ATIACHMENT 4 VALIDATION PARAMETERS SUMMARY TABLES

VALIDATION PARAMETERS SUMMARY FOR CARS 11 (1983) HYDROGEN SULFIDE

VALIDATION PARAMETERS Stack ID 10810 15110 15210 15310 15410 15510 16210 16510 16610

SAMPLING EQUIPMENT Field qas meter pre- and oost-test Y not within {+/-) 5%? V V V V V V V V V

.

SAMPLING PROCEDURES .•.. ' ' . · .

Sample time < 10 minutes? Indication of leaks? y V V V V V V V y

Reaqent blank not conducted daily? R R R R R R R R R .IMPINGER SOLUTIONS

Hydrogen peroxide (H2O2) not used? Cadmium sulfate {CdS) not used? ANALYSIS METHOD I

0.01 n sodium thiosulfate solution not used for titration? Iodine solution not used?

R R

A-Not reported RF-Runs do not pass check

V-Values not provided RN-Runs could not be checked

N-Not conducted PF-Points do not pass check

P-Not provided PN-Points could not be checked

Y-Failed check Blank Cells - Indicates check passed

4-1

VALIDATION PARAMETERS SUMMARY FOR CARB 12 (1986) INORGANIC LEAD

VALIDATION PARAMETERS Stack ID 15410 15510 15910 16310 63310

SAMPLE LOCATION .•

Averaoe absolute value of swirl anales >10%? V V V V Stack diameter < 12 inch? Stack area < 113 inch sauared? Method 1 not used?

V SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? Pre- and post-test meter Y not within (+/·l 5%? N N V V Pitot tube semi-annual calibration sheet included? p p p p

SAMPLING PROCEDURES Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaae? lsokinetic variation <90 or > 110%? FIELD REAGENT BLANK Not conducted on 2 filters & 0.1 N HNO3? Not used to correct samoles?

y y

y y

A y y

ANALYSIS METHOD Atomic absorption spectrometrv not used? y y

Analvsis not conducted in triolicate? y y y y

A-Not reported RF-Runs do not pass check V-Values not provided RN-Runs could not be checked N-Not conducted PF-Points do not pass check P-Not provided PN-Points could not be checked Y-Failed check Blank Cells - Indicates check passed

4-2

VALIDATION PARAMETERS SUMMARY FOR GARB 15 (1983) HYDROGEN SULFIDE

VALIDATION PARAMETERS Stack ID 16010

SAMPLING PROCEDURES .··· . Indication of leaks? V Sample line loss not conducted for post-test? Sample not corrected for < 20% loss? Samole corrected for > 20% loss?

R R R

ANALYSIS METHOD . . .

GC/FPD not used?


4-3

VALIDATION PARAMETERS SUMMARY FOR GARB 101A (1986) fv'EFO,fl'(

VALIDATION PARAMETERS Stack ID 16010 16510 60110 62310

SAMPLE LOCATION Averaae absolute value of swirl anales >10%? V V V V Stack diameter < 12 inch? Stack area < 113 inch sQuared? Method 1 not used? R SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V V Pre- and Dost-test meter Y not within (+/-) 5%? V V V V Pitot tube semi-annual calibration sheet included? p p p

SAMPLING PROCEDURES ·. .

Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaae?

V V

lsokinetic variation <90 or > 110%? V Filter temDerature not between 106 and 134 dearees, R y R R Flow rate > 28 liter Der minute (1 cfml? V V V V FIELD REAGENT BLANK Not conducted once per test? Not used to correct samples? y

R R y

.

ANALYSIS METHOD Atomic absomtion SDectrometrv not used? Combined analvsis not used? y R y y

R-Not reported RF-Runs do not pass check V-Values not provided RN-Runs could not be checked




4-4

VALIDATION PARAMETERS SUMMARY FOR CARB 104 (1986) BERYLLIUM

VALIDATION PARAMETERS Stack ID 10110

.

1111 0 12810 14210 16610 43510 62410 .SAMPLE LOCATION

Averaae absolute value of swirl anQles >10%? V V V V V V Stack diameter < 12 inch? Stack area < 113 inch souared? Method 1 not used? R SAMPLING EQUIPMENT

~

Variation in nozzle diameter > 0.004 inch? V V V y V Pre- and post-test meter Y not within (+/-) 5%? V V V V V Pilot tube semi-annual calibration sheet included? p p p p p

SAMPLING PROCEDURES .

Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of averaae?

3RN

lsokinetic variation <90 or >110%? 1RF 1RF Flow rate < 0.5 or > 1 elm? V V 3RF V V FIELD REAGENT BLANK Not conducted for acetone? Not used to correct samples?

R R y y

R y

R y

R y

R R

ANALYSIS METHOD .

Atomic absomtion soectrometrv not used? R y R

A-Not reported RF-Runs do not pass check V-Values not provided RN-Runs could not be checked




4-5

VALIDATION PARAMETERS SUMMARY FOR CARB 106 (1983) VINYL CLORIDE

VALIDATION PARAMETERS Stack ID 13910 43310

ANALYSIS METHOD .• •.

GC/FID not used? R R Analvsis date not within 72 hours from collection? y y

3-point calibration curve not conducted daily or before and after test? Percent difference > 5%?

R V

R V


4-6

VALIDATION PARAMETERS SUMMARY FOR CARB 410A (1986)

VAI.JDATION PARAMETERS Stack ID

10310 10410 10510 10610 10710 10810 10910 11010 11110 11210 11310 11410 11510 11610 11710 11810 11910 12010 12110 TEDLAR BAG CONTAMINATION CHECK Nol conducted for all baas? R A A A

LEAK CHECK Not conducted before and after each test? A A A R R A R A A R R A R R R

,,ANALYSIS METHOD FID not used for high concenlrations (60ppb to .01 )?

PIO not used for low concentralions (1.0 to 1000 oob)?

y y

y y

y y

y y

Analvsis date not within 96 hours from collection?

A-Not repor1ed RF-Runs do not pass check




Y-Fa1led check Blank Cells • Indicates check passed

4-7


VALIDATION PARAMETERS Slack ID 12210 12310 12410 12510 12610 12710 12810 13210 13310 13410 13510 13810 13910 14210 14310 14410 14510 14610 15110

TEOLAR BAG CONTAMINAllON CHECK . .

R . .

Not conducted for all baas? R RR R

LEAK CHECK Not conducted before and aher each test? R R R R R

.

R R R R R R y y R R ANALYSIS METHOD .

..

FID not used for high concentrat1ons (60ppb to .01)? PID not used for low concentrations f1.0 to 1000 oob\?

y y

y y

y y

R R

y y

y y

y y

y y

y y

Analvsis date nol within 96 hours from collection? y y y y

A-Not repor1ed RF-Runs do not pass check

V-Values not provided AN-Runs could not be checked



Y-Fa1led check Blank Cells - Indicates check passed

4-8


VALIDATION PARAMETERS

TEDLAR BAG CONTAIIINAllON CHECK

Not conducled for all bans?

LEAK CHECK Not conducled before and aher each test?

ANALYSIS METHOD .~:

FID not used for high concentrations (60ppb to .01 )?

PIO not used for low concentrations 11.0 to 1000 nnb\? Analvsis date not within 96 hours from collection?

15210 15310 15610 15710

y y

y

AF-Runs do not pass dleck RN-Runs could not be dlecked PF-Points do not pass check

PN-Points could not be checked

15810 15910

A

A R

y y

y y

Stack ID 16410 16710 17210 17310

' '

A R A

R

y y y

A

17410 17510 17710 17810 41110 41410 41510 41810 42310 ~

,'

R A y A A R R

A R R R A

y y y y A R y y y y A A

y y A R

A-Not reported V-Values not provided N-Nol conducted P-Not provided Y-Fa1led check Blank Cells - Indicates check passed

4-9


VALIDATION PARAMETERS Slack 10 42510 42710 43310 43410 60410 60510 60610 62310 62410 62810 63010 63310 63410 63610 63710 63810 63910 64110 42610

TEDLAR BAG CONTAMINATION CHECK .. .

Nol conducied for all baas? R R R R R R R R R R R R R R R R R A R LEAK CHECK Not conducted before and aNer each test? R R R R R R R R R R R

I R R R R A y

.ANALYSIS IIIETHOO ..

. .

FID not used tor high concentrations (60ppb to .01}? PIO not used for low concentrations l1.0 to 1000 oobl?

y y

y y

y y y

y y

y y

y y

R R

Analvs1s date not within 96 hours from collection? y y R


V-Values not provrded RN-Runs could not be checked N-Nol conducted PF-Points do not pass check


Y-Failed check

Blank Cells - Indicates check passed

4-10

VALIDATION PARAMETERS SUMMARY FOR GARB 421 (1987) HYDROGEN CHLORIDE


SAMPLE LOCATION AveraQe absolute value of swirl anQles >10%? Stack diameter < 12 inch? Stack area < 113 inch SQuared? Method 1 not used? SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? Pre- and post-test meter Y not within (+/-) 5%? Pilot tube semi-annual calibration sheet included? SAMPLING PROCEDURES Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of averaQe? lsokinetic variation <90 or > 110%? FIELD REAGENT BLANK Not collected once per test?

Stack ID 10010 1011 0 13210 13310 13610 13910 15710

V V V V V V

y .. ..

V V V V V V N N N N N N V

p p p p p

V 2RF V

V 1RF N

R R Not used to correct sample oeaks on the chromatoQraph R R y y y R IMPINGER SOLUTIONS Biocarbonate (NaHCO3) not used? Sodium carbonate (Na2CO3) not used? Water not used? ANALYSIS METHOD Ion chromatoaraohv not used? Lab spike not conducted for 10% of samples? Duplicate not conducted for each sample? Percent difference > 5%?

y y

R R R R V V V V

RF-Runs do not pass check RN-Runs could not be checked PF-Points do not pass check PN-Points could not be checked

4-11

R R y R V V V

16010 42710 60110 60310 60510

V V V V V

.

V V V V V N V p p p p p

V V V 1RF V

R R R R R

R

R y y

R R y y y

V V 2PF

A-Nol reported V-Values not provided N-Not conducted P-Not provided Y-Failed check Blank Cells - Indicates check passed

VALIDATION PARAMETERS SUMMARY FOR CARB 421 (1991) HYDROGEN CHLOOIDE

VALIDATION PARAMETERS Stack ID 43110 43310

SAMPLE LOCATION Averaae absolute value of swirl anoles >10%? V V Stack diameter < 12 inch? Stack area < 11 3 inch squared? Method 1 not used?

,, .· .SAMPLING EQUIPMENT .

Variation in nozzle diameter > 0.004 inch? V V Pre- and post-test meter Y not within (+/-) 5%? Pilot tube semi-annual calibration sheet included? p SAMPLING PROCEDURES .

Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of average? lsokinetic variation <90 or >110%? V Number of sample runs < 3? Sample time not reported for each run? Samele time < 60 minutes? FIELD BLANK Not collected per test? R Used to correct sample peaks on the chromatograph? R Contamination > 20% of anv run?

R R

IMPINGER SOLUTIONS Biocarbonate (NaHCO3) not used? A Sodium carbonate (Na2CO3) not used? A Water not used? A R

.ANALYSIS METHOD .

Ion chromatoaraohv not used? Lab spike not conducted prior, daily, and alter every 40 samples? A A Percent recovery < 95% or > 105%? V V Duplicate not conducted for 10% of all samples? A A Percent difference > 5% STD? V V

A-Not reported V-Values not provided N-Not conducted P-Not provided Y-Failed check Blank Cells - Indicates check passed


4-12

VALIDATION PARAMETERS SUMMARY FOR CARB 422 (1987) VOLTILE HALOGENATED ORGANIC COMPOUNDS

VALIDATION PARAMETERS Stack ID 16510 17610 17710 17810

TEDLAR BAG CONTAMINATION CHECK ...

Not conducted for all bags? Levels not reported?

A A

A A

. ; .LEAK CHECK ,: ,,, :>; •f .·. ; .; .;;/,: ., t,· ·'. . . ;

Not conducted before and after each test? Leak rate > 5% of sample rate? A

·.

ANALYSIS METHOD ··. .

GC not used? Analvsis date not within 24 hours of collection? A y

A-Not reported RF-Runs do not pass check V-Values not provided RN-Runs could not be checked N-Not conducted PF-Points do not pass check



4-13

VALIDATION PARAMETERS SUMMARY FOR CARS 422 (1991) VOLTILE HALOGENATED ORGANIC COMPOUNDS

VALIDATION PARAMETERS Stack ID 15610 17210 17310 17410 17510 41810 62610 62611 62612 62613

y

TEDLAR BAG CONTAMINATION CHECK Not conducted for all bags? Levels not reported?

R R

R R

R R

R R

R y y y y

FIELD BLANK . . ' ·, '

Not conducted once per test? Used to correct sample? Blank > 20% of the stack samples?

R R R

R R R

LEAK CHECK .

.

Not conducted before and after each test? Leak rate > 5% of sample rate?

R R R

R R

y

R

y

R

y

R

y

R FIELD SPIKE .

.

Not collected once per source? R R y y y y

ANALYSIS METHOD GC not used? Analysis date not within 72 hours from collection?

R V

Duplicates not conducted once per sample? Values > 3 x RSD?

R V 3PN 3PN 3PN V

y y y y






4-14

VALIDATION PARAMETERS SUMMARY FOR GARB 423 (1987) INORGANIC ARSENIC

VALIDATION PARAMETERS Stack ID 12910 13010 13610 13910 14610 15710 16310 60610

SAMPLE LOCATION Averaae absolute value of swirl anales >10%? V V V V V V V V Stack diameter < 12 inch? Stack area < 113 inch sauared? Method 1 not used? SAMPLING EQUIPMENT

.··. .

Variation in nozzle diameter > 0.004 inch? V V V V V Pre- and oost-test meter Y not within (+/-) 5%? N N N V Pilot tube semi-annual calibration sheet included? p p p p p p p p

SAMPLING PROCEDURES Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaae? 1RF lsokinetic variation <90 or > 110%? Filter temperature not between 107 and 135 deorees'i R R R R R y R Flow rate > 28 liter oer minute (1 cfm)? 3RF 1RF 2RF FIELD REAGENT BLANK Not conducted for two filters and 0.1 N NAOH? Not used to correct samole?

R y

R y y

y

ANALYSIS METHOD Atomic absomtion soectrometrv not used? Combined analvsis used? y y






4-15

VALIDATION PARAMETERS SUMMARY FOR CARS 424 (1987) INORGANIC CADMIUM

VALIDATION PARAMETERS Stack ID 13810 16410 60110 60410 63410

SAMPLE LOCATION .

AveraQe absolute value of swirl anales >10%? V V V V Stack diameter < 12 inch? Stack area < 113 inch squared? Method 1 not used? SAMPLING EQUIPMENT .

Variation in nozzle diameter > 0.004 inch? V V V V Pre- and post-test meter Y not within (+/-) 5%? V V V Pitot tube semi-annual calibration sheet included? p p p p SAMPLING PROCEDURES

.

.· . · .

Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaQe? lsokinetic variation <90 or > 110%? FIELD REAGENT BLANK Not conducted for two filters and 0.1 N HNO3? R R R R R Not used to correct samole? y y y y

ANALYSIS METHOD Atomic absorption spectrometry not used? R y

Not conducted in triplicate? R R R R R


4-16

VALIDATION PARAMETERS SUMMARY FOR CARB 425 (1987) TOTAL AND HEXAVALENT CHROMIUM

VALIDATION PARAMETERS Stack ID 13610 14210 14310 14610 15710 16010 42710 43510 60210 60310 60810 63010 63310 63410 63810 64010

SAMPLE LOCATION AveraQe absolute value of swirl anflles >10%? V V V V V V V V N V V V V V V V Stack diameter < 12 inch?

Stack area< 113 inch snuared?

Method 1 not used? R

SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V N V V V V V V V y V V V V V Pre- and oost-test meter Y not within (+/-) 5%? N N N N V V V V N V N Pilot tube semi-annual calibration sheet included? p p p p p p p p p p p p p p


Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of averaoe?

1RN 1RN 1RF

lsokinetic variation <90 or >110%? V 2Rf 1RN

REAGENT BLANK .

Not conducted once per sample batch? Used to correct samole?

R R

R y y

ANALYSIS METHOD Matrix spike not conducted once per test (Hexavalent Chromium)?

Percent recoverv > 10%?

R

V R V

R V

R V

y y

V 1PF

Matrix soike not conducted dailv ITotal Chromium\? y R R y y

Ouolicates not conducted for everv 10 samnles lTotal Chromium\? R y R R R R y y

RF-Runs do not pass check

V-Values not provided A-Not reponed

RN-Runs could not be checked



Y -Failed check Blank Cells - Indicates check passed

4-17

VALIDATION PARAMETERS SUMMARY FOR CARB 425 (1990) TOTAL AND HEXAVALENT CHROMIUM

VALIDATION PARAMETERS Stack ID 10010 10110 10310 10410 10510 10610 11110 12910 13010 13810 13910 15410 15510 15810 15910 16210 16310 16410

SAMPLE LOCATION Averane absolute value of swirl annles >10%?

Stack diameter < 12 inch? Stack area < 113 inch snuared? Method 1 nol used?

V V y V V V V V V V V V V V V

R R R

SAMPLING EQUIPMENT Variation 1n nozzle diameter > 0.004 inch? Pre- and □ ost-tesl meter Y not within t+/-\ 5%? Pilot tube semi-annual calibration sheet included?

V V V V V V V V

VN N N N N N N V V V p p p p p p p p p p p p p p p

SAMPLING PROCEDURES Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rale > 0.02 elm or 4% of averane? lsokinelic variallOn <90 or >110%?

V V

V

V 3RF 1RF

PROBE PROOF Not conducled per probe? Total chrome > detection limit?

R V

R V

R

V

R V

R V

R V

R

V

R V

R

V R V

R

V R V

R V

R V

R

V 3PF R V

REAGENT BLANK Nol conducted once per sample batch? Nol used to correct samnle?

R

R

R R

R

R

R R

R y y y y

y y

y y y

R

R

y y

ANALYSIS METHOD .

·.

Matm: spike not conducted once per test (Hexavalent Chromium)? Percent recoverv > 10%?

R V

R V

y R V

R V

R V

y R V

R

V

y

V

R

V R

V

R V

R V

R

V

R V

y

V 1PF Malnx soike nol conducted dailv tTotal Chromium\? A R R R R R R R y

Ouohcates not conduc1ed for everv 10 samoles ITolal Chromium)? R R y R R y R A y y R R R R y y

A-Nol reported RF-Runs do not pass check


N-Nol conducted PF-Points do not pass check

P-Nol provided PN-Points could not be checked


4-18

VALIDATION PARAMETERS SUMMARY FOR GARB 425 (1990) TOTAL AND HEXAVALENT CHRQMIUM


SAMPLE LOCATION Averane absolute value of swirl anales >10%? Stack diameter < 12 inch? Stack area < 113 inch snuared? Method 1 not used? SAMPLING EOI.IPMENT Variation in nozzle diameter > 0.004 inch? Pre- and nosl-tesl meter Y not within 1+/-\ 5%? Pilot tube semi-annual calibration sheet included? SAMPLING PROCE~ ,ne~

Pre-test leak rate > 0.02 ctm or 4% of average? Posl-test leak rate > 0.02 cfm or 4% of averane? lsokinetic vanalion <90 or > 110%?

PROBE PR""" Not conducted per probe? Total chrome > delectIon limit? Dl<&GENT 111.ANK Not conducted once per sample batch? Not used to correct samnle?

ANALYSIS METHOD Matrix spike not conducted once per test (Hexavalent Chromium)?

Percent recoverv > 1 0%? Matrix s0Ike not conducted dailv ITotal Chromium\? Ouolicates not conducted for everv 10 samnles fTotal Chromium)?

Stack ID 16510 16610 41610 42010

V V V N

A

V V V V p p

V 1RF

V 1RF

V V

R R R R

V V V V

R R

R R R

R R R

V V V 1PF

R R A A A

42110

N

V

.

1RF

1RF

R V

R R

1PF R A

42410 42510 42910 43010 43110

V V V R

R -· A

V V V p p

V V V V V

A y R R A V V V V

A R A A A A y A R

R y A R

V V 1PF V V R R R R A R R R

43210 43310 43410 60110 60410 60510 60610 60710

V V V V V V V

R R

V V V V V V V V p p p p p p p

V V 1RN V V 1RN

1RN

A R R R R R R A V V V V V V V V

A R R R R R y

R R V V 1PF2PN 1PF

A R R A R


V-Values not provided A-Not reported

RN-Runs coukj not be checked

N-Nol conducted PF-Points do not pass check

P•NOI provided PN-Poinls could not be checked

Y •Failed check Blank Cells • Indicates check passed

4-19

VALIDATION PARAMETERS SUMMARY FDR GARB 425 (1990)

TOTAL AND HEXAVALENT CHADMILJM


V

64110

V

SAMPLE LOCAT10N Averaae absolute value ol swir1 anales >10%/?

Slack diameter< 12 inch? Slack area < 113 inch snuared?

V V V V V V V V V V V V V

Method 1 not used?

SAMPLING EQUIPMENT

VVariation in nozzle diameter > 0.004 inch? Pre- and oost-test meter Y not within(+/-) 5%?

V V V V V V V V V V V V V V V N V V

Pitot lube semi-annual calibration sheet induded? p SAMPU'"" PROC~N •RES . .

Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 c1m or 4''/o of averaae?

1RF

1RF 1RF

1Rf

lsokinetic 11arialion <90 or >110%? 1RF

PROBE PROOF Not conducied per probe?

Total chrome > deteciion limit?

R V

R V

R

V R V

R

V A V

R V

R V

R

V R V

R V

R V

R V

R

V A V

A V

R V

R V

R V

REAGENT BLANK Not conducted once per sample batch?

Not used to correci samole? A R R R R R R R R R R R R

y

y y y

y

y y

ANALYSIS IIE'nllVl Mallix spike not conducted once per test (Hexavalent Chromium)?

Percent recoverv > 10%? R V

Matrix soike not conducted dailv (Total Chromium)? Duolicates not conducted tor eveN 10 samoles (Total Chromium)?

y y y y y y y y y y y y y y y y y y y y y y y y y y y y y y

A-Not reponed RF-Runs do not pass check


N-Not conduC1ed PF-Points do not pass check


Y-F ailed check

Blank Celts • lndica1es check passed

4-20

VALIDATION PARAMETERS SUMMARY FOR CARB 428 (1988) PCDD/PCDF

VALIDATION PARAMETERS Stack ID 13610 14210 14610 15710 42710 60310

SAMPLE LOCATION AveraQe absolute value of swirl anales >10%? V V V V V V Stack diameter < 12 inch? Stack area < 113 inch squared? Method 1 not used? SAMPLING EQUIPMENT · · .. .

. . ·.

.

Variation in nozzle diameter > 0.004 inch? V V V V V Pre- and oost-test meter Y not within (+/-\ 5%? N N N V V Pilot tube semi-annual calibration sheet included? p p p p p p

SAMPLING PROCEDURES '

Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of averane? lsokinetic variation <90 or > 110%? Samnle runs < 3? Samole time < 3 hours? 3RF

FIELD BLANK Not conducted once per test? Used to correct samole? SURROGATE STANDARDS Not conducted once per run? y R R R Percent recovery< 60 or> 140% (37C1-2,3,7,8-TCDD)? R R R R Percent recoverv < 60 or> 140% 113C-1,2,3.4.6,7 8-HoCDFl? R R R R

LABORATORY CONTROL SPIKE Percent accuracv < 60 or > 140 % ? V V V V V V

INTERNAL STANDARDS ..

Not conducted once per sample? R R R

Percent recoverv < 60 or > 120%? R R SPF SPF R

RF-Runs do not pass check A-Not reported V-Values not provided RN-Runs could not be checked

PF-Points do not pass checkN-Not conducted PN-Points could not be checkedP-Not provided


4-21

VALIDATION PARAMETERS SUMMARY FOR GARB 428 (1990) PCDD/PCDF

VALIDATION PARAMETERS Stack ID 10010 1 011 0 13710 13910 41310 42410 42510 42610 43110 60110 60510

SAMPLE LOCATION .

Averaae absolute value of swirl anales >10%? V V V V V V V V Stack diameter < 12 inch? Stack area < 113 inch sauared?

R R

Method 1 not used? SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V V V V V V V Pre- and eost-test meter Y not within I+/-\ 5%? N N N V V Pilot tube semi-annual calibration sheet included? p p p p p p p



V V

V V

V V

1RF

lsokinetic variation <90 or > 110%? V

Samele runs < 3? Samele time < 3 hours? 1RF

FIELD BLANK Not conducted once per test? Used to correct samele?

R R

A A R

SURROGATE STANDARDS Not conducted once per run? Percent recovery < 60 or > 140% (LAMS)? Percent recoverv < 60 or > 140% /HRMSI?

V 3PN 5PF

LABORATORY CONTROL SPIKE Laboratorv control seike eercent accuracv < 60 or > 140%? 30PN 24PN 24PN 24PN 3PF V 3PF V 45PN 6PF.45PN V

INTERNAL STANDARDS ·.

Not conducted once per sample (LAMS)? Percent accuracv < 40 or > 120%? 13PF

Not conducted once per sample (HAMS)? Percent accuracv < 40 or > 120%?

R V 19PF SPF 18PF

A V

R V


V-Values not provided RN-Runs could not be checked PF-Points do not pass check

A-Not reported

N-Not conducted PN-Points could not be checkedP-Not provided


4-22

VALIDATION PARAMETERS SUMMARY FOR CARB 429 (1989) PAH


SAMPLE LOCATIOH Averane absolute value of swirl annles >10%?

Stack diameter < 12 inch? Stack area < 113 inch snuared?

Method 1 not used? SAMPLING EQUIPMENT .

Variation in nozzle diameter > 0.004 inch? Pre- and cost-test meter Y not within t+/-1 5%? Pitot tube semi-annual calibration sheet included?

SAMPLING PROCEDURES . .

Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averane? lsokinetic variation <90 or > 110%? Samole runs < 3? FIELD BLANK Not conducted once per test? Used to correct samnle?

SURROGATE STANDARDS Not conducted once per run? Percent recoverv < 50 or > 150%? LABORATORY CONTROL SPIKE Percent accuracv < 50 or > 150%? INTERNAL STANDARDS Not conducted once per run? Percent accuracv < 50 or > 150%? ANALYSISIEXTRACTION DATES Analysis date not within 40 days of extraction? Extraction date not within 7 davs of collection?

10010 10110 10210 10310

V V

V V V N N N

p

V V 1RF V V 1RF

R R

R V V

V .

y R 39PN V 28PN

y y


.

Stack ID 10410 10510 10610 10710 10810

V y

R R R .

V V V

p p p p p .

..·

2RF 1RF

.

'.·. .

R V V V V V

1PF 15PF 1PF SPF

10910 1111 0 11210 11310 12210 12710 12810

V V V V V y R y y R y

R .

V V V

p p p p p p p

N N N

y y y

V V V V 1RF V

V V V V V

R R R R V V V 8PF 3PN 4PN V


4-23



SAMPLE LOCATION Averaae absolute value of swirl anales >10%? V V V V V V V V V N V V V V V V Stack diameter < 12 inch?

Stack area < 113 inch sauared?

y

y

Method 1 not used? .SAMPLING EQUIPMENT . .·

Variation in nozzle diameter > 0.004 inch? V V V V V V V V N N V V V Pre- and oost-test meter Y not within (+/-) 5%? N N N N N N N N N N N N Pilot tube semi-annual calibration sheel included? p p p p p p p p p p p p p p p p

SAMPLING PROCEDURES Pre-test leak rate > 0.02 cfm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaoe?

V V

2RF 1RF

lsokinetic variation <90 or >110%? Samole runs < 3?

FIELD BLANK Not conducted once per lest? Used to correct sample?

A A

SURROGATE STANDARDS Not conducted once per run? Percent recoverv < 50 or > 150%?

y

V A V

A V

y

V V 2RF A A

V

y

V A V

A V V

y

V LABORATORY CONTROL SPIKE Percent accuracv < 50 or > 150%? V V V V V V V V V V

INTERNAL STANDARDS Not conducted once per run? Percent accuracv < 50 or > 150%? 4PF 1PF

A V

y

V 3PN A V

y

V

y

V A A

V A V SPF 17PN

A

ANALYSISIEXTRACTION DATES Analysis date not within 40 days of extraction? Extraction date nol within 7 davs of collection? y

A A y y

A A

A A

A A

y

A A A A

A A





Y-Failed check Blank Cells - lndicales check passed

4-24



SAMPLE LOCATION Averane absolute value of swirl anoles >10%?

Stack diameter < 12 inch? Stack area < 113 inch snuared? Method 1 not used? SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? Pre- and oost-test meter Y not within I+/-\ 5%? Pilot tube semi-annual calibration sheet included?

·.

SAMPLING PROCEDURES Pre-test leak rate > 0.02 elm or 4% of average? Post-lest leak rate > 0.02 elm or 4% of averane? lsokinelic variation <90 or > 110%? Samole runs < 3? FIELD BLANK Not conducted once per test? Used to correct samole? SURROGATE STANDARDS Not conducted once per run? Percent recoverv < 50 or > 150%? LABORATORY CONTROL SPIKE Percent accuracv < 50 or > 150%?

INTERNAL STANDARDS Not conducted once per run? Percent accuracv < 50 or > 150%?

ANALYSIS/EXTRACTION DATES Analysis date not within 40 days of extraction? Extraction date not within 7 davs of collection?

15910 16010 16110 16410

V V V V

V V V V p p p

y y

R y

R y

V V V

V V

y R V V SPF 2PF

R R R R


Stack ID 16510 16710 17210 17310 17410

V V V V

. .•·

V V V p p p

V V V

.

R

R R R y y

V V V V V

V

R V 2PF 21PF 1PF

R R

-17510 17710 17810 17910 18010 18110 41010

V V V V V V V y y

..

V V y

V V V p p p p

.. ··

R R R .

y R R y y y

V V V

V

11PF ?PF SPF 11PF 3PF 21PF !PF

y

A-Not reported V-Values not provided N-Not conducted P-Not provided Y -Failed check Blank Cells - Indicates check passed

4-25

VALIDATION PARAMETERS SUMMARY FOR CARB 429 (1989) PAI-I


SAMPLE LOCATION Averaoe absolute value of swirl anoles >10%? V V V V V V V V V V V V V Stack diameter < 12 inch? Stack area < 113 inch sauared?

y y

y y

R R

y y

R R

Method 1 not used? R R SAMPLING EQUIPMENT

. . . . Variation in nozzle diameter > 0.004 inch? V V V V V V V V V V V Pre- and cost-test meter Y not within (+/-) 5%? V V V V V V V V V V Pilot tube semi-annual calibration sheet included? p p p p p p p p p p SAMPLING PROCEDURES . .· ..


V V

V V

V V 1RF 1RF

V V

lsokinetic variation <90 or > 110%? V V Samele runs < 3? FIELD BLANK

. •.· . ..

Not conducted once per test? Used to correct samole?

R R

R R

R R y y

R

SURROGATE STANDARDS •·. , .. ·;.,;<' :

Not conducted once per run? Percent recoverv < 50 or > 150%? V V V V

R V

R V V

R V 3RF V V

LABORATORY CONTROL SPIKE Percent accuracv < 50 or > 150%? V V V V V V V V V V V INTERNAL STANDARDS Not conducted once per run?

Percent accuracv < 50 or > 150%? 18PF SPF 2PF 4P~ 3PN R V

R V

R V

R V 2PF 3PF 23PF 25PF 2PF 4PF 3PF

ANALYSISIEXTRACTION DATES Analysis date not within 40 days of extraction? Extraction date not within 7 davs of collection?

R y

R y

R R y

R R y

R R

R R

R R

R R

R R y

R R

R-Not reported RF-Runs do not pass check





4-26

VALIDATION PARAMETERS SUMMARY FOR CAAB 429 (1989) PAH


"M-"" I Averane absolute value al swirl andes >10¾?

Slack diameter< 12 inch? Stack area < 113 inch sguared? Method 1 not used? 1r-..............

Varialioo m nozzle diameter > 0.004 inch? Pre- and nr,sHest meter Y not w1th1n l ♦ /-l 5"/.?

Pilot lube sem1-annuaI callbrat,on sheet included? SAIi.. ,..,...,

Pre-lest leak rate > 0.02 elm or 4% ol average? Post-test leali( rate > 0.02 elm or 4"/a ol averane?

lsokinetic variation <90 or > 110%? Samole runs < 3? FE1 nBLANK

Nol conducted once per lest? Used to correct samnle?

Nol conducted once per run? Percent reco..erv < 50 or > 1 !)0% '7

LA -KE Percent accurarv < 50 or> 150%? ,,M~&O

Nol conducted once per run? Percent accuracv < !)0 or> 150%?

ANALY n.&TE~

Analysis dale not wilhm 40 days ol extrachon' Exuac11on dale not within 7 davs ol collection?

43510 60110 60310 60410

V V V V

V V V V V V p p p p

JAN

2AF 1Af

y y

A V V V

V JPN V V

A y y

V 27PN V

A A A A A A A

RF-Runs do not pass Check RN-Runs could not be checked PF-Pomts do not pass check PN-Pomls could not be checked

60510

V

p

1Af

V

A V

A A

Stack 10 60610 62310 62410 63010 63110 63210

V V V V V

A

V V V V V V V V

p p p p

2AN lAN

y

3Af V V V

V V V V

V SPF 30PN 2PF 24PN 3PF '4PN

A A A A A A A A A A A

63310 63410 63510 63610 63710 63810 63910 64010 64110 .

V V V V V V V V V y y y

V V V V V V V V V N V

p p p p p p p p p

1Af

V V V V V V V V V

V 45PN JPN V V V V V

SPF '>4PN 24PN 1Pf 1PF 27PN 1PF 27PN tPF 24PN 2PF 24PN 24PN 24PN

A A A A A A A A A A A A

A-Nol reported V-Values not provided N-Nol conducted P-Not provided Y-Falled check Blank Cells Indicates check passed

4-27

VALIDATION PARAMETERS SUMMARY FOR CARB 430 (1989) ALDEHYDES

VALIDATION PARAMETERS Stack ID 10010 10110 10210 10310 10510 10610 11010 11110 11210 11310 11410 11510 11610 11710 11810 11910 12010 12110 12210

FIELD DRY GAS METER CHECK . .

Pre- and oost-test meter Y not within f +/-) 5%? N N N V

SAMPLING PROCEDURES Sample flow not checked per run? Sample flow > 1.0 Umin? Pre-test and oost-test samo\e flow not within 15% 7

2RF 3AN

R V V

R V V 3RN 3RN 3RN

R V V

R

V V

R V V

R V V 3RN 3RN 3AN 3RN 3RN 3RN 3AN 3AN 3RN

Indication of leaks? V V V V V V V V V

FIELD BLANK .

Not conducted once per test? Not conducted on 2 impingers? Used to correct samnles?

R R R

R R

R R

FIELD SPIKE .

Not conducted oer run? 3RF 3RF ANALYSIS METHOD .·

Extraction date not within 7 davs of collection? R

Analvsis date not within 30 davs of extraction? R

Reverse phase HPLC not used? Matrix spike not conducted per test?

Not reported?

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y

R y



N-Not conducted PF·Points do not pass check

P-Not prO\/ided PN·Points could not be checked

Y-Fa1led check Blank Cells - Indicates check passed

4•28

VALIDATION PARAMETERS SUMMARY FOR GARB 430 (1989) ALOEHYOES


FIELD DRY GAS METER CHECK .

Pre- and oost-tesl meter Y not within l+/-l 5%? y N N V V N N N N N N N SAMPLING PROCEDURES Sample flow not checked per run? Sample flow > 1.0 Umin? Pre-test and oost-test samole flow not within 15%? 3RN 3Ff\l 3Ff\l 3Ff\l 3RN 1RF 1Ff\j 3Ff\l 3RN 3RN 3Ffll

3RF 3RN 3Ff\l

R V V 3Ff\l 3ffll 3Ff\l

3RF 3RN

Indication of leaks? V V V V V V

FIELD BLANK . . . . .

Not conducted once per test?

Not conducted on 2 impingers? Used to correct samoles?

R R R R y

y

FIELD SPIKE Not conducied oer run? 3RF 3RF 3RF 3RF 3RF 3RF 3RF 3RF 3RF ANALYSIS METHOD Extraction date not within 7 davs of collection? R R R y y y

Analvsis date not within 30 davs of extraction? R R

Reverse ohase HPLC not used? Matrix spike not conducted per test?

Not reoorted?

R y

R y

R y

R y

R y

y y

R y

R y

R y

R y

R y

R y

y y

y y


V.Values not provided RN-Runs could not be checked


P-Nol provided PN-Points could not be checked


4-29

VALIDATION PARAMETERS SUMMARY FOR CARS 430 (1989)

ALDEHYDES


FIELD DRY GAS METER CHECK Pre- and oosHest meter Y not within (+/-) 5%? N N N N N N N N N V N V V V V SAMPLING PROCEDURES ·.

Sample flow not checked per run? Sample flow > 1.0 Umin? Pre•test and oost test samole flow not within 15%?

3RF 3AN 3RN

1RF

3RN

1RF

3AN 3RN 3RN 3RN 3RN 3RN 3RN

R

V

V

R

V

V

2RF

2RN 3RN V

V --Indication of leaks? V V V V V V V FIELD BLANK . .

Not conducted once per test? Not conducted on 2 impingers? Used to correct samotes?

R y y y

y y

y y

y y

A A A A A R

y y A

A A A R FIELD SPIKE Not conducted oer run? 3AF 3AF 3AF 3AF 3AF 3AF 3AF 3AF 3RF 3AF 2RF 1RF 3RF 3RF 2RF 3RF 3Rf' ANALYSIS METHOD

.

Extrac1ion date not within 7 davs of collection? R R R R R

Analvsis date not within 30 davs of extraction? R A R y

Reverse phase HPLC not used?

Matrix spike not conducted per test? Not reported?

R y

y y

R y

R y

R y

R y

R y

R y

R y

R y

R R y

R y

y y

R y y y





Y-Failed check

Blank Cells - Indicates check passed

4-30

VALIDATION PARAMETERS SUMMARY FOR GARB 430 (1989)

~s VALIDATION PARAMETERS

18110 41010 41110 41210 FIFI n DAV t'!!.as MCTCD ruccK

Pre· and nost-test meter Y not within /+/-\ 5%? V V V

CAUPUNGPR Sample flow not checked per run? A

Sample flow > 1 0 Umin? V V Pre-lest and nost-test samole !low nol within 15°/o? V V

lnd1ca11on of leaks? ...,,neu.NK Not conducted once per test? Not conducted on 2 imp1ngers? Used 10 correct samnles? FIEI O.,...,...,e

Not conducted ner run? ,ANA• vv.1• ME~" EJllraction date not within 7 davs ol collection? Analvs1s dale not within 30 davs of extraction? Reverse nhase HPLC not used? Malm. spike not conducted per test? Not reoorted'i'

y y

A A A

A A y .

3RF

y

R y y

RF-Runs do not pass check RN-Runs could not be checked PF-Points do not pass check PN-Pomts could not be checked

Stack ID 41710 42210 42610 42710 42810 43410 43510 60110

V V V V V V

A A A A A V V V V V V 3RF V V V V V V 3AN V y V y V V

A

A A A A A A A

A A A y A A y

2RF

A R A A R A y

R A A R A R

A R A A R R R y y y y y y

60310 60410 60610 63010 63310 63410 63610 63710 63810 63910 •. .

N

3AF 3AF JAF SRF 3AF 2RF 3RF 3AF JAF JAN 3AN JAN 6RN 6RN 6RN JAN 3AN 3AN 5AN

N N N N N y y N

A A A A A A A A

. .

1AF 2RF 2RF SRF SRF 5AF 1RF 2AF 2AF

y y R y y R

A

y R y y

A-Not repor1ed V-Values not provided N-Not conducted P-Not provided Y-Falled check Blank Cells - Indicates check passed

4-31

VALIDATION PARAMETERS SUMMARY FOR GARB 430 (1991) ALDEHYDES

VALIDATION PARAMETERS Stack ID 10410 10710 10810 10910 13710 15610 16710 16810 16910 17010 17110 17210

CALIBRATION CHECK Not conducted for each rotometer? Calibration sheet not included?

R y

R y

R y

R y

R y

R y

R R

SAMPLING PROCEDURES Sample flow not checked per run? Sample flow > 1.0 Umin? Pre-test and oost-test samole flow not within 15%? 3RN 3RN 3RN 3RN 3RN 3RN

1RN 3RN 3RN

2RN 3RN 3RN

Indication of leaks? V V

Number of samole runs < 3? FIELD BLANK Three blanks not collected per test? Reporting limit not given (sample /field blank < 5)? Samele not corrected (samnle/lield blank > 5l? 3PF

y

2PF 1PF

9PF 3PF

y

3PF

y

3PF

y

3PF

y

3PF

y

ANALYSIS METHOD .

Sampling date not within 2 days of reagent blank check? Extraction date not within 7 days of collection? Analvsis date not within 30 davs of extraction?

R R R R

R R R

R R R

R R R

R R R

R R R

Reverse chase HPLC not used? lmpinQers not analvzed seoeratelv? y y y y y y

Matrix spike not conducted per test? Recoverv not reported?

R y






4-32

VALIDATION PARAMETERS SUMMARY FOR CARB 430 (1991) Al..DEHYDES

VALIDATION PARAMETERS Stack ID 17310 17410 17510 41310 41410 41510 41810 42410 42510 43110 43310 60510 63510

CALIBRATION CHECK ..·

Not conducted for each rotometer? Calibration sheet not included?

R y

R y

R y y

R y

R y

R y

R y

R y y

. ' SAMPLING PROCEDURES ,.·. .

Sample flow not checked per run? Sample flow > 1.0 Umin? Pre-test and oost-test samole flow not within 15%? 3RN 3RN 3RN 3RN

R V V

R V V

R V V 3RN

3RF 3RN

3RF 3RN 3RN

Indication of leaks? V V V V V V

Number of samole runs < 3? FIELD BLANK Three blanks not collected per test? Reporting limit not given (sample /field blank < 5)? Sample not corrected lsamole/field blank > 5\? ANALYSIS METHOD

9PF 3PF 3PF

9PF 3PF 3PF

.

R 5PF

R 3PF

y

3PF

y

3PF

y

3PF 2PF

Sampling date not within 2 days of reagent blank check Extraction date not within 7 days of collection? Analvsis date not within 30 davs of extraction?

R R y

R R R R R R

R R

R R R

R R R R

R R R

R R R

Reverse ohase HPLC not used? lmoinoers not analvzed seoeratelv?

R y y y R y R y y y

Matrix spike not conducted per test? Recoverv not reoorted?

R y

R y

R y

RF-Runs do not pass check RN-Runs could not be checked

A-Not reported V-Values not provided N-Not conducted PF-Points do not pass check

PN-Points could not be checkedP-Not provided Y-Failed check Blank Cells - Indicates check passed

4-33

VALIDATION PARAMETERS SUMMARY FOR GARB 433 (1989) NICKEL

VALIDATION PARAMETERS Stack ID 15110 15210 15310 15510 15810 16210 42510 43410 60710 63010 63810

SAMPLE LOCATION Averaae absolute value of swirl anales >10%? V V V V V V V V V Stack diameter < 12 inch? Stack area < 113 inch souared? Method 1 not used? R R R R R SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V V Pre- and post-test meter Y not within /+/-\ 5%? V V V V V V V V V Pilot tube semi-annual calibration sheet included? p p p

SAMPLING PROCEDURES Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 elm or 4% of averaoe?

1RN 1RN 2RN

1RN 1RN

V V

V V

V V

lsokinetic variation <90 or > 110%? 2RF FIELD REAGENT BLANK Not conducted for two filters and 0.1 N HNO3? Not used to correct samole?

y y

y y

y y

R y

R R

R y

R y

R R y

R y

ANALYSIS METHOD Atomic absorption soectrometrv not used? y y y y R y y y y

Not conducted in triplicate? R

R-Not reported RF-Runs do not pass check





4-34

VALIDATION PARAMETERS SUMMARY FOR EPA MMT (1989) lRACE METALS


SAMPLE LOCATION .

Averaae absolute value of swirl annles >10%? V V V V V V V V V V V V V V V V V

Stack diameter < 12 inch? Stack area < 113 inch snuared? Method 1 not used? SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V V V V V V

Pre· and nost-test meter Y not within l+/-l 5%? N N N N N N N N N N V N V V

Pitot tube semi-annual calibration sheet included? p p p p p p p p p p p p p p p

SAMPLING PROCEDURES : ·.... Pre-test leak rate > 0.02 elm or 4% of average? PosHest leak rate > 0.02 cfm or 4% of averaae?

1RF 1RF

Isokinetic variation <90 or > 110%? 1RF

FIELD REAGENT BLANK y y

Not collected once per test? Not used 10 correct samoles? y y y y y y

y y

y y

y y

y y y y y y y y y

DUPLICATES VPercent difference > 5% (ICAP)?

Not conducted per run (GFAAS)? Not conducted ner run fCVAASl?

V A A

V A A

V A A

V A A

V A A

V A A

V V V R A

V A A

V A A

V

A

V

A

V R

V A A

V V 2RF

A

MATRIX SPIKES

V Not conducted on front- and back-hall (GFAAS)? Percent recoverv < 75 or > 125%? Not conducted on one nitric impinger (CVAAS)?

Percent recoverv < 75 or > 125%?

A

V V

A V V V

R V

R V

A V

R V

R V

A V

A

V

A

V

A

V

A V

A V

A V

A V

R V

A V

A V

A V

R V

A V


V•Values not provided A-Nol reported

RN-Runs could not be checked


P-Not provided PI\I-Points could not be checked


4.35

VALIDATION PARAMETERS SUMMARY FOR EPA MMT (1989) TRACE MTTAl.,S

VALIDATION PARAMETERS Stack ID

42310 42610 42710 43410 43510 60110 60310 60410 60510 60610 62310 62410 63010 63310 63410 63810 64010 64110 SAMPLE LOCATlON .·

Avera □ e absolute value of swirl anales >10%? V V V V V V V V V V V V V V V Stack diameter < 12 inch? Stack area < 113 inch sauared?

Method 1 not used? R .

SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? V V V V V V V V V V V V V V V Pre- and oosHest meter Y not within t+J-\ 5%? Pilot tube semi-annual calibration sheet included?

V V V V V V N p p p p p p p p p p p p p

SAMPLING PROCEDURES . ·... ·' -,-. ·.' ..·

Pre~test leak rate > 0.02 cfm or 4% of average? PosMest leak rate > 0.02 elm or 4% of averaae?

V V

lsokinelic variation <90 or >110%? V

FIELD REAGENT BLANK ' .

Not collected once per test? Not used to correct samoles? y

R

R

R R R

R

R y y

DUPLICATES Percent difference > 5% (ICAP)? Not conducted per run (GFAAS)? Not conducted oer run ICVAAS\?

V

R

V

R

V R

R

V V

R R

1PF

R 2RF 2RF

R 2RF

R 2RF

V

R

V

R

1PF 2RF

1RF R

2RF 2RF 1RF

1PF R R

1PF R

2RF 2RF

R

MATRIX SPIKES .

Not conducted on lront· and back-half (GFAAS)?

Percent recoverv < 75 or > 125%? Not conducted on one nitric impinger (CVAAS)?

Percent recoverv < 75 or > 125%?

R

V

R

1PF

R

V

R

6PF

y

3PN

R V

R V 1PF

R V tPF V V 3PN

R

V

R

V

R R

V

R

V

R

V






4".'J6


SAMPLE LOCATION Averane absolute value of swirt anales > 10%? Stack diameter < 12 inch? Stack area < 113 inch squared? Method 1 not used? SAMPLING EQUIPMENT Variation in nozzle diameter > 0.004 inch? Pre- and nost-test meter Y not within /+/-\ 5%? Pilot tube semi-annual calibration sheet included? SAMPLING PROCEDURES Pre-test leak rate > 0.02 elm or 4% of average? Post-test leak rate > 0.02 cfm or 4% of averaae? lsokinetic variation <90 or > 110%? Number of Samole runs < 3?

FIELD BLANK Not collected once per test? Used to correct samples? Samnle/field blank < 5? FIELD REAGENT BLANK Not collected once per test? Not used to correct samples? ANALYSIS DATES Not within 2 months (ICAP)? Not within 2 months (GFAAS)? Not within 28 davs /CVAASl? DUPLICATES Percent difference > 10% (ICAP)? Not conducted per run (GFAAS)? Not conducted oer run /CVAAS\?

MATRIX SPIKES Not conducted on front- and back-half (GFAAS)? Percent recoverv < 75 or > 125%? Not conducted on one nitric impinger (CVAAS)? Percent recoverv < 75 or > 125%?


VALIDATION PARAMETERS SUMMARY FOR GARB 436 (1992) TRACE METALS

10110 10310 10410 10510 10610

V V

A A

V V V V N

p p p

V V

13PF 14PF 18PF

A A A A y y y y

V V V V A A A A A A A A

A A A V 3PN V V A A A A V V V V


y

A

V

p

15PF

A y

V A A

A V

4-37

Stack ID 12810 13810 13910

V V

V N

p p

23PF 7PF

A y y

.

V V A A A A

A A V V A A V V

16510 42410 42510 43010 43110 43310

V V V V A

·•

V V V V V V p p p p

V V V V V V 1RF V V 1RF

A y

A A A A 23PF 3PF 11 PF

A A A A A y y y

A A A

A A A A A y A A

V V V V V V

A A A A A A A A A A

A A A A A

V V V V V A A A A A A

V V V V V V

A TI ACHMENT 5 SUBSTANCE SPECIFIC QA FAILURE FREQUENCY

ATTACHMENT 5 • SUBSTANCE SPECIFIC QA FAILURE FREQUENCY

Samole Method Version Check Substance Count GARB 421 87 Duplicate oercent difference > 5% HCI 2 GARB 422 91 Duolicate values > 3 X RSD not reoorted 1 3-Butadiene 9 GARB 425 87 Matrix soike oercent recoverv > 10% Chromium (Hexl 1 CARB425 90 Matrix soike oercent recoverv > 10% Chromium (Hex) 6 GARB 425 90 Matrix spike percent recovery not reoorted Chromium /Hexl 2 GARB 425 90 Probe oroof total chrome > DL Chromium 3 GARB 428 88 Internal standards values not reported 4D2378 2 GARB 428 88 4F 2378 2 CARB428 88 5D 12378 3 GARB 428 88 6D 123678 2 CARB428 88 8D 4 CARB428 90 Laboratory control spike percent recovery < 60 or > 140% SF 23478 3 CARB428 90 6D 123789 3 GARB 428 90 6D Total 3 GARB 428 90 6F Total 3 CARB428 90 Laboratory control spike percent accuracy not reported 4D 2378 3 CARB428 90 4D Total 15 CARB428 90 4F 2378 3 CARB428 90 4F Total 15 GARB 428 90 5D 12378 3 CARB428 90 5D Total 15 GARB 428 90 5F 12378 3 GARB 428 90 5F 23478 6 GARB 428 90 5F Total 15 GARB 428 90 6D 123478 3 GARB 428 90 6D 123678 9 GARB 428 90 6D 123789 6 CARB428 90 6D Total 15 GARB 428 90 6F 123478 3 GARB 428 90 6F 123678 9 GARB 428 90 6F 123789 6 GARB 428 90 6F 234678 6 GARB 428 90 6F Total 15 GARB 428 90 7D 1234678 3 GARB 428 90 7D Total 15 GARB 428 90 7F 1234678 3 GARB 428 90 7F 1234789 6 GARB 428 90 7F Total 15 GARB 428 90 Internal standards (HAMS) percent accuracy < 40 or > 120% 4D 2378 4 GARB 428 90 4F 2378 5 CARB428 90 5D 12378 2 GARB 428 90 5F 12378 9 GARB 428 90 6D 123678 5 GARB 428 90 6F 123678 5 GARB 428 90 7D 1234678 5 GARB 428 90 7F 1234789 5 GARB 428 90 8D 5 CARB428 90 Internal standards (LAMS) percent accuracy < 40 or > 120% 6D 123678 2 CARB428 90 4D 2378 2 GARB 428 90 4F 2378 2 GARB 428 90 5D 12378 2 GARB 428 90 7D 1234678 2 CARB428 90 8D 3 GARB 428 90 Surroaate standards (LAMS) oercent recoverv not reoorted 6D 123789 3 GARB 428 90 Surrooate standards (HAMS) percent recovery< 60 or> 140°/4 4D 2378 3

5-1

ATTACHMENT 5 • SUBSTANCE SPECIFIC QA FAILURE FREQUENCY

Samele Method Version Check Substance Count GARB 428 90 Surroaate standards (HAMS) oercent recoverv < 60 or> 140% 7F 1234678 2 CARB429 89 Laboratory control spike percent accuracy not reported Acenaphthene 3 CARB429 89 Anthracene 3 CARB429 89 Benzo(a)pyrene 3 CARB429 89 Benzo(b+k)fluoranthene 3 GARB 429 89 Chrysene 3 CARB429 89 lndeno(1,2,3-cd)pyrene 3 CARB429 89 Naphthalene 3 CARB429 89 dibenz(a,h)anthracene 3 CARB429 89 Acenaphthylene 3 GARB 429 89 Benzo(a)anthracene 3 CARB429 89 Benzo(g,h,i)perylene 6 CARB429 89 Fluoranthene 3 GARB 429 89 Fluorene 3 GARB 429 89 Naphthalene 3 CARB429 89 Phenanthrene 3 CARB429 89 Pvrene 3 CARB429 89 Internal standards percent accuracy < 50 or > 150% Acenaphthene 25 GARB 429 89 Acenaphthylene 19 GARB 429 89 Anthracene 24 CARB429 89 Benzo(a)anthracene 17 CARB429 89 Benzo(a)pyrene 18 CARB429 89 Benzo(b)fluoranthene 14 CARB429 89 Benzo(g,h,i)perylene 13 CARB429 89 Benzo(k)fluoranthene 12 CARB429 89 Chrysene 18 CARB429 89 Fluoranthene 13 CARB429 89 Fluorene 15 CARB429 89 Naphthalene 30 GARB 429 89 Phenanthrene 14 CARB429 89 Pvrene 15 GARB 429 89 Internal standards percent accuracy not reported Acenaphthene 17 CARB429 89 Acenaphthylene 43 CARB429 89 Anthracene 11 CARB429 89 Benzo(a)anthracene 39 CARB429 89 Benzo(a)pyrene 6 CARB429 89 Benzo(b )fluoranthene 6 CARB429 89 Benzo(g,h,i)perylene 42 CARB429 89 Benzo(k)fluoranthene 6 CARB429 89 Chrysene 9 GARB 429 89 Fluoranthene 42 GARB 429 89 Fluorene 47 GARB 429 89 Naphthalene 42 GARB 429 89 Phenanthrene 42 CARB429 89 Pvrene 48 GARB 430 91 Reporting limit not given (Sample/Field Blank < 5) Acetaldehyde 14 GARB 430 91 Acrolein 12 CARB430 91 Formaldehvde 40 CARB430 91 Samole not correct (Samole/Field Blank > 5) Formaldehyde 13 GARB 436 92 Sample/Field Blank < 5 Antimony 3 GARB 436 92 Arsenic 3 GARB 436 92 Barium 3 GARB 436 92 Cadmium 18 GARB 436 92 Chromium 18 GARB 436 92 Coooer 22

5-2

ATTACHMENT 5 - SUBSTANCE SPECIFIC QA FAILURE FREQUENCY

Samole Method Version Check Substance Count CARB436 92 Sample/Field Blank < 5 Lead 18 CARB 436 92 Manganese 15 CARB 436 92 Nickel 5 CARB 436 92 Selenium 1 CARB 436 92 Silver 2 CARB 436 92 Zinc 19 CARB 436 92 Matrix soike oercent recoverv < 75 or> 125% !GFAASI Cadmium 3 EPA MMT 89 Duplicate percent difference > 5% Cadmium 1 EPA MMT 89 Lead 1 EPA MMT 89 Nickel 1 EPA MMT 89 Selenium 1 EPA MMT 89 Matrix spike percent recovery< 75 or> 125% (GFAAS) Arsenic 6 EPAMMT 89 Selenium 3 EPA MMT 89 Matrix spike percent recovery not reported (GFAAS) Arsenic 3 EPA MMT 89 Selenium 3

5.3

A TI ACHMENT 6 STATISTICAL ANALYSIS OF GROUPS

System Type

Asphalt production Asphalt production Asphalt production Asphalt production

Asphalt production

Asphalt production Asphalt production Asphalt production

Asphall production Asphalt production

Category

Metals

Metals Metals

Metals Metals Metals Metals

Metals Metals Metals

Metals

Met~ Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals

~tals Metals Metals Metals Metals Metals

MetaJ!. Metals Metals Metals Metals Metals

~tals Metals Me1ats Melals Metals

Metals M_!ttals Metals Metals Metals

Metals Metats

Me~ Metals Metals

Metals

Metals Metals Ma@!! Metals

Metals Metals Metals Metals

Substance

Arsenic Arsenic Arsenic Arsernc Arsenic

Ars~.!l.k Beryllium Berylhum

Beryllium

Beryllium Beryllium Beryllium Cadmium Cadmtum Cadmium Cadmium Cadmium

Cadmium Chromium Chromium Chromium Chromium Chromium Chromium_ Chromium (Hex)

Chromium (Hex) Chromium (Hex) Chromium (Hex) Chromium {Hex) Chromi1,1_1!1 (Hex Copper Copper Copper Copper Copper

C

Lead Lead lead Lead Lead

Lea!!_ Manganese Manganese Manganese Manganese

Manganese Manganese

Mercury Mercury Mercury Mercury Mercury

Me!.£1,!, Nickel Nickel

Nickel Nickel Nickel

EF Unit Value Type

lbs/ton production EF lbs/ton production EF lbs/ton production EF lbs/Ion production EF lbs/Ion production EF lbs/Ion roduction EF lbs/Ion production EF lbs/ton production EF lbs/Ion production EF lbs/Ion production EF lbs/Ion production EF lbs/ton roduction EF lbs/ton production EF lbs/ton production EF lbs/ton production EF lbs/Ion production EF lbs/Ion production EF lbs/ton roduction EF lbs/ton production EF lbs/ton production EF lbs/Ion production EF lbs/Ion production EF lbs/Ion production EF lbs/ton roduct1on EF lbs/Ion production EF lbs/Ion production EF lbs/Ion production EF lbs/ton production EF lbs/ton production EF lbs/ton roduction EF lbs/Ion production EF lbs/ton production EF lbs/Ion production EF lbs/Ion production EF lbs/ton production EF lbs/Ion pr_pduction ~

lbs/ton produchon EF lbs/ton production EF lbs/ton p,oducl1on EF lbs/Ion production EF lbs/ton production EF lbs/ton production ~ lbs/Ion produclton EF lbs/ton produchon EF lbs/ton production EF lbs/ton production EF lbs/ton production EF lbs/Ion roduction EF

lbs/ton producti.MI Ef lbs/ton production EF lbs/Ion production EF lbs/ton

lbs/ton lbs/ton lbs/ton production EF lbs/ton production EF lbs/ton production EF lbs/ton production EF lbs/Ion produc1ion EF

TABLE AS-1a. MAJOR GROUP COMPARISON (t-atatiatica).

First j I Description e

Statistics Average Standard

Deviation

Detect

MateriaVFuel _ _T~ Di&&el Diesel

Diesel

Natural gas I 14 Natural gas 1 4

2.17E-06 2.17E-06 2.17E-06 6.92E-06 6.92E-06 L57E-0S

3.12E-06 3.12E-06 3.12E-06 1 .85E-0S 1.8SE-05 1.25E-05

0.01 0.72 0.72 0.64_ Qi!

