Attachment 4.8.3 Baseline Report · produce a baseline report. MSD Brinny appointed AECOM Ireland...
Transcript of Attachment 4.8.3 Baseline Report · produce a baseline report. MSD Brinny appointed AECOM Ireland...
Attachment 4.8.3 Baseline ReportIEL Review P0005-02Application ID LA001617
MSD Ireland (Brinny)
Project reference: PR-25391Project number: 60563354
19 July 2018
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Attachment 4.8.3 Baseline Report Project reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM
Quality information
Prepared by Checked by Verified by Approved by
Brendan McCarthyEnvironmental Scientist
Caroline DonnellyAssociate Director
Caroline DonnellyAssociate Director
Sinéad FitzpatrickTechnical Director
Revision History
Revision Revision date Details Authorized Name Position
1 09th July 2018 Draft CD Caroline Donnelly
Associate Director
2 19th July 2018 Final SF Sinéad Fitzpatrick
Technical Director
Distribution List
# Hard Copies PDF Required Association / Company Name
0 1 MSD Ireland (Brinny)
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM
Prepared for:MSD Ireland (Brinny)
Prepared by:Brendan McCarthyEnvironmental ScientistT: 021 4365006M: 087 1872998E: [email protected]
AECOM Ireland Limited1st Floor Montrose HouseCarrigaline RoadDouglasCork
T: 021 436 5006aecom.com
© AECOM recognises that Merck & Co retains the copyright of this report content, but not theintellectual rights, under the terms of Section 8 to an Engineering, Procurement and ConstructionManagement Master Agreement between Merck & Co and AECOM Technical Services Inc., dated 30th
March 2016.
Where any conclusions and recommendations contained in this Report are based upon informationprovided by others, it has been assumed that all relevant information has been provided by thoseparties and that such information is accurate. Any such information obtained by AECOM has not beenindependently verified by AECOM, unless otherwise stated in the Report. AECOM accepts no liabilityfor any inaccurate conclusions, assumptions or actions taken resulting from any inaccurateinformation supplied to AECOM from others.
The methodology adopted and the sources of information used by AECOM in providing its servicesare outlined in this Report. The work described in this Report was undertaken between May 2018 andJuly 2018 and is based on the conditions encountered and the information available during the saidperiod of time. The scope of this Report and the services are accordingly factually limited by thesecircumstances. AECOM disclaim any undertaking or obligation to advise any person of any change inany matter affecting the Report, which may come or be brought to AECOM’s attention after the date ofthe Report.
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM
Table of Contents
1. Introduction.............................................................................................................................. 51.1 Project Background........................................................................................................ 51.2 Baseline Assessment ..................................................................................................... 51.3 Project Objective ............................................................................................................ 51.4 Scope of Work ............................................................................................................... 5
2. Identification of Hazardous Substances (Stage 1) .................................................................... 63. Identification of ‘Relevant Hazardous Substances’ (Stage 2) .................................................... 64. Assessment of Site Specific Pollution Possibility (Stage 3) ....................................................... 7
4.1 Diesel and Light Fuel Oil ................................................................................................ 74.2 Sodium Hypochlorite ...................................................................................................... 84.3 Ammonia Hydroxide Solution ......................................................................................... 84.4 Hydrogen Peroxide ........................................................................................................ 84.5 Environ Vesphene® SE Phenolic Disinfectant ................................................................ 8
5. Site History (Stage 4) ............................................................................................................... 95.1 Historic Land Use .......................................................................................................... 95.2 Historic Losses to Ground .............................................................................................. 95.2.1 Diesel Spill 2001 ............................................................................................................ 95.2.2 Ethylene Glycol Spill, 2003............................................................................................. 95.2.3 Diesel Spill, 2004 ........................................................................................................... 95.2.4 Ethylene Glycol Spill, 2006............................................................................................. 9
6. Environmental Setting (Stage 5) ............................................................................................. 116.1 Site Setting and Topography ......................................................................................... 116.2 Hydrology ..................................................................................................................... 116.3 Geology ........................................................................................................................ 116.4 Site Hydrogeology and Groundwater Flow .................................................................... 116.5 Surface Runoff Drainage Systems ............................................................................... 126.6 Ecology........................................................................................................................ 126.7 Surrounding Land use .................................................................................................. 12
7. Site Characterisation (Stage 6) .............................................................................................. 137.1 Sources ....................................................................................................................... 137.2 Pathways ..................................................................................................................... 137.3 Receptors .................................................................................................................... 137.4 Summary ..................................................................................................................... 14
8. Site Investigation (Stage 7) .................................................................................................... 148.1 Rational ....................................................................................................................... 148.2 2002 Site Investigation ................................................................................................. 158.3 2003 Site Investigation ................................................................................................. 158.4 2004 Source Protection Area Assessment .................................................................... 168.5 2006 Water Level Survey ............................................................................................. 168.6 2009 Geotechnical Investigation .................................................................................. 168.7 2012 IPC Well Replacement ........................................................................................ 168.8 2017 Zone of Contribution Estimate ............................................................................. 168.9 IEL Groundwater Sampling .......................................................................................... 178.9.1 IEL Groundwater trends ............................................................................................... 178.9.1.1 Diesel and LFO ...................................................................................................... 178.9.1.2 Inorganics............................................................................................................... 17
9. Production of Baseline Report (Stage 8) ................................................................................ 189.1 Stage 1 - Identification of Hazardous Substances ......................................................... 189.2 Stage 2 – Identification of ‘Relevant Hazardous Substances’ ........................................ 18
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM
9.3 Stage 3 – Assessment of Site Specific Pollution Possibility ........................................... 189.4 Stage 4 – Site History .................................................................................................. 189.5 Stage 5 – Environmental Setting .................................................................................. 189.6 Stage 6 – Site Characterisation .................................................................................... 189.7 Stage 7 – Site Investigation .......................................................................................... 18
Appendix A Figures .......................................................................................................................... 19Appendix B Relevant Hazardous Substances Tables ....................................................................... 20Appendix C Site Investigation Data .................................................................................................. 21Appendix A FiguresFigure 1 Site Location PlanFigure 2 Site Layout PlanFigure 3 Well LocationsFigure 4 Cross SectionFigure 5 Shallow Aquifer Contour Plan – April 2018Figure 6 Deep Aquifer Contour Plan – April 2018
Appendix B Relevant Hazardous Substances TablesTable 1 Relevant Hazardous Substances (Stage 1 and 2)Table 2 Relevant Hazardous Substances (Stage 3)
Appendix C Site Investigation DataTable 1 Well InventoryTable 2 IEL Sampling ScheduleTable 3 IEL Well Historic Data
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EPA Export 20-11-2018:04:05:08
Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM5
1. Introduction
1.1 Project BackgroundMSD Ireland Brinny (MSD Brinny) operate a site in Innishannon, Co. Cork (the site), under IndustrialEmissions Licence (IEL) P0005-02, granted by the Environmental Protection Agency (EPA). Under theterms of this licence, the site is licensed for the use of a chemical or biological process for theproduction of basic pharmaceutical products. Under current licensed site operations, the biologicsbuildings on-site are configured for the fermentation process necessary to produce a singlepharmaceutical product. It is planned to reconfigure the internal structure of these buildings to permitmulti-product fermentation processes. This planned change in site operations has obliged the site toundertake a review of the site’s IEL. As part of the IEL review application MSD Brinny are obliged toproduce a baseline report. MSD Brinny appointed AECOM Ireland Limited (AECOM) to assist in thepreparation of their IEL review application including the production of this Baseline Report.
1.2 Baseline AssessmentWhen the European Union Directive on Industrial Emissions1 came into force, it became necessaryfor licensees to prepare a baseline report with regard to soil and groundwater contamination whenactivity on the site involves the use, production or release of relevant hazardous substances, undereither of the following scenarios:
· When applying for an IEL to operate a new installation; and,
· When revising the permit for an existing licensed installation.
Under the Industrial Emissions Directive, a Relevant Hazardous Substance is a raw material, product,intermediary, by-product, emission or waste which, as a result of their hazardousness, mobility,persistence and biodegradability (as well as other characteristics), is capable of contaminating soil orgroundwater.
1.3 Project ObjectiveThe main objective of the project is to complete a baseline assessment for the site in support of thecurrent licence review application.
1.4 Scope of WorkThe aim of baseline assessment is to generate a report which, on cessation of the licensed activity,will allow for direct comparison to determine if contamination has been added in the course of thelicensed activity since the baseline was established. Therefore, the baseline report needs to be ascomprehensive as possible.
The Official Journal of the European Union has issued guidance2 on the stages to be completed andthe scope of content for baseline reports. In total there are eight stages to be completed, as listedbelow:
· Stage 1 – Identification of hazardous substances used;
· Stage 2 – Identification of relevant hazardous substances used;
· Stage 3 – Assessment of the site specific pollution possibility;
· Stage 4 – Site history;
· Stage 5 – Environmental setting;
· Stage 6 – Site characterisation;
1 Industrial Emissions Directive, Directive 2010/75/EU2 European Commission Guidance concerning baseline reports under Article 22(2) of Directive 2010/75/EU on industrialemissions (2014)
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM6
· Stage 7 – Site investigation; and,
· Stage 8 – Production of the baseline report.
2. Identification of Hazardous Substances (Stage 1)The first stage in preparing a baseline assessment is to identify every hazardous substance that iscurrently used, produced or released at the site.
MSD Brinny has collated a comprehensive inventory of substances used and stored on site (seeAttachment 4-6-2 as an example). AECOM were supplied with a list of substances used and storedon site.
Substances were classified as hazardous if:
· They were identified as ‘Hazardous’ by the EPA Document Classification of Hazardous and Non-Hazardous Substances in Groundwater (2010)3; and,
· If they have a relevant environmental hazard statement on the European Chemicals Agencywebsite4.
A list of the hazardous substances identified on site are listed in Appendix B Table 1.
3. Identification of ‘Relevant Hazardous Substances’(Stage 2)
Stage 2 screens the hazardous substances identified following stage 1 for potential pollution risk dueto their chemical or physical properties.
This risk-based assessment screens the list of substances given in Appendix B Table 1 inconsideration of:
· The physical state of substances used and stored on site, e.g. solids and gases can be removedfrom the list as part of the screening process; and,
· The overall quantity used on site. The EU Guidance states that “where very small quantities areused, produced or released on the site of the installation then the possibility of contamination islikely to be insignificant for the purpose of producing a baseline report”.
An annual usage of >250 L (or >250 kg) was used as the threshold above which substances used onsite were considered in this assessment. Those substances that are used/stored in small quantitieson site have not been considered, for example substances used in laboratories, canteen or medicalcentre on site.
Five Relevant Hazardous Substances were identified in stage 2:
· Diesel and light fuel oil;
· Ammonia hydroxide solution;
· Sodium hypochlorite;
· Hydrogen peroxide; and,
· Environ Vesphene® SE phenolic disinfectant.
3 http://www.epa.ie/pubs/reports/water/ground/classificationofhazardousandnon-hazardoussubstancesingroundwater.html4 http://echa.europa.eu/
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM7
4. Assessment of Site Specific Pollution Possibility(Stage 3)
In stage 3, the hazardous substances which were taken forward from stage 2 were considered in thecontext of the site to determine whether circumstances exist which may result in the release of asubstance in sufficient quantities to pose a pollution risk. Specific issues include:
· The quantity of each hazardous substance or groups of similar hazardous substances;
· How and where hazardous substances are stored and used on site;
· How the hazardous substances are transported around the installation; and,
· In case of existing installations, the measures that have been adopted to ensure that it isimpossible in practice for contamination of soil or groundwater to take place (including thepresence and integrity of containment mechanisms, condition of site drainage etc.)
MSD Brinny provided AECOM with details of the storage locations and containment measures for thehazardous chemicals. The storage and usage locations of the relevant hazardous substances arepresented in Figure 2.
For the current list of on-site relevant hazardous substances which were not screened out in stage 2,AECOM assessed both the storage arrangement of each chemical substance, together with theassociated containment measures. At MSD Brinny, the storage and handling of process materials areundertaken in accordance with the EPA Guidance Document “IPC Guidance Note on Storage andTransfer of Materials for Scheduled Activities”, EPA 20045. Details on current site containment wereobtained from MSD’s documented site procedures and a review of site bund reports. Brief details ofthe storage arrangements of the current on-site hazardous chemical substances and associatedcontainment measures for each of the hazardous substances are provided in Appendix B Table 2.
Bunded liquid chemicals or liquid chemicals that are not stored in bulk storage tanks and possesssecondary and tertiary containment facilities were also screened out of the list of chemicals to beassessed.
Based on the information provided by MSD Brinny to AECOM, it is expected that, as a result ofcurrent site storage, containment and handling practices, the likelihood of possible contamination ofsoils and groundwater from the current on-site hazardous substances is low.
4.1 Diesel and Light Fuel OilDiesel (sulphur free gas oil) and light fuel oil (LFO) were considered together due to their similarproperties. They are liquid at room temperature and have the potential to contaminate soil and/orgroundwater if lost to ground. Diesel and LFO are stored in five bulk above ground storage tanks(AST) on site. The bulk diesel tanks are contained within bunds, which are integrity tested on a threeyear cycle. None of the relevant bunds are noted as having failed integrity testing.
Diesel and LFO are transported across site through above ground pipelines. The site has a number ofinterceptors in case of spillage on roadways or around filling points, to reduce the potential forhydrocarbons to enter the storm water drainage system at the site. In addition in the event of a spillcontaminated liquid entering the storm water system, it will be automatically diverted to a retentionlagoon (see section 6.5). However it was noted in the MSD Brinny Overhead Pipeline RiskAssessment 2016 (AECOM) that diesel is transported over areas of unmade ground withoutsecondary containment. Following the completion of this report a survey was conducted by Metlabwho confirmed that there were no flanges on the diesel pipework above unmade ground.
As diesel is stored within secondary containment and MSD Brinny have documented procedures onmaterial use and storage, the risk of diesel entering soil and/or groundwater is considered low.
5 http://www.epa.ie/pubs/advice/licensee/guidancetostorageandtransferofmaterialsforscheduledactivities.html
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM8
However as diesel is stored in bulk and is transported over sections of made ground diesel is aconsidered a Relevant Hazardous Substance.
4.2 Sodium HypochloriteSodium hypochlorite is a liquid at ambient temperature and stored within bunds which are integritytested. None of the relevant bunds are noted as having failed integrity testing. Sodium hypochlorite isnot stored in bulk which significantly reduces the risk of a large scale release.
Due to the provision of secondary and tertiary containment and as sodium hypochlorite is not storedin bulk the risk of sodium hypochlorite entering soil and/or groundwater is considered very low andhas been screened out as a Relevant Hazardous Substance.
4.3 Ammonia Hydroxide SolutionThe storage of ammonia hydroxide solution in quantities greater than 250 litres will be introduced aspart of the planned change to the site Biologics operations. Ammonia hydroxide solution is a liquid atambient temperature and will be stored in a newly installed ChemStore near the WwTP which will beintegrity tested. Ammonia hydroxide is not stored in bulk which significantly reduces the risk of alarge scale release.
Due to the provision of secondary and tertiary containment and as ammonia hydroxide is not stored inbulk the risk of ammonia hydroxide entering soil and/or groundwater is considered very low and hasbeen screened out as a Relevant Hazardous Substance.
4.4 Hydrogen PeroxideHydrogen Peroxide is a liquid at ambient temperature and is stored in ChemStores in the mainWarehouse which are integrity tested. None of the relevant bunds are noted as having failed integritytesting. Hydrogen peroxide is not stored in bulk which significantly reduces the risk of a large scalerelease.
Due to the provision of secondary and tertiary containment and as hydrogen peroxide is not stored inbulk the risk of hydrogen peroxide entering soil and/or groundwater is considered very low and hasbeen screened out as a Relevant Hazardous Substance.
4.5 Environ Vesphene® SE Phenolic DisinfectantAll of the remaining relevant hazardous substances (p-(1,1-dimethylpropyl)phenol, biphenyl-2-ol,clorofene and potassium hydroxide) are constituents of Environ Vesphene® SE, a germicidaldetergent. While the cumulative volume used on the site inventory is >250 L, Environ Vesphene® SEis contained in bottles and sachets, which individually contain small volumes.
Therefore, the risk of and its constituents entering soil and/or groundwater is considered very low andhas been screened out as a Relevant Hazardous Substance.
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM9
5. Site History (Stage 4)
5.1 Historic Land UseIn 1973 an antibiotic manufacturing facility was built by Chemibiotic (Ireland) Ltd. After termination ofthis activity Schering Plough purchased the site in 1980 and commenced operations at the site. In2009 Schering Plough merged with MSD. In September 2016 the company name was transferred toMSD International GmbH, trading as MSD Ireland (Brinny). Since operations began the facility hasproduced a range of biotechnology derived pharmaceutical products.
Prior to the construction of the Chemibiotic facility the site use was agricultural.
5.2 Historic Losses to GroundA site data review was conducted in 20156 to assess historic groundwater sampling data and trends.This data review and historic reports identify four distinct events which resulted in losses to ground.They are:
· Diesel in 2001;
· Ethylene glycol in 2003;
· Diesel in 2004; and,
· Ethylene glycol 2006.
5.2.1 Diesel Spill 2001A site investigation completed in 2001 details the remediation of a diesel spill. Approximately 24 m3 ofcontaminated soil was excavated and moved off site. Sampling as part of the site investigation (seesection 8.2) did not identify elevated hydrocarbon concentrations following the completion of theexcavation.
5.2.2 Ethylene Glycol Spill, 2003In August 2003, a site investigation was undertaken (see section 8.2 ) following a spill of ethyleneglycol coolant close to Building 18. The investigation concluded that the ethylene glycol biodegradedin the environment and did not pose a threat to the environment.
5.2.3 Diesel Spill, 2004In June 2004, a small diesel leak occurred on a pipeline that connected a decommissioned generatorwith an AST located west of the purification building. An area of 1 m x 1 m was excavated down to adepth of 1.1 m below ground level (bgl). The excavated soil, from which a hydrocarbon odour wasnoted, was stockpiled. A soil sample was taken from the base of the excavation and analysed forhydrocarbons, no hydrocarbons were detected.
Following the diesel spills in 2001 and 2004 additional control measures were put in place to reducethe likelihood of future incidents including the installation of oil interceptors in the drainage networkand the introduction of a permit system and documented procedures for diesel deliveries.
5.2.4 Ethylene Glycol Spill, 2006In August 2006, the TOC alarm in the storm water drain was activated. Storm water was then divertedto the tertiary containment lagoon. A glycol spray was observed from the automatic air vent on theglycol loop in an open area south of the laboratory building. 5,000 litres of water containing an 11.7%glycol mix was lost (see Figure 2). Following the loss, a series of groundwater sampling rounds wereconducted, no ethylene glycol was detected.
