APPENDIX A

ILLINOIS ENVIRONMENTAL

PROTECTION AGENCY'S

MACROINVERTEBRATE

TOLERANCE LIST

Macroinvertebrate

PLATYHELMINTHESTURBELLARIA

ANNELIDAOLIGOCHAETAHIRUDINEA

RhynchobdellidaGlossiphoniidaePiscicolidae

GnathobdellidaHirudinidae

PharyngobdellidaErpobdellidae

ARTHROPODACRUSTACEA

ISOPODAAsellidae

Caecidoteabrevicaudaintermedia

LirceusAMPHIPODA

HyalellidaeHyalella

aztecaGammaridae

BactrurusCrangonyxGammarus

DECAPODACambaridaePalaemonidae

PalaemonetesINSECTA

EPHEMEROPTERASiphlonuridae

AmeletusSiphlonurus

Oligoneuriidae

Tolerance value

6

108

87

7

8

66664

5

143

5

4

O2

Macroinvertebrate

HeptageniidaeArthropleaEpeorus

vitreusHeptagenia

diabasiaflavescenshebelucidipennismaculipennismarginalisperfidapulla

RhithrogenaStenacron

candidumgildersleeveiinterpunctatumminne tonka

Stenonemaannexumaresexiguumfemoratumintegrumluteummediopunctatummodestumnepotellumpudicumpulchellumquinquespinumrubromaculatumscitulumterminatumvicarium

EphemerellidaeAttenellaDanella

Tolerance value

31O34233311OO4114444357412352352143

22

M acroinvertebrate

I sony chiaMetretopodidae

SiphloplectonBaetidae

Baetisbrunneicolorflavistrigafrondalisinter c alar islongipalpusmacdunnoughipropinquuspygmaeustricaudatus

Callibaetisfluctuans

CentroptilumCloeonPseudocloeon

dubiumparvulumpunctiventris

Hexagenialimbatamunda

PalingeniidaePentagenia

vittigeraPolymitarcyidae

EphoronTortopus

ODONATAANISOPTERA

CordulegasteridaeCordulegaster

GomphidaeDromogomphusGomphusHageniusLanthusOphiogomphusProgomphus

AeshnidaeAeshnaAnaxBasiaeschnaBoyeriaEpiaeschnaNasiaeschna

MacromiidaeDidymopsMacromia

Tolerance value

3

2

444476444144234444657

44

24

2

473625

452312

43

Macroinvertebrate

DrunellaEphemerellaEurylophellaSeratella

TricorythidaeTricorythodes

CaenidaeBrachycercusCaenis

BaetiscidaeBaetisca

LeptophlebiidaeChoroterpesHabrophlebiodes

americanaLeptophlebiaParaleptophlebia

PotamanthidaePotamanthus

EphemeridaeEphemera

simulansPLECOPTERA

PteronarcyidaePteronarcys

TaeniopterygidaeTaeniopteryx

NemoundaeNemoura

LeuctridaeLeuctra

CapniidaeAllocapniaCapnia

PerlidaeAcroneuriaAtoperiaNeoperiaPerlesta

placidaPerlinella

PeriodidaeHydroperiaIsoperia

ChloroperiidaeChloroperia

MEGALOPTERASialidae

SialisCorydalidae

ChauliodesCorydalus

Tolerance value

1241

5

36

3

22232

4

33

2

2

1

1

21

111442

12

3

4

43

Macroinvertebrate

CorduliidaeCorduliaEpithecaHelocorduliaNeurocorduliaSomatochlora

LibellulidaeCelithemisErythemisErythrodiplaxLibellulaPachydiplaxPantalaPerithemisPlathemisSympetrumTramea

ZYGOPTERACalopterygidae

CalopteryxHetaerina

LestidaeAr chiles tesLestes

CoenagrionidaeAmphiagrionArgia

moestatibialis

Enallagmasignatum

IschnuraNehalennia

HydroptilidaeAgrayleaHydroptilaIthytrichiaLeucotrichiaMayatrichiaNeotrichiaOchrotrichiaOrthotrichiaOxyethira

RhyacophilidaeRhyacophila

BrachycentridaeBrachycentrus

LepidostomatidaeLepidostoma

LimnephilidaeHydatophylaxLimnephilusNeophylax

Tolerance value

24231

2558874344

43

16

55556667

221314412

1

1

3

233

Macroinvertebrate

NigroniaNEUROPTERA

SisyridaeTRICHOPTERA

HydropsychidaeCheumatopsycheDiplectronaHydropsyche

arinalebettenibidenscuanisfrisoniorrisphalerataplacodasimulans

MacronemaPotamyiaSymphitopsyche

PhilopotamidaeChimarraDolophilodes

PolycentropodidaeCyrnellusNeureclipsisNyctiophylaxPolycentropus

PsychomyiidaePsychomyia

GlossosomatidaeAgapetusProtoptila

DIPTERABlephariceridaeTipulidae

AntochaDicranotaErioceraHeliusHesperoconopaHexatomaLimnophilaLimoniaLiriopePediciaPilariaPolymedaPseudolimnophilaTipula

ChaoboridaeCulicidae

Aedes

Tolerance value

2

1

625555554245244

3O

5313

2

21

O454752443744224888

Macroinvertebrate

Platycen tropusPycnopsyche

PhryganeidaeAgrypniaBanksiolaPhryganeaPtilostomis

HelicopsychidaeHelicopsyche

LeptoceridaeCeracleaLeptocerusMystacidesNectopsycheOecetisTriaenodes

COLEOPTERAGyrinidae (larvae only)