Oieael Diesel Dieael

Natural gas

Natural gaa

Q1l Dieael Diesel Dieael

Natural gas Natural gas

o, Diesel

Diesel Dieael

Natural gaa Natural \}H

Qi! Diesel Dieael DiNel

Natural gas

D1eael Diesel Diesel

Natural gas Natural gas

Qft Diesel Diesel

Diesiel Natural gu Natural gas

Qi! Dieael Diesel

Diesel Natural gas

Diesel

Naturalgaa Natural gal

6-1

7.92E-07 1.22E-06 o.oo 7.92E-07 1.22E-06 0.00 7.92E-07 1.22E-06 0.00

14 7.53E-07 5.94E•07 0.oo 14 7.53E-07 5.94E-07 0.00 3 7.94E-07 1.12E-07 0.00

7.10E-06 1.42E-05 0.98 7.10E-06 1.42E-0S 0.98 7.10E-06 1.42E-05 0.98

14 2.16E-06 J.0JE-06 0.75 14 2.16E-06 3.0JE-06 0.75 3 2.02E-06 5.43E-07 0.43

1.09E-05 I 2. 75E-0S I 1.00 1.09E-0S 2. 75E-0S 1.00

1.09E-05 12. 75E-o5 13 2.13E-06 2.26E-06 131 2 .. 13E-06 2.26E-06

6 0 ~7E-05 8.46E-05

5.86E-07 I 6.92E-07 5.SBE-07 6.92E-07 5.BBE-07 6.92E-07

2.4SE-04 7.29E-04 1.00 2.45E-04 7.29E-04 1.00 2.45E-04 7.29E-04 1.00

14 1.12E-05 2.82E-05 0.93 14 1.12E-os 2.82E-05 0.93 3 2.24E·05 1.84E-0S 1.00

1.90E-04 S.42E-04 1.00 1.90E-04 S.42E-04 1.00

9 1.90E-04 5.42E-04 1 .00 14 4.28E-0S 6.30E-05 1 .00 14 4.28E-05 6.J0E-05 1.00 3 2.25E·04 5.SJE-05 1.00

9 I , .23E-06 I 1.99E-06 0.80 1.23E-08 1.99E·06 0.80 1.23E-08 1.99E·06 0.80

14 I 7 .27E•06 1.09E-05 1.00 1.09E-05 1.00

4.46E-05 1.26E-04 0.00 4.46E-05 1.26E-04 0.00

Q I 4.46E-05 1.26E-04 0.00 14 8.28E-06 1.04E-05 0.59 14 6.28E-06 1 .04E-05 0.59

Proceao oil 70 Oil

Process oi! 70 Process oil 70

Natural gu Oil

Process oil 70 Oil

Proc&Ba oil 70 Proc&as oil 70

Natural gas Oil

Process oil 70

on Proceaa oil 70 Process oil 70

Natural oaa Oil

Proce11 od 70 Proce11 oil 70

Natural gas Oil

Process oil 70 0lt

Process oil 70 Process oil 70

Natural gas

Oil Process oil 70

Oil Proce&a 011 70 Process oil 70

Natural gas

Oil

Second Samr Statiatica I Size Av.-age Standard I Delaet

Deviation I Ratio 14 j 6.92E-06 1.85E-05 o. 72

'!tc>t!:>,~oj; · s, •• ~-~·• 2.37E-06 1.S0E-06 1.00 1.57E-05 1.25E-05 0.64 2.37E-06 1.80E-06 1.00 2.37E-06 1.80E·08 1.00

14 7 .53E-07 5.94E-07 0.00 J 7.94E-o7 1.12E-07 o.oo 3 4.16E-07 2.80E-08 0.00 3 7.94E-07 1.12E-07 0.00 3 4.16E-07 2.B0E-08 0.00 3 4.16E-07 2.80E-08 0.00 14] 2.16E-06 3.0JE-08 0.75

2.02E-06 S.43E-07 0.43 7.67E-D7 9.69E-07 0.82 2.02E-06 S.4JE-07 0.43 7.67E-07 9.69E-07 0.82 7.67E-07 9.69E-07 0.62

13 / 2.13E-08 I 2.26E-06 I 0.69 6.57E-0S 8.46E-05 1.00

14

0.79 1.00 LQ_Q_ 0.86 1.00 1.00 , ... 1.00

a.01 E-06 I 2.96E-06 L_L_QQ 14, 1.12E-05 2.82E-0S 0.93 3 2.24E-05 1.84E-o5 1.00

1.41E·06 5.S0E-07 1.00 2.24E•0S 1,84E-05 1.00 1.41E-06 5.S0E-07 1.00 1.4tE-06 5.S0E-07 10 Q_Q

" I 4.28E-051.6.30E-05 1 1.00 3 2.25E-04 5.83E·0S

t.40E-04 ,c!.-79E-05

:to2E-06 ! 5,_7_1-f:~ "I 8.28E-06 , 1.04E-05 I 0.59 3 3.60E-05 5.54E-08 1.00 3 8.42E-06 2.SJE-06 1.00

8.42E-06 I 2.63E-06 I 1.00

Significant DiHetanca at

~~%Conftdene, No Ym No No No !lg_

No No No No No

Y• No No No No No !lg_

No No No

Y• Y• !lg_

No y,_

No No No y~ No No No Ym No Yl!_B_ No No No No No !lg_

No No No v .. Y• !fq_ No

Y• Y• Y• No

Y~. No No No

Y• No

TABLE A6-1a. MAJOR GROUP COMPARISON (t-statistica).

System Type Category Substance EF Unit Value Type Firs! Samn e Statietics Second Sam :>la Statistics Significant Dascription Size Average Standard Detect Dascription Slz& Average Standard Detect Difference at

MateriaVFuel Tu .... Deviation Ratio Material/Fuel Tu..,. Deviation Ratio 95%Confidenc• Asohalt oroduclion Metals Nickel lbs/ton oroduction a= 1~·:c,,;c:;_4~r;,;s;:: Process oil 70 3 8.42E-06 2.63E-06 1.00 v. Asphalt production Metals Selenium lbs/Ion production a= Dieeel Q 2.54E-06 2.89E-08 0.08 Natu,eloaa 14 1.12E-05 3.42E-05 0.83 No

Asphalt production Metals Selenium lbs/ton production a= Diesel Q 2.54E-06 2.89E-08 0.08 ;,~ .;:~;' ,~, v .. Asphalt produc110n Metals Selenium lbs/Ion production a= Diesel Q 2.54E-06 2.89E-06 0.08 Proceee oil 70 ' 2.08E-07 1 .40E-08 0.00 No Asphalt production Metals Selenium lbs/Ion production a= Natural gaa 14 1.12E-05 3.42E-05 0.83 011 3 2.71E-05 3.22E-OS 0.79 No Asphalt production Metals Selenium lbs/ton production s= Natural gas 14 1.12E-05 3.42E-05 0.83 Proceaa oil 70 3 2.0SE-07 1.40E-08 0.00 No Asohalt oroduction Metals Selenium lbs/Ion nroduclion s= Oil ' 2.71 E-05 3.22E-05 0.79 Procus oil 70 ' 2.0BE-07 1.40E-08 0.00 No Asphalt production Metals Zinc lbs/ton production s= Diesel Q 5.36E-04 1.53E-03 1.00 Natural gas 1. 2.59E-05 2.06E-OS 1.00 No Asphalt production Metals Zinc lbs/ton production s= Diesel Q 5.36E-04 1.53E-03 1.00 o, 3 3.46E-04 2.25E-04 1.00 No Asphalt production Metals Zinc lbs/Ion production s= Diesel Q 5.36E-04 1.53E-03 1.00 Process oil 70 ' 2.52E-05 8.55E-08

~ No

Asphalt production Metals Zinc lbs/ton production s= Natural ga11 14 2.59E-05 2.06E-05 1.00 ~-~Jlt : C rli C v ..

Asphalt production Metals Zinc lbs/ton production s= Natural gaa 14 2.59E-05 2.0SE-05 1.00 Procaaa oil 70 3 2.52E-05 8.55E-06 1.00 No Asnhalt nroduct1on Metals Zinc lbs/ton nroduction EF o, 3 3.46E-04 2.25E-04 1.00 Process oil 70 3 2.52E-05 B.SSE-06 1.00 No Asphalt production p,.. Acenaphlhene lbs/ton production s= Diesel ' 4.93E-07 5.52E-07 0.38 Natural gas 14 6.17E-07 4.35E-07 0.67 No Asphalt production p"' Acenaphthene lbs/Ion production s= Diesel ' 4.93E-07 5.52E-07 0,38 Oil 3 6.13E-07 1.17E-07 0.00 No Asphalt production p"' Acenaphthene lbs/Ion production a= Diesel ' 4.93E-07 5.52E-07 0.38 Proceaa oil 70 ' 3.06E-07 8.20E-08 1.00 No Asphalt production PAH Acenaphthene lbs/ton production s= Natural gas 14 6.17E-07 4.35E-07 0.67 Oil ' 6.1 JE-07 1.17E-07 0.00 No Asphalt production PAH Acenaphthene lbs/ton production s= Natural gaa 14 6.17E-07 4.35E-o7 0.67 Process oil 70 ' 3.08E-07 8.20E·08 1.00 No Asnhalt nroducl1on p,.. Acenanhthene lbs/ton oroducl10n a= o, 3 6.13E-07 1.17E-07 0.00 Process oil 70 3 3.06E-07 A.20E-08 1.00 v .. Asphalt production p"' Acenaphthylene lbs/ton production a= Dieeel ' 4.39E-07 5.31E-07 0.30 Natural gu 14 1.19E-06 2.7SE-06 0.83 No Asphalt production p"' Acenaphthylena lbs/ton production s= Diesel ' 4.39E-07 5.31E-07 0.30 Oil 3 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Acenaphthylene lbs/ton production s= Die.ael ' 4.39E-07 5.31E-07 0.30 ProceH oil 70 ' 5.26E-07 2.35E-07 1.00 No Asphalt production p"' Acenaphthylene lbs/ton production s= Natural gas 14 1.19E-06 2.75E-06 0.83 Oil ' 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Acenaphthylene lbs/ton production s= Natural gas 14 t.19E-06 2.75E-OB 0.83 Proceu oil 70 ' 5.26E-07 2.35E-07 1.00 No Asnhall nroduct1on PAH Acenanhth11lene lbs/ton 1:1roduction s= Oil ' 6.13E-07 1.17E-07 0.00 Proceaa oil 70 ' 5.26E-07 2.35E-07 1.00 No Asphalt production PAH Anthracene lbs/ton production a= Dies.el ' 7.13E-07 1.57E-06 0.81 Natural gas 14 3.27E-07 4.23E-07 0.37 No Asphalt production P"' Anthracene lbs/ton production a= Diesel ' 7.13E-07 1.57E-06 0.81 Oil 3 6.13E-07 1.17E-o7 0.00 No A8phalt product•on p"' Anthracene lbs/ton producllon EF Diesel ' 7.13E-07 1.57E-06 0.81 Procesa oH 70 3 5.74E-08 1. 78E-oa 1.00 No Asphalt productaon P"' Anthtacene lbs/ton production a= Natural gas 14 3.27E-07 4.23E-07 0.37 Oil 3 B.13E-07 1.17E-07 0,00 No Asphalt production p"' Anthracene lbs/ton ptoduclion ~ Natural oas 14 3.27E-07 4.23E-07 0.37 Proceaa oil 70 ' 5.74E-08 1.78E-OB 1.00 No Asnhalt nroduct1on PAH Anthracene lbs/Ion nroduction s= Oil ' 6.13E-07 1.17E-07 0.00 Process oil 70 ' 5.74E-08 1.78E·08 1.00 Y• Asphall production PAH Benzo(a)anthracene lbs/Ion production s= Diesel ' 3.JOE-07 S.56E-07 0.08 Natural ii&• 14 2.11E-07 4.07E-07 0.02 No Asphalt production PAH Benzo(a)anlhracene lbs/ton production s= Diesel ' 3.30E-07 5.56E-07 0.08 Oil ' B.1 JE-07 1.17E-07 0.00 No Asphalt production PAH Benzo(a)anlhracene lbs/Ion production s= Diesel ' 3.30E-07 S.56E-07 0.08 ProceH oil 70 ' 1.11E-08 2.14E-09 1.00 No Asphalt production PAH Benzo(a)anthracene lbs/ton production s= Natural gas 14 2.11E-07 4.07E-07 0.02 o, 3 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Benzo(a)anthracene lbs/ton production s= Natural gas 14 2.11 E-07 4.07E-07 0.02 ProceH oil 70 3 1.11E-08 2.14E-09 1.00 No Asohall oroduction PAH Benzola)anthracene lbs/ton nroduction EF Oil ' 6.13E-07 1.17E-07 0.00 Process oil 70 3 1.11E-08 2.14E-09 1.00 YM Asohall oroduclion p"' Benzola)f1ouranthene lbs/ton nroduction EF Diesel 2 1.22E-06 2.17E-07 0.00 OH 3 6.13E-07 1.17E-07 0.00 Y• Asphalt produc!lon P"' Benzo(a)pyrena lbs/ton production EF Diasel ' 3.06E-07 5.70E-07 0,00 Natural gas 14 2.07E-07 4.09E-07 0.00 No Asphalt production P"' Benzo(a)pyrene lbs/ton production EF Diesel ' 3.06E-07 5.70E-07 0.00 o, ' 8.13E-07 1 .17E-07 0,00 No Asphalt production PAH Benzo(a)pyrene lbs/ton production EF Diesel ' 3.06E-07 5.70E-07 0.00 Process oil 70 ' 1.84E-09 1.84E-09 0.72 No Asphall production PAH Benzo(a)pyrene lbs/ton production s= Natural gas 14 2.07E-07 4.0QE-07 0.00 Oil 3 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Benzo(a)pyrene lbs/Ion production s= Natural gas 14 2.07E-07 4.09E-07 0.00 Procea■ oil 70 ' 1.84E-09 1.84E-09 0.72 No Asohalt oroduction PAH Benzo/a\ovrene lbs/ton nroduction s= Oil 3 6.13E-07 1.17E-07 0.00 Proceaa oil 70 ' 1.84E-OO 1.84F"-09 0.72 v .. Asphalt production PAH Benzo(b)lluoranlhene lbs/Ion production s= Diesel 6 9.16E-09 8.94E-09 1.00 Natural gas 14 2.07E-07 4.00E-07 0.00 No Asphalt production PAH Benzo(b)lluoranthene lbs/Ion production s= Diesel 6 9.16E-09 8.94E-09 1.00 Proceas oil 70 3 2.10E-09 2.45E·10 1.00 No Asnhall nroduct1on PAH Benzofbllluoranthene lbs/ton oroduction s= Natural OU 14 2.07E-07 4.0QE-07 0.00 ProceH oil 70 ' 2.10E-09 2.45E-10 1.00 No Asphalt production PAH Benzo(g,h,i)perylene lbs/ton production a= Diesel ' 3.06E-07 5.70E-07 0.00 Natural gu 14 2.07E-07 4.09E-07 0.00 No Asphalt production PAH Bunzo(g,h,i)perylene lbs/ton production s= Diesel • 3.06E-07 5.70E-07 0.00 OH 3 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Benzo(g.h,1)perylene lbs/ton production s= Diesel • 3.08E-07 5.70E-07 0.00 Proceaa oil 70 ' 1.20E-09 2.59E-10 0.75 No Asphalt production PAH Benzo(g,h,i)perylene lbs/ton production s= Natural gas 14 2.07E-07 4.09E-07 0.00 OH ' 6.13E-07 1.17E-07 0.00 No Asphalt producl1on p"' Benzo(g,h,i)perylene lbs/ton production s= Naturalgu 14 2.07E-07 4.09E-07 0.00 Proc .. , oil 70 ' 1.20E-09 2.59E-10 0.75 No Asohall oroduc11on PAH Benzoln hp- lene lbs/ton nroduchon s= o, 3 6.13E-07 1.17E-07 0.00 Process oil 70 3 1.20E·09 2.59E-10 0.75 Y• Asphalt production PAH Benzo(k)lluoranthene lbs/ton production s= Dieael ' 3_07E-07 5.69E-07 0.01 Natural gu 14 2.0SE-07 4.0SE-07 0.00 No Asphalt producnon PAH Benzo(k)ftuoranthene lbs/ton production s= Diesel ' 3.07E-07 5.89E-07 0.01 Oil 3 6.13E-07 1_17E-07 0.00 No Asphalt production p"' Benzo(k)lluoranthene lbs/Ion production s= Diesel • 3.07E-07 5.69E-07 0.01 Proceee oil 70 ' 8.17E·10 7.87E-11 0.00 No Asphalt produc,ion PAH Benzo{k)lluoranrliene lbs/ton productmn EF Natural gas 14 2.0SE-07 4.0BE-07 0.00 o, ' 8.13E-07 1.17E-07 0.00 No Asphalt producfion PAH Benzo(k)fluoranthene lbs/ton production s= Natural gaa 14 2.0SE-07 4.oeE-07 0.00 Procesa otl 70 ' 8.17E-10 7.87E-11 0.00 No Asohalt oroduction PAH Benzolklfluotanthene lbs/ton oroduction s= o, 3 6.13E-07 1.17E-07 0.00 Proceas oil 70 3 8.17E-10 7.87E-11 0.00 Y•

6-2

TABLE A6-1a. MAJOR GROUP COMPARISON (t-slatisOCS).

System Type Category Substance EF Unit Value Type First Samo e Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Oeacription Size Average Standard Detect Dinerenca at

MateriaVFuel Tvoa Deviation Ratio MateriaVFuel Tvne Deviation Ratio 95%Conlidenc, Asphalt production PAH Chry$ene lb:;i/ton production g: Diesel 8 J.16E-07 5.65E-07 0.03 Natural gas 14 2.07E-07 -4.09E-07 o.oo No Asphalt producllon P"' Chrysene lbs/Ion production EF Diesel 8 3.16E-07 5.65E-07 0.03 Oil ' 6.13E-07 1.17E-07 0.00 No Asphalt producl1on PAH Chrysene lbs/ton production g: Diesel ' 3.16E-07 5.65E-07 0.03 Process oil 70 ' 8.17E-10 7.87E-1 t 0.00 No Asphalt production PAH Chrysene lbs/ton production g: Natural gas 14 2.07E-07 4.09E·07 0.00 Oil 3 6.1JE-07 1.17E-07 0.00 No Asphall production PAH Chrysene lbs/Ion production EF NabJral gaa 14 2.07E-07 4.09E-07 0.00 Proceas oil 70 3 B.17E-10 7.87E-11 0.00 No Asohalt nroduction p,.. Chrvsene lbs/ton nroduction EF Oil 3 6.13E-07 1.17E-07 0.00 Process oil 70 3 8.17E-10 7.87E-11 0.00 Ym Asphalt production p"' dibenz{a.h)anlhracene lbs/ton production EF Diesel ' J.06E-07 5.70E-07 0.00 Natural gH 14 2.07E-07 4.09E-07 0.00 No Asphalt production PAH dibenz(a,h)anlhracene lbs/ton producllon g: Dieael ' 3.06E-07 5.70E-07 0.00 Oil 3 6.13E-07 1.17E-07 0.00 No Asphalt production PAH dibenz(a,h)anlhracene lbs/ton production EF Dieeel ' 3.06E·07 5.70E-07 0.00 Process oit 70 ' 8.17E-10 7.B7E-11 o.oo No Asphall production p,.. dibenz(a,h)anthracene lbs/Ion producI1·on EF Natural gas 14 2.07E-07 4.09E-07 0.00 o, ' 6.13E-07 1.17E-07 o.oo No Asphalt product10n p,.. dibenz(a,h)anthracene lbs/ton production EF Natural gas 14 2.07E-07 4.09E-07 0.00 Process oil 70 3 8.17E-10 1.s7E-11 o.oo No Asnhalt nroduction p,.. dibenzta h\anthracene lbs/ton oroductmn EF Oil ' 6.13E-07 1.17E-07 0.00 Process oil 70 3 8.17E-10 7.87E-11 o.oo v .. Asphalt production PAH Fluoranthene lbs/ton production EF Diesel 8 4.19E-07 5.06E-07 0.27 Natural gas 14 4.99E-07 9.72E-07 0.59 No Asphalt production p"' Fluoranthene lbs/ton production EF Diesel 8 -4.19E-07 5.06E-07 0.27 Oil 3 6.13E-07 1.17E-07 0.00 No Asphalt production P"' Fluoranthene lbs/Ion production EF Diesel ' 4.19E-07 5.06E-07 0.27 Process oil 70 3 3.57E-OB 9.BSE-09 1.00 No Asphalt production PAH Fluoranthane lbs/Ion production s= Natural gas 14 4.99E-07 9.72E-07 0.59 Oil ' 6.13E-07 1.17E-07 0.00 No Asphalt production PAH Fluoranthene lbs/ton production g: Natural gas 14 4.99E-07 9.72E-07 0.59 Process oil 70 ' 3.57E-08 9.68E-09 1.00 No Asnhalt nroduction PAH Fluoranthene lbs/ton Droduction S:: Oil ' 6. t3E-07 1.17E-07 0.00 Process oil 70 ' 3.57E-08 9.68E-09 1.00 v .. Asphalt production p,.. Fluorene lbs/ton production EF Diesel ' 7.41E-07 4.SBE-07 0.59 t:)0!:,;'.f:t+::ai.-.-at~, ,j,Jd: <'It j!;j ktQl~ v .. Asphalt production PAH Fluorene lbs/ton production EF Dieeel ' 7.41E-07 4.58E-07 0.59 Oil ' 9.14E-07 1.BJE-07 1.00 No Asphalt production PAH Fluorena lbs/ton production EF Diesel ' 7.41E-07 4.SBE-07 0.59 Process oil 70 ' 6.SBE-07 2.07E-07 1.00 No Asphalt production PAH Fluorene lbs/ton production g: Natural g_as 14 _1.7~,~-06", 7.78E-07 ~\;: Oil ' 9.14E•07 1.SJE-07 1.00 No Asphalt production PAH Fluorene tbs/ton production EF .;, ;,;; ; ;;.__..¢ .. , .. ,;; t1t4¼ ;, .. i'1H.'' '"li{Mi:i'! Process oil 70 ' 6.SBE-07 2.07E-07 1.00 Y• Asnhalt oroduction PAH Fluorene lbs/Ion oroduction EF Oil 3 9.14E-07 1.83E-07 1.00 Process oil 70 3 6.58E-07 2.07E-07 1.00 No Asphalt production PAH lndeno( 1,2 ,3-cd)pyrene lbs/Ion production EF Diesel 8 3.06E-07 5.70E-07 0.00 Natural gaa 14 2.07E-07 4.09E·07 0.00 No Asphalt production PAH lndeno( 1,2,3-cd)pyrene lbs/ton production g: Diesel 8 3.06E-07 5.70E-07 0.00 Oil 3 6.13E-07 1.17E·07 0.00 No Asphalt production PAH lndeno( 1,2.3-cd)pyrene lbs/ton production g: Diesel 8 3.06E-07 5. 70E·07 0.00 Process oll 70 ' 8.17E-10 7.B7E-11 0.00 No Asphalt production PAH lndeno(1,2.J-cd)pyrene lbs/Ion production EF Natural gas 14 2.07E-07 4.09E-07 0.00 Oil 3 6.13E-07 1.17E-07 o.oo No Asphalt production PAH lndeno{ 1,2 ,3-cd)pyrene lbs/ton production EF Natural gas 14 2.07E-07 4.09E-07 0.00 Process oil 70 ' 8.17E-10 7.B7E-11 o.oo No Aanhalt oroduct,on PAH lndenol 1 2 3-cd\nvrene lbs/ton oroduc!Ion EF Oil ' 6.13E-07 t.17E-07 0.00 Process oil 70 3 8.17E-10 7.87E-11 o.oo v .. Asphalt production PAH Naphthalene lbs/ton production EF Diesel ' 4.51E-04 7.94E•04 1.00 Natural gas 14 7.07E-05 1.02E-0-4 1.00 No Asphalt production PAH Naphthalene lbs/ton production g: Diesel ' 4.51E-04 7 .94E-04 1.00 Oil ' 3.94E•04 1.07E-04 1.00 No Asphalt production p"' Naphthalene 1bs/ton production EF Diesel 8 4.51 E-04 7 .94E-0-4 1.00 Process oil 70 3 3.0BE-05 2.70E·06 1.00 No Asphalt production p"' Naphthalene lbs/Ion production S:: Natural gas 14 7.07E-05 1.02E-04 1.00 011 • ;,U4&0& •'' 1..mt.o.t I 1M Ym Asphalt product,on p"' Naphthalene lbs/Ion production EF Natural gas 14 7.07E-05 1.02E-04 1.00 Process oil 70 3 3.0BE-05 2.70E-06 1.00 No Asohalt oroducI1on PAH Nanhthalene lbs/ton nroductIon EF , ·. ·-· ; I· j,; .·•·-·- ' ' ' ' ... ·••t:.oila' :."; .,_,::tc .. ._i,; Process oil 70 3 J.oeE-05 2.70E-06 1.00 y,_

Asphalt production p"' Phenanthrene lbs/ton production EF Diesel ' J.JJE-06 5.63E-06 1.00 Natural gas 14 2.65E-06 1.83E-08 1.00 No Asphalt production p"' Phenanthrene lbs/ton production EF Diesel ' 3.33E-06 5.63E-oe 1.00 Oil 3 1.98E-06 7 .OOE-07 1.00 No Asphalt production PAH Phenanthrene lbs/Ion production EF Die&al ' 3.3JE-06 5.63E-06 1,00 Process oil 70 3 6.64E-07 2.t8E-07 1.00 No Asphalt production PAH Phenanthrene lbs/ton produchon EF Natural gas 14 2.esE-oe 1.83E-06 1.00 Oil 3 1.9eE-oe 7.00E-07 1.00 No

Asphalt production PAH Phenanthrene lb.s/ton produclton g: Natural gas 14 2.65E-06 1.B3E-06 k,1:2B Process o~ 70 3 6.64E-07 2. tBE-07 1.00 No

Asohalt oroduct1on PAH Phenanthrene lbs/1on nroduct1on EF .• m" .. ~ '•~·-, --.❖ Process oil 70 ' 6.6-4E-07 2.18E-07 1.00 v .. Asphalt production PAH Pyrene lbs/ton production EF Die:tel ' 3.90E-07 5.22E-07 0.22 Natural gas 14 7.-47E-07 1.85E-06 0.7-4 No

Asphalt production PAH Pyrene lbs/ton production EF DieNI ' 3.90E-07 5.22E-07 0.22 Oil ' e. t3E-07 1.17E-07 0.00 No

Asphalt production PAH Pyrene lbs/ton production EF Diesel ' 3.90E-07 5.22E-07 0.22 PrOCHS oil 70 3 5.62E-08 2.23E-08 1.00 No Asphalt production PAH Pyrene lbs/ton production EF Natural gas 14 7.47E-07 1.85E-06 0.7◄ Oil 3 6.13E-07 1.17E-07 0.00 No

Asphalt production PAH Pyrene lbs/ton production EF Natural gas 14 7.47E-07 1.85E-06 0.7◄ Process otl 70 ' 5.82E-08 2.23E·08 1.00 No

Asnhalt nroducbon PAH Pvrene lbs/1on oroduclion EF Oil ' 6.13E-07 1.17E·07 0.00 Process oil 70 ' 5.62E-08 2.23E-08 1.00 Yeo Asphalt production voc Benzene lbs/ton production EF '! ::'t ,~ "0c,,, .... 5$:-:/~·- ·._;,,;;;,; f't .. ·~ Natural QM 13 8.24E-05 1.0BE-04 1.00 Y• Asphalt production voc Benzene lbs/Ion production EF Diesel ' 5.5BE-03 7.58E-03 0.9-4 Ool 3 2.02E-05 5.00E-06 0.71 No

Asphalt production voc Benzene lbs/ton production EF Diesel ' 5.58E-03 7.58E-03 0.94 Process oil 70 ' 5.90E·05 1.11E-05 1.00 No

Asphalt production voe Bonzene lbs/ton production IF NeibJral gas 13 8.24E-05 1.0SE-04 1.00 o, ' 2.02E-05 5.00E-06 0.71 No

Asphalt production = Benzene lbs/Ion production IF Natural gas 13 8.24E•05 1.0BE-04 1.00 Process oiil 70 3 5.90E-05 1.11E-05 1.00 No

Aschalt oroduct1on voc Benzene lbs/Ion nroduction EF Oil ' 2.02E-OS 5.00E-06 0.71 ,:::0,,iii,f\ll;:' ., " ., . ._., ,·,, ~ , .,; I.""-'· I.;,;; , ',!',: '.·''" Y• Asphalt production voe Formaldehyde lbs/ton production s= Diesel ' 1.56E-04 9.40E-05 1.00 Natural gas ' 2.57E-0-4 3.51E·04 1.00 No

Asphalt producllon voc Formaldehyde lbsflon production S:: Diesel ' 1.56E-04 9.40E-05 1.00 Oil ' 3.22E-04 2.07E-0-4 1.00 No

Asphalt produclion voc Formaldehyde Iba/ton production EF Diesel ' 1.56E-04 9.40E-05 1.00 Process otl 70 3 1.38E-04 2.29E-05 1.00 No

Asphalt produc1ion = Formaldehyde lbs/ton production EF Natural gas ' 2.57E-04 3.51E-04 1.00 o, 3 3.22E-0-4 2.07E-04 1.00 No

Asphalt produc1ion = Formaldehyde lbs/ton production EF Naturalgu ' 2.57E-04 3.51E-04 1.00 Process otl 70 ' 1.38E·04 2.29E-05 1.00 No

.. ,

TABLE M--1a. MAJOR GROUP COMPARISON (1-statiatica).

System Type Category Substance EF Unit Value Type First Samnle Statistics Second Sam le St&tistics Significant Description Size Average Standard Detect Deacription Size Average Standard Detect Difference at

MateriaVFuel T-·-- Deviation Ratio MateriaL'Fusl T··· Deviation Ratio 95%Confidencf

Asohalt oroduclion voc Formaldehvde lbs/ton nroduction EF Oil 3 3.22E-04 2.07E-04 1.00 Proceas oil 70 3 1.38E-04 2.29E-05 1.00 No

Boiler Metals Antrmonv lbs/Maal "' • . 1 ,-.r:- Residual fuel 3 5.42E·0◄ 3.87E-04 0.00 y.,.

Boiler Metals Arsemc lbs/Maal "' No. 6 fuel oil 27 8.55E-04 8.18E·04 0.72 Residual fuel 3 4.14E·05 5.5SE·06 0.00 No

Boiler Metals Barium lbs/Moal "' No. 6 fuel oil 3 2.23E-02 6.41E-03 1.00 Residual fuel 3 7.78E-03 1.14E-02 1.00 No

Boiler Metals Be~lhum lbs/Moal "' No. 6 fuel oil 27 3.EI0E-04 9.61E-04 0.94 Residual fuel 3 1.65E-05 1.90E-06 0.00 No

Boiler Metals Cadmium 1bs/Moal "' No. 6 fuel oil 27 2.BSE-03 9.76E-03 0.96 Residual fuel 3 1.SSE-04 1 .90E-05 0.00 No

Boiler Melals Chromium lbs/Mnal "' No 6 fuel oil 27 1.49E-03 1.89E-03 0.85 Residual fuel 3 3.42E-04 2.59E-04 0.82 No

Boiler Metals Chromrnm IHexl lbs/Mnal "' No. 6 fuel oil 24 3.22E-04 3.◄◄ E-04 0.30 Residual fuel 3 6.05E-05 7.01E-05 0.88 No

Boiler Metals Cnnner lbs/Mnal "' No. 6 fuel oil 27 3.96E-03 4.57E-03 1.00 Residual fuel 3 1.70E-03 3.54E-04 1.00 No

Boiler Metals Lead lbs/Mnal "' No. 6 fuel oil 27 -4.45E-03 9.37E-03 0.90 Residual fuel 3 3.31E-04 -4.61E-05 0.00 No

Boiler Metals Ma""anese lbs/Mnal "' No. 6 fuel oil 27 2.26E-02 1.05E-01 0.99 Residual fuel 3 5.51E-03 9.22E-03 0.99 No

Boiler Metals Mercu~ lbs/Mnal "' No. 6 fuel oil 27 1.17E-03 1.75E-03 0.10 Residual fuel 3 8.28E·05 1.1tE-05 0.00 No

Boiler Metals Nickel lbs/Mnal "' No. 6 fuel oil 27 1.30E-0t t.48E-01 1.00 Residual fuel 3 6.77E-04 7.83E·04 0.92 No

Boiler Metals Selenium lbs/Mnal "' No. 6 fuel oil 27 3.0BE-03 8.68E-03 0.65 Residual fuel 3 4.1-4E-05 5.SSE-06 0.00 No

Boiler Metals Silver 1bs/Mnal "' .. ,,. ........ ~:.Ii--,, " ·"S''. ,,.~ Residual fuel 3 2.00E-04 7.86E-05 0.<48 y,.

Boiler Metals Thallium lbs/Mnal "' No. 6 fuel oil 3 3.27E-04 3.98E-04 0.00 Residual fuel 3 1.65E-03 1.90E-04 0.00 y,.

Boiler Melals Zinc lbs/Mnal "' No. 6 fuel oil 27 7.54E-02 2.16E-01 1.00 R&aidual fuel 3 4.51E-02 3.54E-02 1.00 No

Boiler PA'< Acenaphthene lbs/Mgal "' rnual .,.,. }8 2.51E-04 4.14E-04 0.97 Fuel oil 3 2.18E-03 3.51E·03 0.00 y,.

Boiler PA'< Acenaphlhene lbs/Mgal "' .. , ,, *- ;;:19U;;; ;~1~;,,; 1-;;ZMk1 No. 8 fuel oit 30 2.69E-0S 3.43E-05 0.48 y,.

Boiter PA'< Acenaphthene lbs/Mgal "' Diesel 18 2.51E-04 4.1-4E-04 0.97 Reaidual fuel 3 2. lBE-06 1.78E-08 1.00 No

Boiler PA'< Acenaphlhene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-o3 0.00 No. 6 fuel oil 30 2.69E-05 3.-43E-05 0.-48 y,.

Boiler PA'< Acenaphlhene lbs/Mgal "' Fuel od 3 2.16E-03 3.51E-03 0.00 Rnidual fuel 3 2.16E-06 1.7BE-06 1.00 No

Boiler PA'< Acenanhthene lbs/Mnal "' No. 6 fuel od 30 2.69E-05 3.43E-05 0.48 Residual fuel 3 2.18E-06 1.78E-06 1.00 No

Boiler PA'< Acenaphthylene lbs/Mgal "' Diesel 19 1.04E-04 1.4-4E·04_,.. 0.70 Fuel oil 3 2.16E-03 3.!51E·03 0.00 y,.

Boiler PA'< Acenaphthylene lbs/Mgal "' --- ., .: '::;; }it' 'Y.fAU':'. '..fj\dl!!ir',, :o;i.'11 No. 8 fuel oil 30 2.19E-05 -4.16E-05 0.28 y,.

Boiler PA'< Acenaphlhylene lbs/Mgal "' Diesel " 1.04E-04 1.44E-04 0.70 Residual fuel 3 6.4!5E-06 7.-45E-06 1.00 No

Boiler PA'< Acenaphthylene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 2.19E-05 -4.16E-05 0.28 y,.

Boiler PA'< Acenaphthylene lbs/Mgal "' Fuel otl 3 2.16E-03 3.51E-03 0.00 Residual fuel 3 6.4!5E-06 7.-45E-06 1.00 No

Boiler PA'< Acenanhthvlene lbs/Maal "' No. 6 fuel ml 30 2.19E-05 -4.16E-05 0.28 Residual fuel 3 6.45E-06 7.-45E-06 1.00 No

Boiler PA'< Anthracene lbs/Mgal "' Diesel " 3.68E-05 6.0SE-05 0.57 Fuel oil 3 2.16E-03 3.51E-03 0.00 YM

Boiler PA'< Anthracene lbs/M9al "' Diesel 19 3.68E-05 6.0!SE-0!5 0.57 No. 6 fuel oil 30 1.50E-05 2.B0E-05 0.05 No

Boiler PA'< Anthracene lbs/Mg al "' Diesel 19 3.68E-05 6.0SE-05 0.57 Residual fuel 3 7.29E-06 -4.9-4E-06 1.00 No

Boiler PA'< Anthracene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.S0E-05 2.80E-05 0.05 Yoo

Boiler PA'< Anthracene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-03 0.00 Residual fuel 3 7.29E-06 -4.9-4E-06 1.00 No

Boiler PA'< Anthracene lbs/Maal "' No. 6 fuel oil 30 1.50E-05 2.B0E-05 0.05 Residual fuel 3 7.29E·06 4.94E·06 1.00 No

Boiler PA'< Benzo(a)anthracene lbs/Mgal "' Diesel " 2.01E-0S 3.56E-05 0.82 Fuel oil 3 2.16E·03 3.!StE-03 0.00 Yoo

Boiler PA'< Benzo(a)anthracene lbs/Mgal "' Diesel " 2.01E-05 3.56E-05 0.82 No. 6 fuel oil 30 t.48E-0!S 2.82E-05 0.03 No

Boiler PA'< Benzo(a)anthracene lbs/Mgal "' Diesel " 2.01e-os 3.SBE-05 0.82 Residual fuel 3 t.67E-06 9.18E-07 1.00 No

Boiler PA'< Benzo(a)anthracene lbs/Mgal "' Fuel oit 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.48E-05 2.82E-05 0.03 Yoo

Boiler PA'< Benzo(a)anthracene lbs/Mg al "' Fuel oil 3 2.16E-03 3.51E-03 0.00 Residual fuel 3 1.67E-06 9.18E-07 1.00 No

Boiler PA'< Benzolalanthracene lbs/Maal "' No. 6 fuel oil 30 t.-48E-05 2.82E-05 0.03 Residual fuel 3 1,67E-06 9.18E-07 1.00 No

Boiler PA'< Benzo(a)pyrene lbs/Mgal "' Diesel 19 4.-46E-05 1.62E-04 0.01 Fuel oil 3 2.16E-03 3.StE-03 0.00 y,.

Boiler PA'< Benzo(a)pyrene lbs/Mgal "' Die1el 19 4.-48E-05 1.62E-04 0.01 No. 6 fuel oil 30 1.68E-05 2.B0E-05 0.1-4 No

Boiler PA'< Benzo(a)pyrene lbs/Mgal "' Die1el 19 -4.-46E-0S 1.62E-04 0.01 Residual fuel 3 1.73E-06 5.59E-07 1.00 No

Boiler PA'< Benzo(a)pyrene lbs/Mgal "' Fuel oil 3 2.16E-03 3.StE-03 0.00 No. 6 fuel oil 30 t.saE-05 2.80E-05 0.14 y.,

Boiler PA'< Benzo(a)pyrene lbs/Mgal "' Fuel oil 3 2.16E-03 3.SlE-03 0.00 Residual fuel 3 1.73E·08 !5.!59E-07 1.00 No

Boiler PAH Benzo/alnurene lbs/Mnat "' No. 6 fuel oil 30 1.68E-05 2.B0E-05 0.14 Residual fuel 3 1.73E·06 5.59E-07 1.00 No

Bo1ter PAH Benzo(b)lluoranthene lbs/Mgal "' DiHel 19 2.87E-05 9.60E-05 0.03 Fuel oil 3 2.16E-03 3.51E-03 0.00 Ye,

Boiler PA'< Ben:ro(b)lluoranthene lbs/Mgal "' Diesel 19 2.87E-05 9.S0E-05 0.03 No. 6 fuel oil 12 3.54E•0!S 3.62E-05 0.02 No

Boiler PA'< Benzo(b)lluoranthene lbs/Mgal "' Diesel 19 2.B7E-05 9.60E·05 0.03 Residual fuel 3 3.15E-oe 5.73E-07 1.00 No

Boiler PA'< Benzo(b)lluoranthene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-03 0.00 No. e fuel oil 12 3.54E-0S 3.62E-05 0.02 Y• Boiler PAH Benzo(b)fluoranthene lbs/Mgal "' Fuel oil 3 2.16E-03 3.StE-03 0.00 Residual fuel 3 3.1SE-06 5.73E-07 1.00 No

Boiler PA'< Ben:rotblfluotanthene lbs/Moal "' No. 6 fuel oil 12 3.54E-05 3.62E-05 0.02 Residual fuel 3 3.15E-06 5.73E-07 1.00 No

Boiler PA'< Benzolelnvrene lbs/Mnal "' Diesel 3 1 .87E-04 2.99E-04 0.00 No. 6 fuel oit 8 9.-40E-07 9.35E-07 0.00 No

Boiler PA'< Benzo(g.h,i)perylene lbs/Mgal "' Diesel 21 5.54E-05 2.15E-0-4 0.03 Fuel oil 3 2.16E-03 3.51E-03 0.00 Yao

Boiler PAH Benz o( g.h, 1 )perylene lbs/Mgal "' Diesel 21 5.54E-05 2.15E-0-4 0.03 No. 6 fuel oil 30 1.47E-05 2.BtE-05 0.01 No

Boiler PAH Benz o{ g.h, 1 )perylene lbs/Mgal "' Diesel 21 5.54E-05 2.15E-0-4 0.03 Residual fuel 3 3.16E-06 1.02E-06 1.00 No

Boiler PA'< Benzo(g.h.i)perylene 1bs/Mgal "' Fuel o~ 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.47E-05 2.BtE-05 0.01 y.,

Boiler PA'< Benzo(g.h.i)perylene lbs/Mgal "' Fuel oil 3 2.16E-03 3.51E-03 0.00 Reaidual fuel 3 3.16E-08 1.02E-08 1.00 No

64

TABLE A6-1a. MAJOR GROUP COMPARISON (t-stalistica).

System Type Category Substance EF Umt Value Type First Samo! a Statistics Second Sam ~ Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

MateriaVFuel Tvoe Deviation Ratio MateriaVFuel T---- Deviation Ratio g50J,,Conlidenc1 Boiler PAH Benzo/n h i\oervlene lbs/Moal Ef No. 6 tuel oil 30 1.47E-05 2.BtE-05 0.0t Residual fuel 3 3. t6E-06 1.02E-06 1.00 No Boiler PAH Benzo(k)lluoranlhene lbs/Mgal Ef Diesel 19 1.14E-04 2.56E-04 0.66 Fuel oil 3 2.16E-03 J.StE-03 o.oo Ym Boiler PAH Benzo(k)tluoranthene lbs/Mgal Ef Diesel 19 1.14E-04 2.56E-04 0.66 No. 6 fuel oil 12 3.43E-05 J.72E-05 o.oo No Boiler PAH Benzo(k)ftuoranlhene lbs/Mgal Ef Diesel 19 1-1-4E-04 2.56E-04 0.66 Residual fuel 3 6.4BE-07 l.17E-07 1.00 No Boiler PAH Benzo(k)fluoranthene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 12 3.43E-05 l.72E-05 0.00 Y• Bader PAH Benzo(k)fluoranthene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 o.oo Residual fuel 3 6.4BE-07 3.17E-07 1.00 No Boiler PAH Benzolkllluoranthene lbs/Mnal Ef No. 6 fuel oil 12 3.43E-05 3.72E-05 o.oo Residual fuel 3 6.4BE-07 3.17E-07 1.00 No Boiler PAH Chrysene lbs/Mgal Ef Diesel 18 1.35E-05 2.30E-05 0.79 Fuel oil 3 2.16E-OJ 3.51E-03 0.00 Y• Boiler PAH Chrysene lbs/Mg al Ef Diesel 18 t.35E-05 2.30E-05 0.79 No. 6 fuel oil 30 1.72E-05 2.76E-05 0.17 No Boiler PAH Chrysene lbs/Mgal Ef Dieael 18 1.35E-05 2.30E·05 0. 79 Reaidual fuel 3 1.17E-06 7.0SE-07 1.00 No Boiler PAH Chrysene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.72E-05 2.76E-05 0.17 Ym Boiler PAH Chrysene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.StE-03 0.00 Residual fuel 3 1.17E-06 7.0SE-07 1.00 No Boiler PAH Chrvsene lbs/Mnal Ef No. 6 fuel oil 30 t.72E-05 2.76E-05 0.17 Residual fuel 3 1.17E·06 7.0SE-07 1.00 No Boiler PAH dibenz(a,h)anthracene lbs/Mg al Ef Diesel 21 7.49E-05 3.13E-04 0,01 Fuel oil 3 2.16E-03 3.51 E-03 0.00 y .. Boller PAH dibenz(a,h)anthracene lbs/Mgal Ef Diesel 21 7.49E-05 3.13E-04 0.01 No. 6 fuel oil 30 1.46E-05 2.B2E-05 0.00 No Baiter PAH dibenz(a,h)anthracene lbs/Mgal Ef Diesel 21 7.49E•05 3.13E-04 0.01 Residual fuel 3 3.09E-06 1.80E-06 1.00 No Boiler PAH dibenz(a,h)anthracene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.46E-05 2.82E-05 0.00 y .. Boiler PAH dibenz(a ,h)anthracene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 Residual fuel 3 3.09E-06 I.BOE-OS 1.00 No Boiler PAH dibenzla hlanthracene lbs/Mnal Ef No. 6 fuel oil 30 1.46E-05 2.82E-05 0,00 Residual fuel 3 3.09E-06 1.80E-06 1.00 No Boiler PAH Fluoranthene lbs/Mgal Ef Diesel 18 4.27E-05 4.59E-05 l;:;;0,98 Fuel oil 3 2. 16E-OJ 3.SIE-03 0.00 Y .. Boiler PAH Fluoranthene lbs/Mgat Ef ff,'.~;:~:: ;\!:A:·: OlliiltP:j ., :", ·-·,. •Ii\

; ~"" %.-J/4 3,-~, No. 6 fuel oil 30 1.99E-05 2.83E-05 0.37 y,., Boiler PAH Fluoranthene lbs/Mgal Ef Diesel 18 4.27E-05 4.59E-o5 0.96 Residual fuel 3 2.69E-06 3.33E-07 1.00 No Boiler PAH F1uoranthene tbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.99E-05 2.83E-05 0.37 y.,. Boiler PAH Fluoranthene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.SIE-03 0.00 Residual fuel 3 2.69E-06 3.J3E·07 1.00 No Boiler PAH Fluoranthene lbs/Moal Ef No. 6 fuel oil 30 1.99E-05 2.83E·05 0.37 Residual fuel 3 2.69E-06 3.33E-07 1.00 No Boiler PN1 Ftuorene lbs/Mgal Ef D,eael 18 3.63E-04 1.00E-03 0.95 Fuel oil 3 2.16E-03 l.51E·03 0.00 No Boller PAH Fluorene lbs/Mgal Ef Dieael 18 3.63E-04 1.00E-03 0.95 No. 6 fuel oil 30 2_37E-05 3.13E-05 0.41 No Boller PAH Fluorene !bs/Mgal Ef Dtesel 18 3.63E-04 1.00E-03 0.95 Residual fuel 3 3.31E-06 1.73E·06 1.00 No Boiler PAH Fluorene !bs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 2.37E-05 3.13E-05 0.41 y., Boiler PAH Fluorene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E·03 0.00 Residual fuel 3 3.31E-06 1.73E-06 1.00 No Boiler PAH Fluorene lbs/Moat Ef No. 6 fuel oil 30 2.37E-05 3.13E-05 0.41 Residual fuel 3 3.31E·06 1. 73E-06 1.00 No Boiler PAH lndeno( t .2 ,3-cd)pyrene lbs/Mgal Ef Diesel 21 6.12E-05 2.SOE-04 0.02 Fuel 011 3 2.16E·03 3.51E-03 0.00 Yeo Boiler PAH lndeno( l ,2 ,3-cd)pyrene lbs/Mgal Ef Dieael 21 6.12E-05 2.SOE-04 0.02 No. 6 fuel otl 30 1.46E-05 2.B2E-05 0.01 No BOIier PAH lndeno( 1.2,3-cd)pyrene lbs/Mgal Ef Diesel 21 6.12E-05 2.SOE-04 0.02 Residual fuel 3 1.92E-06 1.tOE-06 1.00 No Boiler PAH lndeno( 1.2.3-cd)pyrene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.46E-05 2.B2E-05 0.01 Yeo Boiler PAH lndeno(1.2.3-cd)pyrene lbs/Mg al Ef Fuel oil 3 2.16E-03 3.51E-03 0.00 Residual fuel 3 1.92E-06 1_10E-06 1.00 No Boiler PAH lndeno{1 2 3-cd\nvrene lbs/Moal Ef No. 6 fuel oil 30 1.46E-05 2.82E-05 0.01 Residual fuel 3 1.92E-06 1.IOE-06 1.00 No Boiler PAH Naphthalene lbs/Mgal Ef Dieael 21 3.51E-01 8.84E-01 1.00 Fuel od 3 2.57E-02 1.BOE-02 0.92 No Boiler PAH Naphthalene lbs/Mgal Ef - ,,•<: -.tt ·.·UUiil . .-...,:;.y ;;._,.., No. 6 fuel oil 30 5.68E-03 1.26E-02 1.00 Y• Boiler PAH Naphthalene lbs/Mgal Ef Diesel 21 3.51E-01 B.B4E-01 1.00 Residual fuel 3 1.03E-04 2.33E-05 1.00 No Boiler PAH Naphthalene lbs/Mgal Ef ...... 1f ''C"I,,,:. ,.~ .. ·· . 1.-..,, ii!it.tli No. 6 fuel oil 30 5.88E-03 1.26E-02 1.00 y,.

Boiler PAH Naphthalene lbs/Mgal Ef Fuel oil 3 2.57E-02 1.SOE-02 0.92 R85idual fuel 3 1.03E-04 2.JJE-05 1.00 No Boiler PAH Naohthalene lbs/Mnal Ef No. 6 luel oil 30 5.SBE-03 1.26E-02 1.00 Residual fuel 3 1.03E-04 2.33E·05 1.00 No Boiler PAH Phenanthrene lbs/Mgal Ef Dieael 19 8.BBE-04 2.27E-03 1.00 Fuel oil 3 2.16E-OJ 3.51E-03 0.00 No Boiler PAH Pheoanthrene tbs/Mgal Ef ·,.,·,tX,' ......... ... ~tt. ,,. ...... , ; .. ~ ~S\~Mt!; No. 6 fuel oil 30 3.45E-05 6.47E-05 0.68 Y• Boiler PN1 Phenanthrene lbs/Mgal Ef Dieael 19 8.68E·04 2.27E-03 1.00 Reaidual fuel 3 1.35E-05 6.32E-06 1.00 No

Boiler PAH Phenanthrene lbs/Mgal Ef Fuel oit 3 2.16E-03 3.51E-03 0.00 No. 6 fuel oil 30 3.45E-05 6.47E-05 0.68 Yeo Boiler PAH Phenanthrene lbs/Mga,I Ef Fulll oil 3 2.16E-03 3.51E·03 0.00 Reaidual fuel 3 1.JSE-05 6.J2E-06 1.00 No Boiler PAH Phenanthrene lbs/Maal Ef No. 6 fuel oil 30 3.45E-05 6.47E-05 0.68 Residual fuel 3 1.35E·05 6.32E-06 1.00 No Boiler PAH Pyrerie lbs/Mgal Ef Diesel 18 6.0SE-05 !~91.E..:PS 0.89 Fuel oil 3 2.16E-03 3.51E-03 0.00 Ym Boiler PAH Pyrene lbs/Mgal Ef s!~~i:i,0,: DlllillAt;, ,,. :>".: >-'. '; ~1•, ;;;~;:. ·- - 'Ui,tii'. No. 6 luel oil 30 1.59E-05 2.77E-05 0.10 Y• Boiler PAH Pyrene lbs/Mgal Ef Dieael 18 6.0SE-05 8.97E-05 0.89 Reaidual fu91 3 1.65E-06 4.09E-07 1.00 No

Boiler PAH Pyrene lbs/Mgal Ef Fuel oil 3 2. 16E-03 3.51E-03 0.00 No. 6 fuel oil 30 1.59E-05 2.77E-05 0. 10 y,.

Boiler PN1 Pyrene lbs/Mgal Ef Fuel oil 3 2.16E-03 3.51E·OJ 0.00 Residual fuel 3 1.65E-06 4,QgE-07 1.00 No Boiler PAH Pvrene lbs/Mnal Ef No. 6 fuel oil 30 1.SQE-05 2.77E-05 0.10 Residual fuel 3 1.65E-06 4.09E-07 1.00 No Boiler svoc 2-Chloronanhthalene lbs/Mnal Ef Diesel 3 7.15E-o5 lil.21E·05 0.00 No. 6 fuel oil 6 1.53E-07 1.56E-07 0.00 No

Boiler svoc 2-Melh~ lnaohthalene lbs/Mnal Ef Diesel 3 1.40E-04 3.SOE-05 0.57 No. 6 fuel oil 6 7.99E-05 8_ 17E-05 1.00 No

Boiler svoc Ethvlbenzene lbs/Mnal Ef D"'881 3 1.49E-03 1.99E-04 n.oo No. 6 fuel oil 3 t.42E-03 9.75E-CM 1.00 No

Boiler svoc P8fVlene lbs/Mnal Ef Diesel 3 4.J7E-04 7. lOE-04 0.00 No. 6 fuel oil 8 5.13E-07 t .06E·06 0.00 No

6-5

TABLE A6-1a. MAJOR GROUP COMPARISON (t-atatislics).

System Type Category I Substance EF Unit Value Type First Sa:~e Statistics Second Sampfe Statistics Significant Description

Materi_!_iVFuel Tvoe Size I Av•age I Sta~~rd Detect Description Size Av•age l Standard Detect Difference at

Devtalion Ratio Material/Fuel T _____l_ Deviation Ratio 95%Confidenc

Boller jVOC r~•n• lb,/Mg•I El' □;u,I 3 2.54E-03 3.46E-04 1.00 No. 6 luel oH 29 5.63E·03 8.75E-03 0.84 No Boiler VOC Benzene lbs/Mgal S:: Diesel 3 2.54E-03 3.46E-04 1.00 Residual fuel 3 5.78E-03 0.00E+00 0.00 Y• !!_rn1er VCC _ Benzene lbs/M al S: No. 6 fuel oil 29 5.63E-03 8.75E-03 0.B4 Residual fuel 3 5.78E-03 0.00E+00 0.00 No

Boller VCC Formaldehyde lbs/Mgal s= Di~sel... .· .~8: ,,3-_49E-01_,_ , 5:32E·01, ._L_00 _ Fuel oil 1.00 No Boiler VOC Formaldehyde lbs/Mgal s= ·~" ~ ,·/) ~j~ ,;t'Jilili(;1 !~;';. )aJM .. ,'J, No. 6 fuel oil 0.93 Y• Boiler VOC Formaldehyde lbs/Mgal s= Diesel 1 8 3.49E-01 5.32E-01 1.00 1.00 No Boiler V0C Formaldehyde lbs/Mgal s= Fuel oil 3 2.65E-02 2.40E-02 1.00 No Boiler VOC Formaldehyde lbs/Mgal S:: Fuel oil 3 2.65E-02 2.40E-02 1.00 Boiler VOC Formaldeh de lbs/M al S:: No. 6 fuel oil 24 2.48E·02 3.75E-02 0.93 Boiler VCC Forma1_9eh de lbs/MMe! s= landfill as 3 1.25E-01 7.92E-03 1.00 Boiler s= Diesel 3 1.71E-03 1.51E-04 1.00 Boiler s= Diesel 3 1.S0E-03 1.85E-04 0.38 Boiler s= Diesel 3 1.49E·03 1.99E-04 0.00

Gl!l_menl kiln ===~=~ Coal 6 5.01E-11 4.71E-11 0.23 CemeriJ_k,_ln__ jDioxin&Furan l4DTotal libs/ton production!IF Coal I 6 2.20E-09 2.61E·09 [ 1.00 Coal/coke I 3 I 4.60E-13 3.78E-13 j 0.00 I No Cemen\_k_1ln___ JDioxin & Furan 14F 2378 lbs/ton oroduction EF Coal 6 1.08E-09 1.22E-09 1.00 Coal/coke 3 3.15E-13 I 3.59E·13 I 0.00 I No Ceman! kiln____ \Dioxin & Furan 14F Total lbs/ton oroduction IF Coal 6 4.29E·08 4.81E-08 1.00 Coal/coke 3 3.08E-12 I 2.37E-12 I 0.92 I No Cement kiln __ ]Dioxin & Furan lsD 12378 lbs/ton oroduction s= Coal 6 8.74E-11 7.18E-11 0.60 Coal/coke 3 4.36E-13 I 2.71E-13 I 0.00 I No Cement kiln _ !Dioxin & Furan lso Total lbs/ton oroduction a= Coal 6 1.15E-09 1.15E-09 0.93 Coal/coke 3 4.36E-13 I 2.71E-13 I 0.00 I No Cement kllfl __ !Dioxin & Furan lsF 12378 lbs/ton oroduction s= Coat 6 4.30E-10 5.00E-10 0.99 Coal/coke 3 3.25E-13 I 1.73E-13 I 0.00 I No Cement k1jn___ Jpioxm & Furan lsF 23478 lbs/ton oroduction s= Coal 6 5.66E-10 6.37E-10 1.00 Coal/coke 3 3.25E-13 I 1.73E-13 I 0.00 I No Cement kiln I Dioxin & Furan lsF Total lbs/ton oroduction s= Coal 6 7.58E-09 8.89E-09 1.00 Coal/coke 3 3.25E-13 I 1.73E-13 I 0.00 l No Cement ktln lD_iox1n & Furan lsD 12347B lbs/ton oroduction s= ;,;-~, · ,.....,.-.,., : "'"' Coal/coke 3 4.36E-13 I 2.76E-13 I 0.00 I Y• C.!_menl kiln _ _ /Dioxin & Furan lso 123678 libs/Ion nroduction EF Coal 6 6.45E-11 5.39E-11 0.87 Coal/coke 3 4.36E-13 I 2.76E-13 I 0.00 l No Cement kiln _ ]Dioxin & Furan 16D 123789 libs/Ion nroduction EF Coal 6 9.0SE-11 7.76E-11 0.60 Coal/coke 3 4.36E·13 I 2.76E-t3 I 0.00 I No Cement ktln _ ]Dioxin & Furan 160 Total libs/Ion nroduction a= Coal 6 8.97E-10 9.46E-10 0.99 CoaVcoke 3 4.36E-13 I 2.76E•t3 I 0.00 I No Cement kiln I Dioxin & Furan 16F 123478 libs/Ion nroduchon EF Coal 6 3.96E-10 5.14E-10 0.99 Coal/coke 3 3.27E·13 I 2.40E-13 I 0.00 l No Cement kiln I Dioxin & Furan 16F 123678 I tbs/Ion nroduction e= Coal 6 1.37E-10 1.66E-10 0.98 Coat/coke 3 3.27E-13 I 2.40E-13 I 0.00 I No Cement kiln I Dioxin & Furan 16F 123789 libs/Ion nroduction s= , - ,........_ C: (e.,,. Coal/coke 3 3.27E-13 I 2.40E-13 I 0.00 I Yf//8

Cement kiln I Dioxin & Furan )6F 234678 fibs/ton produclionjs= ! Coal I 6 1.32E·10 I 1.53E-10 I 0.97 Coal/coke I 3 I 3.27E-13 2.40E-13 I 0.00 j No Cement ki!n ID1ox1n & Furan l6F Total llbs/ton produclionjs= Coal I 6 1.51E-09 j 1.96E-09 I 1.00 Coal/coke ! 3 I 3.27E-13 2.40E-13 I 0.00 No Cement kiln IDioxm & Furan 170 1234678 !lbs/ton productionlB= Coal I 6 2.61E·10 2.61E·10 I 0.99 Coal/coke I 3 j 3.21E-12 9 SSE-14 I 1.00 No Cement kiln jDioxm&Furan l7DTotal libs/ton productionlB= Coal 6 I 5.71E-10 5.80E-10 1.00 Coal/coke j 3 I 5.65E-12 6.39E-13 j 1.00 No Cement kiln I Dioxin & Furan l7F 1234678 libs/ton productionlB= Coal I 6 I 1.10E-10 1.07E-10 0.97 Coal/coke j 3 j 6.55E•13 2.83E-13 j 0.00 No Cemenl kiln /D1oxm & Furan (7F 1234789 (lbs/ton producllon(S: ( Coal f 6 j 3.57E-11 ( 2.59E-11 ( 0.29 ( Coal/coke j 3 ( 6.55E-13 ( 2.83E-13 ( 0.00 I No Cemenl kiln joioxin & Furan l7F Total libs/ton production!S: Coal I 6 J 1.44E-10 1.47E-10 0.97 ! Coal/coke I 3 I 6.55E-13 2.83E-13 j 0.00 I No Cement kiln ID,oxin & Furan j8D libs/ton product,on!s= Coal 6 I 4.97E-10 4.54E-10 1.00 ! Coal/coke I 3 I 3.01E-11 I 5.40E-12 I 0.60 I No _Cement kiln !Dioxin & Furan \SF libs/ton production!s= Coal J 6 I 9.08E-11 8.83E-11 0.63 j Coal/coke I 3 I 1.26E-12 I 6.95E-13 I 0.00 I No Ce!flent kiln !Metals !Arsenic jibs/ton produclion!Er I Coal 6 I 3.02E-06 I 2.76E-06 0.81 Coal/coke I 3 I 2.59E-06 I 3.08E-07 I 0.00 I No Cement kiln !Metals !Beryllium jibs/ton production!s= ! Coal I 6 2.25E-06 I 2.75E-06 I 0.90 Coal/coke 3 I 5.03E·06 6.23E-07 0.00 I No Cement kiln !Metals ICadm,um llbs/ton productionjs= j Coal I 6 1.46E-06 I 8.87E-07 I 0.51 CoaVcoka 3 I 2.90E-07 I 2.38E-07 1.00 I No Cement kiln Metals Chromium lbs/ton roduction s= Coal 5 2.43E-06 1.19E-06 1.00 4.43E-07 1.00 No Cement k1!n Metals Chromium Hex lbs/ton roduction EF Coal 3 6.70E-07 1.70E-07 1.00 _ Y• Cement kiln Metals C er lbs/ton roduction EF Coal 6 8.00E-06 3.22E-06 0.62 Coal/coke 3 3.81E·06 9.40E-07 1.00 No Cement kiln Metals Lead lbs/ton roduction EF Coal 6 9.70E-05 1.36E-04 1.00 CoaVcoka 3 1.24E·06 9.66E·07 1.00 No Cement kiln Metals Ma anese lbs/ton roduction IF Coal 6 5.51E-04 1.20E-03 1.00 CoaVcoke 3 8.85E-06 1.32E-06 0.00 No Cement kiln Metals Mercu lbs/ton roduction s= ;;~·- ''I; Coal/coke 3 3.83E-06 9.60E-07 1.00 Y• Cement kiln Metals Nickel lbs/ton roduction a= Coal 5 5.44E·06 5.42E-06 1.00 Coal/coke 3 2.60E-0S 3.18E-06 0.00 Y@ Cemenl kiln jMetals !Selenium jibs/ton production!IF Coal j 6 I 5.91E-06 8.21E-06 0.91 I CoaVcoke I 3 I 3.78E-08 I 7.98E-07 I 1.00 I No Cement kiln !Metals !Zinc [tbs/ton productionllF Coal I 6 j 1.34E-03 1.54E-03 1.00 I Coal/coke I 3 I 1.02E-05 I 3.59E-06 1.00 I No Cement kiln jPN-i fAcenaphthene pbs/ton productionlB= Coal I 6 7.80E·06 8.60E·06 1.00 I Coal/coke I 3 I 1.95E-07 I 1.91E-07 I 0.69 j No Cement kiln IPAH fAcenaphthylene lfbs/ton produclion!s= Coal I 6 I 2.35E-07 3.32E-07 1.00 I Coal/coke I 3 I 2.21E-06 I 3.12E-06 j 1.00 I No Cement kiln IPAH jAnlhracene pbs/ton produclionlEF Coal j 6 I 2.84E-06 I 3.S9E-06 I 1.00 I Coal/coke I 2 I 1.25E-07 I 1.70E·07 0.98 I No Cemenl kiln P.AH Benzo a anthracene lbs/ton roduction a= Coal 6 2.11E-07 2.CME-07 1.00 CoaVcoke 1.00 No Cement kiln PAH Benzo a rene lbs/ton roduction EF rt/' CoaVcoke 1.00 Y• Cement kiln_ PAH Benzo b fluoranthene lbs/ton roduction Er Coal 6 1.75E-07 2.40E-07 1.00 Coal/coke ~~==~ 0.12 No Cement kiln PAH Coat 4 1.12E-08 6.87E-09 0.02 Coal/coke 3 1.45E-09 4.0SE-10 1.00 No Ceme,:il __ l(jln_ PAH Coal 6 1.27E-08 1.41E-08 0.75 CoaVcoke 3 3.88E-OV !.67E-09 0.51 No C!!!flent kiln__ JP_.AH IChrysena llbs/ton produclionjs= I Coal 6 I 1.16E-06 I 1.7gE-06 I 1.00 I Coal/coke J 3 I 3.0JE-09 I 8.66E-10 I 1.00 I No

6-<i

TABLE A6-1 a. MAJOR GROUP COMPARISON (t-statistice).

