ARKEMA IN 2015 - ECR-Belgium · 2015-12-01 · Organic peroxides Specialty adhesives (Bostik)...

ARKEMA IN 2015

Chemical SpecialtiesInnovative chemistry

2015 CORPORATE PRESENTATION

The new Arkema:

a global producer of specialty chemicals

Worldwide presence

in 50 countries

137industrial sites

13R&D centers

19,000 employeesworldwide

€7,500m

sales*

* 2014 pro forma3


3 business segments and 12 business units

Global and integrated industrial niches

Solutions for decorative paints, industrial coatings and high-growth acrylic applications

World of high valueand innovative solutions

● Thiochemicals

● Fluorogases

● PMMA (Altuglas International)

● Hydrogen peroxide

● Acrylics

● Coating resins

● Photocure resins (Sartomer)

● Rheology additives (Coatex)

● Technical polymers (Specialty polyamides and Fluoropolymers)

● Adorption/filtration (CECA)

● Organic peroxides

● Specialty adhesives (Bostik)

Coating

Solutions

Industrial

Specialties

High Performance

Materials

4


Sales breakdown by business units

12% Acrylics

8% Thiochemicals

6%Fluorochemicals

3%Hydrogen peroxides

Organic peroxides 6%

IndustrialSpecialties

Coating Solutions

26%

29%

5

2014REVENUE OF€7,5 billion

High PerformanceMaterials 45%

Photocure resins (Sartomer)

4%

3%Rheology additives (Coatex)

Coatingresins

9%

Specialty adhesives (Bostik)

21%

Technical polymers (Specialty polyamides and Fluoropolymers)

10%

Filtration and adsorption (CECA)

8%

10%

PMMA(Altuglas International)

2015 CORPORATE PRESENTATION6

North America34 production sites

3 R&D centers

3,400 employees

Europe61 production sites

7 R&D centers

10,800 employees

Asia and rest of the world42 production sites

3 R&D centers

4,800 employees

Broad geographical presence

25%

30%

45%

2015 CORPORATE PRESENTATION7

13 research centers 2.5% of sales allocated to R&D 1,700 researchers

Cary

King of PrussiaGenay (Coatex)

Changshu

Shanghai (Bostik)Pierre BéniteLacq

CoatingSolutions

CoatingSolutions

Industrial Specialties



High Performance Materials




Venette (Bostik)


Milwaukee (Bostik)


Serquigny


Kyoto

CoatingSolutions

CoatingSolutions

Verneuil Carling


Innovation is the heart of Arkema’s strategy

Fluorochemicals Business Unit

9 Confidential This presentation and the information contained wit hin are privileged and confidential and the property of Ark ema9

Arkema’s Fluorochemicals Business Unit :

a worldwide presence

3 R&D centres

3 production facilities located in the US, Europe and China

9

Changshu

Pierre-BéniteCalvert-City

KOP

R&D centres

Production facilities

CRRA

10 Confidential This presentation and the information contained wit hin are privileged and confidential and the property of Ark ema

A complete range of refrigerants available worldwide

Production facilities

Pierre Benite, FranceHFC-134aBlends

Changshu, ChinaHCFC-22HFC-125

HFC-32HFC-134aBlends

Calvert City, KY


The Forane® range of refrigerants


Announcements

Forane® 1234yf announcement

● construction of a 1234yf production plant with start-up in 2016

● two phase strategy based on proprietary technology– first phase based in Asia– second phase investment in Europe

● 1234yf has been confirmed as safe for use in replacement of 134a by the EuropeanCommission’s Joint Research Centre in MAC systems (7 March 2014)

Forane® 1233zd molecule blowing agent

● Trans-1-chloro-3,3,3-trifluoropropene, a liquid halogenated olefin

● Granted US and EU patents as blowing agent in manufacture of polyurethane foam

New F-Gas Regulation (EU 517/2014)


