Annual Meeting, June 15-16 2015, Istanbul, Turkey EMODnet Chemistry Partner contribution: HCMR/HNODC...
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Transcript of Annual Meeting, June 15-16 2015, Istanbul, Turkey EMODnet Chemistry Partner contribution: HCMR/HNODC...
Annual Meeting, June 15-16 2015, Istanbul, Turkey
EMODnet Chemistry
Partner contribution: HCMR/HNODC
WP1: Data collection and metadata
compilation in sea regions: current status
Annual Meeting, June 15-16 2015, Istanbul, Turkey
General overview of the HMCR’s contribution:
Current status (April 2015)
Seawater Sediment Biota
Number of CDIs at beginning: 3268 62
Number of CDIs at year 1: + 1324
Number of CDIs at year 2: + 900
Total number of CDIs (Mediter. & Black Sea)
5492 62
Note 1: For Seawater the number of CDIs is for bottles not CTDs or Buoys (oxygen)
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Total number of stations(=CDIs) per parameter group per matrix:
Group Seawater Sediment Biota
Fertilizers 4339
Silicates 4332
Organic matter 1166
Chlorophyll 702
Partial pressure dissolved gases
4672
Acidity 193
Pesticides and biocides
Antifoulants
Pharmaceuticals
Heavy metals 783 62
Hydrocarbons
Radionuclides
Plastics
Current status
Current status vs Inventory
Seawater* Sediment Biota
Group Med.Sea Currentstatus
Med. Sea Inventory
Black Sea
Current status
Black sea Inventory
Med.Sea Currentstatus
Med. Sea Inventory
Black Sea
Current status
Black sea
Inventory
Med.Sea
Current
Med. Sea
Inventory
Fertilizers 4335 3400 4 4
Silicates 4328 3400 4 4
Organic matter 1148 960 18
Chlorophyll 684 1080 18 21
Partial pressure dissolved gases
4672 3800 30
Acidity 193 172
Antifoulants
Pharmaceuticals
Heavy metals 783 130 39 62 400 39 4
Hydrocarbons 89125 58
Pesticides and biocides
Radionuclides 80 4 7 1
Plastics
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Data quality control performed by the data center:
Type of QC: Seawater Sediment Biota Notes:
Position check Y Y Y
Date/time check Y Y Y
Missing value Y Y Y
Range check Y Y
Spike Y
Pre-existing statistics
Y* Y Y *for NTRA, PHOS,SLCA,DOXY
Visualization and manual checks
Y Y Y
Negative Values Check:
Y Y Y
Manual checks of zeros (but not part of the local software)
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Difficulties encountered:
•Some datasets cannot be processed because the corresponding metadata are missing
•Missing P01 and P09 labels from the elements/compounds result in delay of data processing. Different methods of analysis along the decades demand different P01 and P09 labels increasing the time for processing
•Not uniform units among datasets for the same chemical elements/compounds increase the time of processing
•In some cases, there is a mismatch between the reported datasets and the actual scientist holdings (a time-consuming procedure to find these data)
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Spatial distribution of HNODC’s CDIs uploaded during the 2nd yearSpatial distribution of HNODC’s CDIs uploaded during the 2nd year
2nd Year
Metals in Seawater
15 stations 783 CDIs from 1985 to 2009
Fertilizers, Silicates, Organic matter and Chlorophyll in Seawater
Spatial distribution of CDIs that will be uploaded by HNODC the last year
Spatial distribution of CDIs that will be uploaded by HNODC the last year
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Planning for the last year
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Total number of stations per parameter group per matrixGroup Seawater Sediment Biota
Fertilizers
Silicates
Organic matter +54 +37 (submitted on
May 2015)
Chlorophyll
Partial pressure dissolved gases
Acidity
Antifoulants
Pharmaceuticals
Heavy metals +51 +69(submitted on
May 2015)
+34 ts
Hydrocarbons
+78 +17 tsPesticides and biocides
Radionuclides
Plastics
Planning for the last year
P01 and P09 new labels(some background info)
Group Seawater Sediment Biota
Fertilizers
Silicates
Organic matter 2 new labels in P012 new labels in P09
Chlorophyll
Partial pressure dissolved gases
Acidity
Pesticides and biocides
Antifoulants
Pharmaceuticals
Heavy metals 4 new labels in P09 40 new labels in P0173 new labels in P09
77 new labels in P01
Hydrocarbons 8 new labels in P01 130 new labels in P01
Radionuclides
Plastics
TOTAL 4 in P09 50 in P0175 in P09
207 in P01
Some examples of new P01 parameters
New P01 parameters for Hydrocarbons in SedimentCODE GROUP
CODEUNITCODE
DUMMYVAL
MINPERMISS
VAL
MAXPERMISS
VAL
BEFOREDP
AFTERDP
SHORTTITLE
FULLTITLE
DEFINITION
HCMRAG06 SCAH KGUM -9 0 9 1 3 methyldibenzothiophenes_sed
not specified Quantity or mass of the sum of all isomers of the specified analyte per unit weight of dried unsieved sediment.
