ANALYTICAL REPORTThe high-biased CCV in the original run sequence was clearly due to carry over from...

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Sacramento880 Riverside ParkwayWest Sacramento, CA 95605Tel: (916)373-5600

TestAmerica Job ID: 320-4479-1Client Project/Site: Stringfellow Acid Project

For:CH2M Hill Constructors, Inc.3 Hutton Centre DriveSuite 200Santa Ana, California 92707

Attn: Emily Keene

Authorized for release by:10/31/2013 3:01:02 PM

Jill Kellmann, Project Manager II(916)[email protected]

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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SDMS DOCID#1142029

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Table of Contents

Client: CH2M Hill Constructors, Inc.Project/Site: Stringfellow Acid Project

TestAmerica Job ID: 320-4479-1

of 57TestAmerica Sacramento

10/31/2013

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

Isotope Dilution Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57

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Definitions/GlossaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.

Project/Site: Stringfellow Acid Project

Qualifiers

GC/MS VOA

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

GC Semi VOA


B Compound was found in the blank and sample.

Qualifier

X Surrogate is outside control limits


F MS/MSD Recovery and/or RPD exceeds the control limits

HPLC/IC



Qualifier

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not

applicable.

LCMS


F MS/MSD Recovery and/or RPD exceeds the control limits

Qualifier

* LCS or LCSD exceeds the control limits

I Ion Ratio outside of limits, value is EMPC.


* Isotope Dilution analyte exceeds control limits

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Sacramento

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Case NarrativeClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-4479-1


Job ID: 320-4479-1

Laboratory: TestAmerica Sacramento

Narrative

Job Narrative

320-4479-1

Receipt

The samples were received on 10/9/2013 9:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice.

The temperature of the cooler at receipt was 0.7º C.

GC/MS VOA - GRO

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate (MS/MSD) associated with batch 27338.

The closing continuing calibration verification (CCV) for GRO (C7-C12) associated with analytical batch 27338 recovered above the upper

control limit. The samples associated with this CCV were non-detect for the affected analyte. The samples were re-analyzed.

The re-analysis sequence (batch 28211) also had a closing gas CCV that recovered above the upper acceptance limit. The method blank

and some samples had positive detections of the target analyte below the reporting limit. It was determined that the instrument sensitivity

had drifted upwards after the start of the analysis sequence, resulting in a high bias for client and quality control samples. The original

sample injection data is considered more technically sound. The high-biased CCV in the original run sequence was clearly due to carry

over from the previous sample injection which had visible high levels of hydrocarbons near the back end of the C7-C12 GRO window. The

affected samples were all analyzed prior to the sample with severe matrix. There was an additional GRO CCV analyzed after the failing

CCV, that did not bracket these samples, that did meet acceptance limits for the C7-C12 gasoline range, indicating the system had

returned to control.

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate (MS/MSD) associated with analytical batch

27878.


28211.


27955.

The Gasoline Range Organics (GRO) concentration reported for the following sample is due to the presence of discrete peaks:

EPAZ5S8AS03 (320-4479-2).

No other analytical or quality issues were noted.

GC/MS Semi VOA - NDMA

The following samples and associated MB and LCS were not spiked with recovery standard EPAZ5S8AS00 (320-4479-1), EPAZ5S8AS03

(320-4479-2), EPAZ5S8BS00 (320-4479-4), EPAZ5S8CS00 (320-4479-5), EPAZ5S8CS03 (320-4479-6). This error was discovered upon

analysis of the samples. The appropriate amount of recovery standard was added and the sample reconcentrated. The sample was

re-injected and results reported. The recovery of the isotope diltution analytes were within acceptance criteria.

The isotope dilution analyte (IDA) recovery for the following samples were outside acceptance limits: EPAZ5S8BS00 (320-4479-4),

EPAZ5S8CS00 (320-4479-5), EPAZ5S8CS03 (320-4479-6). No corrective action was performed per the laboratory's standard operating

procedure since the recovery was above 10% and the signal to noise criteria was met.

The laboratory control sample (LCS), matrix spike (MS) and matrix spike duplicate (MSD) for prep batch 27542 (analytical batch 28138)

recovered outside control limits for the following analytes: NDMA. These analytes were biased high in the LCS, MS and MSD and were not

detected in the associated samples; therefore, the data have been reported.

The isotope dilution analyte (IDA) recovery for the following samples were outside acceptance limits: EPAZ5S2AS03 DUP (320-4518-2

DU). No corrective action was performed per the laboratory's standard operating procedure since the recovery was above 10% and the

signal to noise criteria was met.

