CHEM-E7140 - Process Automation Lecture 2: Basic measurements of process industry Jukka Kortela.
Basic chem mine
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Transcript of Basic chem mine
3
MatterEverything in
the universe is composed of matter.
Matter is anything that occupies space or has mass
4
Measuring MatterMass –
quantity of matter an object has
Weight – pull of gravity on an object
Space Moon Earth
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ElementsIn total,
117 elements have been observed as of 2008
Of which 94 occur naturally on Earth.
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Principle Elements in Organisms
90% of the mass of an organism is composed of 4 elements OxygenCarbonHydrogen Nitrogen Carbon Ring
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ElementsEach element unique chemical symbol
Consists of 1-2 letters
First letter is always capitalized
Use Latin/Greek names or neo-Latin names
PotassiumLatin: kalium
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KPotassium39.0983
2881
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ElementsEach element unique chemical symbol
Consists of 1-2 letters
First letter is always capitalized
Use Latin/Greek names or neo-Latin names
IronLatin: ferrum
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FeIron
55.845
28142
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Elements
6
CCarbon12.0107
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Common parts of information found in an element’s box.
Atomic Number
Atomic Mass
Shells
Element Symbol
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AtomsThe simplest particle
of an element that retains all the properties of that element
Properties of atoms determine the structure and properties of the matter they compose
Our understanding of the structure of atoms based on scientific models, not observation
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Basic Atom PartsThe Nucleus Central Core Made of
a) Protons (P+)b) Neutrons (N)
It is surrounded by an Cloud of particles
c) Electrons (e—)
Nucleus
Cloud
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The Protons (P+)All atoms of a given
element have the same number of protons
Number of protons called the atomic number
Number of positive protons are balanced by an equal number of negative electrons
Protons are attracted to the electrons in orbit around the atom
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CCarbon12.0107
24
P
P
P
PN
N
N
N
NN
PP
P
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The Neutrons (N)The neutron
number varies slightly among atoms of the same element
Different number of neutrons produces isotopes of the same element
Hydrogen 11P, 0NMass # = 1
Hydrogen 21P, 1NMass # = 2
Hydrogen 31P, 2NMass # = 3
Isotopes of Hydrogen
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Atomic MassProtons & neutrons
are found in the nucleus of an atom
Protons and neutrons each have a mass of 1 amu (atomic mass unit)
The atomic mass of an atom is found by adding the number of protons & neutrons in an atom
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Electrons (e—)Negatively charged
high energy particles with little or no mass
Travel at very high speeds at various distances (energy levels) from the nucleus
The areas where electrons travel are called electron clouds
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Electrons (e—)In the clouds they
are arranged in to layers called shells
Electrons in the same energy level are approximately the same distance from the nucleus
Outer energy levels have more energy than inner levels
Each level holds only a certain number of electrons
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Electrons (e—)The Octet Rule:
Atoms are most stable when they have 8 electrons in their outer-most shell.
The exception is the first shell which is most stable with TWO electrons.
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Electrons (e—)If you know the
Atomic Number and Mass Number of an element and the maximum number of electrons in each electron shell you can draw a diagram of the element.
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CCarbon12.0107
24
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Energy LevelsAtoms have 7 energy levelsThe levels are
K (closest to the nucleus)LMNOPQ (furthest from the nucleus)
The K level can only hold 2 electrons
Levels L – Q can hold 8 electrons (octet rule)
1. 22. 83. 84. 85. 86. 87. 8
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8e—
Energy Levels
19 N19 P+
2e—
Shell K Shell L
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KPotassium39.0983
2881
8e—
Shell M
1e—
Shell N
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Valence ElectronsValence
electrons are the outermost electrons of an atom
They determine the number of chemical bonds formed by the atoms of a given element.
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Valence ElectronsHow many
electrons are needed in the outer shell for the atom to be stable?
4e—6 N
6P+
2e—
6
CCarbon12.0107
24
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Valence ElectronsHow many
electrons are needed in the outer shell for the atom to be stable?
Apply the octet rule
Wants 8 to be stable
Needs 4
4e—6 N
6P+
2e—
6
CCarbon12.0107
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Valence ElectronsHow many
more electrons are needed in the outer shell to make a stable atom?
? e—
? N? P+
? e—
? e—
8
OOxygen15.9994
Valence ElectronsHow many
more electrons are needed in the outer shell to make a stable atom? 8 N
8 P+6 e
—2 e
—8
OOxygen15.9994
Needs 2 electrons
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Polar-Covalent BondAtomic bond
where electrons are shared unevenly giving a slight charge to the molecule.
Ex: H2O (hydrogen bonding)
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Ionic BondAtomic bond
where electrons are not shared evenly
Results in a charged molecule.
Charged atoms are called ions.
Ex: NaCl (Sodium Chloride)
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Ionic BondAtomic bond where
electrons are not shared evenly
Results in a charged molecule.
Ex: NaCl (Sodium Chloride)
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Writing Chemical Formulas
Determine the different kinds of atoms.HydrogenCarbonOxygen
Count the number of atoms of each type.Hydrogen — 12Carbon — 6Oxygen — 6