6 AECOM (2015) 47092942 / CKRP0004 Issue 2 Final - MSD Brinny 2014 IEL Groundwater Data Review
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM10
A qualitative risk assessment was undertaken and it was concluded that the zone of groundwatercontribution (ZOC) to the on-site production wells could encompass the spill area - see section 8.5.
Ethylene glycol is miscible in water, tends not to sorb to soil and is readily biodegraded. Therefore, itis unlikely that ethylene glycol lost to ground in 2006 would persist in soil and groundwater beneaththe site.
Ethylene glycol has been routinely analysed since 2009, and was most recently sampled for in April2018. Ethylene glycol has not been detected in groundwater from any well since routine monitoringbegan in 2009. Therefore MSD Brinny is proposing (Attachment 9.1) not to include ethylene glycol infuture groundwater monitoring rounds.
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM11
6. Environmental Setting (Stage 5)
6.1 Site Setting and TopographyThe site is situated at an elevation of between 20 m and 30 m above Ordnance Datum (OD) and landacross the site slopes gently to the south-west toward the valley of the River Brinny, with a steepslope along the western site boundary.
6.2 HydrologyThe River Brinny flows past the western and southern site boundary, with an old mill race flowing atthe base of the steep slope along the western and southern site boundary. The mill race joins theRiver Brinny south of the site.
The River Sall, which flows from west to east, also joins the River Brinny to the south of the site, justup-stream of Brinny Bridge; and the River Brinny continues to flow south-eastwards, joining the RiverBandon 2.5 km down-stream. Surface water quality in the section of the River Brinny adjacent to thesite (EPA reference Brinny_020) is classified as High7.
6.3 GeologyThe site is underlain by made ground on glacial till derived from Devonian/Carboniferous sandstoneand shales. Available drilling records for the site indicate that the shallow overburden compositionvaries from soft, silty clay to gravel, with the deeper overburden consisting of sand and gravel. Thebedrock beneath is Carboniferous sandstones, mudstones and dolomites.The generalised geological sequence is:
· 0 – 2 m below ground level (bgl): made ground;
· 2 – 5 m bgl: clayey, sandy gravel (perched aquifer);
· 5 – ~10 m bgl: sandy, gravelly, clay and silt (aquitard);
· ~10 m - ~22 m bgl: sand and gravel (with discontinuous silt and clay zones) (aquifer); and,
· Below ~22 m bgl: mudstone, sandstone and dolomite (bedrock aquifer).
6.4 Site Hydrogeology and Groundwater FlowPrevious investigations (see section 8) at the site have classified the overburden into a shallowperched gravel aquifer and deeper sand and gravel aquifer, which are separated by a lowerpermeability aquitard. The deeper gravel unit is classed as a ‘Locally Important Aquifer (Lg)’ while thebedrock aquifer is classed as ‘Locally Important Aquifer (LI) – Bedrock which is moderately productiveonly in Local Zones’.8
Under natural gradient conditions, groundwater would be expected to mirror the topographic gradientand flow across the site to the west/south-west. Shallow groundwater in the perched aquifer generallyappears to do this, and groundwater seepages from the base of the slope are seen. These seepagesdischarge to the mill race. Continuous groundwater abstraction from the deeper sand and gravelaquifer does not appear to affect the direction of groundwater flow in the shallow perched aquifer.
Groundwater in the deeper sand and gravel aquifer is confined by the aquitard, with the verticalhydraulic gradient downwards between the two gravel aquifers.
7 www.catchments.ie – accessed 20 June 20188 www.gsi.ie – accessed 20 June 2018
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM12
Groundwater abstraction from the deeper gravel is understood to alternate between three productionwells on an approximate 8-hour rotation, groundwater level monitoring conducted in 20179 indicatedthat pumping is not continuous during an 8-hour period.
As seen with the dip round data for April 2018 (Appendix A Figure 6), groundwater flow will convergeon whichever well is actively pumping at any given time. Over the course of a day, the focus ofgroundwater flow in the deeper gravel changes depending on which production well is operational.Under natural gradient conditions, it is expected that groundwater in the deeper gravel woulddischarge to the River Brinny.
Water levels in well MW-1D have been monitored since November 2007 and have not shown anylong term changes in groundwater level as a result of changes to the abstractions regime at the siteduring that time, suggesting that the zone of contribution to the site’s abstraction wells does notextend to the north-eastern edge of the site.
6.5 Surface Runoff Drainage SystemsStorm water run-off is directed to surface water drains which discharge to the River Brinny via anumber of oil/water interceptors (Class I and Class II) and then to a Total Organic Carbon(TOC)/pH/Temperature monitoring chamber (SW2).
In the event of a chemical release the surface water drainage system is set up to re-route the stormwater to the onsite retention pond if TOC/pH/Temperature levels exceed specific limits. The retentionpond is linked to the MSD Brinny operating site storm water system via a 900 mm undergroundconcrete pipeline. In the same trench there is a 100 mm polyethylene pipeline that facilitates thepumping of contaminated water back to the main site wastewater treatment plant (WwTP).
Site process wastewater and sanitary wastewater is directed to the on-site WwTP where physical,chemical and biological treatment is provided. The treated effluent from the WwTP is dischargedunder EPA license into the Bandon River estuary approximately 700 m north of Kilmacsimon via anapproximately 9 km long pipeline.
6.6 EcologyThere are no direct hydrogeological links between the MSD Brinny site and any Special Areas ofConservation or Special Protection Areas. However, there are three proposed Natural Heritage Areas(pNHA) downstream of the site; these are the Bandon Valley above Innishannon (pNHA 001740),Bandon Valley below Innishannon (pNHA 01515) and James Fort (pNHA 001060).
6.7 Surrounding Land useMost current land use in the surrounding area is agricultural, other than a sandstone quarrydevelopment (Kilmore Concrete Ltd) and modular building supplier (Spacecab Limited), bothapproximately 200 m west of the site. There are no other EPA licensed facilities located within a 2 kmradius of the facility.
In addition to a number of supply wells in the general area, the site itself abstracts groundwater for allproduction and supply purposes on site from three on-site wells. Groundwater is abstractedpredominantly from the sand and gravel aquifer, but some production wells extend into the deeperbedrock.
9 AECOM (2017) 60533059 Issue 2 Final - MSD Ireland (Brinny) Response to EPA RFI Zone of Contribution Estimate
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM13
7. Site Characterisation (Stage 6)Potential pollutant linkages are considered viable where there is a source of contamination on sitewhich can migrate via a defined pathway to identified receptors. Receptors can be eitherenvironmental or human, and located either within or outside the site boundary.
7.1 SourcesFrom a review of the site history (see section 4), it appears that losses to ground from distinct eventsare limited to:
· Diesel in 2001;
· Ethylene glycol in 2003;
· Diesel in 2004; and,
· Ethylene glycol in 2006.
7.2 PathwaysLosses to ground would migrate vertically downwards to the shallow perched aquifer. Contaminantsin perched groundwater would then migrate with groundwater flow down hydraulic gradient.
It appears that perched groundwater flows to the south-west toward the mill race; indeed, seepages of shallow groundwater from the base of the slope between the site and the mill race have beenobserved historically. The mill race flows from north-west to south-east and joins the River Brinnyfurther to the south-east of the site just upstream of Brinny Bridge.
Although the vertical hydraulic gradient between the two aquifer units is downward across the lowerpermeability aquitard, it is considered unlikely that diesel, ethylene glycol or inorganics (major ions)would have impacted/impact the deeper gravel aquifer, as the aquitard provides protection andseparates the two aquifer units. The primary groundwater flow path through the perched aquiferwould likely follow the horizontal hydraulic gradient.
It is also noted that the three active production wells on site abstract groundwater from the deepergravel aquifer. It is expected that, under active pumping conditions, the vertically downward hydraulicgradient across the aquitard would increase close to the active pumping well, which would locallyincrease leakage of groundwater from the perched aquifer to the deeper gravel aquifer.
Under natural gradient conditions, the direction of groundwater flow in the deeper gravel aquifer isexpected to be to the south or south-west, i.e. toward the River Brinny. However, active pumpingalters this, with each production well becoming the focus for groundwater flow when actively pumping.The three active production wells are located in the centre of the site:
· To the north of the purification building (654);
· To the north-east of the services building (651); and,
· Immediately east of the operations building (653).
The source protection plan completed in 2004 concluded that the zone of contribution to the threeproduction wells extended beyond the site boundary, and was elongated to the north-east.
The zone of contribution was reassessed in early 2017 and an area of ~2.2 km2 was conservativelydelineated, extending from the River Brinny in the west to a local highpoint at Old Chapel CrossRoads in the north-east.
7.3 ReceptorsThe site uses groundwater for all water supply requirements on site. The three active production wellson site abstract groundwater, principally from the deeper gravel aquifer, but with a proportion of water
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM14
also likely to come from deeper bedrock. As noted above, there is a vertically downward hydraulicgradient between the two sand and gravel aquifer units, which is likely to increase in the vicinity of anactively pumping well; however, the aquitard is considered to provide a protective hydraulic barrierbetween the two aquifer units.
Therefore, the receptors of groundwater from production wells (i.e. site staff using the water forpotable supply) are not considered likely to be at risk from potential groundwater contamination in theshallow aquifer zone. It is understood that groundwater from the abstraction wells is sampled on aquarterly basis and analysed for a suite of drinking water parameters. No issue with the potable waterquality has been reported since monitoring began.
The consumption of groundwater from groundwater wells is not considered to be a potential risk to off-site receptors.
The mill race, into which shallow groundwater from the perched aquifer discharges, joins the RiverBrinny to the south-east of the site at a location, which appears to be, directly up-gradient of thesurface water quality monitoring point at Brinny Bridge. Surface water quality at Bridge West ofRockfort House is classified as High Status (Q4-Q5), this is a slightly higher quality classification thanthe Q4 status which is registered for the upstream monitoring point at Bridge near BallinacurraHouse10. Therefore, water quality in the River Brinny improves slightly as it flows by the site,indicating that site operations are not having an adverse impact on surface water quality.
7.4 SummaryReported groundwater data ranges in April 2018 were within ranges previously reported (seeAppendix C Table 3) and do not indicate a deterioration in groundwater quality. There is no evidenceof impact to the adjacent surface water courses; in fact, the quality of water in the River Brinny actually increases down-stream of the site. It is understood that water from the on-site productionwells meets the standards for potable supply. A cross section of the site is presented in Appendix AFigure 4.
8. Site Investigation (Stage 7)
8.1 RationalSufficient data has been gathered from several phases of historic site investigations to characterisethe site. These have been conducted for various reasons, including:
· Groundwater resource assessment through the installation of trial and abstraction wells;
· Geotechnical investigations related to construction works on site; and,
· Installation of monitoring wells in the assessment of potential sources of contamination.
From available data, it appears that contamination issues on site have been localised and/or of shortduration.
As discussed in Section 1.1, this Baseline Report has been prepared to supplement an IE LicenceApplication which MSD Brinny are making for a revision of their existing IE Licence (P0005-02) due tochanging manufacturing operations within the MSD Brinny existing Biologics Buildings.
Due to changes in operations at MSD Brinny additional substances will be used. These additionalsubstances are
· Ethanol;
· Ammonium hydroxide;
· Potassium phosphate;
10 https://gis.epa.ie/EPAMaps/ - accessed 29 June 2018
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM15
· Phosphoric acid; and,
· Ammonium phosphate.
These additional substances are not classified as relevant hazardous substances with the exceptionof Ammonium Hydroxide. However Ammonium Hydroxide has been screened out as a relevanthazardous substances as discussed in Section 4.3 of this report. Furthermore under the proposednew process, there will be no change in chemical handling practices or chemical storage practices.
Additionally:
· The site history and environmental setting are well understood and documented;
· Site investigation and monitoring data are available, not only for the IE Licensed monitoringwells, but also for additional monitoring and site investigation points across the site; and,
· The existing groundwater monitoring suite includes data relevant to the new substances to beused on site
Therefore a site investigation is not warranted in support of this Baseline Report.
8.2 2002 Site InvestigationA site investigation was conducted in 2001 close to the generator building located to the west of thesite. The site investigation was conducted following the remediation of an oil spill close to thegenerator building (see section 5.2.1).
Three boreholes (GMW1 to GMW3) were drilled to between 7.0 m and 7.2 m bgl. The wells werescreened within the silty sand unit. Soil and groundwater samples were taken and analysed for asuite of hydrocarbon parameters. In addition a vapour survey was conducted inside the generatorbuilding. No elevated hydrocarbon concentrations were detected indicating that the remediation wassuccessful.
8.3 2003 Site InvestigationA site investigation was conducted in 2003 close to the fermenter building located to the south of thesite. The site investigation was conducted following the loss of ethylene glycol (see section 5.2.2).
A zone of contribution for the three onsite production wells was completed in 2003 which indicatedthat the spill occurred within the zone of contribution of well 653.
Initially a series of five boreholes (GMW4S/D, GMW5S/D and GMW6) were installed. The four pairedwells were screened within the interbedded sands, silts clays and gravels. The single installation wellGMW6 was installed within the deeper gravel aquifer. Groundwater from the five wells andgroundwater seepages at the base of the embankment to the west of the site adjacent to the mill racewere sampled for ethylene glycol. No ethylene glycol was detected in any of the groundwatersamples.
An additional five boreholes (GMW7 to GMW11) were installed to a depth of 8 m bgl in close proximityto Building 18 in late 2003. Nineteen soil samples were analysed for ethylene glycol. Ethylene glycolwas only detected above the method detection limit (MDL) in one sample (2.8 m bgl from boreholeGMW10) at a concentration of 35 mg/kg.
Monthly groundwater sampling took place in the five newly installed wells. Ethylene glycol wasdetected above the MDL in GMW10 and intermittently in GMW11.
A total of 75 surface water samples were taken following the spill. Ethylene glycol remained below theMDL in all samples tested.
The report concluded that ethylene glycol will readily biodegrade under both aerobic and anaerobicgroundwater conditions. The 2004 site investigation report concluded that:
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM16
“The remaining low levels which are well below the concentrations identified as posing a risk theenvironment, would be expected to be biodegraded and be assimilated in the environment in duecourse”11
Ethylene glycol has not been detected in groundwater from any of the onsite wells since testing for itresumed in 2009.
8.4 2004 Source Protection Area AssessmentFollowing on from the 2001 diesel spill and 2003 ethylene glycol spill it was recommended that aSource Protection Area assessment take place. Initially a zone of contribution for the three onsiteproduction wells was completed in 200312. Drilling records of the existing wells were used to definethe extents of the shallow and deep aquifers beneath the site. It was noted that groundwater flowwould be altered by the three onsite wells which would draw water radially in towards the activepumping well. A downward hydraulic gradient was identified through the low permeability aquitardseparating the two aquifers.
8.5 2006 Water Level SurveyIn 2006 a water level survey13 was conducted for selected wells on site to assist in the development ofa conceptual site model.
The monitoring wells used for the survey were surveyed to an arbitrary site datum to allowcomparisons of water levels and geological logs.
The survey confirmed that the lower aquifer is confined by the aquitard identified in previous siteinvestigations. Groundwater in deeper wells was found to be flowing radially towards the three on siteproduction wells. However, groundwater in the shallower wells flowed in a south easterly directiontowards the mill race where seepages of groundwater have been identified in the past. Theinvestigation concluded that groundwater in the deeper aquifer was of “high to moderate vulnerabilitydue to the presence of the overlying low permeability aquitard.”
However AECOM would classify the deeper aquifer as having a medium vulnerability due to thepresence of the aquitard.
8.6 2009 Geotechnical InvestigationA geotechnical assessment was conducted in 2009 to facilitate the extension of Building No. 19. Fourboreholes BH01 – BH04 were drilled to depths ranging from 8.0 m to 16.1 m bgl. A series of in-situand ex-situ geotechnical tests were conducted.
8.7 2012 IPC Well ReplacementIn 2012 due to the expansion of one of the existing on site structures, the original MW3S and MW3Dwere decommissioned. Two new wells were installed using the names MW-3S and MW-3D as closeas possible to original well locations. MW-3S was screened between 4 m bgl and 9 m bgl. No waterstrikes were noted. MW-3D was screened from 12.5 m to 13.8 m within the deeper sand and gravelaquifer. There was no evidence of contamination during drilling.
8.8 2017 Zone of Contribution EstimateAt the request of the EPA an updated zone of contribution (ZOC) report was produced in June 2017for the three on site production wells. Six data loggers were installed in wells across site to measurethe effect of pumping on site. The report concluded that a conservative estimate for the ZOC is 2.2
11 WYG (2004): Environmental Assessment – Phase III Schering-Plough (Brinny) Company, Innishannon, Co. Cork12 • WYG, 2004: Schering-Plough (Brinny) Company Source Protection Study, report reference #C00169713 • WYG, 2006: Groundwater Level Investigation at Schering-Plough Pharmaceutical Plant, Brinny, Co. Cork, report reference# CE05101
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM17
km2. The report concluded that there is no indication of long term declining water levels caused bythe current groundwater extraction regime.
8.9 IEL Groundwater SamplingUnder the terms of the site’s IEL, the site is required to conduct groundwater monitoring on a biannualbasis from seven wells: MW-1S, MW-1D, MW-2S, MW-3S, MW-3D, MW-4S and MW-4D (Condition 6and Schedule C.6 of the licence). The location of onsite monitoring wells are presented in Appendix AFigure 3
Groundwater samples are analysed for a suite of parameters as presented in Appendix C Table 2.
8.9.1 IEL Groundwater trendsGroundwater trends for the IEL wells are presented in Appendix C Table 3.
8.9.1.1 Diesel and LFOTotal petroleum hydrocarbons (TPHs) which would incorporate both diesel and LFO were below thelaboratory MDL in all samples taken since 2016. TPHs were not included in groundwater analyticalsuites at the MSD Brinny site prior to May 2016, however, constituents of diesel and LFO such astrimethylbenzene and napthalene were analysed for as part of volatile organic compound (VOC) andpolycyclic aromatic hydrocarbons (PAH) analysis suite, which were conducted annually for allsampled wells. VOC and PAH concentrations were low to below the MDL in every monitoring roundand do not indicate diesel or LFO contamination.
8.9.1.2 InorganicsSodium hypochlorite, ammonia hydroxide and hydrogen peroxide are inorganic materials. However,sodium hypochlorite, ammonia hydroxide and hydrogen peroxide cannot be readily analysed directlyby commercial laboratories.
