Anne xure I: Certificate of accredited consu...

Annexure I:

Certificate of accredited consultant

Annexure II

Copy of TOR letter TOR Letter

Annexure III

Copy of Earlier EC with compliance report

Annexure IV

Air Water Consent

Annexure V

EC Compliance letter

Annexure VI

Raw data of all AAQ measurement for 12

weeks of all stations as per frequency given in

the NAQQM Notification of Nov. 2009

Annexure VII

Annual report of heath status of workers with

special reference to Occupational Health and

Safety

INDIA PESTICIDES LIMITED • IIPL CIN No . U24112 UP 1984PLC006894

Phase I, UPSIDC Industrial Area, Sandila

District Hardoi PIN 241127 U.P. INDIA

Website: www.indiapesticideslimited.com

Email : [email protected]

To,

The

Om Hospital

Station Road Near - Old Kerosene Depot,

Sandila (Hardoi)

Su b: Agreement of Doctor's visit to the factory.

The Doctor of Om Hospital will visit Mis. India Pesticides Limited once in a week

(Four times a month). We will pay Rs. 15,000.00 (Fifteen Thousands Only) on

monthly basis against above said four visits.

This agreement will be valid up to one year from the date of commencement.

~ ~'P ....~-«5J (Dr. Vineet Verma)

(General Manager) Om HGSpital

India Pesticides Limited Sandi1a Hardoi

Sandila, Hardoi

Dr. Ajay ~ . : tnag ~ r ,

Date: 01.07.2016

Regd. Office: Swarup Bhawan, 35A, Civil lines, Bareilly243 001. Phone: 05812567476 Office: Water Works Road, Aishbagh. Lucknow 226 004 (INDIA)

Tel. : +915222653602,2653603 , 3255885,2653622, 7499494587, Fax: + 915222653610

COrJTROl TERMITE EFFECTIVELY USE CHLORM

Thyro care" Think Thyroid . Think Thyrocare.

"U::O n_~.., Thyrocare ..

· TT c." ~~ e : Thyrocare Technologies Limited q 0-37/3, TTC M I ~ C, Turbhe, Navi Mumbal 400703 Murnbal400 7(Q 022 3090 0000 I 4125 2525 ~ [email protected] e www . thyrocar~ . com

NAME : MR SHYAMVEER SINGH (SOY/M) SAMPLE COLLECTED AT :

REF. BY : INDIA PESTICIDES LTD INOlA PESTICIDES l TDPEsnCIDES l TO. UPSIOC INDUSTRIAL AREA, SANDlLA. HARDOI

TEST ASKED: AAROGYAM 1.2

TEST NAME TECHNOLOGY VAlUE UNITS REFERENCE RANGE

TOTAL TRIIODOTHYRONINE (TJ) C.L.I.A 137 ng/dl 60200

TOTAL THYROXINE (T4) C.L.I.A 10.2 ~g/dl 4 .512

THYROID STIMULATING HORMONE (TSIl) C.I'!>:I.A 3.90 ~IU/rnl 0.35.5

Comment5: SUGGESTING THYRONORMALCY

Ple••e correlate with clinical conditions.

Method:

T3 COMPETITIVE CHEMI LUMINESCENT IMMUNO ASSAY J

T4 COMPETITIVE CHEMI LUMINESCENT IMMUNO ASSAY

TSH ULTRA SENSITIVE SANDWICH CHEMI LUMINESCENT I.MMUNO ASSAY

End of report

Sample Collected on (SCT) : 20 Mar 2017 09:00

Sample Received on (SRT) : 21 Mar 201700:31

Report Relea.ed on (RRT) : 21 Mar 2017 02:38

lO lO o

~ r-..... N ..... o

Sample Type

labcode ·

Barcode

: SERUM

: 200341498/UTT06

: 84474760

Dr.Durgaprasad N Agrawal MD Dr.Caesar Sengupta MD

• Page: 6 ot6

Reporting conditions overleaf (

mailto:[email protected]

Olnlcal Significance

m..

Thyroc are ' ~ Think Thyroid. Think Thyrocare .

.. : Thyrocare Technologies Umlted 9 037/3, TIC M I DC, Turbhe, Navl Mumbal ~ 400703 3090 0000 / 4125 2525 a [email protected] • www.thyrocare.com

NAME

REF. BY

: MR SHYAMVEER SINGH (50Y/M)

: INDIA PESTICIDES LTD

TEST ASKED AAROGYAM 1.2

TEST NAME

SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPEsnODES LTD. UPSIDC

INDUSTRIAL AREA. SANDILA. HARDOI

TECHNOLOGY VALUE UNITS

EST. GLOMERULAR FILTRATION RATE (eGFR) CALCULATED 108 mL/min/1. 73 m2

Reference Range :

> = 90 : Normal

60 89 : Mild Decrease

45 - 59 : Mild to Moderate Decrease 30 44 : Moderate to Severe Decrease

15 29 : Severe Decrease

The normal serum aeatlnlne reference interval does not necessarily retlect a normal GFR for a patient. Because and moderate kidney Injury is poorly inferred from serum creatinine alone. Thus, it Is recommended for clinical

IabOralDrtes to routinely estimate glomerular filtration rate (eGFR), a "gold standard" measurement for assessment rI renal functfon, and report the value when serum creatinine is measured for patients 18 and older, when ..,..optIate and feasibIe_ It cannot be measured easily in clinical practice, instead, GFR is estimated from

-..uans using serum creatinine, age, race and sex. This provides easy to 'Interpret information for the doctor end peHent on the degree of renal Impairment since it approximately equates to the percentage of kidney function nmaJrmg. Application of CKDEPI equation together with the other diagnostic tools in renal medicine will further

IrnprcM! the deb!ction and management of patients with CKD.

Levey AS, Stevens LA, Schmid CH, Zhang YL, Castro AF, 3rd, Feldman HI, et al. A new equation to estimate

glomerular filtration rate. Ann Intern Med. 2009; 150(9):60412.

Please correlate with clinical conditions.

Method : CKDEPI Creatinine Equation

Sample Collected on (SCT) 20 Mar 2017 09:00

Sample Received on (SRT) 21 Mar 2017 00:31

Report Released on (RRT) 21 Mar 2017 02:38

Sample Type SERUM Dr.Durgaprasad N Agrawal .' Dr.Caesar Sengupta MD

Labcode

Barcode

200341498/UTI06

84474760 Page: 1 of6



ThyrCJc are ' ~ ' Think Thyroid . Think Thyrocare .

REPORT

.CotpOrute . O/If~ : Thyrocare Technologies Umited 9 037/3, nc MIOC, 'KJrbhe, Navl Mumbai 400703 3090 0000 /4125 2525 Gii [email protected] • www.thyi.oeare.com


REF. BY : INDIA PESTICIDES LTD


TEST NAME

SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HARDOI


IRON PHOTOMETRY 100.3 IJg/dl

Reference Range :

Male: 70 180

Female: 60 180

Method: FERROZINE METHOD WITHOUT DEPROTEINIZAnON

TOTAL IRON BINDING CAPACITY (TIBC) PHOTOMETRY 364 IJg/dl

Reference Range :

Male: 225 535 IJg/dl Female: 215 535 IJg/dl

Method:· SPECTROPHOTOMETRIC ASSAY

1M. TRANSFERRIN SATURATION CALCULATED 27.55

Reference Range:

13 45

Method: DERIVED FROM IRON AND nBC VALUES


SlIm"" Collected on (SCT) : 20 Mar 2017 09:00

SIImpie ReceIved on (SRT) : 21 Mar 201700:31

Report Released on (RRT) : 21 Mar 2017 02:38

SlimpieType : SERUM Dr.Durgaprasad N Agrawal MD Dr.caesar Sengupta MD

Labcode : 200341498/UTT06 Page: 2 of6

Barcode : 84474760


Thyrocare" Think Thyroid. Think Thyrocare.

Corporate Offtce : Thyrotare Technologies Umlted 9 037/3, TIC M IDC, Turbhe, Navl Mumbai 400703 MIDC,Tu.etQ22 3090 0000 /4125 2525 ~ [email protected] • www.thyrocare.com

: MR SHYAMVEER SINGH (SOY/M)


TEST ASKED : AAROGYAM 1. 2

TECHNOLOGY

SAMPLE COLLECTED AT : INDIA PEsnODES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HAROOI

VALUE UNITS NORMAL RANGETEST NAME

BLOOD UREA NITROGEN (BUN) PHOTOMETRY 15.8 mg/dl 7.920

CREATININE SERUM PHOTOMETRY 0.73 mg/dl 0.61.1

URIC ACID PHOTO"'ETRY 4.4 mg/dl 3.57.2

CALCIUM PHOTOMETRY 9.78 mg/dl 8.810.6

BUN / SR.CREATININE RATIO CALCULATED 21.64 Ratio 9:123:1

PIeaH correlate with clinical conditions.

BUN KINETIC W ASSAY.

SCRE ~n NINE ENZVMAnC METHOD

URIC - Uricase I Peroxidase Method CM.C ARSENAZO III METHOD, END POINT.