System Type Category Substance EFUnit Value Type First Sam11le Statistics Second Sam le Statistics Significant Description Size Average Slandard Detect Description Size Average Standard Detect Difference at

Material/Fuel Tv.-.e Deviation Ratio MateriaVFuel T Deviation Ratio 95%Confidencm

Cement kiln P,'J-i dIbenz1a h'anthracene lbs/ton oroduction EF Coal 3 1.46E-08 6.22E-10 0.00 Coal/coke 3 1.19E-09 ".73E-10 1.00 v .. Cement kiln P,'J-i Fluoranthene lbs/ton oroduction EF .. . ;,';:•· "~' INt, Coal/coke 3 1.64E-07 8.90E-08 1.00 v .. Cement kiln P,'J-i Fluorene lbs/ton oroduclIon EF Co~ 6 9.59E-07 5.SSE-07 t.oo Coal/coke 3 3.StE-07 ?.94E-07 1.00 No

Ceman! kiln P,'J-i lndeno'1 2 3-cd'""rene lbs/ton oroduction EF Coal 5 9.SSE-09 6.78E-09 0.09 Coal/coke 3 1.a2E-09 7.12E-10 1.00 No

Cement kiln P,'J-i Nanhthalene lbs/ton oroduction EF Coal 6 1.64E-OS 2.00E-06 1.00 Coal/coke 3 3.24E-05 3.68E-05 1.00 No

Cement kiln P,'J-i Phenanthrene lbs/ton nroduction EF c~ 6 3.68E·06 1.31E-06 1.00 Coal/coke 3 7.44E-06 7.98E-06 1.00 No

Cement kiln P,'J-i P"rene lbs/ton oroduction EF c~ 6 2.03E-06 1.71E·06 1.00 Coal/coke 3 8.24E-08 4.87E-08 1.00 No

Cement kiln voe Benzene tbs/ton nroduction EF Coal 3 1.◄0E-03 6.04E-04 0.00 Coal/coke 3 2.99E·04 7.47E-05 1.00 v .. Cement kiln voe Formaldeh··de lbs/ton nroduction EF Coal 6 5.72E-05 4.HE-05 ~.:~- No

Coating operation Metals Chromium lbs/gal pamt EF 15"4 Cr 12 1 .62E-04 1.20E-04 v .. Coating operation Metals Chromium lbs/gal paint EF 15"4 Cr 12 1.62E-04 t.20E-04 0.92

4 ~ v .. Coatinn o,..eration Metals Chromium lbs/"al nainl EF 25-35"4 Chromate 20 8.45E-04 7.49E-04 0,96 ~ '¥•\c "~ v .. Coatmg operation Metals Chromium lbs/lbs powder EF 100% Chromium Oidde 1 1.42E-01 1.00 49% Ni. 44% Cr 1 4.02E·04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 100% Chromium Oxide 1 1.42E·01 1.00 70% Ni, 4% Cr 1 1.86E-04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 100% Chromium Oxide 1 1.42E-01 1.00 75% Cr3C2, 20% NiCr. 5% Cr 1 3. 75E-01 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 100% Chromium Oxide 1 1.42E-01 1.00 BO% Ni, 20%Cr 1 1.86E·03 1.00 NA

Coaling operation Metals Chromium lbs/lbs powder EF 100% Chromium Oxide 1 1.42E-01 1.00 B7% Al203. 13% Ti02 1 3.48E·04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 49% Ni. 44o/~ Cr 1 4.02E-04 1.00 70% Ni. 4% Cr 1 1.86E·04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 49"4 Ni, 44% Cr 1 4 .02E-04 1.00 75% Cr3C2, 20"4 NiCr, 5% Cr 1 3.75E-01 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 49% Ni, 44% Cr 1 4.02E•04 1.00 80% Ni, 20%Cr 1 1.86E-03 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 49% Ni. 44% Cr 1 4.02E-04 1.00 87% Al203, 13% Ti02 1 3.48E-04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 70% Ni. 4% Cr 1 1.86E-04 1.00 75% Cr3C2, 20% NiCr. 5"4 Cr 1 3.7SE-01 1.00 NA

Coating operation Melals Chromium lbs/lbs powder EF 70% Ni, 4% Cr 1 1.86E-0-4 1.00 80% Ni, 20%Cr 1 1.86E-03 1.00 NA

Coaling operaIIon Metals Chromium lbs/lbs powder EF 70% Ni. 4% Cr 1 1.B6E•04 1.00 87% Al203, 13% Ti02 1 3.48E·04 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 75% Cr3C2. 20'% NiCr. 5% Cr 1 3.7SE-01 1.00 80% Ni, 20%Cr 1 1.86E-03 1.00 NA

Coating operation Metals Chromium lbs/lbs powder EF 75% Cr3C2, 20'% NiCr. 5% Cr 1 3.75E-01 1.00 87% Al203, 13% Ti02 1 3.48E-04 1.00 NA

Coatin,.. oneration Metals Chromium lbs/lbs "OWder EF 80% Ni 20%Cr 1 1.B6E-03 1.00 87% AI203 13% Ti02 1 3.48E-04 1.00 NA

Coaling operation Metals Chromium (He)() lbs/gal paint EF 15% Cr 12 6.47E-05 8.-49E-05 1.00 ' ' -~~1,1:~.~.~~:~·:'.<:::· >at. :~Uf ........ :,.-: v .. Coaling operation Metals Chromium (He)() lbs/gal paint EF 15% Cr 12 6.47E-05 8.49E-OS 1.00 ,:.4' 1Al!liMt. ;~)!: v .. Coatma ooeration Metals Chromium 1He)(I lbs/nal naInt EF 25-35% Chromate 20 6.tOE-04 5.BOE-04 1.00 ,,.s· -;..~...,;;,, v .. Coaling operahon Metals Chromium (Hex) lbs/lbs powder EF 100% Chromium Oxide 1 8.91E-03 1.00 49% Ni, 44"4 Cr 1 3.ooE-04 1.00 NA

Coating operation Metals Chromium {Hex) lbs/lbs powder EF 100% Chromium Oxide 1 8.91E-03 1.00 70% Ni, 4% Cr 1 1.81E-04 1.00 NA

Coating operation Metals Chromium (Hex) lbs/lbs powder EF 100"4 Chromium Oxide 1 8.91E-03 1.00 75% Cr3C2, 20% Ni Cr. 5"4 Cr 1 1.63E-02 1.00 NA

Coating operation Metals Chromium (Hex) lbs/lbs powder EF 100"4 Chromium Oxide 1 8.91 E-03 1.00 BOo/& Ni, 20%Cr 1 2.58E-04 1.00 NA

Coahng operation Metals Chromium (He)() lbs/lbs powder EF 49% Ni, 44"4 Cr 1 3.00E-04 1.00 70% Ni. 4% Cr 1 1.81E•04 1.00 NA

Coaling operation Metals Chromium (Hex) lbs/lbs powder EF 49% Ni. 44"4 Cr 1 3.00E-04 1.00 75% Cr3C2, 20% NiCr, 5% Cr 1 1.63E·02 1.00 NA

Coatmg operahon Metals Chromium (Hex) lbs/lbs powder EF 49% Ni, 44"4 Cr 1 3.00E-04 1.00 80% Ni. 20%Cr 1 2.58E-04 1.00 NA

Coating operatrnn Metals Chromium \Hex) lbs/lbs powder EF 70% Ni, 4"4 Ct 1 1.81E-04 1.00 75% Cr3C2, 20% NiCr, 5% Cr 1 1.63E-02 1.00 NA

Coating operation Metals Chromium (Hex) lbs/lbs powder EF 70% Ni, 4"4 Cr 1 t.atE-04 1.00 80% Ni. 20%Cr 1 2.58E-04 1.00 NA

Coatin.-. onerat1on Metals Chromium 'Hex' lbs/lbs nowder EF 75% Cr3C2 20% NiCr 5"4 Cr 1 1.63E-02 1.00 80% Ni 20%Cr 1 2.58E-04 1.00 NA

FlmdIzed bed combuslor D1o)(in & Furan 4D 2378 lbs/ton EF Agricultural wa1te 3 4.46E-10 4.17E-11 0.00 Coal 15 7.00E-10 9.00E-10 0.00 No

Fluidized bed combtJslor DioKin & Furan 4D 2378 lbs/Ion EF Agricultural waste 3 4.46E-10 4.17E-1t 0.00 Wood waste 3 2.89E-11 1.0JE-11 0.00 v .. Fluidized bed combustor Dioxin & Furan 4D 2378 lbs/ton EF Coal 15 7.00E-10 9.00E-10 0.00 Wood waste 3 2.89E-11 1.03E·11 0.00 Nn

Fluidized bed combustor Dioxin & Furan 4D Total lbs/ton EF . . -· ,••--: Coal 15 7.46E-10 8.94E·10 0.00 Y• Fluidized bed combuslor DIoxm & Furan 4F 2378 lbs/ton EF Agricultural Watte 3 3.20E-09 2.68E-09 1.00 Coal 15 1.24E·09 1.75E-09 0.0-4 No

Fluidized bed combustor Dioxin & Furan 4F 2378 lbs/Ion EF Agricultural Walle 3 3.20E-09 2.88E-09 1.00 Wood waste 3 1.29E·10 5.25E-11 1.00 No

Fluidized bed combustor Dioxin & Furan 4F 2378 lbs/ton EF c~ 15 1.24E-09 1.75E-09 0.0-4 Wood waste 3 t.29E-10 5.25E-11 1.00 No

Flu1d1zed bed combustor Dioxin & Furan 4F T"lal lbs/ton EF ., ... ,. , .. ,, Coal 15 2.03E-09 2.17E·09 0.45 v ..

FluIdIzed bed combustor Dioxin & Furan SD 12378 lbs/ton EF Agricultural waste 3 1.10E·09 1.61E·10 0.28 c~ 15 3.SOE-09 8.36E·09 0.00 No

Fluidized bed combustor Dioxin & Furan SD 12378 lbs/Ion EF .............. :/ .. -:•: '.l"ffliilliii':: ,,1ij&fr!' a:;a:, Wood waata 3 3.28E-11 1.1-4E·11 0.00 Ym Fluidized bed combustor Dioxm & Furan so 12378 lbs/ton EF c~ 15 3.SOE-09 B.36E·09 0.00 Wood waste 3 3.28E·11 1.UE-11 0.00 No

Fluidized bed combustor Dioxin & Furan SD Total lbs/ton EF ';',•;;>, " : Coal 15 3.SSE-09 8.34E·09 0.01 v ..

Fluidized bed combustor Dioxin & Furan SF 12378 lbs/ton EF AJ;lricultural wa~le 3 3.09E-09 1.30E-09 1.00 Co~ 15 1.31E-09 2.31E·09 0.09 No

Fluidized bed combustor Dioxin & Furan SF 12378 lbs/Ion EF .,,.,~ .... ,-....... < :•C 7J~ :\\tlli:iiZt• 'Itr.- Wood waste 3 6.27E-11 2.28E-11 1.00 Ym

Fluidized bed combustor Dioxin & Furan SF 12378 lbs/ton EF Coal 15 t.3tE-09 2.3tE-09 0.09 Wood waste 3 6.27E-11 2.28E-11 1.00 No

Fluidized bed combustor Dioxin & Furan SF 23478 lbs/ton EF Agric_ultu~at_ wa~te 3 4.4BE-09 2.42E·09 1.00 c~ 15 1.38E-09 2.JOE-09 0.15 No

Fluidized bed combuslor Dioxin & Furan SF 23478 lbs/ton EF >:., <1411"•·- .. :t: . : ~": it.,_t, ~:•;<' Wood waste 3 1.03E·10 2.6UE-11 1.00 v .. Fluidized bad combustor DIoxm & Furan SF 23478 lbs/ton EF c~ 15 1.38E-09 2.30E-09 0.15 Wood waste 3 1.03E·10 2.sgE-11 1.00 No

Fluidized bed combustor Dioxin & Furan SF Total lbs/Ion EF ,:J1!8l:i:::aj; -~, ., :B Coal 15 3. lOE-09 4.34E-09 0.60 v-

f,.7

System Type

Flu1d1zed bed combustor Fluidized bed combustor Fluidized bed combustor

Fluidized bed combustor Fluidized bed combustor Fluidized be~ combustor Fluidized bed combustor Fluidized bed combustor

Fluidized bad combustor Fluidized bed combtJ~!Q! Fluidized bed combustor Fluidized bed combustor

f.!.\!.!dized b~Q_fombustor Fluidtzed bed combustor Fluidized bed combustor

Fluidiz1t~ bed combustor Fluidized bed combustot Fluidized bed combustot Fluidized bed combustor Fluidtzed bed combustor Flutdized bed combustor Fluidized bad combustor

fluidized bed combustor Fluidized bed combustor

Flu1d1zed bed combustor Fluid1zed bed combuslor Flu1d1zed bed comt;>_u_stor Fluidized bed combustor Fluidized bad combustor Fluidized bed comtiustor Flu1d1zed bed combustor Flu1d1zad bed combustor Fluidized bed combustor Fluidized bed comt,ustor Fluidized bed combus!or

Fluidized bed combuslor Flmd,zad ~~d combustor Fluidized bad combustor Fluidized bed combustor Fluidized bed combustor Fluidized bed combustor

Fluidized bed combustor Flu_i_,;lized bed combus!pJ Fluidized bed combustor Fluidized bed combustor

Fluidized bed combustor FluidtZI!:~ bed combustor Fluidized bad combustor

Fluidized bed combustor Fluidized ti_ed combustor Fluidized bed combustor

Fluidized bed combustor Fluidized bed combusto_r Fluidized bed combustor

Fluidized bed combustor Fluidized ti_ed combustor Fluidtzad bed combustor Fluidized bed combustor Fluidized beg_.f.Q.mbustor

Category Substance

Dioxin & Furan 60 123478 Dioxin & Furan 60 123478

Dioxin & Furan 6D 123471! Dioxin & Furan 6D 123678 Dioxin & Furan 60 12367B Dioxin_& Furan 60 12367B

Dioxin & Furan 6D 123789 Dioxin & Furan 6D 123789 Dioxin & Furan 6D 123789

_Q_ioxin ~- Furan 6D Total Dioxin & Furan 6F 123478

Dioxin & Furan 6F 123478 Dioxin & Fu ran _ 6F 1 ~4 78 Dioxin & Furan 6F 123678 Dioxin & Furan 6F 123678 D_ioxin & Furan 6F 123m Dioxin & Furan 6F 1237B9 Dioxin & Furan 6F 123789 _Q_ioxin &_Furan 6F 123789

Dioxin & Furan Dioxin & Furan Dioilin & Furan Dioxin & Fura.r::t Dioxin & Furan 7F 1234678 Dioxin & Furan 7F 1234678 .QMin & Furan 7F 12346~ Dioxin & Furan 7F 1234789 Dioxin & Furan 7F 1234789

_Q.!Q_xin & Furan 7F 1234]~ Dioxin & Fura[llIE__!.olal Dioxin & Furan 8D Dioxin & Furan 8D

P1oxm & Furan BD

D,.·ox1.·n & F.uran 1•• Dtoxm & Furan SF

_Q1oxm & fi,,[email protected] ~ Halogens Halogens _tl~ogens

~ns Metals Metals

M~~! Metals Metals

!,1~1-~ Metals Melals

l!4~tals Metals Metals

~eta~_ Metals Metals

~tals

HCI HCI HCl

l£ Arsenic Arsernc Arsen_k

Beryllium Beryllium

~lliu.m_ Cadmium Cadmium

Cadmium Chromium Chromium

ChromjlJ!!! Chromium (Hex) Chromium (Hex)

Chromium--1.t!fil

EF Unit

lbs/ton lbs/ton

lbsl'-2..!1 lbs/ton lbs/ton

lbs/ton lbs/ton lbs/ton lbs/ton

!bs/lon_ lbs/ton lbs/ton

lbs/to!:!_ lbs/ton lbs/ton lbs/Ion lbs/ton lbs/ton

lbs/ton lbs/Ion

lbs/Ion lbs/ton lbs/tQ.!1 lbs/ton lbs/ton lbs/ton lbs/l_Qf!. lbs/Ion lbs/ton

lbslt.Qn lbs/ton lbs/ton lbs/Ion

lbs/JQ.!1 lbs/ton lbs/ton lbs/ton

lbs/ton lbs/ton

.!.!2.!L!C?ll lbs/ton lbs/ton

lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton

lbs/ton lbs/Ion

lbs/Ion lbs/ton lbs/ton

lbs/lc;i..[1 Iba/Ion lbs/ton

lbs/ton lbs/ton

lbs/ton lb_!/tof!_

TABLE A6-1a. MAJOR GROUP COMPARISON (t-statiatica).

Value Type First Sa le Statistics Second Sam le Statistics

El' El' ~ El' El' §' El' El' §' El' El' El' §' El' El' §' El' El' [I' El' El' §' §' El' El' §' §' El' El' El' El' El' El' §' El' El' ~ El' El' §' El' El' §' §' El' El' ~ El' El' El' El' El' §' El' El' El' El' El' §'

Description Size Average Standard Detect Description Size Av•age Standard Detect MateriaVFuel T Deviation Ratio MateriaVFuel T P~la_!l_Q!l__ _ Ratio

Agricultural waste 3 1.22E-09 4.69E-10 0.00 Coal J 15 l 2.92E·::U_8.68E-09 0.01 Agricultural waste 3 1.22E-09 4.68E-10 0.00 Wood waste . 3 4.3.6E-11 4.88E·12 0.29

Coal 15 2.92E-09 6.68E-09 0.01 Wood waste ~ _ 4~3.fil;-11 4.BBE-12 0.29 Agricultural waate 3 1.27E-09 4.45E-10 0.00 Coal 15 2.94E-09 6.67E-09 0.01 Agricultural waste 3 1.27E-09 4.45E-10 0.00 Wood wuta 3 6.38E-11 2.75E-11 0.50

Coal 15 2.94E·09 6.67E-09 0.01 Wood waste 3 6.38E·11 2.75E-11 0.50

Agricultural waste 3 1.15E-09 I 5.30E-10 0.00 Coal 15 2.92E-09 6.68E-09 0.01 Agricultural waste 3 1.15E-09 5.30E·10 0.00 Wood wasle 3 4.77E-11 8.28E-12 0.40

C~ 15 2.92E-09 6.GBE-09 0.01 Wood waste 3 4.77E-11 8.28E-12 0.40

Agricultural waste 3 1.53E·09 6.21E-10 1.00 ~,fi'$17@U!IJll't'f , . . " ' , . , , Coal 15 1.89E-09 3.23E-09 0. 13

~griculturat_waste_··· 1--3-. l ... 1_.5~E. -~9.· j 3._91E·19 I. 1 .. 00 ~,,, t: : t\ : :, .• ~'"f :,iu,w:hf : . .1.t11li

Co~ Agricultural waste Agricultural waste

1 5 I 1.98E-09 I 3.23E-09 j 0. 1?

3 I 6.51E-10 I 5.42E-10 I 0.00 3 6.51E-10 5.42E-10 0.00

Coal_ I 15 I 1.85E-09 I 3.24E-09 I 0. 11 Agricultural waste 1.40E-10 1.00 ;ljr · 1 ·,·,:11YiMt;~:::· ·:<.,--.'4);:t tz:t•: ~ 3.34E-09 0.28

i½ccli::t,;; A~ricuttural waste 1. 00

~~Tk:;: ';~ Coal 0.25 ---- -tM1·

Agricullural waste .......... Coal

Agricultural waste Agricultural waste

Coal Agricultural waste

'Aallc~ -~ _Q~ Agricultural waste Agricultural w111t11

Coal -Agricultural waste

Co~


Coal Agricultural waste

Agricultural waste

Coal Agncultural waste Agricultural waale

Coal Agricultural waste Agricultural waste

Coal Agricultural waste Agricultural wHte

Coal

3

p li

7.32E·09 I 1.09E-09 1.00 .r.il.- 't ..... ::. 1M 6.16E·09 9.41E-09 0.53

3 7.43E·10 5.89E-10 0.63 3 7.43E·10 5.89E-10 0.63

1 5 3.28E·09 6.40E-09 0.12 9.79E·09 3.22E-09 1.00

.. 1. ,~_e" 1~2;;~ i ·--' . t-'- .. f»:

15 1.36E-Q_Q 2.13E-08 0.41

3 5.24E•09 3.44E-09 0.81 3 5.24E•09 3.44E-09 0.81 15 1.41E-08 3.0◄ E-08 0.18

·•1 r~ ~·11.-3 7.21E-02 3.55E-02 1.00 15 2.29E-02 1.21E-02 L_O_Q_

3 2.35E-05 o.oo 3 2.35E-05 0.00

15 4.43E-05 0 43 3 2.16E·06 1.02E-07 0.00 3 2.16E-06 1.02E-o7 0.00

15 3.43E-06 4.23E-06 0.00 3 8.87E·05 1.17E-04 0.00

3 8.87E-05 1.17E-04 o.oo .1_5 1.19E-05 6.36E-06 0.35

312.BBE-06 t.35E-06 0.52 3 2.88E·06 1.35E-06 0.52 li _ 4.37E-05 6.72E·05 0,9~ 3 4.28E-05 6.16E-08 0.00

3 4.28E-05 e.1eE-08 0.00 15 1.65E-05 1.37E-05 0.47

(>8

Coal 15 3.44E-09 6.63E-09 0.16 Coat 15 1.89E-09 3.23E-09 0.13

Wood wasts 3 7.59E-11 3.95E-11 t.00 '!'f9od waste 3 7.59E-11 ~95E-11 1.00

Coal 15 1.98E-0V 3.23E-0V 0. 17 Wood waste 3 1.12E-10 5.11E-11 1.00 Wood waste 3 1.12E-10 5.11E-11 1.00

Coal J 15 1.85E-09 3.24E-09 0.11 Wood waste 3 2.77E-11 2.63E·11 0.70

W~.W~I!~--- _ 3 2.77E-11 2.63E-11 0.70 Coal 15 2.28E-09 3.34E-09 0.28

Wood waata 3 3.02E-10 2.69E-10 1.00 Wood waste 3 3.02E-10 2.69E-10 1.00

Coal 15 5.06E-09 J;l,2J£.:~- 0~7 Coal 15 3.70E-09 6.33E-09 0.25

Wood waste 3 e.90E-10 2.02E-10 1.00 Wood waste 3 6.90E-10 2.02E-10 1.00

Coal 15 4.70E-09 6.68E-09 o.~Q

Coal 15 6.16E-0V 9.41E-09 I 0.53 Wood waste 3 1.37E-0V 1.44E-09 1.00 Wood waste 3 1.37E-09 1.44g-o~ 1.00

Coal 15 3.28E-09 6. ◄ 0E-09 0.12 Wood waste 3 8.97E-11 9.71E-11 0.92 Wood waate 3 8.97E-11 9.71E-11 0.92

Coat 15 9.04E-09 1.52E·08 0.68 Coal 15 1.36E-08 2.13E-08 0.41

Wood waste 3 6.89E-09 2.53E-09 1.00

_Wood~ 3 6.89E-09 2.53E-09 1.00 Cool

Wood waste Wood waste

"°" c ...

"'·~" ' Cob

"°" Coke

Cob Coal Cob c ... ea. c ... Cob Coal

c ... Coal c ... Coke

"I 1..,1El,OB .3.04E-08.J 0.18 3 1.61E-CK> 1.85E-09 1.00

3 1.61 E-09 1.B5E:Q.9 _ 1 . .9.9

'. ·.1 ...... • .. 29E-02 L1.2.1E-02l ... 1..00 6 7.37E-02 5.18E-02 1.00 I -a·· ,:1'~ . ., ..... t" .·::r~~

6 7.10E·CM 1 5 3.40E-05 6 4.62E-05 6 4.62E-05

15 3.43E·08 8 2.14E-08 6 2.14E-06

15 1.19E-05

6 1.69E-05 6 1.69E-OS

4.37E-05 ··;ii~

1.0tE-05 15 1.65E-05 6 9.31E-06

1J 9.31E·06

8.24E·CM 0.98 4.4:IE-05 0.43 4.39E-05 0.93 _!.39E-05 0.93

4.23E·08 0.00 1.11E-08 0.00 1.11 -06 O,QQ_ 6.36E-08 0.35 8.82E-08 0.64

8.62E-06 0.64

6.72E-05 J 0.lil9

3.93E·06 I 1.00 1.37E-05 0.47 2. 72E-08 0.00

2.72E-06 0.00

Significant

Difference at 95%Confidence

No Ym ]'lg_ No

Y• No

No y,. _!li_Q_

v. No Yeo _N_Q_

No

Y• No No No

]'lg_ No Yeo

_!li_Q_ y,. No Yeo

No

Y• No Ym No No No No

!1!, YM y,.

]'lg_ No No No

Y• No

YM Y• No No

]'lg_

No No

!!o Ye No No No

Yeo

]'lg_

Y• Y• ]'lg_

TABLE A6-1a. M.6JOR GROUP COMPARISON {t-etatistics).

System Type Category Substance EF Unit ValU8 Type First Samo e Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect 0iHerence at

MaleriaVFuel Tv"e Deviation Ratio MateriaVFuel T·-~ Deviation Ratio 95%Conlidenc1 Fluidized bed combuslor Metals Copper lbs/ton EF Agricultural waste 3 6.15E-05 2.11E-05 1.00 Coal 15 1.33E-04 1.31E-04 o_gg No Fluidized bed combuslor Metals Copper lbs/ton EF Agricultural wasle 3 6.15E-05 2.11E-05 1.00 Coke 6 7 .95E-05 4.B2E-05 1.00 No Fluidized bed ccmbustor Metals c""'"'er lbs/ton EF Coal 15 1.33E-04 1.31E-04 0.99 Coke 6 7 .95E·05 4.B2E·05 1.00 No Fluidized bed combustor Metals Lead lbs/ton EF Agricultural waste 3 6.54E·05 3.40E·06 0.00 Coal 15 6.13E-05 7.56E-05 0.7B No Fluidized bed combustor Metals Lead lbs/ton EF Agricultural waste 3 6.~E-05 3.40E-08 0.00 Coke 6 1.57E·04 1.B6E-04 1.00 No Fluidized bed combustor Metals Lead lbs/ton EF Coal 15 6.13E-05 7.56E-05 0.78 Coke 6 1.57E-04 1.86E-04 1.00 No Fluidized bed combustor Metals Manganese lbs/Ion EF Agricultural waste 3 2.86E-04 3.84E-04 1.00 Coal 15 2.10E-0J 7. 70E-03 1.00 No Fluidized bed combustor Metals Manganese lbs/Ion EF Agricultural wasle 3 2.BSE-04 3.84E-04 1.00 Coke 6 1.32E-04 1.07E-04 1.00 No Fluidized bed combustor Metals Manoanese lbs/ton EF Com 1 5 2. t0E-03 7.70E-03 1.00 Coke 6 1.32E-04 1.07E-04 1.00 No Flu1d1zed bed combustor Metals Mercury lbs/ton EF Agricultural waste 3 1.92E·04 1.13E·04 1.00 Coal 15 2.57E-04 4.56E-04 0.09 No Flu1d1zed bed combustor Metals Mercury lbs/ton EF Agricultural waste 3 1.92E-04 1.1JE·04 1.00 Coke 6 1.25E-03 1.47E-03 0.00 No Fluidized bed combuslor Metals Mercurv lbs/ton EF Coal 15 2.57E-04 4.SBE-04

.. 0.09 .. .

-c> -~-1 tbc·""''"""· k<t•~- Yeo Fluidized bed combustor Metals Nickel lbs/ton EF Agricultural waste 3 4.50E·05 9.6QE-07 0.34 Coal 15 1.92E·04 3.97E-04 0.Q4 No Fluidized bed combustor Metals Nickel lbs/Ion EF Agricultural waste 3 4.S0E-05 9.6QE-07 0.34 Coke 6 1.24E-04 1.06E-04 1.00 No Fluidized bed combustor Metals Nickel lbs/ton EF Coal 15 1.92E-04 3.97E-04 0.94 Coke 6 1.24E-04 1.06E-04 1.00 No Fluidized bed combustor Melals Selenium lbs/ton EF Agricultural waste 3 1.Q0E-05 7.71E-06 0.00 Coal 15 4.81 E-05 7.BJE-05 0.00 No Fluidized bed combu1Stor M8tals Selemum lbs/ton EF Agricultural waste 3 1.90E-05 7.71E-06 0.00 Coke 6 8.91E-05 6.46E-05 0.00 No Fluidized bed combus1or Metals Selemum lbs/ton EF Coal 15 4.81E-05 7.83E-05 0.00 Coke 6 8.91E-05 6.46E-05 0.00 No Fluidized bed combustor Metals Zinc lbs/ton EF Agricultural waste 3 3.36E-04 2.26E-04 1.00 Com 15 1.06E-03 1.20E-0J 1.00 No Fluidized bed combustor Metals Zinc lbs/ton EF Agricultural waste 3 3.36E-04 2.26E·04 1.00

,· .-,:,:, .;;• ... :-~"<"';,;..•,,,:':··.•: 6 9.96E-03 7.62E-03 1.00 No

Fluidized bed combustor Metals Zinc lbs/Ion EF Coal 15 1.0BE-03 1.20E-03 1.00 , .. •,y:.;,·.~•·,..'2'.Y ,..; ..... .., •• , • .c: ;•:'4le..i.-, Yeo Fluidized bed combustor PAH Acenaphthene lbs/ton EF Agricultural waste 3 1.20E-05 3.01E-06 0.00 Coal 1B 2.25E-06 4.84E-06 0.03 Yeo Fluidized bed combustor PAH Acenephthene lbs/ton EF Agricultural waste 3 1.20E-0S 3.01E·06 0.00 Coke 6 6.12E-07 4.27E-07 0.53 Yeo Fluidized bed combustor PAH Acenaphlhene lbs/ton EF Agricultural waste 3 1.20E-05 3.0tE-06 0.00 Wood waste 3 7.04E-07 3.SJE-07 1.00 y., Fluidized bed combustor PAH Acenaphlhene lbs/ton EF Coal 18 2.25E-06 4.84E-06 0.03 Coke 6 6.12E·07 4.27E-07 0.53 No Fluidized bed combualor PAH Acenaphlhene lbs/Ion EF Coel 1B 2.25E-06 4.84E-06 0.03 Wood wuie 3 7.04E·07 3.SJE-07 1.00 No Fluidized bed combustor PAH Acenaohlhene lbs/ton EF Coke 6 6.12E-07 4.27E-07 0.53 Wood waste 3 7.04E-07 3.SJE-07 1.00 No Fluidized bed combustor PAH Acenaphlhylene lbs/ton EF Apllltlril.walla . • ...,,.. . ..,._, ,.us' Coal 1B 2.24E-06 4.B4E-06 0.02 Ym Fluidized bed combustor PAH Acenaphlhylene !bs/ton EF . ..., ........ • ·- uili;el o.tt' Coks 6 3.97E-07 2.17E-07 0.23 Yeo Fluidized bed combustor PAH Acenaphthylene lbs/ton EF Agricultural waste 3 9.47E-os 9.77E-o5 0.95 Wood weate 3 2.67E-05 1.31E·05 1.00 No Fluidized bed combustor PAH Acenaphthylene lbs/ton EF Coal 18 2.24E•06 4.84E-06 0.02 Coko 6 3.97E-07 2.17E·07 0.23 No Fluidized bed combustor PAH Acenaphthylene lbs/Ion EF Coal 18 2.24E-0B 4.84E-06 0.02

·Wood.-- • --- u, .... ·.···~:•, Yeo Fluidized bed combustor PAH Acenaohthvlene lbs/lon EF Coko 6 3.97E-07 2.17E-07 0.23 -..:..~ • "~-.J.;".t. ,. .... IO!·..:... Yeo Fluidized bed combustor PAH Anthracene lbs/ton EF Agricultural waste 3 1.20E-05 3.01E·06 0.00 Com 16 2.24E-06 4.84E-06 0.03 Yeo Fluidized bed combustor PAH Anthracene lbs/Ion EF Agricultural waste 3 1.20E-05 3.0tE-06 0.00 Coke 6 2.34E-07 7 .32E-08 0.27 Yeo Flu1d1zed bed combustor PAH Anthracene lbs/ton EF Agricultural waste 3 1.20E-os 3.0lE-06 0.00 Wood waste 3 5.68E-07 1 .92E-07 1.00 Ym Flu1d1zed bed combustor PAH Anthracene lbs/ton EF Coal 18 2.24E-06 4.84E-06 0.03 Coks 6 2.34E-07 7.32E-08 0.27 No Flutd1zed bed combustor PAH Anlhracene lbs/ton EF Coal 18 2.24E-06 4.84E-06 0.03 Wood waste 3 5.68E-07 1 .92E-07 1.00 No Fluidized bed combus1or PAH Anthracene lbs/ton EF Coke 6 2.34E-07 7 .32E-08 0.27 ·.

.. . ·.·-- ··-- ·- Yeo Fluidized bed combuslor PAH Benzo(a)anthracene lbs/ton EF Agricultural waste 3 1.20E-05 3.01E-06 0.00 Coal 18 2.21E-06 4.SSE-06 0.00 Yeo Ftu1d1zed bed combustor PAH Benzo(a)anthracene lbs/ton EF Agricultural waste 3 1.20E-05 3.01E-06 0.00 Coks 6 2.35E-07 7.88E-08 0.28 Y• Fluidized bed combustor PAH Benzo(a)anthracene lbs/ton EF Agricultural wasle 3 1.20E-os 3.01E-06 0.00 Wood waste 3 2.osE-oa 4.18E-09 0.74 y,. Flu1d1zed bed combustor PAH Benzo(a)anthracene lbs/1on EF Coal 1 8 2.21E-06 4.85E·06 0.00 Coke 6 2.35E-07 7 .86E-08 0.28 No Flutdized bed combustor PAH Benzo(a)anthracene lbs/Ion EF CooJ 1 8 2.21E·06 4.8SE·06 . 0.00 Wood waallt 3 2.ose-oa 4.1BE-0Y 0.74 No Fluidized bed combustor PAH Benzo(a)anthracene lbs/Ion EF ~ ... '" ·:& ··-- , ......... _

1, ·- Wood waste 3 2.0SE-08 4.18E·09 0.74 y,. Fluidized bed combustor PAH Benzo(a)pyrene lbs/ton EF Agricullural waste 3 1.20E-05 3.0tE-08 0.00 Coal 1 8 2.44E-06 4.78E·06 0.00 Y• Fluidized bed combustor PAH Benzo(a)pyrene lbs/ton EF Agricultural waste 3 1 .20E-05 3.01E-06 0.00 Co .. 6 2.03E-07 1.26E-08 0.00 y,. Fluidized bed combustor PAH Benzo(a)pyrene lbs/Ion EF Agricultural waste 3 1 .20E-05 3.0lE-06 0.00 Wood waste 3 1.84E-08 8.2JE-10 0.00 y,. Fluidized bed combustor PAH Benzo(a)pyrene lbs/ton EF Coal 18 2.44E·06 4.78E-06 0.00 Coke ' 2.03E-07 1.26E-08 0.00 No Flu1d1zed bed combustor PAH Benzo(a)pyrene lbs/ton EF Coal 18 2.44E•06 4.78E·06 0.00 Wood WHIB 3 1.64E-08 6.2JE-10 0.00 No Fluidized bed combustor PAH Benzofalovrene lbs/ton EF Coke 6 2.0JE-07 1.26E·08 0.00 w--~ waale 3 1.64E·08 6.23E-10 0.00 y,. Fluidized bed combustor PAH Benzo(b)lluoranthene lbs/ton EF Agricultural waste 3 1.20E·05 3.0tE-06 0.00 Coal ' 4.34E·06 6.31E-06 0.01 No Fluidized bed combustor PAH Benzo(b)lfuoranlhene lbs/ton EF Agricultural waste 3 1.20E·05 3.01E-06 0.00 Wood WHllt 3 1.25E-07 1 .BBE-08 1.00 y,.

Fluidized bed combustor PAH Benzolbllluoranthene lbs/ton EF Com ' 4.34E-06 6.31E-06 0.01 Wood wasle 3 1.25E•07 1.86E-08 1.00 No Fluidized bed combustor PAH Benzolb+k111uoranlhene lbs/ton EF Com • 9.S0E-08 7 .62E-08 0.00 / - -,y Y• Fluidized bed combustor PAH Benzo(g.h.i)perylene lbs/ton EF Agricultural waste 3 1 .20E-05 3.01E·06 0.00 Coal 16 2.23E-06 4.85E-06 0.00 Y• Fluidized bed combuslor PAH Benzo( g, h ,i )perylene lbs/ton EF Agricultural waste 3 1.20E·0S 3.01E-06 0.00 Coko 6 2.09E-07 1.S0E-08 0.18 y,. Fluidized bed combustor PAH Benzo(g,h,i)perylene lbs/ton EF Agricultural waste 3 1.20E·05 3.01E·06 0.00 Wood wast& 3 5.94E•08 3.59E-08 1.00 Y• Fluidized bed combustor PAH Benzo(g,h,i)perylene lbs/Ion EF Coal 18 2.23E-06 4.SSE-06 0.00 Coke 6 2.09E-07 1.S0E-08 0.18 No

...

System Type I Category

Fluidized bed combus.tor I PAH Flrnd1zed bed coml:l\!S19.!._ ~ Flutdized bed combustor Ip'°" Fluidized bed combustor PN--1 Fluidized bed combustor PN--1 Fluidized bed combustor PN--1

Fluidized bed combustor PN--1 Fluidized bed combustor PN--1 Fluidized bed combustor PN--1 Fluidized bed combustor PN--1

fJ!l~d:iitti1_ b~(j combustor PN-1 Fluidized bed combuslor PN-1 Fluidized bed combuslor PN-1 Fluidized bed combustor PAH Fluidized bed combustor PAH Fluidized bed combustor PAH Fluidized bed combustor PAH Fluidized bed combustor PAH Fluidized bed combustor PAM Fluidized bed combustor PAM Fluidized bed combustot PN--1 Fluidized bed combustor PAH

Fluidized bed combustor PPM Fluidized bed combustor PN-i Fluidized bed combustor PN--1 Fluidized bed combustor PPH Fluidized bed combustor PN-1 Fluidized bed combustor PPl-1 Flmd1~d bed combustor Pptl Fluidized bed combustor PAH Fluidized bed combustor PN-1 Flmd1zed bed combustor PN-1 Fluidized bed combustor PN-1 Fluidized bed combustor PN-1 Fluidized bed combustor PN--1 Fluidized bed combuator PAM Fluidized bed combuator PAM Fluidized bed cambustor PAM Fluidized bed combustor PAM Fluidized bed combustor PN-i Fluidized bed combustor PN-i

Fluidized bed combustor PN-i Fluidized bed combustor PN-i

Fluidized bed combustor PN-1 Flu1d1zed bed combustor PN-i Fluidized bed combustor PN-1

Fluidi_!_ed bed combustor PAH Fluidized bed combualor PN-1 Flu1d1zed bed combustor PN-1

Fluidized bed combustor PN-i Fluidized bed combustor PN-i Fluidized bed combustor PN-i

&i!'.lized bed combu&tor PAH

Fluidized bed combustor ! PCl3 F_h,!_idizeg_ P.~Cj!!.flbustor I PCl3 Fluidized bed combustor PCB Fluidized bed combustor PC8 F!!!!dize~ bed com_l;_>u~or PCB Fluidized ___ beC, combustor ! PCB

Substance

Benzo{g,h.i)perytene

Benzo(g,h,1Jp11~ Benzo(k)fluoranthene Benzo(k)fluoranlhene Benzo{k)lluoranthene

Chrysene Chrysene Chrysene Chrysene Chrysene _Q_hrysene dibenz(a.h)anthracene dibenz(a,h)anthracene dibenz(a,h)anthracene dibenz(a,h)anthracene

dibenz(a,h)anthracene d,benz{a_J!}_anthracene Fluoranthene Fluoranlhene Fluoranthene Fluoranthene Fluoranthene

Fluoran!hene Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene lndeno( 1,2,J-cd)pyrene lndeno{1,2,J-cd)pyrene lndeno{ 1,2,J-cd)pyrene lndeno( 1,2 ,J-cd)pyrene

lndeno( 1.2 .3-cd)pyrene lndeno( 1,2,3-1e_(!

Naphlhalene Naphlhalene Naphthalene Naphthalene Naphthalene ~halene Phenanthrene Phenanthrene

Phenanthrene Phenanthrene Phenanthrene P~nanthrene

Pyrene Pyrene Pyrene

Pyrene Pyrene

EF Unit

lbs/ton

lbs/ton lbs/ton lbs/ton lbs/ton

lbs/ton lbs/ton lbs/Ion lbs/Ion lbs/Ion lbs/Ion Iba/ton lbs/ton lbs/ton lbs/ton

Iba/ton lbs/ton lbs/ton lbs/ton lbs/Ion lbs/Ion lbs/ton lbs/Ion 1bs/ton lbs/ton

lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton lbs/ton lbs/Ion lbs/Ion

lbs/ton lbs/ton lbs/ton

lbs/Ion lbs/tpri lbs/ton lbs/Ion lbs/ton lbs/Ion

lbs/ton lbs/Ion lbs/ton lbs/ton

lbs/Ion

lb&/lon lbs/ton

TABLE A6-1e. MA.JOA GROUP COMPARISON (t-statistics).

Significant Size! Av.-age j Standard Detect Difference at

Deviation Ratio 95%Confidenc,

s= Wood waste 3 5.94E·08 3.59E-08 J 1.00 I No s= Wood waste 3 5.94E-08 3.59E-08 1 .00 Y~

"' "' !!'

"' "' "' "' "' "' "' "' "' "' "' "' "' "' "' "' "' !!'

"' "' "' "' "' !!'

"' "' "' "' "' !!'

"' "' "' "' "' "' "' "' "' "' "' !!'

"' "' "' "' "' !!' !!'

"' !!' !!' !!' !!'


C.!!O[ Agricultural waste


CooJ Coal Coke

Agncultural waste Agricultural waste

Agricultural waste Coal Coal

Agricultural waste Agricultural waste Agricultural waste

Coal

Coal Coke

Agricultural waste Agricultural waste Agricultural waste

Coal Coal

Coal

Coke

Coal

_Q~

Coal

Coal

Coal

Coal

6-10

1.20E-05 t .20E-05 4.31E·06 1.20E-05 1.20E-05 1.20E-05

'" I 2.25E-06 18 2.25E-06

~J~E-07 1.20E-05 1.20E-05 1.20E·OS

1 • 1 2.24E-06 16 2.24E-06

1.20E-05 1.20E-05 1.20E·05 '"I 2.41E-06

16 2.41E-06 1.13E-06 1.20E-05 1.20E-05 1.20E-05

1 8 I 2.24E-06 18 2.24E-06

3.0lE-06 3.01E-06 6.33E·06 3.01E-06 3.01E-06 3.0tE-06 4.84E•06 4.84E-06 3.63E-07 3.01E-06 3.01E-06 3.01E-06 4.84E·06 4.84E·06

3.01E-06 3.01E-06 3.01E·06 4.77E·06 4.77E-06 8.46E-07 3.01E-06 3.01E-06 3.01E-06 4.84E-06 4.84E·06

181 2.26E·06 I 4.83E-06 6 1.30E-06 1.70E-06

lASE-07 I 7.42E-09 t .13E·07 3.42E·09

0.00 0.00 0.00 0.00 0.00 0.00 0.02 0.02 0.40 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.10 0.10 Q,_M

0.00 0.00 0.00 0.00 0.00

2.45E-07 7.42E-09 0.00 1.76E-07 7.08E-09 0.00 1.13E-07 3.42E-09 0.00 2.45E-07 7.42E-09 I 0.00

4.31E-06 6.33E-06 o.oo Wood waste 3 j 3.00E-08 Wood waste 3 3.00E-08

9.68E-09 1.00 9.68E·09 1.00

Coal 18 2.25E-06 4.84E-06 0.02 Coke 6 5.75E-07 3.63E-07 0.40

Wood wute 3 2.35E-07 3.52E-08 1.00 Cote 6 5.75E-07 3.63E-07 0.40

Wood wute 3 2.35E-07 3.52E·08 1.00 Wood ~aste 3 2.JSE-07 3.52E·08 1.00

Coal 18 2.24E-06 4.84E·06 0.00 Coke 6 2.66E-07 1.51 E-07 0.36

Wood waste 3 1.64E-08 6.23E-10 0.00 Cote 6 2.66E-07 1.51E-07 0.36

Wood waste 3 1.64E·08 6.23E·10 0.00 Wood_ waste 3 1.64E-08 6.23E-10 O,_Q9

Coal I 16 I 2.26E-08 Coke 6 9.71E-07

Wood waste 3 6.73E-06 Coke 6 9.71E-07

4.83E-06 0.03 6.0BE-07 1.00 2.44E•06 1.00 6.0BE-07 1 .oo

Wood waate 2.44E-06 1.00 >.:,1@=,;;•c,''

Coal 18 2.41E-06 4.77E-oe 0.10 Coke 6 1.13E-06 B.46E-07 0.94

Wood waste 3 1 .32E-06 6.67E-07 1.00 Coke 6 1.13E-06 B.48E-07 0.94

Wood waale 3 1.32E·06 6.67E-07 1.00 Wood waate_ 3 1 .32E·06 6.67E-07 1_Jl9

Coal 1 8 2.24E•06 4.84E-06 0.00 Coke 6 2.04E-07 1.15E-08 0.16

Wood waste 3 2.47E-08 1.15E-08 0.78 Coka 6 2.04E-07 1. 15E-08 0.16

Wood waste 3 2.47E-06 1.tSE-08 0.78 Wood waste 3 2.47E-08 1- tSE-08 0. 78

Coal I '" I 2.61 E-04 Coke 6 4.96E-05

Wood waste 3 2.99E·04

5.60E·04 I 0.99 5.03E·05 1.00 9.94E-05 1.00

Coke 1.00

Wood wute 3 I 1.SJE-08 I 4.82E·09 I 0.00 Wood wuta Wood wa1ta

W~wute Woaj_ waste

3 7.82E-10 8.58E-t 1 0.00 1.32E·09 6.27E•10 0.00 2.43E·08 3.07E•09 1.00 a.2se-10 1 2.nE-10 I o.oo

No

Y• No Yoo y,.

Yoo No No

~ Ya,

Ym y..,

No No Yoo Y• Y• Y• No No

Y• Ym Ym Y• No No

~ Yoo Yoo Yoo No No Ym Yoo y .. Y• No No y,.

Y• YM Y• No

Y• Y• Yeo

Yoo Y• No No

Y• y.,._ Y• Y• y.,

Y• y,.

TABLE A£-1a. MAJOR GROUP COMPARISON (t-stati&rics).

System Type [Category fSubstallCe jEF Unit fValue Type Fir11t Sam1Jle Statistics Second Sam~ Statistics Significant Description Size Average Standard Detect Deacription Size Average Standard Detect Diflerence at

Material/Fuel Tu.-... Deviation Ra1io Material/Fuel Tvne Deviation Ratio 95%Conlidenc Fluidized bed combustor Fal Octachlorinated biohenvls lbs/ton EF Coal 3 2.45E-07 7.42E-09 0.00 Wood waste 3 1.16E·09 2.65E-10 0.00 v. Fluid1zed bed combustor Fal Pentachlorinated binhenvls lbs/ton EF Coal 3 1.13E·07 3.42E-09 0.00 Wood waste 3 4.61E·09 1.92E-09 1.00 v. Fluidized bed combustor Fal Tetrachlormated binhenvls lbs/ton EF Coal 3 1.13E-07 3.42E-o9 0.00 Wood waste 3 1.69E-08 4.54E-09 1.00 Y• Fluidized bed combustor Fal Trichlorinated binhenYIS lbs/ton EF Coal 3 1.13E-07 3.42E·09 0.00 Wood waste 3 1.53E·08 4.09E·09 1.00 v .. Fluidized bed combustor voe Bon,ene lbs/ton EF Coal 3 2.67E•04 3.77E-05 1.00 v .. Fluidized bed combustor voe Bomene lbs/ton EF "'·'7

Coka 3 1.60E-OS 0.00E+OO 0.00 v. <,

Fluidized bed combustor voe Benzene lbs/ton EF ,c

Cob 3 1.60E-OS 0.00E+OO 0.00 v. :luidized bed combustor voe Formaldehyde lbs/ton EF ~;, .; Coal " 2.53E-03 3.17E-03 0.97 v .. Flu1d1zed bed combustor voe Formaldehyde lbs/ton EF Wood waste 3 3.66E·04 1.35E-0-4 1.00 v .. Flu1d1zed bed combustor voe Formaldehvde lbs/ton EF Coal 18 2.53E-03 3.17E-03 0.97 Wood waste 3 3.66E-04 1.35E-04 1.00 No

Furnace. metal Metals Arsenic lbs/ton production EF Alloy 11tod: 3 5.36E-04 6.45E-04 1.00 Aluminum ' 2.57E-04 3.60E•04 0.00 No Furnace. metal Metals Arsen1c lbs/ton production EF Alloy stock 3 5.36E•D4 6.45E-04 1.00 Braes and bronze ingot 2 3.70E-OS 5.B2E·06 1.00 No

Furnace metal Metals Arsenic lbs/ton oroduclion EF Aluminum ' 2.57E·04 3.60E-04 0.00 Brass and bronze inoot 2 3.70E-OS 5.82E-06 1.00 No

~urnace, metal Metals Beryllium lbs/Ion production EF AHoy stock 3 1.96E·03 s.75E-os 0.00 Aluminum 1B 3.33E-05 3.32E-05 0.00 v .. Furnace. metal Metals Beryllium lbs/ton production EF Alloy stoclt 3 1.Q6E·03 5.75E-05 0.00 Brass and bronze ingot 3 5.76E-05 O.OOE+OO 0.00 v ..

metal Metals Bervlhum lbs/ton oroduction EF Aluminum 18 3.33E·OS 3.32E-05 0.00 Brass and bronze inoot 3 5.76E-05 0.00E+OO 0.00 No

metal Metals Cadmium lbs/ton production EF Alloy stock 3 2.26E-03 2.7BE-03 1.00 Aluminum 18 5.17E-04 1.25E-03 1.00 No

metal Metals Cadmium lbs/ton production EF Alloy stock 3 2.26E-03 2.78E-03 1.00 Brass and bronze ingot 2 4.11E-05 3.49E·OS 1.00 No Metals Cadmium lbs/ton oroduclion EF Aluminum a 5.17E-04

~ Brase and bronze inaot 2 4.11E-05 3.49E·OS 1.00 No

Metals Chromium lbs/ton production EF ,w ,,,¥:mi;'•",,'!" , ,,~ Aluminum 12 1.49E-04 2.29E·04 1.00 v .. :~~:< ,,_/_,,, -~',~-,f:'.Vfi1t:½t. /;~/ Metals Chromium Iba/ton production EF f'~,7J,, .s, <\:;,-,-:;i:;,:-:;n. '·\> , > Brass and bronze ingot 3 3.29E-04 1.65E-04 1.00 Y• Metals Chromium lbs/Ion oroducl1on EF Aluminum 12 1.49E·04 2.29E .oo Brass and bronze inaot 3 3.29E-04 1.65E-04 1.00 No Metals Chromium (Hex) Iba/ton production EF AHoy stock 3 ·=~~ Aluminum 12 3.07E-04 4.97E-04 0.04 No Metals Chromium (Hex) lbs/ton production EF Alloy stock 3 6,86E-04 1.23E-04 0.00 Brass and bronze ingo1 3 2.29E·03 2.07E-04 0.00 v .. Metals Chromium IHexl lbs/ton oroduction EF Aluminum 12 3.07E-04 4.97E·04 0.04 Brass and bronze inoot 3 2.29E·03 ?.07E-04 0.00 v ..

Furnace, metal Metals Copper Iba/ton production EF 1yt~•--1:,ii!3Jf:tt~~:'f l}t' \~Mi·, . ,.·,···•·- Aluminum 18 8.37E·04 1.42E-03 1.00 v .. Furnace, metal Metals Copper lbs/ton production EF ,,l.i .. ·, .• ,, .. Bra11& end bronze ingot 3 2.13E-03 1.41E-03 1.00 Y• Furnace metal Metals c~er lbs/Ion oroduct1on EF Aluminum 18 8.37E-04 - 1.00 Brass and bronze lnoot 3 2.13E-03 1.41E-03 1.00 No

Furnace, melal Metals Lead lbs/Ion production EF ~li!:- .:::::r "';.~ -~• -·Jtm,'- 1~ Aluminum 18 4.18E-04 4.96E-04 1.00 y,.

Furnace. metal Metals Lead lbs/Ion production EF .-:Jk .\:.,)t.. )', Brass and bronze ingot 3 1.04E-03 2. 76E-04 1.00 v .. Furnace metal Metals Lead lbs/ton oroduchon EF Aluminum 18 4. 18E-04 - 1.00 Brass and bronze inaot 3 1.04E-03 2.76E-04 1.00 No

Furnace, metal Metals Manganese lbs/1on production EF ....,._,,,,,, ,a., ·- ;~~;i:~',f Aluminum 1B 2.36E-03 8.77E-03 1.00 v ..

Furnace. metal Metals Manganese lbs/ton production EF -- ;

I l i.-.i'' . ;,tr'{;;i,\ Brass and bronze ingot 3 3.89E-04 3.86E-04 1.00 v. Furnace me!al Metals Mannanese lbs/Ion oroduclion EF Aluminum 18 2.36E-03 8.77E-03 1.00 Brass and bronze inaot 3 3.89E•04 3.86E-04 1.00 No

Furnace. metal Metals Mercury lbs/ton production EF .,, __ &Mai'- ;s ,U-., .. ~.~« ~-" Aluminum 9 1.72E·OS 2.13E-05 0.37 v .. Furnace. metal Metals Mercury lbs/ton production EF Alloy stock 3 2.1SE·04 1.48E-04 1.00 Brass and bronze ingot 3 5.76E-05 8.23E-06 0.00 No

Furnace metal Metals Mercu~ tbs/Ion nroduction EF Aluminum ' 1.72E-05 2.13E-05 0.37 Brass and bronze innot 3 5.76E·OS 8.23E-06 0.00 Y• Furnace, metal Melals Nickel tbs/Ion production EF

., ·-- .- ., u-- ~,:,.-,- Aluminum 1 8 1.98E-04 2.24E-0-4 1.00 v. Furnace, metal Metals Nickel lbs/Ion production EF Alloy stock 3 5.73E-02 6.59E-02 1.00 Brau and bronze ingot 3 9.10E·04 8.28E-05 0.30 No

Furnace metal Metals Nickel lbs/ton ntoduction s= Aluminum 1 8 1.9BE-04 2.24E·04 1.00 ',", C ,.,,.>;,, • 'c ,~·'· ,, I -' ,,,,,, ,-...,-1,,·• 6::,: •. -....-•, .... ·- Y•

Furnace, metal Metals Selenium lbs/ton production EF Alloy stock 3 1.31E·04 4.10E·06 0.00 Aluminum ' 1.ose-0, 1.43E-04 0.02 No

Furnace. metal Metals Selenium Iba/ton production EF Alloy stock 3 1.31E-04 4.10E-06 0.00 Braaa and bronze ingot 3 1.81E-0C 8.23E-06 0.00 v .. metal Metals Selenium lbs/Ion nroduchon EF Aluminum ' 1.0SE-04

~ Brass and bronze innot 3 1.81E·04 8.23E-06 0.00 No

metal Metals Zmc lbs/ton production EF :~tl\ir•l1~:t ·:•' t ~; ••;; , Aluminum 9 3.33E-03 6.04E-03 1.00 Y• Furnace. metal Metals Zmc lbs/Ion production EF ;y;, ..... ;;:,, Brau and bronz• ingot 3 1.14E-03 8.37E-OC 1.00 v .. Furnace metal Metals Zinc lbs/ton nroduction EF Aluminum ' 3.33E·03 6.04E-03 1.00 Brau and bronze innot 3 1.14E-03 8.37E-04 1.00 No

Furnace metal voe Hvdrooen Sulfide lbs/ton oroduction EF Allou stock 3 1.6-4E+OO 1.ase-01 0.00 Aluminum 18 a.01E-02 1.14E-01 1.00 Y• Heater PAH Acenanhthene lbs/MMcf EF Natutalnaa 3 1.39E-06 2.32E-07 0.72 Natural aaa/RFG 3 7.53E-06 !USE-06 1.00 No

Heater PAH Acenanh!hvlene lbs/MMcf "' Natural nas 3 1.21E-05 1.75E-05 0.97 Natural aaa/RFG 3 s.ase-os 9.BOE-05 1.00 No

Heater PAH Anlhracene tbs/MMcf "' Natural naa 3 1.61E·06 3.97E-07 0.76 ,. ,.,, v .. Heater PAH Benzolalanthracene lbs/MMe! EF NalutalnH 3 1.41E-o6 4.21E-07 0.45 Natural aaa/RFG 3 9.57E·06 6.40E-06 1.00 No

Heater PAH Benzolalnvrene lbs/MMe! EF Natural au 3 1.14E·06 S.42E-08 0.00 Natural aaa/RFG 3 6.07E-06 5.27E·06 0.97 No

Heater PAH Benzolblfluoranthene lbs/MMe! EF Natural OH 3 1.14E-06 5.-42E·08 0.00 Natural r:i.aa/RFG 3 2.63E-06 1.35E-06 1.00 No

Healer PAH Benzoln hi ---·lane lbs/MMe! EF :<~ Natural naalRFG 3 -4.13E-07 4.69E·07 0.77 v .. Healer PAH Benzo/kllluoranthene lbs/MMcf EF Natural oas 3 1.14E·08 5.42E·08 0.00 Natural ru1a/RFG 3 1.-46E-06 1.51E-06 0.92 No

Heater PAH Chrvsene lbs/MMcl EF Natural aaa 3 1.39E-06 3.84E-07 0.44 Natural -••IDfG 3 7.91E·07 3.98E-07 0.52 No

Heater PAH dibenzla hlanthracene lbs/MMe! EF Natural oas 3 1.14E-06 5.42E-08 0.00 Natural naa/RFG 3 1.38E·07 6.00E-08 0.00 v. Haater PAH F1uoranlhene lbs/MMe! EF Natural OH 3 1.19E-os 5.48E-06 1.00 Natural naa/RFG 3 1.80E·05 1.76E·05 1.00 No

Healer PAH Fluorene lbs/MMe! - EF Natural aaa 3 4.59E·06 1.taE-06 1.00 Natural naa/RFG 3 6.48E-04 9.05E-04 1.00 No

6-11

TABLE A6-1a. MAJOR GROUP COMPARISON {t-statiatica).

