Band Theory: Metallic Bonding
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Transcript of Band Theory: Metallic Bonding
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Band Theory: Metallic BondingPhotoelectron Spectroscopy
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Band Theory: Metallic BondingPhotoelectron Spectroscopy
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Band Structure for Periods 4-6, Group 1A – 2B
http://employees.oneonta.edu/viningwj/sims/metallic_bonding_band_theory_s.html
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Conduction in Solids
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Silicon Semiconductors
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Silicon Semiconductors
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Chip Fabrication
1. Make really, really pure Si2. Add impurities in a controlled way (doping)
SiO2(s) + 4 HCl SiCl4 (l) + H2O(l)
SiCl4 purified by distillation.
SiCl4 + 2 Zn Si + ZnCl2
Si now 99.9% pure.
Zone refining used to purify to 99.99999% pure.
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Doping
1. Apply coating2. Illuminate through mask3. Dissolve illuminated areas4. Add gas phase dopant5. Repeat
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np junction: diode npn junction: transistor
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III-V Semiconductors: LED lights
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