WCR DERIVED FROM SERUM BUN AND CREATININE VALUES

s.mple Collected on (SCT) : 20 Mar 2017 09:00

S.mple Received on (SRT) : 21 Mar 2017 00:31


S.mpleType : SERUM Dr.Durgaprasad N Agrawal MD Dr. Caesar Sengupta MD

;; ~ Labcode : 200341498/UTI06 Page: 30f6

Barcode : 84474760Ii ~ -- ~. ..... iiiN --..-&&:0


REF. BY


Thyrocare" Think Thyroid . Think Thyrocare.

Corporate OffIce: Thyrocare Technologies Umlted 9 0-37/3, TIC M 10C, Turbhe, Navj Mumbai 400703 MroC,Tu~~22 ~ 3090 0000 / 4125 2525 [email protected]'ll • www.thyrocare.com

: MR SHYAMVEER SINGH (50Y/M) SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC

: INDIA PESTICIDES L TO INDUSTRIAL AREA, SANDILA, HARDOI

TEST NAME TECHNOLOGY VALUE UNITS 'NORMAL RANGE

TOTAL CHOLESTEROL PHOTOMETRY 282 mg/dl 125-200

HDL CHOLESTEROL DIRECT PHOTOMETRY 54 mg/dl 3580

LDL CHOLESTEROL DIRECT 'PHOTOMll'RY 157 mg/dl 85-130

TRIGLYCERIDES PHOTOMETRY 429 mg/dl 25-200 TCI HDL CHOLESTEROL RATIO CALCULATED 5.3 Ratio 3-5 LDL / HDL RATIO CALCULATED 2.9 Ratio 1.53.5

YLDL CHOLESTEROL CALCULATED 85.8 mg/dl 5 - 40 N~HDLCHOuenE ROL CALCULATED 228.5 mg/dl

-Thyrocare_ Think Thyroid. Think Thyrocare.

[email protected] • www.thyrocare.com

Corporate Offlce : Thyracare Technologies Umlted 9 0-37/3, TTC MIDC, Turbhe, Navi Mumbai 400703 MIDC, TU~d)22 3090.0000 /4125 2525 ~

REF. BY




TEST NAME! TECHNOLOGY

ALKAUNE PHOSPHATASE PHOTOMETRY

BIURUBIN DIRECT PHOTOMETRY

SAMPLE COLLECTED AT : INDIA PESTICIDES LTDPESTlODES LTD. UPSIDC

INDUSTRIAL AREA, SANDILA, HARDOI

VALUE UNITS NORMAL RANGE

102.6 U/I 53 128

0.19 mg/dl

NAME

REF. BY



TEST ASKED : HEMOGRAM

TEST NAME

HbAlc (HPLC NGSP Certified)

HbAlc

ThYfocare" Think Thyroid. Think Thyrocare.

: Thyrocare Technologles Limited 9037/3, TIC M IDC, Turbhe; Navi Mumbai 400703

"' 3090 0000 /4125 2525 ~ [email protected] G www.thyrocare.com

, REPORT -

SAMPLE COLLECTED AT : INDIA PESTIaDES LTDPESTIClDES LTD. UPSIDe

INDUSTRIAL AREA, SANDILA, HARDOI

- 6 PART (DIFF),HBA


• H.P.L.C 4.9 %

Reference Range : "

Below 6.0% - Normal Value

6.0% - 7.0% - Good Control

7.0% - 8.0% - Fair Control

8.0% - 10% - Unsatisfactory Control

Above 10% - Poor Control Method: Fully Automated H.P.L.C. using Biorad Variant II Turbo, NGSP Certified.

AVERAGE BLOOD GLUCOSE ( ABG) CALCULATED 94 mg/dl

Ref..ace bnge :

90 - 120 mgfdl : Excellent Control

121 - 150 mgfdl : Good Control

151 - 180 mgfdl : Average Control

181 - 210 mg/dl : Action Suggested > 211 mgfcl : Panic Value

(Note: Average 6jood Glucose value Is calculated from HBAlc value and It Indicates Average Blood Sugar

level over past three months.) Method : Derived from HBAlc values

Pi.... correlate with dlnlcal conditions.

Sample Collected on (SCT) : 20 Mar 2017 09:00

Sample Received on (SRT) : 21 Mar 2017 00:17

Report Released on (RRT) : 21 Mar 2017 03:51 . Sample Type : EDTA Dr.Durgaprasad N Agrawal MD Dr.Caesar Sengupta MD

Labcode : 200340282/UTT06 Page: 1 of2

Barcode : 84355560



ThYfocare"{1 Think Thyroid . Think Thyrocare.

~~ce : Thyrocare Technololles Umlted 9 D-37/3, TTC M IDC, Turphe, Navl Mumbai - 400703 ImDlal ....'OO 70~ 022 - 3090 0000 /4125 2525 ~ [email protected] ., www.thyrocare.com

NAME : MR SHYAMVEER SINGH (50Y/M) SAMPLE COLLECTED AT :

REF. BY : INDIA PESTICIDES L TO INDIA PESTICIDES LTDPESTICIDES LTD. UPSIDC INDUSTRIAL AREA, SANDILA, HARDOI

TEST ASKED : HEMOGRAM - 6 PART (DIFF),HBA

TEST NAME

TOTAL LEUCOCYTES COUNT

VALUE UNITS REFERENCE RANGE

7.05 X 103 / ilL 4 - 10

NEUlROPHILS 65.2 % 40-80

LYMPHOCYTE PERCENTAGE 26 % 20-40

MONOCYTES 3 .3 % 0-10 .,.EOSINOPHILS 5 % 0-6 e

ThYfocare'" Think Thyroid. Think Thyrocare.

: Thyrocare Technologtes.Limlted ~ 0-37/3, TIC M10C, Turbhe, Navi Mumbai - 400703

@ 022 - 3090 0000/4125 2525 Z· [email protected] • www.thyrocare.com


REF. BY : INDIA PESTICIDES LTD

TEST ASKED: COMPLETE URINE ANALYSIS

SAMPLE COLLECTED AT : INDiA ,PESTICIDES LTDPESTICIDES LTD. UPSIOC INDUSTRIAL AREA, SANDILA, HARDOI

TEST NAME OBSERVAnON UNITS REFERENCE RANGE

• To Obtain Counts In Cells I HPF Divide the Cells I ul ~Y 5


Method: Manual Dipstick Method

- End of report-

---.- - .--- - - ----Sample ~olJected on (SCT) : 20 Mar 2017 09:00

Sample Received on (SRT) : 21 Mar 2017 01:12


COMPLETE URINOGRAM

_RINARY GLUCOSE

URINARY BIURUBIN

URINE KETONE

SPEOFIC GRAVITY

URINE BLOOD

PH

URINARY PROTBN

UROBILINOGEN

NITRITE

URINARY LfUCOCYTES

COLOUR

APPEARANCE

BILE SALT

BILE PIGMENT ·

EPITHEUAl. CEUS

CASTS

,.r-ifrRYSTALS

r.l3ACTERIA

Negative

Negative

Negative

1.01

Negative

6

Negative

0.2

Negative

Negative

Pale Yellow

Clear

Negative

Negative

1-2

Absent

Absent

Absent

mg/dl

mg/dl

mg/dl

Cells/ul·

mg/dl

mg/dl

Cells/ul·

Negative

Negative

Negative

1.003-1.030

Negative

S-8

Negative

Annexure VIII

MSDS of Chemicals

1

Bispyribac-sodium-MATERIAL SAFETY DATA SHEET

Manufacturer/information service:

ZHEJIANG RAYFULL CHEMICALS CO.,LTD ADD: NO.113 PUXING ROAD, PUZHOU INDUSTRIAL PARK, LONGWAN DISTRICT, WENZHOU ZHEJIANG P.R. CHINA Tel: +86-577-88905587 Fax: +86-577-88905567 Email: [email protected] [email protected]

1. Chemical Product Identification

Product Name: Bispyribac-sodium

Molecular Formula: C19H17N4NaO8

Molecular Weight: 452.355

Structural Formula:

Chemical Name: Sodium 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy] benzoate

Form: Solid

Color: White

Odor: Odorless

CAS No.: 125401-92-5

2. Composition / Information on Ingredients

Composition CAS No. Content %

Bispyribac-sodium 125401-92-5 95.0

Other ingredients 5.0

3. Hazards Identification

2

Adverse Human Health Effects: Effect of over exposure: We have never faced the poisoning problem attributed to bispyribac-sodium technical on laboratory researchers, factory workers and users, however, over-exposure experiments on animals showed that the administration of an extra-ordinary

large quantity of bispyribac-sodium technical may cause hypoactivity, abnormal walking and prostration.

4. First Aid Measures

Skin Contact: Wash material off the skin in flowing water or shower with soap. If irritation persists, consult a physician immediately.

Eye Contact: Immediately flush with copious amount of water for at least 15 minutes.

