ATT8TO · Lab Hame_ Head CompuChem_____ EPA Casel/fef? SflS &SVl-ConpuChem* A, SURROGATE SPIKE...
87
ATT8TO
Transcript of ATT8TO · Lab Hame_ Head CompuChem_____ EPA Casel/fef? SflS &SVl-ConpuChem* A, SURROGATE SPIKE...
ATT8TO
i, ENVIRONMENTAL PROTECTION AKNCT-CLP Swlt Mmignmt Otllct„•. tax 818, AlMinorll, VA 22313 - 703/557-2490
ORGANIC: WALTSis DATA SHEET - fig* iUDoritory *•» Hud ConpuCtiwn Cm NwwrUb S-Pli ID No. <<f(oO QC topcrt Na.
Multiply Deletion Units by 1 j/J"1 "'d'''!] ____(Qwck BOH (or Approprllti Foetcr)
ACID COMPOUtOS BASE/NEUTRAL COMPOUNDS
JW CAM uj/l PJI CAM ug/l
I21A)(22A)<24A)I3IA)(MA)IJ7A)(S8AI(99A)1 60A)I64A)(6M)
M-Ot-259-50-7»5-57-8I22-B3-2105-67-9B8-75-5100-02-7JI-M-9534-52-187-36-5I04-9J-2
2i4i6-trlcnloropninolp-cnioroii-criiol2-cnloropMnol2,4-dlctiloropntnol2i4-4lMtnylpninol2-olTroptitnol4-tiltropninol2.4-dlnltropninol4,6-dlnltro-2iwTnylpntnolptnticnloropninolpninol
20U40U20U20U20U40UZOOU100U40U40U20U
(Non-Priority Pollutint Mzirdout Sutntincii)
Mniolc t o l a 2 0 0 1 )95-48-7 2-mtHylpntnol_________200108-39-4 4-mttnylpmnol 21X1
___95-9S4 2,4,?-trlchloropninol_____200U
BASE-NEUTRAL COMPOUNQS
( IB) 63-32-9 ictfl«pnttnnt__________20U( 5fl) 92-87-} Mnildlfi»___________KWI 681 120-82-1 I,2i4-trlcnlorob«n»n»_____200I 96) 118-74-1 lnmcniofOMnlini ______200II2B) 67-72-1 nmienlorottmni________JOU1186) 111-44-4 bli!2-<!liloro«tnylHtn«r 20UI20B) 91-58-7 2-CHIorcmiptlTllimil______20UI25B) 95-50-1 1,2-OlcftlM-QMnitm______200(26B) 541-73-1 l.j-OlcliloroMnint 20U (Non-Priority Pollutint Hiiiraoui Subitancti)I27B) IQft-46-7 l,4-<llcniorol)initii»______20U12861 91-94-1 a.V-OlcnioroMnilOlm____40U 62-53-3 inlllni_____________20UI35BI I2I-H-2 2i4-<llnltrotolmn>_______40U 100-51-6 Ptntyl «I cow I <OUlitfl) 606-20-2 2.6-dlnltrotolmm_______4W 106-47-e 4-cHloroinllln«________10011
1,2-tflprwnylnyiirKlnt I38-M-9 Q-|l)«n»o(urin ZOU13761 122-66-7 111 tioBOTi»n»)________JOU 91-57-6 2-mtliyln«PHtntliii»______JOU139BI 206-44-0 (luorintlitni__________20U M-74-4 2-nltro«nlllnt 200U1406) 7005-72-3 4-cnloropn«nyl pntnyHtlitr 200 99-09-2 3-<iltrMnllln«________2.00UI4IBI 101-}}-? 4-branopntflyl pMnyl ttntr 2PU i___100-01-6 4-flltrcnnlllni________200U
f\ • r •**«>•*I U u , J (
• OD
^ ^ ir ~''
I (tool* MM«r
OMMICi MW.ni! OATA KH • Fig* 2ugoTD
Utwitory mm ** QmvQm _____m_m CutLK> tallll 10 Ms. IH(aQ US *»»rt No. X||?
!>••<;<(« _ _ _/ sBtttetlw Milts ly I 0or lOflorfy a
(ChMh km tor Approirliti Factor)
fOiATliK
JJJ, CAM «g/l
7VI 107-02-1 tcroUIn_________JOOUIV) 107-13-1 14V) 7MM 1IV) 9t-23-9 1TV) tO»-*0-7 1
110V) 107-06-ZI1IV) 7I>9M113V) 75-34-3CI4V) 7VOO-5( 9V) 7>34-9
icrylcnltrll* 1000Mnn* 90jrpon titrtenlorlli 90•filoroewttM 90.MIctilorottfttM 90.1.l»trlchloroitMM JO.MIcnlorottMflt 90.1,2-trleMororrnwi Jo,1.2,2-lrfricnioroilMM 90
1 Ml 75-00-3 tiiloroftMm 90imi 110-7VI 2-cMorortliyl»l>iyl atfttr 90(23V) «7-*6-3 cMofOfom ~5U'(2tVI 79-3M I.MIcnlorortlxi)* ~50130V) 19* 0-9 l. trani lchlcrortr i 90C32VI 7S-I7-5 l.2 ltMBropfOHH« 90
90imi»oi-o5
IOI-H-3 ttlWNtrlcMoro>tti»n<_____90
(MV) 7VOI-4 »|nyl cMorlt* 9>l
f Fulluttnt HinrtM Mttuwx)
•7H4-1 MttiM________1000
79-19 1 HTtOBllHlHIti018119
9II-7IH Hmm*» 1000Ipl-IO-l ^ ntjyl'J'jyMnjcoi lOpu100-42-9 ttvrtn* ~~ 90I0»0>4 »|nyl »t*tit» 100IMT-t P«tlOM 90
, 30
OR8ANICS ANALVSIS DATA SHEET - Pljt 3 ________LM LEVEL LIQUID
UlWitcry Nm Hwd CtnpuCnm dsi NwtwU6 SHDII ID Ha. MO 93 Hxwrt to. /A?-!?
Multiply 0»t»ctlon llmlti by I g'or lo[]orQ _lor Approprliti Factor )~
PESTICIDES
PM CAM ug/l
(39P1 309-00-2 HHrln_________0.10
DIOXIN5 uj/l
2,3,7,ft-titnchloroillt>mio-11286) 1746-01-6 p-dloxln_______0.0020
01812°
ec SCREEN DATA SHEET
Laboratory Name Head CompuChemCase abtr IteM <>flS -fek
SampleID Number. Frtctlon
VOAB/N/APesticidesDloxln
VOAB/N/APesticidesD1ox1n
GCDetectable*
Medium Level
D«teof
Screen
VOAB/N/APesticidesDloxln
VOAB/N/APesticidesD1ox1n
VOAB/N/A 'PesticidesDloxln
GC/MSAnalysis*'L
VOAB/N/APesticidesDloxln
VOAB/N/APesticidesD1ox1n
•Answer Yes or No.**lnd1cate"M" for medium level GC/MS analysis.Indicate"!." for low level GC/MS analysis.
-'v ., 01;018121
90
ORGAN!CS ANALYSIS DATA SHEET - Page 4
Lab Hame_ Head CompuChem_______ EPA Casel/fef? SflS &SVl-ConpuChem*
A, SURROGATE SPIKE RESULTS
COMPOUND
de-Toluene
d*-l,Z-D1chloroethane
FractionVOA
VOA
ConcentrationTotal (ug/< )
v.yff3. 92-
(Surrogates onlyspue
Added (ug/t)
V
V
iRecovery
//A
92
COMPOUND
2-F1uoropheno1
Pentafluorophenol
dg-N1trobenzene
2-FluoroDlphenyl
2-Fluoroan1l1ne
Decaf luoroblphenyl
Fraction
FSCC
FSCC
FSCC,
FSCC
FSCC
FSCC
ConcentrationTotal (ug//)
c25
O
W
70
5?
52
[Surrogates only)SpUe.
Added &Q/f)
/OS
/£0
fC'O
fOO
/e>_i
/Otf
iRecovery
£60
W
70
<&62-
COMPOUND
1,2,3,4-TCDD
Fraction
TCDD
ConcentrationTotal (ug#)
cS?.-S
(Surrogates onl>)Spike.
Addedfuaj' )
P??
*Recovery
to
bisifi*so
LIST OF COMMONLY USED FOOTNOTES FOR EPA
II Indistinguishable Ilowers.I .Presence Indicated by extracted Ion current profile; definitive spectra not
obtainable due to Interference,Q Quantltated from secondary Ion,
Cl Concentration estimated; Interferences present with primary quantltatlonIons.
D Sample analysis using a ____dilution.SE Sample extract could not be concentrated to 1.0 ml, thus the detection
limits are higher than normal.DL Detection Units are adjosted to show change 1n sample quantity processed.