DineutusGyrinus

Psephenidae (larvae only)Psephenus

herrickiEubriidae

Ectopriathoracica

DryopidaeHelichus

lithophilusHelodidae (larvae only)Elmidae

Ancyronyxvariegatus

Dubiraphiabivittataquadrinotatavittata

Macronychusglabratus

MicrocylloepusOptioservus

ovalisStenelmis

crenatavittipennis

OrthocladiinaeCardiocladiusChaetocladiusCorynoneuraCricotopus

bicinctustrifasciatus

Eukiefferiella

Tolerance value

33

3233

2

332353

444444444447

22527722244776

6628

1064

Macroinvertebrate

AnophelesCulex

PsychodidaeCeratopogonidae

AtrichopogonPalpomyia

SimuliidaeCnephiaProsimuliumSimulium

clarkeicorbisdecorumjenningsiluggerimeridionaletuberosumvenustumverecundumvittatum

ChironomidaeTanypodinae

Ablabesmyiamallochipar aj ant apeleensis

Clinotanypuspinguis

CoelotanypusLabrundiniaLarsiaMacropelopiaNatarsiaPentaneuraProcladiusPsectrotanypusTanypusThienemannimyia groupZavrelimyia

DiamesinaeDiamesaPseudodiamesa

SyrphidaeEphydridaeSciomyzidaeMuscidaeAthencidae

AtherixMOLLUSCAGASTROPODA

Tolerance value

68

11526

4264O44214668

66666644676388868

11

118

108

4

Macroinvertebrate

HydrobaenusNanocladiusOrthocladiusParametriocnemusProdiamesaPsectrocladiusRheocricotopusTh ieneman iella

xenaChironominae

Chironomusattenuatusriparius

CryptochironomusCryptotendipesDicrotendipes

modestusneomodestusnervosus

EinfeldiaEndochironomusGlyptotendipesHarnischiaKiefferulusMicrotendipesParachironomusParacladopelmaParalauterborniellaParatendipesPhaenopsectraPolypedilum

fallaxhalteraleillinoensescalaenum

PseudochironomusStenochironomusStictochironomusTribelosXenochironomus

TanytarsiniClado tany tarsusMicropsectraRheotanytarsusTany tar sus

PtychopteridaeTabanidae

ChrysopsTabanus

DolichopodidaeEmpididae

Hemerodromia

Tolerance value

234435622

111011866666

106

10676846346645653554

74678777566

Source. Illinois Environmental Protection Agency, 1987

Macroinvertebrate

ViviparidaeCampelomaLioplaxViviparus

ValvatidaeValvata

BulimidaeAmnicola

PleurocandaeGoniobasisPleurocera

PhysidaeAplexa

PhysaLymnaeidae

LymnaraStagnicola

PlanorbidaeGyraulusHelisomaPlanorbula

AncylidaeFerrissia

PELECYPODAUnionidae

Actinonaiascarinata

Alasmidontamarginatatriangulata

AnodontaCarunculinaEllipticFusronaiaLampsilisLigumiaMargaritiferaMicromyaObliquariaPropleraStrophitusTritagoniaTruncillaUtterbackia

SphaeridaeMusculiumPisidiumSphaeriuni

CyrenidaeCorbicula

Tolerance value

771

2

4

57

79

77

677

7

1

1O37211111114111

555

4

10 10 well functions

u W(u] u W(u] u W(u) u W(u)

l.OE-10 22.45 3.3E-10 21.25 5.6E-10 20.73 7.9E-10 20.381.1E-10 22.35 3.4E-10 21.22 5.7E-10 20.71 8.0E-10 20.371.2E-10 22.27 3.5E-10 21.20 5.8E-10 20.69 8.1E-10 20.361.3E-10 22.19 3.6E-10 21.17 5.9E-10 20.67 8.2E-10 20.341.4E-10 22.11 3.7E-10 21.14 6.0E-10 20.66 8.3E-10 20.331.5E-10 22.04 3.8E-10 21.11 6.1E-10 20.64 8.4E-10 20.321.6E-10 21.98 3.9E-10 21.09 6.2E-10 20.62 8.5E-10 20.311.7E-10 21.92 4.OE-10 21.06 6.3E-10 20.61 8.6E-10 20.301.8E-10 21.86 4.1E-10 21.04 6.4E-10 20.59 8.7E-10 20.291.9E-10 21.81 4.2E-10 21.01 6.5E-10 20.58 8.8E-10 20.272.OE-10 21.76 4.3E-10 20.99 6.6E-10 20.56 8.9E-10 20.262.1E-10 21.71 4.4E-10 20.97 6.7E-10 20.55 9.0E-10 20.252.2E-10 21.66 4.5E-10 20.94 6.8E-10 20.53 9.1E-10 20.242.3E-10 21.62 4.6E-10 20.92 6.9E-10 20.52 9.2E-10 20.232.4E-10 21.57 4.7E-10 20.90 7.OE-10 20.50 9.3E-10 20.222.5E-10 21.53 4.8E-10 20.88 7.1E-10 20.49 9.4E-10 20.212.6E-10 21.49 4.9E-10 20.86 7.2E-10 20.47 9.5E-10 20.202.7E-10 21.46 5.OE-10 20.84 7.3E-10 20.46 9.6E-10 20.192.8E-10 21.42 5.1E-10 20.82 7.4E-10 20.45 9.7E-10 20.182.9E-10 21.38 5.2E-10 20.80 7.5E-10 20.43 9.8E-10 20.173.OE-10 21.35 5.3E-10 20.78 7.6E-10 20.42 9.9E-10 20.163.IE-10 21.32 5.4E-10 20.76 7.7E-10 20.413.2E-10 21.29 5.5E-10 20.74 7.8E-10 20.39