Inhalation: Remove the victim to fresh air and keep him warm and quiet. Get a medical attention immediately. If not breathing, clear the airway and give artificial respiration. If breathing is difficult, give oxygen.

Ingestion: Induce vomiting by giving one or two glasses of water. Get a medical attention immediately. If the victim is unconscious or having convulsions, never give fluids nor induce vomiting.

5. Fire-Fighting Measures

Extinguishing Media: Water, dry chemical powder, foam or carbon dioxide

Special Fire Fighting Procedure: Use water, dry chemical powder or carbon dioxide in extinguishing. For a fire in surrounding area, apply water to cool and protect surrounding equipments. Remove containers, if feasible, from the fire area to safe place immediately. Fire fighters should wear protective gears including a positive pressure self-contained breathing apparatus. Evacuate non essential personnel.

6. Accidental Release Measures

Evacuate non essential personnel by roping the area of leak or spill. Evacuate people to upwind of the spilled area. Remove all sources of ignition; No flares, smoking, or flames in the area immediately. Wear protective gears and never work downwind. For small spills, adsorb with inert materials (e.g. dry sand or earth), then place in a waste chemical container for disposal. Flush residual spill (area) with a plenty of water. Prevent spills from entering sewers, watercourses or low areas.

7. Handling and Storage

Handling: Keep out of reach of children

When handling and spraying the product, wear duty working clothes, cap, gloves, glasses and mask to avoid contact with skin, eyes and inhalation of dust, fog and vapours. After

3

work thoroughly wash hands, face and possible exposed areas of body and change clothing.

Storage: Keep containers tightly closed and store in a cool, dark and dry place.

8. Exposure Controls/Personal Protection

Engineering Controls: The use of local exhaust ventilations is recommended. Containers should be kept tightly closed. Make available emergency showers and eye washes in a work area.

Personal Protective Equipment: Wear chemical cartridge respirator with an organic vapour cartridge, airline respirator, positive pressure self-contained breathing apparatus, safety goggles, gloves and boots as appropriate.

9. Physical and Chemical Properties

Density: 1.29 (20°C)

Boiling Point: Not applicable

Melting Point: 223 - 224°C

Vapor Pressure: 5.04 X 10-9 Pa (25°C)

Solubility in Water: 7.33g/100 ml (25°C)

Solubility in Organic Solvents: Slighly to moderately soluble

Log P (o/w): -1.03 (23°C)

10. Stability and Reactivity

Flash Point: Not applicable

Autoignition Temperature: Not available

Explosion Limit: Not available

Stability and Reactivity: Stable under normal conditions

Hazardous Polymerization: Not available

Incompatibility: Not available

Storage Stability: Stable for 3 years if stored in a cool, dark and dry place.

11. Toxicological Information

Acute Toxicity:

Oral: LD50 (Rat) 4,111 mg/kg (male)

2,635 mg/kg (female)

4

LD50 (Mouse) 3,524 mg/kg (male & female)

Dermal: LD50 (Rat) >2,000 mg/kg (male & female)

Inhalation: LD50 (Rat) >4.48 mg/L (4 hours exp.)

Irritant Properties:

Eye irritation: (Rabbit) Slight irritant

Skin irritation: (Rabbit) Not irritant

Allergenic and Sensitizing Effects: Not sensitizing

Mutagenic Effects:

Amest test: Negative (S-9 Mix + or -)

12. Ecological And Ecotoxicological Information

Fish Toxicity: Bluegill sunfish TLm96 >100 ppm

Daphnia magna TLm48 >100 ppm

Rainbow trout TLm96 >100 ppm

Avian Toxicity: Bobwhite quail Acute LD50 (Oral) >2,250 mg/kg

Bobwhite quail Subacute dietary LC50 >5,620 mg/kg

Mallard duck Subacute dietary LC50 >5,620 mg/kg

Earthworm Toxicity: Acute LC50 >1,000 ppm (14 days exp.)

13. Disposal Considerations

Waste should be disposed of in a chemical incinerator equipped with afterburner and scrubber. Do not dump into sewers or into any body of water.

14. Transport Information

Not applicable.

15. Regulatory Information

Not applicable.

16. Other Information

All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is

5

necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.

Product Name: Captan FS

Page 1 of 5

This revision is issued: June, 2012

MATERIAL SAFETY DATA SHEET Issued by: Arysta Lifescience South Africa Phone: 031 514 5600

Poison Information Centre: 082 446 8946; Tygerberg: (021) 931 6129; Poison Emergency Enquiry: (021) 689 5227

SECTION 1 - PRODUCT & COMPANY IDENTIFICATION

ARYSTA LifeScience South Africa (Pty) Ltd Tel: 031 514 5600 Co. Reg. No.: 2009/019713/07 Fax: 031 514 5611 7 Sunbury Office Park, Off Douglas Saunders Drive, La Lucia Ridge, South Africa, 4019 e-mail: [email protected] Web address: arystalifescience.co.za

Substance: captab Product Name: CAPTAN FS Product Use: Fungicide Creation Date: October 2007 Revision Date: October 13 24 Hr Emergency Number: 082 771 2712 In case of Poisoning: Poison Information Centre 082 446 8946 Tygerberg Hospital: (021) 931 6129 Poison Emergency Enquiries (021) 689 5227 In case of Spillage: HAZMAT: 0800 147 112

SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS

Common name: Captab (South Africa) Chemical Name: N-(trichloromethylthio)cyclohex-4-ene-1,2-dicarboximide (IUPAC) CAS No.: 133-06-2 Chemical Family: N-trihalomethylthio Chemical Formula: C9H8Cl3NO2S (Mol. Wt.: 300.6). Use: Fungicide with protective and curative action. Formulation: Captab: 500 g/kg Flowable fungicide seed-dressing UN number: 3082 Active Ingredient: Captab SYMBOLS: Xn RISK-PHRASE(S): R 36, R 40, R 43

SECTION 3 - HAZARD IDENTIFICATION

Toxicity class: WHO Table; EPA – III A low toxicity fungicide. Likely routes of exposure: Skin and eye contact, inhalation and ingestion. The product may cause eye irritation. Skin contact: Minimally toxic. May cause mild skin irritation and may have moderate sensitizing properties (guinea pig). Ingestion: Minimally toxic. Inhalation: May be irritating to the respiratory system.

SECTION 4 - FIRST AID MEASURES AND PRECAUTIONS

Reactions are not likely to occur unless the absorbed dose is extraordinary. Symptoms of repeated exposure to the product may cause contact dermatitis. When product comes in contact with eyes the effect is redness of and tears. Inhalation: Remove source of contamination or move victim to fresh air and well-ventilated area. Monitor for respiratory distress. Give oxygen or artificial respiration if needed. Seek medical attention if necessary. Skin contact: Remove contaminated clothing, shoes and leather goods. Gently wipe off excess chemical. Wash skin gently and thoroughly with water and non-abrasive soap. Seek medical advice if necessary. Persons who become sensitized may require specialized medical management with anti-inflammatory agents.


Page 2 of 5




Eye contact: Immediately flush the eyes with gently flowing lukewarm water for 20 minutes. Obtain medical attention if necessary. Ingestion: Wash out mouth thoroughly with clean water. In case of ingestion of significant quantities of the fungicide, medical advice should be sought immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Advice to physician: No specific antidotes are available against Captan FS poisoning. If a large amount of Captan FS has been ingested in the last few hours, and if copious vomiting has not already occurred, the stomach must be emptied and steps taken to limit gastrointestinal absorption. If the patient is fully alert and nervous system depression is not anticipated, it is recommended to empty the stomach. When vomiting stops after induced emesis, give activated charcoal and cathartic orally by adding sorbitol to the charcoal slurry. Dosage of Activated Charcoal: Adults and children over 12 years: 50 to 100 mg in 300 to 800 ml water. Children under 12 years: 15 to 30 mg in 100 to 300 ml water. Dosage of Sorbitol: Adults and children over 12 years: 1 to 2 mg/kg body weight to a maximum of 150 mg per dose. Children under 12 years: 1.0 to 1.5 mg/kg body weight to a maximum of 50 mg per dose. If sorbitol is given separately, it should be diluted with an equal volume of water before administration. If there are any indications of central nervous system depression, or if the patient fails to vomit within 30 minutes of Syrup of Ipecac administration, measures should be taken to protect the respiratory tract from aspiration of gastric contents, then the stomach should be emptied by gastric intubation, aspiration and lavage with a slurry of activated charcoal. Install activated charcoal following lavage. Unless diarrhoea has already commenced, include a cathartic to hasten elimination. CAUTION: Do not instill fluid so rapidly that overloading of the stomach leads to vomiting or regurgitation, followed by aspiration. Serious electrolyte disturbances may follow catharsis, especially in young children. If contact with the toxicant has been minimal, administration of charcoal without the cathartic, followed by careful observation of the patient, probably represent optimal management.