Groundwater is analysed biannually for a comprehensive suite of major ions and metals. The currentmajor ion suite is considered sufficient to monitor ambient groundwater quality, while at the same timeincludes constituents of sodium hypochlorite (sodium and chloride are analysed for biannually) andammonia hydroxide (ammonia is analysed for biannually).
Both sodium and chloride are generally detected at low concentrations below relevant assessmentcriteria in groundwater well MW-3S and MW3-D which are located downgradient of the sodiumhypochlorite storage area.
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM18
9. Production of Baseline Report (Stage 8)Stage 8 of the baseline report summarises the information gathered in Stages 1- 7 of the report.
9.1 Stage 1 - Identification of Hazardous SubstancesIn stage one an inventory of raw materials, products, intermediaries, by-products, emissions andwastes which was provided by MSD was screened to identify hazardous substances used on site.
9.2 Stage 2 – Identification of ‘Relevant Hazardous Substances’Hazardous substances identified during stage 1 were screened to identify ‘Relevant HazardousSubstances’.
Five substances were carried through the stage 2 screening process:
· Diesel and light fuel oil;
· Ammonia hydroxide solution
· Sodium hypochlorite;
· Hydrogen peroxide; and,
· Environ Vesphene® SE phenolic disinfectant.
9.3 Stage 3 – Assessment of Site Specific Pollution PossibilityThe relevant hazardous substances identified in Stage 2 were assessed based on their:
· Storage and usage location;
· Usage quantity;
· Storage and transport methods; and,
· Review of secondary containment systems and procedures.
Following the completion of the screening process in stage 3 one relevant hazardous substance wasidentified: Diesel and LFO.
9.4 Stage 4 – Site HistoryThe site history including information of historical incidents which resulted in the loss to ground ofsubstances.
9.5 Stage 5 – Environmental SettingThe existing environment, including, topology, geology, hydrogeology, land use and drainage systemsare assessed.
9.6 Stage 6 – Site CharacterisationA cross section was produced from existing data from historical site investigation. The cross section ispresented in Appendix A Figure 4.
9.7 Stage 7 – Site InvestigationA site investigation was not needed as sufficient information is available from historic siteinvestigations to characterise the site.
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM19
Appendix A Figures
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EPA Export 20-11-2018:04:05:09
BRINNY CROSS ROADS
PUBL
IC ROAD
COVE
RED
WAL
KWAY
SUB-STN.
CORKTO
IRISH MAP GRID
IRISH MAP GRID
GENERATORCOMPOUND
S-300
BL
OW
ER
FIRE TENDER ACCESS
4
6
.
8
4
A
P
E
X
5
5
1
5
0
0
5
5
9
7
2
5
MAIN CAR PARK
CAR PARK
BALLINACURRA ROAD
CAR PARKOVERFLOW
TRUCK/DELIVERY AREA
S
T
O
P
RAMP
R
A
M
P
RAMP
RAMP
RAMP
BA
RR
IE
R
RAMPRAMP
B
I
K
E
S
H
E
L
T
E
R
RA
MP
BARRIER
BU
S
SH
EL
TE
R
SHELTER
BUS
CA
R
ON
LY
CA
R
ON
LY
Firewater Retention Lagoon
Main Site Warehouse
Waste storagelocationsMaterial storage
LEGEND
Satelite Warehouse
Building 18 Fermentation
Building 13 Fermentation & Warehouse
Building 8
Building 21
Utilities
Building 19 Operations
Building 4 Operations
Building 7 Boiler & Utilities
Production Well 651
Production Well 653
Production Well 654
Office Space
Service Building
Office Space
Waste Collection AreaBuilding 25
Solvent Store Building 23
Fire Water Pump House
Cooling Towers
Water Storage
Fire Water Storage
Fire Water Pump House
Waste Store
Waste Compound
Gas cylinder StoreBuilding 22 Technical Operations, Laboratories & Freezer Operations
Engineering Project Office
Building 5 Office and Engineering Store
Material Storage
Material StorageMaterial Storage
Material Storage
Material Storage
Light Fuel Oil AST
Light Fuel Oil AST
Light Fuel Oil AST
Light Fuel Oil AST
Waste StorageWaste Storage
Waste Storage
Engineering Store
Bulk Gas N2 Storage
Bulk Gas O2 Storage
Bulk Gas N2 Storage
Ammonia Hydroxide Solution Storage
Drawing Number Rev
THIS DOCUMENT HAS BEEN PREPARED PURSUANT TO AND SUBJECT TO THETERMS OF AECOM'S APPOINTMENT BY ITS CLIENT. AECOM ACCEPTS NO
LIABILITY FOR ANY USE OF THIS DOCUMENT OTHER THAN BY ITS ORIGINALCLIENT OR FOLLOWING AECOM'S EXPRESS AGREEMENT TO SUCH USE, ANDONLY FOR THE PURPOSES FOR WHICH IT WAS PREPARED AND PROVIDED.
www.aecom.com
DateApprovedCheckedDrawn
AECOM Internal Project No. Suitability
Scale @ A3 Zone / Mileage
Designed
Drawing TitleProject Title
Client
Purpose of issue
Tel:Fax:MSD IRELAND (BRINNY) 002 P01.2
4th Floor Adelphi Plaza, Adelphi CentreGeorge's Street Upper Dun LaoghaireDublin, Ireland
+353 01 2933100+353 01 2933100
JG JG CD CD/DUB 2018
FOR INFORMATION
1:2500
60563354
CORK
INFORMATIONMSD BRINNYBASELINE ASSESSMENT FIGURE 2 SITE LAYOUT
AECOM
Ordinance Survey Ireland Licence No EN0001917
© Ordinance Survey Ireland / Government of Ireland
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EPA Export 20-11-2018:04:05:09
SERVICES BUILDING
API
BUILDING 8
BUILDING 22
TECH OPS &FREEZER STORAGE
BUILDING5
OFFICE & WAREHOUSE
BUILDING 7BOILER & UTILITIES
BUILDING 13FERMENTATION& WAREHOUSE
BUILDING 18FERMENTATION
CONTRACTORS COMPOUND
BUILDING 4OPERATIONS BUILDING No. 1
GENERATOR COMPOUND
MAIN CAR PARK OVERFLOW CAR PARK
BUILDING 19OPERATIONS BUILDING No. 2
WASTE COLLECTION
AREA
SOLVENTSTORE
CYLINDERSTORE
WASTE SEGREGATION AREA
BUILDING 21PURIFICATION
TANK FARMAREA
WASTEWATER TREATMENT
FIRE WATER PUMPHOUSE
DIESEL STORAGE TANK
DIESEL STORAGE TANK
CHP PLANT
UTILITIES
GENERATOR
ESB SUBSTATION
South West
PROJECT
CLIENT
DRAWING TITLE
NOTES
1ST FLOOR, MONTROSE HOUSE, CARRIGALINE ROAD, DOUGLAS,CORK, IRELAND.
T : +353 (21)4365 006 www.aecom.com
MSD BRINNY
BASELINE ASSESSMENT
FIGURE 3_WELL LOCATIONS
DRAWN CHECKED APPROVED
BMC CD CDSCALE DRG NO.
DATE
N.T.S
JUN 2018
PR-253914-ACM-FG-EN-003APPROXIMATE SCALE
0m 50m
Production Well
IEL Monitoring Well Trial Well Location
TW3
WELL 653
GMW5D
GMW12
IPC1DIPC1S
TW2WELL 651
TW3
TW1
BH01 BH03
BH02GMW14GMW14
GMW13GMW13
GMW12
MW-1DMW-1S
TW2WELL 651
WELL 654WELL 654WELL 654 TW3
WELL 653WELL 653
GMW5SGMW5SGMW5SGMW5DGMW5D
GMW6GMW6
GMW10GMW10GMW7GMW7
GMW15GMW15
GMW16GMW16GMW17GMW17GMW17
GMW4SGMW4SGMW4SGMW4DGMW4DGMW4D
IPC3SMW-3S IPC3DMW-3D
IPC4DMW-4D
IPC4SMW-4SGMW2GMW2
GMW1GMW1
TW1
BH01 BH03
BH02 BH04BH04
Additional Groundwater Monitoring Well
GMW3GMW3MW-2SMW-2S
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MILL RACE FERMENTATION BUILDING
STORAGE TANKS
FO
R ILLU
ST
RA
TIV
E P
UR
PO
SE
S O
NLY
NO
TE
: HO
RIZ
ON
TAL A
ND
VE
RT
ICA
L SC
ALE
S D
O N
OT
CO
RR
ES
PO
ND
MILL RACE FERMENTATION BUILDING
STORAGE TANKS
MILL RACE FERMENTATION BUILDING
STORAGE TANKS
653GMW6
GMW10GMW7GMW15
653GMW6
GMW10GMW7GMW15
653
?
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?
?
???
?
?
? ? ?
?
GMW6
GMW10GMW7GMW15
??
?
?
???
?
?
? ? ?
BASELINE ASSESSMENT
MADE GROUND
LEGEND:
LOWER SAND AND GRAVEL (MAIN AQUIFER)
MSD BRINNY FIGURE 4 _ CROSS SECTIONPRESUMED MUDSTONE & SANDSTONE BEDROCK
GROUNDWATER ELEVATION OCTOBER 2015
SOUTH NORTH
1st Floor, Montrose House, Carrigaline Road, Douglas, Cork.Tel: +353 (0)21 436 5006 www.aecom.com
SANDY SILTY CLAY
DRAWN CHECKED APPROVED
CD CDSCALE DRG NO.
DATE
N.T.S
JUN 2018
PR-253914-ACM-FG-EN-001
BMC
UPPER SAND AND GRAVEL (PERCHED AQUIFER)
ME
TRE
S A
BO
VE
OR
DN
AN
CE
DAT
UM
(mA
OD
)
10m
15m
25m
20m
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EPA Export 20-11-2018:04:05:09
Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM20
Appendix B Relevant Hazardous Substances Tables
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
AL-FIX AKTIVATOR SFMixture -
H222, H229, H315,
H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
1, 10-Phenanthroline chloride monohydrate GR
for analysis and redox indicator [reagent for iron
(II)] Reag, Ph Eur
18851-33-7 - H301, H410 Yes No Solid <250 kg No - material is a solid
1,1,2,2-Tetrabromoethane 79-27-6 HazardousH302, H315, H319,
H330, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
1,10-Phenanthroline monohydrate 5144-89-8 - H301, H410 Yes No Solid <250 kg No - material is a solid
16-8420Q (ink)- -
H225, H319, H336,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
2-Hydroxybenzaldehyde for synthesis 90-02-8 -H302, H315, H317,
H319, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
2-Mercaptoethanol 60-24-2 -
H301, H310, H315,
H317, H318, H331,
H373, H410
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
2-tert-Butyl-4-methylphenol 2409-55-4 - H314, H411 Yes No Solid <250 kg No - material is a solid
3,3,5,5-TETRAMETHYL BENZIDINE LIQUID
SUBSTRATE- - H413 Yes No Solid <250 kg No - material is a solid
30% Acrylamide/Bis Solution, 29:1
- -
H302, H312, H315,
H317, H319, H340,
H350, H361, H372
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
3M AMS - - H400, H411 Yes Yes Solid 800 kg No - material is a solid
3M High Performance Rubber and Gasket
Adhesive 1300
- -
H225, H315, H317,
H319, H336, H351,
H360, H372
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
904 ROOF FELT ADHESIVE- -
EUH066, H226, H304,
H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
ALUÂ 1000Â AEROSOL- -
H222, H229, H315,
H319, H336, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Ammonia solution 28-30% GR for analysis
ACS,Reag. PH Eur7664-41-7 Non-Hazardous
H290, H314, H335,
H400Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Ammonia solution 35% 1336-21-6 - H314, H335, H400 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Ammonium cerium(IV) nitrate 16774-21-3 -H272, H290, H302,
H314, H317, H410Yes No Solid <250 kg No - material is a solid
Ammonium hydroxide solution1336-21-6 -
H302, H314, H335,
H410Yes Yes Liquid 2,084 l
Yes - Relevant Hazard
Statement (H410)
Ammonium Test in freshwater and seawater
Method: colorimetric with color card 0.5 - 1 - 2 -
3 - 5 - 10 mg/l NH₄⁺ MColortest
- -
H225, H290, H314,
H315, H318, H336,
H412
Yes Yes Solid 100,000 kg No - material is a solid
Ammonium thiocyanate1762-95-4 -
EUH032, H302, H312,
H318, H332, H412Yes No Solid <250 kg No - material is a solid
ARALDITE AV 138 M-1 - -H315, H317, H318,
H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Arsenic solution 1000 ppm 1327-53-3 Hazardous H290 H350 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Bactoshield CHG 4% Chlorhexidine Gluconate
4% Solution Antiseptic- - H315, H318, H351 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Belt Dressing Spray- - H222, H229, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Boric acid cryst,. suitable for use as excipient
EMPROVE exp Ph Eur, BP, NF10043-35-3 - H360FD Yes No Solid <250 kg No - material is a solid
BRASSO Metal Polish Liquid- - H226, H336, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Bromine 7726-95-6 Undetermined H314, H330, H400 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
CellTiter-Glo Buffer, 10ml- - H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
CENTOPLEX 2 EP- - EUH208, H318, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Chloroform for analysis EMSURE
ACS,ISO,Reag. Ph Eur
- Hazardous
H302, H315, H319,
H331, H351, H361d,
H372
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Cleaning Solution Thiourea / HCI- -
H314, H351, H361,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Cobalt( II) nitrate hexahydrate
10026-22-9
H272, H302, H317,
H318, H332, H334,
H341, H350, H360,
H410
Yes No Solid <250 kg No - material is a solid
Color Reference Solutions acc. to PH Eur- - H350, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Stage 1
Material/Substance
Stage 2
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
Stage 1
Material/Substance
Stage 2
Congo red (C.I. 22120) indicator Reag. Ph Eur- - H350, H361 Yes No Solid <250 kg No - material is a solid
Copper (II) sulfate pentahydrate cryst. suitable
for use as excipient EMPROVE exp Ph Eur, BP,
USP
7758-99-8 - H302, H318, H410 Yes No Solid <250 kg No - material is a solid
Copper Anti-Seize Paste - - H400, H412 Yes No Solid <250 kg No - material is a solid
Copper II nitrate trihydrate for analysis EMSURE10031-43-3 -
H272, H302, H315,
H319, H410Yes No Solid <250 kg No - material is a solid
Copper Sticks, Wires, Standard - - H400, H410 Yes No Solid <250 kg No - material is a solid
Copper(II) nitrate hemi(pentahydrate)19004-19-4 -
H271, H290, H302,
H314, H400, H410Yes No Solid <250 kg No - material is a solid
Copper(II) nitrate hydrate13778-31-9 -
H272, H302, H315,
H319, H410Yes No Solid <250 kg No - material is a solid
Copper(II) nitrate, 2.5-hydrate, reagent ACS 19004-19-4 H302, H314, H410 Yes No Solid <250 kg No - material is a solid
CRYSTAL VIOLET 548-62-9 - H412 Yes No Solid <250 kg No - material is a solid
CRYSTAL VIOLET SOLUTION (SOP 95.10)548-62-9 -
H225, H317, H319,
H341, H350Yes No Solid <250 kg No - material is a solid
Cyanide, standard solution, Specpure, CN
1000μg/ml- - H302, H312, H412 Yes No Liquid <250 l No - material is a solid
Cyclohexane for analysis EMSURE
ACS,ISO,Reag. Ph Eur110-82-7 -
H225, H304, H315,
H336, H410Yes No Liquid <250 l No - material is a solid
DICHLOROMETHANE75-09-2 Hazardous
H315, H319, H336,
H351Yes No Liquid <250 l No - material is a solid
Diesel (low sulphur fuel) 68334-30-5 Hazardous H411 Yes Yes Liquid <250 l Yes
Light Fuel Oil 68955-27-1 - H400, H410 Yes Yes Liquid <250 l Yes
Diphenylamine for synthesis122-39-4 Non Hazardous
H301, H311, H331,
H373, H410Yes No Solid <250 kg No - material is a solid
Divosan Activ VT5
- -
H272, H290, H302,
H312, H314, H335,
H410
Yes No Liquid <250 l No - material is a solid
Divosan QC VT50 - - H315, H318, H410 Yes No Liquid <250 l No - material is a solid
EDTA Calibration Sample 000060-00-4 Undetemined H300, H319, H412 Yes No Solid <250 kg No - material is a solid
Endbac Hand and Utensil Sanitising Wipes - - EUH208, H412 Yes No Solid <250 kg No - material is a solid
Endbac Sanitizing Tablets - - H314 H335 H400 Yes No Solid <250 kg No - material is a solid
Ethidium bromide solution 1239-45-8 - H331, H341 Yes No Liquid <250 l No - material is a solid
EVANS BLUE 314-13-6 - H350 Yes No Solid <250 kg No - material is a solid
EVO-STIK GRIPFILL- -
H225, H315, H336,
H412Yes No Solid <250 kg No - material is a solid
Farbex White Spirit- -
EUH066, H226, H304,
H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
FERROQUEST LP7121- -
EUH208, H290, H315,
H319, H412Yes No Liquid <250 l No - material is a solid
FLEETLUBE 30W- - Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Formaldehyde solution min. 37% stabilized with
about 10% methanol Ph Eur,BP,USP
- -
H301, H311, H331,
H314, H317, H335,
H341, H350, H370
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Free Cyanide IC Standard - - H301, H332, H412 Yes No Solid <250 kg No - material is a solid
Glutaric dialdehyde, 25 wt.% solution in water
111-30-8 Non Hazardous
H290, H302, H314,
H317, H332, H334,
H412
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
ARALDITE HARDENER HV 998-1- -
H315, H317, H318,
H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Heat Transfer Compound - Aerosol- -
H222, H229, H336,
H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
HHS 2000 500ml- -
H222, H229, H315,
H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
HYDRANAL75-12-7 - H351, H360D, H373 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
Stage 1
Material/Substance
Stage 2
Hydrazine sulfate salt10034-93-2 -
H301, H311, H317,
H331, H350, H410Yes No Solid <250 kg No - material is a solid
Hydrogen Peroxide 7722-84-1 Undetermined H302, H318, H413 Yes Yes Liquid <250 lYes - Relevant Hazard
Statement (H413)
Hydrogen sulfide7792-06-4 -
H220, H280, H330,
H400Yes Yes Gas <250 l No - Gas
Hydroxylaine
7803-49-8 -
H290, H302, H312,
H315, H317, H319,
H351, H373, H410
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Hydroxylamine hydrochloride
54-11-1 -
H290, H302, H312,
H315, H317, H319,
H351, H373, H400
Yes No Solid <250 kg No - material is a solid
Hydroxylammonium chloride GR for analysis
ACS,ISO,Reag. Ph Eur
5470-11-1 -
H290, H302, H312,
H315, H317, H319,
H351, H373, H400
Yes No Solid <250 kg No - material is a solid
INSECT KILLER FOGGERS - - H317, H410 Yes No Solid <250 kg No - material is a solid
Iodine sublimated for analysis EMSURE
ACS,ISO,Reag. Ph Eur
- -
H312, H315, H319,
H332, H335, H372,
H400
Yes No Solid <250 kg No - material is a solid
Jotamastic 87 Comp A- -
H226, H315, H317,
H318, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Jotun Thinner No.17
- -
H226, H304, H315,
H318, H335, H336,
H411
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Klubersynth UH1 14-1600 - - H412 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
LABEL REMOVER- -
H222, H229, H315,
H317, H336, H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Lanthanum nitrate hexahydrate for analysis 233-238-0 - H272, H318, H410 Yes No Solid <250 kg No - material is a solid
Lead (II) nitrate for analysis EMSURE ACS,
Reag. Ph Eur10099-74-8 -
H302, H318, H332,
H360, H372, H410Yes No Solid <250 kg No - material is a solid
LEAD ACETATE COTTON EUROPEAN
PHARMACOPOEIA- - H360, H411 Yes No Solid <250 kg No - material is a solid
Lead(II) acetate trihydrate for analysis EMSURE
A CS,Reag. Ph Eur6080-56-4 - H360Df, H373, H410 Yes No Solid <250 kg No - material is a solid
LOCTITE SF 7063 known as Loctite 7063- -
H225, H315, H336,
H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Magnesium (II) chloride tetrahydrate for analysis
EMSURE ACS13446-34-9 - H302, H411 Yes No Solid <250 kg No - material is a solid
Manganese(II) sulfate monohydrate spray-dried
for analysis EMSURE ACS,Reag. Ph Eur
10034-96-5 - H318, H373, H411 Yes No Solid <250 kg No - material is a solid
Mercuric Bromide Paper- -
H300, H310, H319,
H330, H373, H410Yes No Solid <250 kg No - material is a solid
Mercury(II) iodide red, for analysis EMSURE
ACS,Reag. Ph Eur7774-29-0 -
H300, H310, H330,
H373, H410Yes No Solid <250 kg No - material is a solid
Mercury(II) thiocyanate for analysis Reag. Ph
Eur 592-85-8 -
EUH032, H300, H310,
H330, H373, H410Yes No Solid <250 kg No - material is a solid
Metacresol / m-Cresol 108-39-4 -H301, H311, H314,
H412Yes No Liquid <250 -
No - Quantity below 250 l /
250 kg
Mettler-Toledo Calibration substance ME 18870,
Benzophenone 119-61-9 Undetemined H410 Yes No Solid <250 kg No - material is a solid
Mitomycin C from Streptomyces caespitosus 50-07-7 - H302, H351 Yes No Solid <250 kg No - material is a solid
MK-1308- - H360D, H373 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
MK-5890- - H360D, H373 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
N-(2-Hydroxyethyl)aniline 122-98-5 -H310, H318, H373,
H412Yes No Solid <250 kg No - material is a solid
NALCO 93033- - EUH031, H314, H400 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Nessler's reagent A for determination of nitrogen
Solution A: potassium tetraiodomercurate (II)
solution.
