Research Council. We are grateful to BalterMedical AS, Bergen, Norway for technical supportand to two anonymous reviewers for commentsand suggestions on how to improve the paper.

References1. “A guide to reflectance coatings & materials,” http://www

.pro‑lite.co.uk/File/Tech_guide_coatings_&_materials.pdf.2. B. Gordon, “Integrating sphere diffuse reflectance technology

for use with UV-visible spectroscopy,” Tech. Note 51450(Thermo Fisher Scientific, 2007).

3. “Reflectance standards product sheet_8.pdf,” http://www.labsphere.com/data/userFiles/.

4. K. Stamnes, B. Hamre, J. J. Stamnes, G. Ryzhikov, M.Biryulina, R. Mahoney, B. Haus, and A. Sei, “Modeling ofradiation transport in coupled atmosphere-snow-ice-oceansystems,” J. Quant. Spectrosc. Radiat. Transfer 112, 714–726(2011).

5. D. A. Haner, B. T. McGuckin, R. T. Menzies, C. J. Bruegge, andV. Duval, “Directional-hemispherical reflectance for Spectra-lon by integration of its bidirectional reflectance,” Appl.Opt. 37, 3996–3999 (1998).

6. K. J. Voss and H. Zhang, “Bidirectional reflectance of dryand submerged Labsphere Spectralon plaque,” Appl. Opt.45, 7924–7927 (2006).

7. E. A. Early, P. Y. Barnes, B. C. Johnson, J. J. Butler, C. J.Bruegge, S. F. Biggar, P. R. Spyak, and M. M. Pavlov, “Bidir-ectional reflectance round-robin in support of the Earth Ob-serving System program,” Am. Met. Soc. 17, 1078–1091(2000).

8. G. T. Georgiev and J. J. Butler, “Long-term calibration moni-toring of Spectralon diffusers BRDF in the air-ultraviolet,”Appl. Opt. 46, 7892–7898 (2007).

9. D. A. Haner, B. T. McGuckin, and C. J. Bruegge, “Polarizationcharacteristics of Spectralon illuminated by coherent light,”Appl. Opt. 38, 6350–6356 (1999).

10. G. T. Georgiev and J. J. Butler, “The effect of speckle on BRDFmeasurements,” Proc. SPIE 5882, 588203 (2005).

11. B. T. McGuckin, D. A. Haner, R. T. Menzies, C. Esproles, and A.M. Brothers, “Directional reflectance characterization facilityand measurement methodology,” Appl. Opt. 35, 4827–4834(1996).

12. G. T. Georgiev and J. J. Butler, “The effect of incident lightpolarization on Spectralon BRDF measurements,” Proc. SPIE5570, 492–500 (2004).

13. T. A. Germer, “Polarized light diffusely scattered under smoothand rough interfaces,” Proc. SPIE 5158, 193204 (2003).

14. F. E. Nicodemus, “Reflectance nomenclature and directionalreflectance and emissivity,” Appl. Opt. 9, 1474–1475 (1970).

15. G. Thomas and K. Stamnes, Radiative Transfer in the Atmo-sphere and Ocean (Cambridge University, 1999).

16. D. S. Flynn and C. Alexander, “Polarized surface scatteringexpressed in terms of a bidirectional reflectance distributionfunction matrix,” Opt. Eng. 34, 1646–1650 (1995).

17. K. E. Torrance, E. M. Sparrow, and R. C. Birkebak, “Polariza-tion, directional distribution and off-specular peak phenom-ena in light reflected from roughed surfaces,” J. Opt. Soc. Am.56, 916–925 (1966).

18. B. J. DeBoo, J. M. Sasian, and R. A. Chipman, “Depolarizationof diffusely reflecting man-made objects,” Appl. Opt. 44,5434–5444 (2005).

19. D. Torrungrueng and J. T. Johnson, “Numerical studies ofbackscattering enhancement of electromagnetic waves fromtwo dimensional random rough surfaces with the forward-backward/novel spectral acceleration method,” J. Opt. Soc.Am. A 18, 2518–2525 (2001).

20. C. Macaskill, “Geometric optics and enhanced backscatteringfrom very rough surfaces,” J. Opt. Soc. Am. A 8, 88–96 (1991).

21. K. A. O’Donell and E. R. Mendez, “Experimental study ofscattering from characterized random surfaces,” J. Opt. Soc.Am. 4, 1194–1204 (1987).

22. “Observation of depolarization and backscattering enhance-ment in light scattering from Gaussian random surfaces,”Opt. Commun. 61, 91–95 (1987).

23. I. Simonsen, A. A. Maradudin, and T. A. Leskova, “Thescattering of electromagnetic waves from two dimensionalrandom rough penetrable surfaces,” Phys. Rev. Lett. (to bepublished).

24. L. Zhao, K. P. Nielsen, J. K. Lotsberg, E. Marken, J. J.Stamnes, and K. Stamnes, “New versatile setup for gonio-metric measurements of spectral radiance,” Opt. Eng. 45,053606 (2006).

25. H. Parviainen and K. Muinonen, “Rough-surface shadowingof self-affine random rough surfaces,” J. Quant. Spectrosc.Radiat. Transfer 106, 398–416 (2007).

26. K. Fu and P. Hsu, “New regime map of the geometric opticsapproximation for scattering from rough surfaces,” J. Quant.Spectrosc. Radiat. Transfer 109, 180–188 (2008).

27. P. Beckmann and A. Spizzichino, The Scattering of Electro-magnetic Waves from Rough Surfaces (Pergamon, 1963).

28. J. Jaglarz, R. Duraj, P. Szopa, J. Cisowski, and H. Czternastek,“Investigation of white standards by means of bidirectionalreflection distribution function and integrated sphere meth-ods,” Opt. Appl. XXXVI, 97–103 (2006).

29. H. Noble,W. T. Lam, G. Smith, S. McClain, and R. A. Chipman,“Polarization scattering from a spectralon calibrationsample,” Proc. SPIE 6682, 668219, doi:10.1117/12.747483(2007).

2442 APPLIED OPTICS / Vol. 50, No. 16 / 1 June 2011