SECTION 5 - FIRE-FIGHTING MEASURES

Fire hazard and explosion hazard: Slight fire hazard when exposed to heat or flame. Not highly flammable and not explosive. Hazardous decomposition products: Product releases CSCl2, HCl, SOx, NOx, CO and CO2 when exposed to very high temperatures. Extinguishing agents: Extinguish small fires with carbon dioxide, dry or foam chemical. Water spray can be used for cooling of unaffected stock, but avoid water coming in contact with the product. In case of large fires use water spray, fog or regular foam. Dike fire control water for later disposal. Firefighting: Fight fire from maximum distance. Remove container/bag from fire area if possible. Contain fire control agents for later disposal. Use a recommended extinguishing agent for the type of surrounding fire. Water can be used to cool unaffected containers/bags. Avoid inhaling hazardous vapours. Keep upwind. Personal protective equipment: Fire may produce irritating or poisonous vapours (toxic oxides of carbon, nitrogen and sulphur) of combustion. Fire fighters and others that may be exposed should wear full chemical protective clothing and self-contained breathing apparatus.

SECTION 6 - ACCIDENTAL RELEASE MEASURES (SPILLAGE)

Personal precautions: Avoid contact with skin and eyes. Do not breathe in fumes. For personal protection see Section 8. Environmental precautions: Do not allow entering drains or watercourses. When the product contaminates public waters, inform appropriate authorities immediately in accordance with local regulations. Occupational spill: For small dry spills, sweep up with damp earth or sand or other suitable absorbent and taking care not to raise a dust cloud. Place the material into a clean, dry container and cover for subsequent disposal. All contaminated cleaning materials should be placed in closeable receptacles. In situations where product comes in contact with water, contain contaminated water for later disposal. Do not flush spilled material into drains. Keep spectators away and upwind.


Page 3 of 5




SECTION 7 - HANDLING AND STORAGE REQUIREMENTS

Handling: Avoid contact with eyes, prolonged contact with skin, and inhalation of dust and vapour. Use with adequate ventilation. Wash hands before eating, drinking, chewing gum, smoking, or using the toilet. Remove clothing immediately if the product gets inside. Then wash skin thoroughly using a non-abrasive soap and put on clean clothing. Do not apply directly to areas where surface water is present, or to intertidal areas below the mean high water mark. Water used to clean equipment must be disposed of correctly to avoid contamination. Storage: Keep out of reach of unauthorized persons, children and animals. Store in its original labeled container/bag in shaded, well-ventilated area, away from heat, sparks and other sources of ignition - NO SMOKING. Store in dry area and protect from temperatures below 00C and above 500C. Avoid breaking the container/bag, spillage or leaks. Do not allow the product to become wet or overheated in storage, decomposition, impaired activity or fire may result. Not to be store next to foodstuffs and water supplies. Local regulations should be complied with.

SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION

It is essential to provide adequate ventilation. The measures appropriate for a particular work site depend on how this material is used and on the extent of exposure. Ensure that control systems are properly designed and maintained. Comply with occupational safety, environmental, fire, and other applicable regulations. PERSONAL PROTECTIVE EQUIPMENT: Respirator: An approved full-face respirator suitable for protection from dusts and mists of pesticides is required. Limitations of respirator use specified by the approving agency and the manufacturer must be observed. Respirator with P2 filter is recommended. Acceptable exposure limit for Captan: TLV (USA): TWA: 5 mg/m3; A3 (1996) Clothing: Employee must wear appropriate protective (impervious) clothing, boots, hat and equipment to prevent repeated or prolonged skin contact with this substance. Do not wear leather clothing. Gloves: Employee must wear appropriate chemical resistant protective gloves to prevent contact with this substance. Eye protection: The use of a face-shield is recommended. Emergency eyewash: Where there is any possibility that an employee’s eyes may be exposed to this substance; the employer should provide an eye wash fountain or appropriate alternative within the immediate work area for emergency use.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Solid – off-white amorphous wettable powder. Odour: Faint odour – characteristic. Explosive properties: Not explosive. Flammability: Not highly flammable. pH of a 1% aqueous solution: 6 - 9 Bulk density: 0.64 g/l Storage stability: Stable for 2 years under normal, dry storage conditions in unopened bags/containers. The product is

stable after 14 days at 54 oC (accelerated storage test). Solubility in water: Soluble in water. Melting point: 158 to 164°C. Boiling point: Captab decomposes. Vapour Pressure: 2.01 x 10-4 Pa at a temperature of 50°C (pure). Octanol/Water partition coefficient: KOW = 610.

SECTION 10 - STABILITY AND REACTIVITY

Stability: Considered stable in unopened containers/bags. Slowly decomposed by heat and moisture. No decomposition if stored and applied as directed. Incompatibility: Avoid contact with alkali materials, such as lime and Bordeaux mixture. Contact with these products will reduce fungicidal activity. Hazardous reactions: Hazardous polymerization will not occur.


Page 4 of 5




Hazardous decomposition products: CSCl2, HCl, SOx, NOx, CO and CO2.

SECTION 11 - TOXICOLOGICAL INFORMATION

Acute oral LD50: > 5000 mg/kg in rats. Acute dermal LD50: > 2000 mg/kg in rats. Acute inhalation LC50: > 2.6 mg/l in rats for 4 hours. Dermal sensitization: The product provokes moderate dermal sensitization by skin contact (Guinea pigs – maximization test). Skin irritation: Mildly irritant to skin of rabbits. Eye irritation: Irritating to eyes of rabbits. Carcinogenicity: A two-year study of Captan indicated duodenal tumors in mice after repeated administration of high dose levels. The NOEL (No Observed Effect Level) was 400 ppm. No evidence of carcinogenicity was observed in long-term studies with rats. Information on the mechanism of these tumors establishes a threshold for the duodenal tumors, and indicates that this tumor type is not relevant for human risk assessment at likely exposure levels. Teratogenicity: Animal studies did not detect any teratogenic effects. No human data available. Mutagenicity: Results taken from in-vivo tests suggest that the product is not mutagenic.

SECTION 12 - ECOLOGICAL INFORMATION

Degradability: The product is readily biodegraded in the environment. Mobility: The product has now mobility and does not leach. Accumulation: The product shows no tendency to bio-accumulate in aquatic organisms. ECOTOXICOLOGY: For active ingredients: Birds: LD50: mallard ducks & pheasants > 5000 mg/kg

bobwhite quail 2000 – 4000 mg/kg Fish: Toxic to aquatic organisms (fish and algae), in laboratory experiments. Low toxicity in actual use, due to its hydrolytic instability. LC50 (96 h) bluegill sunfish 0.072 mg/l

harlequin fish 0.3 mg/l brook trout 0.034 mg/l

Bees: ED50 oral: 91 μg/bee contact: 788 μg/bee Daphnia: LC50 (48 h) 7 to 10 ppm Other Aquatic organisms: Moderately toxic to aquatic invertebrates.

SECTION 13 - DISPOSAL CONSIDERATION

Pesticide disposal Contaminated absorbents, used containers, surplus product, etc., should be burnt at > 1000oC in an incinerator, preferably designed for pesticide disposal, or buried in an approved landfill. Comply with local legislation applying to waste disposal. Do not allow material to contaminate ground water system and surface water. Package product wastes: Do not re-use empty container/bags for any other purpose. Do not contaminate dams, rivers, drinking water and boreholes with chemical or used container. Incinerate the material at a facility that complies with local, state and federal regulations.


Page 5 of 5




SECTION 14 - TRANSPORT INFORMATION

UN NUMBER: 3082 ADR/IRD: Class: 9 Substance ID no.: 3082 Hazard ID no.: 90 ITEM: 12(c) PACKING GROUP: III Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG/IMO: Packaging group: III Class: 9 Shipping name: Environmentally hazardous substance, liquid, n.o.s. (contains Captab 500 g/kg) IMDG Page: 9029

SECTION 15 - REGULATORY INFORMATION

Symbol: Xn Indication of danger: Harmful Risk phrases: R 36 May cause eye irritation R 40 Possible risks of irreversible effects. R 43 May cause sensitization by skin contact. Safety phrases: S 1/2 Keep locked up and out of reach children. S 13 Keep away from food, drink and animal feeding stuffs. S 22 Do not breathe dust. S 24/25 Avoid contact with skin and eyes. S 36/37 Wear suitable protective clothing and gloves. S 46 If swallowed seek medical advice immediately and show this container and label.

SECTION 16 - OTHER INFORMATION

Packing: Packed in 1, 2, 5, 10, 20, 25 & 50 kg paper lined bags and/or containers and labeled according to South African regulations and guidelines. Disclaimer: The information on this sheet is not a specification; it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage use of the product. It is not applicable to unusual or non-standard uses of the product nor where instructions or recommendations are not followed. All information is given in good faith but without guarantee in respect of accuracy, and no responsibility is accepted for errors and omissions or the consequence thereof.