- -H301, H310, H331,
H373, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
n-Heptane for analysis EMSURE Reag. Ph Eur142-82-5 -
H225, H304, H315,
H336, H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Nickel(II) chloride hexahydrate 7791-20-0 -
H301, H315, H317,
H331, H334, H341,
H350, H360, H372,
H410
Yes No Solid <250 kg No - material is a solid
Nitrilotriacetic Acid 139-13-9 Undetemined H319, H351 Yes No Solid <250 kg No - material is a solid
NOVA PTFE OIL- -
EUH066, H222, H229,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
Stage 1
Material/Substance
Stage 2
NOVELEC-S
- -
EUH018, H229, H315,
H319, H335, H336,
H360FD, H373
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
o-Cresol (Cresylic acid)95-48-7 Non Hazardous
H301, H311, H314,
H411Yes No Solid <250 kg No - material is a solid
Octanoic acid124-07-2 - H314, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
OQ - PV Chemicals Standards Kit 1, Part
Number 5063-6503
- -
EUH210, H225, H302,
H304, H314, H315,
H319, H330, H335,
H336, H361, H373,
H400, H411, H412
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
PARALIQ GA 343- - H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
PENETRON AEROSOL- -
H222, H229, H315,
H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
PETROLEUM ETHER 40-60
101316-46-5 -
H225, H304, H315,
H336, H361, H373,
H411
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Petroleum ether, boiling range 100-120°C64742-49-0 -
H225, H304, H315,
H336, H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
PhastGel Homogenous 20 - - H340, H350 Yes No Solid <250 kg No - material is a solid
Phenacetin Melting Point Standard 62-44-2 - H302, H350 Yes No Solid <250 kg No - material is a solid
Phenol
108-95-2 Non Hazardous
H301, H311, H314,
H331, H341, H373,
H411
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
PHENOLPHTALEIN INDICATOR TS- - H225, H341, H350 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
PHENOLPHTALEIN SOLUTION R1
EP(PH.EUR.)77-09-8 - H225, H341, H350 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Phenylhydrazine hydrochloride
59-88-1 Non Hazardous
H301, H311, H331,
H315, H317, H319,
H341, H350, H372,
H410
Yes No Solid <250 kg No - material is a solid
Phosphate Test Method: colorimetric, PMB, with
color-matching vessel 1.0 -2.5 -5.0 -7.5 -10 mg/l
P2O5 1.3 -3.3 -6.7 -10.0 -13.4 mg/l PO4 3-
MColortest PO4-
- - H317, H411 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Phthaldialdehyde643-79-8 -
H301, H314, H317,
H400, H410Yes No Solid <250 kg No - material is a solid
Pneumococcal Polysaccharide Purified Bulk
Powder containing < 8.5% Alcohol- - H341 Yes No Solid <250 kg No - material is a solid
Pneumococcol Polysaccharide Purified Bulk
Powder containing > 8.5 % Alcohol- - H228, H341 Yes No Solid <250 kg No - material is a solid
Posaconazole - - H361, H372, H410 Yes No Solid <250 kg No - material is a solid
Potassium Bromate 7765-01-2 - H271, H301, H350 Yes No Solid <250 kg No - material is a solid
Potassium chromate for analysis EMSURE
ACS,Reag. Ph Eur
7789-00-6 -
H315, H317, H319,
H335, H340, H350i,
H410
Yes No Solid <250 kg No - material is a solid
Potassium dichromate
7778-50-9 -
H272, H301, H310,
H314, H317, H330,
H334, H335, H340,
H350, H360, H372,
H410
Yes No Solid <250 kg No - material is a solid
Potassium hexahydroxoantimonate(V) cryst. for
analysis EMSURE12208-13-8 - H302, H332, H411 Yes No Solid <250 kg No - material is a solid
Potassium permanganate for analysis EMSURE
ACS,Reag. Ph Eur7722-64-7 Undetemined
H272, H302, H314,
H400, H410Yes No Solid <250 kg No - material is a solid
Potassium Thiocyanatefor analysis EMSURE
ACS, ISO, Reag. Ph Eur333-20-0
EUH032, H302, H312,
H332, H412Yes No Solid <250 kg No - material is a solid
PRESEPT Disinfectant Tablets & Granules
(Product packed in tubs)- -
EUH031, H319, H335,
H410Yes No Solid <250 kg No - material is a solid
PRIMARY BLUE SOLUTION77658-98-7 - H411 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Primary opalescence suspension100-97-0 - H317, H350, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
PRIMARY RED SOLUTION
7646-79-9 -
H302, H317, H334,
H341, H350, H360,
H410
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
RBS R 60Mixture
H226, H315, H319,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
RTD LIQUID- -
EUH066, EUH208,
H362, H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
SAFETY CLEAN AEROSOL- -
EUH066, H222, H229,
H336, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Salicylaldehyde
90-02-8 -
H302, H315, H317,
H319, H335, H341,
H411
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Selenite Cystine Broth- -
H300, H317, H332,
H335, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
Stage 1
Material/Substance
Stage 2
Selenium7782-49-2 -
H301, H331, H373,
H413Yes No Solid <250 kg No - material is a solid
Shell Gadus S2 V100 2 - - H412 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Shell Morlina S2 BL 10- - H304, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
SILICON 100 AEROSOL64742-46-7 -
H225, H304, H336,
H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Silver nitrate for analysis EMSURE
ACS,ISO,Reag.Ph Eur7761-88-8 - H315, H319, H412 Yes No Solid <250 kg No - material is a solid
Sodium azide26628-22-8 -
EUH032, H300, H310,
H373, H400, H410Yes No Solid <250 kg No - material is a solid
Sodium bicarbonate 144-55-8 -EUH014, H260, H301,
H314, H360FYes No Solid 99,360 kg No - material is a solid
Sodium borohydride fine granular for synthesis16940-66-2 -
EUH014, H260, H301,
H314, H360FDYes No Solid <250 kg No - material is a solid
Sodium borohydride, 12% aqueous solution,
(VenPureTM solution), contains 40% NaOH- -
H290, H302, H314,
H360FDYes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Sodium cyanoborohydride solution
25895-60-7 -
EUH032, H228, H300,
H310, H330, H314,
H410
Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
Sodium dodecyl sulfate
151-21-3 -
H228, H302, H315,
H318, H332, H335,
H412
Yes No Solid <250 kg No - material is a solid
Sodium Hexanitrocobaltate (III)
13600-98-1 -
H272, H315, H317,
H319, H334, H335,
H351
Yes No Solid <250 kg No - material is a solid
Sodium Hypochlorite <5%Mixture Non Hazardous H400 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Sodium hypochlorite solution7681-52-9 Non Hazardous
EUH031, H290, H314,
H400, H411Yes Yes Liquid 2,700 l
Yes - Relevant Hazard
Statement (H400 , H411)
Sodium nitrite7632-00-0 -
H272, H301, H319,
H400Yes No Solid <250 kg No - material is a solid
Sodium periodate7790-28-5 -
H271, H314, H372,
H400Yes No Solid <250 kg No - material is a solid
Soft Care Sensisept H34- - H319, H410 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
SOLVETRON AEROSOL- -
H222, H229, H315,
H319, H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Spotcheck SKC-S- -
H225, H304, H315,
H336, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Streptomycin Sulfate, Streptomyces sp. 3810-74-0 - H302, H360Fd Yes No Solid <250 kg No - material is a solid
Suma Bac Conc D10 Conc- -
EUH208, H315, H318,
H410, H411Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Suma Star Plus D1-PLUS- -
H302, H315, H318,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Suma Unison Brite A1- - H315, H319, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Suma Unison Maxi G3- -
EUH031, EUH071,
H314, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Suniso SL 32- - H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Tangit Dytex- -
H315, H319, H335,
H336, H351, H373Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Taski Sani Des Conc W9a- -
EUH208, H290, H315,
H318, H410Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
TDA (Ferric chlotide)7705-08-0 -
H302, H315, H318,
H412Yes No Solid <250 kg No - material is a solid
Tego 2000 VT25 - - H315, H318, H410 Yes No Liquid <250 lNo - Quantity below 250 l /
250 kg
TEMALAC FD 80- -
H226, H315, H319,
H335, H373, H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Tetrahydrofuran109-99-9 -
EUH019, H225, H302,
H319, H335, H351Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Thiazolyl Blue Tetrazolium Bromide298-93-1 -
H315, H319, H335,
H341Yes No Solid <250 kg No - material is a solid
Thioacetamide GR for analysis ACS,Reag.Ph
Eur62-55-5 -
H302, H315, H319,
H350, H412Yes No Solid <250 kg No - material is a solid
Tin Chloride dihydrate
10025-69-1 -
H314, H317, H332,
H335, H341, H361,
H373, H410
Yes No Solid <250 kg No - material is a solid
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Appendix B Table 1 - Stages 1 and 2
CAS NumberEPA's Classification of Hazardous and
Non-hazardous Substances
Relevant Hazard
Statement
Hazardous
Substance
Quantity greater
than 250 l / 250 kg
Physical State of Chemical
Stored On-Site
Amount Stored
(approximate)Unit
Considered a Relevant
Hazardous Substance
Stage 1
Material/Substance
Stage 2
Trifluoracetic acid76-05-1 - H314, H332, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Triton X-100 (Octylphenol ethoxylate)9036-19-5 Undetemined H302, H318, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
TRYPAN BLUE STAIN- - H350, H361 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
TUFCUT - - H362, H411 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Environ Vesphene SE Mixture - - - Yes
biphenyl-2-ol 90-43-7 Non hazardous H400, H410 Yes No
p-(1,1-dimethylpropyl)phenol 80-46-6 - H410 Yes Yes
Potassium Hydroxide
1310-58-3 Undetermined
H225, H290, H302,
H314, H318, H340,
H360, H370, H372
Yes Yes
clorofene
120-32-1 Hazardous H400, H410 Yes Yes
Vi-CELL Quad and Single Pak- -
H225, H317, H319,
H334, H336, H350Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Virkon S - -
EUH208, H315, H318,
H412Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
WEATHERSHIELD SMOOTH MASONRY PAINT- - H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
WELD-ON 725, Wet 'R Dry, Low VOC Cement
for PVC Plastic Pipe- -
EUH019, H225, H319,
H335, H336, H351Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Zinc chloride for analysis EMSURE
ACS,ISO,Reag. Ph Eur7646-85-7 Undetemined H302, H314, H410 Yes No Solid <250 kg No - material is a solid
Zinc solution 10 000 ppm7446-20-0 - H290, H314, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
ZINC SULFATE 0.0500 MOLAR- - H319, H412 Yes No Liquid <250 l
No - Quantity below 250 l /
250 kg
Zinc sulfate heptahydrate for analysis EMSURE
ACS,ISO,Reag. Ph Eur7446-20-0 - H302, H318, H410 Yes No Solid <250 kg No - material is a solid
Zinc Sulphate - - H302, H318, H410 Yes No Solid <250 kg No - material is a solid
Zinc volumetric standard, secondary reference
material for complexometry, traceable to NIST
SRM Certipur Reag. Ph Eur
- - H410 Yes No Solid <250 kg No - material is a solid
Liquid 1,100 l
Yes - Relevant Hazard
Statement (H400 , H411,
H412)
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Appendix B Table 2 - Stage 3
Storage Location Transportation MethodContainment
Measures
Likelihood of
Release to Open
Ground
Previously lost to
ground
Presently Monitored in
Groundwater
To be Monitored for as a
Relevant Hazardous
Substance - Rationale
Ammonia hydroxideIBCs stored in Chemstore
near the WwTP
By forklift over roadways connected to tertiary
containment
Stored in secondary and
tertiary containment, not
stored in bulk
Highly Unlikely No
Yes - constituent inorganic
components (Total Ammonia)
analysed for biannually
No - Not stored in bulk,
adequately bunded
Diesel (low sulphur fuel)Above ground storage
tanks located across sitePipework. Tanks refilled by tanker
Tanks and all flanges
and valves located in
bunds. Tertiary
containment provided in
the event of secondary
containment failure.
Pipework over made
ground along western
boundary
Unlikely Yes in 2001 and 2004 Yes - As TPH annually
Yes - Stored in bulk, Relevant
Hazard Statement (H411),
previously lost on site
Light Fuel Oil (LFO)Above ground storage
tanks located across sitePipework. Tanks refilled by tanker
Tanks and all flanges
and valves located in
bunds. Tertiary
containment provided in
the event of secondary
containment failure.
Unlikely No Yes - As TPH annually
Yes - Stored in bulk,
Relevant Hazard Statement
(H400, H411),
Hydrogen peroxide Main warehouse By forklift over roadways connected to tertiary
containment
Stored in secondary and
tertiary containment, not
stored in bulk
Highly Unlikely No NoNo - Not stored in bulk,
adequately bunded
Sodium hypochlorite solution
25 l drums in bunded
area
By forklift over roadways connected to tertiary
containment
Stored in secondary and
tertiary containment, not
stored in bulk
Highly Unlikely No
Yes - constituent inorganic
components (sodium, chloride)
analysed for biannually
No - Not stored in bulk,
adequately bunded
Environ Vesphene SE
biphenyl-2-ol
p-(1,1-dimethylpropyl)phenol
Potassium hydroxide
clorofene
Highly Unlikely
Material/Substance
Stage 3
Yes- constituent components
(potassium and isopropanol are
analysed for biannually and
annually respectively)
No - Not stored in bulk,
adequately bunded
Main warehouse in small
containers
By forklift or by handover roadways nnected
to tertiary containment
Stored in secondary and
tertiary containment, not
stored in bulk
No
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM21
Appendix C Site Investigation Data
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Prepared by: BMC
Checked by: EOHAppendix C - Table 1 Well Inventory
MSD Brinny1 of 1
Borehole Well Drilled InstalledMeasured
April-2018
Easting Northing m SD m OD m SD m SD 6 m OD mm mm m bgl m bgl m bct m bgl m bct m bgl m bct m
3/hr m/d
PW2 1975 ~ 151630 59320 ~ ~ ~ ~ ~ ~ ~ 25.6 ~ nf ~ ~ ~ ~Gravel, bedrock
at 24 m bgl61.4 ~ Not found. 1, 12
PW4 1975 ~ 151690 59290 ~ ~ ~ ~ ~ ~ ~ 20.2 ~ nf ~ ~ ~ ~Gravel, bedrock
at 18 m bgl13.6 ~ Not found. 1, 12
3 1974 ~ 151660 59340 ~ ~ ~ ~ ~ ~ ~ 70.1 ~ nf ~ ~ ~ ~ Bedrock at 9.1 m bgl 22.7 ~ Not found. 1, 12
PW3 1975 ~ 151590 59290 ~ ~ ~ ~ ~ ~ ~ 26.5 ~ nf ~ ~ ~ ~ Bedrock at 24.5 m bgl 27.3 ~ Not found. 1, 12
651 Pre 1992 na 551549.71 559544.43 28.450 27.204 27.500 39.060 27.204 350 250 23.0 23.0 nm 13.0 ~ 23.0 ~ Gravel and bedrock 39.5 80Well located in pump house, sealed, upright
headworks.3, 4, 5, 6
653 Pre 1992 na 551461.08 559509.14 29.050 26.574 29.300 40.030 26.574 350 250 62.5 60.0 nm 10.0 ~ 60.0 ~ Gravel and bedrock 39.5 17Well located in pump house, sealed, upright
headworks.3, 4, 5, 6
654 1992 na 551538.85 559498.76 27.700 24.450 27.700 38.370 24.450 350 250 23.6 18.0 nm 12.0 ~ 18.0 ~Gravel, bedrock
at 19 m bgl39.5 60
Well located in pump house, sealed, upright
headworks.3, 4, 5, 6, 12
5 Pre 1982 na ~ ~ 28.25 ~ 28.25 38.58 25.517 ~ ~ ~ ~ nf ~ ~ ~ ~ Gravel and bedrock ~ ~ Well decommissioned in 2017 1, 4, 6
PW6 1982 ~ 151520 59450 ~ ~ ~ ~ ~ ~ ~ 23.5 ~ nf ~ ~ ~ ~ Gravel 67.0 50 Not found. 1, 12
7 1974 ~ 151620 59290 ~ ~ ~ ~ ~ ~ ~ 64.0 ~ nf ~ ~ ~ ~Gravel and bedrock,
bedrock at 9.1 mbgl2.3 50 Not found. 1, 12
8 1974 ~ 151630 59450 ~ ~ ~ ~ ~ ~ ~ 17.7 ~ nf ~ ~ ~ ~Gravel, bedrock
at 14 m bgl1.2 ~ Not found. 1, 12
TW1 1992 na 551334.59 559663.06 ~ 27.414 ~ ~ 27.301 ~ 150 22.0 ~ 20.330 ~ ~ ~ ~ Bedrock at 20 m bgl 2.0 ~ Upright cover. 5, 12
TW2 1992 na 551509.04 559602.39 ~ ~ ~ ~ 27.101 ~ ~ 85.0 ~ 23.92 ~ ~ ~ ~ Bedrock at 23.5 m bgl 30.3 ~
Open borehole, with steel casing recessed into
ground. Large steel lid covering well opening.