The surrogate recoveries are not available.SR Surrogate recoveries are not available because It was necessary to dilute
trie extractt based on GC screening results.SC Suspected laboratory contaminant.LT Less than the specified detection Unit but greater than one half of the
detection limit (present but BDL).EV Estimated value. This footnote 1s used when estimating a concentration
for a tentatively Identified compound.H Volatile vial received with headspace.
SV Amount corrected for sample volume,DC Compound calculated from a c___ dilution,CR Compound calculated using total R1C area. All secondary Ions saturated,PC Pesticide or PCB confirmed by GC/MS.PN Pesticide or PCB cannot be confirmed by GC/MS.U Compound analyzed for but not detected. The number 1s the minimum detection
limit.BDL Below Detection Limit
DATA REPORTING QUALIFIERS
The attached list of footnotes Is used by Head CompuChem to qualify dataresults. This 11st Incorporates and/or supersedes footnotes suggested InEPA contracts. Explicit definitions of the footnotes are also provided.As specified contractually-tmr-frrM enfr'ted by Ciiluiu un juiniul, notationsor changes to data values are Initialled by the CompuChem employee makingand/or approving the change,To eliminate any confusion between footnotes and Initials, the followingprocedure 1s employed:
1. Footnotes are Indicated to the left of the data value,2, Initials are Indicated to the right'of the data value.3. Initials are circled,
For example:ug/1 —.
(87V) 79-01-6 Trkloroethylene .......... "9-, ft' «yr_r£lFootnote value Initial
The reported value of 1000 ug/1 trkhloroetnylene has been calculated from asecondary 1on (as Indicated by Footnote Q). This notation has been Initialledby a CompuChem employee with Initials KH.
01812430
QUALITY ASSURANCE NOTICE
This sample has low recovery for pentafluorophenol, The recoveryof the surrogate pentafluorophenol periodically dips below laboratorycontrol limits. This phenomenon 1s under Investigation, Since theother add surrogate exhibits normal recovery, the sample results havebeen reported without any additional analyses.
7Quality Assurance Analyi
," r •• - /• '.t w -i»*
0-18125
W8AHICS ANALYSIS DATA SUET . rtg* 4
UB H»|| MM COHPUCHPtCC RtFOIT Ml _______
I. TIKTATIVUt IDtKTIFIED COMFOUNDS
12
34
50
7a910
11
12
1314151617
ia19
202122
25
24
25
2627
,28
2930
CASf COMPOUND WWC
y/ou^FRACTION
f MAXIMUM SCORE ATTAINEDMASS MATCHING ROUTINES
(SrTCIfTI
01812830
lr
NUTIM MIRU aPIULOW UVU LHJUID
Uff?rut i *t i ..
p ami as. aiaiNU.», PAW. tc npcm «i i JlTflMiCCIATB JWU •»• 14 - 14k A tut-i, I^T—
iMQA*i lug/ •: /wa iwqg _____.
MII ec via AceoCB»OONDS • m»Lt mioiTi tn»it MIULTI «o/i t nieoynrr
( ff) HMH ncmloln( IV) WI.13-1 ncftlonltflli . _______ _____MV) TMV» ^»»__________ UP '' AH « l^C-(iv) |i»n-l orben titrocMnf»»
(lev) 101-Ot-t l.l lletilornottuM(IIV) 1I»9M(19V) J*____—(14V)(19V) H«|4.| 1. H.Mitrotti InrnttMM(HV) T»00-» tt>l«root)»M(IIV) llt-TM I-rtl»not»»l»liiyl nttxr»JV) ««•*•» . tMomfnr*(»V) T»»-l LlMmMnrottMM __«_^ ______ _ ______ I_»_. l»*>» .(9M) Tl-at-i H»«ltMori»mMM(9»V) IQoll-CM
<MV^ mv*HTV)
tflVI TVTMTO«4».)
(HVI
r: •",- •••v .-v -u^. 01812730
^ •j n—T"*"—
LW um Liguic
,.JJ_2L_JI£lJli___________________ IMMWlMwl.VC IfWLI ». IR.IINN.». nTA MO. n «C NMRT Mi_-1 MI N^q - mfagti OAK »L
«c iMm MIM,TI mil, IMPII MM.n Mtnin mammn______M/I_____DiMiKicr
JU-,
I/I
r< • ' " r 1L j-^«M
so 018128
MSE-NEUTML I ACID MATRIX SPIKE
Low liquid Samples 'ubHH.4mdcp.puch..
DC Saav UNO. Original Ho. «•»• DC R.port No.MAssociate
PPf CAS Ho. Compounds Orlg. Sample QC Spike Added IResults Results ug/1 Recovery
(22A) 59-50-7 p-chloroin-crtsol ___t_J(24A) 95-57-8 2-chlorophenol ___^(5BA) 100-02-7 4-n1trophenol _____{(64A) 87-36-5 pentachlorophtnol ___y_(65A) 10B-95-2 phenol Hi4( IB) 83-32-9 acenaphthene jM'_( BB) 120-82-1 1,2,4-trlchlorobenzene ^(278) 106-46-7 1,4-dlchlorobenzene M(35B) 121-14-2 2,4-dlnltrotoluene M(63B) 621-64-7 fJitrosodi-N-f
(6BB) 84-74-2 dl-n-butyl phthalate(69B) 117-84-0 dl-n-octyl phthalate(76B) 316-01-9 chrysene(84B) 129-00-0 pyrene _____L
ao 018129
-Nam-Nead OmpuChem
QC Sample No. Orlg. No. EPA No. QC Report No," Associated Saaoles I JjJ "~ M"3' Case Ho. _
(638) N-n1trosod1-n-propyl«m1ne(6881 dl-n-butvl Phthalate flfc____ &31*-(698) dl-n-octyl phthalate 9 I/1Q(76B) chrysene Q f, 150
PPI Compounds QC Sample Results Original Sample Results Relative %__ Difference
2-fluorophenol ^ ___ JU V,pentafluorophenol.5-2-fluoroblphenyl QT / J2-fluoroan1l1ne
d.-n1trobenzene T HO ____ I i'
decafluoroblphenyl ____"//) __________ ___ _(22A) p-chloro-m-eiresol ____5 "r 2 & ^ '(24A) 2-chlorophenol 2 )|_) (c
»,f> nl f) ——-(5BA) 4-n1trophenol ____IUf ____M
/)/\ jO(64A) pentachlorophenol ____JLJ ___/_a(65A) phenol ts3 ____!!:_( IB) acenaphthene _ _. 9.Cj ___ 'llU( 88) 1,2,4-trlchlorobenzene fcC ^Q____ _JL~_(27B1 1.4-dlchlorobenzene 9' ' f /Q____ ___J_
/ L! 9 A 2£L(358) 2,4-d1n1trotoluene 1C7 ._._ __ &U - — ?>*-.
*• '-•*; ..(i3
018130ao
nrriciDP MM* i*inUN Uvel Liquid /
»*•"*«_
urn)
30 018131
nnicico wu-vnt w*u»i»Low Level Liquid
_ JI9P._, Jldrln90P__ jleldrlnlOOP... Jieotachlor
•II_
**ti II mnort.) w n »or _I|M *-»"•
l» tw«i __4_Bt--!!r-OCWWTCMCWiOCWWTI"". ' »3
"»••? 4,
018132ao
OWNICS /WLTSIS DATA SKCT - Pace 2
Laboratory Hm Hntd Caytim CmNutarL-b Sanple D No, (LOBJP.STI a A.H instnimnt BlanK qc Rnport NoTAssociatedSeiplB /m.a .mio i wqn icig i iffir
YCLATMSug/1
107-02-4 acraleln_________»107-13-171-43-Z
acryiomtnie•Denztne
ae-zi-a carbon tttnehlonot IP1IB-9P-7 cniorcbenaneI07K16-Z
75-3W7>M)U-57S-3W
WiZ-oichioroettiane W,1-tncnlurmflane m
T-fllchloroetflant,1 -tnchloroeuiane nND
75-00-3 w67-66 3 Cti MUfoint
z-cnioroepyivinyl tmtr D
75-35-115D-00-5
P6 • E-€ iTre-ir •flichloroproptne
»-dichlorotgieiB r7B-B7-5 , .z-dicn oropropaneD6 J a-06 clstl ,3H IcniorDpropene
w
Ibenzene75- frz anrnylent cnlondeyi -87-3 Oilonnetnane5-Z>Z broipfoti
75-"DmnxiicniOTiiflePianeTluorotrlchlcfTOttianeo anoroal uorawQ-nefli orooiMuiuiBtliane
1Z7-UM -tnchicmetneneHB-flB-3 aiuene
1 r cnloroeDiBnevTnyraiondtSSLTm(Wirfrlonty Pollutant rauaroous Substaros)
67-«-I ecetme_________»Tb SB-3 z-tutanone75-UH)519-7WKB-10-11UU-42-5ldXfi-4SM7-6
carMMisuinneZ-ntxarane«HKthyl-i!-PBi_nretoraneyinyi acetatec-wiane
018133
Lab Hame; Head CompuChemj____ Case Ho;Lab Sample l.D. to.Miae a'q/.'. Instrument BlankQC Report Ho:__________
A. SURROGATE SPIKE RESULTS
COMPOUNDM 1.2-Dlchloroethane08-Toluene
FRACTIONVOAVOA
CONC.(uo/l),22A\
(Surrogate!AddeS (ug/1)
20.020.0
Only}Recovery
l i D\of
FORM 1 (continued) Data Reporting QualifiersFor reporting results to EPA, the following results qualifiers are used,Additional flags or footnotes explaining results are encouraged, Definition ofsuch flags must be explicit, however,(a) Value - If the result Is a value greater than or equal to the detection
limit, report the value.(b) U - Indicates compound was analyzed for but not detected, Report the
minimum detection limit value with the U, e.g., 10U, The foot-note should read; U-compound was analyzed but not detected. Thenumber 1s the minimum, detection limit.