1

Carboxin -MATERIAL SAFETY DATA SHEET




Product Name: Carboxin

Molecular Formula: C12H13NO2S


Chemical Name: 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxamide

2. Composition / Information On Ingredients


Carboxin 05234-68-4 97%

Other ingredient - 3%


Component Sympol R phrases

Carboxin Xn R36/38/48

More important danger for the man: none

Dangers for the environment:

Soil DT50

2

If in eyes: Hold eye open and rinse slowly and gently with water for 15-20minutes.Remove contact lenses after first 5 minutes. Then continue rinsing eye. Call a Poison control Center of doctor for treatment advie.

If inhaled: remove person to fresh air. Apply artificial respiration if symptoms indicate. Call a physician.

If on skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20minutes Call a Poison Control Center of doctor for treatment advice.

If swallowed: Call a Poison Control Center of doctor for treatment advice. .Do not induce vomiting unless told to do so by a Poison Control Center or doctor. Do not give anything by mouth to an unconscious person.

5 Fire-Fighting Measures

Fire and explosion hazards: not inflammable and not explosive

Extinguishing media: Non-combustible liquid. Use extinguishing media for underlying cause of fire.

Measures of personal protection: Chemical resistant gloves, protective clothing and eye protection should be wore when handling. Lanuder clothing before reuse. In the absence of adequate ventilation, use NIOSH- certified respiratory protection. Environmental cautions EX: prevent the contamination of the floor and of beds of water.

6 Accidental Release Measures Personal cautions: Avoid all personal contact. Observe good personal hygiene.

Cleaning methods

SMALL SPILLS: Wear protective equipment to prevent skin and eye contamination. Contain-prevent run off into drains and waterways. Use absorbent(soil, sand or other inert material). Collect and seal in properly labelled containers for disposal. Wash area down with detergent and excess water.

LARGE SPILLS: Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contamination and the inhalation of vapours. Contain-prevent run off into drains and waterways. Use absorbent(soil, sand or other inert material). Collect and seal in properly labelled drums for disposal. Wash area down with detergent and excess water. If contamination of crops of crops or waterways has occurred advise emergency services or State Department of Agriculture.

7 Handling And Storage

Handling: wearing protective clothing when handling.

Storage: store in a cold and dry location, be far away from fire, heat, food and feed.

3

Technical protective measures: sufficient ventilation to minimize dust exposure. Protect closed dust handling systems against possible dust explosions. Avoid dust accumulations on building or equipment surfaces.

Fire and explosion protection: not inflammable.

8 Exposure Controls / Personal Protection

Personal protective equipment

Respiratory protection: approved respirator

Hand and skin protection : chemical resistant gloves and protective clothing

Eye protection: goggles

Industrial hygiene: use good industrial hygiene. Wear face shield or goggles, elbow lengh PVC gloves, cotton overalls buttoned to the neck and wrist, washable hat and half face respirator with dust and vapour cartridge. After use and before

eating, drinking or smoking, wash hands, arms and face thoroughly with soap and

water.

9 Physical And Chemical Properties

Appearance: white crystals

Boiling point: not available

Density: 1.45

Water solubility: in water 0.147g/L( 20℃)

Other solubility: Soluble in organic solvents, such as acetone 221.2, methanol 89.33, ethyl acetate 107.7(all in g/L,20)

Ph value: 7.5

Flash point: not-applicable

10 Stability And Reactivity

Reactivity: stable for at least 2 years at ambient temperatures. Stable to hydrolysis at pH 5, pH7, and pH9 (25℃),Ina queous solutions exposed to light,DT50 1.54h (pH 7, 25℃)

Conditions to avoid: In condition of heat and humidity

Hazardous decomposition products: Hydrogen cyanide, cyanide salts.

Hazardous reaction: not applicable

11 Toxicological Information

Swallowed:

4

Moderately toxic, Acute oral LD50 (rat): =1300mg/kg

Eyes:

Eye irritation with contact.

Skin:

Low toxicity, acute dermal LD50 (rat): =1050mg/kg. May cause skin irritation with prolonged exposure.

Inhaled:

Mild irritation to nose and throat.

Long term effects:

No information available.

12 Ecological And Ecotoxicological Information

Aquatic Toxicity

Rainbow trout : 96 hr EC50 2.3 mg/L

Bluegill sunfish : 96 hr EC50 3.6mg/L

Daphnia magna : 48 hr EC50 57 mg/L

Terrestrial Toxicity

Mallard duck : LC50(8d) >5000mg/kg diet

Bee: Not hazardous to bees when used as directed; LD50 >181µg/bee

Environmental Fate:

Carboxin will extensively metabolized in rats and eliminated mainly in urine and , to a lesser extent, faeces. Major metabolites in urine are p-hydroxylated carboxin sulfoxide.4-acetamidophenol and its O-glucuronide.

13 Disposal Considerations

Triple or preferably pressure rinse containers before disposal. Add rinsings to spray tank. Do not dispose of undiluted chemicals on site. If recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, break, crush or puncture and bury empty containers in a local authority landfill. If no landfill is available bury the containers below 500mm in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots. Empty containers and product should not be burnt.


Not applicable.

5


Not applicable.


All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.

1

Chlorothalonil -MATERIAL SAFETY DATA SHEET




Product Name: Chlorothalonil

Molecular Formula: C8Cl4N2


Structural Formula:

Chemical Name: Tetrachloroisophthalonitrile (IUPAC)

Form: crystals

Colour: Colourless

Odour: with a slightly pungent odour

CAS No.: 1897-45-6

2. Composition / Information On Ingredients


Chlorothalonil 1897-45-6 98.0

Others ingredients 2.0


2

Symptoms of Acute Exposure ：An extremely severe irritant to eyes. May cause severe skin irritation and contact dermatitis. Allergic skin reactions are possible.

Hazardous Decomposition Products ：Can decompose at high temperatures forming toxic gases.

Unusual Fire, Explosion and Reactivity Hazards ：During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.


Skin: Remove contaminated clothes. Rinse and then wash skin with plenty of water immediately.

Eyes: Rinse with plenty of water for several minutes (remove contact lenses if easily possible) immediately.

Ingestion: If swallowed induce vomiting by tickling the back of throat. Be quiet and call a

physician

Notes to physician: No specific antidote if ingested. Treat symptomatically.


Extinguishing media

To be used: Powder, water spray, foam, carbon dioxide.

Don’t use: Not applicable

Particular risk: None

Measures of personal protection: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants.

Environmental cautions

EX: Prevent the contamination of the floor and the beds of water.


Personal cautions: Safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants.

Cleaning methods

EX: The empty container may be decontaminated by rinsing two or three times with water and detergent and scrubbing the sides.

Environmental cautions

EX: Prevent the contamination of the floor and the beds of water.

3

7. Handling And Storage

Handling: Handle the pesticide with gloves and wash the hand after handling. Do not apply to humans, their clothing, or bedding. Do not contaminate food or use on household tanks.

Storage: Store at normal temperatures, away from children, domestic animals, food and feed products, seed and fertilizer. Do not contaminate other stored products or the storage area by handling or storage of this product. Keep in a well-ventilated room.

8. Exposure Controls / Personal Protection

Personal protective equipment

Respiratory protection: Approved respirator

Protective gloves: Rubber gloves

Eye protection: Safety goggles or face shield.

Industrial hygiene: adequate ventilation.

9. Physical And Chemical Properties Appearance: Colourless crystals with a slightly pungent odour;

Melting point: 252.1℃;

Density: 2.0 (20℃);

Water solubility: 0.81 mg/l (25℃);

Other solubility: In xylene 80, cyclohexanone, dimethylformamide 30, acetone, dimethyl

sulfoxide 20, kerosene 9.

Incompatibility(Materials to Avoid): Incompatible with oils;

Hazardous reaction: The substance decomposes on heating and on burning producing toxic and corrosive fumes including hydrogen chloride and nitrogen oxides.

11. Toxicological Information

4

Acute oral LD50 : >5000mg/kg (rat)

Acute dermal LD50 : >10000mg/kg (rabbit)

Acute inhalation LC50 (1hour) :>4.7mg/L 9 (rat)

Contact with the skin:Modertate irritation (rabbit);

Contact with the eyes: Severe irritation (rabbit).

Reproductive effects: Administration of high doses of chlorothalonil to pregnant rabbits through the stomach during the sensitive period of gestation was required to induce abortion in 4 of the 9 mothers. This and other studies suggest that chlorothalonil will not affect human reproduction at expected exposure levels.

Teratogenic effects: Long-term studies indicate that high doses fed to rats caused reduced weight gains for males and females in each generation studied. Female rats given high doses of chlorothalonil through the stomach during the sensitive period of gestation had normal fetuses, even though that dose was toxic to the mothers. A study of birth defects in rabbits showed no effects. Chlorothalonil is not expected to produce birth defects in humans.

Mutagenic effects: Mutagenicity studies on various animals, bacteria, and plants indicate that chlorothalonil does not cause any genetic changes. The compound is not expected to pose mutagenic risks to humans.

Carcinogenic effects: Based on evidence from animal studies, chlorothalonil's carcinogenic potential is unclear. Male and female rats fed chlorothalonil daily over a lifetime developed carcinogenic and benign kidney tumors at the higher doses. In another study, where mice were fed high daily doses of chlorothalonil for 2 years, females developed tumors in the fore-stomach area (attributed to irritation by the compound) and males developed carcinogenic and benign kidney tumors.