New EU F-Gas regulation

Main measures and overall objective

● Cap and Phase Down

● Selected use bans

● Aims to reduce HFC emissions by 2/3rds by 2030

1515

HFC cap & phase down

-7%

100% baseline

-37%

-55%

-69%-76%

-79%

Base line = annual average of the total quantity of HFCs placed on themarket into the European Union from 2009 to 2012 (quantities beingexpressed in CO2 eq)

1616

HFC cap & phase down

-7%

100% baseline

-37%

-55%

-69%-76%

-79%

Estimated demand for precharged equipment

1717

Impact on future price evolution

17

Source: EU F-Gas Regulation Handbook, Environmental In vestigation Agency, October 2015


Bans on the use of HFC in new equipment and for

servicing / maintenance

0

20

40

60

80

10020

10

2011

2012

2013

2014

2015

2016

2017

2018

2019

2020

2021

2022

2023

2024

2025

2026

2027

2028

2029

2030

2031

2032

HF

C-C

O2

quot

as e

q (%

)

R23 in fire protection

system or fire extinguishers

Domestic refrigerators &

Freezers GWP>150

Movable room AC hermetically sealed,

GWP>150

Refrigerators & Freezers for commercial use (hermetically

sealed) GWP>2500

Stationary refrigeration,GWP >2500

(except <-50°°°°C)

Other foams, with GHG GWP>150

Technical aerosol with GHG GWP>150

XPS foams, with GHG GWP>150

Multipack centralised refrigeration systems for commercial use with

CAP>40kW : GWP>150 (except in the primary refrigerant circuit of cascade

systems : GWP>1500)

Single split AC containing <3kg GHG

GWP>750

Refrigerators & Freezers for commercial use

(hermetically sealed) GWP>150

Servicing /maintenance refrigerating equipment with charge size>40t CO 2

eq. With GHG GWP >2500

Servicing /maintenance reclaimed/recycled GHG

with GWP>2500

Arkema's new low-GWP alternatives

for HVAC and refrigeration

Confidential This presentation and the information contained wit hin are privileged and confidential and the property of Ark ema

Considerations in Fluid Selection

Many factors are important for selecting arefrigerant for any particular application

Fluid selection requires a balance among various drivers, such as direct

environmental impact, energy efficiency, safety, and so forth.

EnvironmentalOzone DepletionGlobal Warming

SafetyFlammability

Toxicity, Pressure

PropertiesDensity, conductivity,

viscosity, …

PerformanceEfficiency, Efficacy, …

DurabilityCompatibility, stability, …

AvailabilitySupply, cost, ease of

manufacture, …

FluidSelection


Arkema is developing multiple HFO refrigerants and blends for various application needs…

HVAC-R applications

…..and different timingShort/medium term : Non-flammable options with GWP of 1300-2300

Long term : Slightly flammable options geared to GWP < 150


0 500 1000 1500 2000 2500 3000 3500 4000

R-410A

R-404A

GWP

R-134aR-1234yf

R-1234ze

Non-flammableMildly flammable

R-22R-407AR-407CR-427A

R-123

VO

LUM

ET

RIC

CA

PA

CIT

Y R-410A ReplacementSolutions

R-404A ReplacementSolutions

R-134a ReplacementSolutions

R-123 ReplacementSolutions

R-449B

ARM-35

ARC-1

ARM-20b

ARM-20a

ARM-25

ARM-42

ARM-71a

Flammable

Arkema’s Refrigerant Solutions for Tomorrow


Arkema’s Refrigerant Solutions for Tomorrow

Current Refrigerant

R-123GWP = 77

R-134aGWP = 1430

R-410AGWP = 2088

R-404AGWP = 3922

R-22GWP = 1810

Non-Flammable

ARC-1(GWP < 15)

R-449B(GWP = 1412)

ARM-35(GWP < 2300)

R-449B (GWP = 1412)

Mildly Flammable

R-1234yf(GWP = 4)

ARM-42 (GWP < 150)

ARM-71a(GWP < 500)

ARM-20a(GWP < 150)

ARM-20b(GWP ~ 250)