(c) X . - If the mass spectral data Indicate the presence of a compoundthat meets the Identification criteria but the quantitativeresults Is less than the specified detection limit out greaterthan zero, report the detection limit as K, e.g., 10K. The foot-note should read: K-Actual value, within the limitations of thismethod, Is less than the value given.
(d) J - Indicates as estimated value which 1s used when estimating a con-centration for tentatively Identified compounds, e.g., 1200J.The footnote should read: J - Estimated value.
(e) Other • Other specific flags and footnotes may be required to properlydefine the results. If used, they must be fully described 1n apage attached to the data summary report,
(f) ** . This flag applies to pesticides parameters where the Iden-tification has been performed using two column confirmation (asspecified In Method 608) but the level 1s too low for verifica-tion of the compound by mass spectrometry. 018134
^ •B pTT-V>">
Lab Na_ti : Case No.Lab Sample I.D. to.PMjpftiaAi, Initrimnt BlankQC Report Ho.: _________
B. TEIITAT1VELY IDENTIFIED COMPOUNDS
f12345678910111213141516171819202122•2324252627282930
CASf
•
COMPOUND NAME '
(V»M
•
RON"INBNBN 'BNBNBNBNBNBNBNACIDACIDACIDACIDACIDACIDACIDACIDACIDACIDVOAVOAVOAVOAVOAVOAVDAVOAVOAVOA
Pur. Est.Cone.
01813530
. QUALITY ASSURANCE HOTICE
., The volatile walysls of blank " t 'aH/t//. ihowi thepresence of the Uboratory ertlfact illoxane it lean f. " .This compound Is routinely observed as en Instrument contaminantand nay or may not actually be present In this sample. Slloxanehas not been listed is one of the non-priority pollutant compoundsIdentified In this sample.
AvLa&ASK.. .''Quality Assurance Ane st
. 018136f> • „1 •'« -1 ji
ao
^ ^ ^ •P-TrW''
,, u.i. tmiioMmAi, mncrioN HOB-ar iwiio Nwtt_wtP.O. m. in, AIMMMI, « mil •IM UVtL LIQOIDMAMICS WALTSII DATA MOT • n«* 't
U» tatll 16 -. llnnr" nS.U r OC R*«rt M.inTCT"7 faIj <WU..1'NIJ HM-V. MS
Htitlili tatoctiw Ibin if 1 13 ff ttf|iICKMk In <r tortfM
nCID CC.MOMBJ
018137
ORtAMCS ANALYSIS DATA SHEET • Page 3
Lab Kerne; Head Co-puChemLib Sample I.D. Mo.Blan
A. SURROGATE SPIKE RESULTS
018138
30
MSUMNB "<JTICEThis sample IMS low recovery for pentafluorophenol. The recovery
•f the surrogate pefitaflworophenol periodically ftps below laboratorycontrol Units. This phenoMnon 1i under Investlgitlon. Since theether add surrogate exhibits noraal recovery, the imple results haviWen reported without my additional inalyses.
n
Quality Assurance
018140
OICTIHS
— -
ton um LIOOIOI
, 80
OftfiANICS ANALYSIS DATA SHEET
_jmA, SURROGATE PIKE RESULTS
018142
TOO (rU-NNtlRP MZAXNVS HAITI)
i ..
I. llPo «f fin f ittnilty W 120 to 122 Mtchisto HtHI n in if luni>rl tail/Hi /H.TNV c-nw, PliM f__] ao
> "™-i "—— '
i» liuntfin tfmi If fflk NifMi fir VTJaoIUCt1/tMtlflVI«2
,4. Kfail IB atfit O
I. Fireent (Ucovery CilnlitlM
A. Mount 1,2,1,4 TOO (n/Ml) fiyntf t« laartTi Nlltf Ml iru If VE MOud iMtirnil lUndirf cilculitlin ta » fM-.c» '•C-MAfi. 5SV/
I, FfMl Mtfli nig.
C. Sifkl 1ml I,2,J,4-T15C: B.OOO
A IJ |
I 1001 _r
I. I1C fertanittj if ttclirMiHl if M-fli f I tt»ithe ivirigi »ictpwnd if ftur pin ttlfbrUli,
f
Vw,iw
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-8
-.JOCEDURE: RK DIAGNOSTIC REPORT 5/03/83 6s 40:36>ATA FILE: CN001460C12.^FERENCe: IFBS^ METHOD: IFBS INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: IFBSS1
I —— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
2 2 A 0 SS 4 1 141 IFBS51/IFBSU12 2 1 0 23 B 1 48 IF6SS2/IFBSU2
45 COMPOUNDS PROCESSED. IS FOUND
; COMPOUND X ————————— SEARCH ————————— X SAT X ———— CHRO ————— ':•NO LIB ENTRY REF 'FRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAKS
130 '182 . 167 S37 . 15062 , . '6 4 . . .9 4 . . .5 6 . . .5 3 . . .130 1S2 . 1B4 118 . 1101966596S36 2 . . \9 7 . , A1171 2 7 . . .5 8 . . .7 2 . . .7 6 . . .B4 330 . 1
108 450 , .16 5 . . .7513078 331 . 175971 2 7 . . .173164 428 1 .8 3 . . .92 453 . i112 476 . 11 0 6 . . .6 3 . . .84 330 , 184 330 , .1
: S :•tj .: 22 :
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122345671234567891011236132345675918111213141511457B9
184237315977471301441841181581731992132252402652722831303391483314503873133S433333B338336386429429453476517357331331394423276683631
IBS23730SB764612914318311715717219821222423926427128212923B147330450306312323332337337335385429429453476517356330330393423274604633
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.•JANTITATION REPORT FILE: CN001460C1S
,"«*TrV CN001460C12. TIj/03/83 6:02:00iAMPLE: 25 ML 1460 + 5 UL (8635+8637)iUBMITTED BY: 12 ANALYST: 714
iMOUNT=AREA * REF. AMNT/IREF, AREA)* RESP. FACT):ESP. FAC. FROM LIBRARY ENTRY
NO NAME1 tBROMQCHLQRQMETHANE (INTERNAL STANDARD)2 CHLOROMETHANE3 VINYL CHLORIDE