APPENDIX B

WELL FUNCTION FOR CONFINED

AQUIFERS

10 9 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-09 20.15 3.3E-09 18.95 5.6E-09 18.42 7.9E-09 18.081.1E-09 20.05 3.4E-09 18.92 5.7E-09 18.41 8.0E-09 18.071.2E-09 19.96 3.5E-09 18.89 5.8E-09 18.39 8.IE-09 18.051.3E-09 19.88 3.6E-09 18.87 5.9E-09 18.37 8.2E-09 18.041.4E-09 19.81 3.7E-09 18.84 6.OE-09 18.35 8.3E-09 18.031.5E-09 19.74 3.8E-09 18.81 6.1E-09 18.34 8.4E-09 18.021.6E-09 19.68 3.9E-09 18.79 6.2E-09 18.32 8.5E-09 18.011.7E-09 19.62 4.OE-09 18.76 6.3E-09 18.31 8.6E-09 17.991.8E-09 19.56 4.1E-09 18.74 6.4E-09 18.29 8.7E-09 17.981.9E-09 19.50 4.2E-09 18.71 6.5E-09 18.27 8.8E-09 17.972.OE-09 19.45 4.3E-09 18.69 6.6E-09 18.26 8.9E-09 17.962.1E-09 19.40 4.4E-09 18.66 6.7E-09 18.24 9.OE-09 17.952.2E-09 19.36 4.5E-09 18.64 6.8E-09 18.23 9.1E-09 17.942.3E-09 19.31 4.6E-09 18.62 6.9E-09 18.21 9.2E-09 17.932.4E-09 19.27 4.7E-09 18.60 7.OE-09 18.20 9.3E-09 17.922.5E-09 19.23 4.8E-09 18.58 7.1E-09 18.19 9.4E-09 17.912.6E-09 19.19 4.9E-09 18.56 7.2E-09 18.17 9.5E-09 17.892.7E-09 19.15 5.OE-09 18.54 7.3E-09 18.16 9.6E-09 17.882.8E-09 19.12 5.1E-09 18.52 7.4E-09 18.14 9.7E-09 17.872.9E-09 19.08 5.2E-09 18.50 7.5E-09 18.13 9.8E-09 17.863.OE-09 19.05 5.3E-09 18.48 7.6E-09 18.12 9.9E-09 17.853.1E-09 19.01 5.4E-09 18.46 7.7E-09 18.103.2E-09 18.98 5.5E-09 18.44 7.8E-09 18.09

10~8 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-08 17.84 3.3E-08 16.65 5.6E-08 16.12 7.9E-08 15.78LIE-08 17.75 3.4E-08 16.62 5.7E-08 16.10 8.OE-08 15.761.2E-08 17.66 3.5E-08 16.59 5.8E-08 16.09 8.1E-08 15.751.3E-08 17.58 3.6E-08 16.56 5.9E-08 16.07 8.2E-08 15.741.4E-08 17.51 3.7E-08 16.54 6.0E-08 16.05 8.3E-08 15.731.5E-08 17.44 3.8E-08 16.51 6.1E-08 16.04 8.4E-08 15.721.6E-08 17.37 3.9E-08 16.48 6.2E-08 16.02 8.5E-08 15.701.7E-08 17.31 4.OE-08 16.46 6.3E-08 16.00 8.6E-08 15.691.8E-08 17.26 4.1E-08 16.43 6.4E-08 15.99 8.7E-08 15.681.9E-08 17.20 4.2E-08 16.41 6.5E-08 15.97 8.8E-08 15.672.OE-08 17.15 4.3E-08 16.38 6.6E-08 15.96 8.9E-08 15.662.1E-08 17.10 4.4E-08 16.36 6.7E-08 15.94 9.OE-08 15.652.2E-08 17.06 4.5E-08 16.34 6.8E-08 15.93 9.1E-08 15.642.3E-08 17.01 4.6E-08 16.32 6.9E-08 15.91 9.2E-08 15.622.4E-08 16.97 4.7E-08 16.30 7.OE-08 15.90 9.3E-08 15.612.5E-08 16.93 4.8E-08 16.27 7.1E-08 15.88 9.4E-08 15.602.6E-08 16.89 4.9E-08 16.25 7.2E-08 15.87 9.5E-08 15.592.7E-08 16.85 5.OE-08 16.23 7.3E-08 15.86 9.6E-08 15.582.8E-08 16.81 5.1E-08 16.21 7.4E-08 15.84 9.7E-08 15.572.9E-08 16.78 5.2E-08 16.19 7.5E-08 15.83 9.8E-08 15.563.OE-08 16.74 5.3E-08 16.18 7.6E-08 15.82 9.9E-08 15.553.1E-08 16.71 5.4E-08 16.16 7.7E-08 15.803.2E-08 16.68 5.5E-08 16.14 7.8E-08 15.79

10 well functions

u W(u} u W(u) u W(u) u W(u)

LOE-07 15.54 3.3E-07 14.35 5.6E-07 13.82 7.9E-07 13.47LIE-07 15.45 3.4E-07 14.32 5.7E-07 13.80 8.OE-07 13.46.2E-07 15.36 3.5E-07 14.29 5.8E-07 13.78 8.1E-07 13.45.3E-07 15.28 3.6E-07 14.26 5.9E-07 13.77 8.2E-07 13.44.4E-07 15.20 3.7E-07 14.23 6.OE-07 13.75 8.3E-07 13.42.5E-07 15.14 3.8E-07 14.21 6.1E-07 13.73 8.4E-07 13.41.6E-07 15.07 3.9E-07 14.18 6.2E-07 13.72 8.5E-07 13.40.7E-07 15.01 4.OE-07 14.15 6.3E-07 13.70 8.6E-07 13.39.8E-07 14.95 4.1E-07 14.13 6.4E-07 13.68 8.7E-07 13.38.9E-07 14.90 4.2E-07 14.11 6.5E-07 13.67 8.8E-07 13.372.OE-07 14.85 4.3E-07 14.08 6.6E-07 13.65 8.9E-07 13.352.1E-07 14.80 4.4E-07 14.06 6.7E-07 13.64 9.OE-07 13.342.2E-07 14.75 4.5E-07 14.04 6.8E-07 13.62 9.1E-07 13.332.3E-07 14.71 4.6E-07 14.01 6.9E-07 13.61 9.2E-07 13.322.4E-07 14.67 4.7E-07 13.99 7.OE-07 13.59 9.3E-07 13.312.5E-07 14.62 4.8E-07 13.97 7.1E-07 13.58 9.4E-07 13.302.6E-07 14.59 4.9E-07 13.95 7.2E-07 13.57 9.5E-07 13.292.7E-07 14.55 5.0E-07 13.93 7.3E-07 13.55 9.6E-07 13.282.8E-07 14.51 5.1E-07 13.91 7.4E-07 13.54 9.7E-07 13.272.9E-07 14.48 5.2E-07 13.89 7.5E-07 13.53 9.8E-07 13.263.OE-07 14.44 5.3E-07 13.87 7.6E-07 13.51 9.9E-07 13.253.1E-07 14.41 5.4E-07 13.85 7.7E-07 13.503.2E-07 14.38 5.5E-07 13.84 7.8E-07 13.49