Organ toxicity: Chronic studies of rats and dogs fed high dietary levels show that chlorothalonil is toxic to the kidney. In addition to less urine output, changes in the kidney included enlargement, greenish-brown color, and development of small grains.

12. Ecological And Ecotoxicological Information

Effects on birds: Chlorothalonil is practically nontoxic to birds. The LD50 in mallard ducks is 5000 mg/kg. Most avian wildlife are not significantly affected by this compound.

Effects on aquatic organisms: Chlorothalonil and its metabolites are highly toxic to fish, aquatic invertebrates, and marine organisms. Fish, such as rainbow trout, bluegill, and channel catfish are noticeably affected even when chlorothalonil levels are low (less than 1 mg/L). The LC50 is 0.25 mg/L in rainbow trout, 0.3 mg/L in bluegills, and 0.43 mg/L in channel catfish. Chlorothalonil does not store in fatty tissues and is rapidly excreted from the body. Its bioaccumulation factor is quite low . Effects on other organisms: The compound is nontoxic to bees.

5

13. Disposal Considerations Disposal must be in accordance with applicable local regulations. Remove nonusable solid materials and/or contaminated soil for disposal in an approved and permitted landfill. Do not flush into surface water or sanitary sewer systems. Spillage disposal: Do not wash away into sewer. Do not let this chemical enter the environment. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place.


Not applicable.


Not applicable.


All information and instructions provided in this Material Safety Data Sheet (MSDS) are based on the current state of scientific and technical knowledge at the date indicated on the present MSDS and are presented in good faith and believed to be correct. This information applies to the product as such. In case of new formulations or mixes, it is necessary to ascertain that a new danger will not appear. It is the responsibility of persons on receipt of this MSDS to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. If the recipient subsequently produce formulations containing this product, it is the recipients sole responsibility to ensure the transfer of all relevant information from this MSDS to their own MSDS.

Phase I, UPSIDe, IndustrtalArea, Sandila

Olstrict·HardOl-241127 .P. INDIA Website : IWW indiapesticldeslimited.com

E-mail : [email protected]

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PROJECT DETAIL

Mis India Pesticides Pvt. Ltd (Sandila Unit) is located at Plots No. K-6, 7, 8, 9 and K-IO, Phase - I,

UPSIDC Industrial Area, Tehsil-Sandila, Hardoi-(Uttar Pradesh) and total land area is about 2.67

hectares. Industry salient features are given below:

Plot No. ! K-6,7,8 ,9 and 10, (K-2- K-II and D2-D4)*

Location UPSIDC Sandi la, Village Mahfona, Tehsi l-

Sandila,Hardoi, Uttar Pradesh .

Latitude 27° OS' 30.67" N

Longitude 80° 27' 14.97" E

I Nearest State Highway SH-25 (Adjacent to Site - S)

Nea rest Railway Station Sandil a (4 km - W)

Nearest Airport Amausi (70 km)

Nearest Town Sandila Town (6 km)

Project Site is Iocatcd within the Notified Industrial Area ofUPSIDC

*Requcst for inclusion of additional plots made to MoEF&CC on 06 September 2016 vide

letter no. IAiUP/IND2/S8820/2016 consent already granted by the UPPCB to include all the

proposed land as given.

CURRENT STATUS OF POINT - WISE COMPLIANCE

A. SPECIFIC CONDITION

I. State Pollution Control Board may grant

~ 'consent to operate' atter ensuri ng comptete

shifting of dumped hazardous waste from the

I other plant premises of Mis India Pesticides

[' I imited at Lucknow to authorized secure landtiU

I. Air & Water Consent is granted from

UP Pollution Control Board. The

copy of Air & Water Consent is

enclosed as Annexure- J.

11.

Ill.

IV.

V.

site.

National emIssIon standard for Pesticide

manufacturing and formulation industry issued

by Ministry vide G.S.R 46(E) dated 3'd

February 2006 and amended time to time shall

be followed by the unit.

Mlilticyclone followed by bagfilter along with

adequate slack height shall be provided to rice

husk fired boiler and thermic fluid heater to

control particulate emissions.

Two stage water scrubber followed by alkali

scrubber shall be provided to process vent to

control S02, HCL, HBr, H2S and CL2emission.

Two stage water scrubbers shall be provided to

process vent to control NHJ emissions. P20 S

shall be controlkd by water scrubber followed

by demister. The scrubber water shal :1 be sent to

ETP for further treatment. Efficiency of

scrubber shall be monitored regulady and

maintained properly. Scrubbers vent shall be

provided within on-line detection and alarm

system to indicate higher than permissible value

of controlled parameters. At no time, the

emission levels shall go beyond the prescribed

standards. The system should be interlocked

with the pollution control equipments so that in

case of any increase III pollutants beyond

permissible limits, plant should be

automatically stopped. Stack monitoring shall

be done regularly and report sha'll be submitted

to UP Poiliution Control Board (UPPCB) and

Ministry's regional office at Lucknow.

rn order to control odour, outlet of process vents

II. Ii Plant has been designed to ensure I

this. The copy of emission test

reports is enclosed as Annexure-2.

III. The nce husk boiler and hot air

generator are equipped with multi

cyclone and bagfilter and stack

height of 30 meters

IV. Two stage water scrubber followed

by aLkal i scrubber has been provided

for process vent gases like HCI &

Cb which are emission gases emitted

during present products

manufacturing. The scrubber water is

being sent to ETP for further

treatment. There is no emission of

NH3 and P20 S 111 the present

prod ucti on process. Scrubbers are

monitored at every 6 hours for

alkalinity.

Efficiency of scrubbers is monitored

regularly, the monitoring reports is

enclosed as annexure-2.

V. As informed earl ier the process vents

I

VI.

VII.

shall be connected to the incinerator.

In plant control measures for checking fugitive

emission from all the vulnerable sources shall

be provided. Fugitive emission shall be

controlled by providing closed storage, closed

handling & conveyance of chemicals/materials,

mul.ti cyclone separator and water sprinkling

system. Dust suppression system including

water sprinkling system shall be provided at

loading and unloading areas to control dust

emission. Fugitive emission in the work zone

environment, product, raw material storage area

etc. shall be regularly monitored and records

maintained. The emission shall conform to the

limits slipulated by the UPPCB.

For further control of fugitive emission,

fol'lowing steps shall be followed:

a. Closed handling system shall be provided

for chemicals.

b. Reflux condenser shall be provided over

reactor

c. System of leak detection and repair of

pUlllp/pipeline based on preventive

maintenance.

d. The acids shall be taken from storage tanks

to reactors through trap recei ver and

condenser operated on chilled water.

e. Cathodic protection shall be provided to the

underground solvent storage tanks.

VI.

VII.

have been connected to scrubber.

Currently no incinrable gases are

emitted. Whenever the product mix

requires the installation of

incinerator, the same shall be

provided.

CJ.osed storage, handling and

conveyance system have been

provided along with water sprinkling

system. Multi cyclone separators I

have been provided in the bagging

area. Regular monitoring of fugitive

emission is being performed. The

Ambient Air analysis report IS


a. Closed handling system is

provided for chemicals.

b. Reflux condenser is provided

over reactors.

c. System for leak deduction of

chlorine has been installed

Preventive maintenance of all

the critical equipments and

pumps is followed with proper

record keeping.

d. Trap receiver /Priming pots is

connected with pumps.

e. There is no underground storage

tank for storage of sol vents for

the present products.

VIII.

IX .

X.

XI.

XII.

~

A proper leak detection and repair (LDAR)

program for pesticide industry shall be prepared

and implemented as per CPCB guidelines.

Focus shall be given for prevention of fugitive

emissions for which preventive maintenance of

pump, valves, pipelines are required. Proper

maintenance of mechanical seals of pumps and

valves shall be given. A preventive maintenance

schedule for each unit shall be prepared and

adhered to.

Continuous monitoring system for VOCs, Hel,

HBr and chlorine, shall be installed at all

important places/areas. Effective measures shall

be taken immediately. When monitoring resu lts

indicate above the permissible limits. All

necessary steps shall be taken for monitoring of

chlorine, HCI and HBr as well as VOCs in the

proposed plant.

Alarm for chlorine leakage if any the liquid

chlorine storage area shall be provided along

with automatic stalt of the scrubbing system.

The gaseous emission DG set shall be dispersed

through adequate stack height as per CPCB

standards . Acoustic enclosure shall be provided

to the DG sets to mitigate the noise pollution.

Tile company shall upload the status of

compliance of the stipulated environmental

clearance conditions, including result of

monitoring data on its website and shall update

the same periodically it shall simultaneollsly be

VIII.

IX

X

XI

XII

A leak deduction and repair program

has been formulated and is pali of

the production process. Preventi ve

maintenance of all the critical

equipments and pumps is followed

with proper record keeping.