System Type Category Substance EFUnit Value Type First Samo e Statistics Second Sam le Statistics Significant Description Size Av8fage Standard Detect Description Size Av8f&ge Standard Detect Difference at

MateriaVFuel Tv...,. Deviation Ratio MateriaVFuel TvD& Deviation Ratio 95%Confidenc1 Heater PAH tndeno/1 2 3-cdlovrene lbs/MMe! EF Natural aas 3 1.14E-06 5.42E-08 0.00 Natural "'"•™FG 3 4.58E-07 1.91E•07 0.49 y .. Heater PAH Nanhthalene lbs/MMe! EF Natural aas 3 2.37E•04 4.33E-05 1.00 Natural aas/RFG 3 2.31E·03 3.35E-03 1.00 No Heater PAH Phenanthrene lbs/MMcf EF Natural oas 3 3.37E-05 1.35E-05 1.00 Natural aas/RFG 3 2.06E-04 1.94E•04 1.00 No Heater PAH Pvrene lbs/MMcf EF Natural aas 3 5.60E-oe 5.24E-06 1.00 Natural aas/RFG 3 1.25E-05 1.20E-05 1.00 No Heater voc Acetaldehvde lbs/MMe! EF Natural aaa 3 4.61E·03 2.06E·04 0.32 " - y,.. Heater voc Acrolein lbs/MMe! EF Natural aas 3 4.51E-03 1.65E-04 0.00 Natural aas/RFG 3 2.29E-03 4.86E-04 0.00 y., Healer voe Benzene lbs/MMcf EF Natural aas 3 2.34E-03 1.19E-03 0.53 Natural aae/RFG 3 2.12e-02 2.76E-03 0.00 Yeo Heater voc Formaldehvde lbs/MMcf EF Natural aas 3 4.75E-03 5.11E·04 0.37 Natural aae/RFG 3 4.33E-02 3.96E·02 1.00 No Healer voc Prn,wtene lbs/MMe! EF ·-;,;: Natural -A~10FG 3 1.20E-02 1.57E-03 0.00 y,..

Heater voc Toluene lbs/MMe! EF Natural oaa 3 3.23E-02 3.68E-02 1.00 Natural nas/RFG 3 2.63E-02 3.43E-03 0.00 No Heater voe Total Xvlene lbs/MMcf EF Natural~ .. 3 1.87E-02 1.21E-02 1.00 Natural nas/RFG 3 3.03E-02 3.95E-03 0.00 No Internal combustion engine PAH Acenaphthene lbs/MMcf EF Field 9&1 2 7.41E·04 4.82E·04 0.00 Landfill ga,a • 1.93E-04 9.65E-05 0.46 No Internal combustion engme PAH Acenaphlhene lbs/MMe! EF Field gea 2 7.41E·04 4.82E-04 0.00 Natural gaa 15 1.02E-03 1.02E-03 1.00 No Internal combustion enome PAH Acenaohlhene lbs/MMe! EF Landfill nas 4 1.93E·04 9.65E-05 0.-46 Natural naa 15 1.02E·03 1.02E-03 1.00 No Internal combustion engine P'-S Acenaphlhylane lbs/MMe! EF <:'~· ·•-•(.• .. · .. :Ii ..... .,....,," .iu••ief . • .. , ... LandliH gas • 1.11E·03 5.38E·04 1.00 y,.. Internal combustion engine PAH Acenaphthylene lbs/MMcf EF Field ga& 2 1.11E·02 6.53E-03 1.00 N~_tur~I_,~ 15 8.81E-03

k 8;~~E-~'~, : 1.00 No Internal combustion ennme PAH Acenanhthvlene lbs/MMcf EF

~ 6 1.11 E-03

536E-.,~u ... , v .. "' '"' ;:CC, ,., .. .,., .. ,i >s:,~;.;,;.,-;-; y.,

Internal combustion engme PAH Anthracene lbs/MMcf EF Landfill gu 6 4.32E-04 3.52E-04 0.72 Y• • C •• • ¾-I~f'; Internal combustion engme PAH Anlhracene lbs/MMe! EF ◊'.C ~• Narural gas 15 6.00E-04 7.15E-04 1.00 y.,

Internal combustion ennine PAH Anthracene lbs/MMe! EF Landfill naa 6 4.32E-04 3.52E-04 0.72 Natural aaa 15 6.00E-04 7.15E-04 1.00 No Internal combustion engine PAH Benzo(a)anlhracene lbs/MMcf EF .

····•· ••<• ➔~--.. ,•;,· ,.:,,.....,.....,...,~,~ :s:stM":;: Landfill gas 3 2.24E-04 5.71E-05 0.00 Y• Internal combustion engine PAH Benzo(a)anthracene lbs/MMcf EF Field IJ&S 2 8.97E-04 1.95E-05 1.00 Natural gas 15 4.99E-04 8.12E-04 1.00 No Internal combustion ennine PAH Benzola\anthracene lbs/MMcf EF Landf~I nas 3 2.24E-04 5.71E-05 0.00 Natural aaa 15 4.99E·04 8.12E-04 1.00 No Internal combustion engine PAH Benzo(a)pyrene lbs/MMcl EF Field IJ&I 2 8.75E-04 9.31E·04 0.00 Landfill gae 4 3.61E-04 2.52~-04 0.87 No Internal combustion engine PAH Benzo(a)pyrene lbs/MMe! EF

I-A\,;,._:· .~1~. 2 8.75E•04 9.31E·04 0.00 Natural gaa 15 8.98E·05 1.2JE-04 0.97 Y• ;$:;.'.•~-.:-r:: '.'.0.'::¥&"'£""•':r I· ...

Internal combustion ennine PAH Benzolalnvrene lbs/MMe! EF Natural aas 15 8.98E·05 1.23E·04 0.97 Y• Internal combustion engine PN< Benzo(b)lluoranlhene lbs/MMcf EF Field ga9 2 1.48E·04 3.31 E-05 0.00 Landfill gas s 5.13E·04 1.95E·04 0.56 No Internal combustion engine P'-S Benzo(b)lluoranthene lbs/MMcf EF Field IJ&S 2 1.48E·0-4 3.31E·05 0.00 Natural gaa 15 5.88E·04 1.00E-03 0.99 No Internal combustion ennme PAH Benzolblfluoranthene lbslMMcf EF Landfill 0111 5 5.13E·04 1.95E-04 0.56 Natural aaa 15 5.88E·04 1.00E-03 0.99 No Internal combustion engine PAH Benzo(g,h.1)perylene lbs/MMcf EF Field IJ&S 2 9.40E·05 7 .27E·06 0.00 ······~•·· "·-· i:,.;: ...... ·. -· Ym Internal combustion engme PAH Benzo(g,h,i)perylene lbs/Mt.tel EF Field gu 2 9.40E-o5 7.27E·06 0.00 Natural gas 15 4.53E-04 7.83E-04 1.00 No Internal combustion ennme PAH Benzo/n h 1loervlene lbs/MMe! EF Landfill aaa 5 5.55E·04 2.35E·04 1.00 Natural oaa 15 4.SJE-04 7.83E-04 1.00 No Internal combustion engine PAH Benz o( k)llu or anthene lbs/MMe! EF lb .. · .... ,,.,, ·'' .... ,~'2~[ ~" ,._i; .. ,....., Landfill gu 3 4.26E-04 2.44E-04 0.15 Y• Internal combustion engine P'-S Benzo(k )II uor a nthene lbs/MMcf EF 1'11111:li'W,:~:~·. ->: ;.'j~ ,y~(-. .. '"f;J''.M;., ,:."·· Natural gaa 15 2.14E•04 3.0JE-04 0.99 Yeo Internal combustion ennine PAH Benzolk'lluoranthene lbs/MMcf EF Landfill aa■ 3 4.26E·04 2.44E-04 0.15 Natural oas 15 2.14E-04 3.03E-04 0.99 No Internal combustion engine PAH Chrysene lbs/MMcf EF > _., ·;, >\£ :•;~•,, :.t:te: Landfill ga■ 3 3.10E·04 5.16E·05 0.00 Yeo Internal combustion engine PAH Chrysene lbs/MMcf EF ..... '.t: ~.'.-·,tlllit?_-\r-' ,, ..... Natural gaa 15 J.30E·04 6.21E-04 1.00 Yeo Internal combustion en ine PAH Ch--ene lbs/MMe! EF Landfill DU 3 3.10E·04 5.16E•05 0.00 Natural t1as 15 J.30E·04 6.21E-04 1.00 No Internal combustion engine PAH dibenz(a,h)anthracene lbs/MMe! EF Field gaa 2 7.70E·05 8.37E·06 0.00 Landfill gaa 3 1.82E-05 6.0SE-06 0.00 Yeo Internal combustion engine PAH dibenz(a,h)anthracene lbs/MMe! EF Field gu 2 7.70E-05 8.37E-06 0.00 Natural gu 15 2.55E-05 4.0SE-05 0.96 No Internal combustion enCJine PAH dibenzla hlanthracene lbs/MMcf EF Landfill oaa 3 1.82E-05 6.0SE-06 0.00 Natural na1 15 2.55E·05 4.0SE-05 0,96 No Internal combus11on engine PAH Fluoranthene lbs/MMcf EF Field gas 2 1 .66E-04 7.13E·05 o_oo I< :.,,;.n...,,.lllilliir, I• I ,o;..- ,._iJ . ,,.! Y• Internal combustion engine PAH Fluoranlhene lbs/MMcf EF Fteld g,aa 2 1.66E·O◄ 7.13E-05 0.00 Nab.Jral gas 15 1.33E·03 1.84E-03 1.00 No Internal combustion emime PAH Fluoranthene lbs/MMcl EF Landfill nas 6 1.61E·03 6.06E·04 1.00 Natural nas 15 1.33E-03 1.84E·03 1.00 No Internal combustion engine PAH Fluorene lbs/MMe! EF Field gu 2 2.-44E-o3 1.65E-03 0.00 Landfill gaa 5 5.03E-04 1.63E-04 1.00 Y• Internal combustion engine PAH Fluorene lbs/MMe! EF Field gaa 2 2.44E·03 1.65E-03 0.00 Natural ga.a 15 3.53E-03 4.0SE-03 0.97 No Internal combustion enoine PAH Fluorene lbs/MMe! EF Landfill naa 5 5.03E·04 1.63E-04 1.00 Natural 15 3.53E·03 4.08E-03 0.97 No Internal combustion engine PAH lndeno( 1,2 ,3-cd)pyrene lbs/MMe! EF Field gu 2 1.37E-04 1.21E-05 0.00 Landfill gas 5 2.07E-04 7.44E·05 1.00 No lnlernal combustion engine PAH lndeno( 1,2 ,J•cd)pyrene lbs/MMe! EF Field gu 2 1.37E-04 1.21E·05 0.00 Natural ga■ 15 3.87E-04 6.51E·04 1.00 No Internal combustion ennine PAH tndeno/1 2 3-cd\ovrene lbs/MMcf EF Landfill aaa s 2.07E·04 7.44E-05 1.00 Natural aas 15 3.87E-04 6.51E-04 1.00 No Internal combustion engine PAH Naphthalene lbs/MMcf EF Field g,as 2 2. rnE-01 4.13E·OJ 1.00 Landfill !JAIi • 9.73E-02 1.s2e-01 1.00 No Internal combustion engine PAH Naphthalene lbs/MMe! EF Fiekl g,aa 2 2.19E·01 4.13E-03 1.00 Nab.Jral gas 15 1.13E·01 1.18E·01 1.00 No Internal combuslion enoine PAH Naohthalene lbs/MMe! EF Landfill oas • 9.73E·02 1.52E·01 1.00 Natural naa 15 1.13E-01 1.18E-01 1.00 No Internal combustion engine PAH Phenanthrene lbs/MMcf EF Field gas 2 ◄ .91 E-03 2.2JE•OJ 1.00 Landfill gaa 6 3.74E-03 1.64E-OJ 1.00 No Internal combustion engine PAH Phenanthrene lbs/MMe! EF Field gaa 2 4_91 E-03 2.23E·03 1.00 Nab.Jral gas 15 7.17E·03 9.89E·03 1.00 No Internal combustion encine PAH Phenanthrene lbs/MMe! EF Landfill oas 6 3.74E•03 1.64E-03 1.00 Natural n•• 15 7.17E-03 9.89E-03 1.00 No Internal combustion engine PAH Pyrene lbs/MMe! EF Field gas 2 2.39E-04 9.57E-05 0.64 I. ' <:,~,''. ,:I•, ~,__.,,,

~'.';_,,_._;,,., .._,,. Yeo Internal combustion engine PAH ""- tbs/MMcf EF Field gaa 2 2.39E-04 9.57E-05 0.64 Natura/g.u 15 1.74E·03 2.53E-03 1.00 No Internal combustion ancine PAH --- lbs/MMcf EF Landfill nu • 2.92E·03 1.19E-03 1.00 Nab.Jral ,., •• 15 1.74E-03 2.53E-03 1.00 No

6-12

TABLE A6-1a. MAJOR GROUP COMPARISON (1-atatistica).

System Type !Category jSubslance EF Unit Value Type First Sam le Statistics Second Sam e Statistics Significant Size Average Starldard Delee! Difference at

Deviation Ratio 95%Confidenc Acetaldeh de lbs/MMe! EF 30 2.32E+00 2.55E+00 0.99 Yee Acrolein lbs/MMe! EF 29 9.74E-01 1.25E+00 0.99 No Benzene lbs/MMe! EF 6 1.75E-01 J.97E-02 1.00 Ym Benzene lbs/MMcl EF 34 1.JJE+00 2.28E+00 1.00 Ym Benzene lbs/MMcf EF 34 1.33E+00 2.28E+00 1.00 No

lbs/MMcl EF 6 1.29E+00 1.64E+00 1.00 Yee lbs/MMe! EF 63 1.15E+01 1.45E+01 0.99 Yee lbs/MMcf EF 63 1.15E+01 1.45E+01 0.99 No lbs/MMcl EF 16 1.31E·01 1.27E-01 1.00 Yee lbs/MMe! "' 16 7.03E·02 6.00E-02 0.97 Y• lbs/MMe! "' 28 1.44E+01 1.74E+01 0.98 No lbs/MMe! EF 28 5.49E-01 6.15E·01 1.00 Ye, m lam -hr EF 19 2.93E-02 2.38E-02 0.62 Y•

,rallOf\ Metals Chromium Hex m /am -hr "' 17 1.57E-02 8.70E-03 0.52 Ye Polystyrene maoulacturmg SNOC Ethylbenzene lbs/lbs production s= EJCtNder 1 1.11E-06 1.00 NA

Polystyrene manufaclurmg = Ethylbenzene lbs/lbs production s= Mix Tank 1 4.35E-08 1.00 NA

Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Raaclor 3 2.43E-07 3.87E-07 1.00 YM Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Devolatizar 1 4.09E-06 1.00 Storage Silo 4 5.S0E-06 7.44E-06 1.00 No

Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Extruder 1 1.11E-06 1.00 Mix Tank 1 4.35E-08 1.00 NA

Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Eldruder 1 1.11E-06 1.00 Reactor 3 2.43E-07 J.87E-07 1.00 No

Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Extruder 1 1.11E-06 1.00 Storage Silo 4 5.60E-06 7.44E-06 1.00 No

Polystyrene manufacturing = Ethylbenzene lbs/lbs production s= Mix Tank 1 4.JSE-08 1.00 Raactor 3 2.43E-07 3.87E-07 1.00 No

Polystyrene manulacturing = Elhylbenzene lbs/lbs production s= Mix Tank 1 4.JSE-08 1.00 Storage Silo 4 5.S0E-06 7.44E-06 1.00 No lbs/lbs roduclion s= Reactor 3 2.43E-07 3.87E-07 1 .00 Stora e Silo 4 5.60E-06 7.44E-06 1.00 No lbs/lbs production Ef 0evolatizer 1 1.29E-09 0.00 EJCtruder 1 1.11E•07 0.00 NA lbs/lbs production Ef Devolatizer 1 1.29E·09 0.00 Mix Tank 1 2.75E-09 0.00 NA

Benzene lbs/lbs production a= 0evolatizer 1 1.29E-09 0.00 Reactor 1 2.76E·09 0.00 NA

Benzene lbs/lbs production a= Extruder 1 1.11E-07 0.00 Mix Tank 1 2.75E-09 0.00 NA

Benzene lbs/lbs production a= Extruder 1 1.11E·07 0.00 Reactor 1 2.76E-09 0.00 NA

Benzene lbs/lbs roduct1on a= Mix Tank 1 2.75E-09 0.00 Reactor 1 2.76E·09 0.00 NA

m,p•Xylene lbs/lbs production a= Devolatizer 1 1.96E-07 1.00 EJCtruder 1 1.53E-07 0.00 NA

m,p-Xylene lbs/lbs production a= 0evolatizer 1 1.96E-07 1.00 Mi)I; Tank 1 3.67E-09 0.00 NA

m,p-Xytene lbs/lbs production a= Devolalizer 1 1.96E-07 1.00 Reactor 1 2.00E-08 1.00 NA

m,p-Xylene lbs/lbs production s= Extruder 1 1.53E-07 0.00 Mix Tank 1 3.67E-09 0.00 NA lbs/lbs production s= Exlruder 1 1.SJE-07 0.00 Reactor 1 2.00E-08 1.00 NA lbs/lbs roduclion e: Mix Tank 1 3.67E-09 0.00 Reactor 1 2.00E-08 1.00 NA lbs/lbs production s= Devolatizer 1 6.22E-08 1.00 EJCtruder 1 1.SJE-07 0.00 NA lbs/lbs production s= Devolatizer 1 6.22E-08 1.00 MiJ1;Tank 1 3.67E-09 0.00 NA lbs/lbs production EF Devolalizer 1 6.22E-08 1.00 Reactor 1 3.68E-09 0.00 NA lbs/lbs production EF Eldruder 1 1.53E-o7 0.00 Mix Tank 1 3.67E-09 0.00 NA

o-Xylene lbs/lbs production EF Extruder 1 1.53E·07 0.00 Raactor 1 3.68E-09 0.00 NA

o-X lene lbs/lbs roduction s= Mix Tank 1 3.67E-09 0.00 Reactor 1 3.68E·09 0.00 NA

Polystyrene manufacturing voe Styrene lbs/lbs production a= Devolati2er 1 2.36E-05 1.00 Extruder 1 1.53E-05 1.00 NA

Polystyrene manufacturing voe Styrene lbs/lbs production s= 0evolati.ter 1 2.36E-05 1.00 Mix Tank 1 2.41E-05 1.00 NA

Polystyrene manulacturmg voe Styrene lbs/lbs production Ef □e'ololalizer 1 2.36E-o5 1.00 Reactor 3 8.41E-06 1.42E-05 1.00 No

Polystyrene manufacturmg voe Styrene lbs/lbs production a= Devolatizer 1 2.36E·05 1.00 Storage Silo ' 2.87E-05 3.93E-05 1.00 No

Polystyrene manufacturing voe Styrene lbs/lbs production a= EJCttuder 1 1.SJE-05 1.00 Mix Tank 1 2.41E·05 1.00 NA

Polystyrene manufacturing voe Styrene lbs/lbs production s= EJCtrudef 1 1.53E-05 1.00 Reactor 3 8.41E·06 1.42E-05 1.00 No

Polystyrene manufacturing voe Styrene 1bs/lbs production s= Extruder 1 1.53E-05 1.00 StOfage Silo ' 2.87E·05 3.93E-05 1.00 No

Polystyrene manufacturing voe Styrene lbs/lbs production EF Mix Tank 1 2.41 E-05 1.00 Reactor l 8.41E-06 1.42E-05 1.00 No

Polystyrene manufacturing voe Styrene lbs/lbs production EF Mix Tank 1 2.41E-05 1.00 StOfage Silo ' 2.87E-05 3.93E-05 1.00 No

S rene lbs/lbs roduction s= Reactor 3 8.41E-o6 1.42E·05 1.00 Stora ... ' 2.87E-05 3.93E·05 1.00 No

Toluene lbs/lbs production a= Davotali2er 1 2.98E-o7 1.00 -· 1 2.34E-07 1.00 NA

Toluene lbs/lbs production a= Devolatizer 1 2.98E·07 1.00 Mix Tank 1 2. 75E-09 1.00 NA

Toluene lbs/lbs production s= Devolatizer 1 2.98E-07 1.00 Aaactor 1 4.37E-08 1.00 NA

Toluene lbs/lbs production a= Extruder 1 2.34E·07 1.00 Mo:Tank 1 2.75E·09 1.00 NA

Toluene lbs/lbs production a= Extruder 1 2.34E·07 1.00 Raact0< 1 4.J7E-08 1.00 NA

Toluene lbs/lbs roduction s= Mix Tank 1 2.75E-09 1.00 Aaacto, 1 4.37E-08 1.00 NA

Benzene lbs/MMcl "' Natural as 3 3.BBE-03 S.82E-11 0.00 Natural as/CVR u • 4.39E-03 1.92E-03 0_,__QQ_ ~q_

6-13

•

TABLE A6-1a. MA.JOA GROUP COMPARISON (t-statisOCS).

System Type Category Substance EF Unit Value Type First Samnle Statistics Second Sam le Statiatica Significant Daacription Size Average Standard Detect Description Si,o Average Standard Detect Dittererice at

MateriaVFuel Tu,... Deviation Ratio MateriaVFuel T Deviation Ratio 95%Confidenc1

Steam oeneralor vrx; Formaldehvde lbs/MMe! EF Natural aas 3 8.72E-03 6.29E-03 1.00 Natural aas/CVR n,ae 3 5.23E-03 3.59E-04 0.32 No

Steam aenerator voe Toluene lbs/MMe! EF Natural OH 3 1.20E·02 t.85E-10 0.00 .• .•· '>;. Yo,

Sleam oenerator vrx; Total X11lene lbs/MMe! EF Natural aas 3 2.77E-02 4.66£-10 0.00 Natural aas/CVR OH • 1.81E-02 1.10E·02 0,60 No

Turbine PAH Acenanhlhene lbs/Maal EF Diesel 3 3.21E-05 2.63£-05 1.00 No. 2 distillate oil 12 7.37E-05 1.07E-04 0.11 No

Turbine PAH Acenanhthene lbs/MMe! EF Field aas 3 1.62E-05 8.40E·06 0.75 Natural oas 18 1.90E-05 3.47E-05 0.16 No

Turbine PAH Aeanaphthulane lbs/Mnal EF Dieael 3 4.14E-06 1.86E-06 0.79 No. 2 distillate oil 12 6.67E-05 1.10E-04 0.07 No

Turbine PAH Aeenaphthvlane lbs/MMcl EF Field oa5 3 1.10E-06 1.23E-07 0.00 Natural aaa 18 1.◄ 7E-05 2.77E-05 0.40 No

Turbine PAH Anthraeene lbs/Mnal EF Die.eel 3 2.52E-06 6.60E·08 0.00 No. 2 distillate oil 12 8.07E-05 1.05E-04 0.18 No

Turbine PAH Anthraeene lbs/MMef EF Field aa.s 3 2.48E-07 5.96E-08 0.00 Natural t1H 18 3.38E·OS 4.77E-05 0.49 No

Turbme PP>< Benzt1(a)anthraeene lba/Mnal EF Oielel 3 2.52E-06 6.SOE-08 0.00 No. 2 distillate oil 12 6.54E-05 1.11E·04 0.01 No

Turbme PP>< Banzolalanthraeene lbs/MMel EF Field nas 3 3.30E-07 1.25E-07 0.00 Natural nas 18 2.26E-05 4.55E-05 0.04 No

Turbine PAH Benzolalovrene lbs/Maal EF DiBHI 3 2.52E-06 6.60E·08 0.00 No. 2 distillate oil 12 6.62E-05 1.10E-04 0.05 No

Turbine PAH Benzoralovrene lbs/MMe! EF Field,..., 3 7.99E-07 3.53E-07 0.00 Nalllral nas 18 1.39E•05 2.71E-05 0.37 No

Turbme PAH Benzolblfluoranthene lbs/MMe! EF Field ""S 3 1.44E-06 5.BOE-07 0.47 Natural nas 1B 1.13E•05 1.97E-05 0.04 No

Turbine PAH Benzolbtkllluoranthene lbs/Moal EF Diesel 3 2.52E·06 6.60E·08 0.00 No. 2 distillate oil 3 3.23E·06 3.82E·07 0.00 Y• Turbine PAH Benzolelovrene lbs/MMe! EF Field n .. s 3 2.24E-06 1.47E-08 0.27 Natural nas 3 5.44E-07 1.64E·07 0.00 No

Turbine PAH Benzo/o.h i\oervlene lbs/Moal EF DiHel 3 2.52E-06 6.60E-08 0.00 No. 2 distillate oil 12 6.24E-05 1.12E-04 0.01 No

Turbine PAH Benzola.h i\oervlene lbs/MMet EF Field n11s 3 S.31E-06 2.42E-06 0.17 Natural nas 18 1.37E·05 2.54E-05 0.01 No Turbine PAH Benzolkllluoranthene lbs/MMet EF Field aaa 3 4.25E-07 1.62E-07 0.00 Natural nas 18 1.10E·05 1.98E-05 0.02 No Turbine PAH Chrvsene lbs/Maal EF Die&el 3 2.52E-06 6.60E-08 0.00 No. 2 distillate oil 12 7.91E-05 1.0SE-04 0.20 No Turbine PP>< Chrvsane lbs/MMe! EF Field aas 3 1.9SE-OS 7.66E-06 1.00 Natural aas 18 2.52E·05 4.90E-05 0.05 No Turbine PP>< dibanzta hlanthraeene lbs/Mt1al EF Diesel 3 2.52E-06 6.BOE-08 0.00 No. 2 distillate oil 12 6.24E-05 1.12E-04 0.01 No Turbine PP>< dibanzta hlanthraeene lbs/MMe! EF Field OU 3 6.91E-06 3.08E-06 0.00 Natural aas 18 2.35E-05 4. 72E-OS 0.00 No Turbine PAH Fluoranthane lbs/Moel EF Diesel 3 a.ttE-06 5.77E-06 1.00 No. 2 distillate oil 12 9.82E-05 1.13E-04 0.38 No Turbine PP>< Fluoranthene lbs/MMe! EF Field oa8 3 1.46E-05 6.04E-06 1.00 Natural aas 18 4.32E-05 8.37E-OS 1.00 No

Turbine PAH Fluorene lbs/Maal EF Diesel 3 1.77E·05 1.45E·05 0.95 No. 2 distillate oil 12 9.97E-05 1.02E-04 0.32 No

Turbine PAH Fluorene lbs/MMe! EF Field oas 3 6.03E-05 4.90E·05 1.00 Natural aas 1B 5.80E-05 1.12E·04 1.00 No Turbine PAH lndeno/1 2 3-cdlovrene lbs/Moal EF Diesel 3 2.52E-06 6.60E-08 0.00 No. 2 distillate oil 12 6.25E-05 1.12E•04 0.01 No Turbine PAH 1ndenol1 2 3-edlovrene lbs/MMcf EF Field aas 3 3.92E-06 1.74E-06 0.00 Natural aas 1B 2.35E-05 4.72E-05 0.01 No Turbine PAH Nanhthalene lbs/Moal EF Diesel 3 5.92E-03 7.08E-04 1.00 No. 2 distillate oil 12 6.78E-03 9.39E-03 1.00 No Turbine PAH Nanhthalene lbs/MMcl EF .. --- • ·- ·- Natural aas 18 1.66E-03 2.26E-03 0.85 y.,.

Turbine PAH Phenanthrene lbs/Moal EF Dieael 3 2.13E-05 1.47E-05 1.00 No. 2 distillate oil 12 3.38E-04 5.62E-04 1.00 No Turbine PAH Phenanthrane lbs/MMet EF Field aas 3 6.19E·OS 2.43E·OS 1.00 Natural oas 18 3.13E·04 5.99E-04 0.99 No Turbme PP>< Pvrene lbs/Maal EF Diasal 3 4.46E-06 2.12E-06 0.81 No. 2 distillate oil 12 6.22E·05 1.04E-04 0.25 No Turbine PP>< Pvr&ne lbs/MMe! EF Field aa1 3 1.28E-05 5.90E-06 1.00 Natural oas 18 2.77E-OS 3.76E-05 1.00 No Turbine svrx; 2-Chloronaohthalene lbs/MMe! EF Field oa1 3 8.53E-08 1.SSE-08 0.00 Natural oas 3 2.72E·07 1. 70E-07 0.00 No Turbine svrx; 2-Mathvlnaohthalene lbs/MMe! EF ... ·-- • '

,, Nal\Jral oas 3 5.29E·08 9.20E-07 1.00 Y•

Turbine svoe PArvlene tbs/MMe! EF Field oa1 3 8.62E-07 2.68£-07 0.00 Natural oas 3 7.00E-07 2.32E-07 0.00 No Turbine vrx; Benzene lbs/MMe! EF Field gas 3 1.46E-02 3.81E-04 0.00 Landfill gas 3 3.96E-01 3.44E-01 1.00 No

Turbine voe Benzene lbs/MMe! EF Field gas 3 1.46E-02 3.81 E-04 0.00 Natural gas 21 1.36E-02 9.82E-03 0.43 No

Turbine voe Benzene lbs/MMe! EF 1 ••. , •• ,·,, , .... ~. . ·' • ·- (•~>' L,,,_ Natural na■ 21 1.36E-02 9.B?E-03 0.43 Yo,

Turbme vrx; Formaldehyde lbs/MMe! EF Field gas 3 1.84E-01 8.SSE-02 1.00 landfill gas 3 1.aoe-01 1.73E-02 1.00 No Turbine voe Formaldehyde 1bs/MMcf EF Field ga1 3 1.84E-01 8.55E-02 1.00 Natural gas 23 1.2SE+OO 2.96E+OO 1.00 No Turbine vrx; Formaldahvde lbs/MMe! EF landfill naa 3 1.SOE-01 1.73E-02 1.00 Natural nas 23 1.25E+OO 2.96E+OO 1.00 No

6-14

TABLE A6-2a. FUEl.JMATERIAL TYPE COMPARISON (t•statistics).

Group Category Substance EF Unit Value Tv~ First Samnie Statistics i;;:.econd Samnle Statistics Significant I Description Size Average Standard Detect Description S~e Average Standard Detect Ollferertce al

MatertaVFuel r---- Deviation Ratio Material/Fuel T Deviation Ratio 95%Confldence Asohalt Prod. Oil Metals Arsenic lbs/ton oroductio1 s= Fuel Oil 2 8.52E·06 1.19E-06 0.00 Process 011 70 3 2.37E·06 1.60E·06 1.00 Yes Asohalt Prod. Oil Metals Bervllium lbs/ton oroductio EF Fuel Oil 3 7.94E-07 1.12E-07 0.00 Process Oll 70 3 4.16E-07 2.BOE-08 0.00 Yes Asohall Prod. Oil Metals Cadmium lbs/ton nroductio EF Fuel OH 3 2.02E·06 5.43E·07 0.43 Process OIi 70 3 7.67E-07 9.69E-07 O.A2 No Asohalt Prod. Oil Metals Chromium lbs/ton nroduclio EF Fuel Oil 3 6.57E-05 8.46E·OS 1.00 Process Oil 70 3 9.04E-06 7.40E-06 1.00 No Asohalt Prod. 011 Metals Chromium fHexl lbs/ton nroductio s= :,!=:,:111!1 Process Oil 70 3 1.04E-07 3. t4E-08 1.00 Yes Asohalt Prod. Oil Metals Conner lbs/ton nroductio• s= Process 011 70 3 6.01E·06 2.96E-06 1.00 Yes Asohalt Prod Oil Metals Lead lbs/ton nroductio s= Process Oil 70 3 1.41E·06 5.SOE-07 1.00 Yes Asohall Prod. Oil Metals Mann"'nese lbs/ton nroduclio s= Process Oil 70 3 1.40E-04 7.79E·05 1.00 No Asnhalt Prod Oil Metals Mercun, lbs/ton nroduclio s= Process Oil 70 3 7.02E-06 5.71E·06 1.00 Yes Asnhalt Prod. Oil Metals Nickel lbs/ton nroductio s= L. ,' .• c.. ,:,ilr.°;( ••H•' Process Oil 70 3 8.42E-06 2.63E·06 1.00 Yes Asnhalt Prod. Oil Metals Selenium lbs/ton nroductio s= :f'"lil 3 2.71E-05 3.22E·05 0.79 Process Oil 70 3 2.0BE-07 1 AOE-08 0.00 No Asnhalt Prod. Oil Metals Zinc lbs/Ion nroduclio s= w fe' Process Oil 70 3 2.52E·05 8.SSE-06 1.00 Yes Asnhalt Prod. Oil PAH Acenaohthene lbs/ton nroduclio• EF Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process Oil 70 3 3.06E·07 6.20E-08 1.00 Yes Asnhalt Prod Oil PAH Acenaohthvlene lbs/ton nroduclio• EF Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process Oil 70 3 5.26E·07 2.35E-07 1.00 No Asnhalt Prod. on PAH Anthracene lbs/ton nroductio EF Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process Oil 70 3 5.74E·08 1.76E-08 1.00 Yes Asnhalt Prod. Oil PAH Benzolalanthracene lbs/ton nroduclio s= Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process Oil 70 3 1.11E·08 2.14E·09 1.00 Yes Asnhalt Prod. Oil PAH Benzola\ovrene lbs/Ion nroductio EF Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process Oil 70 3 1.64E·09 1.84E·09 0.72 Yes Asnhalt Prod. Oil PAH Benzolo.h .i\nervlene lbs/ton nroduclio" s= Fuel Oil 3 6.13E-07 1.17E-07 0.00 Process OU 70 3 1.20E·09 2.,;.9E·10 0.75 Yes Asnhalt Prod. Oil PAH Benzolk\lluoranthene lbs/ton nroduclio EF Fuel OH 3 6. 13E-07 1.17E-07 0.00 Process OU 70 3 8.17E·10 7.87E·11 0.00 Yes Asnhalt Prod. Oil PAH Chrvsene lbs/ton nroductior EF Fuel 011 3 6.13E·07 1.17E-07 0.00 Process Oil 70 3 8.17E-10 7.A?E-11 0.00 Yes Asnhall Prod Oil PAH dibenzra h)anthracene lbs/ton nroductior EF Fuel OIi 3 6.13E·07 1.17E-07 0.00 Process on 10 3 8.17E-10 7.87E-11 0.00 Yes Asnhalt Prod. Oil PAH Fluoranthene tbs/ton nroductior EF Fuel Oil 3 6.13E·07 1.17E•07 0.00 Process Oil 70 3 3.57E-08 9.68E-09 1.00 Yes Asohalt Prod. Oil PAH Fluorene lbs/ton oroductior EF Fuel Oil 3 9.14E·07 1.83E-o7 1.00 Process Oil 70 3 6.58E-07 2.07E-07 1.00 No Asohall Prod. Oil PAH lndeno/1 2 3-cdlnvrene tbs/ton oroduclior EF Fuel Oil 3 ·a ··liii• Process Oil 70 3 8.17E-10 7.87E-11 0.00 Yes Asohall Prod. Oil PAH Nanhlhalene lbs/ton oroduclior EF •:, .,;_,_:_ D ' J, Process Oit 70 3 3.0SE-05 2.?0E-06 1.00 Yes Asohalt Prod. Oil PAH Phenanthrene lbs/ton nroductior EF .• ... ·• ... Process Oil 70 3 8.84E-07 2.18E-07 1.00 Yes Asohalt Prod 011 PAH Pvrene lbs/ton oroductior s= Fuel Oil 3 6.13E·07 1.17E-07 0.00 Process Oil 70 3 S.62E·08 2.23E-08 1.00 Yes Asohalt Prod. Ott voc Benzene lbs/ton oroduclior s= Fuel Oil 3 2.02E-05 5.00E·06 0. 71 . < ....... •-( Yes Asohalt Prod. Oil voc Formaldehvde lbs/ton oroductmr EF FuetOil 3 3.22E·04 2.07E•04 1.00 Process Oil 70 3 1.JBE-04 2.29E-05 1.00 No Boiler Fuel Oil Metals Antimonv lbs/Moal EF •F · .. . - . ,,-, ... ~ Residual Fuel 3 5.42E·04 3.87E-04 0.00 Yes Boiler Fuel Oil Metals Arsenic lbs/Mnal EF No. 6 Fuel Oil 27 8.SSE-04 B.16E·04 0.72 Residual Fuel 3 4.14E-05 5.SSE-06 0.00 No Boiler Fuel Oil Metals Barium lbs/Mnal EF No. 6 Fuel Oil 3 2.23E-02 6.41 E-03 1.00 Residual Fuel 3 7.78E-03 1.14E-02 1.00 No Boiler Fuel Oil Metals BervUium lbs/Mnal EF No. 6 Fuel OH 27 3.SOE-04 9.61 E-04 0.94 Residual Fuel 3 1.SSE-05 1.90E-06 0.00 No Baiter Fuel Oil Metals Cadmium lbs/Mnal EF No. 6 Fuel Oil 27 2.BSE-03 9.76E·03 0.96 Residual Fuel 3 1.65E-04 1.90E-05 0.00 No

Boiler Fuel 011 Metals Chromium tbs/Mnal EF No. 6 Fuel Oil 27 1.49E-03 1.89E-03 0.85 Residual Fuel 3 3.42E-04 2.59E·04 0.62 No Boiler Fuel 011 Metals Chromium IHex\ lbs/Mnal EF No. 6 Fuel OH 24 3.22E-04 3.44E-04 0.30 Residual Fuel 3 6.0SE-05 7.01E·05 0.88 No Boiler Fuel Oil Metals Conner lbs/Mnal EF No. 6 Fuel OH 27 3.96E·03 4.57E-03 1.00 Residual Fuel 3 1.70E-03 3.54E-04 1.00 No Boiler Fuel Oil Metals Lead lbs/Mnal EF No. 6 Fuel Oil 27 4.45E·03 9.37E-03 0.90 Residual Fuel 3 3.31E-04 4.61E·05 0.00 No Boiler Fuel Oil Metals Mannanese lbs/Mnal EF No. 6 Fuel Oil 27 2.26E·02 1.0"'i.E-01 0.99 Residual Fuel 3 s.s1E-03 9.22E-03 0.99 No Boller Fuel Oil Metals Mercuru lbs/Mnal EF No. 6 Fuel Oil 27 1.17E·03 1.75E·O~ 0.10 Residual Fuel 3 8.28E-05 1.11E-05 0.00 No Boiler Fuel Oil Metals Nickel lbs/Mnal EF No. 6 Fuel Oil 27 1.30E·01 1.48E·01 1.00 Residual Fuel 3 6.77E-04 7.83E-04 0.92 No Boiler Fuel Oil Metals Selenium lbs/Mnal EF No. 6 Fuel Oil 27 3.08E-03 8.68E·03 0.65 Residual Fuel 3 4.14E·05 5.ssE-os 0.00 No Boiler Fuel 011 Metals Silver lbs/Mnal EF No IF...a·NI .. , .. .

Residual FuAI 3 2.00E-04 7.66E-05 0.48 Yes Boiler Fuel Oil Metals Thallium lbs/Mnal EF No. 6 Fuel OH 3 3.27E·04 3.98E-04 0.00 Residual Fuel 3 1.65E·03 1.90E-04 0.00 Yes Boiler Fuel Oil Metals Zinc lbs/Mnal EF No. 6 Fuel Oil 27 7.54E-02 2.16E-01 1.00 Residual Fuel 3 4.51 E-02 3.54E·02 1.00 No Boiler. Fuel Oil PAH Acenaphlhene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E·06 0.00 No. 6 Fuel Oil 30 2.69E-05 3.4JE-05 0.48 Yes Boiler. Fuel Oil PAH Acenaphlhene lbs/Mgal EF Fuel Oil 2 1.JBE-04 1.24E-06 0.00 Residual Fuel 3 2.16E-06 1.78E-06 1.00 Yes Boiler Fuel Oil PAH Acenanhlhene lbs/Mnal EF No. 6 Fuel 011 30 2.69E·05 3.43E-05 0.48 Residual Fuel 3 2.16E·06 1.78E-OA 1.00 No

Boiler, Fuel 011 PAH Acenaphthylene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E·06 0.00 No. 6 Fuel 011 30 2.19E·05 4.16E·05 0.28 Yes Boiler, Fuel Oil PAH Acenaphlhylene lbs/Mgal EF Fuel Oll 2 1.38E·04 1.24E-06 0.00 Residual Fuel 3 6.45E·06 7.45E·06 1.00 Yes Boiler Fuel Oil PAH Acenanhthvtene lbs/Moal EF No. 6 Fuel Oil 30 2.19E·05 4.16E-05 0.28 Residual Fuel 3 6.45E·06 7.45E·06 1.00 No

Boiler, Fuel Oil PAH Anthracene lbs/Mgal EF Fuel Oil 2 1.38E·04 1.24E-06 0.00 No. 6 Fuel OH 30 1.SOE·OS 2.80E·05 0.05 Yo, Boiler, Fuel Oil PAH Anthracene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E•06 0.00 Residual Fuel 3 7.29E-06 4.94E•06 1.00 Yes Boiler Fuel Oil PAH Anthracene lbs/Mnal EF No. 6 Fuel Oil 30 1.SOE-05 2.80E·05 0.05 Residual Fuel 3 7.29E-06 4.94E-06 1.00 No

Boiler, Fuel Oil PAH Benzo(a)anthracene lbs/Mgal EF Fuel Oil 2 1 .3BE-04 1.24E·06 0.00 No. 6 Fuel Oil 30 1.48E-05 2.82E·OS 0.03 Yes Boiler, Fuel Oil PAH Benzo(a)anthracene lbs/Mgal EF Fuel Oil 2 1.JBE-04 1.24E-06 0.00 Residual Fuel 3 1.67E-06 9.18E-07 1.00 Yes Boiler Fuel Oil PAH Benzol a \anthracene lbs/Mnal EF No. 6 Fuel OH 30 1.48E-05 2.82E-05 0.03 Residual Fuel 3 1.67E-06 9.18E·07 1.00 No

Boiler, Fuel Oil PAH Benzo(a)pyrene lbs/Mgal EF Fuel OIi 2 1.36E•04 1.24E·08 0.00 No. 6 Fuel Oil 30 1.68E-05 2.80E-05 0.14 Yes Boiler. Fuel Oil PAH Benzo(a)pyrene lbs/Mgal EF Fuel Oil 2 1.38E·04 1.24E-06 0.00 Residual Fuel 3 1.73E-06 5.59E-07 1.00 Yes

6-IS

TABLE A6-2a. FUEl..JMATERIAL TYPE COMPARISON (t•statistics).

Group Category Substance EF Unit Value Tvo First Sam"1e Statistics Second Samnle Statistics Significant I Description Size Average Standard Detect Description Size Average Standard Delee! Difference at

Material/Fuel T .. "" Deviation Ratio Material/Fuel T Deviation Ratio 95%Confidence

Boiler Fuel Oil PAH Benzola\ovrene lbs/Mnal EF No. 6 Fuel Oil 30 1.68E·OS 2.80E·05 0.14 Residual Fuel 3 1.73E·06 5.59E·07 1.00 No

Boiler, Fuel Oil PAH Benz o( b) fl uo ra nthe ne lbs/Mgal EF Fuel Oil 2 1.38E·04 1.24E·06 0.00 No. 6 Fuel Oil 12 3.54E-05 3.62E·05 0.02 Yes Boiler, Fuel Oil PAH Benz o( b )II uoran the ne lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E·06 0.00 Residual Fuel 3 3.15E-06 5.73E-07 1.00 Yes Boiler Fuet Oil PAH BenzolbHluoranthene lbs/Mnal EF Nn. 6 Fuel Oil 12 3.54E-05 3.62E·05 0.02 Residual Fuel 3 3.15E-06 5.73E-07 1.00 No

Boiler, Fuel 011 PAH Benzo( g,h, i)pe rylene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E-06 0.00 No. 6 Fuel Oil 30 1.47E·05 2.81 E-05 0.01 Yes Boiler, Fuel Oil PAH Benz o( g,h ,i)pe ryl ene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E-06 0.00 Residual Fuel 3 3.16E-06 1.02E·06 1.00 Yes Boiler Fuel Oil PAH Benzoln h l\nervlene lbs/Maal EF No. 6 Fuel Oil 30 1.47E·OS 2.e1E-OS 0.01 Residual Fuel 3 3.16E-OR 1.02E-06 1.00 No

Boiler, Fuel Oil PAH Benzo( k)f luor an the ne lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E-06 0.00 No. 6 Fuel Oil 12 3.43E·05 3.72E-05 0.00 Yes Boiler, Fuel Oil PAH B enzo( k)fl uo ranth en e lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E·06 0.00 Residual Fuel 3 6.48E·07 3.17E-07 1.00 Yes Boiler Fuel Oil PAH Ben zotklfl uo ranthene lbs/Moal EF No. 6 Fuel Oil 12 3.43E-05 3.72E-05 0.00 Residual Fu...a 3 6.48E·07 3.17E-07 1.00 No

Boiler, Fuel Oil PAH Chrysene lbs/Mgal EF Fuel Oil 2 1.38E·04 1.24E-06 0.00 No. 6 Fuel Oil 30 1.72E·05 2.76E·05 0.17 Yes Boiler, Fuel Oil PAH Chrysene lbs/Mgal EF Fuel OH 2 1.38E·04 1.24E·06 0.00 Residua! Fuel 3 1.17E-06 7.05E·07 1.00 Yes Boiler Fuel Oil PAH Chrvsene lbs/Mnal EF No. 6 Fuel Oil 30 1.72E·05 2.76E-05 0.17 Residual Fuel 3 1.17E-06 7 OSE-07 1.00 No

Boiler, Fuel Oil PAH d ibenz (a, h )a nth racene lbs/Mgal EF Fuel Oil 2 1.38E·04 1.24E-06 0.00 No. 6 Fuel Oil 30 1.48E-OS 2.62E-OS 0.00 y ..

Boiler, Fuel Oil PAH di benz (a, h) an th racene lbs/Mgal EF Fuel Oil 2 1.36E·04 1.24E-06 0.00 Residual Fuel 3 3.09E-06 1.60E-06 1.00 Yes Boiler Fuel Oil PAH dibenzla hlanthracene lbs/Mnat EF No. 6 Fuel Oil 30 1.46E-05 2.82E-05 0.00 Residual Fuel 3 3.09E·OA 1.80E-06 1.00 No Boiler. Fuel Oil PAH Fluoranthene lbs/Mgal EF Fuel Oil 2 1.38E-04 1.24E-06 0.00 No. 6 Fuel Oil 30 1.99E·05 2.B3E-OS 0.37 Yes Boiler. Fuel Oil PAH Fluoranthene lbs/Mgal EF Fuel 011 2 1.3BE-04 1.24E·06 0.00 Residual Fuel 3 2.69E-06 3.33E-07 1.00 Yes Boiler Fuel Oil PAH Fluoranthene lbs/Mnal EF No. 6 Fuel OH 30 1.99E-OS 2.83E·05 0.37 Residual Fuel 3 2.69E-Oll 3.33E-07 1.00 No Boiler, Fuel Oil PAH Fluorene lbs/Mgal EF Fuel OH 2 1.38E-04 1.24E-06 0.00 No. 6 Fuel Oil 30 2.37E-05 3.13E-05 0.41 Yes Boiler, Fuel Oil PAH F1uorene lbs/Mgal EF Fuel OIi 2 1.38E-04 1.24E-06 0.00 Residual Fuel 3 3.31 E-06 1.73E-06 1.00 Yes Boiler Fuel Oil PAH Fluorene lbs/Mnal EF No. 6 Fuel Oil 30 2.37E-05 3.13E-OS 0.41 Residual Fuel 3 3.31 E-06 1 .73E·06 1.00 No Boiler, Fuel Oil PAH lndeno(1,2,3-cd)pyrene lbs/Mgat EF Fuel Oil 2 1.36E-04 1.24E·06 0.00 No. 6 Fuel Oil 30 1.46E·OS 2.82E·05 0.01 Yes Boiler, Fuel m PAH lndeno(1,2,J-cd)pyrene lbs/Mgal EF Fuel OIi 2 1.36E-04 1.24E·06 0.00 Residual Fuel 3 1.92E·06 1.10E·06 1.00 Yes Boiler Fuel Oil PAH lndenoI 1 2 3-cd\nurene lbs/Mnal EF Nn 6 Fuel OH 30 1.46E-05

~ Residual Fuel 3 1.92E·06 1.10E·06 1.00 No

Boiler, Fuel Oil PAH Naphlhalene lbs/Mgal EF ·:.:'0.'l!l'i ,,,,,, .i(j\71 t~ No. 6 Fuel Oil 30 5.68E·03 1.26E-02 1.00 y ..

Boiler. Fuel Oil PAH Naphthalene lbs/Mgal EF >C' :., :',f ··.tiila' : Residual Fuel 3 t .03E·04 2.33E-OS 1.00 y ..

Boiler Fuel Oil PAH Nanhthalene lbs/Mnal EF No. 6 Fuel Oil 30 5.68E-03 1.26E-02 1.00 Residual Fuel 3 t.03E-04 2.33E-05 1.00 No Boiler, Fuel Oil PAH Phenanlhrene lbs/Mgal EF Fuel Oil 2 1.JBE-04 1.24E·08 0.00 No. 6 Fuel Oil 30 3.45E-OS 6.47E-05 0.66 Yes Boiler, Fuel Oil PAH Phenanlhrene lbs/Mgal EF Fuel OH 2 1.JBE-04 1.24E-06 0.00 Residual Fuel 3 1.35E-OS 6.32E-06 1.00 Yes Boiler Fuel Oil PAH Phenanthrene lbs/Mnal EF No. 6 Fuel OU 30 3.45E-OS 6.47E-05 0.68 Residual Fuel 3 1.35E-05 6.32E-06 1.00 No

Boiler, Fuel Oil PAH Pyrene lbs/Mgal EF Fuel Oil 2 1.36E-04 1.24E-06 0.00 No. 6 Fuel OIi 30 1.59E-05 2.77E-05 0.10 Yes Boiler, Fuel 011 PAH Pyrene lbs/Mgal EF Fuel Oil 2 1.36E-04 1.24E-06 0.00 Residual Fuel 3 1.6SE·06 4.09E-07 1.00 Yes Boiler Fuel OIi PAH Pvrene lbs/Mnal EF No. 6 Fuel Oil 30 1.59E·OS 2.77E-05 0.10 Residual Fuel 3 1.65E·06 4.09E·07 1.00 No Boiler Fuel Oil voe Benzene lbs/Mnal EF No. 6 Fuel 011 29 5.63E-03 8.75E-03 0.84 Residual Fuel 3 5.78E·03 0.00E+OO 0.00 No Boiler. Fuel Oil voe Formaldehyde lbs/Mgal EF Fuel Oil 3 2.65E-02 2.40E-02 1.00 No. 6 Fuel Oil 24

~; 0.93 No

Boiler. Fuel Oil voe Formaldehyde lbs/Mgal EF Fuel OH 3 2.65E-02 2.40E·02 1.00 ~~tffi~t :;r,t(r.M.!~y;· ;~> ,:!t ~}!!.f? Yes Boiler Fuel Oil voe Formaldehvde lbs/Mnal EF No. 6 FuAI OH 24 2.48E-02 3.75E-02 0.93 ' Yes Coating, Powder Metals Chromium lbs/lbs powder EF Ct (75% Cr3C2, 20% NICr, 5% Cr) 1 3.75E-01 1.00 C2 (87% A.I203, 13% Ti02) 1 3.48E-04 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C1 {75% Cr3C2, 20% NICr, 5% Cr) 1 3.75E-Ot 1.00 CJ (70"/o Ni, 4% Cr) 1 1.86E-04 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C1 (75% Cr3C2. 20% NICr, 5% Cr) 1 3.75E-01 1.00 C4 (49% Ni, 44% Cr) 1 4.02E·04 1.00 NA Coating, Powder Metals Chrommm lbs/lbs powder EF C1 (75% Cr3C2, 20% NICr, 5% Cr) 1 3.75E·01 1.00 C6 (80% Ni, 20% Cr) 1 1.86E-03 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF Ct (75% Cr3C2, 20% NICr, 5% Cr) 1 3.75E·01 1.00 C7 (100% Chromium Oxide) , 1.42E·01 1.00 NA Coaling, Powder Metals Chromium lbs/lbs powder EF C2 (87% A.1203, 13% TI02) 1 3.48E•04 1.00 C3 (70"/a Ni, 4% Cr) 1 1.86E-04 1.00 NA Coaling, Powder Metals Chromium lbs/lbs powder EF C2 (87% A.1203, 13% Ti02) 1 3.48E·04 1.00 C4 (49% Nl, 44% Cr) 1 4.02E-04 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C2 (87% A.1203, 13% Tl02) , 3.48E·04 1.00 C6 (80% NI, 20% Cr) 1 1.86E·03 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C2 (87% Al203, 13% TI02) 1 3.48E-04 1.00 C7 (100% Chromium Oxide) 1 1.42E-01 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C3 (70% NI, 4% Cr) 1 1.86E·04 1.00 C4 (49%. Ni, 44% Cr) 1 4.02E-04 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C3 (70% Ni. 4% Cr) 1 1.86E-04 1.00 ca (60% NI, "°"' c~ 1 1.86E·03 1.00 NA Coating, Powder Metals Chromium lbs/lbs powder EF C3 (70% Ni, 4% Cr) 1 1.86E·04 1.00 C7 (100°k Chromium Oxide) 1 1.42E-01 1.00 NA Coating, Powder Metals Chromium lbs/lbs p,owder EF C4 (49% NI, 44% Cr) 1 4.02E·04 1.00 C6 (80% NI, 20% Cr) 1 1.86E-03 1.00 NA Coating, Powder Melals Chromium lbs/lbs powder EF C4 (49% Ni, 44% Cr) 1 4.02E·04 1.00 C7 {100% Chromium Oxide) 1 1.42E-01 1.00 NA Coatinn Powder Metals Chromium lbs/lbs nowder EF CB '80% Ni 20% en 1 1.86E·03 1.00 C7 '100% Chromium Oxidel 1 1.42E·01 1.00 NA Coating. Powder Metals Chromium (Hex) lbs/lbs powder EF Ct (75% Cr3C2, 20% NICr, 5% Cr) 1 1.63E·02 1.00 C3 (70% Ni. 4% Cr) 1 1.81E-04 1.00 NA Coating, Powder Metals Chromium (Hex) tbs/lbs powder EF C1 (75% Cr3C2, 20% NICr, 5% Cr) , 1.63E-02 1.00 C4 (49% NI, 44% Cr) 1 3.00E-04 1.00 NA Coaling, Powder Metals Chromium (Hex) lbs/lbs powder EF Ct (75% Cr3C2, 20% NICr, 5% Cr) 1 1.63E-02 1.00 ce (80% NI, 20% Cr) 1 2.58E•04 1.00 NA Coating, Powder Metals Chromium (Hex) lbs/lbs powder EF C1 (75% Cr3C2. 20% NICr, 5% Cr) 1 1.63E-02 1.00 C7 (100% Chromium Oxide) 1 8.91E·03 1.00 NA Coating, Powder Metals Chromium (Hex) lbs/lbs powder EF C3 (70% Ni. 4% Cr) 1 1.81E·04 1.00 C4 (49% Ni. 44% Cr) 1 3.00E-04 1.00 NA Coating, Powder Metals Chromium (Hex) lbs/lbs powder EF C3 (70% Ni, 4% Cr) 1 1.81E·04 1.00 ce {80% NI, 20% Cr) 1 2.58E·04 1.00 NA

6-16

TABLE A6-2a. FUEL/MATERIAL TYPE COMPARISON (t·statlstics).

Group /Category /Substance IEF Unit /Value T;:;I First Samnle Statistics Second SamnJe Statistics Significant I Description Size Average Standard Detect Description Size Average Standard Delect Difference at

Matertal/Fuel r-·-- Deviation Ratio Material/Fuel r-- Deviation Ratio 95%Conlidence

Coating, Powder Metals Chromium (Hex) lbs/tbs powder Er C3 (70% Ni, 4% Cr) 1 1.B1E-04 1.00 C7 ( 100% Chromium Qxide) 1 B.91E-03 1.00 NA

Coating, Powder Metals Chromium (Hex) lbs/lbs powder Er C4 (49% Ni, 44% Cr) 1 3.00E-04 1.00 C6 (BO% Ni, 20% Cr) 1 2.SBE-04 1.00 NA

Coaling, Powder Metals Chromium (Hex) lbs/lbs powder Er C4 (49% Ni, 44% Cr) 1 3.00E-04 1.00 C7 {100% Chromium Oxide) 1 8.91E-03 1.00 NA

Coatina. Powder Melals Chromium /Hex\ lbs/lbs nowder Er C6 180% Ni 20% Cr\ 1 2.58E-04 1.00 C7 i100% Chromium Oxide\ 1 8.91 E-03 1.00 NA

FBC Biomass Dioxin & Furan 4D 2378 lbs/ton Er A,..ricultural W"'-ste 3 4.46E-10 4.17E-11 0.00 Wood Waste 3 2.89E-11 1.0JE-11 0.00 Yes FBC Biomass Dioxin & i=uran 4F 2378 lbs/Ion Er Wood Waste 3 1.29E-10 5.25E-11 1.00 No

FBC Biomass Dioxin & Furan SD 12378 lbs/ton Er Wood Waste 3 3.28E-11 1.14E-11 0.00 Yes FBC Biomass Dioxin & Furan SF 12378 lbs/ton Er Wood Wast" 3 6.27E-11 2.28E-11 1.00 Yes FBC Biomass Dioxin & Furan SF 23478 lbs/ton Er Wood Waste 3 1.03E·10 2.69E-11 1.00 Yes '

FBC Biomass Dioxin & Furan 6D 123478 lbs/Ion Er A ric ltural Waste 3 1.22E 09 4.69E 10 0.00 Wood Waste 3 4.36E-11 4.R6E·12 0.29 Yes FBC Biomass Dioxin & Furan 6D 123678 lbs/ton Er Anricultural W•st11 I 3 1.27E-09 4.4'-E·t0 I 0.00 Wood Waste 3 6.38E-11 2.75E·11 0.50 Yes FBC Biomass Dioxin & Furan 6D 123789 lbs/Ion Er Wood Waste 3 4.77E-11 B.2AE-12 0.40 Yes FBC Biomass Dioxin & Furan 6F 123478 lbs/ton Er c' Wood Waste 3 7.59E-11 3.%E-11 1.00 Yes FBC Biomass Dioxin & Furan 6F 123678 lbs/ton Er ... Wood Waste 3 1.12E-10 5.11E-11 1.00 Yes FBC Biomass Dioxin & Furan 6F 123789 lbs/Ion Er 0 Wood Waste 3 2.77E·11 2.63E-11 0.70 No

FBC Biomass Dioxin & Furan 6F 234678 lbs/Ion Er ', . , Wood Waste 3 3.02E·10 2.69E·10 1.00 Yes FBC Biomass Dioxin & Furan 7D 123467R lbs/Ion Er ' Wood Waste 3 6.90E-10 2.02E·10 1.00 Yes FBC Biomass Dioxin & Furan 7F 1234678 lbs/Ion Er , Wood Waste 3 1.37E·09 1.44E-09 1.00 Yes FBC Biomass Dioxin & Furan 7F 1234789 lbs/Ion Er 4nricultural Waste 3 7.43E-10 5.89E·10 0.63 Wood Waste 3 8.97E·11 9.71E-11 0.92 No

FBC Biomass Dioxin & Furan 8D lbs/Ion Er ·,; ,,,,

Wood Waste ' 6.6Qf-09 2.53E-09 1.00 Yes FBC Biomass Dioxin & Furan BF lbs/Ion Er Anricultural Waste 3 ~.24E-0° 3.44E-09 0.81 Wood Waste 3 1.61E·09 1.BSE-09 1.00 No

FBC Biomass PAH Acenanhthene lbs/Ion Er Anricultural Waste 3 1.20E-0C 3.01 E-06 0.00 Wood Waste 3 7.04E·07 3.53E·07 1.00 Yes FBC Biomass PAH Acenanhthvlene lbs/ton Er Anricultural W"'Sle 3 9.47E-0"' 9.77E-05 0.95 Wood Waste 3 2.67E-05 1.31E·0S 1.00 No

FBC Biomass PAH Anlhracene lbs/Ion Er Anricultural Waste 3 1.20E-05 3.01E·06 0,00 Wood Waste 3 5.68E-07 1.92E-07 1.00 Yes FBC Biomass PAH Benzor alanthracene lbs/Ion Er Anricultural Waste 3 1.20E-05 3.01E·06 0,00 w Waste ' 2.05E-08 4.1 BE-09 0.74 Y-FBC Biomass PAH Benzotaln11rene lbs/Ion Er 4nrirullura1 Waste 3 1.20E·05 3.01 E-06 0.00 Wood Waste 3 1.64E-08 6.23E·10 0.00 Yes FBC Biomass PAH Benzotbllluoranlhene lbs/Ion Er Anricultural Waste 3 1.20E·05 3.01 E-06 0.00 Wood Waste 3 1.25E-07 1.66E·08 1.00 Yes FBC Biomass PAH Benzoln h ilnerulene lbs/ton Er Anricultural Waste 3 1.20E-05 3.01E·06 0,00 Wood Waste 3 5.94E-08 3.59E·08 1.00 Yes FBC Biomass PAH Benzo/klfluoranthene lbs/Ion Er Anricultural Waste 3 1.20E-05 3.01E·06 0,00 Wood Waste 3 3.00E-08 9.68E·09 1.00 Yes FBC Biomass PAH Chrvsene lbs/Ion Er Anricullural Waste 3 1.20E·05 3.01E-06 0,00 Wood Waste 3 2.JSE-07 3.52E·08 1.00 Yes FBC Biomass PAH dibenzra hlanthracene lbs/Ion Er Anricultural Wasle 3 1.20E-oc 3.01E-06 0.00 Wood Waste 3 1.64E-08 6.2JE-1 o 0.00 Yes FBC Biomass PAH Fluoranthene lbs/Ion Er . . '-,,,,.,,, Wood Waste 3 6.73E·06 2.44E-06 1.00 Yes FBC Binmass PAH Fluorene lbs/ton Er Anricultural Waste 3 1.20E-05 3.01 E-06 0.00 Wood Waste 3 1.32E-06 6.67E-07 1.00 Yes FBC Biomass PAH lndenol 1 2 3-cdlm,rene lbs/ton Er Anricullural Waste 3

1=1 ~06

0.00 Wood Waste 3 2.47E-08 1.15E-08 0.78 Yes FBC Birvnass PAH Nanhthalene lbs/Ion Er • . ......... , Wood Waste 3 2.99E-04 9.94E-05 1.00 Yes FBC Biomass PAH Phenanthrene lbs/Ion Er . , .. Wood Waste 3 1.92E-05 5.JSE-06 1.00 Yes FBC Biomass PAH Pvrene lbs/Ion Er ,. ' . . . .