10~ well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-06 13.24 3.3E-06 12.04 5.6E-06 11.52 7.9E-06 11.17LIE-06 13.14 3.4E-06 12.01 5.7E-06 11.50 8.OE-06 11.161.2E-06 13.06 3.5E-06 11.99 5.8E-06 11.48 8.1E-06 11.15L3E-06 12.98 3.6E-06 11.96 5.9E-06 11.46 8.2E-06 11.131.4E-06 12.90 3.7E-06 11.93 6.OE-06 11.45 8.3E-06 11.121.5E-06 12.83 3.8E-06 11.90 6.1E-06 11.43 8.4E-06 11.111.6E-06 12.77 3.9E-06 11.88 6.2E-06 11.41 8.5E-06 11.101.7E-06 12.71 4.OE-06 11.85 6.3E-06 11.40 8.6E-06 11.09L8E-06 12.65 4.1E-06 11.83 6.4E-06 11.38 8.7E-06 11.071.9E-06 12.60 4.2E-06 11.80 6.5E-06 11.37 8.8E-06 11.062.OE-06 12.55 4.3E-06 11.78 6.6E-06 11.35 8.9E-06 11.052.1E-06 12.50 4.4E-06 11.76 6.7E-06 11.34 9.0E-06 11.042.2E-06 12.45 4.5E-06 11.73 6.8E-06 11.32 9.1E-06 11.032.3E-06 12.41 4.6E-06 11.71 6.9E-06 11.31 9.2E-06 11.022.4E-06 12.36 4.7E-06 11.69 7.OE-06 11.29 9.3E-06 11.012.5E-06 12.32 4.8E-06 11.67 7.1E-06 11.28 9.4E-06 11.002.6E-06 12.28 4.9E-06 11.65 7.2E-06 11.26 9.5E-06 10.992.7E-06 12.25 5.OE-06 11.63 7.3E-06 11.25 9.6E-06 10.982.8E-06 12.21 5.1E-06 11.61 7.4E-06 11.24 9.7E-06 10.972.9E-06 12.17 5.2E-06 11.59 7.5E-06 11.22 9.8E-06 10.963.0E-06 12.14 5.3E-06 11.57 7.6E-06 11.21 9.9E-06 10.953.1E-06 12.11 5.4E-06 11.55 7.7E-06 11.203.2E-06 12.08 5.5E-06 11.53 7.8E-06 11.18

10 5 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-05 10.94 3.3E-05 9.74 5.6E-05 9.21 7.9E-05 8.87LIE-05 10.84 3.4E-05 9.71 5.7E-05 9.20 8.OE-05 8.861.2E-05 10.75 3.5E-05 9.68 5.8E-05 9.18 8.1E-05 8.84.3E-05 10.67 3.6E-05 9.65 5.9E-05 9.16 8.2E-05 8.83.4E-05 10.60 3.7E-05 9.63 6.OE-05 9.14 8.3E-05 8.82.5E-05 10.53 3.8E-05 9.60 6.1E-05 9.13 8.4E-05 8.81.6E-05 10.47 3.9E-05 9.57 6.2E-05 9.11 8.5E-05 8.80.7E-05 10.41 4.OE-05 9.55 6.3E-05 9.10 8.6E-05 8.78.8E-05 10.35 4.1E-05 9.52 6.4E-05 9.08 8.7E-05 8.77.9E-05 10.29 4.2E-05 9.50 6.5E-05 9.06 8.8E-05 8.762.OE-05 10.24 4.3E-05 9.48 6.6E-05 9.05 8.9E-05 8.752.1E-05 10.19 4.4E-05 9.45 6.7E-05 9.03 9.OE-05 8.742.2E-05 10.15 4.5E-05 9.43 6.8E-05 9.02 9.1E-05 8.732.3E-05 10.10 4.6E-05 9.41 6.9E-05 9.00 9.2E-05 8.722.4E-05 10.06 4.7E-05 9.39 7.OE-05 8.99 9.3E-05 8.712.5E-05 10.02 4.8E-05 9.37 7.1E-05 8.98 9.4E-05 8.702.6E-05 9.98 4.9E-05 9.35 7.2E-05 8.96 9.5E-05 8.682.7E-05 9.94 5.OE-05 9.33 7.3E-05 8.95 9.6E-05 8.672.8E-05 9.91 5.1E-05 9.31 7.4E-05 8.93 9.7E-05 8.662.9E-05 9.87 5.2E-05 9.29 7.5E-05 8.92 9.8E-05 8.653.OE-05 9.84 5.3E-05 9.27 7.6E-05 8.91 9.9E-05 8.643. IE-05 9.80 5.4E-05 9.25 7.7E-05 8.893.2E-05 9.77 5.5E-05 9.23 7.8E-05 8.88

