Auxiliaries (1)
-
Upload
amar-nath-prasad -
Category
Documents
-
view
216 -
download
0
Transcript of Auxiliaries (1)
8/4/2019 Auxiliaries (1)
http://slidepdf.com/reader/full/auxiliaries-1 1/6
The purpose of auxiliaries is to facilitate a textile process and/or increase its efficiency. They serve as sizing materials,
lubricants, wetting agents, emulsifiers, agents accelerating or decelerating the dyeing rate, thickeners, binders, etc.
often with considerable overlap in the functions and abilities of a specific chemical. Compounds used encompass
many different chemical classes, some of which are affected by enzymes and thus can be regarded as substrates, and
some of which remain unaffected. Owing to environment and economical concerns, auxiliaries are used as sparingly
as possible.
Once the respective process is terminated they are to be removed completely from the treated material; however,
traces could still be present and interfere negatively with subsequent processing steps
HERE ARE SOME OF THE AUXILIARIES USED IN TEXTILE
Organic DefoamersOrganic defoamers is a silicone based proprietory product used extensively in a
variety of industrial batch processing applications.In case of textile it acts as an
effective antifoam during jet dyeing and for production of predefoamed surfactants fortextiles and other applications. Organic defoamer which effectively kills and
suppresses foam formation in a wide variety of textile processes. Organic defoamer
has a high flash point and functions well in variety of application.
Hydrophilic SoftenersWe specialize in providing a spectrum of hydrophilic softeners, which is a textile
treatment composition that contains siloxanes. These siloxanes have epoxy andglycol- functionalities as well as an aminosilane or a silicone quaternary ammonium
compound. Formulated as an aqueous emulsion, our hydrophilic softeners impart
durable hydrophilicity to textiles, such as cotton fabric and others.
1. Quaternary ammonium cations, also known as quats, are positively charged polyatomic ions of
the structure NR4+, R being an alkyl group or an arylgroup.
Quaternary ammonium salts are used as fabric softeners, and as antistatic agents (e.g.
in shampoos). In liquid fabric softeners, the chloride salts are often used. In dryeranticling strips,the sulfate salts are often used.
2. Triethylamine is the chemical compound with the formula N(CH2CH3)3
Triethylamine is mainly used in the production of quaternary ammonium compounds for textile
auxiliaries and quaternary ammonium salts of dyes
8/4/2019 Auxiliaries (1)
http://slidepdf.com/reader/full/auxiliaries-1 2/6
3. Tannic acid is a specific commercial form of tannin, a type of polyphenol. Its
weak acidity (pKa around 6) is due to the numerous phenol groups in the structure. The chemical
formula for commercial tannic acid is often given as C76H52O46, Tannic acid is a
common mordant used in the dyeing process for cellulose fibers such as cotton, often combined
with alum and/or iron..
A mordant is a substance used to set dyes on fabrics or tissue sections by forming
a coordination complex with the dye which then attaches to the fabric or tissue.[1]
It may be used
for dyeing fabrics, or for intensifying stains in cell or tissue preparations. In the past, it was
thought that a mordant helped the dye bite onto the fiber so that it would hold fast during washing.
Mordants include tannic acid, alum, urine, chrome alum, sodium chloride, and
certain salts of aluminium, chromium, copper, iron, iodine, potassium, sodium, and tin.
4. An acid dye is a dye, in chemical regard a sodium (less often –ammonium) salt
of a sulfonic, carboxylic or phenol organic acid. Acid dye is soluble in water
and possesses affinity for amphoteric fibers while lacking direct dyes' affinity
for cellulose fibers. When dyeing, ionic bonding with fiber cationic sites
accounts for fixation of colored anions in the dyed material. Acids are added
to dyeing baths to increase the number of protonated amino-groups in fibers.
In the laboratory, the home or art studio, the acid used in the dyebath is oftenvinegar (acetic acid) or citric acid. The uptake rate of the dye is controlled with
the use of sodium chloride. In textiles, acid dyes are effective
on protein fibers, i.e. animal hair fibers like wool, alpaca andmohair. They are
also effective on silk. They are effective in dyeing the synthetic fiber nylon but
of minimal interest in dyeing any othersynthetic fibers.
Acid dyes fall into several classes:
Leveling acid or strong acid dye,
Milling or weak acid dyes, and Super milling or fast acid or neutral acid dyes.
5. Azo dyes: The structure of azo dyes is based on azobenzene, Ph-N=N-Ph (see
right showing cis/ trans isomers) Although Azo dyes are a separate class of
8/4/2019 Auxiliaries (1)
http://slidepdf.com/reader/full/auxiliaries-1 3/6
dyestuff mainly used in the dyeing of cotton (cellulose) fibers, many acid dyes
have a similar structure, and most are red in color.