Wood Waste 3 4.78E-06 1.66E-06 1.00 Yes FBC Biomass voe Formaldehvde lbsl!on Er . 3 . . -- Wood Waste 3 3.66E-04 1.35E-04 1.00 Yes Turbine Distillate PAH Acenanhthene lbs/Mnal Er Diesel 3 3.21E-05 2.63E·05 1.00 No. 2 Distillate 12 7.37E-05 1.07E-04 0.11 No

Turbine Distillate PAH Acenanhthvtene lbs/Mnal Er Diesel 3 4.14E-06 1.86E-06 0.79 No. 2 Distillate 12 6.67E·05 1.l0E-04 0.07 No

Turbine Dislillate PAH Anthracene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0.00 No. 2 Distillate 12 8.07E-05 1.05E·04 0.18 No

Turbine Distillate PAH Benzo' aianthracene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0.00 No 2 Dislitlate 12 6.54E-05 1.11E·04 0.01 No

Turbine Distillate PAH Benzo/alnvrene lbs/Mnal Er Diesel 3 2.52E-06 6.60E·08 0.00 No. 2 Dlstlllate 12 6.62E-05 1.t0E-04 0.05 No

Turbine Distilla!e PAH Benz o/ b+ kl II u o ranthene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0.00 No. 2 Distlllate 3 3.23E-06 3.82E-07 0.00 Yes Turbine Distillate PAH Benzo/o.h iloervlene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0,00 No. 2 Distillate 12 6.24E-05 1.12E-04 0.01 No

Turbine Distillate PAH Chrvsene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0.00 No. 2 Distillate 12 7.91E-0S 1.08E-04 0.20 No

Turbine Distillate PAH dibenz/a hlanlhracene lbs/Mnal Er Diesel 3 2.52E-06 6.60E-08 0.00 No. 2 Dlstlllate 12 6.24E-os 1.12E-04 0.01 No

Turbine Distillate PAH Fluoranthene lbs/Mnal Er Diesel 3 8.11E-06 ~77E-06 1.00 No. 2 Dlsflil .. te 12 9.82E·0S 1.13E-04 0.38 No

Turbine Distillate PAH F1uorene lbs/Mnal Er Diesel 3 1.77E·05 1.45E-05 0.95 No. 2 Dislill'"le 12 9.97E-05 1.02E-04 0.32 No

Turbine Distillate PAH lndenol1 2 3-cdlnvrene lbs/M,.,al Er Diesel 3 2.52E·06 6.60E-08 0.00 No. 2 Dislill"'I"' 12 6.25E-05 1.12E-04 0.01 No

Turbine Disliltale PAH Nanhthalene lbs/Maal Er Diesel 3 5.92E-03 7.0BE-04 1.00 No. 2 Distillate " 6.78E-03 9.J9E·03 1.00 No

Turbine. Distillate PAH Phenanthrene lbs/Maal Er Diesel 3 2.13E·05 1.47E·05 1.00 No. 2 Dlsllllate 1' 3.38E-04 5.62E·04 1.00 No

Turbine DJ§!illate Ml:!__ ~~~ lbs/Mnal Er Diesel 3 4.46E-06 2.12E·06 0.81 No. 2 DistlHate 1' 8.22E-05 1.04E-04 0.25 ~

6-17

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (I-statistics).

Group Category Substance EFUnrt Value Type First Samole Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

s::c Deviation Ratio s::c Deviation Ratio 95%Confidence Asohalt Prod. Diesel Metals Arsenic lbs/ton oroduction EF 30500205 6 3.12E-06 3.51E-06 0.01 30500211 3 2.73E-07 3.93E·09 0.00 No Asohalt Prod. Diesel Metals Bervllium lbs/ton oroduction EF 30500205 6 9.15E-07 1.53E-06 0.00 30500211 3 5.45E-07 7.85E-09 0.00 No Asohalt Prod. Diesel Metals Cadmium lbs/ton oroduction EF 30500205 6 7.92E-06 1.77E-05 0.98 30500211 1 1.62E-06 1.00 No Asohalt Prod. Diesel Metals Chromium lbs/ton nroduction EF 30500205 6 1.53E-05 3.37E-05 1.00 30500211 3 1.96E-06 1.27E·06 1.00 No Asohalt Prod. Diesel Metals Chromium lHex) lbs/ton oroduction EF 30500205 5 7.24E-07 8.74E-07 0.07 30500211 3 3.61E-07 1.59E·07 1.00 No Asnhalt Prod. Diesel Metals Cooner lbs/ton oroduction EF 30500205 6 2.28E-05 5.36E-05 1.00 30500211 2 1.50E-06 2.22E-07 1.00 No Asohalt Prod .. Diesel Metals Lead lbs/ton oroduction EF 30500205 6 3.67E-04 8.92E-04 1.00 30500211 3 2.01E·06 8.58E-07 1.00 No Asohalt Prod. Diesel Metals Manaanese lbs/ton nroduction EF 30500205 6 2.79E-04 6.64E-04 1.00 30500211 3 1.24E-05 4.38E-06 1.00 No Asohalt Prod. Diesel Metals Mercurv lbs/ton oroduction EF 30500205 6 1.82E-06 2.25E-06 0.81 30500211 3 4.88E-08 2.84E-08 0.52 No Asnhalt Prod .. Diesel Metals Nickel lbs/ton oroduction EF 30500205 6 6.55E-05 1.54E-04 0.00 30500211 3 2.73E-06 3.93E·08 0.00 No Asohalt Prod .. Diesel Metals Selenium lbs/ton oroduction EF 30500205 6 3.67E-06 2.96E-06 0.08 30500211 3 2.73E-07 3.93E-09 0.00 No Asohalt Prod. Diesel Metals Zinc lbs/ton nroduction EF 30500205 6 7.96E-04 1.87E-03 1.00 30500211 3 1.82E-05 5.62E-06 1.00 No Asohalt Prod. Diesel PAI-I Acenaohthene lbs/ton oroduction EF 30500205 5 5.01E-07 6.66E-07 0.03 30500211 3 4.80E-07 4.21 E-07 1.00 No Asnhalt Prod. Diesel PAI-I Acenanhth"lene lbs/ton oroduction EF 30500205 5 5.00E-07 6.66E-07 0.02 30500211 3 3.36E-07 2.72E-07 1.00 No Asohalt Prod .. Diesel PAI-I Anthracene lbs/ton oroduction EF 30500205 5 1.12E-06 1.94E•06 0.81 30500211 3 3.21E-08 7.68E-09 1.00 No Asohalt Prod. Diesel PAI-I Benzola)anthracene lbs/ton nroduction EF 30500205 5 4.92E-07 6.74E-07 0.01 30500211 3 6.12E-OB 2.51E-08 1.00 No Asnhalt Prod. Diesel PAI-I Benzola'n."rene lbs/ton oroduction EF 30500205 5 4.88E-07 6.77E-07 0.00 30500211 3 2.79E-09 1.45E-09 1.00 No Asnhalt Prod .. Diesel PAI-I Benzotb\fluoranthene lbs/ton oroduction EF 30500205 3 4.39E-09 6.44E·09 1.00 30500211 3 1.39E-08 9.49E-09 1.00 No Asohalt Prod., Diesel PAI-I Benzo{o.h i\nervlene lbs/ton oroduction EF 30500205 5 4.88E-07 6.77E-07 0.00 30500211 3 1.90E-09 6.76E-10 0.23 No Asohalt Prod. Diesel PAI-I Benzo(kHluoranthene lbs/ton nroduction EF 30500205 5 4.89E-07 8.77E-07 0.00 30500211 3 5.13E-09 2.90E-09 1.00 No Asohalt Prod. Diesel PAI-I Chn/C!ene lbs/ton oroduction EF 30500205 5 4.89E-07 6.77E-07 0.00 30500211 3 2.70E-08 1.23E-08 1.00 No Asnhalt Prod. Diesel PAI-I dibenzla h\anthracene lbs/ton oroduction EF 30500205 5 4.88E-07 6.77E-07 0.00 30500211 3 1.76E-09 B.74E-10 0.00 No Asnhalt Prod .. Diesel PAI-I Fluoranthene lbs/ton oroduction EF 30500205 5 5.40E-07 6.31E-07 0.10 30500211 3 2.17E-07 1.63E-08 1.00 No Asohatt Prod. Diesel PAI-I Fluorene lbs/ton oroduction EF 30500205 5 6.55E-07 5.44E-07 0.25 30500211 3 8.83E-07 3.05E-07 1.00 No Asohalt Prod. Diesel PAI-I lndenol1 2 3-cdlnvrene lbs/ton oroduction EF 30500205 5 4.88E-07 6.77E-07 0.00 30500211 3 2.06E-09 5.13E-10 0.29 No Asohalt Prod. Diesel PAI-I Naohthalene lbs/ton oroduction EF 30500205 5 6.93E-04 9.53E-04 1.00 30500211 3 4.75E-05 2.78E-05 1.00 No Asnhalt Prod. Diesel PAI-I Phenanthrene lbs/ton oroduction EF 30500205 5 4.95E-06 6.84E-06 1.00 30500211 3 6.27E-07 2.36E-07 1.00 No Asohalt Prod. Diesel PAI-I Pvrene lbs/ton oroduction EF 30500205 5 5.24E-07 6.45E-07 0.07 30500211 3 1.66E-07 8.21E-09 1.00 No Asohalt Prod. Diesel voe Benzene lbs/ton nroduction EF 30500205 6 5.81E-04 5.20E-04 0.10 , ' ".,: ... ,_,

Yes Asohalt Prod. Diesel voe Formaldehvde lbs/ton oroduction EF 30500205 5 1.70E-04 1.14E-04 1.00 30500211 3 1.32E-04 5.94E-05 1.00 No Asnhatt Prod. Natural Gas Metals Arsenic lbs/ton oroduction EF 30500205 3 2.16E-06 4.32E-07 0.00 30500211 11 8.22E-06 2.09E-05 0.77 No Asnhatt Prod. Natural Gas Metals Beryllium lbs/Ion oroduction EF 30500205 3 2.13E-07 4.12E-OB 0.00 30500211 11 9.00E-07 5.89E-07 0.00 No Asohalt Prod. Natural Gas Metals Cadmium lbs/ton nroduction EF 30500205 3 4.27E-07 8.25E-08 0.00 30500211 11 2.64E-06 3.28E-06 0.78 No Asohalt Prod. Natural Gas Metals Chromium lbs/ton oroduction EF 30500205 2 4.51 E-06 4.53E-06 1.00 30500211 11 1.69E-06 1.65E-06 0.84 No Asnhatt Prod. Natural Gas Metals Chromium /Hex) lbs/ton oroduction EF 30500205 2 5.60E-07 1.63E-07 0.60 30500211 11 1.59E-06 2.82E-06 0.83 No Asohalt Prod. Natural Gas Metals Conner lbs/ton oroduction EF 30500205 3 3.38E-06 6.12E-07 1.00 30500211 11 4.38E-06 4.39E-06 0.83 No Asohatt Prod. Natural Gas Metals Lead lbs/ton oroduction EF 30500205 3 1.07E-OB 2.10E-07 0.00 30500211 11 1.40E-05 3.16E-05 0.95 No Asohatt Prod. Natural Gas Metals Mann<>nase lbs/ton oroduction EF 30500205 3 1.47E-05 8.27E-06 1.00 30500211 11 5.05E-05 6.96E-05 1.00 No Asnhalt Prod. Natural Gas Metals Mercurv lbs/ton aroduction EF 30500205 3 4.73E-07 1.19E-07 1.00 30500211 11 9.12E-06 1.17E-05 1.00 No Asohalt Prod. Natural Gas Metals Nickel lbs/ton nroduction EF 30500205 3 9.53E·06 5.66E-06 1.00 30500211 11 7.94E-06 1.15E-05 0.46 No Asohalt Prod. Natural Gas Metals Selenium lbs/ton oroduction EF 30500205 3 2.15E-06 4.19E-07 0.00 30500211 11 1.36E-05 3.86E-05 0.86 No Asnhatt Prod. Natural Gas Metals Zinc lbs/ton oroduction EF 30500205 3 3.99E-05 2.43E-06 1.00 30500211 11 2.21E-05 2.18E-05 1.00 No Asohalt Prod. Natural Gas PAI-I Acenaohthene lbs/ton nroduction EF 30500205 3 1.92E-07 7.35E-09 0.00 30500211 11 7.33E-07 4.20E-07 0.71 No Asohalt Prod. Natural Gas PAI-I Acenaohthvlene lbs/ton oroduction EF 30500205 3 1.92E-07 7.35E-09 0.00 30500211 10 1.61 E-06 3.20E-06 0.86 No Asohatt Prod. Natural Gas PAI-I Anthracene lbs/ton oroduction EF 30500205 3 1.92E-07 7.35E-09 0.00 30500211 11 3.64E-07 4.75E-07 0.42 No Asnhalt Prod. Natural Gas PAI-I Benzot a \anthracene lbs/ton nroduction EF 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.97E-07 5.29E-07 0.03 No Asohalt Prod. Natural Gas PAI-I Benzo(a)ovrene lbs/ton oroduction EF 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.89E-07 5.34E-07 0.00 No Asohalt Prod. Natural Gas PAI-I Benzo(b)fluoranthene lbs/ton oroduction EF 30500205 3 1.92E·07 7.35E-09 0.00 30500211 8 2.90E-07 5.33E-07 0.00 No

6-18

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (t-s1atistics).

Group Category Substance EF Uni Value Type First Samnle Statistics Second Same le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

sx Deviation Ratio sx Deviation Ratio 95%Confidence Asphalt Prod. Natural Gas PAH Benzo(a h i\oervlene lbs/ton oroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.89E-07 5.33E-07 0.00 No

Asohalt Prod Natural Gas PAH Benzo{k\fluoranthene lbs/ton nroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.90E-07 5.33E-07 0.01 No

Asohalt Prod Natural Gas PAH Chrusene tbs/ton nroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.90E-07 5.33E-07 0.00 No

Asnhalt Prod. Natural Gas PAH dibenzla h)anthracene lbs/ton nroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.89E-07 5.34E-07 0.00 No Asohalt Prod. Natural Gas PAH Fluoranthene lbs/ton oroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 11 5.82E-07 1.09E-06 0.64 No

Asohalt Prod. Natural Gas PAH Fluorene lbs/ton nroductlon s= 30500205 3 2.23E-06 2.52E-07 1.00 30500211 11 1.62E-06 8.29E-07 0.87 No

Asohalt Prod. Natural Gas PAH lndeno(1 2 3•cd\..,..,rene lbs/ton nroduction s= 30500205 3 1.92E-07 7.35E-09 0.00 30500211 8 2.89E-07 5.33E-07 0.00 No

Asnhalt Prod. Natural Gas PAH Naohthalene lbs/ton oroduction s= 30500211 11 2.05E-05 2.34E-05 0.99 Yes Asohalt Prod. Natural Gas PAH Phenanthrene lbs/ton nroduction s= 30500205 3 3.76E-06 6.58E-07 1.00 30500211 11 2.35E-06 1.95E-06 1.00 No

Asohalt Prod .. Natural Gas PAH Pvrene lbs/ton nroduction s= 30500205 3 1.99E-07 1.09E-08 0.35 30500211 11 8.97E-07 2.08E-06 0.77 No

Asohalt Prod. Natural Gas voe Benzene lbs/ton nroduction s= 30500205 2 2.29E-05 2.74E-06 1.00 30500211 11 9.32E-05 1.15E-04 1.00 No

Boiler Distillate PAH Acenaohthene lbs/Mnal s= 10200501 2 1 .31 E-05 1.00E-06 0.00 10300501 14 2.39E-04 4.10E·04 1.00 No

Boiler Distillate PAH Acenanhthvlene lbs/Moal s= 10200501 2 1.92E-05 1.20E-06 0.00 10300501 15 7.11E-05 8.69E·05 0.79 No

Boiler Distillate PAH Anthracene lbs/Mnal s= 10200501 2 1.53E-05 6.97E-07 0.00 10300501 16 2.50E-05 2.43E-05 1.00 No

Boiler Distillate PAH Benzo' a \anthracene lbs/Mnal s= 1 0200501 2 1.04E-05 2.80E-06 0.59 10300501 14 7.78E-06 4.90E-06 0.48 No

Boiler Distillate PAH Benzofa)ovrene lbs/Mnal s= 1 0200501 2 1.58E-05 1.94E-06 0.00 10300501 16 6.52E-06 6.17E-06 0.12 No

Boiler Distillate PAH Benzolb)fluoranthene lbs/Moal s= 10200501 2 1.15E-05 5.25E-07 0.00 10300501 16 6.07E-06 6.64E-06 0.20 No

Boiler Distillate PAH Benzoln h i)nervlene lbs/Mnal s= 10200501 2 1.77E-05 1.32E-06 0.00 10300501 18 7.48E-06 7.69E-06 0.26 No

Boiler Distillate PAH Benzo(k)fluoranthene lbs/Mnal s= 10200501 2 1.43E-05 2.53E-06 0.00 10300501 16 9.17E-05 2.37E-04 0.97 No

Boiler Distillate PAH Chrvsene lbs/Mnal s= ,,,~,; -,Iii· ~::.f.M,H 10300501 14 6.53E-06 6.02E-06 0.54 Yes Boiler Distillate PAH dibenzla h)anthracene lbs/Maal s= 10200501 2 2.60E-05 1.76E-06 0.00 10300501 18 4.33E-06 3.41E-06 0.17 Yes

Boiler Distillate PAH Fluoranthene lbs/Mnal s= 10200501 3 4.99E-05 2.75E-05 1.00 10300501 14 2.97E-05 2.1 lE-05 0.93 No

Boiler Distillate PAH Fluorene lbs/Mnal s= 10200501 2 2.04E-05 7.72E-07 0.00 10300501 14 1.31E-04 7.95E-05 1.00 No

Boiler Distillate PAH lndeno/1 2 3-cd' ... "rene lbs/Mnal s= 10200501 2 2.06E-05 1.71E-06 0.00 10300501 18 5.09E-06 3.34E-06 0.23 Yes

Boiler Distillate PAH Naohthalene lbs/Mnat s= 10200501 3 1.97E-02 3.89E-03 1.00 10300501 17 4.28E-01 9.71 E-01 1.00 No

Boiler Distillate PAH Phenanthrene lbs/Moal s= 1 0200501 3 1.59E-04 3.28E-05 1.00 10300501 15 4.14E-04 3.06E·04 1.00 No Boiler, Distillate PAH Pvrene lbs/Mnal s= 10200501 3 6.30E-05 5.00E-05 0.39 10300501 14 3.60E-05 2.40E·05 1.00 No

Boiler Distillate voe Formaldehvde lbs/Mnal s= 1-1 3· ·· .. 1-'---'¼-• . - " ..... 10300501 15 2.14E-01 4.71E-01 1.00 Yes

Boiler, Fuel 011 Metals Arsenic lbs/Mgal s= 10100401 9 1.06E-03 5.51 E-04 I.~:: 10200401 15 5.76E-04 9.64E-04 0.78 No

Boiler, Fuel Oil Metals Arsenic lbs/Mgal s= 10100401 ... ·t~, ,,.~ 10200402 3 2.29E-04 5.83E-05 0.31 Yes

Boiler, Fuel Oil Metals Arsenic lbs/Mgal s= 10100401 9 1.06E-03 5.51E-04 1.00 10200403 3 1.44E-03 2.44E·04 0.00 No

Boiler, Fuel Oil Metals Arsenic lbs/Mgal s= 10200401 15 5.76E-04 9.64E-04 0.78 10200402 3 2.29E-04 5.83E·05 0.31 No

Boiler, Fuel Oil Metals Arsenic lbs/Mgal EF 1 0200401 15 5.76E-04 9.64E-04 0.78 10200403 3 1.44E-03 2.44E-04 0.00 No

Boiler Fuel Oil Metals Arsenic lbs/Moal s= 10200402 3 2.29E-04 5.83E-05 0.31 10200403 3 1.44E-03 2.44E-04 0.00 Yes

Boiler, Fuel Oil Metals Beryllium lbs/Mgal s= 10100401 9 1.48E-05 1.50E-05 0.62 10200401 15 6.19E-04 1.25E-03 0.97 No

Boiler, Fuel Oil Metals Beryllium lbs/Mgal s= 10100401 9 1.48E-05 1.50E-05 0.62 10200402 3 5.12E-05 1.48E-o6 0.00 Yes

Boiler, Fuel Oil Metals Beryllium lbs/Mgal s= 10100401 9 1.48E-05 1.50E-05 0.62 10200403 3 6.29E-05 7.69E-o8 0.00 Yes

Boiler, Fuel Oil Metals Beryllium lbs/Mgal s= 10200401 15 6.19E-04 1.25E•03 0.97 10200402 3 5.12E-05 1.48E-06 0.00 No

Boiler, Fuel Oil Metals Beryllium lbs/Mgal s= 10200401 15 6.19E-04 1.25E-03 0.97 10200403 3 6.29E-05 7.69E-06 0.00 No

Boiler Fuel Oil Metals Bervllium lbs/Mnal s= 10200402 3 5.12E-05 1.48E-06 0.00 10200403 3 6.29E-05 7.69E·06 0.00 No

Boiler. Fuel Oil Metals Cadmium lbs/Mgal s= 10100401 9 2.23E-04 2.32E-04 1.00 ~-2~.?~401 1 5 4.12E-04 1,1o_E-04 0.80 No

Boiler, Fuel Oil Metals Cadmium lbs/Mgal s= 10100401 9 2.23E-04 2.32E-04 1.00 :,{. ;, ,,;,~--,~ ~-. j~-;j Yes

Boiler, Fuel Oil Metals Cadmium lbs/Mgal s= 10100401 9 2.23E-04 2.32E-04 1.00 10200403 3 8.56E-04 3.52E-04 0.00 Yes lbs/Mgal s= 10200401 15 4.12E-04 7.l0E-04 A ::)~Ji :?< ,,_,., .,,,,3-••-e,~

Yes Boiler, Fuel Oil Metals Cadmium 0.80 :.,,, ~. Boiler, Fuel Oil Metals Cadmium lbs/Mgal s= 10200401 15 4.12E-04 7.10E-04 0.80 10200403 3 8.56E-04 3.52E-04 0.00 No

Boiler Fuel Oil Metals Cadmium lbs/Mnal s= 10200402 3 2.23E-02 2.45E-02 1.00 10200403 3 8.56E-04 3.52E·04 0.00 No

Boiler, Fuel Oil Metals Chromium lbs/Mgal s= 10100401 9 6.09E-04 2.44E-04 1.00 10200401 15 1.01 E-03 1.86E-03 0.97 No

Boiler, Fuel Oil Metals Chromium lbs/Mgal s= 10100401 9 6.09E-04 2.44E-04 1.00 10200402 3 1.99E-03 4.18E-04 0.00 Yes

6-19

TABLE AB-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (!-statistics).

Group I Category! Substance \ EF Unit !Value Typel First Sample Statistics Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

9X Deviation Ratio S::C Deviation Ratio 95%Confidence Boiler, Fuel Oil Metals Chromium lbs/Mgal EF 10100401 9 6.09E-04 2.44E-04 1.00 •:l~'!\i,t;· ;/•:·~ne:q;'',ii;;J'[fi~,li G~,"if.ilfJt Yes

Boiler,FuelOi-I Metals Chromium 1bs/Mgal s= 10200401 15 1.01E-03 1.86E-03 0.97 liiiia---•·4.18E-~1.,, No Boiler. Fuel Oil Metals Chromium lbs/Mga1 s= 10200401 15 1.01 E-03 1.86E-03 0.97 -. Yes Boiler Fuel Oil Metals Chromium lbs/Maal e= 10200402 3 1.99E-03 4.1 SE-04 0.00 · "' ,__ Yes Boiler, Fuel Oil Metals Chromium (Hex) lbs/Mgal EF 10100401 9 1.81 E-04 1.72E-04 0.90 10200401 12 1.50E-04 8.63E-05 0.56 No Boiler, Fuel Oil Metals Chromium (Hex) lbs/Mgal EF 10100401 9 1.81E-04 1.72E-04 0.90 10200402 3 3.48E-04 5.15E-05 0.00 No Boiler, Fuel Oil Metals Chromium (Hex) lbs/Mgal EF 10100401 9 1.81E-04 1.72E-04 0.90 10200403 3 1.15E-03 5.70E-05 0.00 Yes Boiler, Fuel Oil Metals Chromium (Hex) lbs/Mgal EF 10200401 12 1.50E-04 8.63E-05 0.56 10200402 3 3.48E-04 5.15E-05 0.00 Yes Boiler, Fuel Oil Metals Chromium (Hex) lbs/Mgal EF 10200401 12 1.50E-04 8.63E-05 0.56 10200403 3 1.15E-03 5.70E-05 0.00 Yes Boiler Fuel Oil Metals Chromium IHexl lbs/Moal EF 10200402 3 3.48E-04 5.15E-05 0.00 10200403 3 1.15E-03 5.70E-05 0.00 Yes Boiler, Fuel Oil Metals Copper lbs/Mgal EF 10100401 9 1.40E-03 5.60E-04 1.00 10200401_ 15 5.18E-03 •·· 5.52E-03 _/-90 No Boiler, Fuel Oil Metals Copper lbs/Mgal EF 10100401 9 1.40E-03 5.60E-04 1.00 . •lltoiwlil•.--, ,,,JI, :•*~};, ,;.czliil!i%;: ,:•~- Yes Boiler, Fuel Oil Metals Copper lbs/Mgal EF 10100401 9 1.40E-03 5.60E-04 1.00 10200403 3 3.86E-03 4.20E-03 1 .00 No Boiler, Fuel Oil Metals Copper lbs/Mgal EF 10200401 1 5 5.18E-03 5.52E-03 1.00 10200402 3 3.41 E-03 2.35E·03 1.00 No Boiler, Fuel Oil Metals Copper lbs/Mgal EF 10200401 15 5.18E-03 5.52E-03 1.00 10200403 3 3.86E-03 4.20E-03 1.00 No Boiler Fuel Oil Metals Cooner lbs/Maal EF 10200402 3 3.41 E-03 2.35E-03 1.00 10200403 3 3.86E-03 4.20E-03 1.00 No Boiler, Fuel Oil Metals Lead lbs/Mgal EF 10100401 9 1.61 E-03 1.12E-03 1 .00 10200401 1 5 6.32E-03 1.24E·02 0.96 No Boiler, Fuel Oil Metals Lead lbs/Mgal EF 10100401 9 1.61E-03 1.12E-03 1.00 10200402 3 2.44E-03 4.06E·04 0.39 No Boiler, Fuel Oil Metals Lead lbs/Mgal EF 10100401 9 1.61E-03 1.12E-03 1.00 10200403 3 1.56E-03 1.54E-03 0.00 No Boiler, Fuel Oil Metals Lead lbs/Mgal EF 10200401 1 5 6.32E-03 1.24E-02 0.96 10200402 3 2.44E-03 4.06E-04 0.39 No Boiler, Fuel Oil Metals Lead lbs/Mgal EF 10200401 1 5 6.32E-03 1.24E·02 0.96 10200403 3 1.56E-03 1.54E-03 0.00 No Boiler. Fuel Oil Metals Lead lbs/Mnal EF 10200402 3 2.44E-03 4.06E-04 0.39 16200403 3 1.56E-03 1.54E-03 0.00 No Boiler, Fuel Oil Metals Manganese lbs/Mgal S:: l 0100401 9 1.58E-03 1.37E-03 1 .00 1 0200401 15 3.94E-02 1.41 E-01 1.00 No Boiler, Fuel Oil Metals Manganese lbs/Mgal B= 10100401 9 1.58E-03 1.37E-03 1.00 1~20_~~-~2,, __ ., 3 1.~6E:03 2.~2E~0~ 0.0~ No Boiler, Fuel Oil Metals Manganese lbs/Mgal EF 10100401 9 1.58E-03 1.37E-03 1.00 :t~:•. -_i# ·JJl'tm, °>"ii.-S f.00 Yes Boiler, Fuel Oil Metals Manganese lbs/Mgal EF 1 0200401 1 5 3.94E-02 1.41 E-01 1.00 10200402 3 1.66E-03 2.32E-04 0.00 No Boiler, Fuel Oil Metals Manganese lbs/Mgal S:: 10200401 1 5 3.94E-02 1.41 E-01 1 .00 1 0200403 3 5.81 E-03 5.54E-03 1 .00 No Boiler Fuel Oil Metals Manaanese lbs/Maal EF 10200402 3 1.66E-03 2.32E-04 0.00 10200403 3 5.81 E-03 5.54E-03 1.00 No Boiler, Fuel Oil Metals Mercury lbs/Mgal EF 10100401 9 3.06E·03 1.91 E-03 0.00 10200401 1 5 2.76E-04 3.73E-04 0. 75 Yes Boiler, Fuel Oil Metals Mercury lbs/Mgal EF 10100401 9 3.06E-03 1.91 E-03 0.00 10200402 3 5.43E-05 9.58E-07 0.00 Yes Boiler, Fuel Oil Metals Mercury lbs/Mgal EF 10100401 9 3.06E-03 1.91E-03 0.00 10200403 3 1.03E-05 3.93E-06 0.00 Yes Boiler, Fuel Oil Metals Mercury lbs/Mgal EF 10200401 1 5 2.76E-04 3.73E-04 0. 75 10200402 3 5.43E-05 9.58E-07 0.00 No Boiler, Fuel Oil Metals Mercury lbs/Mgal S:: 10200401 1 5 2.76E-04 3. 73E-04 0. 75 10200403 3 1.03E-05 3.93E-06 0.00 No Boiler Fuel OIi Metals Mercurv lbs/Maal EF 1 0200402 3 5.43E-05 9.58E-07 0.00 10200403 3 1.03E-05 3.93E-06 0.00 Yes Boiler, Fuel Oil Metals Nickel lbs/Mgal EF 10100401_ 9 9,75E-02 ·•5A5E-02 1.00 10200401 15 1.06E-01 1.71E-01 1.00 No

Boiler, Fuel Oil Metals Nickel lbs/Mgal EF • liJHoi' .•11 · ,t',~{ E :-J'~l!/,?}11-0\~ ,1,0200402 ,,,} .. 1 -,~~§:OJ .. ,. _L97E·03 •. 0.65_ Yes Boiler,FuelOil Metals Nickel lbs/Mgal EF 10100401 9 9.75E-02 5.45E·02 1.00 ,· ' if. · ... " .~a:;. Yes Boiler, Fuel Oil Metals Nickel lbs/Mgal EF 10200401 15 1.06E-01 1.71 E-01 1.00 10200402 3 1.59E-02 1.97E-03 0.85 No Boiler, Fuel Oil Metals Nickel lbs/Mgal EF 10200401 1 5 1.06E-01 1.71 E-01 1.00 t." - ' " . Yes Boiler Fuel Oil Metals Nickel lbs/Maal EF 10200402 3 1.59E-02 1.97E-03 0.65 '· Yes Boiler, Fuel Oil Metals Selenium lbs/Mgal EF 10100401 9 9.61 E-04 6. 71 E-04 0.87 10200401 15 4.32E-03 1.18E-02 0.69 No Boiler, Fuel Oil Metals Selenium lbs/Mgal EF 10100401 9 9.61 E-04 6.71 E-04 0.87 10200402 3 __ ,.__ 3.67E-04 __ 6.47E•05 0.00 No Boiler,Fuel01I Metals Selenium lbs/Mgal s= 10100401 9 9.61E-04 6.71E-04 0.87 !:;- :~·,- ,. "'"''· Yes Boiler, Fuel Oil Metals Selenium lbs/Mgal EF 10200401 15 4.32E-03 1.16E-02 0.69 10200402 3 3.67E-04 6.47E-05 0.00 No Boiler, Fuel Oil Metals Selenium lbs/Mgal EF 1 0200401 15 4.32E-03 1-16E-02 0.69 10200403 3 2.88E-03 1.24E-03 0.17 No Boiler Fuel Oil Metals Selenium lbs/Maal EF 10200402 3 3.67E-04 6.47E-05 0.00 it~~:~<~· ·1,: ~ ,.::::-- ,:t, Yes

Boiler. Fuel Oil Metals Zinc lbs/Mgal EF 10100401 9 1.41E-02 8.27E-03 1.00 10200401 15 1.26E-01 2.84E-01 1.00 No Boiler,FuelOil Metals ZJlC lbs/Mgal S:: 10100401 9 1.41E-02 8.27E-03 1.00 ~ ... ,d Ym

6-20

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (1-statistics).

Group Category Substance EFUnrt Value Type First Samele Statistics Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at = Deviation Ratio = Deviation Ratio 95%Confidence

Boiler, Fuel Oil Metals Zinc lbs/Mgal EF 10100401 9 1.41E-02 8.27E-03 1.00 10200403 3 1.B0E-02 1 .29E-02 1.00 No Boiler, Fuel Oil Metals Zinc lbs/Mgal EF 10200401 1 5 1.26E-01 2.84E-01 1.00 10200402 3 3.55E-02 1.74E-02 1.00 No Boiler, Fuel Oil Metals Zinc lbs/Mgal EF 10200401 15 1.26E-01 2.84E-01 1.00 10200403 3 1.BOE-02 1.29E-02 1.00 No Boiler Fuel Oil Metals Zinc lbs/Maal EF 10200402 3 3.55E-02 1 .74E-02 1.00 10200403 3 1.BOE-02 1.29E-02 1.00 No Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100401 12 3.11E-05 3.67E-05 0.99 10100501 2 1.38E-04 1.24E-06 0.00 Yes Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100401 12 3.11E-05 3.67E-05 0.99 10200401 15 2.85E-05 3.51E-05 0.03 No Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100401 12 3.11E-05 3.67E-05 0.99 10200402 3 2.79E-06 1.87E-06 1.00 No Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100401 12 3.11E-05 3.67E-05 0.99 10200403 3 1.44E-06 1.1 0E-07 1.00 No Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.85E-05 3.51 E-05 0.03 Yes Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 2.79E-06 1.87E-06 1.00 Yes Boiler. Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 1.44E-06 1.10E-07 1.00 Yes Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 10200401 15 2.85E-05 3.51 E-05 0.03 10200402 3 2.79E-06 1 .87E-06 1.00 No Boiler, Fuel Oil PAI-I Acenaphthene lbs/Mgal EF 1 0200401 15 2.85E-05 3.51 E-05 0.03 10200403 3 1.44E-06 1.1 0E-07 1.00 No Boiler Fuel Oil PAI-I Acenanhthene lbs/M□al EF 10200402 3 2.79E-06 1.87E-06 1.00 10200403 3 1.44E-06 1.10E-07 1.00 No Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00 10100501 2 L~8E-04 1.24E-06 0.00 Yes

/t\ % " '1= Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00 Yes Boiler, Fuet Oil PAI-I Acenaphthylene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00

.. J·, ~ ;) Yes Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00 10200403 3 2.86E-07 4.B0E-08 0.00 Yes Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.92E-05 3.47E-05 0.05 Yes Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 7.48E-05 9.57E-05 0.81 No Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 2.86E-07 4.60E-08 0.00 Yes Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 1 0200401 1 5 2.92E-05 3.47E-05 0.05 10200402 3 7.48E-05 9.57E-05 0.81 No Boiler, Fuel Oil PAI-I Acenaphthylene lbs/Mgal EF 10200401 15 2.92E-05 3.47E-05 0.05 10200403 3 2.86E-07 4.B0E-08 0.00 No Boiler Fuel Oil PAI-I Acenaohthvlene lbs/Mnal EF 10200402 3 7.48E-05 9.57E·05 0.81 10200403 3 2.86E-07 4.60E-08 0.00 No Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 10100401 12 2.27E-06 1.56E-06 0.90 10100501 2 1.38E-04 1.24E-06 0.00 Yes Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 10100401 12 2.27E-06 1.56E-06 0.90 '10tol401' i:-15' I :t•'"· ~) O.ol Yes Boiler. Fuel Oil PAI-I Anthracene tbs/Mgal EF 10100401 12 2.27E-06 1.56E-06 0.90 10200402 3 9.08E-07 8.86E-07 0.00 No Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 101INl401 12· :t271!,01., t;lilliQjl;':. fl. o;eo .. 10200403 3 4.03E-08 2.36E·08 0.00 Yes Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.94E-05 3.45E-05 0.05 Yes Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 9.08E-07 8.86E-07 0.00 Yes Boiler, Fuel Oil PAH Anthracene lbs/Mgal EF 10100501 2 1 .38E-04 1.24E-06 0.00 10200403 3 4.03E·08 2.36E·08 0.00 Yes Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 10200401 15 2.94E-05 3.45E-05 0.05 10200402 3 9.08E-07 8.86E·07 0.00 No Boiler, Fuel Oil PAI-I Anthracene lbs/Mgal EF 1 0200401 15 2.94E-05 3.45E-05 0.05 10200403 3 4.03E-08 2.36E·08 0.00 No Boiler Fuel Oil PAI-I Anthracene lbs/Moal EF 10200402 3 9.08E-07 8.86E-07 0.00 10200403 3 4.03E-08 2.36E·08 0.00 No Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100401 12 2.08E-06 3.45E-06 0.52 10100501 2 1.38E-04 1.24E-06 0.00 Yes Boiler. Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100401 12 2.08E-06 3.45E-06 0.52 .i 10200,uf~ t,;'.tl: i/-t.-llf:; ·-~: ,-:@.i:-, Yes Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100401 12 2.08E-06 3.45E-06 0.52 10200402 3 1.76E-08 1.92E-08 0.00 No Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100401 12 2.08E-06 3.45E-06 0.52 10200403 3 5.99E·08 4.25E-08 0.00 Na Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.82E-05 3.53E-05 0.01 Yes Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100501 2 t.38E-04 1.24E-06 0.00 10200402 3 1 .76E-08 1.92E·08 0.00 Yes Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 5.99E-08 4.25E·08 0.00 Yes Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10200401 15 2.82E-05 3.53E-05 0.01 10200402 3 1 .76E-08 1.92E-08 0.00 Na Boiler, Fuel Oil PAI-I Benzo(a)anthracene lbs/Mgal EF 10200401 15 2.82E-05 3.53E-05 0.01 10200403 3 5.99E-08 4.25E·08 0.00 No Boiler Fuel Oil PAI-I Benzo(a)anthracene lbs/Maal EF 10200402 3 1.76E-08 1.92E-08 0.00 10200403 3 5.99E-08 4.25E-08 0.00 No Boiler, Fuel Oil PAI-I Benzo(a)pyrene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00 10100501 2 1.38E-04 1.24E-06 0.00 Yes Boiler. Fuel Oil PAI-I Benzo(a)pyrene lbs/Mgal EF 10100401 12 1.08E-06 2.09E-07 0.00 ,.MMi a, ~'l,Q;Ji]il;: f:~ , .~~· Yes Boiler, Fuel Oil PAI-I Benzo(a)pyrene lbs/Mgal EF 10100401 12 t.08E-06 2.09E-07 0.00 10200402 3 9.09E-07 1.53E·06 0.00 No Boiler, Fuel Oil PAI-I Benzo(a)pyrene lbs/Mgal EF 10100401 12 1 .08E-06 2.09E-07 0.00 10200403 3 7.07E-08 3.78E·08 0.00 Yes

6-21

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (!·statistics).

Group Category Substance EFUnn Value Type First Samele Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

= Deviation Ratio sec Deviation Ratio 95%Confidence Boiler, Fuel Oil PAH Benzo(a)pyrene lbs/Mgal 8' 10100501 2 1 .38E-04 1.24E-06 0.00 10200401 1 5 3.28E-05 3.28E-05 0.16 Yes Boiler, Fuel Oil PAH Benzo(a)pyrene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 9.09E-07 1.53E-06 0.00 Yes Boiler, Fuel Oil PAH Benzo(a)pyrene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 7.07E-08 3.78E-08 0.00 Yes Boiler, Fuel Oil PAH Benzo(a)pyrene \bs/Mgal 8' 10200401 15 3.28E-05 3.28E-05 0.16 10200402 3 9.09E-07 1.53E-06 0.00 No Boiler, Fuel Oil PAH Benzo(a)pyrene \bs/Mgal 8' 10200401 15 3.28E-05 3.28E-05 0.16 10200403 3 7.07E-08 3.78E-08 0.00 No Boiler Fuel Oil PAH Benzofa\,...,,rene lbs/Maal 8' 10200402 3 9.09E-07 1.53E-06 0.00 10200403 3 7.07E-08 3.78E-08 0.00 No Boiler, Fuel Oil PAH Benzo(b)fluoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200401 9 4.68E-05 3.48E-05 0.02 Yes Boiler, Fuel Oil PAH Benzo(b)tluoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 2.36E-06 1.25E-06 0.63 Yes Boiler, Fuel Oil PAH Benzo(b)fluoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 1.95E-06 5.53E-07 0.37 y..,

Boiler, Fuel Oil PAH Benzo(b)fluoranthene lbs/Mgal 8' 1 0200401 9 4.68E-05 3.48E-05 0.02 10200402 3 2.36E-06 1.25E-06 0.63 No Boiler, Fuel Oil PAH Benzo(b)ftuoranthene lbs/Mgal 8' 1 0200401 9 4.68E-05 3.48E-05 0.02 10200403 3 1.95E-06 5.53E-07 0.37 No Boiler Fuel Oil PAH Benzo(b)fluoranthene lbs/Maal 8' 10200402 3 2.36E-06 1.25E-06 0.63 10200403 3 1.95E-06 5.53E-07 0.37 No Boiler Fuel Oil PAH Benzo<b+k)fluoranthene lbs/Maal 8' 10100401 12 1.52E-06 1.52E-06 0.34 10200401 6 1.60E-06 1.28E-06 0.43 No Boiler Fuel Oil PAH Benzofe'•"•rene lbs/Maal 8' 10200402 3 1.03E-06 1.42E-06 0.00 10200403 3 8.53E-07 3.85E-07 0.00 No Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10100401 12 1.29E-06 7.46E-07 0.23 ~_g __ 1,2c2,~2 1 2 1.38E-04 1.24E-06 0.00 Yes Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10100401 12 1.29E-06 7.46E-07 0.23 Lt. . ' ;,-'~ ~---•!. ·[---~ '•zr Yes Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10100401 1 2 1.29E-06 7.46E-07 0.23 10200402 3 1.02E-06 1.50E-06 0.00 No Boiler, Fuel Oil PAH Benzo(g,h.i)perylene lbs/Mgal 8' 10100401 12 1.29E-06 7.46E-07 0.23 10200403 3 1.65E-06 4.81 E-07 0.00 No Boiler, Fuel Oil PAH Benzo(g, h, i)perylene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.85E-05 3.51 E-05 0.02 Yes Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 1.02E-06 1.50E·06 0.00 Yes Boiler, Fuel Oil PAH Benzo(g,h,i)perylene \bs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 1.65E-06 4.81E-07 0.00 Yes Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10200401 15 2.85E-05 3.51E-05 0.02 10200402 3 1.02E-06 1.50E-06 0.00 No Boiler, Fuel Oil PAH Benzo(g,h,i)perylene lbs/Mgal 8' 10200401 15 2.85E-05 3.51E-05 0.02 10200403 3 1.65E-06 4.81E-07 0.00 No Boiler Fuel Oil PAH Benzo(a,h i\nervlene lbs/Mnal 8' 10200402 3 1.02E-06 1.50E-06 0.00 10200403 3 1.65E-06 4.81 E-07 0.00 No Boiler, Fuel Oil PAH Benzo(k)fluoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200401 9 4.60E-05 3.60E-05 0.00 Yes Boiler, Fuel Oil PAH Benzo(k)ffuoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 1.28E-08 9.24E·09 0.00 Yes Boiler, Fuel Oil PAH Benzo(k)fluoranthene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 6.69E-08 6.32E·08 0.00 Yes Boiler, Fuel 011 PAH Benzo(k)fluoranthene \bs/Mgal 8' 10200401 9 4.60E-05 3.60E-05 0.00 10200402 3 1.28E-08 9.24E-09 0.00 No Boiler, Fuel Oil PAH Benzo(k)fluoranthene lbs/Mgal 8' 10200401 9 4.60E-05 3.60E-05 0.00 10200403 3 6.69E-08 6.32E-08 0.00 No Boiler Fuel Oil PAH Benzolklfluoranthene lbs/Maal 8' 10200402 3 1.28E-08 9.24E-09 0.00 10200403 3 6.69E-08 6.32E-08 0.00 No Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10100401 12 1.14E-06 2.70E-07 0.12 :i-~ 1.38E-04 \.~, Yes Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10100401 12 1.14E-06 2.70E-07 0.12 • Yes

. ~iq: ,, ":' -;~;;

llf Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10100401 12 1.14E-06 2.70E-07 0.12 : )1"· -_ :. :~~ Yes

Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10100401 12 1.14E-06 2.70E-07 0.12 Yes Boiler. Fuel Oil PAH Chrysene !bs/Mgat 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.81 E-05 3.54E·05 0.01 Yes Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 2.16E-05 3.99E-06 1.00 Yes Boiler, Fuel Oil PAH Chrysene \bs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 6.45E-06 1.89E-06 1.00 Yes Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 10200401 15 2.81 E-05 3.54E-05 0.01 10200402 3 2.16E-05 3.99E-06 1.00 No Boiler, Fuel Oil PAH Chrysene lbs/Mgal 8' 1 0200401 15 2.81E-05 3.S_~E-05, ,, 0.01 10200403 3 6.45E-06 1.89E-06 1.00 No

'"' i ;jj :iif'"",i·<,,",,~,-,, ➔

Boiler Fuel Oil PAH Chrvsene lbs/Mna\ 8' \,:_, -;;f, 10200403 3 6.45E-06 1.89E-06 1.00 Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100401 12 1.10E-06 2.11E-07 0.09 10100501 2 1.38E-04 1.24E-06 0.00 Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100401 12 1.10E-06 2.11E-07 0.09 ~t-, 7,"';-· ,., {~'.;

. ' '.IIIM*,' Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100401 12 1.10E-06 2.11 E-07 0.09 10200402 3 1.1 BE-06 1.44E-06 0.00 No Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100401 12 1.10E-06 2.11E-07 0.09 10200403 3 1.06E-06 1.40E-06 0.00 No Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200401 15 2.85E-05 3.51E-05 0.02 Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200402 3 1.16E-06 1.44E-06 0.00 Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10100501 2 1.38E-04 1.24E-06 0.00 10200403 3 1.06E-06 1.40E-06 0.00 Yes Boiler, Fuel Oil PAH dibenz(a,h)anthracene lbs/Mgal 8' 10200401 15 2.85E-05 3.51E-05 0.02 10200402 3 1.16E-06 1.44E-06 0.00 No

6-22

Group

Boiler, Fuel Oil Boiler, F_uel Oil Boiler. Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel 011 Boiler, Fuel 011 Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel 011 Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, F~~I Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler. Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil

Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil

Boil~[. F~I Oil Boiler, Fuel Oil Boiler, Fuel Oil

Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil

Category! Substance

PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH PAH

dibenz(a,h)anthracene

dib~z(a,h)anthracene Fluoranthene Fluoranthene Fluoranthene Fluoranthene Fluoranthene Fluoranthene Fluoranthene Fluoranthene Fluoranthene FluoranthenE;t Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene Fluorene lndeno(1,2 ,3-cd)pyrene lndeno( 1,2,3-cd)pyrene lndeno( 1,2,3-cd)pyrene lndeno( 1,2,3-cd)pyrene lndeno(1,2,3-cd)pyrene lndeno(1,2 ,3-cd)pyrene lndeno( 1 ,2 ,3-cd)pyrene lndeno( 1,2,3-cd)pyrene lndeno( 1,2,3-cd)pyrene lndeno{1,2,3-cd Naphthalene Naphthalene Naphthalene Naphthalene Naphthalene

Naphthalene Naphthalene Naphthalene Naphthalene Nap_hthalene Phenanthrene Phenanthrene Phenanthrene

Phenanthrene Phenanthrene Phenanthrene

TABLE A6•3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (l·stalistics).

EF Unrt

lbs/Mgal lbs/M_g!!_I lbs/Mgal

lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lb:,,'Mgal lbs/Mgal lbs/Mgal

lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lb~_LMgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal

lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal

lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal

Value Type First Sam le Statistics Second Sam le Statistics

El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El'

!E El' El' El' El' El' El' El' El' El' El' El' El' El' El' El' El'

Description Size Average Standard Detect Size Average Standard Detect Rati9 ~~-'--'----- Deviation Ratio _ Deviation

10200.401115 I 2.85E·05 I 3.51E __ •o5 J 0.02 10200403 3 1.06E-06 I 1.40E-06 10200~ 3 1.16E-06 1.44E-0_6 __ 0.00 10200403 3 1.06E-06 1.40E-06

0.00 0.00

10100401 112 , 3.24E-06 , 4.80E-06 0.87 10100401 1 2 3.24E-06 4.80E-06 0.87 10100401 12 3.24E-06 4.80E-06 0.87 10100401 12 3.24E-06 4.80E-06 0.87 10100501 2 1 01 00501 2 10100501 2 10200401 1 5 10200401 1 5 1 0200402 ~

10100401 1 2 10100401 12 10100401 1 2 10100401 1 2 I 0100501 2 10100501 2 10100501 2 10200401 15 10200401 ji~'i'-:..>:C'C

10100401 12 10100401 12 10100401 I 2 10100401 12 1 01 00501 2 10100501 2 10100501 2 10200401 1 5 1 0200401 I 5 1 0200_4_02 3

10100401 11 2 10100401 12 10100401 12

1.38E-04 1.38E-04 1.38E-04 2.92E-05 2.92E-05 2.86E·OS_ 3.75E-06 3.75E-06 3.75E-06 3.75E-06 1.38E-04 1.38E-04 1.38E·04 2.93E-05

1.26E-06 1.26E·06 1.26E-06 1.26E-06 1.38E-04 1.38E-04 1.38E-04 2.83E·05 2.83E-05 5.01 E_-0_7 3.21E-03 3.21E-03 3.21E·03

1010040~1~ 3.21E-03 10100501 2 3.54E-02

•~w',;~ 0•~ ':1)11' t '1ii ?~,-- __ ,_ _ - _j 1 0200401 15 1 0200401 15 10200402 3 10100401 12 10100401 12 10100401 12 10100401 12 10100501 2 10100501 2

6-23

8.78E-03 8.78E-03 9.77E·05 7.47E-06 7.47E-06 7.47E-06 7.47E-06 1.38E-04 1.38E-04

1.24E-06 0.00 1.24E-06 0.00 1.24E-06 0.00 3.65E-05 0.24 3.65E-05 0.24 9.5J_E·06 0.58 3.60E-06 0.90 3.60E-06 0.90 3.60E-06 0.90 3.60E-06 0.90 1.24E-06 0.00 1.24E-06 0.00 1.24E·06 0.00 3.44E-05 0.06 3.44E-05 0.06

6.42E-07 6.42E-07 6.42E-07 6.42E-07 1.24E-06 1.24E-06 1.24E-06 3.53E-05 3.53E-05 5_._86E-07 2.85E-03 2.85E-03 2.85E-03 2.85E-03

1.73E-02 1.73E-02 6.35E-05 7.63E-06 7.63E-06 7.63E-06 7.63E-06 1.24E-06 1.24E-06

0.21 0.21 0.21 0.21 0.00 0.00 0.00 0.01

1.00 1.00 1.00 0.97 0.97 0.97 0.97 0.00 0.00

10200401 115 10200402 3 10200403 3 10200402 3

2.92E-05 2.86E-05 1.36E-05 2.86E-05

3.65E-05 9.51 E-06 3.74E·06 9.51 E-06

0.24 0.58 1.00 0.58

102004·0·31 3 j 1.36E-05 3.74E-06 I 1.00 10200403 _ _L 1.36E-05 3.74E·06 1.00 10100501 2 1.38E-04 1 24 ·O 0.00 ~--w: :, ,r,'~ ; ~; 10200403 3 8.18E-06 2.93E·07 1.00 10200401 1 5 2.93E-05 3.44E•05 0.06 10200402 3 7.01 E-05 1.63E·05 1 .00 10200403 3 8.18E-06 2.93E-07 1.00 10200402 3 7.01E-05 1.63E·05 1.00 1 0200403 3 8.18E-06 2.93E·07 1.00 102004Q3 I 3 10100501 2

10~1.::1• 10200402 3 10200403 3 10200401 1 5 10200402 3 10200403 3 10200402 3 10200403 3

3

c:>l

8.1 S:E-06 1.38E-04

~-• 5.01 E-07 5.69E-07 2.83E-05 5.01 E-07 5.69E-07 5.01 E-07

15 8. 78E-03 3 9. 77E-05 3 7.26E-05

15 8.78E-03 3 9.77E-05 3 7.26E-05

10.200.40u 3 1 0200403 3 102004Q_3 ~

9.77E-05 7.26E-05 7.26E_-05

10100501 2 1.38E-04 10200401 1 5 5.05E-05

,:;-,_.;_ :,:j;, ;,.-.~;; 10200403 3 1.64E-05 10200401 15 5.05E-05 10200402 3 6.00E-05

2.93la.:_07 1.24E-06 ~,;•

5.86E-07 2.53E-07 3.53E·05 5.86E·07 2.53E-07 5.86E-07 2.53E·07

1.73E·02 6.35E·05 8.87E-06 1.73E·02 6.35E-05 8.87E-06 6.35E·05 8.87E•06 8.87E-06

1.00 0.00 -~1 0.00 0.00 0.01 0.00 0.00 0.00 0.00 Q.00

.f.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00

LQQ 1.24E·06 0.00 8.65E·OS 0.57

. ·':D:ll 3.05E·06 1.00 8.65E-05 3.15E-05

0.57 1.00

Significant Difference at

i~CQO!id~nce No No Yes Yes Yes Yes Yes

Yes Yes No No NQ

Yes Yes Yes No Yes Yes

Yes No No

Yl!O,_

Yes Yes No No Yes Yes Yes No No t,!Q Yes No No No No Yes Yes No No Nq Yes No Yes No No Yes

Group

Boiler. Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, f!,i~I Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil

Boiler, Fuel Oil Boile_h_fuel O_il Boiler, Fuel Oil ~gilfil,_fu~I_ Qil Boiler, Fuel O_il Boiler, Fuel Oil Boiler, Fuel Oil Boiler, fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel 011 Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler1.fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler. Fuel Oil Boiler, Fuel Otl Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fuel Oil Boiler, Fu_g_!_Q1I BoilfilL_fuel O_il B_~l!.fi!J _Qil Q9_filfil9, Powd~r Coating, Powder Fumac~, Aluryiinum Furnace, Ah.minum Furnace, Aluminum Fu_m~Aluminum Furnace. Aluminum Furnace, Aluminum Fumac_e~_Al!!miny_m

Category I Substance

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH

PAH PAH

PAH_

svoc svoc SVOQ voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe voe Ve& M_filals Metals M~tals Metals Metals MetAls Metals

Phenanthrene Phenanthrene Phenanthrene Phenanthrenfl Pyrene Pyrene Pyrene Pyrene Pyrene Pyrene Pyrene Pyrene Pyrene Pyrene 2-Chloronaphthalene 2-M_e1hvlnaphthal~.me PeryleQ~ Acetaldehyde Acetaldehyde Ace_t~ldehyde Acrolein Benzene Benzene Benzene Benzene Benzene Benz_g_ne Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyde Formaldehyg~ T_Q!!Jfi!_n_g_ Totii,1 Xylene Chromium Chr_omiumJH_g_x} Ar~nic_ Beryllium Beryllium Berylliu_m Cadmium

Metals / Cadmium M__g_tals C~mium

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (I-statistics).

EFUn< Value Type First Sam le Statistics Second Sam le Statistics

lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal ll)~Mgal lbs/Mgal lbs/M!ll!I 11)_§/'Mgal lbs/Mgal lbs/Mgal l_bs/Mgal lbs/M!ll!I lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mg_a_l lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal lbs/Mgal ll)~Mgal lbs/M_!ll!I l~lbs powder lbs/lbs powd~r

EF EF EF EF EF EF EF EF EF EF EF EF EF

fl' !E !E !E EF EF

!E !E EF EF EF EF EF EF EF EF EF EF EF EF EF EF EF EF

!E EF EF EF

lbs/ton production Is= lbs/ton production ~EFlbs/ton production EF I_Qs/ton production_ EE lbs/ton produ. ction I EF lbs/ton production EF lbs/ton produc_tj_on EF

Description Size Average Standard Detect Description Size Average Standard Detect _R_(l\!Q_ S:X:: _ Deviation Ratio SJ:; Deviation

10100501 I 2 I 1.38E-04 I 1.24E-06 I 0.00 1102004031 3 I 1.64E-05 I 3.0SE-06 8.65E·05 0.57 10200402 3 6.00E-05 3.15E-05 1020040111 5

10200401 15 1020040.l! 3

5.0SE-05 5.05E-05 6.00E0Q§_

1.00 1.00

10100401 12 10100401 12 10100401 1 2 10100401 12 10100501 2 10100501 2 10100501 2 1 0200401 1 5 10200401 1 5 10200402 ~

1929g~o,21 3 1! 1 0200~_Q.tl ~

101004.:11 3 10100401 3 10200401 3 10200401 I 3 10100401 9 10100401 9 10100401 9 10200401 1 8 10200401 1 8 10200402 2 10100401 9 10100401 9 10100401 9 10100401 9 10100501 3 10100501 3 10100501 3 10200401 12 1 0200401 12 1 02.Q.0402 3 1 0200401 I 3 102_2.0401 I 3 402001011 4 402J)J)JQ!J .:!. 3_Q_400103 I 3 30400103 6 30400103 6 30400107 _:!.