10~4 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-04 8.63 3.3E-04 7.44 5.6E-04 6.91 7.9E-04 6.57.1E-04 8.54 3.4E-04 7.41 5.7E-04 6.89 8.OE-04 6.55.2E-04 8.45 3.5E-04 7.38 5.8E-04 6.88 8.1E-04 6.54.3E-04 8.37 3.6E-04 7.35 5.9E-04 6.86 8.2E-04 6.53.4E-04 8.30 3.7E-04 7.33 6.OE-04 6.84 8.3E-04 6.52.5E-04 8.23 3.8E-04 7.30 6.1E-04 6.83 8.4E-04 6.51.6E-04 8.16 3.9E-04 7.27 6.2E-04 6.81 8.5E-04 6.49.7E-04 8.10 4.OE-04 7.25 6.3E-04 6.79 8.6E-04 6.48.8E-04 8.05 4.1E-04 7.22 6.4E-04 6.78 8.7E-04 6.47.9E-04 7.99 4.2E-04 7.20 6.5E-04 6.76 8.8E-04 6.462.OE-04 7.94 4.3E-04 7.17 6.6E-04 6.75 8.9E-04 6.452.1E-04 7.89 4.4E-04 7.15 6.7E-04 6.73 9.OE-04 6.442.2E-04 7.84 4.5E-04 7.13 6.8E-04 6.72 9. IE-04 6.432.3E-04 7.80 4.6E-04 7.11 6.9E-04 6.70 9.2E-04 6.412.4E-04 7.76 4.7E-04 7.09 7.OE-04 6.69 9.3E-04 6.402.5E-04 7.72 4.8E-04 7.06 7. IE-04 6.67 9.4E-04 6.392.6E-04 7.68 4.9E-04 7.04 7.2E-04 6.66 9.5E-04 6.382.7E-04 7.64 5.OE-04 7.02 7.3E-04 6.65 9.6E-04 6.372.8E-04 7.60 5.1E-04 7.00 7.4E-04 6.63 9.7E-04 6.362.9E-04 7.57 5.2E-04 6.98 7.5E-04 6.62 9.8E-04 6.353.OE-04 7.53 5.3E-04 6.97 7.6E-04 6.61 9.9E-04 6.343.IE-04 7.50 5.4E-04 6.95 7.7E-04 6.593.2E-04 7.47 5.5E-04 6.93 7.8E-04 6.58

10 3 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-03 6.33 3.3E-03 5.14 5.6E-03 4.61 7.9E-03 4.271.1E-03 6.24 3.4E-03 5.11 5.7E-03 4.60 8.0E-03 4.261.2E-03 6.15 3.5E-03 5.08 5.8E-03 4.58 8.1E-03 4.251.3E-03 6.07 3.6E-03 5.05 5.9E-03 4.56 8.2E-03 4.231.4E-03 6.00 3.7E-03 5.03 6.OE-03 4.54 8.3E-03 4.221.5E-03 5.93 3.8E-03 5.00 6.1E-03 4.53 8.4E-03 4.211.6E-03 5.86 3.9E-03 4.97 6.2E-03 4.51 8.5E-03 4.201.7E-03 5.80 4.OE-03 4.95 6.3E-03 4.50 8.6E-03 4.191.8E-03 5.74 4.1E-03 4.92 6.4E-03 4.48 8.7E-03 4.181.9E-03 5.69 4.2E-03 4.90 6.5E-03 4.47 8.8E-03 4.162.OE-03 5.64 4.3E-03 4.88 6.6E-03 4.45 8.9E-03 4.152.1E-03 5.59 4.4E-03 4.85 6.7E-03 4.44 9.OE-03 4.142.2E-03 5.54 4.5E-03 4.83 6.8E-03 4.42 9.1E-03 4.132.3E-03 5.50 4.6E-03 4.81 6.9E-03 4.41 9.2E-03 4.122.4E-03 5.46 4.7E-03 4.79 7.OE-03 4.39 9.3E-03 4.112.5E-03 5.42 4.8E-03 4.77 7.1E-03 4.38 9.4E-03 4.102.6E-03 5.38 4.9E-03 4.75 7.2E-03 4.36 9.5E-03 4.092.7E-03 5.34 5.OE-03 4.73 7.3E-03 4.35 9.6E-03 4.082.8E-03 5.30 5.1E-03 4.71 7.4E-03 4.34 9.7E-03 4.072.9E-03 5.27 5.2E-03 4.69 7.5E-03 4.32 9.8E-03 4.063.OE-03 5.23 5.3E-03 4.67 7.6E-03 4.31 9.9E-03 4.053.1E-03 5.20 5.4E-03 4.65 7.7E-03 4.303.2E-03 5.17 5.5E-03 4.63 7.8E-03 4.28

10~2 well functions

u W(u) u W(u) u W(u) u W(u)

l.OE-02 4.04 3.3E-02 2.87 5.6E-02 2.36 7.9E-02 2.04UE-02 3.94 3.4E-02 2.84 5.7E-02 2.34 8.OE-02 2.031.2E-02 3.86 3.5E-02 2.81 5.8E-02 2.33 8.1E-02 2.021.3E-02 3.78 3.6E-02 2.78 5.9E-02 2.31 8.2E-02 2.001.4E-02 3.71 3.7E-02 2.76 6.OE-02 2.30 8.3E-02 1.9931.5E-02 3.64 3.8E-02 2.73 6.1E-02 2.28 8.4E-02 1.9821.6E-02 3.57 3.9E-02 2.71 6.2E-02 2.26 8.5E-02 1.9711.7E-02 3.51 4.OE-02 2.68 6.3E-02 2.25 8.6E-02 1.9601.8E-02 3.46 4.1E-02 2.66 6.4E-02 2.23 8.7E-02 1.9501.9E-02 3.41 4.2E-02 2.63 6.5E-02 2.22 8.8E-02 1.9392.OE-02 3.35 4.3E-02 2.61 6.6E-02 2.21 8.9E-02 1.9292.1E-02 3.31 4.4E-02 2.59 6.7E-02 2.19 9.OE-02 1.9192.2E-02 3.26 4.5E-02 2.57 6.8E-02 2.18 9.1E-02 1.9092.3E-02 3.22 4.6E-02 2.55 6.9E-02 2.16 9.2E-02 1.8992.4E-02 3.18 4.7E-02 2.53 7.OE-02 2.15 9.3E-02 1.8892.5E-02 3.14 4.8E-02 2.51 7.1E-02 2.14 9.4E-02 1.8792.6E-02 3.10 4.9E-02 2.49 7.2E-02 2.12 9.5E-02 1.8692.7E-02 3.06 5.OE-02 2.47 7.3E-02 2.11 9.6E-02 1.8602.8E-02 3.03 5.1E-02 2.45 7.4E-02 2.10 9.7E-02 1.8512.9E-02 2.99 5.2E-02 2.43 7.5E-02 2.09 9.8E-02 1.8413.OE-02 2.96 5.3E-02 2.41 7.6E-02 2.07 9.9E-02 1.8323.1E-02 2.93 5.4E-02 2.39 7.7E-02 2.063.2E-02 2.90 5.5E-02 2.38 7.8E-02 2.05