' 4 CHLOROETHANE5 BROMOMETHANE6 ACROLEIN7 ACRYLONITRILEB tBROMOCHLOROMETHANE (INTERNAL STANDARD)9 METHYLENE CHLORIDE10 TRICHLOROFLUOROMETHANE11 1,1-DICHLOROETHYUENE12 1,1-DICHLOROETHANE13 TRANS-1,2-DICHLQROETHYLENE14 CHLOROFORM15 1> 2-DICHLOROETHANE16 1,1,1-TRICHLOROETHANE17 CARBON TETRACHLORIDE18 6ROMODICHLORQMETHANE1.9 *D6 BENZENE (INTERNAL STANDARD)0 1,2-DICHLOROPROPANE21 TRANS-1,3-DICHLOROPROPENE22 TRICHLOROETHYLENE23 BENZENE24 CIS-1,3-DICHLOROPROPENE25 1, i, 2-TRICHLOROETHANE26 DIBROMOCHLQRQMETHANE27 BROMOFORM28 1, A, 2, 2-TETRACHLOROETHYLENE29 1, i, 2, 2-TETRACHLOROETHANE30 TOLUENE31 CHLQRQBENZENE32 ETHYLBENZENE33 2-CHLOROETHYL VINYL ETHER34 *D6 BENZENE (INTERNAL STANDARD)35 «D4 L 2-DICHLOROETHANE (SURROGATE)36 #DB TOLUENE (SURROGATE)37 »D6 BENZENE (INTERNAL STANDARD)38 ACETONE (2-PROPANONE)39 2-BUTANONE40 4-METHYL-2-PENTANONE41 2-HEXANONE42 CARBON DISULFIDE43 VINYL ACETATE44 STYRENE45 0-XYLENE
M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TO*
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NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/JOT._1 130 182 9:15 11. 060 A BV 15510, 4, 000 UG/L 12. 682 NOT FOUND3 NOT FOUND4 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUNDB 130 182 9:15 B 1. 000 A BV 15510. 4. 000 UC/L 12. 689 84 1AB 6:00 8 0. 648 A BV 13527. 2, 868 UG/L 9, 0910 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 NOT FOUND16 NOT FOUND17 NOT FOUNDIB NOT FOUND19 84 330 16: 46 19 1. 000 A BB 89336, 4. 000 UC/L 12. 6620 NOT FOUND21 NOT FOUND22 NOT FOUND23 78 331 16:50 19 1. 063 A BB 582, 0. 041 UC/L 0. 1324 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND28 164 428 21:45 19 1.297 ABB 1260, 0, 104 UC/L 0,33? NOT FOUND
JO 92 453 23:02 19 1. 373 A BB 1922, 0, 163 UC/L 0. 5231 112 476 24:12 19 1. 442 A BB 464, 0. 025 UC/L 0. 6832 NOT FOUND33 NOT FOUND34 84 330 16: 46 34 1. 000 A BB B9336, 4, 000 UC/L 12, 6835 67 837 IS: 03 34 0, 718 A BB 13169. 3. 922 UG/L 12, 4336 100 450 22:52 34 1. 364 A BB 70575. 4, 476 UG/L 14. 1937 84 330 16: 46 37 1, 000 A BB B9336. 4, 000 UG/L 12. 6838 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIO1 9:21 0. 99 1. 000 1. 00 4. 00 4. 00 1. 000 A, 000 A, 002 1:35 0.168 16,00 A. 3683 3:00 0, 32A A6. 00 A. 5734 3:55 0, 4AB A6. 00 0, 9325 2'. 23 0, 255 16. 08 2. 0826 6:36 0, 707 159. 99 0. 0357 7:19 0,783 A59. 99 0. 054B 9:21 0.99 1,000 1,00 4.00 4,00 1,000 1,0009 6:00 1. 00 0. 641 1, 01 2. 87 16. 00 0, 21B 1, 217
NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIO.: 3 02 0. 859 16. 60 5. 138
"\ 8:48 0, 940 16. 00 1, 37912 10:07 1. 082 16. 00 0. B3713 10:50 1, 158 16. 00 1. 03B14 ,U:26 1,223 16.00 4,151IF 12: IS 1. 304 16, 00 1, 68516 13:28 1.440 16.06 3, 84317 13:50 1, 478 16. 00 4, 691IB 14;23 A, 538 16,00 0.264A9 16:46 1. 00 1, 000 1. 00 4. 00 4. 00 1. 000 1. 000 1, 0020 15:36 0. 930 16. 00 0. 07921 15:55 0,948 16.00 0,375.22 16:28 0, 982 16. 00 0. 45223 16:56 0. 99 1, 009 0. 99 0. 04 16. 00 0, 002 0. 630 0. 0024 17:11 1.024 16.00 0.16425 17:11 1.024 16.00 0,16126 17:05 1.018 16.00 0,24127 19:37 1. 170 16. 00 0. 124SB 21:48 1,00 1.300 A, 00 0.10 16.00 0,004 0,542 0.0129 21:48 A. 300 16.00 0. A2330 23:02 1. 00 A, 373 1. 00 0. 16 16. 00 0, 005 0, 527 0. 0131 24:12 1,00 1,442 1,00 0.02 16,00 0,001 0. 835 0,0032 26:17 1, 567 16, 60 0, 37433 IB: 09 1, 082 16. 06 0, 06234 16:46 1. 00 A, 000 1, 00 4. 00 4. 00 1, 000 1, 000 1, 0035 12:06 1, 00 0. 721 1, 00 3. 92 4, 60 0.147 0.150 0. 9836 22:52 1, 00 1, 364 1, 00 4. 48 4. 66 0, 796 0. 706 1, 1237 16:46 1,00 1,000 1.60 4,00 4,66 1,000 1,000 1,00'& 6:36 0, 394 128. 00 0, 003j9 12:06 0, 721 ISO. 06 0. 004 \40 20:02 1. 194 120. 00 0. 02341 21:30 1. 2B2 ISO. 66 6. 01B42 7:31 0,448 16,06 0, B6843 14:02 0,836 16.60 0.17444 30:42 1,830 . 16,60 0,72345 32:08 1, 915 16. 60 0. 488
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COMPUCHEM HO.______ DATEIDENTIFIER VOA - LOH LEVEL LIQUID
COMPOUND LIST - HO.___ (Page One of T*o)COHPUCHEMCOMPOUND QUANT.REPORT CORRECTION DETECTION
COUNTER NUMBER COMPOUND NAME____ VALUE x FACTOR • RESULT LIMIT lug/I)Z. 221 CHLOROMETHANE ............. ____ / ___ -5-|3. 231 VINYL CHLORIDE4. 209 . CHLOROETHANE ...5. 220 'BROMOMETHANE .............. ____ ____ ___ 5- '•6. 201 ACROLEIN .................. ____ ____ ___ W&-5W7. 202 ACRVLONITRILE .....8. 222 KETHYLENE CHLORIDE9. 230 TRICHLOROFLUOROMETHANE .... ____ ____ ___ -5-10. 216 1,1-DICHLOROETHYLENE ...... __,__ ____ ___ *~11. 214 1,1-DICHLOROETHANE ........ _,___ ____ ___ *-12. 226 TRANS-1.2-DICHLOROETHYLENE ____ ____ ___ *13. 211 CHLOROFORM ................ ____ ____ ___ -5-14. 215 1,2-D I CHLOROETHANE ........ ____ ____ ___ *-15. 227 1,1,1-TRICHLOROETHANE ..... ____ ____ ___ -6-16. 206 CARBON TETRACHLORIDE ...... ____ ____ ___ •*"17. 212 BROMOD1CHLOROMETHANE ...... ____ ____ ___ *-18. 217 1,2-DICHLOROPROPANE ....... ____ ____ ___ -S-19. 250 TRANS-1,3-DICHLOROPROPENE20. 229 TRICHLOROETHYLENE21. 203 BENZENE ................... ____ ____ ___ *- I22. 218 CIS.1,3-DICHLOROPROPENE ... ____ ____ ___ W- 223. 228 1,1,2-TRICHLOROETHANE ..... ____ ____ ___ *~|24. 208 DIBROMOCHLOROMETHANE ...... ____ ____ ___ *" I25. 205 BROHOFORM ................. ____ ____ ___ •*• I26. 224 1,1,2,2-TETRACHLOROETHYLENE ____ ____ ___ *• I27. 223 1,1,2,2-TETRACHLOROETHANE . ____ ____ ___ '* '28. 225 TOLUENE ................... ____ ____ ___ *• \29. 207 CHLOROBENZENE ............. ____ ____ ___ -5- I30. 219 ETHYLBENZENE .............. ____ ____ ___ •*-131. 210 2-CHLOROETHYL VI34. 252 ACETONE (2-PROP
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST!!