30400103 6 30400103 6 30400107 3

6-24

2.SOE-06 2.SOE-06 2.50E-06 2.50E-06 1.38E-04 1.3BE-04 1.38E-04 2.82E-05 2.82E-05 1_Jl_7E-06 2J14E-07

!1_.17E-07 5.33E·03 5.33E-03 4.86E-03 4._l,!§_E-03 3.49E-04 3.49E-04 3.49E-04 8.66E-03 8.66E-03 3.82E-03 4.90E-02 4.90E-02 4.90E-02 4.90E-02 2.65E-02 2.65E-02 2.65E-02 8.82E-02 8.82E-02 1.02E-03 8.85E-03 7.o.2E-03 1 ,30E-01 8.48E-03 7,52E-06 2.16E-05 2.16E-05 8.00E-05 9.36E-05 9.36E-05 4.37E-04

8.65E-05 3.1_5E-05 3.53E-06 3.53E-06 3.53E-06 3.53E-06 1.24E-06 1.24E-06 1.24E-06 3.53E-05 3.53E-05 1.9.0E-06 9.93E_-_Q_e_

1.52E-06 4.23E-03 4.23E-03 4.]!6E-04 4.86E..:Q4 2.54E-05 2.54E·05 2.54E-05 1.01E-02 1.01 E-02 6.70E-04 5.13E-02 5.13E-02 5.13E-02 5.13E-02 2.40E-02 2.40E-02 2.40E-02 1.52E-01 1.52E-01 7 ~5E-04 3.86E-03 4.61 E-03 1.77E-01 8.02E-03 5.54E-07 9.26E-06 9.26E-06 O.OOE+OO 1.13E-04 1.13E-04 3.71E·O~

0.57 1.00

10200403 3 1.64E-05 3.05E-06 I 1.00 10200403 3 1.64E-05 3.0SE-06 _LQQ

0.7B 0.78 0.78 0.78 0.00 0.00 0.00 0.01 0.01 Q.70

,,)~_ .. s .. o~.1;,,_} ... ,,l".'i~.•"'.'l.iJ-2. 4. e. -06 __ .. "''~i,,. ~4::J!l~;. - .,,,:_. ::-:.:- _ a• _ L .. ' : r~r. :k.~'UUJA 10200402 3 1.87E-06 1.90E·06 0.70 1:~~ __ .ii r'0c'fiinli:,;;:,,llla ''.'..,

10200401 15 2.82E-05 3.53E-05 0.01 102004021 3 10200403 3

1.87E-06 7.48E-06

1.90E·06 3.56E·06

0.70 1.00

102·0-·0402 3.lli.87E-06 1.90E-06 0.70 10200403 3 7.48E-06 3.56E-06 1.00 10209403 3 7.48E-06 3.56E·06 1.00

Q.00 10200403 3 2.27E-08 6.16E-09 0.00 1 Q.200403 3 1.09E-05 1.25E·06 J .00

0.00 10200.§~LL 1.09E-07 I 9.58E·08 I o.oo 0.82 0.82 0.00

10200401 3 4.86E-03 4.86E-04 0.00 10200403 3 1.79E-03 1.38E-03 0.87 1 Q_2_Q0403 3 1.79E-03 1.38E·03 0.87

0.00 10200403 3 2.17E-03 0.00 0.00 0.00 0.00 0.85 0.85

\·faBh ~~- l~-)%l £':ti:' 1 0200403 3 4.63E-03 1.51 E-04 0.00 10200402 2 3.82E-03 6.70E-04 0.56 10200403 3 4.63E-03 1.51E-04 0.00

o.56 I 10200AQ:U_3 1.00 10100501 3 1.00 10200401 1 2 1.00 10200402 3 1.00 10200403 3 1.00 10200401 1 2 1.00 10200402 3 1.00 1 0200403 3 0.99 10200402 3 0.99 10200403 3 0.48 10200403 3 1.00 I 10200~ 1.00 I 102004031 3 1.00 I 40_l!J)_g_499 I 2 1.00 I 40202499 I 2 o.oo I 30AQQm.l_§_

0.00 3040010713 0.00 30400199 9 0.Qll 30400199 9

0.95 304001071 3 0.95 30400199 9 1.00 304001_!1_9 9

4.filE-03 2.65E-02 8.82E-02 1.02E-03 1.09E-02 8.82E-02 1.02E-03 1.09E-02 1.02E-03 1.09E-02 1ME-02 5.75E-~ U9E·02 2.94E-04 :UJE-04 3.82E-04 8.00E-05 2.56E-05 2.56f_:Q_5_ 4.37E-04 8.26E-04 8.26E-04

1.51 E-04 2.40E·02 1.52E·01 7.55E·04 5.14E-03 1.52E·01 7.55E·04 5.14E-03 7.55E-04 5.14E·03 5.14E•03 1.BBE-04 3.61 E-04 1.53E-04 jj.44E·05 3.89E-04 O.OOE+OO 3.82E·05 3.62E-05 3.71E-04 1.74E•03 1.74E-03

O,QO 1.00 0.99 0.48 0.00 0.99 0.48 0.00 0.48 0.00 0.00 0.00 0.00 LOJ) 1.00 0.00 0.00 0.00 0.00 1.00 1.00 1.00


~%Confidence Yes No No No Yes Yes No Yes Yes Yes Yes No No No Yes Yes No No No

Yes Yes Yes Yes Yes No No No No No No No

No

No

No No No Yes No No No No No Yes No

Y_!!I!_

No No No

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (!-statistics).

Group Category Substance EF Unn Value Type First Samele Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at = Deviation Ratio = Deviation Ratio 95%Confidence

Furnace Aluminum Metals Chromium lbs/ton oroduction EF 30400!03 6 5.07E-05 5.60E-05 1.00 30400199 6 2.48E-04 2.99E-04 1.00 No Furnace Aluminum Metals Chromium (Hex) lbs/ton oroduction EF 30400!03 6 2.21 E-05 2.07E-05 1.00 30400199 6 5.91 E-04 5.90E-04 0.00 Yes Furnace, Aluminum Metals Copper lbs/ton production EF 30400103 6 2.80E-04 3.00E-04 1.00 '"~ ~! 'ti/.~ .,,_::,. ~lt:8,:1° Yes Furnace, Aluminum Metals Copper lbs/ton production EF 30400103 6 2.80E-04 3.00E-04 1.00 30400199 9 1.l0E-03 1.96E-03 1.00 No Furnace Aluminum Metals Coooer lbs/ton nroduction EF 30400107 3 1.15E-03 1.21 E-04 1.00 30400199 9 1.l0E-03 1.96E·03 1.00 No Furnace. Aluminum Metals Lead lbs/ton production EF 30400103 6 5.42E-04 6.57E-04 1.00 30400107 3 4.48E-04 6.97E-05 1.00 No Furnace, Aluminum Metals Lead lbs/ton production EF 30400103 6 5.42E-04 6.57E-04 1.00 30400199 9 3.26E-04 4.79E-04 1.00 No Furnace Aluminum Metals Lead lbs/ton nroduction EF 30400107 3 4.48E-04 6.97E-05 1.00 30400199 9 3.26E-04 4.79E·04 1.00 No Furnace, Aluminum Metals Manganese lbs/ton production EF 30400103 6 6.38E·03 1.52E-02 1.00 30400107 3 1.87E-04 4.03E-05 1.00 No Furnace. Aluminum Metals Manganese lbs/ton production EF 30400103 6 6.38E-03 1.52E-02 1.00 30400199 9 4.05E-04 8.49E-04 1.00 No Furnace, Aluminum Metals Manru:i.nese lbs/ton nroduction EF 30400107 3 1.87E-04 4.03E-05 1.00 30400199 9 4.05E-04 8.49E-04 1.00 No Furnace Aluminum Metals Mercurv tbs/ton nroduction EF 30400103 3 4.64E-06 2.63E-06 1.00 30400199 6 2.35E·05 2.41E-05 0.30 No Furnace, Aluminum Metals Nickel lbs/ton production EF 30400103 6 2.33E-04 2.75E-04 1.00 30400107 3 2.51 E-04 8.81 E-05 1.00 No Furnace, Aluminum Metals Nicket lbs/ton production EF 30400103 6 2.33E-04 2.75E-04 1.00 30400199 9 1.56E-04 2.31 E-04 1.00 No Furnace Aluminum Metals Nickel lbs/ton oroduction EF 30400107 3 2.51 E-04 8.81 E-05 1.00 30400199 9 1.56E-04 2.31E-04 1.00 No Furnace Aluminum Metals Selenium lbs/ton nroduction EF 30400103 3 8.16E-06 2.09E-06 0.73 30400199 6 1.53E-04 1.56E-04 0.00 No Furnace Aluminum Metals Zinc lbs/ton nroduction EF 30400103 3 5.14E·04 4.07E-04 1.00 30400199 6 4.73E-03 7.16E-03 1.00 No Furnace, Aluminum voe Benzene lbs/ton production EF 30400103

!!~ 5.84E·02 2.95E-02 1.00 30400107 3 1.17E-02 1.27E-02 0.75 No

Furnace, Aluminum voe Benzene lbs/ton production EF "3~811 '.1lt;l!li:oi:z ~'$ :· ... :!(;ii ... t 30400199 3 8.00E-06 0.00E+00 0.00 ,;'.;:· . ,, . Yes Furnace Aluminum voe Benzene lbs/ton oroduction EF 30400107 3 1.l?E-02 1.27E-02 0.75 30400199 3 8.00E-06 0.00E+00 0.00 No Furnace, Aluminum voe Formaldehyde lbs/ton production EF 30400103 3 - - 1.00 ~' tt~t Yes ' ., "'--· Furnace, Aluminum voe Formaldehyde lbs/ton production EF 1mi~ "''. ft!;, 30400199 3 2.56E•04 9.06E-05 1.00 Yes

tbs/ton oroduction 01; : Furnace Aluminum voe Formaldehvde EF 30400199 3 2.56E-04 9.06E-05 1.00 Yes Furnace, Aluminum voe Hydrogen Sulfide lbs/ton production EF 30400103 6 9.46E-02 7.82E-02 1.00 30400tfl'l , .. ,· ,...,._ ;c,.f~.- 1.00 Yes Furnace, Aluminum voe Hydrogen Sulfide lbs/ton production EF ~03 .,, := 1~;1;, H 1.CIO . 30400199 9 3.88E-04 2.17E-04 0.47 Yes Furnace Aluminum voe Hvdrooen Sulfide lbs/ton oroduction EF !IOIMl117 . ':r ,1··~:?:r. .. f.00 30400199 9 3.88E-04 2.17E-04 0.47 Yes Furnace Glass Metals Arsenic lbs/ton oroduction EF 30501402 6 2.0SE-04 2.13E-04 1.00 30501403 3 8.26E-05 1.56E-05 1.00 No Furnace Glass Metals Chromium lbs/ton oroduction EF 30501402 6 5.02E-05 3.99E-05 1.00 305014113 ;3 a--114. ,._, . 1.00 Yes Furnace Glass Metals Chromium (Hex) lbs/ton nroduction EF 30501402 6 3.30E-06 8.71E-07 0.00 30501403 6 1.53E-03 1.72E·03 0.99 No ICE, Diesel PAH Acenaphthene lbs/Mgal EF 20100102 3 2.85E-06 1.lSE-07 0.00 20200102 15 2.08E-03 5.18E-03 1.00 No ICE, Diesel PAH Acenaphthene lbs/Mgal EF 20100102 3 2.85E-06 1.15E-07 0.00 20300101 6 8.71E-04 1.33E-03 0.84 No ICE Diesel PAH Acenaohthene lbs/Moal EF 20200102 15 2.08E-03 5.18E-03 1.00 20300101 6 8.71E-04 1.33E-03 0.84 No ICE, Diesel PAH Acenaphthylene lbs/Mgal EF 20100102 3 2.85E-06 1.1 SE-07 0.00 20200102 1 5 2.87E-03 4.43E·03 1.00 No ICE, Diesel PAH Acenaphthylene lbs/Mgal EF 20100102 3 2.85E-06 1.15E-07 0.00 20300101 6 9.45E-04 7.35E-04 0.90 No ICE Diesel PAH Acenaohthvlene lbs/Maal EF 20200102 15 2.87E-03 4.43E-03 1.00 20300101 6 9.45E-04 7.35E-04 0.90 No ICE, Diesel PAH Anthracene lbs/Mgal EF 20100102 3 1.33E-03 2.13E-04 1.00 20200102 15 5.80E-04 8.0lE-04 1.00 No ICE, Diesel PAH Anthracene lbs/Mgal EF .; .. , _::l:& ,,;,,~, .C:ilf_,, r ,-.-, 20300101 6 2.67E-04 2.33E-05 0.47 Yes ICE Diesel PAH Anthracene lbs/Moal EF - - 20300101 6 2.67E-04 2.33E·05 0.47 No ICE, Diesel PAH Benzo(a)anthracene lbs/Mgal EF . 20200102 15 1.61 E-04 1.76E·04 1.00 Yes ICE, Diesel PAH Benzo(a)anthracene lbs/Mgal EF . 20300101 6 1.42E-04 1.52E-04 0.01 Yes ICE Diesel PAH Benzo(a)anthracene lbs/Mnal EF 20200102 15 1.61 E-04 1.76E-04 1.00 20300101 6 1.42E-04 1.52E·04 0.01 No ICE, Diesel PAH Benzo(a)pyrene lbs/Mgal EF 20100102 3 2.85E-06 1.15E-07 0.00 20200102 1 5 1.81 E-05 2.28E·05 0.19 No ICE, Diesel PAH Benzo(a}pyrene lbs/Mgal EF 20100102 3 2.85E-06 1.lSE-07 0.00 20300101 6 1.40E-04 1.53E-04 0.00 No ICE Diesel PAH Benzo(a\nvrene lbs/Moal EF 20200102 15 1.81 E-05 2.28E-05 0.19 20300101 6 1.40E-04 1.53E·04 0.00 Yes ICE Diesel PAH Benzo(bHluoranthene lbs/Moal EF 20200102 12 8.31 E-05 7.26E-05 0.63 20300101 6 1.44E-04 1.49E-04 0.03 No ICE Diesel PAH Benzo<b+k\fluoranthene lbs/Moal EF 20100102 3 2.85E-06 1.15E-07 0.00 20200102 3 1.44E-06 2.72E-08 0.00 Yes ICE, Diesel PAH Benzo(g,h,i}perylene lbs/Mgal EF ·•Mii!t i.'/J;l; ~<,.. .;;,;111,c 20200102 15 4.52E-05 4.40E-05 0.65 Yes ICE, Diesel PAH Benzo(g,h,i}perylene lbs/Mgal EF 20100102 3 3.39E-04 6.94E-05 1.00 20300101 6 1.42E-04 1.51 E-04 0.02 No

6-25

TABLE A6-3a. SOURCE CLASSIFICATION CODE TYPE COMPARISON (t-statistics).

Group I Category! Substance EF Unit Value Type First Sample Statistics Description Size Average Standard

S:X:: D ICE. Diesel PAH Benzo(a.h i'nervlene lbs/Mnal s= 1

ICE Diesel PAH Benzolk\fluoranthene lbs/Maal e= ICE,Diesel P/11, Chrysene lbs/Mgal EF r;:!!li~;,l. 1111.·· ,,,\•j{~mar~t.f.lllltt .. • 20200102 15 7.43E-05 7.53E-05 1.00 Yes ICE, Diesel P/11, Chrysene lbs/Mgal EF ''XL , ·'' \/!,~~-.t· 20300101 6 1 .53E-04 1.39E-04 0.09 Yes ICE Diesel P/11, Chrvsene lbs/Mnal EF 7.43E-05 7.53E-05 1.00 20300101 6 1.53E-04 1.39E-04 0.09 No ICE, Diesel PAH dibenz(a,h)anthracene lbs/Mga1 Er ., '"' 20200102 15 4.27E-05 4.44E-05 0.28 Yes ICE, Diesel P/11, dibenz(a,h)anthracene lbs/Mgal EF 20100102 3 2.85E-04 5.89E-05 1.00 20300101 6 1.40E-04 1.53E-04 0.00 No ICE. Diesel P/11, dibenzla h\anthracene lbs/Maal EF 20200102 1 5 4.27E-05 4.44E-05 0.28 20300101 6 1 .40E-04 1 .53E-04 0.00 Yes

ICE, Diesel P/11, Fluoranthene lbs/Mgal EF 2. ?··.,··o·,o· 1 ... 02J._i., "p.oE-.. 0] ... A.)·7~E,o4 ....• ! .. oo .•• 20200102 15 9.45E-04 8.20E-04 1.00 No ICE, Diesel P/11, Fluoranthene lbs/Mgal EF ·@:1!i10l½l•i~ :Mt~~'. lI• zc'llt" 20300101 6 2.84E-04 2.40E-05 0.51 Yes ICE Diesel P/11, Fluoranthene lbs/Maal EF 20200102 15 9.45E-04 8.20E-04 1.00 20300101 6 2.84E-04 2.40E-05 0.51 No

ICE,Diesel P/11, Fluorene lbs/Mgal EF --: 20200102 15 3.82E-03 3.61E-03 1.00 Yes ICE, Diesel P/11, Fluorene lbs/Mgal EF . ;. 20300101 6 6.49E-04 4.23E-04 0. 78 Yes ICE Diesel P/11, Fluorene lbs/Maal EF ; 20300101 6 6.49E-04 4.23E-04 0.78 Yes ICE, Diesel P/11, lndeno(1.2,3-cd)pyrene lbs/Mgal EF . · 20200102 1 5 3.94E-05 4.34E-05 0.34 Yes

ICE.Diesel P/11, lndeno(1.2.3-cd)pyrene lbs/Mgal EF 20100102 3 2.25E-04 2.43E-05 1.00 }?J~2!.\1), -t .1}!)E·0,~., •;~· ,2·~~-• No ICE Diesel P,6,H lndeno(1 2 3-cd\nvrene lbs/Mnal e= 20200102 1 5 3.94E-05 4.34E-05 0.34 :t'. ~ • ' ':;,,·t·':..,,;.;:-.,:o<:;.,.: ~-::;- (l ;::]~.;tr;~ Yes ICE. Diesel P/11, Naphthalene lbs/Mgal EF 20100102 3 1.91 E-02 3.19E-03 1.00 20200102 15 3.92E-02 5.28E-02 1.00 No ICE. Diesel P/11, Naphthalene lbs/Mgal EF 20100102 3 1.91E-02 3.19E-03 1.00 20300101 6 1.56E-02 1.41E-02 1.00 No ICE Diesel P/11, Nanhthalene lbs/Maal EF 20200102 15 3.92E-02 5.28E-02 1.00 20300101 6 1.56E-02 1.41 E-02 1.00 No ICE,Diesel P/11, Phenanthrene lbs/Mgal EF 201,0 ... ~1.o,2.J 3. L45E-.02 L.1.3E-03 1. 90 .•. 20200102 15 7.27E-03 7.13E-03 1.00 No ICE. Diesel P/11, Phenanthrene lbs/Mgal EF 201li10if'<J,'\fi; :f.':'l~i;: • ,,f1.1''.~':: ,.,t.QO ,: 20300101 6 3. 11 E-03 3.07E·03 1 .00 Yes ICE Diesel P/11, Phenanthrene lbs/Maal EF 20200102 15 7.27E-03 7.13E-03 1.00 20300101 6 3.11 E-03 3.07E-03 1.00 No

ICE. Diesel P/11, Pyrene lbs/Mgal EF ~~!!!OZ,. _ t;ij :: 'l~. • rt W~:f; /:f""' • 20200102 15 6.57E-04 4 .83E-04 1 .00 Yes ICE. Diesel P/11, Pyrene lbs/Mg al EF 2Cr111Q02. S•, ·· •7- •,,f.ff!~,,.: t.ili,• 20300101 6 2.37E-04 5.42E-05 0.41 Yes ICE Diesel P/11, Pvrene lbs/Mnal EF 20200102 15 6.57E-04 4.83E-04 1.00 20300101 6 2.37E-04 5.42E-05 0.41 Na

ICE.Diesel voe Benzene lbs/Mgal EF 20100102 3 3.25E-02 4.18E-03 1.00 ,:~ .•. •.· ... )·•·j(.~.•'.t .• 0• .... J, .. '.~.·•.··.·.·· .. ·.i.•·L~Ld• @I!. Yes ICE.Diesel Voe Benzene lbs/Mgal EF 20100102 3 3.25E-02 4.18E-03 1.00 •-~~Sf¥f3 ... ~ :.~ii ,1,0 ·: Yes ICE Diesel VOC Benzene lbs/Maal a= 20200102 9 1.15E-01 4.BOE-02 1.00 ~ •"~"~ r--~ ::;;~•-· ,.,. . ..,._,.;.·,,, ~2€ )ii:M,-h Yes .ICE. Diesel Voe Formaldehyde lbs/Mgal EF 20100102 3 6.82E-02 4.59E-02 1 .00 20200102 15 7.47E-02 9.47E·02 1 .00 No ICE. Diesel VOC Formaldehyde lbs/Mgal EF 20100102 3 6.82E-02 4.59E-02 1 .00 20300101 6 8.79E-02 6.83E-02 1 .00 No ICE Diesel voe Formaldehvde lbs/Maal EF 20200102 15 7.47E-02 9.47E-02 1.00 20300101 6 8.79E-02 6.83E-02 1.00 No ICE Diesel Voe Pronvlene lbs/Maal EF 20200102 9 3.67E-01 1.62E-01 1.00 20300101 3 2.97E-01 4.54E-02 1 .00 No ICE Diesel VOC Toluene lbs/Maal EF 20200102 9 4.92E-02 1.BBE-02 1.00 ··u I·- -, :;Y ·:,•,-·,: Yes

ICE Diesel voe TotalX,lene lbs/Mnal EF --- ·•••: .• 3.••~• f-..,5 .·, 20300101 3 1.51E-02 693E-03 1.00 Yes

ICE.FieldGas voe Benzene lbs/MMcf EF 20200202 6 1.72E+00 6.13E-01 1.00 .~ fi.(~.' .. :)~-;.! Yes ICE. Field Gas voe Benzene lbs/MMcf EF 20200202 6 1.72E+00 6.13E-01 1.00 ti,-~ ,.,:,,.ft,:;/;~ , Yes ICE Field Gas voe Benzene lbs/MMcf EF 20200252 5 7.85E+00 4.77E+00 1.00 20200254 2 1.10E+01 1.26E-01 1.00 No ICE, Field Gas Voe Formaldehyde lbs/MMcl EF 20200202 9 4.15E+01 3.18E+01 1.00 20200252 6 5.09E+01 3.55E+01 1.00 No ICE. Field Gas voe Formaldehyde lbs/MMcl EF 20200202 9 4.15E+01 3.1BE+01 1 .00 20200254 3 5.05E+00 8.04E-01 1 .00 No ICE Field Gas voe Formaldehvde lbs/MMcf EF 20200252 6 5.09E+01 3.55E+01 1.00 20200254 3 5.05E+00 8.04E•01 1.00 No ICE. Field Gas voe m,p-xylene lbs/MMcf EF 20200202 6 3.02E-01 3.01 E-01 1.00 20200252 5 6.04E-01 4.88E-01 1.00 No ICE. Field Gas voe m.p-xylene lbs/MMcf EF 20200202 6 3.02E-01 3.01 E-01 1.00 20200254 2 5.37E-01 3.62E·02 1.00 No ICE Field Gas voe m n-x,lene lbs/MMcf EF 20200252 5 6.04E-01 4.88E-01 1.00 20200254 2 5.37E-01 3.62E·02 1.00 No ICE. Field Gas voe o-xylene lbs/MMcf EF 20200202 6 8.97E-02 2.30E-02 1 .00 20200252 5 2.88E-01 2.54E-01 1.00 No ICE.Field Gas voe a-xylene lbs/MMcf EF 20200202 6 8.97E-02 2.30E-02 1.00 ', .,., ·••·•: •· •. , , .. :;;/- . Yes

ICE FieldGas voe 0-X\lene lbs/MMcf EF 20200252 5 2.88E-01 2.54E-01 1.00 20200254 2 2.68E-01 1.81E-02 1.00 No ICE. Field Gas voe Propylene lbs/MMcf EF 20200202 6 1.59E+01 4.86E+00 1.00 20200252 5 2.49E+01 1.41 E+01 1.00 No

6-26


Group Category Substance EFUnit Value Type First Sam., le Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

= Deviation Ratio = Deviation Ratio 95%Confidence

ICE, Field Gas voe Propylene lbs/MMcf s= ~' 1, ,_,A;;' I~1· ,~t ;~1.1111· 20200254 2 3.04E+00 0.00E+00 0.00 Yes ICE Field Gas voe Procvlene lbs/MMe! s= 20200252 5 2.49E+01 1.41 E+01 1.00 ,. -,~~-Joo" No ICE, F"ld Gas voe Toluene lbs/MMe! s= 20200202 6 7.68E-01 3.92E-01 1.00 ,.Z-ii Yes ICE, Foeld Gas voe Toluene lbs/MMcf s= 20200202 6 7.68E-01 3.92E-01 1.00 :it ~1 Yes ICE Field Gas voe Toluene lbs/MMe! s= 20200252 5 2.86E+00 2.08E+00 1.00 20200254 2 3.44E+00 1.57E 01 1 .00 No 1CE, Natural Gas PAH Acenanhthene lbs/MMe! s= 20200202 12 7.91E-04 8.62E-04 1.00 20200254 3 1.94E-03 1.26E-03 1.00 No

ICE Natural Gas PAH Acenanhthvlene lbs/MMe! s= 20200202 12 7.40E-03 8.82E-03 1.00 20200254 3 1.45E-02 1.74E-03 1.00 No

ICE Natural Gas PAH Anthracene lbs/MMef s= 20200202 12 2.91 E-04 3.17E-04 1.00 ,,e

''2' Yes

ICE. Natural Gas PAH Benzotalanthracene lbs/MMe! s= 20200202 12 5.50E-04 9.08E-04 1.00 20200254 3 2.94E-04 4.08E-05 1.00 No ICE Natural Gas PAH Benzo(a\n.,rene lbs/MMe! s= 20200202 12 8.36E-05 1.38E-04 0.96 20200254 3 1.15E-04 3.18E-05 1.00 No

ICE Natural Gas PAH Benzotb\fluoranthene lbs/MMe! s= 20200202 12 6.76E-04 1.11E-03 0.99 20200254 3 2.37E-04 5.53E-05 1.00 No

ICE Natural Gas PAH Benzo(a.h iloervlene lbs/MMe! s= 20200202 12 5.17E-04 8.71E-04 1.00 20200254 3 1.95E-04 4.46E-05 1.00 No ICE Natural Gas PAH Benzolk)fluoranthene lbs/MMe! s= 20200202 12 2.42E-04 3.36E-04 0.99 20200254 3 1.03E-04 2.07E-05 1.00 No ICE. Natural Gas PAH ChNsene lbs/MMe! s= 20200202 12 3.35E-04 6.99E·04 1.00 20200254 3 3.10E-04 7.71E-05 1.00 No ICE Natural Gas PAH dibenzla h\anthracene lbs/MMe! s= 20200202 12 2.87E-05 4.50E-05 0.95 20200254 3 1.25E-05 1.72E-06 1.00 No ICE Natural Gas PAH Fluoranthene lbs/MMef s= 20200202 12 1.41E-03 2.06E-03 1.00 20200254 3 9.95E-04 1.94E·04 1.00 No ICE Natural Gas PAH Fluorene lbs/MMe! s= 20200202 12 2.68E-03 4.07E-03 0.96 20200254 3 6.91 E-03 1.99E-03 1.00 No ICE. Natural Gas PAH lndenol1 2 3-cd'nvrene lbs/MMe! s= 20200202 12 4.42E-04 7.23E-04 1.00 20200254 3 1.69E-04 3.43E-05 1.00 No ICE. Natural Gas PAH Nanhthalene lbs/MMef s= 20200202 12 1.23E-01 1.31E-01 1.00 20200254 3 7.65E-02 1.58E-02 1.00 No

ICE Natural Gas PAH Phenanthrene lbs/MMe! s= 20200202 12 7.19E-03 1.11 E-02 1.00 20200254 3 7.07E-03 1.92E-03 1.00 No

ICE Natural Gas PAH Pvrene lbs/MMe! s= 20200202 12 1.73E-03 2.84E-03 1.00 20200254 3 1.79E-03 7.53E-04 1.00 No ICE Natural Gas svoc Ethvlbenzene lbs/MMcf s= , .•• , i' ' 20200254 3 1.16E-02 3.13E-03 1.00 Yes tCE. Natural Gas voe ~ 3-Butadiene lbs/MMef s= 20200202 9 7.70E-01 6.07E-01 1.00 20200254 3 1.04E-01 3.92E-04 1.00 No

ICE. Natural Gas voe Acetaldehvde lbs/MMef s= 20200202 24 2.67E+00 2.72E+00 0.99 20200254 6 8.83E-01 9.05E-01 1.00 No

ICE Natural Gas voe Acrolein lbs/MMe! s= 20200202 23 1.02E+00 1.40E+00 0.99 20200254 6 7.94E-01 3.38E-01 1.00 No ICE Natural Gas voe Benzene lbs/MMcf s= 20200202 23 1.05E+00 7.21 E-01 1.00 20200254 11 1.91 E+00 3.94E+00 1.00 No

ICE, Natural Gas voe Formaldehyde lbs/MMcf s= 20200202 42 1.53E+01 1.60E+01 1.00 20200252 9 5.15E+00 7.50E+00 0.91 No

ICE, Natural Gas voe Formaldehyde lbs/MMcf s= 202QOioi ~i· ,,.E+01 ·.·•1.--1,. /,1. 20200254 12 2.80E+00 4.47E+00 1.00 Yes

ICE Natural Gas voe Formaldehvde lbs/MMe! s= 20200252 9 5.15E+00 7.50E+00 0.91 - 12 &: 4.47E+00 1.00 No

ICE Natural Gas voe m.o-xvlene lbs/MMcf s= 20200202 14 8.63E-02 3.99E-02 1.00 ·-11, -~. ··•••·· Yes

ICE Natural Gas voe o-xvlene lbs/MMef s= 20200202 14 4.94E-02 1.95E-02 0.95 ·~k'2J;' ti . . ,v, ·~-, > Yes ..

ICE Natural Gas voe Pronvlene lbs/MMe! s= 20200202 23 1.40E+01 1.69E+01 0.97 20200254 5 1.60E+01 2.15E+01 1.00 No

ICE Natural Gas voe Toluene lbs/MMe! s= 20200202 23 4.36E-01 2.67E-01 1.00 .•. /'" ,,,, ' Yes

ICE Natural Gas voe Total Xvlene lbs/MMcf s= ... _. i ."/i '>"'.:AA'·,' 20200254 3 6.02E-02 1.86E-02 1.00 Yes

Turbine Distillate PAH Acenaohthene lbs/Mnal s= 20100101 9 9.69E-05 1.16E-04 0.12 20200103 6 1.82E-05 2.03E-05 0.76 No

Turbine Distillate PAH Acenanhthvlene lbs/Moal s= 20100101 9 8.61 E-05 1.22E-04 0.06 20200103 6 6.32E-06 7.79E-06 0.59 No

Turbine Distillate PAH Anthracene lbs/Mnal s= 20100101 9 9.80E-05 1.17E-04 0.17 20200103 6 1.56E-05 1.83E-05 0.32 No

Turbine Distillate PAH Benzo(a)anthracene lbs/Mnal s= 20100101 9 8.53E-05 1.23E-04 0.01 20200103 6 4.22E-06 2.93E-06 0.00 No

Turbine Distillate PAH Benzola'""rene lbs/Moal s= 20100101 9 8.33E-05 1.24E-04 0.01 20200103 6 8.61E-06 1.01 E-05 0.56 No Turbine Distillate PAH Benzolb\fluoranthene lbs/Mnal s= 20100101 6 1 .32E-04 1.29E-04 0.08 20200103 3 2.15E-05 1.45E·05 0.86 No Turbine Distillate PAH Benzo(b+k\fluoranthene lbs/Mnal s= 20100101 3 2.52E-06 6.60E-08 0.00 20200103 3 3.23E-06 3.82E-07 0.00 Yes

Turbine Distillate PAH Benzota.h i)oervlene lbs/Mnal s= 20100101 9 8.26E-05 1.25E-04 0.01 20200103 6 2.18E-06 1.25E-06 0.00 No

Turbine. Distillate PAH BenzafkHluoranthene lbs/Moal s= 20100101 6 1.30E-04 1.31E•04 0.07 20200103 3 6.92E-06 4.04E-06 0.00 No Turbine Distillate PAH Chrusene lbs/Mnal s= 20100101 9 1.03E•04 1.15E-04 0.21 20200103 6 4.82E-06 2.70E-06 0.00 No Turbine Distillate PAH dibenz(a h'anthracene lbs/Mnal s= - 20200103 6 2.30E-06 1.19E-06 0.00 No Turbine Distillate PAH Fluoranthene lbs/Moal s= 20200103 6 1.34E·05 1.16E-05 0.88 y.,.

Turbine. Oislillate PAH Fluorene lbs/Mnal s= 20200103 6 1.76E-05 1.22E-05 0.21 Yes

Turbine Dislillate PAH lndeno(1 2 3-cd1. .... rene lbs/Mnal s= 20100101 9 8.26E 05 1.24E 04 0.01 20200103 6 2.29E-06 1.22E·06 0.00 No

6-27


Group Category Substance EF Unit Value Type First Samole Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

sec Deviation Ratio sec Deviation Ratio 95%Confidence Turbine Distillate PAH Nanhthalene lbs/Mnal s= ,·,:'{ ,.st<:1~ ;_:t:·f""- ,,,, __ 20200103 6 3.87E-04 1.0BE-04 1.00 Yes Turbine Distillate PAH Phenanthrene lbs/Maal s= 20100101 9 4.12E-04 6.40E-04 1.00 20200103 6 6.91 E-05 5.97E-05 1.00 No Turbine Distillate PAH Pvrene lbs/Maal s= 20100101 9 1.01E-04 1.1 SE-04 0.20 20200103 6 1.44E-05 1.40E-05 0.89 No Turbine Distillate voe Formaldehvde lbs/Maal s= 20100101 6 3.19E-02 2.66E-02 1.00 20200103 6 7.0SE-02 6.83E-02 1.00 No Turbine, Nautral Gas voe Formaldehvde lbs/MMe! s= :-~,'-'.'; :•a:, ,· 20200203 19 1.10E-01 1.06E-01 0.97 Yes

6-28

TABLE A6-4a. AIR POLLIJTION CONTROL SYSTEM COMPARISON (t-stalistics).

Group Category Substance EF Unit Value Type First Sam le Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference et APC ~stem Deviat_i_r;m Rctti9__ APC System De~iation Ratio 9_Ei%_ConfidencJ:

Asphalt Prod., Diesel Metals Arsenic lbs/ton production a= C/FF 3 2.73E-07 3.93E-09 0.00 C/WS 2 5.26E-06 7.65E-07 0.00 Yes Asphalt Prod., Diesel Metals Arsenic lbs/ton production S: C/FF 3 2.73E-07 3.93E-09 0.00 FF 3 6.GOE-08 4. 74E-OB 1.00 Yes Asphalt Prod., Diesel Metals Arsenic lbs/ton production a= C/FF 3 2.73E-07 3.93E-09 0.00 WS 1 8.02E-06 0.00 Yes Asphalt Prod., Diesel Metals Arsenic lbs/ton production a= C!WS 2 5.26E-06 7.SSE-07 0.00 FF 3 6.60E-08 4.74E-08 1.00 Yes Asphalt Prod., Diesel Metals Arsenic lbs/ton production e= crws 2 5.26E-06 7.65E-07 0.00 ws 1 8.02E-06 0.00 No A~phatt Prod., Diesel Metals Arsenic lbs/ton oroduction EF FF 3 6.60E-08 4.74E-08 1.00 WS 1 8.02E-06 0.00 -~

Asphalt Prod., Diesel l~etals Berylli.um lbs/ton production e= C/FF 3 5.45E-07 7.85E-09 0.00 C/WS 2 5.17E-07 5.77E·OB 0.00 No Asphalt Prod., Diesel Metals Beryllium lbs/ton production e= C/FF 3 5.45E-07 7.85E-09 0.00 FF 3 1.50E-07 1.42E-08 0.00 Yes Asphalt Prod., Diesel Metals Beryllium lbs/ton production a= C/FF 3 5.45E-07 7.85E-09 0.00 WS 1 4.01E-06 0.00 Yes Asphalt Prod., Diesel Metals Beryllium lbs/ton production e= crws 2 5.17E-07 5.77E-08 0.00 FF 3 1.50E-07 1.42E-OB o.oo Yes Asphalt Prod., Diesel Metals Berylhum lbs/ton production a= crws 2 5,17E-07 5.77E-08 0.00 WS 1 4.01E-06 a.ob Yes Afil)halt l:rod., Diesel Metals BeNlhum lbs/ton oroduction EF FF 3 1.50E-07 1.42E-08 0.00 WS 1 4.01E·06 _9..:.2Q Yes Asphalt Prod., Diesel Metals Cadmium lbs/ton production e= _. __ C/FF . 1 . _•.· _\6?f:·06. 1.00 C/WS 2 7.86E·07 0.68 No Asphalt Prod., Diesel Metals Cadmium lbs/ton production e= .. 'Clf-'F --~-:1:f.t:, cs\,. ~1-:, ., J)) .. •hQ,i•+;•~ 3 3.92E-08 O. 78 Yes Asphalt Prod .. Diesel Metals Cadmium lbs/ton production e= CIFF 1 NA Asphalt Prod .. Diesel Metals Cadmium lbs/ton production e= , :-: :.QWS ~_,;'~i; Yes Asphalt Prod., Diesel Metals Cadmium lbs/ton production e= C/WS 2 till Yes

\ As halt Prod. Diesel Metals Cadmium lbs/ton roduction EF FF 3 1.38E-07 Yes Asphalt Prod., Diesel Metals Chromium lbs/ton production EF C/FF 3 1.96E-06 No

Asphalt Prod., Diesel Metals Chromium lbs/ton production e= CIFF 3 1.96E-06 -fS,jij~t£f(;,~;;.":; No Asphalt Prod., Diesel Metals Chromium lbs/ton production e= ... GIFF _ 3 __ 1.96E:~~-. Yes Asphalt Prod., Dieset Metals Chromium lbs/ton production a= ._·.e,ws- ', ·I ,;:,.~1~.': Yes Asphalt Prod., Diesel Metals Chromium lbs/ton production EF C/WS 2 3.15E-06 ,[t;'.V~~;'.>';I Yes As halt Prod. Diesel Metals Chromium lbs/ton roduction Er FF 3 5.23E-07 3.40E-07 Y~ Asphalt Prod., Diesel _m•tals Chromium (Hex) lbs/ton production EF C/FF 1. :00 C/WS 2 1.68E-06 6.04E·08 I 0.00 I Yes Asphalt Prod., Diesel Metals Chromium (Hex) lbs/ton production e= CIFF UIO FF 3 8.56E-08 3.14E·08 1.00 Yes Asphalt Prod., Diesel Metals Chromium Hex lbs/ton roduction a= CNvS 0.00 FF 3 B.56E-OB 3.14E-08 1.00 Yes Asphalt Prod., Diesel Metals Copper tbs/ton production a= cn:F Z i~ tu&Ot·'-' f·- 5.45E-07 9.71E-08 0.56 Yes Asphalt Prod., Diesel Me!als Copper lbs/ton production EF C/FF 2 1.50E-06 2.22E-07 1 .00 3.15E-07 No Asphalt Prod .. Diesel Metals Copper lbs/ton production EF GIFF 2 1.50E-06 2.22E-07 1 .00 Yes Asphalt Prod., Diesel Metals Copper lbs/ton production EF C/WS 2 5.45E-07 9.71E-08 0.56 No Asphalt Prod .. Diesel Metals Copper ibs/ton production e= C/WS 2 5.45E-07 9.71E-08 0.56 Yes Asphalt Prod., Diesel Metals Co r lbs/ton roduction e= FF 3 1.12E-06 3.1 SE-07 1 .00 Yes

AsphaltProd.,Di.esel Metals Lead lbs/ton prod.uctionEF GIFF I! l.2.01E-06 8.SSE-07 1.00 ~~S 2 312E-06t111E-06 t 063 No Asphalt Prod., Diesel Metals Lead lbs/ton production EF GIFF 3 2.01E-06 8.SBE-07 1.00 FF 3 2 27E-06 1 54E-06 1 00 No Asphalt Prod., Diesel Metals Lead lbs/ton production e= CIFF 3 2.01E-06 8.58E-07 1.00 ·- WS.- ~ ,'5- 1 %.~] ~'1"j"f ' 1,00 Yes Asphalt Prod .. Diesel Metals Lead lbs/ton production e= G/WS 2 3.12E·06 1.11E-06 0.63 FF 3 2 27E-06 1 54E-06 1 00 No AsphaltProd.,D1esel Metals Lead lbs/ton production Er C/WS 2 3.12E-06 1.11E-06 0.63 vWS: ·l ,:1 - Z~; "v;,.._.,,, .,_ 14, Yes A§phalt Prod., Diesel Metal~ LeaQ_ lbs/to'l.....Q!Qduction e= FF _ 3 2.27E-06 1.5_4E-06 1 .00 "y ~ t.._ ~ "I cL:.,..,_,_-'"\ ~" f-!:'Z~ """" 1..1t.'c. Yes Asphalt Prod., Diesel Metals Manganese lbs/ton production e= GIFF 3 1.24E-05 C/WS 2 1.86E-05 No Asphalt Prod., Diesel Metals Manganese lbs/ton productions= ,·:::\~•;" :!f3:1~ '.f-.~~i •~ljjjii!f~ 3 9.11E-07 Yes Asphalt Prod .. Diesel Metals Manganese lbs/ton production e= GIFF 3 1.24E-05 4.38E-06 1 .00 l;i;;iillll·~: <ffe''l'<\~ai: Yes Asphalt Prod., Diesel Metals Manganese lbs/ton production e= G/WS 2 1.86E-05 1.34E-05 1 .00 No Asphalt Prod .. Diesel Metals Manganese lbs/ton production a= G/WS 2 1.86E-05 1.34E-05 1 .00 Yes

)As halt Prod. Diesel Metals Ma anese lbs/ton roduction EF FF 3 9.11E-07 1.82E-07 1.00 ~ill!lB]!i1:j Yes Asphalt Prod., Diesel Metals Mercury lbs/ton production e= C/FF 3 4.BBE-08 2.84E-08 0.52 No I Asphalt Prod., Diesel Metals Mercury lbs/ton production a= C/FF 3 4.88E-08 2.84E-08 0.52 FF Yes Asphalt Prod., Diesel Metals Mercury lbs/ton production e= GIFF 3 4.88E-08 2.84E-08 0.52 ,t)~~:: l;i:}~lfi!![~llfli:i Yes Asphalt Prod .. Diesel Metals Mercury lbs/ton production Ef" C/WS 2 4.00E-06 3.33E-06 1.00 FF 3 7.06E-07 7.92E-08 0.00 No Asphalt Prod., Diesel Metals Mercury lbs/ton production a= C/WS 2 4.00E-06 3.33E-06 1.00 WS 1 8.02E-07 1.00 No A!Q_halt Prod'..L_Piesel Metal~ MercQrv _ lbs/ton roduction s= FF 3 7.06E-07 7.92E-08 0.00 WS 1 8.02E-Q_7 1.0Q__ No Asphalt Prod., Diesel I Metals I Nickel [lbs/ton productlon[EF I GIFF I 3 I 2.73E-06 I 3.93E-08 I 0.00 I C/WS I 2 I S.26E-06 I 7.SSE-07 I 0.00 I Yes

6-29

TABLE A6-4a. AIR POLLUTION CONTROL SYSTEM COMPARISON (t·Slatistics).

Group Category Substance EFUnit Value Type First Sam le Statistics Second Sam le Statistics Description Size Average Standard Detect Description Size Average Standard APC $~m ---'----- Deviation !3.atio APC em Deviation

Asphalt Prod .. Diesel Metals Nickel lbs/ton production EF C/FF 3 2.73E-06 3.93E-08 0.00 Ff" 3 5.35E-07 2.00E-07 1.00 Yes Asphalt Prod., Diesel Metals Nickel lbs/ton production EF C/FF 3 2.73E-06 3.93E-08 0.00 WS 1 3.61E-04 0.00 Yes Asphalt Prod., Diesel Metals Nickel lbs/ton production e= CNi/S 2 5.26E-06 7.65E-07 0.00 FF 3 5.35E-07 2.00E-07 1.00 Yes Asphalt Prod., Diesel Metals Nickel lbs/ton production EF CNi/S 2 5.26E-06 7.65E-07 0.00 WS 1 3.81E-04 0.00 Yes A~t Prod., Diesel Metals Nickel lbs/ton nroduction EF Ff" 3 5.35E-07 2.00E-07 1.00 WS 1 3.81E-04 0.00 Yes

Asphalt Prod., Diesel Metals Selenium lbs/ton production EF C/FF 3 2.73E-07 3.93E-09 0.00 ·,, __ .. _G_/WS .:<•. _ 2 ... : __ 5;2~E~~6. _J.65E-,07 _ 0.00" Yes Asphalt Prod., Diesel Metals Selenium lbs/ton production EF C/FF 3 2.73E-07 3.93E-09 0.00 zfi~~y.Jt~ 'is"'t:Ji> ~\:)tl-~(i~:i~~ S$:liJ;:J Yes Asphalt Prod., Diesel Metals Selenium lbs/ton production EF e/FF 3 2.73E-07 3.93E-09 0.00 WS 1 8.02E-06 0.00 Yes Asphalt Prod., Diesel Metals Selenium lbs/ton production s= ems 2 5.26E-06 7.65E-07 0.00 FF 3 1. 16E-06 5.0BE-07 0.50 Yes Asphalt Prod .. Diesel Metals Selenium lbs/ton production EF ems 2 5.26E-06 7 .65E-07 0.00 WS 1 8.02E-06 0.00 No A~lt Prod.,_Diesel M~tals Selenium lbs/ton nroduction EF FF 3 1.16E-06 5.0SE-07 0.50 WS 1 8.02E-06 0.00 Y85 Asphalt Prod., Diesel Metals Zinc lbs/ton production EF e/FF 3 1.82E-05 5.62E-06 1.00 S:%::C1~, _ -- - · , .. ,.8

.; :;"·\··: _- :J Yes

Asphalt Prod., Diesel Metals Zinc lbs/ton production s= C/FF 3 1.82E-05 5.62E-06 1 .00 , . . ~ ., 0. No Asphalt Prod., Diesel Metals Zinc lbs/ton production EF ... ~/FF_ _ .1:e.2E_~OS. _.s .. _~2E:06. : .. 1_.0_~. (~1.;t 1

: - ~&;,;,iillli!: Yeo Asphalt Prod., Diesel Metals Zinc lbs/ton production EF _:,;.:~; ;:.~t.~.h ,_;,~--~i;; ~1A04' Yes Asphalt Prod., Diesel Metals Zinc lbs/ton production EF ems 2 6.62E-05 1.34E-05 1.00 Yes

I As halt Prod. D~esel Metals Zinc lbs/ton roduction s= ~ 3 6.71 E-06 6.28E-06 1 .00 Yes I Asphalt Prod., Diesel PAI-I Acenaphthene lbs/ton production EF e/FF 3 4.SOE-07 4.21E-07 1.00 No Asphalt Prod., Diesel PAI-I Acenaphthene lbs/ton production EF e/FF 3 4.BOE-07 4.21E-07 1.00 2.11E-08 1 No Asphalt Prod., Diesel PAI-I Acena_p_hthene lbs/ton reduction EF ems 2 1.22E-06 2.17E-07 0.00 2.11 E-08 1 .00 Yes Asphalt Prod., Diesel IPAH IAcenaphthylene lbs/ton production EF GIFF 3 3.36E-07 2.72E-07 1.00 ems 2 1.22E-06 2.17E-07 0.00 Yes Asphalt Prod., Diesel PAI-I Acenaphthylene lbs/ton production EF C/FF 3 3.36E-07 2.72E-07 1.00 FF 3 2.04E-08 1.89E-08 1.00 No A~t Prod., Diese!_ PAI-I _ Acenaphthylene lbs/ton roduction EF C/WS 2 1.22E·06 2.17E-07 0.00 FF 3 2.04E-08 1.89E-08 1.00 '(es

Asphalt Prod., D .. i.eset IPAH IAnthracene lbs/ton production s= e/FF 3 3.21 E-08 7.68E-09 1.00 ems 2 2.78E-06 2.42E-06 l o.a81 No Asphalt Prod., Diesel PAH Anthracene lbs/ton production EF GIFF 3 3.21 E-08 7.68E-09 1.00 FF 3 1.68E-08 7 .54E-09 1 .00 No Asphalt Prod., Di~sel PAI-I __ Anthracene lbs/ton reduction e= C/WS 2 2.78E-06 2.42E-06 0.81 ~ 3 1.68E-08 7 .54E-09 _.'! .00 No

Asphalt Prod .. Diesel IPAH IBenzo(a)anthracene lbs/ton production s= 2:_s.1_~-.oe "· ·. _ 1 .00 erws 2 l .22E-06 2.17E-07 0.00 Yes Asphalt Prod., Diesel PAI-I Benzo(a)anthracene lbs/ton production EF 2; ..... '.)t ,.,. 1;00 FF 3 6.41 E-09 2.56E-09 1.00 Yes A~lt Prod., Diesel PAI-I __ Benzo a anthracene lbs/ton roduction Ef 2.17E-07 0.00 ~ 3 6.41E-09 2.56E-09 1.00 Yes

Asphalt Prod., Diesel IPAH Benzo(a)pyrene lbs/ton production EF 2. 7_9E~O~ _L,4. 5E···0··9.. ·.1 .. 00 C/WS 2 1.22E-06 2.17E-07 0.00 Yes Asphalt Prod., Diesel PAI-I Benzo(a)pyrene lbs/ton production EF 2:-'191f.;ost.: ;-.f ...... ,:;; ~-:1'00:,L FF 3 3.13E-10 5.29E-11 1 .00 Yes Asphalt Prod., Diesel PAH Benzo a rene lbs/ton roduction EF 1.22E-06 2.17E-07 0.00 FF 3 3.13E-10 5.29E-11 1 .00 Yes A~lt Prod., Diesel /PAI-I /Benzo(b)fluoranthene /lbs/ton production/EF 1.39E-08 / 9.49E-09 / 1.00 / FF / 3 / 4.39E-09 / 6.44E-09 / 1.00 I N~ Asphalt Prod., Diesel PAI-I Benzo(g,h,~)pe,y1ene lbs/ton production EF .. _ .. _e_/FF ___ 3 .... 1::~01:_~09 6._?6E~!.o,. ·--~-:2.3 ems 2 1.22E-06 2.17E-07 0.00 Yes Asphalt Prod., Diesel PAI-I Benzo(g,h,1)pe,ylene lbs/ton production EF ';:;tCIB;/-.•i 'iAll> : "'1'~ ~ll&flh? (;_q_:; FF 3 5.03E-10 3.10E-11 1.00 Yes AsphaltProd.,_Diesel PAI-I Benzo hi e lene roduction EF ems 2 1.22E-06 2.17E-07 0.00 FF 3 5.03E-10 3.10E-11 1.00 Yes Asphalt Prod., Diesel IPA!-1 Benzo(k)fluoranthene lbs/ton production s= e/FF 3 5.13E-09 2.90E-09 1.00 C/WS 2 1.22E-06 2.17E-07 0.00 Yes Asphalt Prod., Diesel PAI-I Benzo(k)fluoranthene lbs/ton production EF e/FF 3 5.13E·09 2.90E-09 1.00 FF 3 1.13E-09 1.31 E-09 1.00 No Asphalt Prod._._ Diesel PAH Benzo k fluoranthene tbs/ton roduction e= ems 2 1.22E-06 2.17E-07 0.00 FF 3 1.13E-09 1.31E-09 1.00 Yes

Asphalt Prod., Diesel PAI-I Ch,ysene lbs/ton production EF , .. '.·"gl,E_~; ._ ~, . __ ,j:.70. E-_O. 8 .. · ... 1.2~E-08 .,,, .. ~- .. 0. ~.. erws 2 1.22E-06 2.17E-07. l 0 ...... 00 l Y'"' Asphalt Prod., Diesel PAI-I Ch,ysene lbs/ton production EF :'(-;{~~:r;"' r •J,.r~}'•;;i'i';iil!lli.~[;; FF 3 1.25E-09 3.67E-10 1.00 Yes A~lt Prod.LDiesel PAI-I Ch sane lbs/ton roduction EF ems 2 1.22E-06 2.17E-07 0.00 FF 3 1.25E-09 3.67E-10 ___ 1.Q_Q_ y~ Asphalt Prod., Diesel PAI-I dibenz(a.h)anthracene lbs/ton production e= e/FF 3 1.76E·09 B.74E-10 0.00 ems 2 1.22E-06 2.17E-07 l o.oo I y'"' Asphalt Prod., Diesel PAH dibenz(a,h)anthracene lbs/ton production EF e/FF 3 1.76E-09 8.74E·10 0.00 FF 3 1.90E-10 1.0BE-10 0,00 Yes Asp_h_altProd. Diesel PAI-I dibenzahanthracene lbs/ton roduction a= C/WS 2 1.22E-06 2.17E-07 0.00 FF 3 1.90E-10 1.0SE-10 0.00 Yes Asphalt Prod., Diesel IPAH Fluoranthene lbs/ton production EF ~:,63E-08 .oo ems 2 1.22E-06 2.17E-07 o.oo Yes Asphalt Prod., Diesel PAI-I Fluoranthene lbs/ton production EF '~;/·jj "' , - FF 3 8.67E~08 3.88E·08 1.00 Yes A~lt Prod., Diesel_ _ PN-i Fluoranthene lbs/ton reduction e= 2.17E-07 .00 FF 3 8.67E-08 3.88E-08 1.00 Yes

Asp.ha.It Prod., Diesel lP.A!-1 Fluorene tbs/ton production EF ems5Jili1.22E-06 2.17E-·0·7·· l 0.0.0 L No Asphalt Prod., Diesel PAI-I Fluorene lbs/ton production s= Q~Ai~ii FF 3 2.78E-07 1.92E-07 1.00 Yes Asp/)_alt Prod. Diesel PAI-I Fluorene lbs/ton roduction EF ff_ 3 2. 78E-07 1.92E-07 _ 1.0Q__ Yes Asphalt Prod., Diesel !PAH l1ndeno(1,2,3-cd)pyrene libs/ton productlon!EF I C/FF I 3 I 2.06E·09 I S.13E-10 I 0.29 I C/WS I 2 I t.22E·06 I 2.17E-07 I 0.00 I Yeo

6-30

!Group

!Asphalt Prod., Diesel A_~halt Prod., Diesel

!Asphalt Prod., Diesel Asphalt Prod., Diesel .sphalt Prod., D_i_esel

'\Sphalt Prod., Diesel ~sphalt Prod., Diesel M?_hatt Prod., D_iesel

!

Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod .. Diesel Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod., Di~~ Asphalt Prod., Diesel Asphalt Prod., Diesel Asphalt Prod Die~~J

Category

P!'H P!'H P!'H P!'H P!'H P!'H P!'H P!'H P!'H P!'H P!'H voc voc voc voc voc voc voc voc voc

TABLE A6-4a. AIR POl.LlfTION CONTROL SYSTEM COMPARISON (!-statistics).

Substance EF Unit Value Typel

lndeno(1,2,3-cd)pyrene libs/to. n productionl.EF lnd~no(l ,2,3-cd)pyrene lbs/ton productio_n l;f"

Naphthalene llbs/ton production,.EF .. Naphthalene lbs/ton production s= Naphthalene lbs/ton production S:

_Eioo__S_ample Statistics Description! Size I Average I Standard Detect APC S_ystem _ Deviation _A~tio

"~~'.•"'.'iliit.ilt\1.~"L.i .. t. -.. lflr~ii __ Cl'W.f!. l 2 I t.22E·QLI_ 2._17E-07 I O.QQ_

CiFF 3 4.75E-OtL2.78E·05 1.00 CiFF 3 4.75E·05 2.78E-05 1.00

".'-·:"' ' ' ~f . ~:::~- }~ ,_ . , ;11

Description

A!'.C_System ff ff

FF ff

Second Sam e Statistics Size Average Standard

3 3.00E-10 3 3.00E-10

:,.i,'-',

. 3 j 1 .. oaE:os :,_J_u1_aE-os

Deviation 6.03E-12 6.03E-12

4.70E-06 4.70E·06

Detect Ratio 1.00 1.00

"~;-,;,__,'""' . 1.00

_LQ_Q_

Phenanthrene lbs/ton production e= C/FF 3 6.27E-07 2.36E-07 1.00 l C/WS 12 , 1.13E-05 7.28E-06 1.00 Phenanthrene lbs/ton production e= C/FF 3 6.27E-07 2.36E-07 1.00 FF 3 7 .23E-07 3.10E-07 1.00 Phenanthrene lbs/ton roduction e= C/WS 2 1.13E-05 7.28E-06 1_J)_O FF 3 7.23E-07 3.10E-07 1.00 Pyrene lbs/ton production e= -- -~~F, .·· C/WS 2 1.22E-06 2.17E-07 0.00 Pyrene lbs/ton produc11on e= <tflf?;hf- rilHl&lii. FF 3 5.99E-08 2.56E-08 1.00 P rene lbs/ton roduction e= C/WS 2 FF 3 5.99E-08 2.56E-08 1.00

Benzene lbs/ton production e= ;:· .. ·~.·:.s1·.·.:µ.·· :· .. : .. •··:'(·,.l.j~l,~.- C/WS 2 2.21E-05 7.81E-06 0.63 Benzene lbs/ton production EF ·:<;~, "·• ;~<~ S~i Ff 3 1.04E-03 4.65E-05 0.00 Benzene lbs/ton production e= ,,j . ---'~t,, WS 1 3.05E-04 1.00 Benzene lbs/ton production s= CNIS 2 FF 3 Benzene lbs/ton production e= CN/S };~~~~ Benzene lbs/ton roduction e= FF 1.04E-03 WS 1 Formalde .. hyde lbs/ton productions= C/FF 3 1.32E•04 5.94E-05 1.00 C/WS 2 6.12E-05 , 1.53E-05 I 1.00 Formaldehyde lbs/ton production e= C/FF 3 1.32E·04 5.94E-05 1.00 FF 3 2.43E-04 7.74E-05 1.00 Formaldeby-de lbs/ton roduction e= C/WS 2 6.12E-05 1.53E-05 1.00 FF 3 2.43E.:_Q_4 __ 7.74E-05 1.00

Asphalt Prod., Natura.I GEs M.•.•.•ls IA.r.senic lbs/ton production EF C/FF 6 9.48E-07 5.49E-07 0.00 C/WS 5 1.70E-05 3.03E-05 0.83 Asphalt Prod .. Natural Gas Metals Arsenic lbs/ton production e= C/FF 6 9.48E-07 5.49E-07 0.00 Ff 3 2.16E-06 4.32E-07 0.00 Asphalt Prod., Natur_aLGas 1',_ieti;!_ls Arsenic lbs/ton roductian e= ems 5 1.70E-05 3.03E-05 0.83 FF 3 2.16E-06 4.32E-07 0.00 Asphalt Prod., Natural Gas.lMetals I Beryllium lbs/ton produc1ion EF C/FF 6 1.14E-06 5.31E-07 0.00 C/WS 5 6.17E-07 I 5.74E-07 I 0.00 Asphalt Prod .. Natural Gas Metals Beryllium lbs/ton production EF C/FF 6 1.14E-06 5.31E-07 0.00 Ff 3 2.13E-07 4.12E-08 0.00 Asphalt Prod., Natural Gas Metals Beryllium_ lbs/ton roduction EF C/WS 5 6.17E-07 5.74E-07 0.00 FF 3 2.13E-07 __ 4.12E-08 0.00 Asphalt Prod., Natural GaslM. eta1s !Cadmium lbs/ton production EF C/FF 6 2.30E-06 2.83E-06 0.75 C/WS 5 3.04E-06 4.06E-06 0.81 Asphalt Prod., Natural Gas Metals Cadmium lbs/ton production EF C/FF 6 2.30E-06 2.83E-06 0.75 FF 3 4.27E-07 8.25E-08 0.00 Asphalt Prod., Natural Gas M__filals Cadmium lbs/ton roduction a= ems 5 3.04E-06 4.06E-06 0.81 FF 3 4.27E-07 8.25E-08 0.00 Asphalt Prod., Natural Gas,Metals I Chromium lbs/ton production EF C/FF 6 1.17E-06 2.65E-07 0.58 C/WS 5 2.32E-06 , 2.41E-06 I 1.00 Asphalt Prod., Natural Gas Metals Chromium lbs/ton production a= C/FF 6 1.17E-06 2.65E-07 0.58 FF 2 4.SlE-06 4.53E-06 1.00 Asphalt Prod., Natural Gas Metals Chromium lbs/tan reduction EF ems 5 2.32E-06 2.41E-06 1.00 FF 2 -!.:_91E-06 4.53E-06 1.00 Asphalt Prod .. Natural Gas1M•t·a·ls !Chromium (Hex) lbs/tan production EF C/FF 6 6.StE-07 3.68E-07 0.25 C/WS 5 2.72E·O~ 4.09E-06 I 1.00 Asphalt Prod., Natural Gas Metals Chromium (Hex) lbs/ton production a= C/FF 6 6.51E-07 3.68E-07 0.25 FF 2 5.60E-07 1.63E-07 0.60 Asphalt Prod., Natural Gas Metaj~ Chromium (Hex} lbs/ton roductian a= ems 5 2.72E-06 4.09E-06 1.00 FF 2 5.60E-07 1.63E-07 0.60 Asphalt Prod., Natural GaslMetals ICoppe. r lbs/tan production EF C/FF 6 3.49E-06 1.51E-06 0.61 C/WS 5 5.46E-06 6.53E-06 1.00 Asphalt Prod., Natural Gas Metals Capper lbs/ton production EF C/FF 6 3.49E-06 1.51E-06 0.61 FF 3 3.38E-06 6.12E-07 1.00 Asphalt Prod., Natural Gas Metals Cop~r lbs/ton roduction EF C/WS 5 5.46E-06 6.53E-06 1.00 FF 3 3.38E-06 6.12E-07 1.00 Asphalt Prod., Natural G.~Metals I Lead lbs/ton production e= C/FF 6 6.03E-06 7.BOE-06 1.00 C/WS 5 2.36E-05 4.70E-05 0.94 Asphalt Prod., Natural Gas Metals Lead lbs/ton production EF C/FF 6 6.03E-06 7.BOE-06 1.00 FF 3 1.07E-06 2.10E-07 0.00 Asphalt Prod., Natural Gas Metals Lead lbs/ton roduction EF C/WS 5 2.36E-05 4.70E-05 0.94 FF 3 1.07E-06 2.10E-07 0.00 Asphalt Prod., Natural Gas Metals Manganese lbs/ton production e= C/FF 6 1.41E-05 1.10E-05 1.00 C/WS 5 9.42E-05 8.72E-05 1.00 Asphalt Prod., Natural Gas Metals Manganese lbs/ton praduc1ion EF C/FF 6 1.41E·05 1.10E-05 1.00 FF 3 1.47E-05 8.27E-06 1.00 Asohalt Prod., Natural Gas Metals Mannanese lbs/tan oroduction a= ems 5 9.42E-05 8.72E-OS 1.00 FF 3 1.47E-05 8.27E-06 1.00. Asphalt Prod., Natural Gas Metals Mercury lbs/ton production e= '! ;::ftQlf';;f;Ci ~,; -1~} ·s;',k C/WS 5 1.66E-06 1.0SE-06 1,00 Asphalt Prod., Natural Gas Metals Mercury lbs/ton production EF C/FF 6 1.53E-05 1.31E-05 1.00 FF 3 4.73E-07 1.19E-07 1.00 AsphaH __ Pr()d~i;!_tural Gas Metals Mercury lbs/ton nroduction EF ems 5 1.66E-06 1.0BE-06 1.00 FF 3 4.73E-07 1.19E-07 1.00 Asphalt Prod .. Natural Gas,Metals !Nickel lbs/ton production e= C/FF 6 4.86E-06 3.40E-06 0.00 C/WS 5 1.16E-05 1.69E-05 0.69 As. phalt Prod .. Natural Gas Metals N~ckel 1bs/ton production e= C/FF 6 4.86E-06 3.40E-06 0,00 FF 3 9.53E-06 5.66E-06 1.00 Asphalt Prg__g,_,_Natural Gas Metals N.!ckel lbs/ton roduction EF ems 5 1.16E·05 1.69E-05 0.69 FF 3 9.53E-06 5.66E-06 1.00 Asphalt Prod., Natural GaslMetals I Selenium I lbs/ton praductionlEF I CiFF I 6 I 9.47E-07 5.47E-07 I 0.00 I C/WS 5 I 2.89E-05 I 5.66E-05 I 0.90 Asphalt Prod., Natural Gas Metals Selenium lbs/ton production EF C/FF 6 9.47E-07 5.47E-07 0.00 FF 3 2.15E-06 4.19E-07 0.00

6-31


95%Confidence Yes Yes Yes No Yes No No No Yes Yes Yes Yes Yes Yes Yes Yes Yes No No No No Yes l!Q. No Yes No No No No No No No No No No No No !-IQ No No NQ No No No Yes No No No No No No Yes

TABLE A64a. AIR POLLUTION CONTROL SYSTEM COMPARISON (t-stalistics).