10 ! well functions

u W(u) u W(u) u W(u) u W(u)

.OE-Ol 1.823 3.3E-Ol 0.836 5.6E-Ol 0.493 7.9E-Ol 0.316

.1E-Ol 1.737 3.4E-01 0.815 5.7E-01 0.483 8.0E-01 0.311

.2E-Ol 1.660 3.5E-Ol 0.794 5.8E-Ol 0.473 8.1E-Ol 0.305

.3E-Ol 1.589 3.6E-Ol 0.774 5.9E-Ol 0.464 8.2E-Ol 0.300

.4E-Ol 1.524 3.7E-Ol 0.755 6.OE-Ol 0.454 8.3E-Ol 0.2941.5E-01 1.464 3.8E-01 0.737 6.1E-01 0.445 8.4E-Ol 0.2891.6E-01 1.409 3.9E-01 0.719 6.2E-01 0.437 8.5E-01 0.2841.7E-Ol 1.358 4.OE-Ol 0.702 6.3E-Ol 0.428 8.6E-Ol 0.2791.8E-Ol 1.310 4.1E-Ol 0.686 6.4E-Ol 0.420 8.7E-Ol 0.2741.9E-01 1.265 4.2E-01 0.670 6.5E-01 0.412 8.8E-01 0.2652.OE-Ol 1.223 4.3E-Ol 0.655 6.6E-Ol 0.404 8.9E-Ol 0.2652.1E-Ol 1.183 4.4E-Ol 0.640 6.7E-Ol 0.396 9.OE-Ol 0.2602.2E-Ol 1.145 4.5E-Ol 0.625 6.8E-Ol 0.388 9.1E-Ol 0.2562.3E-01 1.110 4.6E-01 0.611 6.9E-01 0.381 9.2E-01 0.2512.4E-Ol 1.076 4.7E-Ol 0.598 7.OE-Ol 0.374 9.3E-Ol 0.2472.5E-Ol 1.044 4.8E-Ol 0.585 7.1E-Ol 0.367 9.4E-Ol 0.2432.6E-Ol 1.014 4.9E-Ol 0.572 7.2E-Ol 0.360 9.5E-Ol 0.2392.7E-Ol 0.985 5.OE-Ol 0.560 7.3E-Ol 0.353 9.6E-Ol 0.2352.8E-Ol 0.957 5.1E-Ol 0.548 7.4E-Ol 0.347 9.7E-Ol 0.2312.9E-Ol 0.931 5.2E-Ol 0.536 7.5E-Ol 0.340 9.8E-Ol 0.2273.OE-Ol 0.906 5.3E-Ol 0.525 7.6E-Ol 0.334 9.9E-Ol 0.2233.1E-Ol 0.882 5.4E-Ol 0.514 7.7E-Ol 0.3283.2E-Ol 0.858 5.5E-Ol 0.503 7.8E-Ol 0.322

O well functions

u W(u) u W(u) u W(u) u W(u)

l.OE + 00 0.219 2. IE+ 00 0.043 3.2E + 00 0.010 4.3E + 00 0.0031.1E + 00 0.186 2.2E + 00 0.037 3.3E + 00 0.009 4.4E + 00 0.0021.2E + 00 0.158 2.3E + 00 0.033 3.4E + 00 0.008 4.5E + 00 0.0021.3E + 00 0.135 2.4E + 00 0.028 3.5E + 00 0.007 4.6E + 00 0.0021.4E + 00 0.116 2.5E + 00 0.025 3.6E + 00 0.006 4.7E + 00 0.0021.5E + 00 0.100 2.6E + 00 0.022 3.7E + 00 0.005 4.8E + 00 0.0011.6E + 00 0.086 2.7E + 00 0.019 3.8E + 00 0.005 4.9E + 00 0.0011.7E + 00 0.075 2.8E + 00 0.017 3.9E + 00 0.004 5.0E + 00 0.0011.8E + 00 0.065 2.9E + 00 0.015 4.OE+ 00 0.0041.9E + 00 0.056 3.0E + 00 0.013 4.1E + 00 0.0032.OE+ 00 0.049 3. IE+ 00 0.011 4.2E + 00 0.003

Source: Illinois Environmental Protection Agency (1990)

APPENDIX C

SOLUBILITY PRODUCT

CONSTANTS FOR SOLUTION AT

OR NEAR ROOM TEMPERATURE

Substance Formula Kjp

Aluminum hydroxideBarium arsenateBarium carbonateBarium chromateBarium fluorideBarium iodateBarium oxalateBarium sulfateBeryllium hydroxideBismuth iodideBismuth phosphateBismuth sulfideCadmium arsenateCadmium hydroxideCadmium oxalateCadmium sulfideCalcium arsenateCalcium carbonateCalcium fluorideCalcium hydroxideCalcium iodateCalcium oxalateCalcium phosphateCalcium sulfateCerium(III) hydroxideCerium(III) iodateCerium(III) oxalateChromium(II) hydroxideChromium(III) hydroxideCobalt(II) hydroxideCobalt(III) hydroxideCopper(II) arsenateCopper(I) bromideCopper(I) chlorideCopper(I) iodideCopper(II) iodateCopper(I) sulfideCopper(II) sulfideCopper(I) thiocyanate