We are regularly monitor ambient air

for the parameters S02, NOx, SPM

(PM 1o & PM 2.5, ), C1 2, HCL, HBr &

CO the repolis is attached as

annexure-2. There is no emission of

VOC' s and HBr during the present

manufacturing operation.

Alarm for chlorine leakage is

instaUed 111 the liquid chlorine

storage area along with automatic

start of the scrubbing system.

All the D.G sets have proper stack

height along with acoustic enclosure.

a. The compliance repOli is

regul arly submitted to the

MoEF&CC and UPPCB.

b. The compl iance repolt IS

regularly uploaded on the

company website. sent to the regional office of MoEF the

XIII.

XIV.

xv.

respective zonal office of CPCB and the

UPPCB. The levels of PM IO, S02, Nox, VOCs,

HCI, HBR, CO and HC (Methane and Non-

Methane) in ambient air and emission from the

stacks shall be monitored and displayed at a

convenient location near the main gate of the

company and at important publ ic places.

Chilled brine circulation system shall be

provided condensate sol vent vapors and reduce

solvent losses. It shall be ensured that solvent

I recovery shall not be less than 95%

Solvent management shall be carried out as

follows:

f. Reactor shall be connected to chilled brine

condenser system.

g. Reactor and solvent handling pump shall

have mechanical seals to prevent leakages.

h. The condensers shall be provided with

sufficient HTA and residence time so as to

achieve more than 95% recovery.

I. Solvent shall be stored in a separate space

specified with all safety measures.

J. Proper earthing shall be provided in all the

electrical equipment wherever solvent

handling is done.

k. Entire plant shall be flame proof. The

solvent storage tanks should be provided

with breather valve to prevent losses.

Total water requirement from groLind water

source shall not exceed 135m3/day and prior

permission shall be obtained from the

CGWA/SGWA.

Xlli.

XIV.

XV.

c. We regularly monitor and

display ambient air and stack

emission near the main gate of

company which IS distinctly

visible to the public.

Has been provided as directed

Currently no solvent based product is

being manufactured.

Solvent management will be

complied with before start of

production of solvent based

products, however reactors are

connected to chil iled brine condenser

system and pumps are provided with

flame proof motors and electric

connections.

Central Ground Water authority

permission has been granted vide

letter no.

(521 )INR/CGWA/20 13-1850 dated

14/11/2014. We monitor daily water

21-4

XVI.

XVII.

XVIII.

XIX.

As proposed industrial effluent generation shall XVI.

not ex.ceed 60 m3/day effluents shall be

segregated into high COD, high TDS and low

CODITDS effluent steams. High COD

effluent/mother liquor shall be incinerated. High

TDS effluent shall be treated through stripper

followed by MEE. Low COD/TDS effluent

shall be treated in ETP. Treated effiuent shall be

recycled/ reused within the factory premises.

Water quality of treated effluent shall be

monitored regularly and monitodng report shall

be submitted to the UPPCB. Domestic

wastewater shall be treated n STP.

No effluent shall be discharged outside the XVII.

premises and "Zero" discharge concept shall be

adopted.

Process eftluent/any waste water shall not be . XVIII.

allowed to mix. storm water. Strom water drain

shall be passed through guard pond.

Incinerator comprising primary & secondary XIX

chamber shall be designed as per CPCB

guidelines . S02, NOx, HCL and CO emission

consumption i~ our plant. The record I.

of water consumption is enclosed as

annxure-3.

The industry is a zero liquid

discharged industry. All the waste

water generated during the process

are treated in a 150 KLD treatment

plant consisting of one equalization

tank, sparger filter (for removed of

suspended inspirits), steam stripper

(for removal of organic compounds.

The em uents from here are taken to

a two stage RO system. . The

permeate IS recycled back In the

process and the reject is further

evaporated in MEE. The condensates

used in process and solid residue

send to TSDF.

AS described the industry is a Zero

liquid discharge unit removed solids

from MEE arc regularly sent to

TSDF. A sample copy of Frol11-1 0 is


Recovered water frol11 RO & MEE is

recycled in the plant.

Process effluent/any waste water IS

not allowed to mix with storm water.

Strom water drai ns are separated and

entire storm water is collected in

impervious guard pond.

Whenever the product mix requires

the installation of incinerator we

stand committed to instal l the same.

S02, NOx, HCL and CO are beingshail be monitored in the stack regularly. I regularly monitored in stack.

Hazardous chemicals shall be stored in tank in XX Flame arresters shall be provided on

tank forms, carboys etc. Flame arresters shall be

xx.

tank farm when ever solvents are

provided on tank farm. Sol:vent transfer shall be stored.

by pumps.

The company shall obtain authorization for XXI We have membership of UP Waste

collection, storage and disposal of hazardous

XXI.

Management Project and we are

waste under the Hazardous waste (Management sending all the generated hazardous

handling and trans-boundary movement) Rules, waste to TSDF. The sample copy of

2008 and amended as on date for management From-lOis enclosed as annexure-4.

of hazardous waste and prior permission from

UPPCB shall be obtain for disposal of solid I

hazardous waste in the TSDF measure shall be

taken for fine fighting facilities 111 case of

emergency membership of TSDF of hazardous

waste disposal sha'" be obtained.

XXII. As proposed, ETP slludge & 'ncineration ash XXII No incinerable ash IS being

shall be sent to TSDF site. High calorific vallues generated.

waste such as spent organic shall be inci nerated. We have membership of UP waste

management project and we are

sending all the generated ETP sludge

to TSDF. The sample copy of From-

lOis enclosed as annexure-4.

XXIII. The company shall strictly comply with the rule XXIII We are complying with the '

& guideline under manufacture, storage and manufacture, storage and import of

impact of hazardous chemicals (MSIHC) rules Hazardous Chemicals (MSIHC)

1989 as amendment in October 1994 & January rules 1989. Under its compliance we

2000. A II transportation of hazardous chemicals ha ve prepared -

shall be as per the Motor vehicle Act (MYA) i. Notification of Site report I

1989. (Schedule-7)

ii. Safety report (Schedule-8)

iii. On-Site emergency plan

XXIV . The company shall undertake following waste

minimization measures.

a. Metering & control of quantities of active

ingredients to minimize waste.

b. Reuse by products from the process as raw

materials or as raw material substitutes in

other process.

c. Use of automobile filling to minimize

spillage.

d. Use of close feeds system in to batch

reactors.

e. Venting equipment through vapour I

recovery system. i

f. Use of high pressure hoses for equipment

clearing to reduce waste water generation.

XXV. The unit shall make the arrangement for

protection for possible fire hazards during

manufacturing process in mater·ial handling.

I Fire fighting system shall be as per the norms.

XXVI. Occupational health survei lIance of the workers

shall be done on a regular basis and records

mainta,ined as per the factory Act.

XXVII. Green belt shall be developed at least in 33% of

(Schedule-II)

iv. Safety Audit (Rule-l 0)

And these reports have been

submitted to concerning authorities.

XXIV Rotameter, Level Gauges weighing

balance & close feed system are

provided by-products are reused in

process. Automated filling system

has been installed. Batch reactor has

been provided with closed feed

system. Venting equipment has been

installed. High pressure hoses will be

used for clearing.

XXV I We are fdlly equipped with tire

fighting & inbuilt safety systems.

We have No-objection certificate

from UP fire department. The copy

of NOC of fire fighting & inbuilt

safety system is enclosed as

annexure-5.

XXVI Occupational health center is

provided and employee 's medical

record is maintained. As per

Factories rules i 950, the med ical

record of employees is maintained in

Form-17 & 27.

XXVII 500 trees of various species have

the plant area in and around the plant premises already been planted.

to mitigate the effects of fugitive emission all

around the plant as per the CPCB Guideline in

consultation with DFO. Thick greenbelt with

suitable plant species sha!! be developed around

the proposed pesticides unit to mitigate the

odour problem. Selection of plant species shall

be as per the CPCB guidelines.

XXVIII. Provision shall be made for the housing for the XXVIII Local construction workers

construction labour within the site with all employed. No worker is residing in I

I necessary infrastructure and faci Iities such as the plant premises.

fuel for cooking, mobile toilets, safe drinking

water, medical health care, creche etc. The

hOLlsing may be 111 the form of temporary I

I structure to be removed after the complet,ion of

the project. All the construction \Nastes shall be

managed so that there is no impact on the

surrounding environment

B. GENERAL CONDITION

The prqject authorities shall strictly adhere to I We are committed to comply all

the stipulations made by the UP Pollution the conditions impose in the Air

Control Board. & water consents order of UP

Poll ution Control Board. The

compliance report of Air & Water

consent is enclosed as annexure-

6.

II No further expansion or modi fication in the II *Request for incli.lsion of

plant shall be carried out without prior approval

of the Ministry of Environment and Forests. In

case of deviations or allteration in the project

proposal from those submitted to the ministry of

additional plots made to

MoEF&CC on 06 September

2016 vide letter no.