Not locked.
5, 12
TW3 1992 na 551534.59 559499.43 ~ ~ ~ ~ ~ ~ ~ 17.8 ~ 14.370 ~ ~ ~ ~ Bedrock at 17 m bgl 38.5 ~ Locked, upright cover, good condition. 5, 12
MW-1S 1991 na 551643.10 559681.20 27.908 28.058 28.228 41.440 28.137 ~ 50 ~ 6.0 6.250 ~ ~ ~ ~ ~ ~ ~Locked, labelled upright cover, holes in lid due
to rust. PVC bailer installed2, 6, 8
MW-1D 1991 na 551642.38 559681.00 27.903 28.058 28.273 41.410 28.101 ~ 50 ~ 9.0 9.220 ~ ~ ~ ~ ~ ~ ~ Locked, labelled upright cover, good condition 2, 6, 8
MW-2S 1991 na 551553.65 559337.24 24.771 24.891 24.885 37.900 24.877 ~ 50 ~ 5.9 6.230 ~ ~ ~ ~ ~ ~ ~Labelled upright cover, good condition. Waterra
installed. Needs new lock2, 6, 8
1991 2012 151441 59342 26.049 ~ 26.331 39.300 ~ ~ 50 ~ 5.9 ~ ~ ~ ~ ~ ~ ~ ~ 2, 6, 7, 8
2012 na 551409.95 559406.97 ~ 26.871 ~ ~ 26.909 150 50 11.0 9.0 5.540 4.0 ~ 9.0 ~ Sandy silt and clay ~ ~ 7
1991 2012 151441 59342 26.067 ~ 26.232 39.160 ~ ~ 50 ~ 9.1 ~ ~ ~ ~ ~ ~ ~ ~ 2, 6, 7, 8
2012 na 551408.74 559407.47 ~ 26.865 ~ ~ 26.877 150 50 13.8 13.8 13.760 12.5 ~ 13.8 ~ Gravel ~ ~ 7
MW-4S 1992 na 551356.88 559555.00 27.027 27.177 27.217 40.000 26.975 200 50 7.5 7.5 7.780 4.5 4.69 7.5 7.69 Silty sand ~ ~Locked, labelled upright cover, good condition.
PVC bailer installed.2, 6
MW-4D 1992 na 551356.48 559554.66 27.020 27.177 27.210 40.200 27.168 200 50 12.0 12.0 11.070 9.0 9.19 12.0 12.19 Gravel ~ ~ Locked, labelled upright cover, good condition. 2, 6
GMW1 2001 na 551373.80 559544.91 28.940 27.073 29.190 ~ 27.210 200 50 7.0 7.0 6.810 5.0 ~ 7.0 ~ Silty sand ~ ~ Upright cover, good condition. 3
GMW2 2001 na 551354.97 559561.61 28.880 27.216 28.900 ~ 27.048 200 50 7.0 7.0 7.290 5.0 ~ 7.0 ~ Silty sand ~ ~ Upright cover, good condition. 3
GMW3 2001 na ~ ~ 28.850 ~ 28.760 ~ ~ 200 50 7.2 7.0 6.980 5.0 ~ 7.0 ~ Silty sand ~ ~ Flush cover, no label, chamber filled with mud. 3
GMW4S 2003 na 551492.88 559380.67 27.740 24.886 27.440 37.630 24.607 150 50 8.5 8.5 7.860 5.5 5.20 8.5 8.20 Sand, silt and clay ~ ~Locked, labelled upright cover, good condition.
HDPE sampling tubing installed.4, 6
GMW4D 2003 na 551492.16 559380.87 27.740 24.879 27.350 37.670 25.059 150 50 18.0 17.5 17.110 14.5 14.11 17.5 17.11 Sandy gravel ~ ~Locked, labelled upright cover, good condition.
No sampling equipment installed.4, 6
GMW5S 2003 na 551491.73 559445.30 27.980 25.235 28.150 38.700 25.317 150 50 8.0 8.0 6.700 5.0 5.17 8.0 8.17 Sand, silt and clay ~ ~Locked, labelled upright cover, good condition.
PVC bailer installed.4, 6
GMW5D 2003 na 551492.63 559443.97 27.980 25.164 28.120 38.670 25.292 150 50 18.0 18.0 16.650 15.0 15.14 18.0 18.14 Sandy gravel ~ ~ Labelled upright cover, good condition. 4, 6
GMW6 2003 na 551471.51 559450.04 28.360 25.620 28.400 38.870 25.562 150 50 15.0 12.0 11.540 9.0 9.04 12.0 12.04Sand, silt and clay and
sandy gravel~ ~
Locked, labelled upright cover, good condition.
PVC bailer installed.4, 6
GMW7 2003 na 551472.41 559405.20 27.700 24.654 27.700 37.580 24.554 100 50 8.0 8.0 7.600 6.0 ~ 8.0 ~ Boulder clay ~ ~Locked, labelled upright cover, good condition.
PVC bailer installed.6, 8, 9
GMW8 2003 2004 ~ ~ 27.700 ~ 27.715 ~ ~ 100 50 8.0 8.0 ~ 6.0 ~ 8.0 ~ Boulder clay ~ ~ Well decommissioned. 8, 9
GMW9 2003 2004 ~ ~ 27.700 ~ 27.710 ~ ~ 100 50 8.0 8.0 ~ 6.0 ~ 8.0 ~ Boulder clay ~ ~ Well decommissioned. 8, 9
GMW10 2003 na 551475.09 559411.06 27.700 24.734 27.720 37.590 24.740 150 50 8.0 6.0 5.320 4.0 ~ 6.0 ~ Silty sand ~ ~Labelled upright cover, good condition. PVC
bailer installed. Needs new lock6, 8, 9
GMW11 2003 2004 ~ ~ 27.700 ~ 27.710 ~ ~ 150 50 8.0 8.0 ~ 6.0 ~ 8.0 ~ Sand ~ ~ Well decommissioned. 8, 9
GMW12Pre July
2004na 551569.91 559685.71 ~ 28.368 ~ 41.740 28.443 ~ ~ ~ ~ 8.100 ~ ~ ~ ~ ~ ~ ~ Labelled upright cover, good condition. 6
GMW13Pre July
2004na 551567.06 559583.00 ~ 27.325 ~ 40.720 27.410 ~ ~ ~ ~ 4.200 ~ ~ ~ ~ ~ ~ ~ Labelled upright cover, good condition. 6
GMW14Pre July
2004na 551493.04 559489.20 ~ 26.402 ~ 39.660 26.358 ~ ~ ~ ~ nf ~ ~ ~ ~ ~ ~ ~ Capped under a new building. 6
GMW15 Q4 2004 na 551462.61 559389.92 ~ 24.817 ~ 37.690 24.744 ~ 50 ~ ~ 6.300 ~ ~ ~ ~ ~ ~ ~Labelled upright cover, good condition. PVC
bailer installed. Needs new lock6
GMW16 Q4 2004 na 551480.25 559380.88 ~ 24.726 ~ 37.630 24.600 ~ 50 ~ ~ 6.820 ~ ~ ~ ~ ~ ~ ~Locked, labelled upright cover, good condition.
PVC bailer installed.6
GMW17 Q4 2004 na 551485.17 559380.96 ~ 24.745 ~ 37.720 24.691 ~ 50 ~ ~ 5.090 ~ ~ ~ ~ ~ ~ ~Locked, labelled upright cover, good condition.
Needs new lock.6
BH01 2009 na 551399.09 559652.91 ~ 27.483 ~ ~ 27.737 200 50 16.1 13.0 11.960 10.0 ~ 13.0 ~ Sand and gravel ~ 11 - 25 Locked. labelled upright cover. 10
BH02 2009 na 551381.75 559637.40 ~ 27.443 ~ ~ 27.723 200 50 11.1 8.0 5.850 4.0 ~ 8.0 ~ Sand, clay and gravel ~ 0.08 - 0.18 Locked. labelled upright cover. 10
BH03 2009 na 551387.25 559668.85 ~ 27.443 ~ ~ 28.040 200 50 8.0 6.0 4.970 3.0 ~ 6.0 ~ Clay ~ 7Labelled upright cover. Lid bent, lock cannnot be
closed. Needs bung10
BH04 2009 na 551370.118 559653.074 ~ 27.474 ~ ~ 27.942 200 50 15.3 15.0 14.260 8.5 ~ 15.0 ~ Gravel ~ 3 Locked. labelled upright cover. 10
Notes:
m OD -
m SD -
m SD 6 -
m bgl -
m bct -
m3/hr -
m/d -
na -
nf -
nm -
~ -
Bold -
No data
Indicates data for decommissioned well
Metres to Ordnance Datum, as surveyed 21 August 2015
Cubic metres per hour
Metres per day
Not applicable
Not found
Not measured due to access
Well Condition
Labelled, upright cover, good condition. PVC
bailer installed. Needs new lock
Upright cover, good condition.
Hydraulic
Conductivity Sources of
Information
Sources of Information:
Trial or
Unused
Production
Production
Year
Installed
Site
Investigation
and
Additional
Monitoring
Total Depth Screen Interval
Geological Unit
Well
IEL
Monitoring
Diameter
Top Base
Location Co-ordinate, as
surveyed 21 August 2015
Elevation
Ground Casing
Yield
Year
Deco
mm
issio
ned
MW-3S
MW-3D
3 - KT Cullen, 2002: Environmental Investigation, Schering-Plough (Brinny) Company, Innishannon, Co. Cork FINAL, # 3037
4 - WYG, 2003: Environmental Assessment Phase II, Schering-Plough (Brinny) Company, Innishannon, Co. Cork DRAFT, # C002681/2
5 - WYG, 2004: Schering-Plough (Brinny) Company Source Protection Study, # C001697
6 - WYG, 2006: Groundwater Level Investigation at Schering-Plough Pharmaceutical Plant, Brinny, Co. Cork, # CE05101
7 - WYG, 2012: The Relocation of Groundwater Monitoring Boreholes MW3S & MW3D due to Site Expansion Works, # CE08805
11 - WYG, 2010 IPPC Licence Application
12 - Geological Survey of Ireland website, www.gsi.ie
1 - KT Cullen, 1982: Report on the Possible Effect on Local Groundwater Levels due to Increased Abstractions at Chemibitoic (Irl.) Ltd., Brinny, Co. Cork
8 - WYG, CE08805 project file
9 - WYG, CE02681 project file
10 - WYG, 2009: Geotechnical Interpretive Report, # CE06761
2 - KT Cullen, 1992: Groundwater Monitoring Well Installation and Sampling, Schering-Plough, Brinny, Innishannon, Co. Cork FINAL Metres to site datum, as originally reported
Top of well casing elevations as re-surveyed in 2006
Metres below ground level
Metres below casing top
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C Table 1
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EPA Export 20-11-2018:04:05:09
Prepared by: BMC
Checked by: EOHAppendix C Table 2 - Analytical Schedule
MSD Brinny Groundwater Monitoring 2017 - 2018
Page 1 of 1
Total
Ammonia
Nitrate /
NitriteMajor Ions Metals VOCs
Alcohols &
AcetatesTCA TPH Glycols COD
MW-1S B B B B A A A A A B
MW-1D B B B B A A A A A B
MW-2S B B B B A A A A A B
MW-3S B B B B A A A A A B
MW-3D B B B B A A A A A B
MW-4S B B B B A A A A A B
MW-4D B B B B A A A A A B
Notes:
Major Ions:
Metals:
VOCs:
TCA:
TPH:
including: methanol and ethanol
Glycols: including ethylene glycol
COD:
B: sampled and analysed biannually
A: sampled and analysed annually
arsenic, cadmium, chromium, cobalt, copper, lead, iron, nickel, manganese, mercury and zinc
volatile organic compounds
Alcohols & Acetates:
chemical oxygen demand
trichloroacetic acid
total petroleum hydrocarbons (with aliphatic/aromatic speciation)
chloride, phosphate, sulphate, fluoride, calcium, potassium, magnesium, manganese, nitrite, sodium and total alkalinity
Monitoring Well
IEL Parameter Additional Parameter
IEL Wells
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C Table 2
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Updated by: BMC
Checked by: EOHAppendix C - Table 3.1 IEL Groundwater Monitoring Data
MSD BrinnyPage 1 of 18
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95 0.100 0.129 6.0 26.5 1.000 33 21 15 1.2 31 5.6
Dec-95 0.130 0.167 9.4 41.7 1.000 37 14 8 1.6 24 4.2
Aug-96 0.040 0.051 0.5 2.0 10.000 51 19 17 5.2 31 6.1
Dec-96 0.100 0.129 8.8 39.0 0.050 28 18 15 2.7 29 4.5
Apr-97 0.100 0.129 7.2 31.8 0.100 33 20 16 1.4 16 4.2
Oct-97 0.200 0.257 7.6 33.7 0.500 25 13 17 4.2 19 4.0
Mar-98 0.100 0.129 7.6 33.6 0.100 28 13 14 1.8 29 4.9
May-98 0.100 0.129 5.2 23.0 0.100 16 44 13 0.3 51 3.3
Nov-98 0.100 0.129 7.3 32.3 0.100 26 12 14 1.7 28 4.8
Jun-99 0.700 0.900 7.3 32.3 0.500 25 12 17 2.2 17 5.1
Dec-99 0.200 0.257 6.1 27.0 0.200 24 11 14 1.7 33 4.7
Feb-00 2.300 2.957 5.2 22.9 0.200 25 11 15 2.0 20 5.3
Jul-00 0.200 0.257 6.8 29.9 0.160 27 45 14 1.5 28 3.8
Apr-01 0.050 0.064 5.2 23.2 0.160 28 12 16 1.8 32 4.2
Oct-01 0.050 0.064 6.3 28.1 0.160 26 11 14 1.8 28 4.5
Apr-02 5.1 22.4 0.160 27 16 15 1.9 32 5.0
Oct-02 0.080 0.103 5.4 23.8 0.160 26 26 17 1.5 29 3.6
Feb-03 0.200 0.257 6.2 27.3 0.160 28 22 18 1.6 36 4.4
Sep-03 0.070 0.090 6.4 28.2 0.160 27 20 15 1.4 30 3.7
Jan-04 0.060 0.077 7.0 30.8 0.160 25 38 20 1.6 33 5.6
Aug-04 6.1 26.9 0.160 26 12 20 1.3 32 4.2
Mar-05 0.030 0.039 6.1 27.1 0.160 26 13 15 1.6 28 4.3
Dec-05 0.020 0.026 6.1 26.8 0.160 26 12 2 1.4 3 4.0
Feb-06 0.050 0.064 6.5 28.6 0.160 29 13 15 0.5 31 3.1
Jul-06 0.020 0.026 7.8 34.6 <0.16 29 13 <0.1 721.0 <0.1 0.1
Feb-07 <0.02 <0.026 0.5 2.3 <0.16 4 8 14 2.0 28 4.0
Nov-07 0.020 0.026 10.0 44.4 0.160 29 13 17 2.0 32 4.0
May-08 0.020 0.026 7.1 31.4 0.160 28 19 18 1.6 31 5.0
Dec-08 0.020 0.026 7.5 33.2 0.160 27 12 16 1.7 27 4.4
Jun-09 0.020 0.026 8.8 39.0 0.160 30 12 19 2.0 31 5.6
Nov-09 0.020 0.026 7.4 32.9 0.160 29 12 15 1.4 33 4.3
Mar-10 0.020 0.026 6.1 26.9 0.160 26 12 15 1.7 30 4.4
Aug-10 0.020 0.026 7.2 31.9 0.160 27 10 17 1.7 30 4.8
May-11 0.020 0.026 6.7 29.4 0.160 25 11 17 1.7 33 5.2
Sep-11 0.020 0.026 7.1 31.3 0.160 29 12 15 1.6 30 4.6
Mar-12 <0.020 0.026 6.9 30.4 <0.16 24 11 <0.1 16 2.0 30 5.0
May-12
Oct-12
Jul-13 0.122 0.157 6.7 29.8 0.056 23 8 19 7.3 29 7.3
Dec-13 0.014 0.018 7.2 31.7 0.083 23 7 16 2.5 29 5.0
Mar-14 0.008 0.010 4.8 21.3 0.029 22 11 <0.1 16 5.8 28 4.6
Jul-14 0.019 0.024 8.7 38.5 0.011 23 9 <0.1 14 2.3 26 4.1
Mar-15 <0.03 <0.039 5.6 24.6 <0.02 0.030 26 9 <0.3 15 1.9 29 4.9 0.031 76
May-15
Aug-15
Oct-15 <0.03 <0.039 6.1 27.1 <0.02 0.030 30 22 <0.3 15 1.8 41 4.9 0.020 82
May-16 <0.02 <0.032 5.4 23.7 <0.02 0.036 26 8 <0.3 15 2.1 28 4.4 58
Oct-16 <0.03 <0.039 6.4 28.2 <0.02 0.029 27 9 <0.3 16 2.1 29 4.9 68
Apr-17 <0.03 <0.039 5.3 23.2 <0.02 <0.03 26 11 <0.3 15 1.9 29 4.9 84
May-17
Oct-17 <0.03 <0.039 6.5 29.0 <0.02 <0.02 26 12 <0.3 13 1.5 27 4.5 78
Apr-18 <0.03 <0.039 7.2 31.9 <0.02 0.040 27 10 <0.3 14 1.6 29 5.1 70
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
ChloridePhosphate-P
Total
Alkalinity
as CaCO3
PhosphorousMagnesiumCalciumPotassium
Major Ions
Nitrite as
NO2
Sodium FluorideMW-1DNitrate as
NO3
Nitrate-NAmmoniumAmmonia-N Sulphate
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-1D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
285 6.2
287 6.5
273 6.5
278 6.6
322 6.9
311 6.5
324 6.9
284 7.0
301 6.3
268 6.1
282 5.9
264 6.0
260 6.1
271 7.3
283 6.0
287 6.3
284 6.2
265 5.8
272 5.9
291 7.2
297 6.5
303 7.1
312 7.0
297 295 6.7 5.7 11.6 7.65 20.45 9.20
306 6.9
280 285 6.8 5.9 10.8 6.87 21.23 9.46
299 382 6.5 6.3 11.9 7.16 20.94 9.42