Al(OH)3Ba3(AsO4)2BaCO3BaCrO4BaF2Ba(I03)22H20BaC2O4H2OBaSO4Be(OH)2BiI3BiPO4Bi2S3Cd3(AsO4)2Cd(OH)2CdC2O4BH2OCdSCa3(AsO4)2CaCO3CaF2Ca(OH)2Ca(IO3)26H2OCaC2O4H2OCa3(PO4),CaSO4Ce(OH)3Ce(IO3),Ce2(C2O4)39H2OCr(OH)2Cr(OH)3Co(OH)2Co(OH)3Cu3(As04)2CuBrCuClCuICu(I03)2Cu2SCuSCuSCN

2 x 10-32

7.7 x 1(T51

8.1 x 1(T9

2.4 x 1(T10

1.7 x IQ-6

1.5 x 1(T9

2.3 x 1(T8

1.08 x 1(T10

7 x 1(T22

8.1 x 10-19

1.3 x 10"23

1 x 10-97

2.2 x 1(T33

5.9 x 1(T15

1.5 x 1(T8

7.8 x IQ-27

6.8 x 1(T19

8.7 x 1(T9

4.0 x 10~n

5.5 x 10~6

6.4 x 10~7

2.6 x 10~9

2.0 x 10~29

1.9 x 10~4

2 x 10-20

3.2 x 10-10

3 x 10-29

1.0 x 10~17

6 x 10"31

2 x 10~16

1 x 10-43

7.6 x 10"76

5.2 x 10~9

1.2 x 10~6

5.1 x 10~12

7.4 x 10"8

2 x 10~47

9 x 10~36

4.8 x 10~15

Substance

Iron(III) arsenateIron(II) carbonateIron(II) hydroxideIron(III) hydroxideLead arsenateLead bromideLead carbonateLead chlorideLead chromateLead fluorideLead iodateLead iodideLead oxalateLead sulfateLead sulfideMagnesium ammonium phosphateMagnesium arsenateMagnesium carbonateMagnesium fluorideMagnesium hydroxideMagnesium oxalateManganese(II) hydroxideMercury(I) bromideMercury(I) chlorideMercury(I) iodideMercury(I) sulfateMercury(II) sulfideMercury(I) thiocyanateNickel arsenateNickel carbonateNickel hydroxideNickel sulfideSilver arsenateSilver bromateSilver bromideSilver carbonateSilver chlorideSilver chromateSilver cyanideSilver iodateSilver iodideSilver oxalateSilver oxideSilver phosphateSilver sulfateSilver sulfideSilver thiocyanateStrontium carbonateStrontium chromateStrontium fluorideStrontium iodateStrontium oxalateStrontium sulfate

Formula

FeAsO4FeCO3Fe(OH)2Fe(OH)3Pb3(As04)2PbBr2PbCO3PbCl2PbCrO4PbF2Pb(I03)2PbI2PbC2O4PbSO4PbSMgNH4PO4Mg3(AsO4)2MgCO3SH2OMgF2Mg(OH)2MgC2O4IH2OMn(OH)2Hg2Br2Hg2Cl2Hg2I2Hg2SO4HgSHg2(SCN)2Ni3(AsO4),NiCO3Ni(OH)2NiSAg3AsO4AgBrO3AgBrAg2CO3AgClAg2CrO4Ag[Ag(CN)2]AgIO3AgIAg2C2O4Ag2OAg3PO4Ag2SO4Ag2SAgSCNSrCO3SrCrO4SrF2Sr(IO3),SrC2O4H2OSrSO4

rf^sp

5.7 x 1(T21

3. 5 x 1(T11

8 x 1(T16

4 x 1(T38

4.1 x 1(T36

3.9 x 1(T5

3.3 x IQ-14

1.6 x 10~5

1.8 x 1(T14

3.7 x 1(T8

2.6 x 10~13

7.1 x 1(T9

4.8 x 1(T10

1.6 x 10~8

8 x 1(T28

2.5 x 1(T13

2.1 x 1(T20

1 x 1(T5

6.5 x 1(T9

1.2 x IQ-11

1 x 1(T8

1.9 x 1(T13

5.8 x 1(T23

1.3 x 1(T18

4.5 x 1(T29

7.4 x 1(T7

4 x 1(T53

3.0 x IQ-20

3.1 x 1(T26

6.6 x 10"9

6.5 x 10~18

3 x 10-19

1 x 10-22

5.77 x 1(T5

5.25 x ID'13

8.1 x 10~12

1.78 x 1(T10

2.45 x 1(T12

5.0 x 10"12

3.02 x 10~8

8.31 x 10~17

3.5 x 10"11

2.6 x 10"8

1.3 x 10-20

1.6 x 10~5

2 x 10-49

LOOx 10"12

1.1 x 10-10

3.6 x 10~5

2.8 x 10~9

3.3 x 10~7

1.6 x 10~7

3.8 x 10~7

Substance

Thallium(I) bromateThallium(I) bromideThallium(I) chlorideThallium(I) chromateThallium(I) iodateThallium(I) iodideThallium(I) sulfideTin(II) sulfideTitanium(III) hydroxideZinc arsenateZinc carbonateZinc ferrocyanideZinc hydroxideZinc oxalateZinc phosphateZinc sulfide

Formula

TlBrO3TlBrTlClTl2CrO4TlIO3TlITl2SSnSTi(OH)3Zn3(As04)2ZnCO3Zn2Fe(CN)6Zn(OH)2ZnC2O42H2OZn3(PO4),ZnS

K^^sp

8.5 x IQ-5

3.4 x 1(T6

1.7 x 1(T4

9.8 x ID'13

3.1 x 1(T6

6.5 x 1(T8

5 x ID'21

1 x ID"25

1 x 1(T40

1.3 x 1(T28

1.4 x 1(T11

4.1 x 1(T16

1.2 x 1(T17

2.8 x 1(T8

9.1 x IQ-33

1 x 10-21

^ The solubility of many metals is altered by carbonate complexation. Solubility predictions without consideration forcomplexation can be highly inaccurate.Source: Benefield, L. D. and Morgan J. S. 1990. Chemical precipitation. In: AWWA, Water Quality and Treatment. NewYork: McGraw-Hill. Reprinted with permission of the McGraw-Hill Co.