Flammable ARM-25

(GWP < 150)

GWP on 100yr time horizon (IPCC AR4)

R-404A/R22 replacements

Confidential This presentation and the information contained wit hin are privileged and confidential and the property of Ark ema25

R-404A replacement

Different solutions for different timing and balances of GWP/COP/CAP/flammability

Stationary and transport refrigeration

Non-flammable

Forane® 407AGWP = 2107

Replacement/Retrofit

Non-flammable

ARM-35GWP < 2300Near Drop-in

R-449BGWP = 1412

Replacement/Retrofit

Mildly Flammable

ARM-20aGWP < 150

ARM-20bGWP ~ 250

ARM-25GWP < 150

New Systems / Retrofits

Drop-in Retrofits / New Systems

New Systems

Commercially available

Under developmentGWP<2500

Under developmentGWP<300


Low-GWP R-404A Replacement : Short/medium term

80%

60%

40%

20%

100%

120%

A1 A1A1A1

∆∆∆∆Tdis. +25K ~ +5 K ~ +25K

R-449BR-404A ARM-35R-407A

LT Refrigeration

GWP

COP

CAP

Evap glide 3.5K ~ 2K ~ 3K

Mass Flow 69% > 95% ~ 70%

Mean Evaporator Temperature (°C)Mean Condenser Temperature (°C)Superheat (K)Subcooling (K)

= -32= 41= 22= 0


Non-flammable candidates

ARM-35 R-449B

Composition Not yet disclosed

25.2% R-32

24.3% R-125

23.2% R-1234yf

27.3% R-134a

ASHRAE Safety RatingClass A1**** anticipated

Class A1

GWP reduction

vs R-404A48% 67%

NBP (˚C) ~ -49 ~ -46

Glide (˚C) at 101kPa 4 6

∆Discharge T vs R-404A (˚C)

(-32/41 ˚C)~ +5 ~ +20

∆Mass Flow vs R-404A (%)

(-32/41 ˚C)< 10 ~ 30


Test unit – Air cooled Walk-in freezer

Drop-in” tests

R-404A, 1 HP, Walk-in Freezer

with matching evaporator

● Semi-hermetic Reciprocating

Compressor

System configuration

● R-404A 1 Ton Thermostatic Expansion

Valve

+/- 2% uncertainty in

experimental values



Medium Temperature

(Indoor of -9 ˚C)

Outdoor temperatures

16˚C 29˚C 41˚C

COP + 5% + 6% + 11%

CAP + 1% + 3% + 8%

R-449B : R-404A retrofit / replacement

vs R-404A

Medium to Low Temperature

(Indoor of -23 ˚C)


16˚C 29˚C 41˚C

COP 0% + 1% + 4%

CAP - 3% - 2% 0%



Medium to Low Temperature

(Indoor of -23 ˚C)


21˚C 32˚C

COP + 7% + 7%

CAP + 7% + 5%

ARM-35 : R-404A easy retrofit / near “drop-in”

Low Temperature

(Indoor of -32 ˚C)


21˚C 32˚C

COP +18% +11%

CAP +16% + 5%

vs R-404A


Low-GWP R-404A Replacement : long term

80%

60%

40%

20%

100%

120%

A1 A2/A2LA2LA2L

∆∆∆∆Tdis. ~ 15 K ~ 30 K ~10 K

ARM-25R-404A ARM-20bARM-20a

GWP

COP

CAP

LT Refrigeration

New equipments

Balance between CAP/GWP/flammability


= -32= 41= 22= 0


Flammable candidates

ARM-20a ARM-20b ARM-25

ASHRAE Safety Rating Class A2L** Class A2L** Class A2**

GWP <150 ~ 250 <150

NBP (˚C) ~ -42 ~ -46 ~ -52

Glide (˚C) at 101kPa 7 6 12

∆Discharge T vs R-404A (˚C)