315 6.8
287 207 6.6 6.5 11.4 6.79 21.31 9.24
330 290 6.5 5.9 11.2 7.32 20.78 9.24
296 248 6.6 6.1 11.1 6.99 21.11 9.24
288 284 6.6 6.2 10.9 7.74 20.36 9.24
ND <2 <5 288 275 6.6 6.2 11.1 7.26 20.84 9.24
248 6.1 11.1 6.99 21.11 9.24
267 5.7 10.0 7.21 20.89 9.22
0.11 0.9 6.40 21.70 10.40
0.41 18.3 7.90 20.20 9.80
<0.195 ND ND <1 <2 <7 <2 261 7.2 10.9 7.13 20.97 9.26
6.94 21.16
7.03 21.07 9.25
<1 <4 <7 <2 252 6.4 11.3 6.90 21.20 9.26
ND ND <10 <1 <10 <7 242 6.9 11.2 6.93 21.17 9.27
<7 242 7.2 11.4 7.48 20.62 9.20
ND ND <10 <1 ND <7 163 7.0 12.6 6.88 21.22 9.22
7.18 20.92
<7 231 6.6 12.6 6.26 21.85 9.22
ND ND <10 <10 <7 433 5.7 12.4 5.64 22.46 9.22
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Trichloroacetic
Acid
Total Petroleum
Hydrocarbons
Groundwater
Elevation
Depth to
GroundwaterTemperature
Total
DepthpH
Organics and Field Measurements
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-1D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.020 10.800 1.410 0.030
0.010 0.020 0.090 0.020
0.010 4.200 0.040 0.010
0.030 0.040 0.040 0.180
0.030 0.040 0.060 0.060
0.030 0.810 0.040 0.020
0.030 0.040 0.040 0.050
0.030 0.040 0.040 0.160
0.030 0.040 0.040 0.100
0.030 0.040 0.040 0.200
0.002 0.002 0.007 0.086
0.018 0.002 0.003 0.234
0.002 0.100 0.003 0.053
0.002 0.100 0.040 0.057
0.002 0.100 0.002 0.007
0.002 0.100 0.002 0.007
0.003 0.100 0.006 0.073
0.002 0.100 0.003 0.053
0.002 0.100 0.003 0.079
0.002 0.100 0.003 0.110
0.002 0.100 0.002 0.255
0.002 0.100 <0.100 0.049
0.002 0.100 0.022 0.002
0.002 0.300 0.211 0.150
<0.002 0.100 0.148 0.002
<0.002 <0.100 0.003 0.160
0.002 0.100 0.003 0.091
0.001 0.038 0.001 0.003
0.001 0.002 0.001 0.019
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.003 0.002
0.002 0.100 0.007 0.003
0.002 0.100 0.002 0.010
<0.002 <0.002 <0.002 0.005 <0.002 <0.002 <0.002 <0.002 <0.002 <0.1 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 0.003
0.052 0.148 0.032 0.060
<0.003 <0.02 0.002 0.010
0.009 <0.0001 0.0003 0.009 <0.001 <0.0001 <0.001 <0.001 0.005 <0.020 <0.0003 <0.001 <0.00002 <0.0005 0.0006 <0.001 0.001 0.005
<0.005 <0.0001 0.0002 0.009 <0.001 <0.0001 <0.001 <0.001 <0.003 <0.02 <0.0003 <0.001 0.00004 <0.0005 0.0007 <0.001 <0.001 0.004
<0.02 <0.002 <0.0025 0.007 <0.0005 0.016 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.005 <0.001 <0.002 <0.003 <0.005 <0.005 <0.003
<0.02 <0.002 <0.0025 0.006 <0.0005 0.015 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.004 <0.001 <0.002 <0.003 <0.005 <0.005 0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 0.008 <0.020 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 <0.003
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
CobaltChromiumCadmiumBoronBeryllium MercuryManganeseLeadIronCopperBariumArsenicAntimonyAluminium
Metals
ZincTinSilverSeleniumNickel
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mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95 1.700 2.185 2.1 9.3 1.000 90 115 118 8.5 69 4.0
Dec-95 0.130 0.167 0.4 2.0 1.000 119 203 74 9.8 36 2.6
Aug-96 1.300 1.671 0.5 2.0 10.000 67 707 12 4.7 49 6.4
Dec-96 1.400 1.800 3.2 14.2 0.050 68 302 134 12.7 50 3.8
Apr-97 2.000 2.571 0.2 1.0 0.100 78 140 139 10.2 34 4.3
Oct-97 0.200 0.257 5.0 22.2 0.500 65 144 117 29.7 51 3.5
Mar-98 0.100 0.129 1.0 4.4 0.100 400 265 140 23.3 92 5.5
May-98 0.100 0.129 0.8 3.7 0.100 108 126 102 19.5 71 3.0
Nov-98 0.100 0.129 0.5 2.2 0.100 70 149 121 18.3 59 3.8
Jun-99 1.600 2.057 0.5 2.2 0.500 51 122 89 13.3 66 3.0
Dec-99 0.320 0.411 1.1 4.9 0.200 43 96 92 14.4 66 4.0
Feb-00 0.300 0.386 2.2 9.7 0.200 39 72 54 17.0 43 3.6
Jul-00 0.200 0.257 2.6 11.4 0.160 41 139 76 13.0 55 2.3
Apr-01 0.560 0.720 5.8 25.5 0.160 35 102 56 18.0 69 3.0
Oct-01 0.800 1.028 6.3 28.1 0.160 60 64 75 15.0 64 4.0
Apr-02 0.9 4.0 0.160 39 61 49 12.0 54 3.4
Oct-02 1.670 2.147 0.1 0.4 0.160 29 102 66 9.3 46 2.6
Feb-03 1.200 1.543 0.8 3.5 0.160 28 79 48 15.0 62 2.6
Sep-03 0.580 0.746 2.3 10.3 0.160 78 156 92 18.0 60 2.8
Jan-04 2.560 3.291 0.2 0.8 0.160 82 119 93 14.0 60 4.7
Aug-04 0.2 0.8 0.160 71 107 101 13.0 58 3.4
Mar-05 3.100 3.985 1.6 7.0 0.160 42 92 68 9.3 44 2.6
Dec-05 2.680 3.445 0.9 3.9 0.160 43 76 8 1.1 5 0.4
Feb-06 1.730 2.224 2.4 10.6 0.160 49 76 77 7.9 45 1.5
Jul-06 2.450 3.150 0.4 1.6 <0.16 47 87 85 8.0 32 2.0
Feb-07 2.630 3.381 2.0 8.7 <0.16 35 83 63 8.0 37 3.0
Nov-07 2.680 3.445 0.4 1.7 0.160 27 87 60 8.0 37 2.0
May-08 2.780 3.574 0.3 1.2 0.160 68 69 85 9.8 44 3.0
Dec-08 2.330 2.995 0.4 1.9 0.160 33 61 58 9.6 35 2.4
Jun-09 1.450 1.864 0.8 3.3 0.160 29 57 58 9.4 58 2.3
Nov-09 0.680 0.874 1.2 5.2 0.160 22 43 44 15.0 64 2.7
Mar-10 0.200 0.257 0.1 0.4 0.160 21 34 29 9.2 49 2.3
Aug-10 0.830 1.067 0.8 3.5 0.160 23 55 47 8.8 36 2.3
May-11 0.020 0.026 4.2 18.6 0.160 47 50 55 13.0 63 3.0
Sep-11 0.190 0.244 3.7 16.2 0.160 49 67 78 11.0 39 2.0
Mar-12 <0.020 <0.026 15.5 68.7 <0.16 115 128 <0.1 158 15.0 59 3.0
May-12
Oct-12
Jul-13 0.137 0.176 34.7 153.7 0.203 169 94 273 22.0 50 4.5
Dec-13 0.097 0.125 13.8 61.2 0.182 240 89 176 15.2 32 1.3
Mar-14 0.020 0.026 5.8 25.8 0.119 77 55 <0.1 129 23.4 36 1.9
Jul-14 0.111 0.143 9.0 39.8 0.088 87 86 <0.1 118 13.2 38 1.9
Mar-15 <0.03 <0.039 2.0 8.9 <0.02 0.090 45 36 <0.3 62 12.2 49 2.6 0.136 180
May-15
Aug-15
Oct-15 <0.03 <0.039 1.7 7.4 <0.02 0.100 36 38 <0.3 56 13.4 51 2.4 0.148 174
May-16 <0.02 <0.032 4.7 20.9 <0.02 0.075 48 40 <0.3 45 11.4 60 2.8 150
Oct-16 <0.03 <0.039 7.1 31.4 <0.02 0.114 41 76 <0.3 91 16.5 40 1.8 180
Apr-17 <0.03 <0.039 2.0 8.6 <0.02 0.060 47 61 <0.3 50 14.9 53 2.4 156
May-17
Oct-17 <0.03 <0.039 2.8 12.2 <0.02 0.121 38 32.1 <0.3 41 13.8 50 2.5 178
Apr-18 <0.03 <0.039 1.8 7.8 <0.02 0.140 35 25 <0.3 31 10.0 50 2.4 144
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Nitrate-NAmmoniumAmmonia-N Sodium FluorideSulphateChloridePhosphate-P
Total
Alkalinity as
CaCO3
PhosphorousMagnesiumCalciumPotassiumNitrite as NO2MW-2S
Major Ions
Nitrate as
NO3
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-2S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
996 7.1
1078 7.3
898 7.3
1232 7.1
867 7.7
953 7.3
732 7.3
764 7.1
616 7.3
670 7.0
554 6.7
714 6.9
531 6.8
571 7.0
532 6.6
855 6.1
764 6.5
752 6.6
618 6.6
624 7.4
652 7.3
643 7.4
589 7.5
546 529 7.3 6.2 14.9 4.65 20.23 6.32
681 7.6
491 496 7.4 6.3 13.7 4.12 20.76 6.30
475 430 7.4 6.3 12.4 4.37 20.51 6.31
510 7.3
408 306 7.6 7.1 10.1 3.85 21.03 6.27
489 444 7.2 6.2 12.8 4.39 20.49 6.27
621 517 7.2 6.8 12.2 3.51 21.37 6.27
618 610 7.4 7.0 13.0 4.84 20.04 6.27
ND <5 1067 1041 7.3 6.9 12.7 4.00 20.88 6.27
517 6.8 12.2 3.51 21.37 6.27
1443 6.8 15.9 4.02 20.86 6.42
<0.05 ND 3.00 21.88 6.40
0.26 0.5 4.90 19.98 6.40
<0.195 ND ND <1 <2 8 <2 507 6.8 11.5 3.41 21.47 6.28
3.55 21.33
4.16 20.72 6.25
<1 2 9 2.00 480 6.4 13.8 4.12 20.76 6.25
ND ND <10 <1 <10 14 559 7.3 11.9 3.06 21.82 6.24
11 584 7.4 16.6 4.45 20.43 6.40
ND ND <10 <1 ND <7 250 6.9 12.9 5.06 19.82 6.25
4.13 20.75
<7 449 7.0 15.4 2.96 21.92 6.25
ND ND <10 <10 <10 12 398 6.9 12.7 2.60 22.28 6.23
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Total Petroleum
Hydrocarbons
Groundwater
Elevation
Depth to
GroundwaterTemperaturepH Total Depth
Trichloroacetic
Acid
Organics and Field Measurements
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-2S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.020 4.000 1.600
0.010 0.730 0.090 0.020
0.010 6.400 0.080 0.020
0.030 0.040 5.100 0.140
0.030 0.040 5.400 0.030
0.030 12.400 8.540 0.090
0.030 0.040 0.040 0.030
0.030 0.040 1.060 0.160
0.030 0.040 2.000 0.060
0.030 0.040 0.040 0.280
0.002 0.023 0.021 0.050
0.007 0.002 0.573 0.079
0.002 0.100 0.871 0.062
0.002 0.100 0.040 0.082
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 1.223 0.089
0.013 0.100 2.896 0.047
0.013 0.100 1.848 0.841
0.002 0.200 6.008 0.106
0.002 0.200 3.466 0.208
0.002 0.100 1.000 0.063
0.002 0.100 0.438 0.002
0.007 0.600 0.101 0.136
<2 0.100 2.131 0.071
<0.002 <0.100 3.874 0.066
0.002 0.100 3.303 0.061
0.001 0.020 0.002 0.001
0.002 0.005 0.534 0.016
0.002 0.100 0.023 0.002
0.002 0.100 0.349 0.002
0.002 0.100 0.083 0.002
0.002 0.100 0.608 0.002
0.002 0.100 0.111 0.021
0.002 0.100 0.135 0.009
0.007 <0.002 0.004 0.038 <0.002 <0.002 <0.002 <0.002 0.003 <0.1 <0.002 0.114 <0.002 0.002 <0.002 <0.002 0.016
0.082 0.258 0.508 0.089
0.008 0.025 0.008 0.003
0.014 0.0006 0.0023 0.020 <0.001 <0.0001 <0.001 <0.001 0.007 <0.02 <0.0003 <0.001 <0.00002 0.0009 0.0037 <0.001 0.001 0.010
<0.005 0.0006 0.0018 0.025 <0.001 0.038 0.001 0.0010 0.004 0.027 0.0003 <0.001 0.00012 0.0012 0.0020 <0.001 <0.001 0.002
<0.02 <0.002 0.0029 0.024 <0.0005 0.035 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003 <0.005 <0.005 <0.003
<0.02 <0.002 0.0051 0.017 <0.0005 0.040 <0.0005 <0.0015 <0.002 <0.007 0.022 <0.005 <0.002 <0.001 <0.002 <0.003 <0.005 <0.005 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.002 <0.001 <0.002 <0.003
0.0030 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.004 <0.001 <0.002 <0.003
0.0039 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 <0.003
0.0041 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 <0.003
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
SilverSeleniumNickelBariumArsenicAntimonyAluminium CobaltChromiumCadmiumBoronBeryllium
Metals
MercuryManganeseLeadIronCopper ZincTin
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95
Dec-95 0.130 0.167 0.2 1.0 16 28 8 0.4 34 1.0
Aug-96
Dec-96 0.100 0.129 6.5 28.6 0.050 20 34 15 1.0 47 1.4
Apr-97 0.100 0.129 7.9 35.1 0.100 30 24 15 0.1 30 1.7
Oct-97 0.200 0.257 3.5 15.6 0.500 14 17 17 2.8 43 5.2
Mar-98 0.100 0.129 3.8 16.7 0.100 25 17 17 0.2 50 1.7
May-98 0.100 0.129 4.1 18.0 0.100 32 19 21 0.3 53 1.7
Nov-98 0.100 0.129 5.7 25.2 0.100 24 14 14 0.1 55 2.1
Jun-99 Dry
Dec-99 0.290 0.373 4.0 17.7 0.200 31 15 15 0.2 61 2.3
Feb-00 0.020 0.026 4.3 18.9 0.200 45 20 19 0.4 41 2.7
Jul-00 Dry
Apr-01 0.040 0.051 7.4 32.6 0.160 47 18 24 0.1 25 2.3
Oct-01 0.060 0.077 5.6 25.0 0.160 29 15 15 0.3 58 2.9
Apr-02 4.5 19.8 0.160 39 16 16 0.2 62 2.6
Oct-02 0.170 0.219 2.7 11.9 0.160 23 19 13 0.4 53 2.5
Feb-03 0.200 0.257 5.8 25.5 0.160 25 21 23 0.2 74 2.3
Sep-03 0.020 0.026 8.0 35.6 0.160 13 89 12 0.1 53 2.4
Jan-04 0.030 0.039 9.4 41.8 0.160 33 55 20 0.3 65 3.3
Aug-04 10.1 44.5 0.160 21 13 13 0.2 60 3.0
Mar-05 0.020 0.026 7.0 31.0 0.160 19 28 13 0.3 57 2.6
Dec-05 0.030 0.039 11.9 52.8 0.160 24 25 2 0.1 7 0.4
Feb-06 <0.02 <0.026 12.9 57.2 0.160 28 25 18 <0.1 63 2.0
Feb-07 0.020 0.026 21.9 96.9 <0.16 22 20 17 <0.1 60 3.0
Nov-07 0.040 0.051 8.4 37.1 0.160 16 17 13 0.1 60 3.0
May-08 0.020 0.026 8.4 37.3 0.160 28 18 18 0.8 36 3.0
Dec-08 0.020 0.026 5.3 23.4 0.160 37 16 17 0.2 59 2.8
Jun-09 0.020 0.026 7.2 32.0 0.160 38 15 17 0.4 21 2.9
Nov-09 0.020 0.026 2.5 11.2 0.160 47 21 31 0.1 72 2.0
Mar-10 0.020 0.026 5.1 22.8 16.000 29 16 21 0.1 66 2.5
Aug-10 0.080 0.103 5.4 23.8 0.160 18 11 13 0.3 41 2.6
May-11 0.030 0.039 1.7 7.5 0.160 24 12 18 0.1 58 2.3
Sep-11 0.020 0.026 0.3 1.1 0.160 13 8 13 0.1 54 2.3
Mar-12 <0.020 <0.026 1.1 5.0 <0.16 18 10 <0.1 18 <0.1 62 3.0
Mar-15 0.030 0.039 1.2 5.1 <0.02 <0.02 46 12 <0.3 24 2.3 36 2.2 0.015 90
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Nitrate-NAmmoniumAmmonia-N Sodium FluorideSulphateChloridePhosphate-
P
Total
Alkalinity as
CaCO3
PhosphorousMagnesiumCalciumPotassiumNitrite as
NO2
MW-3S
Major Ions
Nitrate as
NO3
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-3S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
329 6.9
357 7.3
311 7.1
342 7.0
363 7.3
391 7.1
384 7.1
408 7.2
429 6.5
372 6.7
405 6.8
353
384 6.5
367 6.3
413 6.5
343 7.5
392 6.8
459 7.4
470 7.2
442 7.4
382 287 7.3 5.6 13.1 5.38 6.30
458 7.6
394 413 7.5 6.5 12.4 4.77 6.28
443 412 7.2 7.0 13.0 5.44 6.30
635 7.1
432 312 7.6 6.7 10.2 4.88 6.21
329 362 6.8 6.6 14.0 5.49 6.21
404 323 7.3 6.3 11.0 4.58 6.21
331 333 7.1 6.7 11.9 5.23 6.21
ND <5 377 356 7.2 6.4 11.4 5.12 6.21
<0.195 ND ND <1 5 <7 3.00 209 7.4 10.2 4.43 22.48 5.92