1C
CO'MPUfJHEM NO.______ DATE' > IDENTIFIER VOA ... LOH LEVEL LIQUID
COMPOUND LIST , • NO. ___ (Page Two of T*o)COMPUCHEMCOMPOUND QUANT.REPORT CORRECTION DETECTION
COUNTER NUMBER COMPOUND NAME_____ VALUE x FACTOR • RESULT LIMIT (ug/1)39. 253 2-BUTANONE ................ ____ I poL -260 fo40. 256 4-MHHYL-2-PENTANONE ...... ____41. 255 2-HEXANONE ................ ____42. 264 CARBON D1SULFIDE .......... ____43. 257 VINYL ACETATE ............. ____44. 251 STYRENE .45. 239 o-XYLENE
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018162
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01816330
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PROCEDURE: F'K DIAGNOSTIC REPORT. 3/06/83 0:52: C:.OATA FILE: CHCi61460Ci5EFERENCE: FSC-lc
METHOD: FSCC6 INITIALIZATION OPTION: 2 PROCESSING OPTION: 3REPORT: FSCC69
: ——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN
4 4 1 137 79 IB 1 135 F5CC6S/FSCC6U
79 COMPOUNDS PROCESSED, 10 FOUND
: COMFC'JHD X --———•——— SEARCH -———————— X SAT X ———— CHRO ————— .NO LIB ENThY REf . PRED SEL DELTA PEAKS FIT PEAKS M/E TOP DELTA PEAK".'.1 Fl 1 -61" 617 616 -1 1 960 . 97 616 . i2 FS 1 -So* B?i8 B5B . 1 997 . 136 856 . i3 F3 1 -Hit. 11J5 1417 a 1 994 IBS 1417 . :4 F4 1 -133" ISM 1392 -1 i 998 . 240 138E , i5 F l 2 -396 3 0 1 . . . . . 7 4 . . .a Fl 3 -al = 615 , . 947 F l 4 -617 6 1 3 . . . . . 9 3 . . .S F l 5 -63<; D B S . . . . . 9 3 . . .9 Fl a -632 623 . . , 123
1 6 F l 7 ~bS2 t,49 . . . . . 1 4 61 1 F i . S -660 6 5 6 . . . . . 1 4 612 Fl f -637 663 . . 1461 3 F l I d -o3'.. 6 B 3 . . . . . 1 6 31A Fl U -?:: 709 . . . . 1S1 .1 5 F l 1 3 -766 7 0 4 . . . . . 1 0 8 . .1 6 F l 1 5 -734 7 3 8 . , . . . 1 1 717 Fi 1A ~73£ 729 , . . , 109IS Fl IS -4S-. 4fca 479 -3 1 9B9 . 112 "79If Fl Ii -6ia fcJ7 1BA2C FJ 17 -71'- 745 745 , J 995 B3 745 . 121 Fl J.3 -73i. 7E2 78S . 1 995 334 7SS . 122 Fl 19 -3*3 56:9 588 -1 1 996 . Ill 586 , 1123 Fl ?<j -1S4': 10-17 104B 1 1 996 . 172 104B . 1S I F E 2 -73* 7 2 0 . . . . . I S O25 F S 3 -75S 7 1 9 . . . . . 1 S 3
^ H TF?"""
2 6 F S A -790 7 B 7 . . . . . . B 3 . .27 FS 5 -SC3 BOO . , . , , 13*9 . .2 S F 2 e -315 B 1 2 . . . . . 1 2 3 , .5 9 F S 7 -93E B & 9 . . . . . 9 3 . . .3 0 F 2 S -341 B 3 B . . . . . 1 6 23 1 F S < ? -3S4 B 5 1 . . . . . 1 B 3 , .3 , ? F S K I -S7B B 7 5 . . . . . 1 2 7 . .3 3 F S 1 1 -S5£ 8 4 9 . . . . . 1 0 5 . ,34 FS 13 -395 B<?2 . . . 2S53 5 F S 1 3 -965 94.2 . . . . . 1 0 7 . ,3 6 F S 1 4 -979 7 7 6 , . . . 1 1 5 . . .3V FE 15 -1019 1016 . . . . 2373 5 F S 1 6 -1041 1039 . . . . . 1 9 6 , , .3<? FS 17 -1062 1060 16240 FS 13 -1134 1133 15241 FS 19 -1131 11S9 . . . , , 1 6 3 . *• - ,„,„ - .43 F£ gft -363 BfcO , . , , 128 •y<','-i>'J1A 3 F S S i -1141 1139 . . . . . 1 6 5 . ,4 * F S 2 2 -130B 1206 . . . . . 1 6 5 , ,45 FS S3 -1-169 1167 . . , . . 1 3 9 . ,4 6 F S S 4 -1(191 10E9 . . . . . 1 3 8 . 018165-7 FS 25 -119& 1153 . . . . . 1 6 8 * .t 3 F S 3 6 -1279 1277 . . . . . 1 3 9 , , ,.'? PI T'? -'..'..I- -0"'5 1BA Ofl
S» FS 2 -116" litSi.l F!. 3 -USi 117932 F3 4 -ll S 119353 F3 5 -1254 12523< F3 6 -125S 1356
~V- rj ',• -iS5i, 1253£6 F3 3 -1278 127657 FS 9 -iaaa ISBO38 F3 18 -1342 1341*r> F3 11 -1364 13636v F3 12 -1430 1419ij F3 13 -142B 1427a.1 F3 14 -1629 1629.•.: r;, 15 -166B 1668....• FS 16 -1236 lSf-4.-.". F3 17 -1539 15JS66 FS 13 -13°5 13=7*v F4 2 -1950 iBt'lo.". F4 3 -18ci7 1BB86? F4 4 -1S84 13B570 FA 5 -ISC'Cr 1B6071 F4 6 -196t. 1907 1966 -172 f4 7 -3*58 200973 F4 6 -1357 1B&8">•* Ft 9 -2127 21 £"75 F4 16 -3414 E41776 F4 11 -2422 2«c577 F4 12 -24"e 2«?97K F4 13 -2u65 2ut97* F4 1.4 -2Cii6 2069
950
1B4139166204149 125619916"249SB'117817920220277149 15405662S3asa253149149 190fr1491B4S53276278276252252
01816830
.'"JANTITATION REPORT FILE: GH601460C15
'" TA. CH0014e8C15. TI...5/06/B3 0:13-. 68SAMPLE: 1UL #146<J *(B699 IS) ON N1SSUBMITTED BY'. #15 ANALYST: 659
AMOUNTsAREA * REF, AMNT/!REF. AREA)* RESP. FACT)r;ESF. FAC, FROM LINEAR FIT TO WHOLE . RL
NO NAME1 *D3-PHEN'3L (INTERNAL STANDARD 1 (624)2 N-NITR050DIMETHVLAMINE (441)3 PHENOL (61614 ANILINE (473)5 BISia-CHUOROETHYU)ETHER (411)s S-CHLOPOPHENSL (601)7 1,3-DICHLOROBENZENE (431)8 1. t-DJCHLfiROBENZENE (422)9 1, B-DICHUQROBENZENE1 (420)10 BENZYL ALCOHOL (474)11 6XS(a-CHi,OROIBOPPQFYUETHER (412)12 a-METHYuF-r!£l«u (6SC)13 HEXACHLORC'ETHANE (436)14 4-METHVI.rHcH:iL (62E)15 a-FLUOROF'HSNOi. (SURROGATE) (619)16 PEMTAFLiJOFOFHENOL (SURROGATE) (623)17 DS-NITROBENiENt (SURROGATE) (447)13 DECAFLU'JROBIF'HENYL (SURROGATE) 1470)19 2-FLUOROANILIME (BLiRROGATE) (472)3<S> a-FLUOR'5l!iIF.HENiL (SURROGATE) (449)21 *DB-NAF'HTHALENE (INTERNAL STANDARD) 1460)32 N-NITROS-S-DI-N-PPOPYLAMINE (442)52 NITROBENZENE (440)34 IBOPHORONE !43f?>25 2-MITROPHENdu (606)26 2, 4-DICiETH'r'i.PHENOL (603!27 BIS(2-CHLOROETHOXV)rlETHANE (410)23 2,4-DICHLOROPHENOL (602)39 1, S. 4-TRICHLOROBENZENE (446)30 4-CHLOROANILINE (475)31 BEN20IC ACID (623,'32 HEXACHLOFiOEi'JTADIENE (434)33 P-CHLOP'0-M-CRESOL (608)•JA S-METHYLNAPHTHAUENE (477)35 HEXACHLttRCCiXOPENTADIENE (433)3a 2, 4, 6-TRICHLOROPHENOL (611)37 2-CHLOR'SNAPHTHALENE (416)73 ACENAPHTHYLENE (402)29 DIMETHYLPHTHALATE (425)Aii NAPHTHALENE (439)41 2,6-DINITROTOLUENE (428)*2 2,4-DINITROTOLUENE (427)43 3-MITROANILINE(479!44 2-NITROANILINE(47B) •45 DIBENZOFURAN (476)46 4-NITROANILINE(4BO)
018167
Ut NAMEr"V-.' J. 4, 11-miCHLOROPHENOL (636)