Group Category Substance EF Unit Value Type -First Samole Statjstics Second Samrile Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at APC Svstem Deviation Ratio APC Svstem Deviation Ratio 95%ConfidencE

Asohalt Prod. Natural Gas Metals Selenium lbs/ton oroduction El' C/WS 5 2.89E-05 5.66E-05 0.90 FF 3 2.15E-06 4. 19E-07 0.00 No Asphalt Prod., Natural Gas Metals Zinc lbs/ton production El' CIFF 6 1.48E-05 6.66E-06 1.00 C/WS 5 3.0BE-05 3.10E-05 1.00 No Asphalt Prod., Natural Gas Metals Zinc lbs/ton production El' CIFF 6 1.48E-05 6.66E-06 1.00 i<~~0~~S:til 'ii.'4& ,:,~-), :,t~li ,;:as~ Ya, Asohalt Prod. Natural Gas Metals Zinc lbs/ton nroduction El' C/WS 5 3.08E-05 3.10E-05 1.00 FF 3 3.99E-05 2.43E-06 1.00 No Asphalt Prod., Natural Gas PAH Acenaphthene lbs/ton production El' C,FF 6 8.29E-07 3.34E-07 1.00 C/WS 5 6.19E-07 5.22E-07 0.25 No Asphalt Prod., Natural Gas PAH Acenaphthene lbs/ton production El' ,fafc:IF,f,, ,\ [iii ~--;::~ ';;\ __ Qfi', s3t~i0'.} FF 3 1.92E-07 7.35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH Acenaohthene lbs/ton oroduction El' C/WS 5 6.19E-07 5.22E-07 0.25 FF 3 1.92E-07 7.35E-09 0.00 No Asphalt Prod., Natural Gas PAH Acenaphthylene tbs/ton production El' CIFF 6 2.24E-06 4.12E-06 1.00 CIWS 4 6.69E-07 5.60E-07 0.14 No Asphalt Prod., Natural Gas PAH Acenaphthylene lbs/ton production El' CIFF 6 2.24E-06 4.12E-06 1.00 FF 3 1.92E-07 7.35E-09 0.00 No Asnhalt Prod. Natural Gas PAH Acenaohthvlene lbs/ton oroduction El' C/WS 4 6.69E-07 5.60E-07 0.14 FF 3 1.92E-07 7.35E-09 0.00 No Asphalt Prod., Natural Gas PAH Anthracene lbs/ton production El' CIFF 6 2.50E-07 3.63E-07 1.00 C/WS 5 5.00E-07 5.98E-07 0.08 No Asphalt Prod., Natural Gas PAH Anthracene lbs/ton production El' C,FF 6 2.50E-07 3.63E-07 1.00 FF 3 1.92E-07 7.35E-09 0.00 No Asohalt Prod. Natural Gas PAH Anthracene lbs/ton oroduction El' C/WS 5 5.00E-07 5.98E-07 0.08 FF 3 1.92E-07 7.35E-09 0.00 No Asphalt Prod., Natural Gas PAH Benzo{a)anthracene lbs/ton production El' C,FF 6 1.12E-08 2.54E-09 1.00 C/WS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo(a)anthracene lbs/ton production El' CIFF 6 1.12E-08 2.54E-09 1.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH Benzo(alanthracene lbs/ton oroduction El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Ya, Asphalt Prod., Natural Gas PAH Benzo(a)pyrene lbs/ton production El' CIFF 6 1.15E-09 3.82E-10 0.33 CIWS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo(a)pyrene lbs/ton production El' C,FF 6 1.15E-09 3.82E-10 0.33 FF 3 1.92E-07 7.35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH Benzo{a)ovrene lbs/ton croductlon El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo(b)fluoranthene lbs/ton production El' CIFF 6 1.67E-09 1.52E-09 0.90 CIWS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo(b)fluoranthene lbs/ton production El' C,FF 6 1.67E-09 1.52E-09 0.90 FF 3 1.92E-07 7.35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH Benzo(b)fluoranthene lbs/ton nroduction El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo( g, h, i) pe rylene lbs/ton production El' CIFF 6 1.44E-09 3.65E-10 0.57 CIWS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo(g,h,i)perylene lbs/ton production El' CIFF 6 1.44E-09 3.65E-10 0.57 FF" 3 1.92E-07 7.35E-09 0.00 Yes Asnhalt Prod. Natural Gas PAH Benzo( o. h Doervlene lbs/ton oroduction El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Ya, Asphalt Prod .. Natural Gas PAH Benz o ( k )fluo ra nthe ne lbs/ton production El' CIFF 6 2.67E-09 1.58E-09 0.77 C/WS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH Benzo ( k )fluora nth en e lbs/ton production El' C,FF 6 2.67E-09 1.58E-09 0.77 FF 3 1.92E-07 7.35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH Benzolklfluoranthene lbs/ton nroduction El' CIWS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH Chrysene lbs/ton production El' C,FF 6 1.75E-09 7.87E-10 0.64 CIWS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod,, Natural Gas PAH Chrysene tbs/ton production El' CIFF 6 1.75E-09 7.87E-10 0.64 FF 3 1.92E-07 7 .35E-09 0.00 Yes Asnhalt Prod. Natural Gas PAH Chrvsene lbs/ton oroduction El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH dibenz( a,h)anthracene lbs/ton production El' CIFF 6 1.09E-09 5.37E-10 0.38 C/WS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH dibenz(a,h)anthracene lbs/ton production El' CIFF 6 1.09E-09 5.37E-10 0.38 FF 3 1.92E-07 7 .35E-09 0.00 Yes Asohalt Prod. Natural Gas PAH dibenzta Manthracene lbs/ton nroduclion El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH Fluoranthene tbs/ton production El' CIFF 6 6.78E-07 1.43E-06 1.00 C/WS 5 4.67E-07 6.26E-07 0.01 No Asphalt Prod .. Natural Gas PAH Fluoranthene lbs/ton production El' CIFF 6 6.78E-07 1.43E-06 1.00 FF 3 1.92E-07 7 .35E-09 0.00 No Asohalt Prod. Natural Gas PAH Fluoranthene lbs/ton oroduction El' C/WS 5 4.67E-07 6.26E-07 0.01 FF 3 1.92E-07 7.35E-09 0.00 No Asphalt Prod., Natural Gas PAH Fluorene lbs/ton production El' C,FF 6 1.82E-06 7.23E-07 1.00 C/WS 5 1.38E-06 9.67E-07 0.67 No Asphalt Prod., Natural Gas PAH Fluorene lbs/ton production El' C,FF 6 1.82E-06 7.23E-07 1.00 FF 3 2.23E-06 2.52E-07 1.00 No Asohalt Prod. Natural Gas PAH Fluorene lbs/ton croduction El' crws 5 1.38E-06 9.67E-07 0.67 FF 3 2.23E-06 2.52E-07 1.00 No Asphalt Prod., Natural Gas PAH lndeno(1,2,3-cd)pyrene lbs/ton production El' CIFF 6 1.29E-09 4.93E-10 0.52 C/WS 2 1.15E-06 4.87E-08 0.00 Yes Asphalt Prod., Natural Gas PAH lndeno(1,2.3-cd)pyrene tbs/ton production El' CIFF 6 1.29E-09 4.93E-10 0.52 FF 3 1.92E-07 7.35E·09 0.00 Yes Asnhalt Prod. Natural Gas PAH lndenof 1 2 3-cd 1n"rene lbs/ton oroduction El' C/WS 2 1.15E-06 4.87E-08 0.00 FF 3 1.92E-07 7.35E-09 0.00 Yes Asphalt Prod., Natural Gas PAH Naphthalene lbs/ton production El' c--:i:lC/l!tO:: ·i i:l .. ~'."! -':f,\111_

y£HS·-•itW11;■ Yes

Asphalt Prod., Natural Gas PAH Naphthalene lbs/ton production El' CIFF 6 3.30E-05 2.54E-05 1.00 Yes Asohalt Prod. Natural Gas PAH Naohthalene lbs/ton oroduction El' CIWS 5 5.43E-06 6.61 E-06 0.92 -=-;·'"" _..1i<~ ·,.. - ,. <:tr · i- ·-' Yes Asphalt Prod., Natural Gas PAH Phenanthrene lbs/ton production El' CIFF 6 2.88E-06 2.44E-06 1.00 C/WS 5 1.71E-06 1.03E-06 1.00 No Asphalt Prod., Natural Gas PAH Phenanthrene lbs/ton production El' CIFF 6 2.88E-06 2.44E-06 1.00 FF 3 3. 76E-06 6.58E-07 1.00 No Asohalt Prod. Natural Gas PAH Phenanthrene lbs/ton croduction El' C/WS 5 1.71E-06 1.03E-06 1.00 t·."'~x~ Yes Asphalt Prod., Natural Gas PAH Pyrene lbs/ton production El' CIFF 6 1.25E-06 2.83E-06 1.00 C/WS 5 4.72E-07 6.23E-07 0.02 No Asphalt Prod., Natural Gas PAH Pyrene lbs/ton production El' CIFF 6 1.25E-06 2.83E-06 1.00 FF 3 1.99E-07 1.09E-08 0.35 No Asohatt Prod. Natural Gas PAH Pvrene lbs/ton oroduction El' C/WS 5 4.72E-07 6.23E-07 0.02 FF 3 1.99E-07 1.09E-08 0.35 No

6-32

TABLE A6-4a. AIR POLLUTION CONTROL SYSTEM COMPARISON (t-statislics).

Group Category Substance EF Unit Value Type First Samole Statistics Second Samrile Statistics Significant Description Siz:e Average Standard Detect Description Size Average Standard Detect Difference at APC SvS1em Deviation Ratio APC SvS1em Deviation Ratio 95%Confidenct

Asphalt Prod., Natural Gas voc Benzene lbs/ton production EF GIFF 6 1.27E-04 1.37E-04 1.00 CIWS 5 5.32E-05 7.82E·05 1.00 No Asphalt Prod., Natural Gas voc Benzene lbs/ton production EF GIFF 6 1.27E-04 1.37E-04 1.00 FF 2 2.29E-05 2.74E-06 1.00 No

Asohalt Prod. Natural Gas voc Benzene lbs/ton nroduction EF CIWS 5 5.32E-05 7.82E-05 1.00 FF 2 2.29E-05 2.74E-06 1.00 No

Asnhalt Prod. Natural Gas VOC Fonnaldehvde lbs/ton oroduction EF GIFF 6 3.79E-04 3.79E-04 1.00 CIWS 3 1.33E-05 3.43E-06 1.00 No Boiler Fuel Oil PAI-I Acenanhthene lbs/Moal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 2.47E-05 3.34E-05 0.48 Yes Boiler Fuel OU PAI-I Acenanhthvlene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 2.05E-05 3.99E-05 0.30 Yes Boiler Fuel Oil PAI-I Anthracene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.43E-05 2.68E·05 0.10 Yes Boiler Fuel Oil PAI-I Benzo(a\anthracene lbs/Maal EF FF 2 1.38E-04 1.24E·06 0.00 None 33 1.36E-05 2.71E-05 0.04 Yes Boiler Fuel Oil PAI-I Benzol a )ovrene lbs/MnaJ EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.54E-05 2.70E-05 0.15 Yes Boiler Fuel Oil PAI-I Benzolb\fluoran1hene lbs/Mnal EF FF 2 1.38E-04 1.24E-06 0.00 None 1 5 2.89E-05 3.47E-05 0.04 Yes Boiler Fuel Oil PAI-I Benzofa.h.iloervlene lbs/Mnal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.37E-05 2. 70E-05 0.03 Yes Boiler Fuel Oil PAI-I Benzolk\fluoran1hene lbs/Mnal EF FF 2 1.38E-04 1.24E-06 0.00 None 1 5 2.76E-05 3.58E-05 0.00 Yes Boiler Fuel Oil PAI-I Chrvsene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.58E·05 2.67E-05 0.17 Yes Boiler Fuel Oil PAI-I dibenzfa h\an1hracene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.36E·05 2. 70E-05 0.02 Yes Boiler Fuel Oil PAI-I Fluoranthene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.83E-05 2. 74E-05 0.38 Yes Boiler Fuel Oil PAI-I Fluorene lbs/Mnal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 2.18E-05 3.04E-05 0.42 Yes Boiler Fuel Oil PAI-I lndeno(1 2 3-cd\'"'"rene lbs/Mnal EF FF 2 1.38E•04 1.24E·06 0.00 None 33 1.34E-05 2.71E-05 0.02 y..,

Boiler Fuel Oil PAI-I Nanhthalene lbs/Moat EF ,,, )¾ C None 33 5.17E-03 1.21E-02 1.00 y..,

Boiler Fuel Oil PAI-I Phenanthrene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 3.26E-05 6.19E-05 0.69 y..,

Boiler Fuel Oil PAI-I Pvrene lbs/Maal EF FF 2 1.38E-04 1.24E-06 0.00 None 33 1.46E-05 2.67E-05 0.11 Yes Boiler Fuel Oil voc Forrnaldehvde lbs/Mnal EF FF

~ •••• 1,00

None 27 5.69E-02 1.08E-01 0.97 No

Coating, Green PE Metals Chromium lbs/gal paint EF :~I;J;J;rz? ~l1f PA 4 1.19E-04 5.38E-05 0.68 Yes Coating, Green PE Metals Chromium lbs/gal paint EF w:, 2 4.15E-05 8.22E·06 1.00 y..,

Coating, Green PE Metals Chromium lbs/gal paint EF ·. JIii'. c·c. WT 3 1.28E·04 6.13E-06 1.00 Yes Coating. Green PE Metals Chromium lbs/gal paint EF PA 4 1.19E-04 5.38E-05 0.68 w:, 2 4.15E-05 8.22E-06 1.00 No

Coating, Green PE Metals Chromium lbs/gal paint EF PA 4 1.19E-04 5.38E-05 0.68 WT 3 1.28E-04 6.13E-06 1.00 No

Coatina. Green PE Metals Chromium lbs/nal naint EF w:, 2 4.15E-05 8.22E-06 1.00 ··""'. . 3 1-·-.a· ... 1- Yes Coating, Green PE Metals Chromium (Hex) lbs/gal paint EF EF 3 1. 75E-04 1.18E-04 1.00 PA 4 3.1 0E-05 2.02E-05 1.00 No

Coating, Green PE Metals Chromium (Hex) lbs/gal paint EF EF 3 1.75E-04 1.18E-04 1.00 w:, 2 4.31E-06 1.03E-06 1 .00 No

Coating, Green PE Metals Chromium (Hex) lbs/gal paint EF EF 3 1.75E-04 1.18E-04 1.00 wr 3 3.99E-05 9.96E-06 1.00 No

Coating, Green PE Metals Chromium {Hex) lbs/gal paint EF PA 4 3.10E-05 2.02E-05 1.00 Ye 2 4.31E-06 1.03E-06 1.00 No

Coating, Green PE Metals Chromium (Hex) lbs/gal paint EF PA 4 3.10E-05 2.02E-05 1.00 wr 3 3.99E-05 9.96E-06 1.00 No

Coatina. Green PE Metals Chromium /Hex\ lbs/aal naint EF Ye 2 4.31E-06 1.03E-06 1 00 ··- • ... - .... . ---~-,,, ... Yes

Coating, Green Primer Metals Chromium lbs/gal paint EF EF 3 1.53E-03 7.22E-04 1.00 PA 4 7.33E-04 7.81E-04 0.95 No

Coating, Green Primer Metals Chromium lbs/gal pain1 EF EF 3 1.53E-03 7.22E-04 1.00 Ye 4 1.18E-03 9. 76E-04 1.00 No

Coating, Green Primer Metals Chromium lbs/gal paint EF EF 3 1.53E-03 7.22E-04 1.00 WSN 3 1.03E-03 6.24E-04 1.00 No

Coating, Green Primer Metals Chromium lbs/gal paint EF Bf .. 3. 1.63E.Q3 7.Z!E.'04. MO WT 6 2.60E-04 1.21E-04 0.63 Yes

Coating, Green Primer Metals Chromium lbs/gal paint EF PA 4 7.33E-04 7.81E-04 0.95 w;; 4 1.18E-03 9.76E-04 1.00 No

Coating, Green Primer Metals Chromium lbs/gal paint EF PA 4 7.33E-04 7.81E-04 0.95 WSN 3 1.03E-03 6.24E-04 1.00 No

Coating, Green Primer Metals Chromium lbs/gal paint EF PA 4 7.33E-04 7.81E-04 0.95 WT 6 2.60E-04 1.21E-04 0.63 No

Coating. Green Primer Metals Chromium lbs/gal paint EF ... 1.18E-03 - 1.00 WSN 3 1.03E-03 6.24E-04 1.00 No

Coating, Green Primer Metals Chromium lbs/gal paint EF I -, jJ!I:;;· WT 6 2.60E-04 1.21E·04 0.63 Yes Coatino. Green Primer Metals Chromium lbs/nal naint EF WT 6 2.60E-04 1.21 E-04 0.63 Yes

Coating. Green Primer Metals Chromium (Hex) lbs/gal paint EF EF 3 1.28E-03 7.08E-04 1.00 PA 4 2.87E-04 3.20E-04 1.00 No

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF EF 3 1.28E-03 7.08E-04 1.00 w;; 4 8.40E-04 7.13E-04 1.00 No

Coating. Green Primer Metals Chromium (Hex) lbs/gal paint EF ······ " , .. ,. 1.28E-03 7.08E-04 1.00 WSN 3 8.32E-04 4.49E-04 1.00 No

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF " '.f',.,19'' i~~ 1•s WT 6 2.26E-04 1.63E-04 1.00 Yes

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF PA 4 2.87E-04 3.20E-04 1.00 Ye 4 8.40E-04 7. 13E-04 1.00 No

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF PA 4 2.87E-04 3.20E-04 1.00 WSN 3 8.32E-04 4.49E-04 1.00 Na

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF PA 4 2.87E-04 3.20E-04 1.00 WT 6 2.26E-04 1.63E-04 1.00 Na

Coating, Green Primer Me1als Chromium (Hex) lbs/gal paint EF w:, 4 8.40E·04 7.13E-04 1.00 WSN 3 8.32E·04 4.49E•04 1.00 No

Coating, Green Primer Metals Chromium (Hex) lbs/gal paint EF w:, 4 8.40E-04 7.13E-04 1.00 WT 6 2.26E-04 1.63E-04 1.00 No

6-33

TABLE A6-4a. AIR POLLlJTION CONTROL SYSTEM COMPARISON (t-stafis11Cs).

Group Category Substance EF Unit Value Type First Samnle Statistics Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at APC Svstem Deviation Ratio APC Svstem Deviation Ratio 95%Confidence

Coatinn Green Primer Metals Chromium (Hex\ tbs/oal oaint 8' ., .,··•-., ·""•-· WT 6 2.26E-04 1.63E-04 1.00 Yes Coatina Powder Metals Chromium lbs/lbs oowder 8' f,F 2 2.94E-04 1.53E-04 1.00 None 4 1.30E-01 1.77E-01 1.00 No Coatino. Powder Metals Chromium (Hex\ lbs/lbs oowder 8' f,F 2 2.41E-04 B.44E-05 1.00 None 3 8.4BE-03 8.02E-03 1.00 No FBC Biomass Dioxin & Furan 40 2378 lbs/ton 8' AI/C/ESP 3 2.89E-11 1.03E-11 0.00 AIIC/FF 3 4.46E-10 4.17E-11 0.00 Yes FBC Biomass Dioxin & Furan 4F 2378 lbs/ton 8' AI/C/ESP 3 1.29E-10 5.25E-11 1.00 No FBC Biomass Dioxin & Furan 50 12378 tbs/ton 8' AI/C/ESP 3 3.28E-11 1.14E-11 0.00 Yes FBC Biomass Dioxin & Furan 5F 12378 lbs/ton 8' AI/C/ESP 3 6.27E-11 2.2BE·11 1.00 Yes FBC Biomass Dioxin & Furan SF 23478 lbs/ton 8' AIICIESP 3 1.03E-10 2.69E-11 1.00 Yes FBC Biomass Dioxin & Furan 6D 123478 lbs/ton 8' AI/C/ESP 3 4.36E-11 4.86E-12 0.29 A C/F 3 1.22E 09 4.69E 10 0.00 Yes FBC Biomass Dioxin & Furan 60 123678 lbs/ton 8' AI/C/ESP 3 6.38E·11 2.75E-11 0.50 AIIC/FF 3 1.27E-09 4.45E-10 0.00 Yes FBC Biomass Dioxin & Furan 6D 123789 lbs/ton 8' AI/C/ESP 3 4.77E-11 8.28E-12 ... _ Yes FBC Biomass Dioxin & Furan 6F 123478 lbs/ton 8' AI/C/ESP 3 7.59E·11 3.95E-11 ,.00 ::lllllr"' , .. ,, , ·. · Yes FBC Biomass Dioxin & Furan 6F 123678 lbs/ton 8' AI/C/ESP 3 1.12E-10 5.11E-11 1.00 f0:, ·,J ~-. .'+ Yes FBC Biomass Dioxin & Furan 6F 123789 lbs/ton 8' AI/CIESP 3 2.77E-11 2.63E·11 0.70 AI/C/FF 3 6.51E-10 5.42E-10 0.00 No FBC Biomass Dioxin & Furan 6F 234678 lbs/ton 8' AIIC/ESP 3 3.02E-10 2.69E-10 1.00 ;.{ J

O ' • Yes

FBC Biomass Dioxin & Furan 70 1234678 lbs/ton 8' AIIC/ESP 3 6.90E-10 2.02E-10 1.00 · . Yes FBC Biomass Dioxin & Furan 7F 1234678 lbs/ton 8' AIIC/ESP 3 1.37E-09 1.44E-09 1.00 • ·.· Yes FBC Biomass Dioxin & Furan 7F 1234789 lbs/ton 8' AIIC/ESP 3 B.97E-11 9.71E-11 0.92 Al/GIFF 3 7.43E-10 5.89E-10 0.63 No FBC Biomass Dioxin & Furan BO lbs/ton 8' AIIC/ESP 3 6.69E-09 2.53E-09 1.00 ':;:\~'.-,: Yes FBC Biomass Dioxin & Furan BF lbs/ton 8' AIICIESP 3 1.61E-09 1.B5E-09 1.00 AIICIFF 3 5.24E-09 3.44E-09 0.81 No FBC Biomass PAH Acenaohthene lbs/ton 8' AI/C/ESP 3 7.04E-07 3.53E-07 1.00 AIIC/FF 3 1.20E-05 3.01 E-06 0.00 Yes FBC Biomass PAH Acenanhthvlene lbs/ton 8' AIIC/ESP 3 2.67E-05 1.31E-05 1.00 AIIC/FF 3 9.47E-05 9.77E-05 0.95 No FBC Biomass PAH Anthracene lbs/ton 8' AI/C/ESP 3 5.6BE-07 1.92E-07 1.00 Al/GIFF 3 1.20E-05 3.01E-06 0.00 Yes FBC Biomass PAH Benzo(a)anthracene lbs/ton 8' AIICIESP 3 2.0SE-08 4.1 BE-09 0.74 Al/GIFF 3 1.20E-05 3.0lE-06 0.00 Yes FBC Biomass PAH Benzola\ovrene lbs/ton 8' AIICIESP 3 1.64E-08 6,23E-10 0.00 AI/C/FF 3 1.20E-05 3.01 E-06 0.00 Yes FBC Biomass PAH Benzo(blfluoranthene lbs/ton 8' AIICIESP 3 1.25E-07 1.66E-OB 1.00 AI/C/FF 3 1.20E-05 3.01 E-06 0.00 Yes FBC Biomass PAH Benzo{n h iloervlene lbs/ton 8' AIIC/ESP 3 5.94E-08 3.59E-08 1.00 Al/GIFF 3 1.20E-05 3.0lE-06 0.00 Yes FBC Biomass PAH Benzo/kHluoranthene lbs/ton 8' AIIC/ESP 3 3.00E-08 9.68E-09 1.00 Al/GIFF 3 1.20E-05 3.0lE-06 0.00 Yes FBC Biomass PAH Chrvsene lbs/ton 8' AIICIESP 3 2.35E-07 3.52E-08 1.00 AI/CIFF 3 1,20E·05 3.01 E-06 0.00 Yes FBC Biomass PAH dibenz{a h)anthracene lbs/ton EF AIIC/ESP 3 1.64E-OB 6.23E-10 0.00 Al/GIFF 3 1.20E-05 3.01 E-06 0.00 Yes FBC Biomass PAH Fluoranthene lbs/ton 8' AIIC/ESP 3 6.73E-06 2.44E-06 1.00 ··,,, .. ,. ,. .. ··•- Yes FBC Biomass PAH Fluorene lbs/ton 8' AIICIESP 3 1.32E-06 6.67E-07 1.00 Al/GIFF 3 1.20E·05 3.01E-06 0.00 Yes FBC Biomass PAH lndeno/1 2 3~cd\ 1•" 1rene lbs/ton 8' AIICIESP 3 2.47E-08 1.15E-08 o. 78

• 3

-Yes

FBC Biomass PAH Ni:1ohthalene lbs/ton 8' AIIC/ESP 3 2.99E-04 9.94E-05 1.00 "' ;f Yes FBC Biomass PAH Phenanthrene lbs/ton 8' AI/C/ESP 3 1.92E-05 5.3BE-06 1.00 i Yes FBC Biomass PAH Pvrene lbs/ton 8' AI/CIESP 3 4.78E-06 1.66E-06 1.00 . t1• Yes FBC Biomass voe Formaldehvde lbs/ton 8' AI/CIESP 3 3.66E-04 1.35E-04 1.00 ' . Yes FBC Coal Dioxin & Furan 40 2378 lbs/ton 8' LIIAIIC/FF 1 2 4.22E-10 4.03E-10 0.00 LI/Al/FF/ESP 2 9.89E-10 8.97E-10 0.00 No FBC Coal Dioxin & Furan 40 Total lbs/ton 8' LIIAIIC/FF 1 2 4.79E-10 4.2BE-10 0.00 LI/Al/FF/ESP 3 1.81E·09 1.56E·09 0.00 Yes FBC Coal Dioxin & Furan 4F 2378 lbs/ton 8' LIIAIICIFF 1 2 8.1BE-10 1.27E-09 0.08 LI/Al/FF/ESP 3 2.92E-09 2.71E-09 0.00 No FBC, Coal Dioxin & Furan 4F Total lbs/ton 8' LI/Al/GIFF 12 1.BOE-09 2.09E-09 0.63 LI/Al/FF/ESP 3 2.92E-09 2. 71 E-09 0.00 No FBC. Coal Dioxin & Furan 5D 12378 lbs/ton 8' LI/AI/CIFF 12 4.99E-10 5.06E-10 0.00 LI/Al/FF/ESP 1 1.BBE-09 0.00 Yes FBC Coal Dioxin & Furan SD Total lbs/ton 8' LIIAIICIFF 12 5.63E-10 4.85E-10 0.06 LI/Al/FF/ESP 3 1.55E-08 1.4BE-08 0.00 Yes FBC Coal Dioxin & Furan SF 12378 lbs/ton 8' LIIAIICIFF 12 4.95E-10 3.78E-10 0.29 LI/Al/FF/ESP 3 4.56E-09 4.09E·09 0.00 Yes FBC Coal Dioxin & Furan 5F 23478 lbs/ton 8' LI/AIIC/FF 12 5.BBE-10 4.BSE-10 0.43 LI/Al/FF/ESP 3 4.56E-09 4.09E-09 0.00 Yes FBC Coal Dioxin & Furan SF Total lbs/ton 8' LI/Al/GIFF 1 2 2.73E-09 4.SOE-09 0.85 LI/Al/FF/ESP 3 4.56E-09 4.09E-09 0.00 No FBC Coal Dioxin & Furan 6D 123478 lbs/ton 8' LI/Al/GIFF 1 2 4.95E-10 3.67E-10 0.06 LI/Al/FF/ESP 3 1.26E-OB 1.16E-0B 0.00 Yes FBC Coal Dioxin & Furan 60 123678 lbs/ton EF LI/Al/GIFF 1 2 5.13E-10 3.66E-10 0.07 LI/Al/FF/ESP 1 2.21E-09 0.00 Yes FBC, Coal Dioxin & Furan 60 123789 lbs/ton 8' LI/Al/GIFF 12 4.93E-10 3.72E-10 0.05 LI/Al/FF/ESP 3 1.26E-08 1.16E-08 0.00 Yes FBC Coal Dioxin & Furan 6D Total lbs/ton 8' LIIAIICIFF 12 1.14E-09 1.63E-09 0.60 LI/Al/FF/ESP 3 1.26E-08 1.16E-08 0.00 Yes FBC Coal Dioxin & Furan 6F 123478 lbs/ton 8' LI/Al/GIFF 12 6.38E-10 5.56E-10 0.48 LI/Al/FF/ESP 3 6.89E-09 4.95E-09 0.00 Yes FBC Coal Dioxin & Furan 6F 123678 lbs/ton EF LI/Al/GIFF 1 2 7.SSE-10 7.75E-10 0.56 LI/Al/FF/ESP 3 6.89E-09 4.95E-09 0.00 Yes

6-34

TABLE A6-4a. AIR POLLlfTION CONTROL SYSTEM COMPARISON (!-statistics).

Group Category Substance EF Unit Value Type First Samnle Statistics Second samnie Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at APC Svstem Deviation Ratio APC Svstem Deviation Ratio 95%ConfidencE

FBC Coal Dioxin & Furan 6F 123789 lbs/ton EF LI/AI/C/FF 12 5.92E-10 4.75E-10 0.44 LI/Al/FF/ESP 3 6.89E-09 4.95E-09 0.00 Yes

FBC Coal Dioxin & Furan 6F 234678 lbs/ton EF LI/AI/C/FF 12 1.12E-09 1.58E-09 0.71 LI/Al/FF/ESP 3 6.B9E-09 4.95E-09 0.00 Yes

FBC Coal Dioxin & Furan 6F Total lbs/ton EF LI/AI/C/FF 12 4.61 E-09 9.03E-09 0.92 LI/Al/FF/ESP 3 6.89E-09 4.95E-09 0.00 No

FBC Coal Dioxin & Furan 7D 1234678 lbs/ton EF LI/AI/C/FF t2 1.56E-09 1.7BE-09 0.74 LI/Al/FF/ESP 2 6.15E-09 5.27E-09 0.00 Yes

FBC Coal Dioxin & Furan 70 Total lbs/ton EF LI/AI/C/FF 12 2.81 E-09 3.B1E-09 0.84 LI/Al/FF/ESP 3 1.23E-0B 1.12E·0B 0.00 Yes

FBC Coal Dioxin & Furan 7F 1234678 lbs/ton EF LI/AI/C/FF 12 4.54E-09 8.77E-09 0.90 LI/Al/FF/ESP 3 1.26E-0B 1.09E-0B 0.00 No

FBC Coal Dioxin & Furan 7F 1234789 lbs/ton EF LI/AI/C/FF 12 9.40E-10 8.57E-10 0.52 LI/Al/FF/ESP 3 t .26E-0B 1.09E-0B 0.00 Yes

FBC Coat Dioxin & Furan 7F Total lbs/ton EF LI/AI/C/FF 12 8.14E-09 1.63E-08 0.94 LI/Al/FF/ESP 3 1.26E-08 1.09E-08 0.00 No

FBC Coat Dioxin & Furan 8D lbs/ton EF LI/AI/C/FF 12 7.2BE-09 1.20E-0B 0.95 LI/Al/FF/ESP 3 3.89E-0B 3.46E-0B 0.00 Yes

FBC Coat Dioxin & Furan BF lbs/ton EF LI/AI/C/FF 1 2 3.69E-09 6.SBE-09 0.88 LI/Al/FF/ESP 3 5.59E-0B 5.45E-OB 0.00 Yes

FBC. Coal Halnnens fO lbs/ton EF LI/AI/C/FF 1 2 2.54E-02 1.21E-02 1.00 LI/Al/FF/ESP 3 1.31E-02 6.39E-03 1.00 No

FBC.Coal Metals Arsenic lbs/ton EF LI/AI/C/FF 12 2.72E-05 4.65E-05 0.11 LI/Al/FF/ESP 3 6.14E-05 2.15E-05 1.00 No

FBC Coal Metals Bervllium lbs/ton EF LI/AI/C/FF 12 1.41E-06 7.61E-07 0.00 LI/Al/FF/ESP 3 1.15E-05 2.61E-07 0.00 Yes

FBC Coal Metals Cadmium lbs/ton EF LI/AI/C/FF 12 1.20E-05 7.17E-06 0.43 - No

FBC Coat Metals Chromium lbs/ton EF LI/AI/C/FF 12 2.69E-05 3.58E-05 0.99 . Yes

FBC. Coal Metals Chromium 1Hex\ lbs/ton EF LI/AI/C/FF 12 1.14E-05 B.93E-06 0.04 Yes

FBC. Coal Metals Con ...... r lbs/ton EF LI/AI/C/FF 12 1.60E-04 1.34E-04 1.00 LI/Al/FF/ESP 3 2.49E-05 1.26E-06 0.68 No

FBC Coat Metals Lead lbs/ton EF LI/AI/C/FF 12 6.76E-05 B.40E-05 0.76 LI/Al/FF/ESP 3 3.61 E-05 7.50E-06 1.00 No

FBC Coat Metals Mannanese lbs/ton EF LI/AI/C/FF 12 2.60E-03 B.61E-03 1.00 LI/Al/FF/ESP 3 1.18E-04 7.33E-06 1.00 No

FBC Coal Metals Mercuru lbs/ton EF LI/AI/C/FF 12 3.22E-04 4.92E-04 0.09 LI/Al/FF/ESP 3 2.56E-07 5.29E-09 0.00 No

FBC Coat Metals Nickel lbs/ton EF LI/AI/C/FF 12 2.25E-04 4.41E-04 1.00 LI/Al/FF/ESP 3 5.75E-05 1.36E-06 0.00 No

FBC Coat Metals Selenium lbs/ton EF LI/AI/C/FF 12 5.99E-05 B.39E-05 0.00 LI/Al/FF/ESP 3 1.15E-06 2.61 E-08 0.00 No

FBC Coat Metals Zinc lbs/ton EF LI/AI/C/FF 1 2 1.24E-03 1.29E-03 1.00 LI/Al/FF/ESP 3 3.41E-04 2.16E-05 1.00 No

FBC Coat PAH Acenanhthene lbs/ton EF LI/AI/C/FF 1 5 2.65E-06 5.23E-06 0.01 LI/Al/FF/ESP 3 2.33E-07 1.04E-07 1.00 No

FBC Coat PAH Acenanhthvlene lbs/ton EF LI/AI/C/FF 1 5 2.65E-06 5.23E-06 0.00 LI/Al/FF/ESP 3 1.89E-07 4.7BE-0B 1.00 No

FBC Coat PAH Anthracene lbs/ton EF LI/AI/C/FF 1 5 2.63E-06 5.24E-06 0.01 LI/Al/FF/ESP 3 2.64E-07 1.87E-07 1.00 No

FBC Coal PAH Benzota\anthracene lbs/ton EF LI/AI/C/FF 1 5 2.64E-06 5.24E-06 0.00 LI/Al/FF/ESP 3 6.22E-08 9.12E-09 1.00 No

FBC Coat PAH Benzota1n.,rene lbs/ton EF LI/AI/C/FF 15 2.66E-06 5.22E-06 0.00 LI/Al/FF/ESP 3 1.31E-06 6.83E-07 0.00 No

FBC Coat PAH Benzotb\fluoranthene lbs/ton EF LI/AI/C/FF 6 6.45E-06 6.91 E-06 0.00 LI/Al/FF/ESP 3 1.21E-07 6.11E-0B 0.82 No

FBC Coat PAH Benzoln h j\nen..lene lbs/ton EF LI/AI/C/FF 1 5 2.66E-06 5.22E-06 0.00 LI/Al/FF/ESP 3 5.46E-0B 2.73E-0B 0.27 No

FBC Coat PAH Benzolk\fluoranthene lbs/ton EF LI/AI/C/FF 6 6.45E-06 6.91E-06 0.00 LI/Al/FF/ESP 3 4.26E-0B 1.58E·0B 0.79 No

FBC Coal PAH Chrvsene lbs/ton EF LI/AI/C/FF 1 5 2.64E-06 5.24E-06 0.00 LI/Al/FF/ESP 3 3.01E-07 9.04E-08 1.00 No

FBC Coat PAH dibenzl a.h\anthracene lbs/ton EF LI/AI/C/FF 1 5 2.6BE-06 5.22E-06 0.00 LI/Al/FF/ESP 3 2.14E-0B B.07E-09 0.46 No

FBC Coal PAH Fluoranthene lbs/ton EF LI/AI/C/FF 1 5 2.64E-06 5.24E-06 0.00 LI/Al/FF/ESP 3 3.B9E-07 2.51E-07 1.00 No

FBC Coat PAH Fluorene lbs/ton EF LI/AI/C/FF 15 2.71E-06 5.20E-06 0.04 LI/Al/FF/ESP 3 9.30E-07 1.06E-07 1.00 No

FBC Coat PAH lndenol1 2 3-cd\nvrene lbs/ton EF LI/AI/C/FF 1 5 2.68E-06 5.22E-06 0.00 LI/Al/FF/ESP 3 4.03E-0B 2.54E-08 0.26 No

FBC Coat PAH Nanhthalene lbs/ton EF LI/AI/C/FF 1 5 2.9BE-04 6.10E-04 0.99 LI/Al/FF/ESP 3 7.33E-05 1.97E-05 1.00 No

FBC Coat PAH Phenanthrene lbs/ton EF LI/AI/C/FF 1 5 2.B0E-06 5.16E-06 0.09 LI/Al/FF/ESP 3 4.93E-06 7.77E-07 1.00 No

FBC Coat PAH Pvrene lbs/ton EF LI/AI/C/FF 1 5 2.64E-06 5.24E-06 0.01 LI/Al/FF/ESP 3 3.37E-07 2.09E-07 1.00 No

FBC. Coal voc Fonnaldehvde lbs/ton EF LI/AI/C/FF 15 2.97E-03 3.30E-03 0.97 LI/Al/FF/ESP 3 3.05E-04 2.94E-05 1.00 No

Furnace Aluminum Metals Arsenic lbs/ton nroduction EF FF 3 7.32E-04 9.74E-05 0.00 None 6 1.93E-05 1.30E-05 0.00 Yes

Furnace Aluminum Metals BervHium lbs/ton nroduction EF FF 9 5.SSE-05 3.23E-05 0.00 None 9 1.12E-05 1.42E-05 0.00 Yes

Furnace Aluminum Metals Cadmium lbs/ton nroduction EF FF 9 1.01 E-03 1.66E-03 1.00 None 9 2.71E-05 2.31E-05 0.89 No

Furnace Aluminum Metals Chromium lbs/ton nroduction EF H , .. None 9 3.72E-05 4.87E-05 1.00 Yes

Furnace Aluminum Metals Chromium fHex\ lbs/ton nroduction EF FF 3 1.12E-03 1.BSE-04 0.00 None 9 3.59E-05 2.65E-05 0.41 Yes

Furnace Aluminum Metals Co""""r lbs/ton nroduction EF _ _, :.;! - None 9 5.B0E-05 6.72E-05 1.00 Yes

Furnace Aluminum Metals Lead lbs/ton nroduction EF FF 9 5.66E-04 3.21E-04 1.00 None 9 2.71E-04 6.0BE-04 1.00 No

Furnace Aluminum Metals Manaanese lbs/ton nroduction EF FF 9 5.00E-04 B.03E-04 1.00 None 9 4.22E-03 1.25E-02 1.00 No

Furnace Aluminum Metals Mercurv lbs/tan nroduction EF ' " ,, None 6 3.1BE-06 2.31E-06 0.73 Yes

Furnace Aluminum Metals Nickel lbs/ton nroduction EF FF 9 2.79E-04 1.72E-04 1.00 None 9 1.16E-04 2.S0E-04 1.00 No

Furnace Aluminum Metals Selenium lbs/ton nroduction EF FF 3 2.93E-04 3. 76E-05 0.00 None 6 1.03E-05 2.74E-06 0.29 Yes

Furnace Aluminum Metals Zinc lbs/ton nroduction EF .. None 6 3.51 E-04 3.17E-04 1.00 Yes

6-35

TABLE A6-4a. AIR POLLUTION CONTROL SYSTEM COMPARISON (t-s1alistics).

Group Category Substance EFUnit Value Type First Samnle Statistics Second SamDle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at APC Svstem Deviation Ratio APC Svstem Deviation Ratio 95%Confidenci

Furnace Aluminum voe Benzene lbs/ton nroduction EF • •• t'-iz None 3 B.OOE-06 O.OOE•OO 0.00 No Furnace Aluminum voe Fonnaldehvde lbs/ton oroduction a= None 3 2.56E-04 9.06E·OS 1.00 Yes

Furnace. Aluminum voe Hvdronen Sulfide lbs/ton oroduction EF None 9 7.95E-03 1.15E-02 1.00 Yes

Furnace Glass Metals Arsenic lbs/ton oroduction EF Fr 3 3.70E-05 8.17E-06 1.00 None 6 2.28E-04 1.92E-04 1.00 No Furnace Glass Metals Chromium lbs/ton oroduction EF Fr 3 t .60E-05 1.67E-05 1.00 None 6 2.06E-04 1.45E-04 1.00 No Furnace Glass Metals Chromium !Hex) lbs/ton nroduction 8' Fr 3 4.09E·06 1.42E-07 0.00 Nono 9 1.02E-03 1.56E-03 0.99 No Platinn Anodizinn Metals Chromium mn/amn-hr 8' DM/WS/FF 4 4.14E-03 2.0BE-04 0.00 ws 7 3.70E-01 3.99E·01 1.00 No Platinn. Anodizinn Metals Chromium tHex\ mn/amn-hr 8' DM/WS/FF 2 4.15E-02 9.41E-04 0.00 ws 7 2.64E-01 3.09E-01 1.00 No Plating, Hard Metals Chromium mg/amp-hr 8' DM 1 5.BOE-02 1.00 DM'PB 1 3.50E-02 1.00 NA Plating, Hard Metals Chromium mg/amp-hr 8' i~;:!;; J~P 'la",•"'- :~~ i.t-l1l1!0\., DM/WS/FF 6 8.23E-04 6.20E-04 0.63 Yes

Plating, Hard Metals Chromium mg/amp-hr 8' DM 1 S.BOE-02 1.00 DM/WS/PB 2 3.76E-02 4.19E-03 1.00 No Plating, Hard Metals Chromium mg/amp-hr 8' DM 1 5.80E·02 1.00 ws 9 4.26E-02 1.84E-02 0.45 No Plating, Hard Metals Chromium mg/amp-hr 8' ;:-9;. ;il!1'f ct~,. .,,,,,,,,, ,;1Jji .. DM/WS/FF 6 8.23E-04 6.20E·04 0.63 Yes Plating, Hard Metals Chromium mg/amp-hr 8' DM'PB 1 3.SOE-02 1.00 DM/WS/PB 2 3.76E-02 4.19E-03 1.00 No Plating, Hard Metals Chromium mg/amp-hr 8' DM'PB 1 3.50E-02 1.00 WS 9 4.26E-02 1.84E-02 Ii; No Plating, Hard Metals Chromium mg/amp-hr 8' DM/WS/FF 6 8.23E-04 6.20E-04 0.63 :--- Yes Plating, Hard Metals Chromium mg/amp-hr 8' DM/WS/FF 6 8.23E-04 6.20E-04 0.63 . Yes Platinn Hard Metals Chromium mo/amo-hr 8' DM/WS/PB 2 3.76E-02 4.19E-03 1.00 ws 9 4.26E-02 1.84E-02 0.45 No Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM 1 2.49E-02 . . 1.00 DM'PB 1 1.36E-02 1.00 NA Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' ;s;OIJJ;,3 i£f:) ~"~-- _. -~'\,_:;' _ '._~l-1J:'i ''ch: , .. ,\1Jji. DM/WS/FF 4 3.96E-03 1.63E-03 0.00 Yes Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM 1 2.49E-02 1.00 DM/WS/PB 2 2.80E-02 1.21 E-02 1.00 No Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM

'f~•-,' 2.49E·02 1.00 ws 9 1.75E-02 3.36E·03 0.29 No

Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' . . ,QM!Plfi ,f.1~2 ., ; 1-90 DM/WS/FF 4 3.96E-03 1.63E-03 0.00 Yes Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM'PB 1 1.36E-02 1.00 DM/WS/PB 2 2.80E-02 1.21E-02 1.00 No Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM'PB 1 1.36E-02 1.00 ws 9 1. 75E-02 3.36E-03 0.29 No Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM/WS/FF 4 3.96E-03 1.63E-03 0.00 ~-- _; i: ;~, ,,~. ~.· Yes Plating, Hard Metals Chromium (Hex) mg/amp-hr 8' DM/WS/FF 4 3.96E-03 1.63E-03 0.00 H''"-'WSili • :•~Y ->i-.a•,•· <• Yes . . ,i.-"" .... ~.: ·' . ",

Platino, Hard Metals Chromium (Hex\ ma/amo-hr 8' .. - .. ..02 ws 9 1.75E-02 3.36E-03 0.29 Yes SG Crude Oil Metals Arsenic lbs/Maal 8' None 3 6.86E-04 9.78E-05 1.00 S02 Scrub 6 1.15E-03 1.01E-03 1.00 No SG Crude Oil Metals Beivllium lbs/Mnal 8' None 3 5.12E-05 6. 7BE-06 0.00 ,,, .. ..

?<,~ ni• Yes SG Crude Oil Metals Cadmium lbs/Mnal 8' None 3 2.81 E-05 6. 72E-06 1.00 S02 Scrub 6 2.30E-04 1.63E-04 1.00 No SG Crude Oil Metals Chromium lbs/Mnal 8' None 3 2.1BE-04 8.24E-05 1.00 S02 Scrub 6 1.18E-03 6.81 E-04 1.00 No SG. Crude Oil Metals Chromium fHex\ lbs/Mnal 8' None 3 9.26E·OS 2.81E-06 0.00 S02 Scrub 6 2.01E-04 9.32E-05 0.58 No SG. Crude Oil Metals Conner lbs/Maal 8' None 3 6.46E-04 2.89E-04 1.00 S02 Scrub 6 1.17E-03 4.57E-04 1.00 No SG, Crude 0,1 Metals Lead lbs/Maal 8' ~--· .:;t:-~ '"'♦-.ml!!.lli . ' ~, . ~-- S02 Scrub 6 2.37E-04 3.47E-05 0.15 Yes SG Crude Oil Metals Man□anese lbs/Maal 8' None 1 2.44E-04 1.00 S02 Scrub 6 3.49E-03 1.64E-03 1.00 No SG Crude Oil Metals Mercurv lbs/Mnal 8' None 1 3.60E-05 1.00 S02 Scrub 6 2.55E-03 2.76E-03 1.00 No SG Crude Oil Metals Nickel lbs/Mnal 8' None 3 3.72E-01 2.53E-02 1.00 S02Scrub 6 3.55E-01 1.82E·02 1.00 No SG Cnide Oil Metals Selenium lbs/Moal 8' None 3 4.41E-04 9.79E-05 1.00 S02 Scrub 6 1.SSE-03 1.45E-03 0.96 No SG. Cn.ide Oil Metals Zinc lbs/Maal 8' None 3 3.28E·02 3.26E-02 1.00 S02Scrub 6 1.05E-01 1.20E-01 0.93 No SG. Cn1de Oil PAH Acenanhthvlene lbs/Maal 8' None 3 B.63E-06 8.44E·06 1.00 S02 Scrub 6 6.91 E-06 5.71E-06 0.13 No SG, Crude Oil PAH Anthracene lbs/Maal 8' None 2 1.29E-05 1. 72E-05 1.00 S02 Scrub 6 5.95E-06 8.68E-06 1.00 No SG Crude Oit PAH Benzo(a\anthracene lbs/Maal 8' None 2 3.16E-06 2.49E-06 1.00 S02 Scrub 6 9.27E-06 5.58E-06 0.35 No SG Crude Oil PAH Chrvsene lbs/Mnal 8' None 3 1.37E-05 1.81E-05 1.00 S02 Scrub 6 9.90E-06 6.18E-06 0.40 No SG Crude Q;I PAH Fluoranthene lbs/Mnal 8' None 3 5.66E-06 8.23E-07 1.00 S02 Scrub 6 1.68E-05 1. 79E-05 0.64 No SG Crude Q;I PAH Fluorene 1bs/Mnal 8' None 3 1.70E·05 1.99E-05 1.00 S02 Scrub 6 1.28E-05 1.65E-05 1.00 No SG Crude Oil PAH Naohtha1ene lbs/Mnal 8' None 2 4.0BE-04 1.61E-04 1.00 S02 Scrub 6 9.26E-04 7.08E-04 1.00 No SG Crude Oil PAH Phenanthrene lbs/Moal 8' None 3 4.67E-06 4.25E-06 1.00 S02Scrub 6 3.50E-os 6.27E-05 1.00 No SG Crude Oil PAH Pvrene lbs/Maal 8' ,~,w.=. Rim\ = . S02 Scrub 6 1.19E-05 B.93E-06 0.50 Yes

&-36

TABLE A6-5a. CONTRACTOR COMPARISON (!-statistics).

jGroup Category! Substance EFUnrt Value Type First Sam le Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at Con_!ractor Deviation Ratjo Q_ontractor Deviation flatiQ. __ !}~%CQflf_idencel

!Asphalt Prod., Diesel ~etals [Arsenic [lbs/ton production[EF V I 2 I 5.26E-06 I 7.65E-07 I 0c90 I Other I 7 I 1.29E-06 I 2.97E-06 I 0.02 I No [Asphalt Prod., Die~I -~etals [Beryllium [lbs/Ion produc{ion[EF V I 2 5.17E-07 5.77E-08 I 0.00 I Other I 7 I 8.70E-07 __ L1.40E-06 I 0.00 I No Asphalt Prod., Diesel IJ,,etals [Cadmium [lbs/ton production[EF V I 2 1.51E-06 7.86E-07 I 0.68 I Other I 5 I 9.22E-06 I 1.95E,05 I 1,0_0_ I lllo iA§llhalt Prod., Diesel I Metals [Chromium [lbs/ton productionlEF V I 2 I 3.15E-06 I 3.04E-07 I 1.00 I Other I 7 I 1.31E-05 I 3.14E-05 I 1.00 I No A~Prod.,Dies.i>.I ~etals [Chromium{Hex) [lbs/ton productionlEF I V 2 I 1.68E-06 I 6.04E-08 I 0.00 I Other I 6 I 2.23E-07j 1.82E-07 I 1.00 I Yes Asph'!I\ Prod,,.Diesel Wetals 1<::.opQM [lbs/ton productionlEF I V I 2 5.45E-07 I 9.71E-08 I 0.56 I Other I 6 I 2.31E-05 I 5.35E-05 J L0Q_l IIIQ. A.<nhalt Prod., Diesel I Metals [Lead [lbs/ton production[EF V I 2 3.12E-06 I 1,11E-06 I 0.63 I Other I 7 I 3.14E-04 I 8.26E-04 I 1.00 I No

lbs/ton roduction EF V 2 1.86E-05 1.34E-05 1.00 Other 7 2.39E-04 6.16E-04 1.00 No lbs/ton roduction EF Other 7 4.38E-07 3.69E-07 0.29 Yes

Nickel lbs/ton roduction EF V 2 5.26E-06 7.65E-07 0,00 Other 7 5.58E-05 1.43E-04 0.00 No Selenium lbs/ton production a= V 2 5.26E-06 7.65E-07 0.00 Other 7 L76E-06 2.81E-06 0.14 No

Asphalt Prod., ~sel~et~ls [Zin.,:_ I lbs/ton production[a= V I 2 I 6.62E-05 I 1.34_E-05 __ L LO!Ll Other I 7 I 6.71E-04 I 1.74E-03 I 1.00 I No AJ;Qhalt PJ:Q.d., Diesel .....Jf>AH [Acenaphthen..l>. [lbs/ton production[EF V I 2 1.22E-06 I 2.17E-07 I 0.00 I Other I 6 2.51E-07 I 3.66E-07 I 1.00 I Yes

lbs/ton V 2 1.22E-06 2.17E-07 0.00 Other 6 1.78E-07 2.44E-07 1.00 Yes lbs/ton ·• '' ~ Other 6 2.45E-08 1.0BE-08 1.00 Yes

AsphJ!ll Prod., Dies~/11:1 [Benzo[a)l!l)\hracene [lbs/ton productionlEF I V 2 I 1.22E-06 2.17E-07 0.00 I Other I 6 I 3.38E-08 3,40E-08 I 1.00 I Yes Asp_t@lt Prod., Die~I . ..lPAH [Benzo(;!)pyren.i>. [lbs/ton production[EF I V I 2 1.22E-06 I 2.17E-07 I 0.00 I Other I 6 I 1.55E-09 I 1.64E-09 I 1.00 I Yes Aspb'!I\ Prod., Diesel .......lPAH IB.~nzo{g,h,i)peryl.l>_ne [lbs/ton production[EF V I 2 I 1.22E-06 I 2.17E-07 I 0.00 I Other I 6 I 1.20E-09 I 8.77E-10 I 0.39 I Yes Asphalt Prod." Diesel lf'll!:i [Ben.?_o(k)fluoranth.i>.ne [lbs/ton production[EF I V ..l 2 I 1.22E-06 I 2.17E-07 I 0.00 I Other I 6 I 3.13E-09 I 2.97E-09 I L0.2. J ~Y@!; Asphalt Prod~sel_..........lPll!:i [Ch'Y§_ene [lbs/ton production!Jf'.. V I 2 I 1.22E-06 I 2.1_7'E-07 I 0.00 I Other I 6 I 1.41E-08 I 1.61E-0B 1 LOO~] YE!". Asph_all Prod., Diesel ........JpAH ]Qibenz(a,h)i,nthracene ..1!1/.sitgn production]EF .L V I 2 I 1.22E-06 I 2.11.E:QLLJ.00 I Other I 6 I 9.74E-10 I 1.02E-09 I 0.00 I Yes Asp~lt Prod., Diesel jpAH [FluorantheD.f!. [lbs/ton production[EF I V I 2 I 1.22E-06 2.17E-07 I 0.00 I Other I 6 I 1.52E-07 I 7.60E-08 I 1.00 I Yes Asphalt Prod,, Diesel jpAH [Fluore_n_.l>. [lbs/ton production[EF I V I 2 1.22E-06 2.17E-07 I 0.00 I Other I 6 I 5.81E-07 I 4.02E-07 j 1cQ0 No

!As halt Prod. D~esel PAH Other 6 1.18E-09 1.02E-09 0.38 Yes As halt Prod. Diesel PAH Other 6 2.91 E-05 2.69E-05 1.00 Yes As halt Prod. Diesel PAH Other 6 6.75E-07 2.52E-07 1.00 Yes Asphalt Prod., D[g_sel PAJ-1 .--~--+~-+~=~=-+- __ Qt@r 6 1.13E-07 6.07E-08 1.00 ____ Yes Asphalt Prod., Diesel Lvoc !Benzene [lbs/ton production[EF j V I 2 I 2.21E-05 7.81E-06 I 0.63 I Other 7 7.17E-03 I 7.93E-03 I 0.94 J ___ Ng_ AsphaJl Prod., Diesel Jvoc [Formald<ehyde [lbs/ton productionlEF I V I 2 6.12E-05 1.53E-05 I 1.00 I Other I 6 I 1.SBE-04 I 8.67E-05 .l 1.00 I No Asphatt Prod., Natural Gas ]Metals I Arsenic I lbs/ton product[<>.nl EF I V I 5. l 1.82E-05 I 2.94E-05 I 0.77 I Other I 9 I 6.69E-07 I 6.02E-07_j_ 0.00 I No Asphalt Prod, Natural Gas I Metals I Beryllium I 11:>slton productionJl;E I V I 5 I 6.12E-07 I 5.B0E-07 I 0.00 I Other I 9 I 8.32E-07 I 6.21 E-07 LQ.,00 J.~ ____ IIIQ.

I As halt Prod. Natural Gas Metals Cadmium lbs/ton roduction e= Other 9 1.78E-06 2.37E-06 0.79 No As halt Prod. Natural Gas Metals Chromium lbs/ton roduction s= Other 9 9.92E-07 3.67E-07 0.67 Yes As halt Prod. Natural Gas Metals Chromium Hex lbs/ton roduction s= Other 9 4.47E-07 4.22E-07 0.27 Yes A.§Qhalt Prod., Natural Gas Metals Copp~{ lbs/ton produc:t_j__Q_n e= -'-"C...-""'-'=-=--1- Other 9 3.27E-06 1.31E-06 0.72 No Asph~lt Prod., Natural Gas]Metals [Lead [lbs/ton production]la' I V I 5_ J 2.36E-05 I 4.69e-~_LJJl.1 I Other I 9 I 4.36E-06 I 6.66E-06 I 1.00 I No Asphalt Prod., r-i_atural Gl!li_Metals [MJ!nQanese [lbs/ton production[EF l V I 5 8.3BE-05 I 9.63E-05 I 1.00 I Other I 9 I 2.00E-05 I 1.37E-05 __ i....LQQ I ~-.J'JQ.

lbs/ton roduction EF V 5 9.S0E-07 6.83E•07 1.00 Other 9 1.0SE-05 1.24E-05 No lbs/ton production e= ~ Other 9 3.63E-06 3.26E-0_9__ Yes

As halt Prod. Natural Gas Metals Selenium lbs/ton 3.01E-05 5.SSE-05 0.86 Other 9 6.68E-07 6.0lE-07 0.00 No As halt Prod. Natural Gas Metals Zinc lbs/ton Other 9 1.30E-05 6.04E-06 1 .00 Yes Aspl!'11! Prod., Natural Gas[PAH [MeD_aJ)hthene ]IIJ§'ton_production[EF V I 5 I 5.77E-07 5.27E-07 I 0.00 I Other I 9 I 6.40E-07 I 4.0BE_-_Q.7 I 1.00 I No Asphalt Prod., Natural G_~AH [Acenaphthylene Jibs/ton productionJEF I V J 5 I 5.77E-07 I 5.27E-07 I 0.00 I Other I 8 I 1.72E-06 I 3.61E-06 __ 1....LQQ L........l'J9. Asphalt Prod., Natural Ga~[PAH [Anthrace® [lbs/ton production]EF V I 5 I 5.77E-07 I 5.27E-07 I 0.00 I OtheL...J ... 9 I 1.BBE-07 I _3c03E-07 I 1.00 I .......J'!9. Asi:>halt Prod., Natural Gas]PAH [Benzo(a)anthrace_ne [l~ton production[EF V I 5 I 5.77E-07 I 5.27E-07 0.00. I Other I 6 I 1.12E-08 I 2,54E-09 I 1.00 I Yes Asphalt Prod, Natural Gas I PAH I Benzo[a)pyrene I lbs/ton production I EF I V __ [ 5 I 5.77E-07 I 5.27E-07 I 0.00 I Ot~e.r I 6 I 1.15E-09 I 3.82E-1 ~ I .. . .'!.<!". Asphalt Prod., Natural G<:1§.[PAH [Benzo{b}fl_l,oranthene [lbs/ton production[EF I V I 5 I 5.77E-07 I 5.27E-07 I 0.00 I Other I 6 I 1.67E-09 j 1._sgE-09 I 0.90 I Yes Asphalt Prod., Natural Gas [PAH [Benzo(Q,h,i)perylene [lb§'ton production[EF V I !; l !;.77E-07 I 5.27E-07_.l. o.oo_j Other I 6 I 1.44E-09 I 3.6§~-10 I 0.57 I Yes

6-37

TABLE A6-5a. CONTRACTOR COMPARISON (I-statistics).