IA/UP/IND2/58820/20 16

clearance, a fresh reference shall be made to the

ministry to assess the adequacy of conditions

imposed and to add additional environmental

protection measures required, if any

III The location of ambient air quality monitoring III

stations shall be decided in consultation with the

UPPCB and it shall be ensured that at least one

station is installed in the upwind and downwind

directions as well as where maximum ground

level concentration are anticipated.

~

The overall noise levels in and around the plant lV.[v .

area be dept well within the standards by

providing noise control measures including

acoustic hoods, si tencers, enclosures etc. on all I

sources of noise generation. The ambient noise

levels sha II conform to the standards prescri bed

under Environment (Protection) Act, 1986 rules,

1989 viz. 75 dBA (Day Time) and 70 dBA

(night time)

The company shall harvested rainwater from the V.

roof-tops of the building and storm water drains

to recharge the ground water and use the same

water for the process acti vities of the project to

conserve fresh water.

V.

VI. During transfer of materials, spillages shall be VI.

avoided and garland drains be constructed to

avoid mixing of accidental spillages with

domestic waste water and storm water drains .

VII. . Usage of personnel protection equipments by al l VII.

employees / workers shull be ensured .

consent already granted by the

UPPCB to include all the

proposed land as given.

We have made two ambient air

monitoring stations equipped with

RDS & PM2.5 in the up wind &

down wind direction. The regular

ambient air monitoring is done by

our plant. The copy of ambient air

monitoring is enclosed as

annexure-2.

Are being complied with

Rain water storage system is

implemented in our plant along

with impervious guard pond. No

recharge to ground water is

prescribed because of being a

pesticide unit.

[s being complied with.

All the workers have helmet,

safety shoes, nose mask and other

VIII. Training shall be imparted to al.1 employees on

safety and health aspects of chemicals handl ing

pre-emp,loyment and routine periodical medical

examinations for all employees shall be

undertaken on regular basis. Training to all

employees on handlling of chemicals shall be

imparted.

IX The company shall also cQmp'ly with all the

environment protection measures and safeguard

I proposed in the project report submitted to the

ministry. All the recommendation made in the

EIA/EMP 111 respect of environment

management, risk mitigation measure & public

hearing relating to the project shall be

implemented.

X The company shall undertake CSR activit,ies

and all relevant measure for im proving the socio

economic condition of the surroundi ng area.

XI The company shall under take Eco-

development measure including community

welfare measure in the project areas for the

overal ll ~ improvement of the environment.

XII A separate Envi ronmental Management Cel I

equipped with full Iledged laboratory facilities

shal 'l be set up -to carry out the environmental

management and monitori ng function.

I XIII The company shall earmark sufficient funds for

I recurring cost pCI' annum to implement the

conditions stipulated by Ministry of

Environment and Forests as well as the State

Government along wi,th implementation.

Schedule for all the condition stipulated herein.

IX.

X.

XI.

XI l.

XIII.

safety PPs which is required.

We have regularly imparted

safety training through our safety

officers, who is well qualified

from Regional Labour Institute

Kanpur.

Is being complied with.

J

We are doing various activities to

Improve the socio economJC

condition of the surrounding area.

For the eco development of the

area we are in the process to plant

various trees along road side of

the industrial area.

We have separate environment

cell equipped with trained man

power along wi th desired

equipment.

The company is committed to

provide suitable funds for

implementing the condlitions of

clearance.

XIV

XV

XVI

XVII

The funds so earmarked for environmental

management/pol 'llution control shall not be

di verted for any other purpose.

A copy of the clearance letter shall be sent by

the project proponent to concerned Panchayat,

Zila parisad/Municipal corporation, Urban local

Body and the local NGO, if any, from who

suggestion/ representation, of any were recei ved

while processing the proposal.

The project proponent shall also submit six

monthly reports on the status of compliance of

the stipulated Environmental Clearance

condition includ ing result of monitored data

(both in hard copies as well as bye-mail) to the

respective Regiona:11 office of MoEF, the

respective Zona] Office of CPCB and the U.P

Pollution Control Board. A copy of

Environmental Clearance and SIX monthly

compliance status reports shall be posted on the

web side of the company.

The Environmental statement for each financial

31 s1year ending march III form-Vas is

mandated shall be submitted to the U.P.

Pollution Control Board as prescribed under the

Environmental (Protection Rules, 1986, as

amended subsequently, shall also be put on the

website of the company along with the status of

compliance of environmental clearance

conditions and shal l be sent to Lucknow

Regional offices of MoEF by e-mai t.

The project proponent shall inform the public I

that the project has accorded environmental

clearance by the Ministry and copies of the

XIV

XV

XVI

XVII

Not applicable as no public

hearing was held. Industry

located in approved industrial

area of UPSIDC.

I

We are regularly submitted

compliance report to MoEF&CC

& UPPCB.

The last environmental statement

is submitted to UPPCB as

prescri be under Envi ronment

Protection rule 1986. The copy of

submission letter is enclosed as

annexure-7.

Already done.

clearance letter are available with the

SPCB/Committee and may also be seen at

website of the ministry at hrt: //envfor.nic.in.

This shall be advertised within seven days from

the date of issues of the clearance letter, at least

In two local newspaper that are widely

circulated in the region of which one shall be in

the vernacular language of the locality

concerned and a copy of the same shall be

forward to concerned regional Office of the

ministry.

I

XVIII The project authorities shall inform the XVIII Shall be complied with.

Regional office as well as the Ministry, the date

of tinancial closure and final approval of the

project by the concerned authorities and the date

of start of the project.

http:hrt://envfor.nic.in

1

Difenoconazole -MATERIAL SAFETY DATA SHEET




Product Name: Difenoconazole

Molecular Formula: C19H17Cl2N3O3


Structural Formula:

Chemical Name: 1H-1, 2, 4-Triazole, 1-[[2-[2-chloro-4-(4-chlorophenoxy) phenyl]-4-methyl-1, 3-dioxolan-2-yl] metyl]

Form: power

Color: gray white

Odor: Paint

CAS No.: 119446-68-3

2. Composition / Information on Ingredients


Difenoconazole 119446-68-3 95.0

Other ingredients 5.0


2

Symptoms of Acute Exposure: May cause eye irritation. Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases. Unusual Fire, Explosion and Reactivity Hazards: During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.


General: Remove the affected person from the danger zone to a well-ventilated room or to fresh air, and protect from undercooling. In case of suspected poisoning: Immediately call a physician.

Eye Contact: Rinse eyes with clean water for several minutes and immediately call a physician.

Ingestion: Repeatedly administer medicinal charcoal in a large quantity of water. Note: Never give anything by mouth to an unconscious person. Do not induce vomiting.

Skin Contact: Remove contaminated clothing and thoroughly wash the affected parts of the body with soap and water, including hair and under fingernails.

Medical Instructions

Antidote: No specific antidote is known! Apply symptomatic therapy. Experiences Specific to Man: No case of human poisoning is on recor


Suitable Extinguishing Media: Dry chemical extinguisher, foam, carbon dioxide or water spray (do not use direct jet of water).

Special Hazards during Fire Fighting: Combustion products are toxic and/or irritant. Measures have to be taken to prevent the contaminated extinguishing agent from seeping into the ground or from spreading uncontrollably.

Protective Equipment for Fire Fighting: Use self contained breathing apparatus. Wear protective equipment.


Control the spill at its source. Contain the spill to prevent from spreading or contaminating soil or from entering sewage and drainage systems or any body of water. Clean up spills immediately, observing precautions outlined in Section 8. Cover entire spill with absorbing material and place into compatible disposal container. Scrub area with hard water detergent (e.g. commercial products such as Tide, Joy, Spic and Span). Pick up wash liquid with additional absorbent and place into compatible disposal container. Once all material is cleaned up and placed in a disposal container, seal container and arrange for disposition.

3

7. Handling and Storage

Store the material in a well-ventilated, secure area out of reach of children and domestic animals. Do not store food, beverages or tobacco products in the storage area. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

8. Exposure Controls/Personal Protection

Ingestion: Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling.

Eye Contact: Where eye contact is likely, use chemical splash goggles.

Skin Contact: Where contact is likely, wear chemical-resistant (such as nitrile or butyl) gloves, coveralls, socks and chemical-resistant footwear. For overhead exposure, wear chemical-resistant headgear.

Inhalation: A respirator is not normally required when handling this substance. Use effective engineering controls to comply with occupational exposure limits.

9. Physical and Chemical Properties

Flash-Point: 64 °C

Melting point : 78.6℃

Density: 1.40g/cm3@20℃

Vapor pressure; 3.3×10-5mPa@25℃

PH Value: 5 - 8 (1 %; in deionised water) CIPAC MT 75

Solubility: 15mg/l@25℃

Partition coefficient; KowlogP=4.20@25℃

10. Stability and Reactivity

Stability: Stable under normal use and storage conditions.

Hazardous Polymerization: Will not occur.

Conditions to Avoid: None known.

Hazardous Decomposition Products: Can decompose at high temperatures forming toxic gases.

Materials to Avoid: Strong oxidizers.

11. Toxicological Infor

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