(-32/41 ˚C)~ +15 ~ +30 ~ +10

** anticipated

R-134a replacement


R-134a Replacement

GWP

COP

CAP

A1 A2LA2L

E-1234zeR-134a ARM-42

ARM-42

● Centrifugal and positive displacement chillers

● Stand-alone refrigeration equipments


= 4= 38= 5= 5

80%

60%

40%

20%

100%

120%

Very Low GWP (< 150)

Zero-glide

Three component blend

● R-1234yf / R-134a / R-152a


ARM-42: Major Results – low-GWP AREP

115

110

105

100

95

% v

sR

-134

a

ScrewJCI

90

ScrewTrane

CentrifugalJCI

Reciprocating Embraco

115

110

105

100

95

% v

sR

-134

a

ScrewJCI

90

ScrewTrane

CentrifugalJCI

Reciprocating Embraco

Capacity

COP

[Data source: AHRI Low-GWP AREP Report : - 018, 2013 : Embraco – Calorimeter test

- 014, 2013 : JCI – Air cooled chiller

- 006, 2012: Trane - Air cooled chiller]


Low-GWP AREP Results: 134a-Replacements

36

[Data source: AHRI Low-GWP AREP Report 006, 2012: Trane]

Example Results:

= 7°°°°C

= 29°°°°C


ARM-42: Major Results – low-GWP AREP [Data source: AHRI Low-GWP AREP Report 018, 2013: Embraco – reciprocating comp]

95

100

105

110

115

-24 -20 -15

CA

P A

RM

-42

a /

R-1

34

a

Evap. Temperature

Cond. T° = 35°C

95

100

105

110

115

-24 -20 -15

CA

P A

RM

-42

a /

R-1

34

a

Evap. Temperature

Cond. T° = 55°C

96

98

100

102

104

-24 -20 -15

CO

P A

RM

-42

a /

R-1

34

a

Evap. Temperature

Cond. T° = 35°C

96

98

100

102

104

-24 -20 -15

CO

P A

RM

-42

a /

R-1

34

a

Evap. Temperature

Cond. T° = 55°C

R-410A replacement


R-410A Replacement

A1 A2LA2L

∆∆∆∆Tdis. ~ 20K ~ 5K

GWP

COP

CAP

80%

60%

40%

20%

100%

120%

ARM-71aR-410A R-32

Air Conditioning


= 4= 38= 5= 5


Refrig CAP COP Pr ∆Tdisch (C) Pcond Pevapglide evap

(C)

R-32 112.5 103.3 100.2 25 102.4 102.1 0

ARM-71a 96.9 103.4 100.5 7 91.8 91.3 1.8

R-410A Replacement

ARM-71a

● Similar CAP and COP to R-410A

● Lower discharge temperature versus R-32

● Moderate glide



= 4= 38= 5= 5

= 4= 38= 5= 5


Efficiency

Capacity

Discharge T

High AmbientFlammability

Toxicity

LCCP

R-32

Efficiency

Capacity

Discharge T


Toxicity

LCCP

R-410A

Efficiency

Capacity

Discharge T


Toxicity

LCCP

ARM-71a

● Mildly flammable

● Similar CAP and COP to R-410A

● Lower discharge temperature vs R-32

● Low glide

R-410A Replacement

Fluids for Energy Recovery


Energy Recovery Technologies

Available Energy Sources

● Industrial processes● Geothermal● Solar● Biomass, ….