Group Category Substance EF Unrt Value Type First Samole Statistics Second Samole Statistics Significant

Description Size Average Standard Detect Description Stze Average Standard Detect Difference at

Contractor Deviation Ratio Contractor Deviation Ratio 95%Confidence

Asohalt Prod. Natural Gas PAH Benzotk\fluoranthene lbs/ton croduction a= V 5 5.77E-07 5.27E-07 0.00 Other 6 2.67E-09 1.58E-09 0.77 Yes

Asohalt Prod. Natural Gas PAH Ch--ene lbs/ton nroduction a= V 5 5.77E-07 S.27E-07 0.00 Other 6 1.75E-09 7.87E·10 0.64 Yes

Asnhalt Prod. Natural Gas PAH dibenzfa h\anthracene lbs/ton nroduction a= V 5 S.77E-07 5.27E-07 0.00 Other 6 1.09E-09 5.37E-10 0.38 Yes

Asnhalt Prod. Natural Gas PAH Fluoranthene lbs/ton oroduction a= V 5 5.77E•07 S.27E-07 0.00 Other 9 4.56E-07 1.18E-06 1.00 No

Asohalt Prod. Natural Gas PAH Fluorene lbs/ton oroduction a= V 5 1.80E-06 6.16E-07 0.74 Other 9 1.72E-06 8.90E-07 1.00 No

Asohalt Prod .. Natural Gas PAH lndenot1 2 3•cd'"·"rene lbs/ton oroduction a= V 5 5.77E-07 5.27E-07 0.00 Other 6 1.29E-09 4.93E-10 0.52 Yes

Asahalt Prod.- Natural Gas PAH N2nhthalene lbs/ton nroduction a= ··:··;;·:\ :?,, Other 9 2.48E-05 2.39E-05 1.00 Yes

Asnhalt Prod. Natural Gas PAH Phenanthrene lbs/ton nroduction a= V 5 3.01E-06 1.17E-06 1.00 Other 9 2.45E-06 2.15E-06 1.00 No

Asnhalt Prod. Natural Gas PAH Pvrene lbs/ton aroduction a= V 5 5.81E-07 5.23E-07 0.07 Other 9 8.39E-07 2.32E-06 1.00 No

As oh alt Prod .. Natural Gas voe Benzene lbs/ton nroduction a= V 4 6.57E-05 8.48E-05 1.00 Other 9 8.98E-05 1.21 E-04 1.00 No

Asnhalt Prod. Oil Metals Arsenic lbs/ton nroduction a= V 2 8.52E-06 1.19E-06 0.00 Other 3 2.37E-06 1.60E-06 1.00 Yes

Asnhalt Prod. Oil Metals Ben•llium lbs/ton oroduction a= V 3 7.94E-07 1.12E-07 0.00 Other 3 4.16E-07 2.80E-08 0.00 Yes

Aschalt Prod. Oil Metals Cadmil.m lbs/ton oroduction a= V 3 2.02E-06 5.43E-07 0.43 Other 3 7.67E-07 9.69E-07 0.82 No

Asohalt Prod. Oil Metals Chromium lbs/ton nroduction a=

-Other 3 9.04E-06 7.40E-06 1.00 No

Asnhalt Prod. Oil Metals Chromium (Hex) lbs/ton nroduction a= Other 3 1.04E-07 3.14E-08 1.00 Yes

Asnhalt Prod. Oil Metals Conner lbs/ton oroduction a= Other 3 6.01E-06 2.96E-06 1.00 Yes

Asohalt Prod. Oil Metals Lead lbs/ton oroduction a= .

Other 3 1.41E-06 5.S0E-07 1.00 Yes

Asohalt Prod. Oil Metals M ...... ,. ...... ,.se lbs/ton oroduction a= 0 Other 3 1.40E-04 7.79E-05 1.00 No

Asohalt Prod. Oil Metals Mercu~ lbs/ton nroduction a= .

Other 3 7.02E-06 5.71E-06 1.00 Yes

Asnhalt Prod. Oil Metals Nickel lbs/ton nroduction a= Other 3 8.42E-06 2.63E-06 1.00 Yes

Asnhalt Prod. Oil Metals Selenium lbs/ton oroduction a= V 3 2.71E05 3.22E05 0.79 Other 3 2.08E-07 1.40E-08 0.00 No

Asnhalt Prod. Oil Metals Zinc lbs/ton oroduction a= ·v .. • , ·<;.'~ Other 3 2.52E-05 8.55E-06 1.00 Yes

Asohalt Prod. Oil PAH Acenanhthene lbs/ton nroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 3.06E-07 8.20E-08 1.00 Yes

Asohalt Prod. Oil PAH Acenanhthvlene lbs/ton nroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 5.26E-07 2.35E-07 1.00 No

Asnhalt Prod. OH PAH Anthracene lbs/ton oroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 5.74E-08 1.78E-08 1.00 Yes

Asnhalt Prod. Oil PAH Benzo'a\anthracene lbs/ton oroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 1.11E-08 2.14E-09 1.00 Yes

Asohalt Prod Oil PAH Benzofa\ ... , rene lbs/ton nroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 1.84E-09 1.84E-09 0.72 Yes

Asohalt Prod. Oil PAH Benzotn h iloervlene lbs/ton nroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 1.20E-09 2.59E-10 0.75 Yes

Asohalt Prod. Oil PAH Benzo1k\fluoranthene lbs/ton oroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 8.17E-10 7.87E-11 0.00 Yes

Asnhalt Prod. Oil PAH Ch"•sene lbs/ton oroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 8.17E-10 7.87E-11 0.00 Yes

Asnhalt Prod. Oil PAH dibenzra h1anthracene lbs/ton oroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 8.17E-10 7.87E-11 0.00 Yes

Asohalt Prod Oil PAH Fluoranthene lbs/ton nroduction a= V 3 6.13E-07 1.17E-07 0.00 Other 3 3.57E-08 9.68E·09 1.00 Yes

Asohalt Prod. Oil PAH Fluorene lbs/ton nroduction a= V 3 9.14E-07 1.83E-07 1.00 Other 3 6.58E-07 2.07E-07 1.00 No

Asohalt Prod. Oil PAH lndeno'l 2 3-cd\nvrene lbs/ton oroduction a= V -~ ~ Other 3 8.17E-10 7.87E-11 0.00 Yes

Asnhalt Prod. Oil PAH Nanhthalene lbs/ton oroduction a= .·v .•. Cf, ·•· Other 3 3.08E·0S 2.70E-06 1.00 Yes

Asohalt Prod. Oil PAH Phenanthrene lbs/ton nroduction a= ··• .• Other 3 6.64E-07 2.18E-07 1.00 Yes

Asohalt Prod. Oil PAH Pvrene lbs/ton nroduction a= V 3 6.13E-07 1.17E 07 0.00 Other 3 5.62E-08 2.23E-08 1.00 Yes

Asnhalt Prod. Oil voe Benzene lbs/ton oroduction a= V 3 2.02E-05 5.00E-06 0.71 a ' ..

Yes

Asnhalt Prod., Oil voe Formaldehvde lbs/ton oroduction a= V 3 I 3.22E-04 2.07E-04 1.00 Other 3 1.38E-04 2.29E-05 1.00 No

6-38

TABLE A6-6a. FUEL REGION COMPARISON {!-statistics).

Group Category Substance EFUnit Value Type First Samnle Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

Reaion Deviation Ratio Rooion Deviation Ratio 95%Contidence

ICE Natural Gas PAH Acenaohthene lbs/MMcf 8' Central 12 1.1 0E-03 1.13E-03 1.00 Southern 3 7.17E-04 2.14E-04 1.00 No

ICE. Natural Gas PAH Acenanhthvlene lbs/MMe! 8' Central 12 9.12E-03 9.32E-03 1.00 Southern 3 7.59E-03 3.15E-03 1.00 No

ICE. Natural Gas PAH Anthracene lbs/MMcf 8' Central 12 6.86E-04 7.80E-04 1.00 Southern 3 2.56E-04 1.06E-04 1.00 No ICE, Natural Gas PAH Benzo(a)anthracene lbs/MMcf 8' Central 12 6.04E-04 8.83E-04 1.00 Southern 3 7.78E-05 1.84E-05 1.00 No

ICE Natural Gas PAH Benzo(a\..,,.,rene lbs/MMe! 8' Central 12 1.03E-04 1.35E-04 0.99 Southern 3 3.55E-05 1.42E-05 0.76 No ICE. Natural Gas PAH Benzo(b\fluoranthene lbs/MMcf 8' Central 12 6.53E-04 1.10E-03 1.00 Southern 3 3.27E-04 5.22E-04 0.95 No ICE. Natural Gas PAH Benzoto.h i\oervlene lbs/MMcf 8' Central 12 5.40E-04 8.5BE-04 1.00 Southern 3 1.03E-04 1.35E-04 1.00 No ICE Natural Gas PAH Benzolklfluoranthene lbs/MMe! 8' Central 12 1.35E-04 1.84E-04 1.00

'2~ ,'• ':.k ,,~,

" Yes

ICE. Natural Gas PAH Chrvsene lbs/MMe! 8' Central 12 3.89E-04 6.87E-04 1.00 Southern 3 9.64E-05 2.63E-05 1.00 No ICE Natural Gas PAH dibenzfa h)anthracene lbs/MMe! 8' Central 12 2.91 E-05 4.48E-05 0.95 Southern 3 1.09E-05 3.86E-06 1.00 No ICE Natural Gas PAH Fluoranthene lbs/MMcf 8' Central 12 1.60E-03 1.97E-03 1.00 Southern 3 2.50E-04 9.05E-05 1.00 No

ICE. Natural Gas PAH Fluorene lbs/MMe! 8' Central 12 4.30E-03 4.24E-03 1.00 Southern 3 4.60E-04 1.50E-04 0.00 No

ICE Natural Gas PAH lndenol1 2 3-cd'~--rene lbs/MMcf 8' Central 12 4.54E-04 7.15E-04 1.00 Southern 3 1.20E-04 1.52E-04 1.00 No

ICE Natural Gas PAH Nanhthalene lbs/MMcf 8' Central 12 1.11E-01 1.27E-01 1.00 Southern 3 1.22E-01 8.93E-02 1.00 No ICE Natural Gas PAH Phenanthrene lbs/MMe! 8' Central 12 8.73E-03 1.05E-02 1.00 Southern 3 8.93E-04 3.36E-04 1.00 No ICE Natural Gas PAH Pvrene lbs/MMe! 8' Central 12 2.15E-03 2.70E-03 1.00

-No

ICE Natural Gas voe Aeetaldehvde lbs/MMe! 8' Central 12 3.69E-01 7.46E-01 0.90 Yes

ICE Natural Gas voe Acrolein lbs/MMcf 8' Central 12 1.92E-01 2.38E-01 0.89 Yes

ICE Natural Gas voe Benzene lbs/MMcf 8' Central 12 6.76E-01 7.97E-01 1.00 No

ICE Natural Gas voe Formaldehvde lbs/MMe! 8' Central 12 3.55E+00 6.68E+00 1.00 Yes »

ICE Natural Gas voe Proovlene lbs/MMe! 8' Central 12 5.13E+00 4.03E+00 1.00 ' Yes

ICE Natural Gas voe Toluene lbs/MMe! 8' Central 12 3.82E-01 3.81E-01 1.00 Southern 16 6.75E-01 7.31E-01 1.00 No

Turbine Nautral Gas PAH Acenaohthene lbs/MMe! 8' Central 15 2.16E-05 3.77E-05 0.13 Northern 3 6.07E-06 1.23E-06 0.72 No

Turbine, Nautra1 Gas PAH Acenanhthvlene lbs/MMe! 8' Central 15 1.66E-05 3.01 E-05 0.38 Northern 3 5.45E-06 6.04E-07 0.69 No

Turbine. Nautral Gas PAH Anthracene lbs/MMcf 8' Central 15 3.62E-05 5.1BE-05 0.44 Northern 3 2.17E-05 1.55E-05 0.92 No

Turbine Nautral Gas PAH Benzo( a)anthracene lbs/MMcf 8' Central 15 2.61 E-05 4.93E-05 0.04 Northern 3 4.95E-06 7.92E-08 0.00 No

Turbine. Nautral Gas PAH Benzota 1 .... "rene lbs/MMe! 8' Central 15 1.57E-05 2.95E-05 0.39 Northern 3 4.95E-06 7.92E·0B 0.00 No

Turbine, Nautral Gas PAH Benzo(b\fluoranthene lbs/MMe! 8' Central 15 1.25E-05 2.15E-05 0.05 Northern 3 4.95E-06 7.92E-08 0.00 No

Turbine Nautral Gas PAH Benzola,h i\oerulene lbs/MMcf 8' Central 1 5 1.55E-05 2.76E-05 0.01 Northern 3 4.95E-06 7.92E-0B 0.00 No

Turbine, Nautral Gas PAH BenzolkHluoranthene lbs/MMcf 8' Central 15 1.22E-05 2.16E-05 0.02 Northern 3 4.95E-06 7.92E-08 0.00 No

Turbine, Nautral Gas PAH Chrvsene lbs/MMe! 8' Central 15 2.92E-05 5.31 E-05 0.06 Northern 3 4.95E-06 7.92E-08 0.00 No

Turbine Nautral Gas PAH dibenz(a,h'anthracene lbs/MMe! 8' Central 15 2.73E-05 5.11E-05 0.00 Northern 3 4.95E-06 7.92E-08 0.00 No

Turbine, Nautral Gas PAH Fluoranthene lbs/MMe! 8' Central 15 4.94E-05 9.0BE-05 1.00 Northern 3 1.1 BE-05 5.95E-06 1.00 No

Turbine, Nautral Gas PAH Fluorene lbs/MMcf 8' Central 15 6.38E-05 1.22E-04 1.00 Northern 3 2.90E-05 2.33E-05 1.00 No

Turbine Nautral Gas PAH lndenot1 2 3-cd\""'"rene lbs/MMe! 8' Central 15 2.73E-05 5.11E-05 0,01 Northern 3 4.95E-06 7.92E·0B 0.00 No

Turbine, Nautral Gas PAH Nanhthalene lbs/MMcf 8' Central 15 1.70E-03 2.49E-03 1.00 Northern 3 1.49E-03 2.27E-05 0.00 No

Turbine Nautral Gas PAH Phenanthrene lbs/MMcf 8' Central 15 3.57E-04 6.51E-04 1.00 Northern 3 9.17E-05 2.47E-05 0.74 No

Turbine Nautral Gas PAH Pvrene lbs/MMe! 8' Central 15 3.05E-05 4.06E-05 1.00 Northern 3 1.35E-05 B.84E-06 1.00 No

Turbine Nautral Gas svo:; Ethvlbenzene lbs/MMe! 8' Central 12 2.00E-02 1.62E-02 0.55 Northern 3 9.74E-03 9.48E-06 0.00 No

Turbine Nautral Gas voe Aeetaldehvde lbs/MMe! 8' Central 7 6.35E-02 1.02E-01 0.96 Northern 3 B.06E-02 2.82E-02 1.00 No Turbine, Nautral Gas voe Acrolein lbs/MMcf 8' Central 9 2.81 E-02 2.47E-02 0.79 Northern 3 1.05E-02 3.02E-04 0.00 No

Turbine, Nautral Gas voe Benzene lbs/MMcf 8' Central 1 5 1.54E-02 1.12E-02 0.53 Northern 3 9.28E-03 9.04E-06 0.00 No

Turbine, Nautral Gas voe Benzene lbs/MMe! 8' Central 1 5 1.54E-02 1.12E-02 0.53 Southern 3 8.71E-03 0.00E+00 0.00 No

Turbine Nautral Gas voe Benzene lbs/MMe! 8' Northern 3 9.28E-03 9.04E-06 0.00 Southern 3 8.71E-03 0.00E+00 0.00 Yes

Turbine, Nautral Gas voe Formaldehyde lbs/MMcf 8' Central 14 8.87E-02 7.10E-02 0.97 Northern - 6.69E-02 2.86E-02 0.82 No lbs/MMcf 8' Central 14 8.87E-02 -- it. ,~&";1rmr --

Turbine, Nautral Gas voe Formaldehyde 7.10E-02 0.97 t ' . w;,:,:,.,.--,.,,,__,,, Yes

6-39

TABLE A6-6a. FUEL REGION COMPARISON (!•statistics). -Group ICategoryl Substance IEFUnit !Value Typel F!rsg;J~~im:uii!~11Jm~11l~mmi;1m ..... Second Sam le Statistics Significant Size Average Standard Detect Difference at

Deviation Ratio 95%Confidenc

Turbine Nautral Gas voe lbs/MMcf EF Southern 5 2.94E+00 2.46E+00 1.00 No

Turbine Nautral Gas voe lbs/MMcf EF Northern 3 1.03E•02 1.88E·03 0.69 Yes Turbine Nautral Gas voe lbs/MMcf EF Northern 3 8.38E·03 2.35E·03 0.23 Yes Turb_ine, Nilutral Gas vex;_ lbs/MMe! EF Nonhern 3 1.66E·02 1.19E·03 1.00 Yes

6-40

TABLE A6-7a. METAL FURNACE COMPARISON (I-statistics).

Group I Category I Substance IEFUnit I Value Type! First Samole Statistics Second Samnle Statistics Significant 'Size I Average Standard Detect Description Size Average Standard Detect Difference at

Deviation Ratio Furnace T··-- Deviation Ratio 95%Confidence

Furnace, Aluminum Metals Beryllium lbs/ton production EF Dross 3 8.00E-05 O.OOE+OO 0.00 Melting Pot 3 4.00E-07 0.00E+OO 0.00 NA Furnace, Aluminum Metals Beryllium lbs/ton production EF Dross 3 8.00E-05 O.OOE+OO o.oo Reverb. 6 2.16E-05 9.26E-06 0.00 Yes

Furnace Aluminum Metals Bervllium lbs/ton nroduction EF Meltinn Pot 3 4.00E-07 O.OOE+OO 0.00 Reverb. 6 2.16E-05 9.26E-06 0.00 Yes

Furnace, Aluminum Metals Cadmium lbs/ton production EF Dross 3 4.37E-04 3.71 E-04 1.00 Melting Pot 3 1.73E-06 4.62E-07 1.00 No

Furnace, Aluminum Metals Cadmium lbs/ton production EF Dross 3 4.37E-04 3.71 E-04 1.00 Reverb. 6 9.36E-05 1.13E-04 0.95 No

Furnace Aluminum Metals Cadmium lbs/ton nroduction EF Reverb. 6 9.36E-05 1.13E-04 0.95 No

Furnace, Aluminum Metals Copper lbs/ton production EF Melting Pot 3 2.53E-06 1.01 E-06 1.00 Yes

Furnace, Aluminum Metals Copper lbs/ton production EF Reverb. 6 2.80E-04 3.00E-04 1.00 Yes

Furnace Aluminum Metals Conner lbs/ton nroduction EF Mellin Pot 3 2.53E 06 1.01 E 06 1.00 Reverb. 6 2.80E-04 3.00E-04 1.00 No

Furnace, Aluminum Metals Lead lbs/ton production EF ·~,,·__ ' ... '

Melting Pot 3 1.33E-06 2.31 E-07 1.00 Yes

Furnace, Aluminum Metals Lead lbs/ton production EF Dross 3 4.48E-04 6.97E-05 1.00 Reverb. 6 5.42E-04 6.57E-04 1.00 No

Furnace Aluminum Metals Lead lbs/ton nroduction EF Meltina Pot 3 1.33E-06 2.31E-07 1.00 Reverb. 6 5.42E-04 6.57E-04 1.00 No

Furnace, Aluminum Metals Manganese lbs/ton production EF :;110i:llt:itJl Melting Pot 3 6.95E-07 5.65E-07 1.00 Yes

Furnace, Aluminum Metals Manganese lbs/ton production EF Dross 3 1 .87E-04 4.03E-05 1.00 Reverb. 6 6.38E-03 1.52E-02 1.00 No

Furnace Aluminum Metals Mannanese lbs/ton nroduction EF Meltinn Pot 3 6.95E-07 5.65E-07 1.00 Reverb. 6 6.38E-03 1.52E-02 1.00 No

Furnace, Aluminum Metals Nickel lbs/ton production EF ~1 Melting Pol 3 8.00E-07 4.00E-07 1.00 Yes

Furnace, Aluminum Metals Nickel lbs/ton production EF Dross 3 2.51 E-04 8.81 E-05 1.00 Reverb. 6 2.33E-04 2.75E-04 1.00 No

Furnace Aluminum Metals Nickel lbs/ton nroduction EF Mellina Pot 3 8.00E-07 4.00E-07 1.00 Reverb. 6 2.33E-04 2.75E-04 1.00 No

Furnace, Aluminum voc Benzene lbs/ton production EF Dross 3 1.17E-02 1.27E-02 0.75 Melting Pot 3 8.00E-06 O.OOE+OO 0.00 No Furnace, Aluminum voc Benzene lbs/ton production EF Dross 3 1.17E-02 1.27E-02 0.75 Reverb. r 5.84E-02 2.95E-02 1.00 No

;;: <·.'.:<">-':\;;{, . ······.~ .... _ _,,.,,,,..,.,-._,, ,,,_ . ..,.,,,. Furnace Aluminum voc Benzene tbs/ton oroduction EF Meltina Pot 3 8.00E-06 0·&-11

-.-, Yes

Furnace, Aluminum voc Formaldehyde lbs/ton production EF ~a) ~j •-c1tM' "*~ Melting Pot 3 2.56E-04 9.06E-05 1.00 Yes

Furnace, Aluminum voc Formaldehyde lbs/ton production EF :>;u:1a.-R~;;: : ;};'' .. . Reverb. 3 8.88E-02 1.58E-02 1.00 Yes

Furnace Aluminum VOC Formaldehvde lbs/ton nroduction EF Meltina Pot 3 2.56E-04 9.06E-05 1.00 I> D ......... , $', ·-~.;:..:...;.:.:.:.· - -~' ,t,;:.~.: -· '"·,·- ...... : .. Yes

Furnace, Aluminum voc Hydrogen Sulfide lbs/ton production EF tlroes ?f':_: tiff -··aa:~1{:~•; Melting Pot 3 5.47E-04 2.31 E-05 1.00 Yes

Furnace, Aluminum voc Hydrogen Sulfide lbs/ton production EF 0,.;. ·.· :,., Reverb. 6 9.46E-02 7.82E-02 1.00 Yes

Furnace, Aluminum voe Hydrogen Sulfide lbs/ton production a= Melting Pot 3 5.47E-04 2.31 E-05 1_,00_ Reverb, 6 9.46E-Q<.. __ Ul2E:Q<... _LQQ No

6-41

TABLE A6-8a. SURFACE COATING APPLICATION COMPARISON (!•Statistics).

Group Category Substance EFUnit Value Type First Samole Statistics Second Samnle Statistics Significant Description Size Average Standard I Detect Description Size Average Standard Detect Difference at

Coatina Sorav Deviation Ratio Coatinn Snrev Deviation Ratio 95%Confidence

Coatina. Green Primer Me1als Chromium lbs/nal oaint s= Conventional 5 1.39E·03 7.64E·04 I 1.00 HVLP Snrav Gun 15 6.63E·04 6.73E·04 0.93 No

Coatinn. Green Primer Metals Chromium /Hex\ lbs/nal naint s= ; ' a

HVLP Snrav Gun 15 4.58E·04 5.36E·04 1.00 Yes

6--42

TABLE A6-9a. INTERNAL COMBUSTION ENGINE OXYGEN LEVEL COMPARISON (I-statistics).

Group Category! Substance EF Unit I Value Type First Sam le Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

Oxygen Level Deviation Ratio Oxygen Level Deviation Ratio 95%Confidence ICE, Diesel IPAH !Acenaphthene llbs/Mgal !EF __ !Oxygen< 13%1 12 j 6.71E-04 I 9.39E·04 I 0.90 !Oxygen> 13°;.j 12 I 2.36E-03 I 5.82E-03 I 1.00 I No ICE Diesel PAH lbs/M al EF 1 2 1.02E-03 5.28E-04 0. 95 No ICE Diesel PAH lbs/M al EF 12 2.23E-04 7.13E-05 0.69 Yes ICE Diesel PAH lbs/Mal EF 12 9.60E-05 1.16E-04 0.27 Yes ICE, Diesel PAH lbs/M al EF 12 7.92E-05 1.22E-04 o.os_~~o!!!!.~~:!!l....!...!e..l..._ No ICE.Diesel IPAH IBenzo(b)fluoranthene llbs/Mgal IEF __ IOxygen<13°/,l 12I 1.12E-04 I 1.20E·04 I 0.12 lOxygen>13%l 6 I 8.66E-05 I 6.76E-05 I 0.93 I No ICE.Diesel IPAH !Benzo(g,h,i)pervlene flbs/Mgal !EF !Oxygen< 13%112 f 9.0SE-05 I 1.19E-04 l 0.22 !Oxygen> 13%! 12 j 1.22E-04 I 1.40E-04 I 0.84 I No ICE, Diesel IPAH !Benzo(k)lluoranthene !lbs/Mgal !EF __ [Oxygen< 13"/,j 12 I 7.81E-05 I 1.23E-04 I 0.08 !Oxygen> 13°/,j 6 I 3.28E-05 I 1.74E-05 I 0.68 I No ICE, Diesel IPAH JChrvsene llbs/Mgal IEF !Oxygen< 13%1 12 l 1.30E-04 I 1.24E-04 I 0.46 _ ]OxyMrl__:•_J;!%l 12 l LSJ;!:-04_ I 1.86E-04 I 1.00 I No ICE Diesel PAH dibenz a h anthracene lbs/M 1 2 8.23E-05 No ICE Diesel PAH Fluoranthene lbs/M 12 3.29E-04 1.45E-04 Yes ICE Diesel PAH Fluorene lbs/M 12 9.62E-04 5.67E-04 Yes ICE, Diesel PAH lndeno(1,2,3-cd)pyrene lbs/M 1 2 8.47E-05 1.20E-04 No ICE Diesel PAH Na hthalene 1 2 1.60E-02 9.64E-03 1.00 No ICE Diesel PAH 1 2 3.53E-03 2.46E•03 1.00 Yes ICE Diesel PAH 1 2 2.63E-04 1. 72E-04 0. 73 Yes ICE Diesel Voe 3 3.47E-03 2.61 E-03 1.00 Yes ICE Diesel voe Acrolein 3 1.07E-03 6.19E-04 0.56 No ICE, Diesel voe Benzene Yes ICE,Diesel Ivoe !Formaldehyde llbs/Mgal IEF !Oxygen< 13%1 12 l 5.0SE-02 I 6.07E·02 I 1.00 !Oxygen> 13°/,l 12 I 1.04E-01 I 9.37E-02 I 1.00 I No ICE.Diesel Ivoe !Propylene llbs/Mgal IEF !Oxygen <13%1 6 I 3.41E-01 I 5.93E-02_L_J.oo !Oxygen> 13°/,l 6 I 3.58E-01 I 2.03E-01 I 1.00 I No ICE, Diesel IVoe !Toluene llbs/Mgal !EF __ !Oxygen< 13'/,l 6 I 6.12E-02 I 3.0IE-02 I 1.00 !Oxygen> 133/.l_JL_l_ 5,50~3!LI 2.10E-02 I 1.00 I No ICE. Diesel JVoe !Total Xylene libs/Mgal IEF !Oxygen< 13°/,l 6 I 2, 10E-02 I 7.79E·03 I 1.00 !Oxygen> 13%1 3 I 3.59E-02 I 1.48E-02 I 1.00 I No ICE, Field Gas JVoe !Benzene llbs/MMcl IEF Lean I 11 I 4.51 E+oo_J_4.42E±90 I 1.00 I Rich I 2 I 1.10E+01 I 1.26E-01 I 1.00 I No ICE, Field Gas JVOC I Formaldehyde Jlbs/MMcl IEF I Lean I t 5 J 4.52E+01 I 3.24E+01 I 1.00 I _ Rich LJ I 5.05E+00 I 8.04E-01 I 1.00 I No ICE, Field Gas JVoe lm,p-xylene llbs/MMcl IEF I Lean I 11 I 4.39E-01 I 4.07E-01 I 1.00 I Rich I 2 I 5.37E-01 I 3.62E-02 I 1.00 I No ICE,FieldGas IVoe lo-xylene llbs/MMcl IEF I Lean I 11 I 1.80E·0LL1.92E-01 I 1.00 I Rich I 2 I 2.68E-01 I 1.81E-02 I 1.00 I No ICE,FieldGas Jvoe !Propylene llbs/MMcl IEF I Lean I 11 [ 2.00E+01 I 1.07E+01 I 1.00 I F!__ich_ I 2 I 3.04E+00 I 0.00E+00 I 0.00 I No ICE,FieldGas Jvoe !Toluene llbs/MMcl IEF Lean I 11 J 1.72E+00_l__1J3E+00 I 1.00 I Rich I 2 I 3.44E+00 I 1.57E-01 I 1.00 I No

ICE, Natural Gas I PAH ICE Natural Gas PAH ICE, Natural Gas PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Na1ural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Na1ural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE, Natural Gas I PAH ICE Natural Gas PAH ICE, Natural Gas SVOC

Acenaphthene llbs/MMcl IEF Lean I 12 I 7.91E-04 l B.62E-04 I 1.00 I Rich I 3 I 1.94E-03 I 1.26E-03 I 1.00 I No Acena hth lene lbs/MMcl EF Lean 12 7.40E-03 8.82E-03 1.00 1.45E-02 1.74E·03 1.00 No Anthrace~ lbs/MMcf EF Lean 12 2.91E·04 __ 3.17E·04 1.00 __ ._ . . •i'fttllO/· Yes Benzo(a)anthracene llbs/MMcf IEF I Lean I 121 5.S0E-04 I 9.0BE-04 I 1.00 I Rich I 3 I 2.94E-04 I 4.08E-05 I 1.00 I No Benzo(a)pyrene !lbs/MMcl IEF I Lean I 12 I 8.36E•0§ I 1.38E-04 I 0.96 I Rich L~L1§Ec91 _ I 3.18E-05 I 1.00 I No Benzo(b)fluoranthene flbs/MMcf !EF _ I Lean I 12 I 6.76E-04 I 1.11E-03 I 0.99 I Rich I 3 I 2.37E-04 I 5.53E-05 I 1.00 I No Benzo(g,h,i)pervlene llbs/MMcf IEF I Lean I 12 I 5.17E-04 I 8.71E-04 I 1.00 I Rich I 3_J 1.95E-04 I 4.46E-05 I 1.00 I No Benzo(k)lluoranthene llbs/MMcl IEF I Lean I 12 I 2.42E-04 I 3"36E·04 I 0.99 I Rich I 3 I 1.03E-04 I 2.07E-05 I 1.00 I No Chrvsene ilbs/MMcl IEF I Lean J 12J 3.35E-04 I 6.99E-04 I 1.00 I Rich __ I 3 I 3.10E-04 I 7.71E-05 I 1.00 I No dibenz(a,h)anthracene_ llbs/MMcl IEF I Lean I 12 I 2.87E-05 I 4,SQ_E-05 I 0.95 I Rich I 3 I 1.25E-05 I 1.72E-06 I 1.00 I No Fluoranthene Jlbs/MMcf IEF I Lean I 12 I 1.41E-03 1 2,96_E·_03 I 1.00 I Rich_ I 3 I 9.95E-04 I 1.94E-04 I 1.00 I No Fluorene llbs/MM~I IEF I Lean I 12 I 2.68E-03 I 4.07E-03 I 0.96 I Rich I 3 I 6.91E·0;!_I 1.99E-03 I 1.00 I No lndeno(1,2,3-cd)pyrene !lbs/MMcl IEF I Lean I 12 I 4.42E-04 I 7.23E-04 I 1.00 I Rich I 3 1 1.69I;_:__D1_ I 3.43E-05 I 1.00 I No Naphthalene llbs/MMcl IEF I Lean I 12 I 1.23E-01 I 1.31E·01 I 1.00 I Rich l 3 I 7.65E-02 I 1.58E-02 I 1.00 I No Phenanthrene llbs/MMcf IEF I Lean I 12 J 7.19E-03 I 1.11E-02 I 1.00 I Rich I 3 I 7.07E-03 I 1.92E-03 I 1.00 I No p rene lbs/MMcf EF Lean 12 1.73E-03 2.84E-03 1.00 Rich 3 1.79E-03 7.53E-04 1.00 No Ethylbenzene lbs/MMcf EF ,,,.,,.. "' Rich 3 _ 1_.16E-02 3.13E-03 1.00 Yes

6-43

TABLE A6-9a. INTERNAL COMBUSTION ENGINE OXYGEN LEVEL COMPARISON (t-slatistics).

Group Category Substance EF Unit Value Type First Samele Statistics Second Sample Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

O,vnen Level Deviation Ratio O""nen Level Deviation Ratio 95%Confidence ICE Natural Gas voe 1 3-Butadiene lbs/MMcf EF Lean 9 7.70E-01 6.07E-01 1.00 Rich 3 1.04E-01 3.92E-04 1.00 No ICE Natural Gas voe Acetaldehvde lbs/MMcf EF Lean 24 2.67E+00 2.72E+00 0.99 Rich 6 8.83E-01 9.0SE-01 1.00 No ICE Natural Gas voe Acrolein lbs/MMcf EF Lean 23 1.02E+00 1.40E+00 0.99 Rich 6 7.94E-01 3.38E-01 1.00 No ICE Natural Gas voe Benzene lbs/MMcf EF Lean 23 1.0SE+0O 7.21E-01

'"~ No

ICE Natural Gas voe Formaldehvde lbs/MMcf EF Yes ICE Natural Gas voe m.o-xvlene lbs/MMcf EF Lean 14 8.63E-02 3.99E-02 1.00 Yes ICE Na1ural Gas voe o-xvlene lbs/MMcf EF Lean 14 4.94E-02 1.95E-02 0.95 Yes ICE Natural Gas voe Proovlene lbs/MMcf EF Lean 23 1.40E+01 1.69E+01 0.97 No ICE Natural Gas voe Toluene lbs/MMcf EF Lean 23 4.36E-01 2.67E-01

• LOO i ,.Jff;,

Yes ICE Natural Gas voe Total Xvlene lbs/MMe! EF

..• ... Rich I 3 I 6.02E-02 I 1.BSE-02 1.00 Yes

6-44

TABLE A6-10a. INTERNAL COMBUSTION ENGINE CAPACITY COMPARISON (!·statistics).

Group Category Substance EFUnit Value Type First Samele Statistics Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

Caoacitv Deviation Ratio Canacih, Deviation Ratio 95%Confidence

ICE Field Gas voe Benzene lbs/MMcf EF <650 Ho 10 5.84E+00 5.39E+00 1.00 >650 Hn 3 4.39E+00 1.91E-01 1.00 No

ICE Field Gas voe Formaldehvde lbs/MMcf EF <650 Ho 15 4.11E+01 3.36E+01 1.00 >650 Hn 3 2.58E+01 3.46E+01 1.00 No

ICE Field Gas voe m.o-xvlene lbs/MMcf EF <650 Ho 10 5.14E-01 4.09E·01 1.00 >650 Hn 3 2.54E-01 6.43E-02 1.00 No

ICE. Field Gas voe o-xvlene lbs/MMcf EF <650 Ho 10 2.20E-01 1.97E-01 1.00 >650 Hn 3 1.03E-01 3.41E-02 1.00 No

ICE. Field Gas voe Pronvlene lbs/MMcf EF <650 Ho 1 0 1.82E+01 1.32E+01 0.97 >650 Hn 3 1.47E+01 3.16E+00 1.00 No

ICE. Field Gas voe Toluene lbs/MMcf EF <650 Ho 1 0 2.1 lE+00 1.87E+00 1.00 >650 Hn 3 1.54E+00 1.15E+00 1.00 No

ICE Natural Gas PAH Acenaohthene lbs/MMcf EF <650 Ho 6 1.33E-03 1.05E·03 1.00 >650 Hn 9 8.15E-04 1.00E-03 1.00 No

ICE Natural Gas PAH Acenaohthvlene lbs/MMcf EF <650 Ho 6 1.l0E-02 4.40E·03 1.00 >650 Ho 9 7.33E-03 1.02E-02 1.00 No

ICE Natural Gas PAH Anthracene lbs/MMcf EF . ' .. ~->650 Hn 9 3.02E-04 3.67E-04 1.00 Yes

ICE Natural Gas PAH Benzota,anthracene lbs/MMcf EF <650 Ho 6 1.86E-04 1.22E·04 1.00 >650 Hn 9 7.07E-04 1.0lE-03 1.00 No

ICE Natural Gas PAH Benzofa '""rene lbs/MMcf EF <650 Ho 6 7.51E-05 4.87E·05 0.94 >650 Hn 9 9.96E-05 1.58E-04 0.98 No

ICE Natural Gas PAH Benzofblfluoranthene lbs/MMcf EF <650 Ho 6 2.82E-04 3.36E·04 0.97 >650 Hn 9 7.92E-04 1.25E-03 1.00 No

ICE Natural Gas PAH Benzo/oh i\oervlene lbs/MMcf EF <650 Ho 6 1.49E-04 1.03E-04 1.00 >650 Hn 9 6.55E-04 9.76E-04 1.00 No

ICE Natural Gas PAH BenzotkHluoranthene lbs/MMcf EF <650 Ho 6 3.16E-04 4.04E·04 0.98 >650 Hn 9 1.46E-04 2.14E•04 1.00 No

ICE Natural Gas PAH Chrvsene lbs/MMcf EF <650 Ho 6 2.03E-04 1.28E·04 1.00 >650 Ho 9 4.15E-04 8.02E-04 1.00 No

ICE Natural Gas PAH dibenz(a h\anthracene lbs/MMcf EF <650 Ho 6 1.17E-05 2.82E·06 1.00 >650 Hn 9 3.47E-05 5.12E-05 0.95 No

ICE Natural Gas PAH Fluoranthene lbs/MMcf EF <650 Ho 6 6.23E-04 4.30E·04 1.00 >650 Hn 9 1.80E-03 2.27E-03 1.00 No

ICE Natural Gas PAH Fluorene lbs/MMcf EF <650 Ho 6 3.69E-03 3.75E-03 0.94 >650 Hn 9 3.43E-03 4.50E-03 1.00 No

ICE Natural Gas PAH lndeno( 1 2.3-cd\nvrene lbs/MMcf EF <650 Ho 6 1.44E-04 1.02E-04 1.00 >650 Hn 9 5.49E-04 8.13E-04 1.00 No

ICE Natural Gas PAH Naohthalene lbs/MMcf EF <650 Hn 6 9.92E-02 6.25E-02 1.00 >650 Ho 9 1.23E-01 1.47E-01 1.00 No

ICE Natural Gas PAH Phenanthrene lbs/MMcf EF <650 Ho 6 3.98E-03 3.60E·03 1.00 >650 Hn 9 9.29E-03 1.23E-02 1.00 No

ICE Natural Gas PAH Pvrene lbs/MMcf EF <650 Ho 6 9.57E-04 1.03E·03 1.00 >650 Hn 9 2.27E-03 3.13E-03 1.00 No

ICE Natural Gas svoc Ethvlbenzene lbs/MMcf EF <650 Ho 3 1.16E-02 3.13E·03 1.00 <;•' .. Yes

ICE Natural Gas voe 1 3-Butadiene lbs/MMcf EF <650 Ho 3 1.04E-01 3.92E-04 1.00 >650 Hn 9 7.70E-01 6.07E-01 1.00 No

ICE Natural Gas voe Acetaldehvde lbs/MMcf EF ----- BI ;ai; ,--~: --s•;d;c,; >650 Hn 9 4.72E-01 8.47E-01 0.90 Yes

lbs/MMcf EF ·-·wu _,._ "-{/· ,··-·· >650 Hn ICE Natural Gas voe Acrolein 9 6.83E-02 6.76E-02 0.60 Yes

ICE Natural Gas voe Benzene lbs/MMe! EF <650 Ho 25 1.51 E+00 2.60E+00 1.00 >650 Hn 9 8.08E-01 8.91 E-01 1.00 No

ICE Natural Gas voe Formaldehvde lbs/MMcf EF ~-- 1,.'a<!fZl;,, -•t-- <

>650 Hn 21 4.24E+00 6.90E+00 0.94 Yes ., ICE Natural Gas voe Pronvlene lbs/MMcf EF <650 Ho 19 1.80E+01 2.01 E+0l 0.98 >650 Hn 9 6.71 E+00 3.32E+00 1.00 No

ICE Natural Gas voe Toluene lbs/MMcf EF <650 Ho 19 5.85E-01 7.0lE-01 1.00 >650 Hn 9 4.74E-01 4.02E-01 1.00 No

ICE Natural Gas voe Total Xvlene lbs/MMcf EF <650 Ho 3 6.02E-02 1.86E·02 1.00 'i ~

Yes

6-45

TABLE A6-11 a. INTERNAL COMBUSTION ENGINE STROKES PER CYCLE COMPARISON (I-statistics).

Group Category Substance EFUnit Value Type First Samole Statistics Second Samole Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Ditterence at

Strokes Deviation Ratio Strokes Deviation Ratio 95%Confidence

ICE, Field Gas voe Benzene lbs/MMcf s= 2S 5 7.85E+00 4.77E+00 1.00 4S 8 4.04E+0O 4.32E+0O 1.00 No ICE. Field Gas voe Formaldehyde lbs/MMcf s= 2S 6 5.09E+01 3.55E+01 1.00 4S 12 3.24E+01 3.18E+01 1.00 No ICE, Field Gas voe m.o-xvlene lbs/MMcf s= 2S 5 6.04E-01 4.BBE-01 1.00 4S 8 3.60E-01 2.77E-01 1.00 No ICE. Field Gas voe o-xvlene lbs/MMcf s= 2S 5 2.BSE-01 2.54E-01 1.00 4S 8 1.34E-01 8.52E-02 1.00 No ICE, Field Gas voe Proovlene lbs/MMcf s= 2S 5 2.49E+01 1.41 E+01 1.00 4S 8 1.27E+01 7.24E+00 0.94 No ICE. Field Gas voe Toluene lbs/MMcf s= 2S 5 2.86E+00 2.0BE+00 1.00 4S 8 1.44E+00 1.28E+00 1.00 No ICE Natural Gas voe Formaldehvde lbs/MMcf s= 2S 9 5.15E+00 7.50E+00 0.91 4S 54 1.26E+01 1.51 E+01 1.00 No

6-46

TABLE A6-12a. SOURCE CLASSIFICATION CODE lYPE COMPARISON ASPHAI. T PRODUCTION: CONTRACTOR V REMOVED ~-statistics).

Group Category Substance EF Unit Value Type First Sam..,le StatisttCS Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at

S::X: Deviation Ratio S:C Deviation Ratio 95%Confidence Asnhalt Prod. Diesel Metals Arsenic lbs/ton oroduction a= 30500205 4 2.05E·06 3.97E-06 0.02 30500211 3 2.73E-07 3.93E-09 0.00 No Asohalt Prod. Diesel Metals Bervllium lbs/ton nroduction a= 30500205 4 1.11E-06 1.93E-06 0.00 30500211 3 5.45E-07 7.85E·09 0.00 No Asohalt Prod. Diesel Metals Cadmium lbs/ton oroduction a= 30500205 4 1.11 E-05 2.20E-05 1.00 30500211 1 1.62E-06 1.00 No Asohalt Prod. Diesel Metals Chromium lbs/ton nroduction a= 30500205 4 2.14E-05 4.16E-05 1.00 30500211 3 1.96E-06 1.27E·06 1.00 No Asohalt Prod. Diesel Metals Chromium /Hex\ lbs/ton oroduction a= 30500205 3 8.56E-08 3.14E-08 1.00 Yes Asohalt Prod. Diesel Metals Conner lbs/ton nroduction a= 30500205 4 3.39E-05 6.56E-05 1.00 I 30500211 2 1.50E-06 2.22E•07 1.00 No Asohalt Prod. Diesel Metals Lead lbs/ton oroduction a= 30500205 4 5.49E-04 1.09E-03 1.00 I 30500211 3 2.01E-06 6.56E·07 1.00 No Asohalt Prod. Diesel Metals M•nnanese lbs/ton nroduction a= 30500205 4 4.09E-04 8.17E-04 1.00 I 30500211 3 1.24E-05 4.38E-06 1.00 No Asohalt Prod. Diesel Metals Mercurv lbs~on oroduction a= 30500211 3 4.86E-08 2.84E-06 0.52 Yes Asohalt Prod. Diesel Metals Nickel lbs/ton nroduction a= 30500205 4 9.56E-05 1.90E-04 0.00 30500211 3 2.73E-06 3.93E·06 0.00 No Asohalt Prod. Diesel Metals Selenium lbs/ton oroduction a= 30500205 4 2.66E-06 3.45E·06 0.15 30500211 3 2.73E-07 3.93E-09 0.00 No Asohalt Prod. Diesel Metals Zinc lbs/ton oroduction a= 30500205 4 1.16E-03 2.31E-03 1.00 30500211 3 1.62E·05 5.62E-06 1.00 No Asnhalt Prod. Diesel PAH Acenaohthene lbs/ton nroduction a= 30500205 3 2.11E-06 1.0SE-08 1.00 30500211 3 4.S0E-07 4.21E-07 1.00 No Asohalt Prod. Diesel PAH Acenaohthvlene lbs/ton oroduction a= 3050020• 3 2.04E-08 1.89E-06 1.00 30500211 3 3.36E-07 2.72E-07 1.00 No Asohalt Prod. Diesel PAH Anthracene lbs/ton nroduction a= 30500205 3 1.68E-08 7.54E-09 1.00 30500211 3 3.21E-08 7.68E-09 1.00 No AsnhallProd. Otesel PAI-I Benzo<alanthracene lbs/ton oroduction a= 30500205 3 6.41E-09 2.56E-09 1.00 - Yes Asohalt Prod. Diesel PAH Benzo(a\··--·rene lbs/ton nroduction Ef' 30500205 3 3.13E-10 5.29E-11 1.00 Yes Asnhalt Prod. Diesel PAH Benzolb\fluoranthene lbs/ton oroduction a= 30500205 3 4.39E-09 6.44E-09 1.00 30500211 3 1.39E-06 9.49E-09 1.00 No Asohall Prod .. Diesel PAI-I Benzoln h i\nervlene lbs/ton nroduction a= 30500205 3 5.0JE-10 3.10E-11 1.00 ,; Yes "'"halt Prod. Diesel PAH Benzolk\tluoranthene lbs/ton oroduction a= 30500205 3 1.13E-09 1.31E-09 1.00 305002111 3 I 5.13E-09 I 2.90E-09 I 1.00 No Asohalt Prod. Diesel PAH Chrvsene lbs/ton oroduction a= 30500205 3 1.25E-09 3.67E-10 1.00 Yes Asohalt Prod. Diesel PAH dibenz(a.h)anthracene lbs/ton nroduct~on e= 30500205 3 1.90E-10 1.0SE-10 0.00 -~0500211 3 1.76E-09 8.74E-1? ,0.00 Yes Asohalt Prod. Diesel PAH Fluoranthene lbs/ton oroduchon a= 30500205 3 8.67E-08 3.BBE-08 1.00 ,_4., , Yes Asohalt Prod. Diesel PAH Fluorene lbs/ton nroduction a= 30500205 3 2.78E-07 1.92E-07 1.00 Yes Asnhalt Prod. Diesel PAH lndenot1 2 3-cd\nvrene lbs/ton nroduction e= 30500205 3 3.00E-10 6.03E-12 1.00 Yes Asohalt Prod. Diesel PAH Nanhthalene lbs/ton oroduction a= 30500205 3 1.08E-05 4.70E-06 1.00 30500211 3 4.75E-05 2.78E-05 1.00 No Asnhalt Prod. Diesel PAH Phenanthrene lbs/ton nroduction e= 30500205 3 7.23E-07 3.10E-07 1.00 No Asohalt Prod. Diesel PAH Pvrene lbs/ton oroduction a= 30500205 3 5.99E-08 2.56E-08 1.00 :i Yes Asohalt Prod. Diesel VOC Benzene lbs/ton nroduction a= 30500205 4 8.60E-04 3.72E-04 0.09 , Yes Asohalt Prod. Diesel VOC Formaldehvde lbs/ton oroduction e= 30500205 3 2.43E-04 7 .74E-05 1.00 o No

6-47

TABLE A6-13a. AIR POLLUTION CONTROL SYSTEM COMPARISON ASPHALT PRODUCTION: CONTRACTORV REMOVED (t-statistics).

Group I Category! Substance !EF Unt [Value Type First Sam le Statistics Second Sam le Statistics Significant Description Size Average Standard Detect Description Size Average Standard Detect Difference at APCS tern Deviation Ratio APCS tern Deviation Ratio 95%Confidence

Asphalt Prod., Diesel Metals Arsenic lbs/ton production a= GIFF 3 2.73E-07 3.93E-09 0.00 FF 3 6.60E-08 4.74E-08 1.00 Yes Asphalt Prod., Diesel Metals Arsenic lbs/ton production a= GIFF 3 2.73E-07 3.93E-09 0.00 ws 1 8.02E-06 0.00 Yes As halt Prod. Diesel Metals Arsenic lbs/ton reduction a= FF 3 6.60E-08 4.74E-08 1.00 ws 1 8.02E-06 0.00 Yes

Metals Beryllium lbs/ton production a= GIFF 3 5.45E-07 7.SSE-09 0.00 FF 3 1.S0E-07 1.42E-08 o.oo Yes Metals Beryllium lbs/ton production a= C/FF 3 5.45E-07 7.SSE-09 0.00 ws 1 4.01 E-06 0.00 Yes Metals Be Ilium lbs/ton reduction a= FF 3 1.S0E-07 1.42E-08 0.00 ws 1 4.01E-06 o.oo Yes Metals CadmiLm lbs/ton production a= 'iii] FF 3 1.JSE-07 3.92E-08 0.78 Yes Metals Cadmium lbs/ton production a= GIFF 1 1.62E-06 ws 1 4.41E-05 1.00 NA

Cadmium lbs/ton reduction a= FF 3 1.38E-07 3.92E-08 . ~-Metals Yes

Metals Chromium lbs/ton production a= GIFF 3 1.96E-06 1.27E-08 No Metals Chromium lbs/tan production a= GIFF 3 1.96E-06 1.27E-06 Yes Metals Chromium lbs/ton reduction a= FF 3 5.23E-07 3.40E-07 Yes Metals Chromium Hex lbs/ton roduction a= '"~ Yes

alt Prod., Diesel Metals Copper lbs/ton production a= C/FF 2 1.S0E-06 2.22E-07 No alt Prod., Diesel Metals Copper lbs/ton production a= C/FF 2 1.S0E-06 2.22E-07 Yes alt Prod. Diesel Metals Co er lbs/ton reduction a= FF 3 1.12E-06 3.15E-07 Yes alt Prod., Diesel Metals Lead lbs/ton production a= GIFF 3 2.0tE-06 8.SSE-07 No 1alt Prod., Diesel Metals Lead lbs/tan production a= GIFF 3 2.01E-06 8.58E-07 Yes 1alt Prod. Diesel Metals Lead lbs/ton reduction a= FF 3 2.27E-06 1.54E-06 Yes

Metals Manganese lbs/ton production a= ~ Yes Metals Manganese lbs/ton production a= C/FF 3 1.24E-05 4.38E-08 Yes Metals Ma anese lbs/ton reduction a= FF 3 9.11E-07 1.82E-07 Metals Mercury lbs/ton production a= GIFF 3 4.88E-08 2.84E-08 Metals Mercury lbs/ton production a= GIFF 3 4.88E-08 2.84E-08 Yes Metals Mercu lbs/ton reduction a= FF 3 7.06E-07 7.92E-08 No Metals Nickel lbs/ton production a= GIFF 3 2.73E-06 3.93E-08 Yes Metals Nickel lbs/ton production a= GIFF 3 2.73E-06 3.93E-08 Yes Metals Nickel lbs/ton reduction a= FF 3 5.JSE-07 2.00E-07 .00 Yes Metals Selenium lbs/ton production a= GIFF 3 2.73E-07 3.93E-09 Yes Metals Selenium lbs/ton production a= GIFF 3 2.73E-07 3.93E-09 Yes Metals Selenium tbs/ton reduction a= FF 3 1.16E-06 5.0SE-07 Yes Metals Zinc lbs/ton production a= GIFF 3 1.82E-05 5.62E-06 No Metals Zinc tbs/ton production a= GIFF 3 1.82E-05 S.62E-06 Yes

Diesel Metals reduction a= FF 3 6.71E-06 6.28E-06 Yes Diesel PAH reduction a= C/FF 3 4.21 E-07 No Diesel PAH reduction a= No Diesel PAH reduction a= FF 7.54E-09 1.00 No Diesel PAH reduction a= FF 3 2.56E-09 1.00 Yes Diesel PAH reduction a= FF 3 5.29E-11 1.00 Yes Diesel PAH reduction a= FF 3 6.44E-09 1.00 No Diesel PAH roduction a= FF 3 3.t0E-11 1.00 Yes Diesel PAH reduction a= FF 3 1.13E-09 1.31E-09 1.00 No Diesel PAH roduction a= FF 3 1.25E-09 3.67E-10 1.00 Yes Diesel PAH reduction a= FF 3 1.90E-10 1.0SE-10 0.00 Yes Diesel PAH reduction a= FF 3 8.67E-08 3.88E-08 1.00 Yes Diesel PAH roduction a= FF 3 2.78E-07 1.92E-07 1.00 Yes Diesel PAH roduction a= FF 3 3.00E-10 6.0JE-12 1.00 Yes Diesel PAH roduc!ion a= FF 3 1.0SE-05 4.70E-06 .LQQ No

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TABLE Afr 13a. AIR POLLUTION CONTROL SYSTEM COMPARISON ASPHALT PRODUCTION: CONTRACTOR V REMOVED ~-statistics).

Group Category Substance EFUnlt Value Type First Samnle StatLStics Second Samnle Statistics Significant Description Size Average Standard Detect Description Size Average Standald Detect Difference at APCSvstem Deviation Ratio APC Suotem Deviation Ratio 95%Conflden"'"

Asnhalt Prod. Diesel PAI-I Phenanthrene lbs/ton nroduction El' FF 3 7.23E-07 3.10E-07 1.00 No

Asnhalt Prod. Diesel PAI-I Pvrene lbs/ton nroduction El' FF 3 5.99E-08 2.56E-08 1.00 Yee

Asphalt Prod., Diesel VOC Benzene lbs/ton production El' FF 3 1.04E-03 4.65E·05 0.00 Yes

Asphalt Prod., Diesel VOC Benzene lbs/ton production El' ws 1 3.0SE-04 1.00 Yes

Asnhalt Prod. Diesel VOC Benzene lbs/ton nroduction El' FF 3 1.04E-03 4.65E-05 o.oo ws 1 3.0SE-04 1.00 Yee

Asohalt Prod. Diesel VOC Formaldehvde lbs/ton nroduction El' C/FF 3 1.32E-04 5.94E-05 1.00 FF 3 2.43E-04 7.74E-05 1.00 No

Asnhalt Prod. Natural Gas Metals Arsenic lbs/ton nroduction El' C/FF 6 9.48E-07 5.49E-07 o.oo C/WS 3 1.11 E-07 6.20E-09 0.00 Yes

Asnhalt Prod. Natural Gas Metals Bervllium lbs/ton nroduction El' C/FF 6 1.14E-06 5.31 E-07 o.oo C/WS 3 2.23E-07 1.24E-0B 0.00 Yee

Asnhalt Prod. Natural Gas Metals Cadmium lbs/ton nroduction El' dilf I Hl0

6ili21·iTi lilw C/WS 3 7.30E-07 2.74E-07 1.00 No

Asohalt Prod. Natural Gas Metals Chromium lbs/ton nroduction El' C/WS 3 6.34E-07 2.78E-07 1.00 Yes

Asnhalt Prod. Natural Gas Metals Chromium tHex\ lbs/ton nroduction El' C/WS 3 3.94E-08 5.BSE-09 1.00 Yee

Asnhalt Prod. Natural Gas Metals Conner lbs/ton nroduction El' C/FF 6 3.49E·06 1.51 E-06 0.61 C/WS 3 2.BSE-06 8.71E-07 1.00 No

Asnhalt Prod. Natural Gas Metals Lead lbs/ton nroduction El' C/FF 6 6.03E-06 7.B0E-06 1.00 C/WS 3 1.03E-06 3.00E-07 1.00 No

Asohalt Prod. Natural Gas Metals M•=anese lbs/ton nroduction Er C/FF 6 1.41E-05 1.1 0E-05 1.00 C/WS 3 3.19E·05 1.17E-05 1.00 No

Asohalt Prod. Natural Gas Metals Mercurv lbs/ton nroduction Er C/FF 6 1.53E-05 1.31 E-05 1.00 C/WS 3 1.63E-06 1.52E-06 1.00 No

Asnhalt Prod. Natural Gas Metals Nickel lbs/ton nroduction El' C/FF 6 4.B6E·06 3.40E-06 0.00 C/WS 3 1.19E-06 4.24E·0B 0.00 No

Asnhalt Prod. Natural Gas Metals Selenium lbs/ton nroduction El' C/FF 6 9.47E-07 5.47E-07 o.oo C/WS 3 1.11E-07 6.20E-09 0.00 Yes

Asnhalt Prod. Natural Gas Metals Zinc lbs/ton nroduction El' C/FF 6 1.48E-05 6.66E-06 1.00 C/WS 3 9.52E·06 2.70E-06 1.00 No

Asohalt Prod. Natural Gas PAI-I Acenaohthene lbs/ton nroduction El' ' C/WS 3 2.62E-07 2.59E-07 1.00 Yes

Asohalt Prod. Natural Gas PAI-I Acenanhthvlene lbs/ton nroduction El' C/FF 6 2.24E-06 4.12E-06 1.00 C/WS 2 1.86E-07 3.97E-08 1.00 No

Asnhalt Prod. Natural Gas PAI-I Anthracene lbs/ton nroduction El' C/FF 6 2.S0E-07 3.63E-07 1.00 C/WS 3 6.45E-0B 5.56E·0B 1.00 No

Asnhalt Prod. Natural Gas PAI-I Fluoranthene lbs/ton nroduction Er C/FF 6 6.78E-07 1.43E-06 1.00 C/WS 3 1.04E-0B 8.57E-09 1.00 No

Asnhalt Prod. Natural Gas PAI-I Fluorene lbs/ton nroduction El' C/FF 6 1.82E-06 7.23E-07 1.00 C/WS 3 1.53E-06 1.34E-06 1.00 No

Asohalt Prod. Natural Gas PAI-I Nanhthalene lbs/ton nroduction El' C/FF 6 3.30E-05 2.54E-05 1.00 C/WS 3 8.28E-06 7.54E-06 1.00 No

Asohalt Prod. Natural Gas PAI-I Phenanthrene lbs/ton nroduction El' C/FF 6 2.BBE-06 2.44E-06 1.00 C/WS 3 1.59E-06 1.3BE·06 1.00 No

Asnhalt Prod. Natural Gas PAI-I Pvrene lbs/ton nroduction El' C/FF 6 1.25E-06 2.83E-06 1.00 C/WS 3 1.75E-0B 1.46E-08 1.00 No

Asnhalt Prod. Natural Gas voc Benzene 1bs/ton nroduction El' C/FF 6 1.27E-04 1.37E-04 1.00 C/WS 3 1.63E-05 2.96E-06 1.00 No

Asohalt Prod., Natural Gas voc Formaldehvde lbs/ton nroduction s= C/FF 6 3.79E-04 3.79E-04 1.00 C/WS 3 1.33E-05 3.43E-06 1.00 No

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ATIACHMENT 4 VALIDATION PARAMETERS SUMMARY TABLES · 2020. 8. 24. · 16010 42710 60110 60310 60510...

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