HCMRAG01 SCOC UUKG -9 0 999 3 1 aliphTPH_sed
not specified The combined mass of all aliphatic (no benzene rings) compounds that may be extracted per unit weight of dried unsieved sediment using an organic solvent. These are presumed to be sourced from crude oil.
New P01 parameters for Metals in Sediment
CODE GROUPCODE
UNITCODE
DUMMYVAL
MIN PERMISS
VAL
MAXPERMISS
VAL
BEFOREDP
AFTERDP
SIGFIG
SHORTTITLE
FULLTITLE
DEFINITION
HCMR0008 RMIN UMKG -9 0 999 3 2 - Lu_sed<63um
not specified
The quantity or mass of the specified analyte contained in a dried subsample of sediment that passes through a 63 micron sieve.
HCMR0028 RMIN UMKG -9 0 999 3 2 - Gd_sed notspecified
The quantity or mass of the specified analyte contained in a dried sample of sediment.
Examples of P01 mapping for contaminants in BiotaSubstance
NameName
QualifierSynonym Relationship Biological Entity P01 Code P01 Label
cadmium not specified Cd per unit dry weight of
Mytilus galloprovincialis (ITIS: 79456: WoRMS 140481) [Subcomponent: flesh]
MMUSCDXX Concentration of cadmium {Cd} per unit dry weight of biota {Mytilus galloprovincialis (ITIS: 79456: WoRMS 140481) [Subcomponent: flesh]}
alpha-hexachlorocyclohexane
not specified alpha-HCH CAS 319-84-6
per unit wet weight of
Boops boops (ITIS: 169218: WoRMS 127047)
W2931256 Concentration of alpha-hexachlorocyclohexane {alpha-HCH CAS 319-84-6} per unit wet weight of biota {Boops boops (ITIS: 169218: WoRMS 127047)}
In these new P01 codes method is not included, this information should be entered elsewhere in the metadata.
Seawater* Sediment Biota
Group Med.Sea Future Status
Med. Sea Inventory
Black Sea
Future status
Black sea
Inventory
Med.Sea Future Status
Med. Sea
Inventory
Black Sea
Future Status
Black sea
Inventory
Med.Sea
Future Status
Med. Sea
Inventory
Fertilizers 4335 3400 4 4
Silicates 4328 3400 4 4
Organic matter 1148 960 18 + 54 + 37
Chlorophyll 684 1080 18 21
Partial pressure dissolved gases
4672 3800 30
Acidity 193 172
Antifoulants
Pharmaceuticals
Heavy metals 783 + 51 130 39 62 + 69 400 39 + 34 ts 4
Hydrocarbons 89 + 78125 58
Pesticides and biocides + 17 ts
Radionuclides 80 4 7 1
Plastics
Annual Meeting, June 15-16 2015, Istanbul, Turkey
Comparison of Inventory and future submissions