5.61 21.30
5.67 21.24 5.69
dry <21.22 5.69
dry <21.31 5.60
dry <21.29 5.62
dry <21.29 5.62
dry <21.29 5.62
5.06 21.85 5.54
4.97 21.94 5.54
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Total Petroleum
Hydrocarbons
Groundwater
Elevation
Depth to
GroundwaterTemperaturepH Total Depth
Trichloroacetic
Acid
Organics and Field Measurements
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-3S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.010 0.100 0.090 0.020
0.030 0.050 0.020 0.240
0.030 0.040 0.040 0.050
0.030 16.900 0.500 0.220
0.030 0.040 0.050 0.070
0.030 0.040 0.040 0.210
0.030 0.040 0.050 0.080
0.002 0.024 0.003 0.058
0.005 0.002 0.008 0.089
0.002 0.100 0.040 0.092
0.003 0.100 0.003 0.006
0.002 0.100 0.002 0.002
0.007 0.100 0.003 0.160
0.002 0.100 0.004 0.048
0.015 0.100 0.018 0.637
0.003 0.200 0.007 0.079
0.005 0.200 0.019 0.112
0.002 0.200 0.100 0.036
0.002 0.100 0.008 0.002
0.005 0.700 0.011 0.093
<0.002 <0.100 0.029 0.079
0.003 0.100 0.030 0.132
0.005 0.070 0.008 0.008
0.003 0.005 0.006 0.016
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.005 0.002
0.002 0.100 0.065 0.002
0.002 0.100 0.028 0.004
0.002 0.100 0.024 0.009
0.042 <0.002 <0.002 0.005 <0.002 <0.002 <0.002 <0.002 0.002 <0.1 <0.002 0.451 <0.002 <0.002 <0.002 <0.002 0.016
<0.02 <0.002 <0.0025 0.025 <0.0005 <0.012 <0.0005 <0.0015 <0.002 <0.007 0.026 <0.005 0.004 <0.001 <0.002 <0.003 <0.005 <0.005 0.004
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
SilverSeleniumNickelBariumArsenicAntimonyAluminium CobaltChromiumCadmiumBoronBeryllium
Metals
MercuryManganeseLeadIronCopper ZincTin
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95 0.130 0.167 8.3 36.6 1.000 49 46 23 1.0 28 1.6
Dec-95 0.130 0.167 10.4 45.9 1.000 53 46 15 0.7 22 2.1
Aug-96 0.027 0.035 0.5 2.0 10.000 25 27 20 2.0 23 2.4
Dec-96 0.320 0.411 9.9 43.7 0.050 30 38 18 1.0 20 1.7
Apr-97 0.100 0.129 6.1 26.9 0.100 27 46 21 0.4 16 1.9
Oct-97 0.200 0.257 3.4 15.1 0.500 10 14 12 3.4 8 1.1
Mar-98 0.040 0.051 4.8 21.3 0.100 17 20 15 0.5 22 1.9
May-98 0.300 0.386 4.3 18.9 0.100 16 20 15 0.7 24 1.7
Nov-98 0.600 0.771 3.5 15.5 0.100 13 17 13 0.5 22 1.6
Jun-99 0.500 0.643 4.4 19.5 0.500 16 37 15 0.7 39 2.1
Dec-99 0.200 0.257 4.3 19.0 0.200 16 19 16 0.6 23 1.9
Feb-00 0.300 0.386 4.6 20.2 0.200 21 33 17 0.8 18 2.4
Jul-00 0.200 0.257 4.6 20.2 0.160 16 48 14 1.6 21 0.5
Apr-01 0.150 0.193 5.8 25.5 0.160 20 120 10 0.4 26 1.5
Oct-01 0.170 0.219 5.0 22.0 0.160 17 11 13 0.4 25 2.1
Apr-02 4.0 17.6 0.160 22 17 14 0.5 27 2.1
Oct-02 0.370 0.476 5.2 22.9 0.160 17 102 5 0.1 7 0.6
Feb-03 0.200 0.257 4.4 19.4 0.160 19 37 19 0.5 36 2.1
Sep-03 0.050 0.064 6.1 26.8 0.160 16 30 14 0.6 20 1.9
Jan-04 0.020 0.026 6.2 27.6 0.160 19 49 20 0.3 31 2.4
Aug-04 7.0 30.9 0.160 17 16 17 0.5 27 2.2
Mar-05 0.020 0.026 7.5 33.4 0.160 18 17 14 0.4 28 2.2
Dec-05 0.040 0.051 7.5 33.0 0.160 18 14 1 0.1 3 0.3
Feb-06 0.030 0.039 9.4 41.8 0.160 21 17 15 0.1 30 1.5
Jul-06 <0.02 <0.026 9.2 40.8 <0.16 20 15 18 <0.1 30 2.0
Feb-07 <0.02 <0.026 17.5 77.5 <0.16 16 15 14 <0.1 32 2.0
Nov-07 0.020 0.026 9.8 43.5 0.160 15 14 11 1.0 30 2.0
May-08 0.020 0.026 9.2 40.5 0.160 22 15 20 0.2 72 4.0
Dec-08 0.180 0.231 6.4 28.2 0.160 20 12 14 0.2 31 2.4
Jun-09 0.020 0.026 8.4 37.1 0.060 25 13 17 0.4 21 2.9
Nov-09 0.020 0.026 7.5 33.1 0.160 22 13 12 4.0 38 2.2
Mar-10 0.040 0.051 7.8 34.3 0.160 25 14 16 0.5 33 2.6
Aug-10 0.020 0.026 6.8 30.1 0.160 18 11 13 0.4 31 2.7
May-11 0.020 0.026 5.9 25.9 0.160 17 11 12 0.4 33 2.7
Sep-11 0.020 0.026 7.0 30.8 0.160 17 11 13 0.4 27 2.5
Mar-12 <0.020 <0.026 5.7 25.1 <0.16 14 10 <0.1 16 <0.1 39 3.0
May-12
Oct-12
Jul-13 1.126 1.448 2.7 11.7 0.089 48 35 71 11.2 28 8.2
Dec-13 0.771 0.991 7.4 32.5 0.108 31 23 46 7.4 20 4.1
Mar-14 0.884 1.136 1.2 5.5 0.055 58 35 0.3 59 9.3 23 5.3
Jul-14 0.821 1.055 2.3 10.1 0.044 49 37 0.2 49 4.4 21 4.6
Mar-15 0.840 1.080 3.2 14.2 <0.02 <0.02 44 21 <0.3 45 3.6 22 5.1 0.066 96
May-15
Aug-15
Oct-15 1.090 1.401 0.3 1.2 <0.02 0.060 53 34 <0.3 50 3.9 27 5.6 0.052 108
May-16 0.83 1.069 0.3 1.5 <0.02 0.062 40 33 <0.3 52 3.3 23 5.0 110
Oct-16 0.85 1.093 5.6 25.0 <0.02 0.023 38 25 <0.3 45 3.6 24 5.5 98
Apr-17 0.86 1.106 0.3 1.3 <0.02 <0.03 45 31 <0.3 52 3.6 25 5.7 130
May-17
Oct-17 0.920 1.183 0.6 2.6 <0.02 0.023 47 30 <0.3 43 3.2 25 5.9 112
Apr-18 1.060 1.363 2.0 8.7 <0.02 0.050 44 29 <0.3 44 3.4 28 6.8 112
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Nitrate-NAmmoniumAmmonia-N Sodium FluorideSulphateChloridePhosphate-
P
Total
Alkalinity as
CaCO3
PhosphorousMagnesiumCalciumPotassiumNitrite as
NO2
MW-3D
Major Ions
Nitrate as
NO3
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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MSD BrinnyPage 11 of 18
IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-3D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
327 6.2
267 5.5
143 6.2
218 6.6
201 6.5
204 6.3
256 6.3
220 6.5
254 6.6
198 6.0
251 6.2
226 6.3
239 6.0
203 5.9
241 6.1
220 6.3
245 6.4
220 5.9
246 6.0
244 7.4
277 7.1
267 7.0
274 7.3
263 251 6.6 5.9 12.8 6.00 9.40
304 6.9
264 261 7.0 6.4 11.1 5.52 9.44
290 305 6.6 7.1 12.1 5.97 9.46
351 6.7
286 210 6.7 6.6 11.4 5.75 9.34
288 259 6.8 6.1 12.6 6.43 9.34
256 209 6.7 6.3 11.7 5.48 9.34
254 250 6.7 6.5 12.0 5.92 9.34
ND <5 262 266 7.3 6.6 11.8 5.84 9.34
209 6.3 11.7 5.48 9.34
433 5.9 12.6 6.84 13.92
<0.05 ND 6.40 13.70
0.13 ND ND 7.30 14.00
<0.195 ND ND <1 4 <7 <2 359 6.7 12.7 6.97 19.91 13.48
6.56 20.31
6.60 20.28 13.62
<1 4 11 <2 372 6.4 13.2 6.53 20.34 13.62
ND ND <10 <1 <10 11 417 7.0 12.8 7.18 19.70 13.69
<7 347 7.7 13.2 7.09 19.79 13.78
ND ND <10 <1 ND <7 265 6.8 13.3 6.86 20.02 13.92
6.91 19.97
13 398 6.8 13.9 6.56 20.32 14.03
ND ND <10 <10 <10 17 400 7.0 12.1 6.57 20.31 13.76
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Total Petroleum
Hydrocarbons
Groundwater
Elevation
Depth to
GroundwaterTemperaturepH Total Depth
Trichloroacetic
Acid
Organics and Field Measurements
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
For
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.
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-3D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.010 1.600 0.770 0.040
0.010 0.030 0.130 0.020
0.010 0.930 0.010 0.010
0.030 0.270 1.130 0.140
0.030 0.040 0.040 0.060
0.030 1.160 0.110 0.060
0.030 7.600 0.040 0.030
0.030 0.040 0.070 0.180
0.030 0.040 0.040 0.080
0.030 0.040 0.040 0.340
0.002 0.002 0.072 0.095
0.016 0.002 0.080 0.090
0.002 0.100 0.600 0.036
0.002 0.100 0.050 0.063
0.002 0.100 0.002 0.002
0.002 0.100 0.016 0.002
0.002 0.100 0.032 0.015
0.002 0.100 0.064 0.056
0.002 0.100 0.044 0.090
0.002 0.100 3.458 0.092
0.002 0.100 0.003 0.158
0.002 0.100 0.100 0.021
0.002 0.100 0.002 0.002
0.002 0.300 0.018 0.057
<2 0.100 0.012 <2
<0.002 <0.100 0.012 0.031
0.002 0.100 0.013 0.038
0.002 0.020 0.001 0.004
0.001 0.002 0.001 0.011
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.074 0.004
0.002 0.400 0.077 0.002
0.002 0.100 0.128 0.008
0.002 0.100 0.064 0.011
0.053 <0.002 <0.002 0.008 <0.002 <0.002 <0.002 <0.002 <0.002 <0.1 <0.002 0.267 <0.002 <0.002 <0.002 <0.002 0.016
0.096 0.780 5.835 0.212
<0.003 <0.02 2.949 0.003
<0.005 <0.0001 0.0005 0.007 <0.001 0.0001 <0.001 0.0041 0.006 <0.02 <0.0003 3.781 <0.00002 0.0036 <0.0002 <0.001 0.002 0.010
<0.005 <0.0001 0.0006 0.008 <0.001 <0.0001 <0.001 0.0038 <0.003 <0.02 <0.0003 3.382 0.00004 0.0033 0.0005 <0.001 <0.001 0.005
<0.02 <0.002 <0.0025 0.006 <0.0005 0.023 <0.0005 <0.0015 0.0030 <0.007 <0.02 <0.005 3.256 <0.001 <0.002 <0.003 <0.005 <0.005 0.008
<0.02 <0.002 <0.0025 0.008 <0.0005 0.023 <0.0005 <0.0015 0.0030 <0.007 0.101 <0.005 3.898 <0.001 <0.002 <0.003 <0.005 <0.005 0.007
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 3.302 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 0.003 <0.007 0.02 <0.005 3.195 <0.001 0.002 <0.003
<0.0025 <0.0005 <0.0015 0.003 <0.007 <0.02 <0.005 3.750 <0.001 0.003 <0.003
<0.0025 <0.0005 <0.0015 0.0020 <0.007 <0.020 <0.005 4.110 <0.001 <0.002 <0.003
<0.0025 <0.0005 0.0016 0.0040 <0.007 <0.020 <0.005 4.449 <0.001 0.003 0.004
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
SilverSeleniumNickelBariumArsenicAntimonyAluminium CobaltChromiumCadmiumBoronBeryllium
Metals
MercuryManganeseLeadIronCopper ZincTin
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mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95 0.100 0.129 7.4 32.7 1.000 15 72 10 1.0 42 4.9
Dec-95 0.130 0.167 4.5 20.0 1.000 11 77 7 0.3 29 2.8
Aug-96 0.230 0.296 0.5 2.0 10.000 21 62 12 4.0 50 5.9
Dec-96 0.100 0.129 5.4 23.8 0.050 17 72 13 0.8 42 3.1
Apr-97 0.100 0.129 4.9 21.8 0.100 18 70 11 0.1 23 3.9
Oct-97 0.200 0.257 6.2 27.5 0.500 20 39 21 3.5 39 3.7
Mar-98 0.100 0.129 5.1 22.6 0.100 13 50 11 0.3 45 3.5
May-98 0.100 0.129 5.2 23.0 0.100 16 44 13 0.3 51 3.3
Nov-98 0.100 0.129 5.4 23.9 0.100 17 28 14 0.1 53 3.6
Jun-99 0.500 0.643 6.6 29.2 0.500 24 36 15 0.6 55 5.0
Dec-99 0.200 0.257 7.2 31.9 0.200 32 32 18 0.3 52 5.0
Feb-00 0.200 0.257 6.4 28.2 0.200 17 45 25 0.4 30 3.9
Jul-00 0.200 0.257 5.6 24.6 0.160 14 46 25 0.3 25 2.9
Apr-01 0.040 0.051 10.7 47.5 0.160 13 135 14 0.1 43 2.4
Oct-01 0.080 0.103 9.3 41.3 0.160 39 22 32 0.4 34 4.5
Apr-02 10.8 48.0 0.160 42 45 61 0.3 27 2.1
Oct-02 0.080 0.103 15.8 70.0 0.160 51 45 120 0.3 5 0.5
Feb-03 0.200 0.257 12.3 54.6 0.160 49 42 154 1.7 4 0.3
Sep-03 0.020 0.026 13.1 58.2 0.160 45 44 100 1.0 4 0.4
Jan-04 0.030 0.039 16.6 73.5 0.160 57 83 168 1.8 3 0.3
Aug-04 12.8 56.8 0.160 44 30 138 0.8 3 0.3
Mar-05 0.020 0.026 15.0 66.4 0.160 46 32 99 1.0 3 0.2
Dec-05 0.020 0.026 9.9 44.0 0.160 35 25 9 0.3 1 0.1
Feb-06 0.040 0.051 11.9 52.8 0.160 44 25 81 0.8 7 0.4
Jul-06 <0.02 <0.026 16.0 70.8 <0.16 44 26 93 2.0 5 1.0
Feb-07 <0.02 <0.026 27.9 123.5 <0.16 39 26 82 2.0 14 <2
Nov-07 0.020 0.026 10.8 47.9 0.160 35 24 58 2.0 8 1.0
May-08 0.020 0.026 11.1 49.3 0.160 38 26 79 2.7 13 2.0
Dec-08 0.020 0.026 10.8 47.8 0.160 37 27 68 2.4 15 2.1
Jun-09 0.020 0.026 10.3 45.8 0.160 41 29 80 3.5 20 2.4
Nov-09 0.020 0.026 11.4 50.5 0.160 39 32 57 2.8 24 2.3
Mar-10 0.020 0.026 7.1 31.3 0.160 17 32 50 1.8 18 1.8
Aug-10 0.020 0.026 8.1 35.8 0.160 21 29 50 2.1 18 2.1
May-11 0.020 0.026 9.8 43.5 0.160 41 21 67 2.3 21 2.6
Sep-11 0.020 0.026 9.5 42.0 0.160 48 21 7 2.9 21 2.5
Mar-12 <0.020 <0.026 11.1 49.2 <0.16 53 27 <0.1 57 3.0 32 4.0
May-12
Oct-12
Jul-13 0.128 0.165 7.0 30.9 0.086 18 22 59 5.2 18 4.5
Dec-13 0.016 0.021 0.3 1.2 0.435 11 21 40 4.2 21 2.4
Mar-14 0.016 0.021 6.6 29.0 0.042 8 21 <0.1 31 4.8 29 3.0
Jul-14 0.016 0.021 7.7 34.2 0.027 8 22 <0.1 37 2.5 23 2.9
Mar-15 0.050 0.064 5.4 24.0 <0.02 <0.02 13 19 <0.3 29 2.1 37 5.3 0.04 126
May-15
Aug-15
Oct-15 <0.03 <0.039 3.5 15.5 <0.02 0.040 26.0 22.5 <0.3 21 2.2 48 6.5 0.04 128
May-16 <0.025 <0.032 4.5 19.7 <0.02 0.033 15.1 27.2 <0.3 9 1.6 43 6.3 88
Oct-16 <0.03 <0.039 4.5 19.8 <0.02 0.062 15.1 37.1 <0.3 11 1.8 47 6.6 108
Apr-17 0.03 0.039 3.3 14.7 <0.02 <0.03 9.8 22.7 <0.3 8 1.6 36 5.0 124
May-17
Oct-17 <0.03 <0.039 3.5 15.5 <0.02 <0.02 16.0 16.5 <0.3 9 1.6 35 5.0 100
Apr-18 <0.03 <0.039 3.8 16.7 <0.02 <0.03 12.2 21.0 <0.3 7 1.5 38 5.2 100
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Nitrite as
NO2Sodium FluorideSulphateChloride
Phosphate-
P
Total
Alkalinity as
CaCO3
PhosphorousMagnesiumCalciumPotassiumMW-4S
Major Ions
Nitrate as
NO3Nitrate-NAmmoniumAmmonia-N
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-4S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
260 6.1
331 6.6
329 6.5
310 6.8
322 6.9
388 6.9
368 7.2
371 7.0
356 7.3
267 6.8
319 6.4
372 6.5
480 6.6
586 6.8
507 6.6
526 7.3
601 6.4
460 7.0
488 6.6
423 7.8
424 7.7
465 7.7
468 7.8
379 332 7.4 6.3 13.2 6.29 20.69 7.65
456 8.0
385 411 7.5 6.6 14.0 5.70 21.28 7.78
433 335 7.3 6.8 14.9 6.11 20.87 7.70
474 7.3
337 226 7.8 7.4 12.4 5.82 21.16 7.82
408 351 7.4 7.0 13.7 6.37 20.61 7.82
444 366 7.7 7.0 12.3 6.10 20.88 7.82
475 477 7.5 7.2 12.6 6.52 20.46 7.82