45 »010-PHENANTHRENE (INTERNAL STANDARD) (467)49 ACENAPHTHENE (401)SS S,4-DINITROPHENOL (685)51 4-NITROPHENOL (607!3S FLUORENE (432)53 4-CHLOROPHENYU PHENYL ETHER (417)54 DIETHYLPHTHALATE (424)5S 4,6-DINITRQ-O-CRESOL (604)56 DIPHENYLAMXNE (N-NITftOSO) (443)57 4-BRQMOPHENYL PHENYL ETHER (414)35 HEXACHLCiROBENZENE (433)5-* PHENANTHRENE (444)n& ANTHRACENE (403)»i FLUOPANTHENE (431)62 PYRiENE (445'o3 1, a-DIPHENYLHYr.>RAZINE (AZOBENZENE) (430)64 DI-N-BUTVLPHTHALATE (426)65 PENTACHLOROPHENOL (609)ca »D12-CHK'i'SEI'JE (INTERNAL STANDARD) (459)o" BENZOiAJANTriF.ACENE (405)63 CHRYSENE (413i69 3, S'-DICHLC'ROBENZIDINE (423)70 BUTYLBENZYLFriTHALATE (415)71 BIS(2-ETHYLHEXYL)PHTHALATE (413)7£ C'1-M-OCTVLPHTriALATE (429)73 BENZIDIIC (404)->J FrNTr.-(A)PYRENE (406)73 IHDEHOa.. S, 3-C, D)PYRENE (#437176 DIEENZOiA, H)ANTHRACENE (419)77 BENZO(G-H, DPEPYLEME (408)78 BEMZOIBIFL'JCiPANTHENE (407)79 BENZOIMFLUORANTHENE (409)
NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT
018168
M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT KTOT97 616 7:42 1 1.900 A BV Wf6. 20. 000 NO 5.79
NOT FOUND /jy/7NOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUND
:.l NOT FOUND.IS NOT FOUND13 NOT FOUND14 NOT FOUND15 llg 479 5-59 1 0. 77E A BV 8623 28. 358 NO B. El'.: NOT FOUNDi' BS 74? -s 19 1 1. 209 A BV 21423. 4B. 773 NO 14.12'S 334 79-: 9 4fr 1 1. S69 ABB 15267, 49. 31V NO 14.27A 9 111 53S 7 Kl 1 0.955 A BV 299B4. S3 975 NO 1562iw 17E i.0450 13 OS 1 1. 701 A BV 4B592 63. 551 N3 IB 3921 136 BI5 IS 43 fl 1,000 A BV 39376. 20, 000 NO 5.7922 NOT FOUNi:21- NOT FOUNDS> NOT FOUHt1TS NCT FOUKV£e NOT FOWDa? NOT FOUNDSS NOT FOUNDi 5 NOT "C'Of130 NOT FOUND31 NOT FO'JtO . ..•i NOT FOUND:•; NOT FOUNDji NOT FOUivi:•': NOT FOUNi.'M NOT FOiJlwi" NOT FOUND;: NCT FOUND..i l.-ij' FOUuC-a* NOT FOU;.;;-1 NOT FOUN1':-v;- NOT POUND- '(C'T FOUND
«s NOT FO'JlvIiA 7 NOT FC-UNi"4,: IB? 1417 17'43 4g 1. 080 A BV 37145. 20.000 NO 5,79
I.1'IT FOUND-:•: NOT FOUND": NOT FOUND».j Ii.:" FOUNDi* NOT FOUND' 149 1S36 15'42 48 0, 9B6 ABB 705. 0. 415 NO 0,12
NOT FOUND .W:T FO'.I',: „„„,.,.oisrt*>V(
rvt S-IA'- TKE REF RRT METH AREA(HCHT) AMOUNT '/.TOTI,OT PCVf.'V!OT FOUiwIvv" FOUUJIU;T FOUNDr,07 FOUNDi'.v" FOUND
.-J 14* 15«1 1" 15 ij 1. OC" A BB 3B43 i. 531 NO 0. 44• • '.:.;•' FO'JNDii. i«0 1633 53 31 i-6 L 0-30 A BV 33733. 40 000 H" U. 53.•/. NOT FO'..".:.'*:• NOT Fowop4 NOT FO'.':.C'10 NOT FOUNL-,'l 149 1W-, .'.•'.• ** t.6 J. 012 A BB 1029. 0 456 NO 0. 1372 NOT FOWi"2 NOT POUNC74 NOT FOdNL-75 NOT FOUND~a NOT FOW.:.177 NOT FOUN:75 NOT FOWL79 NOT FOi.i'-'.''
;.;• wvu **T:;. RR~a> RATIO AMNT AMNTID R FAC R. FACILS RATIO: •' 4-s i ;. i oci1* i. oo 20. oo 20, oo i. eoe i. ooo i oo• 3.4? 0 474 50. 00 0. 623
7: <u 1 000 50. 00 1 175: «j ,N. R'" 50 00 0 9*7
•=, 7 '52 1 '.'it' SO 00 1 0717-5* : c:i 50.00 0.827 'E. c« i o;;: so. eo o. 932D 1? 1 t-t; 50 00 0 945
5 &.35.1 1 H,> 30. 60 0 914•If B.24 i lOi ' 50.00 0. 4SO1.1 B ?4 j. 150 ' 50 00 0 223IS B.S1 1 144 50.ee 0.774i:> 9:10 1 IBt SO. 00 0 387iA ? ec j. 163 50. 00 0. 3*5.13 fc.04 0 ^"p 0. 7&5 099 SB 36 50,00 0.353 0.622 0,57..c, 7:46 1 003 50. 00 0 27417 9.22 6.9* 1 £10 1,00 46.78 50.00 0. 677 0.899 , 0. 9BIS 9' 4? 1 Ov i. £fcB 1. 00 49. 32 50. 00 0. 625 0 632 0, 9919 7.25 69% 0. 95B 100 53.97 50,00 1.227 1,136 1,OB20 13: 07 1. 60 1. c,95 1, 00 63, 55 50. 00 1, 9BB 1. 564 1. 2731 10: 43 1. 66 1. 000 1, 00 20. 00 20, 00 1. 000 1, 000 1, 0033 9. 10 0 853 50. 00 0. 038?.? 9' 24 0. B74 50, 00 0. 190••; 9.5S 0.919 50.00 0,7313S 10' 02 0. 934 50. 00 0, 180S& 10:11 0, 94B 30,00 O.J343 „.37 10.24 0,967 30.08 0,397 I*''-S3 10:31 0,978 50.00 0.291 "•F9 10: 40 0, 993 50, 00 0, 31430 10. 5B 1.021 250,00 0,22931 10: 39 0 991 250, 00 8, 180
fj- RET(L) RATIO RRT(L) RATIO AHNT AMNT(L) R FAC R. FAC(L) RATIOT.s 11:11 1. 041 50, 00 0. 17333 12:04 1. 182 50, 00 0 36234 12:14 1. 136 50, 00 0. 2S93; 12- 44 1. IBS 50. 00 0. 1063i 13:01 1. 210 50. 00 0. 89637 13-. 16 i. 235 50. 00 0, 6243S 14' 10 1. 319 50 00 • 0. 921;•• 14:08 i. 313 50. 00 0. 706A3 1C 47 1. OU3 50, 00 1. 093,U 14 16 1. 3E7 50. 00 0 149A,- 15: OB 1, 405 50. Od 0, 213A ;• in 37 1 359 £50, 00 0. 002
' AA IS' 36 !.'£*.« 230. 00 0. 312*S 14 56 1. 390 56. 00 0. 379A--, 15:59 1.457 250.00 0029A7 13.01 1. £10 250. 00 0 179A3 17'42 1 6f' 1.000 1.00 2000 20.00 1.000 1.000 100AT 14:33 0 Bf< 50. 00 0 667a:- 14:4t 0634 250.00 0. 05S?! 14:56 0. 6*4 125.00 0 S7032 15- 40 0 656 50. CO 0. 76353 :5: 42 o B£3 50. 00 . 0 31634 15:41 1. (16 0. BB6 i. 00 0 41 50 00 0 OOB 0. 916 0 01.33 15' 56 0. 90S 250, 00 0, 09356 in 01 0 955 50 Od 0. 4«3?i If 4C 0 94S 50. 00 0. IS*63 17:03 0,963 50.00 0, 3S«59 17:43 1003 50.00 1.090a? 17.51 i. 005 • 50 00 0. 99541 20:22 1 150 50.00 1 06262 20'51 1 175 50. 00 1. Oilc3 ID: 04 0. 906 SO. 00 1, 2076A 19:14 1 M 1, 067 1. 00 1.53 50. 00 0. 041 1 351 0. 03ii 17: SB 0 9E7 50.00 0.074ie 23.32 1. CiO> 1 000 i, 00 4C1. 00 40. 00 1. 000 1. 000 1 00•j? 23:30 0 998 50, 00 1. 36?63 S3 35 1. 002 50. 00 1. 07769 23:33 1. 001 50. 00 0. 094•?0 2£;30 0 9S6 50.00 0.37171 23:49 1.6C 1. 012 1, 00 C, 46 50. 00 0. 023 2. 523 0. 0172 35-06 1.06* 50,06 2. 18173 23:13 0690 410.99 ' 0.00274 26 35 1. 130 50, 00 0. 87875 36'10 1.282 50.00 0,5627& 30- 16 1. 2Bi 50. 00 0. 53777 31:12 1.326 50.00 0.5537y 25:51 1. 09B 50.00 1.945""» 25:51 1. 09g 50.00 1.989
r
80 018171
UUI ______—————— IDENTIFIER 5EH1-VOLATILES •- LOH LEVEL LIQUID
COMPOUND QUANT.REPORT CORRECTIONNUMBER _ COHPOUNDS _______ VALUE x FACTOR
N-NITROSODIMETHYLAMINEPHENOLANILINEBIS(2-CHLOROETHVL)ETHER2-CHLOROPHENOL1,3-DlCHLOROBENZENE1,4-DlCHLOROBENZENE1,2-DICHLOROBENZENEBENZYL ALCOHOLBIS(2-CHLOROISOPROPYL)ETHER2-METHYLPHENOLHEXACHLOROETHANE4-METHYLPHENOLN-NITROSO-D1-N-PROPYLAMINENITROBENZENEISOPHORONE2-NITROPHENOL2,4-DIMETHYLPHENOLBIS(2-CKLOROETHOXY)METHANE..2,4-DICHLOROPHENOL1,2,4-TRICHLOROBENZENE4-CHLOROAN1LINEBENZOIC ACIDHEXACHLOROBUTADIENEP-CKLORO-M-CRESOL2-METHYLNAPTHALENEHEXACHLOROCYCLOPENTAD1ENE ..2,4,6-TRICHLOROPHENOL.......2-CHLORONAPHTHALENEACENAPHTHYLENEDIMETHYLPHTHALATENAPHTHALENE2,6-DINITROTOLUENE2,4-DINITROTOLUENE2-NITROANIL1NE3-NITROANILINED1BENZOFURAN
PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE COMPOUND LIST!!
