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Transcript of Bentonite
Paper
The Ciba® HYDROCOL® System
Newsprint & Mechanical Specialties
Paper
The Ciba® HYDROCOL® System
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Cationic Polymer
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Bentonite Clay
U.S. Patent No. 4,753,710 - June 1988
Paper
Bentonite - A Closer Look
Negative surface charge - Positive edge charge
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300 nm
100 nm0.9 nm
Swells in water - increases surface area to
700-800 m2/g
Paper
Bentonite Interactions
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Polyamines, PAC,PolyDADMACs,
Alum
Cationic Starch
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Cationic Flocculants
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Bentonite
Paper
Bentonite InteractionsPitch, Ink
Dissolved Solids
Contaminants, Stickies, Oils
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Bentonite
Paper
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Fatty Acid Triglyceride
Pitch Type
PitchAdsorbed(u moles)
Bentonite Talc
Pitch Adsorption - Bentonite & Talc
Paper
Ciba® HYDROCOL® Addition Points
HeadboxScreens
Fan Pump
Percol Polymer
Hydrocol Pigment
(bentonite)
Paper
Ciba® HYDROCOL® Mechanism
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Cationic Polymer
Fibers, fines & filler++++++ ++ ++++++++++++ +
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High Shear
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Bentonite
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Structured Floc
Paper
Particle Sizes in the Wet End
Length (microns) Width (microns)
Hardwood Fiber 1000-1800 10-35
Softwood Fiber 3000-5000 25-40
Fiber Fine 10-70 10-40
Filler Clay 2-5 0.2
Pitch Particle ~0.7 ~0.7
Bentonite 0.3-0.5 ~0.001
Polymer Molecule ~40 uncoiled ~0.001
Paper
Ciba® HYDROCOL® Control Strategy
Polymer addition– Control of white water solids
– Control drainage
Bentonite addition– Stabilize drainage
– Conductivity & dissolved solids driven
Paper
Ciba® HYDROCOL® Benefits
Increased production Increased retention Increased drainage Improved wet end stability Improved machine cleanliness Improved additive efficiency Handles “dirty” & “variable” wet end
conditions