ND <5 479 459 7.4 7.1 12.4 6.23 20.75 7.82
366 7.0 12.3 6.10 20.88 7.82
409 6.6 12.5 6.24 20.74 7.97
<0.05 ND 5.20 21.78 7.90
<0.05 ND 6.70 20.28 8.50
<0.195 ND ND <1 <2 <7 <2 372 7.1 11.7 5.88 21.10 7.78
5.91 21.07
5.97 21.01 7.79
<1 <4 <7 <2 318 6.5 13.1 5.88 21.10 7.78
ND ND <10 <1 <10 <7 308 7.3 12.1 5.76 21.22 7.79
<7 365 7.1 13.1 3.30 21.31 7.87
ND ND <10 <1 ND <7 165 6.9 12.5 5.87 21.11 7.85
6.01 20.97
<7 232 6.5 13.1 5.55 21.42 7.78
ND ND <10 <10 <10 <7 241 6.5 11.8 5.20 21.78 7.78
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Trichloroacetic
Acid
Total Petroleum
HydrocarbonspH
Organics and Field Measurements
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs Temperature
Depth to
Groundwater
Groundwater
ElevationTotal Depth
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IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Apr-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-4S
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.050 13.600 2.100 0.010
0.010 0.020 0.090 0.020
0.010 4.100 0.040 0.010
0.030 0.040 0.020 0.280
0.030 0.040 0.040 0.050
0.030 2.140 0.050 0.450
0.030 0.040 0.040 0.020
0.030 0.040 0.040 0.160
0.030 0.040 0.050 0.070
0.030 0.040 0.040 0.250
0.002 0.010 0.005 0.062
0.004 0.002 0.008 0.150
0.002 0.100 0.006 0.068
0.002 0.100 0.040 0.068
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.030
0.002 0.100 0.002 0.053
0.007 0.100 0.002 0.948
0.002 0.100 3.000 0.084
0.003 0.100 0.002 0.066
0.002 0.100 <0.100 0.039
0.002 0.100 0.002 0.002
0.002 0.100 0.011 0.079
<2 <0.100 0.004 0.017
0.002 <0.100 <0.002 0.048
0.003 0.100 0.002 0.066
0.009 0.200 0.004 0.022
0.001 0.003 0.001 0.013
0.002 0.100 0.002 0.002
0.002 0.100 0.002 0.002
0.002 0.100 0.003 0.002
0.002 0.100 0.003 0.002
0.002 0.100 0.016 0.003
0.002 0.100 0.008 0.011
0.044 <0.002 <0.002 0.012 <0.002 <0.002 <0.002 <0.002 <0.002 <0.1 <0.002 0.005 <0.002 <0.002 <0.002 <0.002 0.018
0.063 0.227 0.050 0.082
<0.003 0.023 <0.001 4.200
0.006 <0.0001 0.0004 0.003 <0.001 0.0001 <0.001 <0.001 0.004 <0.02 <0.0003 <0.001 <0.00002 <0.0005 0.0028 <0.001 0.001 0.018
0.006 <0.0001 0.0003 0.004 <0.001 <0.0001 <0.001 <0.002 <0.003 <0.02 <0.0003 0.001 0.00003 <0.0005 0.0023 <0.001 <0.001 0.003
<0.02 <0.002 <0.0025 0.004 <0.0005 0.022 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003 <0.005 <0.005 0.007
<0.02 <0.002 <0.0025 0.003 <0.0005 0.020 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003 <0.005 <0.005 0.007
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 0.011
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 <0.002 <0.001 <0.002 0.006
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 0.004
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 0.005
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Tin ZincLead Manganese Mercury Nickel SeleniumCadmium Chromium Cobalt Copper Iron SilverAntimony Arsenic Barium Beryllium Boron
Metals
Aluminium
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mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
IGV 0.12 0.15 5.6 25 0.1 0.03 30 200 1 150 5 200 50 - NAC
DWS 0.23 0.3 11.3 50 0.5 - 250 250 1.5 200 - - - - -
GTV 0.175 0.225 8.5 37.5 0.375 0.035 187.5 187.5 - - - - - - -
Date
Jul-95 0.220 0.283 7.6 33.8 1.000 27 33 16 1.0 20 1.6
Dec-95 0.130 0.167 9.2 40.9 1.000 39 36 12 0.3 19 2.2
Aug-96 0.025 0.032 0.5 2.0 10.000 21 31 16 2.0 23 1.8
Dec-96 0.100 0.129 5.8 25.7 0.050 21 22 16 0.6 26 1.6
Apr-97 0.100 0.129 9.3 41.3 0.100 44 30 16 0.6 17 1.8
Oct-97 0.200 0.257 8.8 39.1 0.500 39 27 19 2.1 23 2.0
Mar-98 0.100 0.129 4.5 19.9 0.100 44 32 17 0.5 33 2.3
May-98 0.100 0.129 7.9 34.8 0.100 66 41 25 0.6 48 2.6
Nov-98 0.100 0.129 4.6 20.2 0.100 16 49 32 0.2 28 1.3
Jun-99 0.900 1.157 6.2 27.5 0.500 44 48 31 0.7 42 1.9
Dec-99 0.200 0.257 5.8 25.7 0.200 17 27 24 0.0 19 0.8
Feb-00 0.200 0.257 5.7 25.1 0.200 17 41 24 0.3 13 1.0
Jul-00 0.200 0.257 5.9 26.0 0.160 24 53 20 0.4 19 1.3
Jun-01 7.5 33.4 0.160 22 30 23 0.3 16 0.7
Oct-01 0.060 0.077 6.1 26.8 0.160 21 27 26 0.3 13 0.7
Apr-02 5.9 26.0 0.160 18 24 26 0.2 11 0.4
Oct-02 0.070 0.090 6.7 29.5 0.160 17 26 25 0.1 6 0.3
Feb-03 0.300 0.386 8.4 37.4 0.160 49 47 52 0.5 27 1.4
Sep-03 0.020 0.026 10.2 45.1 0.160 49 44 48 0.5 16 0.9
Jan-04 0.020 0.026 7.4 32.9 0.160 42 68 48 0.1 16 0.8
Aug-04 12.1 53.7 0.160 49 40 57 0.4 14 1.0
Mar-05 0.040 0.051 13.1 58.1 0.160 47 43 58 0.5 12 0.8
Dec-05 0.150 0.193 12.9 57.2 0.160 49 39 10 0.6 7 0.6
Feb-06 0.140 0.180 14.9 66.0 0.160 52 44 79 0.2 8 0.3
Jul-06 0.130 0.167 12.0 53.2 <0.16 48 36 71 1.0 8 1.0
Feb-07 0.120 0.154 5.2 22.8 2.840 22 23 57 1.0 14 <2
Nov-07 0.080 0.103 11.2 49.6 0.160 31 27 29 1.0 16 3.0
May-08 0.120 0.154 11.5 51.0 0.160 36 28 49 0.9 14 2.0
Dec-08 0.120 0.154 10.0 44.1 0.160 35 24 39 0.5 15 2.6
Jun-09 0.040 0.051 10.6 46.9 0.160 33 24 36 0.6 36 3.4
Nov-09 0.020 0.026 10.9 48.1 0.160 30 18 14 0.8 28 4.2
Mar-10 0.140 0.180 10.0 44.4 0.160 59 31 65 0.6 9 1.2
Aug-10 0.060 0.077 9.3 41.3 0.160 32 19 34 0.6 16 3.1
May-11 0.220 0.283 10.3 45.4 0.160 46 27 51 0.6 14 1.8
Sep-11 0.180 0.231 8.2 36.3 0.160 34 23 37 0.6 14 2.4
Mar-12 0.240 0.309 10.2 45.2 <0.16 31 22 <0.1 38 1.0 16 3.0
May-12
Oct-12
Jul-13 0.355 0.456 10.6 46.7 0.069 31 17 44 2.9 15 5.3
Dec-13 0.169 0.217 10.3 45.6 0.083 28 18 36 3.8 15 2.7
Mar-14 0.136 0.175 8.2 36.3 0.034 39 20 <0.1 37 4.0 17 0.003
Jul-14 0.189 0.243 10.2 45.2 0.030 43 21 <0.1 46 1.2 10 1.6
Mar-15 0.240 0.309 6.0 26.4 <0.02 0.040 31 19 <0.3 39 0.6 13 2.4 0.055 48
May-15
Aug-15
Oct-15 0.070 0.090 7.7 34.3 <0.02 0.050 28 18 <0.3 23 0.8 22 4.4 0.044 56
May-16 0.160 0.21 7.4 32.7 0.04 0.055 30 20 <0.3 42 0.6 8 1.2 42
Oct-16 0.03 0.04 7.7 34.0 <0.02 0.026 29 17 <0.3 19 1.0 23 5.3 48
Apr-17 0.12 0.15 6.8 30.2 0.03 <0.03 29 19 <0.3 27 0.9 18 3.7 64
May-17
Oct-17 <0.03 <0.039 7.5 33.3 <0.02 <0.02 26 17.1 <0.3 14 0.8 22 4.8 36
Apr-18 0.050 0.064 7.3 32.4 <0.02 <0.03 35 17 <0.3 30 0.7 16 3.4 48
Notes: Blank cell indicates no data
XXXXX Indicates result above interim guideline value (IGV) - indicates no screening threshold
XXXXX Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
XXXXX Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Ammonia-N PotassiumSodium FluorideSulphateChloridePhosphate-
P
Total
Alkalinity as
CaCO3
PhosphorousMagnesiumMW-4D
Major Ions
Nitrate as
NO3Nitrate-NAmmonium
Nitrite as
NO2Calcium
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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EPA Export 20-11-2018:04:05:09
Updated by: BMC
Checked by: EOHAppendix C - Table 3.6 IEL Groundwater Monitoring Data
MSD BrinnyPage 17 of 18
IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Jun-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-4D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Lab Field Lab Field oC m bct m OD m bct
various various various - - 10 - - NAC 6.5 9.5 25 - - -
0.1 various various - - - - - - 6.5 9.5 - - - -
0.075 various various - - 10 - - - 800 1875 - - - - - -
252 5.5
303 6.0
286 5.8
212 6.0
414 7.7
308 6.1
354 5.9
237 6.2
237 5.9
247 5.6
234 5.5
198 5.6
198 5.3
350 5.4
359 6.1
324 5.8
361 5.3
391 5.4
422 5.9
429 6.2
385 7.0
398 7.0
292 294 6.2 5.6 12.7 6.55 20.62 11.20
342 6.6
280 303 6.4 5.6 12.4 6.10 21.07 11.25
299 1278 6.4 7.0 14.3 6.44 20.73 11.28
288 6.4
402 281 6.8 6.3 12.4 6.16 21.01 11.04
314 292 6.3 5.7 12.9 6.44 20.73 11.04
354 295 6.2 5.8 12.6 6.32 20.85 11.04
301 310 6.4 6.0 12.2 6.68 20.49 11.04
ND <2 <5 309 306 6.3 6.0 12.2 6.41 20.76 11.04
295 5.8 12.6 6.32 20.85 11.04
278 5.5 12.0 6.38 20.79 11.05
<0.05 2 5.80 21.37 11.30
<0.05 ND 7.60 19.57 11.60
<0.195 ND ND <1 <2 <7 2 297 6.2 12.1 6.25 20.92 11.00
6.15 21.02
6.24 20.93 11.00
<1 3 <7 <2 235 5.8 12.5 6.16 21.01 11.00
ND ND <10 <1 <10 9 273 6.1 12.5 6.27 20.89 11.00
<7 231 7.1 12.5 6.66 20.51 11.26
ND ND <10 <1 ND <7 166 6.9 13.6 6.21 20.96 11.04
6.30 20.87
13 220 6.3 12.4 5.86 21.31 11.07
ND ND <10 <10 <10 12 260 6.3 12.2 5.56 21.61 11.07
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
Trichloroacetic
AcidTotal Depth
Groundwater
Elevation
Depth to
Groundwater
Total Petroleum
Hydrocarbons
Organics and Field Measurements
TemperaturepH
2500
Electrical Conductivity
mS/cm
1000
Total
Organic
Carbon
CODBODEthylene
Glycol
Alcohols &
AcetatesVOCsPAHs
AECOM Ireland Limited Z:\UKI\IEORK1\Jobs\PR-253914_MSD_Brinny_IEL_Review_2018\400_Technical\430_TechnicalArea_X\Draft Report\Appendix C IEL Monitoring Data R1 2018
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EPA Export 20-11-2018:04:05:09
Updated by: BMC
Checked by: EOHAppendix C - Table 3.6 IEL Groundwater Monitoring Data
MSD BrinnyPage 18 of 18
IGV
DWS
GTV
Date
Jul-95
Dec-95
Aug-96
Dec-96
Apr-97
Oct-97
Mar-98
May-98
Nov-98
Jun-99
Dec-99
Feb-00
Jul-00
Jun-01
Oct-01
Apr-02
Oct-02
Feb-03
Sep-03
Jan-04
Aug-04
Mar-05
Dec-05
Feb-06
Jul-06
Feb-07
Nov-07
May-08
Dec-08
Jun-09
Nov-09
Mar-10
Aug-10
May-11
Sep-11
Mar-12
May-12
Oct-12
Jul-13
Dec-13
Mar-14
Jul-14
Mar-15
May-15
Aug-15
Oct-15
May-16
Oct-16
Apr-17
May-17
Oct-17
Apr-18
Notes:
XXXXX
XXXXX
XXXXX
MW-4D
mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L
0.2 - 0.01 0.1 - 1 0.005 0.03 - 0.03 0.2 0.01 0.05 0.001 0.02 - - - 0.1
0.2 0.005 0.01 - - 1 0.005 0.05 - 2 0.2 0.01 0.05 0.001 0.02 0.01 - - -
0.15 - 0.0075 - - - - 0.0375 - 1.5 - 0.0075 - 0.00075 - - - - 0.075
0.010 2.950 1.600 0.030
0.010 0.020 0.150 0.020
0.010 0.010 0.040 0.010
0.030 0.040 0.050 0.160
0.030 0.040 0.100 0.140
0.030 2.200 0.110 0.120
0.030 0.040 0.040 0.020
0.030 0.040 0.070 0.190
0.030 0.040 0.040 0.080
0.030 0.040 0.060 0.170
0.002 0.012 0.015 0.064
0.007 0.002 0.009 0.096
0.002 0.100 0.031 0.039
0.003 0.100 0.025 0.013
0.002 0.100 0.006 0.002
0.002 0.100 0.002 0.071
0.006 0.100 0.012 0.032
0.002 0.100 0.076 0.045
0.004 0.100 0.068 0.123
0.002 0.100 0.060 0.107
0.002 0.100 0.050 0.150
0.002 0.100 0.100 0.055
0.002 0.100 0.048 0.002
0.002 0.100 0.217 0.099
<0.002 0.100 0.199 <0.002
<0.002 <0.01 0.063 0.083
0.002 0.100 0.030 0.057
0.001 0.030 0.044 0.004
0.001 0.010 0.032 0.017
0.002 0.100 0.015 0.002
0.002 0.100 0.008 0.004
0.003 0.100 0.032 0.012
0.002 0.100 0.014 0.002
0.002 0.100 0.037 0.014
0.002 0.100 0.002 0.043
0.029 <0.002 <0.002 0.029 <0.002 <0.002 <0.002 0.003 <0.002 <0.1 <0.002 0.025 <0.002 <0.002 <0.002 <0.002 0.043
0.071 0.209 0.064 0.082
<0.003 <0.020 0.025 0.007
0.006 <0.0001 0.0002 0.025 <0.001 0.0003 <0.001 0.002 0.004 <0.020 0.0003 0.021 0.00002 0.0005 0.0003 <0.001 0.001 0.010
0.006 <0.0001 <0.0003 0.332 <0.001 <0.0001 <0.001 0.002 <0.003 <0.020 <0.0003 0.019 0.00006 <0.0005 0.0008 <0.001 <0.001 0.013
<0.02 <0.002 <0.0025 0.021 <0.0005 0.013 <0.0005 <0.0015 0.002 <0.007 <0.020 <0.005 0.019 <0.001 <0.002 <0.003 <0.005 <0.005 0.010
<0.02 <0.002 0.0026 0.018 <0.0005 <0.012 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.007 <0.001 <0.002 <0.003 <0.005 <0.005 0.009
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.018 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.003 <0.001 <0.002 <0.003
0.0028 <0.0005 <0.0015 <0.002 <0.007 <0.02 <0.005 0.009 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 <0.002 <0.001 <0.002 <0.003
<0.0025 <0.0005 <0.0015 <0.002 <0.007 <0.020 <0.005 0.009 <0.001 <0.002 0.004
Blank cell indicates no data
Indicates result above interim guideline value (IGV) - indicates no screening threshold
Indicates result above groundwater threshold value (GTV) < indicates result below reporting limit
Indicates result above IGV and GTV ND indicates nothing detected in suite NAC indicates no abnormal change
ZincTinSilverSeleniumNickelMercuryManganeseLeadIronCopperCobaltChromiumAntimonyAluminium
Metals
CadmiumBoronBerylliumBariumArsenic
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Attachment 4.8.3 Baseline ReportProject reference: PR-25391
Project number: 60563354Application ID LA001617
Prepared for: MSD Ireland (Brinny) AECOM22
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