6.
Is a colourless, anionic liquid ,miscible with water in any proportion.
AQUA SOFT VH has excellent dispersing and sequestering action which is
beneficial in washing/soaping as well as in dyeing processes. It does not impair
the shade of dyed goods or adversely affect their fastness properties.
Applications
Exhaust Method AQUA SOFT VH, due to its dispersing and complexing properties improves
the depth of colour, levelness and fastness of the dyeing viz. vat,Naphthol/Base, Direct, Reactives.
Recommended quantity 1-3 gms/liter
Padding Method AQUA SOFT VH due to its dispersing and sequestering properties is very
useful during padding operation particularly when water used is very hard. It
improves the brightness as well as colour yield and keeps the rolls clean during
silicate padding.
Recommended quantity 1-2 gms/liter
7. AUXI IN UDI
Properties
Salient Feature
Kills +B2 metal, ions like fe etc
Phosphate-free, polymer based sequestering agent with dispersing properties
Application - Dyeing
AUXI IN UDI can be applied both in the exhaust bath as well as in padding processes.
In the exhaust dyeing of reactives and vats prior addition of 1-2% of AUXI IN UDI in the
dyebath prevents Ca and Mg ions interfering with the dyeing process, particularly when
using hard water.
In the dyeing of reactives by cold pad-batch process the addition of 2-3 gm/I AUXI IN UDI
8/4/2019 Auxiliaries (1)
http://slidepdf.com/reader/full/auxiliaries-1 4/6
in the padding solution gives dyeing with good levelness and solidity for the same reason.
Addition of 2 gm/I AUXI IN UDI during the washing of reactive dyeing helps in the rapid
removal of unfixed dye. This leads to improved rub fastness of the dyeings. Additionally,
during washing-off of cold pad-batch dyeings the addition of 2 gm/I of AUXI IN UDI in the
washing bath helps in the quick removal of sodium silicate from the fabric.
8.
Properties
Salient Feature Kills metal ions like fe etc
Phosphate-free, polymer based sequestering agent with dispersing properties
Application - Dyeing
AUXI IN DE SAN can be applied both in the exhaust bath as well as in padding
processes.
In the exhaust dyeing of reactives and vats prior addition of 1-2% of AUXI IN DE
SAN in the dyebath prevents Ca and Mg ions interfering with the dyeing process,
particularly when using hard water.
In the dyeing of reactives by cold pad-batch process the addition of 2-3 gm/I
AUXI IN DE SAN in the padding solution gives dyeing with good levelness and
solidity for the same reason.
Addition of 2 gm/I AUXI IN DE SAN during the washing of reactive dyeing helps
in the rapid removal of unfixed dye. This leads to improved rub fastness of the
dyeings. Additionally, during washing-off of cold pad-batch dyeings the addition
of 2 gm/I of AUXI IN DE SAN in the washing bath help in the quick removal of
sodium silicate from the fabric.
---------------------------------------------------------------------------------
LYOCOL RDNI LIQ A high-pressure stable, super dispersant for dyeing with
disperse, naphthol, vat and indigo dyes. ALINE FI LIQ A versatile dispersing, levelling and emulsifying agent.
LYOCOL POD Special dispersing agent for use in dyeing Polyester fibres in
order to reduce the precipitation and deposition of oligomers on the goods and
in the dyeing machines
DISPERSOGEN S Low salt, low foaming, anionic dispersing agent
--------------------------------------------------------------
8/4/2019 Auxiliaries (1)
http://slidepdf.com/reader/full/auxiliaries-1 5/6
dispersing agents for dyeing of polyester, wool, silk & cotton
LYOCOL RDNI LIQ A high-pressure stable, super dispersant for dyeing with disperse, naphthol,
vat and indigo dyes.
ALINE FI LIQ A versatile dispersing, levelling and emulsifying agent.
LYOCOL POD Special dispersing agent for use in dyeing Polyester fibres in order to reduce theprecipitation and deposition of oligomers on the goods and in the dyeing machines
DISPERSOGEN S Low salt, low foaming, anionic dispersing agent
Waterproof ChemicalsRUBSOL silicone waterproof chemicals are ready to use that is based on
silane/siloxane. dilute solution serve as high-quality general-purpose water repellents
for impregnating and ptiming mineral and highly alkaline substrates.
Features:
Good penetration capacity
High alkaline resistance
Track-free drying
Effective even on damp substrates
Water repellency develops fast
After application, waterproof chemicals reacts with the atmospheric moisture or pore
water in substrate, therby generating the active ingredient and liberating alcohol. The
active ingredient greatly lowers the water absorbency of the substrate. Since neither
pores nor capillaries are clogged, the substrate retains a very high degree of watervapour permeability.