45
COMPUCHEM NO. _____ DATE ______ 2 of 2COMPOUND'LIST NO. ___
———— IDENTIFIER SEM1.VOLATILES LOH LEVEL LIQUID
' " COMPOUND QUANT.REPORT CORRECTION DETECTIONCOUNTER NUMB COMPOUNDS______ VALUE X FACTOR • RESULT LIMIT (uj/ll46 479 4-HITROAN1HNE47 626 t,4,S-TRlCHLOROPKEKOL49 401 ACENAPHTHEHE50 605 2,4-DlNITROPHENOL51 607 4-MTROPKENOL52 432 FLUOREKE .........................53 417 4-CHLOROPHENYL PHENYL ETHER.......54 424 D1ETHYLPHTHALATE55 604 4,6-DINlTRO-O-CRESOL56 443 DIPHENYLAMINE (N-NITROSO) ........57 414 4-BROMOPHENYL PHENYL ETHERSB 433 HEXACHLOROBENZEK59 444 PHENANTHRENE60 403 ANTHRACENE61 431 FLUORANTHENE62 445 PYRENE ...........................63 4)0 1,2-DIPHENYLHYDRAZINE (AZOBENZENE)64 426 DI-N-BUTYLPKTHALATE65 609 PENTACHLOROPHENOL67 405 KNZO(A)ANTHRACENE6B 418 CHRYSENE .............69 423 S.S'-DICTLOROBEHZIDIKE70 415 BUTYLBENZYLPHTHALATE71 413 BIS(2-ETHYLHEXYL)PKTHALATE72 429 DI-N-OCTYLPHTHALATE73 404 BENZ1D1NE .............74 406 KNZO(A)PYREKE ........75 437 INOENO(1,2,3-C,D)PYRENE76 419 DIBENZO(A,H)ANTKRACENE77 4N |ENZO(G,H,1)PERVLENE78 407 KNZO(B)FLUORAKTHENE79 409 KNZO(K)FLUORANTHENE
Initrutint Codt 2)9 • Cornet Ion Factor CalculationFlnil txtrictlon volumt (all 1000 Dilution Conxtpilono.em Tor AC, i.Mi for B/N * vuigut or sinplt uiid (*T) x Factor * * • Factor
.0
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018174
r
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IT
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!018178
FDRMIA,.-,s fiC/NS PERFORMANCE ST AWARD - Decanuorptrlphenylphosphlne
Date g-6-hs iRun Mo.om,»^alr- Analyst
•/•Hi
M-
70
127
197
198
199
275
365
441
442
443
Ion Abundance Criteria
30-601 of MIS 198
list than 2t of Mil 69
list than n of HIS 69
40-601 of MIS 198
IMS than 11 of MSI 198
base peak, 1001 relative abundance
5-91 of MSS 19B
10-30% of MSS 198
11 of MIS 198
lets than MSS 443
greater than 401 of MSI 198
17-231 of MSS 442
Sped
£3%
*\%
1,5%
H\"?o
- <l%
\00tt
fc.n»l*%|,M%
5?J
4l?«
i a
SpKf
i.
Specf
CoMents:CO . Area 266
Fantachiorophenol Response Factor • JWnBo *• SO *• . U islenzttlne Detectable IArea (counts) lOng dlOColum descriptionTemperature
SOng Level Wyeianthracene •
Isothenaal
i PI nozW-r-
OQQfllGPrograM
B7018177
.... ,„. ..
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42 e. eo MiN.ti-in niN INTEN' o. nftx INTEN:444 « 6 MfiXIMA
MASS !i RA Mrt&E V. RA PIAS.3 ',: RA MASS '/, RA
42 0.74 JC'S- 2 0'3 ,!c' 2 3C 40? 0 2443 2. JP J'V C-. 6-3 Jf2 (5 P 42j 2.5244 5. 7B • ::.!' *' 83 IE'? C t. 4 4 0.3V
• 4" J -I?' U; 4 3.7 I'.l 0 3 441 5. OB5i ii I." J:'"' V "1 IV.; C ~! 442 40 bf.SA :•: I- .',.'.•.. C> 3« 1*.' C T 44;- 7 40'.,: i '••: .' '.• 1- a*. .'c •: :• t: M-'. 0 St-£", i'- ,: ;:'.' v; 6i; i-' / (• i?Si i . j.'i i i"i ;: : ic-i. i •S-; ;-. • ..:•.• i c.v ."«• « •).•r v i.-.-. c (:•. i\: o s:"•: . .. ..:•' o s;. .-•: o :..t.*?
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RQCEDURE: RK DIAGNOSTIC REPORT 3/11/83 16:01:22...STA FILE: TC001460A04
• TERENCE: TCMETHOD: TC INITIALIZATION OPTION: 3 PROCESSING OPTION.' 3REPORT: TCS
——— STANDARDS ——— X —— PLUS UNKNOWNS —— X - LISTPROC USED POSS RdS PROC USED POSB RMS STANDARD/UNKNOWN
B 2 1 163 T S 1 2TO TCS/TCU
7 COMPOUNDS PROCESSED, 5 FOUND
COMPOUND >< ————————— SEARCH ————————— X SAT X ———— CMRO ————— :•NO LIB ENTRY REF 'PRED SEL DELTA PEAKS FIT PEAKS PI/6 TOP DELTA PEAKS1 TC 1 -753 767 766 -1 1 831 . 3S2 766 . 12 TC 2 -737 749 750 1 1 990 . 330 750 , 13 TC 3 -737 749 750 1 1 990 . 3S2 750 . 14 TC 4 -733 750 750 . 1 990 . 257 751 1 15 TC 3 -756 768 . , . , 3EO .6 TC 6 -755 767 . . , . 3227 TC 7 -756 768 766 -2 1 987 . 257 765 -1 1
018193
MEAD COnPUCMECI. .iJANTITATION REPORT FILE: TC001460A04
ATA: TC001460A04. TI5/11/83 15.'34: 00AMPLE: 2UL TCDD SAMPLE 01460(5/3/83) ON #4UBMITTED BY.' 04 ANALYST: 719
MOUNT-AREA(HOHT) * REF. AMNT/f REF, AREA!HCHTI* RESP, FACT*ESP. FAC, FROM LIBRARY ENTRY
NO NAME1 »13C12-2i 3i 7, 8-TCDD
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NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT1 332 766 17:09 1 1, 000 A BB 2106650. 200,000 PC 73. 792 320 750 16i 48 1 0. 979 A BB 17664«, 24.777 PC/UL 9. 143 322 730 16:4B 1 0, 979 A VB 1B6304. 21,269 PC/UL 7. BS4 257 751 16:49 1 0,980 A BV 73616, 21. 341 PC/UL 7.875 NOT FOUND6 NOT FOUND7 257 765 17:08 1 8. 999 A W 12096, 3,6£1 PO/UL 1, 34
0 RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R, FAC R, FAC(L) RATIO1 17:05 1,00 1.000 1,00 200.00 200.60 1,000 1,000 1,002 16:47 1, 00 0. 976 1, 00 24,73 200. 00 0. 084 0, 677 0, 123 16:35 1, 01 0, 976 1. 00 21,29 200, 00 0, OBS 0, 831 0, 114 16(37 1,01 0,977 1,00 21,34 200,00 0,035 0,327 0,115 17:01 1,001 200,00 0,5296 17:00 1.000 . 200.00 0,7147 17:01 1, 01 1, 001 1, 00 3, 62 200. 00 0, 006 0, 317 0. 02
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Peaks. 0250 Standard Peaks. 0250 Standard
1A Alpha-BHC IB Alptia-BHC2A Beta.BHC 2B Beta-BHC3A fiiniM-BHC 3B Saima-BHC4A Heptachlor Epoxlde 4B Heptachlor EpoxldeSA Alpha-Chlordane SB Alpha-Chlordane6A p.p'-DDE 6B p,p'-DDE7A p.p'-DDD 7B p.p'-DDDBA p,p'-DDT BB Endosulfan Sulfate9A Endosulfan Sulfate 9B p,p'-DDTPeaks. 0266 Standard Ptaks. 0266 Standard