APPENDIX D

FREUNDLICH ADSORPTION

ISOTHERM CONSTANTS FOR

TOXIC ORGANIC COMPOUNDS

Compound

PCBBis(2-ethylhexyl phthalate)HeptachlorHeptachlor epoxideButylbenzyl phthalateToxapheneEndosulfan sulfateEndrinFluorantheneAldrinPCB- 1232/?-EndosulfanDieldrinAlachlorHexachlorobenzenePentachlorophenolAnthracene4-NitrobiphenylFluoreneStyreneDDT2-Acetylaminofluorenea-BHCAnethole3,3-DichlorobenzidineX-BHC (lindane)2-ChloronaphthalenePhenylmercuric acetateCarbofuran1 ,2-DichlorobenzeneHexachlorobutadiene/?-Nonylphenol4-DimethylaminoazobenzenePCB- 1221DDEm-XyleneAcridine yellowDibromochloropropane (DBCP)Benzidine dihydrochlorideP-BHC«-Butylphthalate^-Nitrosodiphenylamine

K(mg/g)(L/mg)l/n

14,10011,3009,3202,1201,520

950686666664651630615606479450436376370330327322318303300300285280270266263258250249242232230230224220220220220

l/n

1.031.50.920.751.260.740.810.800.610.920.730.830.510.260.600.340.700.270.280.480.500.120.430.420.200.430.460.440.410.380.450.370.240.700.370.750.120.510.370.490.450.37

Compound

SilvexPhenanthreneDimethylphenylcarbinol4-Aminobiphenyl^-Naphthol/7-Xyleneof-EndosulfanChlordaneAcenaphthene4,4'-Methylene-bis-(2-chloroaniline)Benzo[fc]fluorantheneAcridine orangea-NaphtholEthylbenzeneo-Xylene4,6-Dinitro-o-cresola-Naphthylamine2,4-Dichlorophenol1 ,2,4-Trichlorobenzene2,4,6-Trichlorophenol/i-Naphthylamine2,4-Dinitrotoluene2,6-Dinitrotoluene4-Bromophenyl phenyl ether/7-Nitroaniline1 , 1 -DiphenylhydrazineNaphthaleneAldicarb1 -Chloro-2-nitrobenzene/7-Chlorometacresol1 ,4-DichlorobenzeneBenzothiazoleDiphenylamineGuanine1 ,3-DichlorobenzeneAcenaphthyleneMethoxychlor4-Chlorophenyl phenyl etherDiethyl phthalateChlorobenzeneToluene2-NitrophenolDimethyl phthalateHexachloroethane2,4-Dimethylphenol4-NitrophenolAcetophenone1 ,2,3,4-TetrahydronaphthaleneAdenineDibenzo[0,/*]anthraceneNitrobenzene2,4-D3,4-Benzofluoranthene

^mg/gXL/mg)1/"

215215210200200200194190190190181180180175174169160157157155150146145144140135132132130124121120120120118115115111110100100999797787674747169686757

l/n

0.380.440.340.260.260.420.500.330.360.640.570.290.320.530.470.270.340.150.310.400.300.310.320.680.270.160.420.400.460.160.470.270.310.400.450.370.360.260.270.350.450.340.410.380.440.250.440.810.380.750.430.270.37

Compound

2-ChlorophenolTetrachloroethyleneo-Anisidine5-BromouracilBenzo[#]pyrene2,4-DinitrophenolIsophoroneTrichloroethyleneThymine5-Chlorouracil7V-Nitrosodi-tt-propylamineBis(2-Chloroisopropyl) ether1,2-Dibromoethene (EBD)PhenolBromoform1 ,2-Dichloropropane1 ,2-/raHs-Dichloroethylenecis- 1 ,2-DichloroethyleneCarbon tetrachlorideBis(2-Chloroethyoxy) methaneUracilBenzo[g,/z,*]perylene1 , 1 ,2,2-Tetrachloroethane1 ,2-DichloropropeneDichlorobromomethaneCyclohexanone1 , 1 ,2-TrichloroethaneTrichlorofluoromethane5-Fluorouracil1 , 1 -DichloroethyleneDibromochloromethane2-Chloroethyl vinyl ether1 ,2-DichloroethaneChloroform1,1,1 -Trichloroethane1 , 1 -DichloroethaneAcrylonitrileMethylene chlorideAcroleinCytosineBenzeneEthylenediaminetetraacetic acidBenzoic acidChloroethaneTV-Dimethylnitrosamine

^(mg/g)(L/mg)1/w

51515044343332282725242422212019141211111111118.27.96.25.85.65.54.94.83.93.62.62.51.81.41.31.21.11.00.860.760.596.8 x 10~5

\/n

0.410.560.340.470.440.610.390.620.510.580.260.570.460.540.520.590.450.590.830.650.630.370.370.460.610.750.600.241.00.540.340.800.830.730.340.530.511.160.651.61.61.51.80.956.6

1ThC isotherms are for the compounds in distilled water, with different activated carbons. The values of K and \/n shouldbe used only as rough estimates of the values that will be obtained using other types of water and other activated carbon.Source: Snoeyink, V. L. 1990. Adsorption of organic compounds. In: AWWA, Water Quality and Treatment. New York:McGraw-Hill. Reprinted with permission of the McGraw-Hill Co.