High Temperature Heat Pumps

● Generate Hot Fluid/Steam ● Low-grade heat: 60°C → 140°C

Organic Rankine Cycles

● Generate Electricity ● Waste steam or high-grade heat: 120°C → 70°C

Use Industrial Waste Heat to Power Processes


Non-flammable fluids

Substance Bp (̊C) Tc (̊C) GWP

AHP1 ~ 18 ~ 170 <13

AHP2 ~ 35 ~ 170 <10

R245fa 15.1 154 1030

R114 3.6 146 1040


Energy recovery applications

80%

60%

40%

20%

100%

120%

140%

-1.7% +1.4%

AHP1 and AHP2

Very low GWP fluids : GWP <15

Organic Rankine Cycle and High Temperature Heat Pumps

R-245fa AHP1 AHP2

Organic Rankine Cycle

GWP

COP

GWP

COP

Tevap / Tcond : 120°°°°C / 20°°°°C


80%

60%

40%

20%

100%

120%

140%

Tevap / Tcond : 90 / 130°°°°C

R-245fa AHP1 AHP2

GWP

COP

CAP

GWP

COP

CAP

High Temperature Heat Pump

Energy recovery applications

CONCLUSION


Expected general timeframe for the development of new

Low-GWP alternatives for HVACR sectors in Europe

Phase I AREP program

Phase IIAREP program

New Low-GWP HVACR equipments development

March 2011

Dec 2013

Q1 2016(expected)

Duration: 21 months

New refrigerant + lubricants developments

Development of new compressors,

heat eachangers, condensers, expansion devices…

Commercialization

New components developments

Evolution of standards and national regulations


Bans in refrigeration

01/01/2020 01/01/2022

Forane ® 404A / 507Refrigerators & Freezers

for commercial use (hermetically sealed)

01/01/2015

Forane ® 404A / 507Stationary refrigeration

equipments (not concerned: equipments

for cooling < -50 °°°°C)

Forane ® 407A

Multipack centralised refrigeration systems for

commercial use with capacity>40kW

(exception: primary refrigerant circuit of cascade

systems where the use of refrigerants with GWP<1500

will still be authorized)

Forane ® 134a (in the primary refrigerant circuit of cascade syst ems)

> 2030

Forane ® 407A / 410A / 134a

ARM-20aARM-25

GWP<2500 GWP<150

ARM-35 / R-449B

GWP<2500

GWP<150

Forane ® 134a ARM-42

Forane ® 404A / 507

Forane ® 407A

ARM-20aARM-25


Bans in air conditioning

01/01/2020 01/01/2025

Forane ® 134a

Movable room AC (hermetically sealed)

01/01/2015

Forane ® 410A / 407CSingle split AC

(charge size < 3kgs)

Forane ® 410A / 407C

Forane ® 134a

ARM-42

GWP<150

ARM-42

ARM-71a

GWP<750

> 2030


Bans for servicing and maintenance

01/01/202001/01/2015

Servicing / maintenance refrigeration equipment (charge size > 40 tonnes

CO2 eq)

(not concerned: equipments for cooling < -50 °°°°C or for

military applications)

GWP<2500

> 2030

Forane ® 404A / 507 ARM-35 / R-449B

Forane ® 427A (R-22 retrofit)

Forane ® 407A / 407C / 410A / 134a


Arkema’s commitment to a sustainable future

Developing next generation solutions for all major markets

● Forane® 1233zd for PU foams● Forane® 1234yf for Mobile Air Conditioning and chillers● Lower-GWP HFO blends for HVAC-R

Active involvement in industry wide effort to replace current HFCs

● AHRI low-GWP AREP first and second round http://www.ahrinet.org/site/514/Resources/Research/AHRI-Low-GWP-Alternative-Refrigerants-Evaluation

● Joint UNEP/UNIDO project in Egypt (EGYPRA: Egypt-Promoting Refrigerant Alternatives)

● High Ambient Temperature Initiative (Provide arguments to Middle East countries and India that solutions to replace R-22 exist)


Thank You.

Disclaimer

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of the information referred to herein are beyond our control, Arkema expressly disclaims any and all liability as to any results obtained or arising from any reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The user should thoroughly test any application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe any patent, and the user is advised to take appropriate steps to be sure that any proposed action will not result in patent infringement.

© 2013 Arkema Inc.

ARKEMA IN 2015 - ECR-Belgium · 2015-12-01 · Organic peroxides Specialty adhesives (Bostik)...

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Transcript of ARKEMA IN 2015 - ECR-Belgium · 2015-12-01 · Organic peroxides Specialty adhesives (Bostik)...