IDA Delta-BHC 10B Dcltl-BHC11A Heptsenior 11B Heptichlor12A Aldrln 12B Aldrln13A Delta-Chlordane 13B Dclta-Chlordane14A Endosulfan 1 14B Endosulfan 115A D1eldr1n 15B D1eldr1n16A Endrln 16B Endrln and Endosulfan 1117A Endosulfan 11 17B Endrln Aldehyde1BA Endrln Aldehyde
01819730
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018200
DETECTION LIMIT SUMMARY FORVOA OF HAZARDOUS SUBSTANCE LIST COMPOUNDS
Head CoinpuChem*
Compound l.D.Bromochloromethane (IS)ChloroetnaneVinyl ChlorideCnloroethaneBromometnaneAcroleinAcrylonltrlleMetnylene ChlorideTricnlorofluorometnane1,1-Dlchloroetnylenel,l-t)icnloroetnane1,2-Trans-DlcnioroetnyleneChloroform1,2-Plcnloroetnane1,1,1-TrlcnloroetnaneCarbon tetracniorldeJromodlcnlorometnane1,4-DicnloroDutane (15)1,2-DlcnloropropaneTrans-1.3-D1cnloropropyleneTMcnloroethyleneBenzeneI1s-Ij3-D1cnloropropeni!1.1.2-Trlcnloroetnane1, 2-D1oromochlorometnaneBromoform1,1,2,2-Tetracnioroetnylene1,1,2,2-TetrachloroetnaneTolueneCnlorooenzeneEtnyloenzene2-Cnloroetnyl vinyl ether"4-1,2 Picnioroetnane (Surr,)"1U- Benzene (Int.Std.)da • Toluene (Surr.)Acetone2-Butanone4-Metnyl.2-Pentanone2-HexanoneCaroon disulfideVinyl acetateStyrene0-Xylene
Low Level MaterDetection Limit
(ug/1)*
5bbb
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bbb5b5b5bb
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1002001001001010bb
Low Level SolidDetection Limits
(ug/kg)*
2.52.52.52.550502.52.52.52.52.52.52.52.52.52.5
2.52.52.52.55.02.52.52.52.52.52.52.52.52.5
50100bO50b52.52.5
Medium LevelDetection Limits
(ug/g)*
bb55
100100
bbbbbbbbbb
bbbb10bbbbbbbbb
10020010010010
—— ID ————b5
3 x StandardDeviation
ng on-column
111248362123434223
41242
1132111111
19830132bZ .2
"Estimated MDL (J0n "•*3-S1gma DL
018201
DETECTION LIMIT SUMMARY FORSEMIVOLATILE HAZARDOUS SUBSTANCE LIST COMPOUNDS
Compound I.D.
_"3-PHENULN-NITROSO
(ISDIME HYLAM1NE
PHENOLANILINEfclSfi-CHL2-CHLOHOP1,3-0 CH.,4-D CHL.21) CHL
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BENZYL ALCOHOLBIS 2-CHLOROISOPROPYLJETHER2-METHYL 'HEXACHLDR4-METHYLP
HENULdETHANEHENOL
2-FLUORUPHENOL (Surr.)PENTAFLUOKOPHENOL (Surr.)°b- 'HENUL<>b-<ITROJDECAFLUU12-FLUOROA2-FLUORO)<l8- NAPH"N-fi "KOSONITROBENZISOPHORU12-NITROTM2 4-DlfliTIB S(2-C L2,4-DICHl,2,4-TRH' -CHLOROABENZOIC AlHEXACH .OKiP-CHLO IU-1
Surr)EIZENE (Surr.)UIIPHENYL (Surr.)NILINE (Surr)IPHENYL (Surr)HALENE (IS)•DI-N-PROPYLAMINE:NE'.NO.1YLPHENOLIRJiTHOXYlMETHANE)RO 'HENOLHLOROUENZENELINE1)
Bl) ADIENEi-CI ESOL
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Head CompuChem*Low Level MaterDetection Limit
(ug/1 )*
2020202020202020204040202020
•40202040204020201UU20020'0'020202020202040
Low Level SolidDetection Limit
(ug/kg)*
400'00'00'00'00400400400400BOO800400400400
80D400400BOO40080040040020DU4000400BOOaoo400400400400400400BOD
Medium LevelDetection Limit
(ug/g)*101010101010101010zo20101010
2010102010201010t)U100102)2),001010101020
•Estimated MDL V**3-S1gma DL
3 x StandardDeviation**
ng en-column
341064b4t4B343
84322fi5527101043710436b'4
G°3*t
DETECTION LIMIT SUMMARY FORSEMIVOLATILE HAZARD!OUS SUBSTANCE LIST COMPOUNDS
Mead CompuChem*
Compound I.D,2,4-DINlTROTOLUENE2-NITROANILINE3-NITROANILINED1BENZOFURAN4-N1TROANIL1NE2.4,5-TKICHLQROPHENUL"10-PHENANTHRENE (IS)ftCENAPHIHENE2.4-D1NITROPHENOL4-NITRUPHENOLFLUURENE4-CHLOROPHENYL PHENYL ETHERUIETHYLPHTHALATE4.SDINITRO-0-CRESOL01PHENYLAMINE (N-NITR050)4-BROMUPHENYt PHENYL ETHERMEXACHLUROBENZENE
IPHENANTHRENEANTHRACENEFLUURANTHENEPYRENE1 ,2-UIPHENYLHYDRAZINE (AZOBENZENEDI-N-BUTYLPHTHALATEPtNTOLUROPHENOLa12-CHRYSENE (IS)BtNiUIAlflNTHRACENECHRYSENt3,3'«D1CHLUKOBENZ1DINEBUTYLBENZYLPHTHALATEBIS( 2-ETHYLHEXYL JPHTHALATEDl-N-utlTYLPHTHALATEBtNZlulHE•BENMA1 PYRENEiNDENui: ,2.3-C.DlPYREhE 'UlbENZU(A.H ANTHRACENEUENAHG.H.l PERYLENEJENZO(B)FLUORANTHENEBENZO(K)FLUORANTHENE•Estimated MOL " " '
Low Leviil MaterDetection Limit' (UQ/D*
4020020020200ZOO
2010010U2020204020202020202020402040
20204020202080'0^040 "40
Low Level solidDetection Limit
(ug/kg)*8004000400040040004000
. 40020004000400400400BOO400400400400400400400BOO400BOO
400400BOO400400401)1600BOOBOOBOD800
Medium LevelDetection Limit
(ug/g)*2010010010100100
10501001010102010101010101010201020
1010201010104020202020
4 x Standard.Deviation**
ng on-column
8199355
47
11454214696b963
1310
108204166
>209
'108B7
>20
**3-S1gma CL
000942
30
I ' '\
DETECTION LIMIT SUMMARY FORPESTICIDES HAZARDOUS SUBSTANCE LIST COMPOUNDS
Mead CompuChem*
Compound I.D.ALPHA BHC
BETA BHC
DELTA BHC
HEPTACHLOK EPOXIDE
CHLURODANE
DUE
DDU
DOT
ENDOSULFAN SULFATE
(iAMMA BHC
HEPTACHLOR
GAMMA CHLORDANE
ENUUSULFAN 1
ENDOSULFAN 11
ALUK1N
DIELDH1N
ENDR1N
TCDD
Low Level MaterDetection Limit
(ug/D*0.10.10.10.10.10.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.002
Low Level SolidDetection Limit
(ug/kg)*4.04.04.0
4.0 •4.0
4.04.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
4.0
0.08
Medium LevelDetection Limit
(ug/g)*0.010.010.010.010.010.010.01
0.01
0.01
0.01
0.01
0.010.01
0.010.01
0.01
0.01
0.002
3 x standardDeviation**
ng on-column0.0019U.0030
0.0008
0.0013
0.0008
0.0007
0.0062
0.0136
0.0091
0.0023
0.0027
0.0025
0.0039
0.0126
0.0032
0.0043
0.0082
•Estimated MBL•**3.S1gma DL