The matrix spike / matrix spike duplicate (MS/MSD) recoveries for prep batch 27934 (analytical batch 28059) were outside control limits.

The associated laboratory control sample (LCS) recovery met acceptance criteria. Additonally, this analyte was biased high in the MS/MSD

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Job ID: 320-4479-1 (Continued)

Laboratory: TestAmerica Sacramento (Continued)

and was not detected in the associated samples. Therefore, the data have been reported.

The laboratory control sample (LCS), matrix spike (MS) and matrix spike duplicate (MSD) for prep batch 27642 (analytical batch 28194)

recovered outside control limits for the following analytes: NDMA. These analytes were biased high in the LCS, MS, and MSD and were

not detected in the associated samples. Therefore, the data have been reported. Additionally, for sample 4452-11 MSD, recoveries were

over the calibration range and is being reported with an E flag.


HPLC

No analytical or quality issues were noted.

GC Semi VOA - DRO

Sample was re-extracted in this batch with a sample duplicate because it was initially overlooked on the first extraction batch. Both sets of

data are reported.

The matrix spike duplicate (MSD) precision for prep batch 27641 (analytical batch 28409) was outside control limits. Non-homogeneity of

the sample matrix is suspected. The associated laboratory control sample / laboratory control sample duplicate (LCS/LCSD) precision

met acceptance criteria.

The surrogate recovery for the following samples was outside control limits: EPAZ5SMW4S00 (320-4479-10). The samples shows

evidence of matrix interference; therefore, re-extraction and/or re-analysis was not performed.

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate (MS/MSD) associated with batch 27435 for

method 8015B_DRO-aqueous.

The laboratory control sample (LCS) associated with samples EPAZ5S8AS00 (320-4479-1), EPAZ5S8AS03 (320-4479-2), EPAZ5S8BS00

(320-4479-4), EPAZ5S8CS00 (320-4479-5), EPAZ5S8CS03 (320-4479-6), EPAZ5S8CS13 (320-4479-7), EPAZ5S8DS00 (320-4479-8),

EPAZ5S8DS03 (320-4479-9) for method 8015-solid was concentrated to approximately 4mL instead of the recommended 8mL on the

concentration bath prior to brining the extract to final volume under nitrogen. This should not affect surrogate or analyte recoveries.


LCMS

No analytical or quality issues were noted.

General Chemistry - Method 9056

The sulfate results for the following samples: (320-4452-11 DU), EPAZ5S31DS53 (320-4452-11), are less than one half the reporting

limit. Because these results are estimated values the RPD limits do not apply for these samples.

The sample duplicate analyzed with batch #28551 did not pass the established RPD limits. The laboratory control sample and all

associated CCV's associated with the following samples: EPAZ5S8AS00 (320-4479-1), EPAZ5S8AS03 (320-4479-2), EPAZ5S8BS00

(320-4479-4), EPAZ5S8CS00 (320-4479-5), EPAZ5S8CS13 (320-4479-7), EPAZ5S8DS00 (320-4479-8) in batch #28551 were within

established control limits. The data for the following samples: EPAZ5S8AS00 (320-4479-1), EPAZ5S8AS03 (320-4479-2),

EPAZ5S8BS00 (320-4479-4), EPAZ5S8CS00 (320-4479-5), EPAZ5S8CS13 (320-4479-7), EPAZ5S8DS00 (320-4479-8) is being reported

from batch #28551.

The matrix spike(MS) recovery of nitrate and nitrite for batch 28577 was outside control limits. The associated laboratory control sample

(LCS) recovery met acceptance criteria. The spike of nitrate was 4X lower than the sample result.

The nitrate results for the following samples: (320-4452-11 DU), EPAZ5S31DS53 (320-4452-11), are less than the reporting limit and

flagged as J values. As a result the RPD limits are not applicable for the sample and it's duplicate.



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Job ID: 320-4479-1 (Continued)

Laboratory: TestAmerica Sacramento (Continued)

I certify that this data package is in compliance with the terms and conditions of the contract and Statement of Work both technically and for

completeness, for other than the condition(s) detailed above. Release of the data contained in this hardcopy data package and in the

computer-readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following

signature.


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Detection SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Client Sample ID: EPAZ5S8AS00 Lab Sample ID: 320-4479-1

☼Diesel Range Organics (C10-C24)

RL

1.0 mg/Kg

MDL

0.31

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1B1.6 8015B

☼Fluoride 2.5 mg/Kg0.30 Soluble11.5 J 9056

☼Nitrate 0.25 mg/Kg0.11 Soluble11.5 9056

☼Sulfate 5.0 mg/Kg0.24 Soluble17.5 9056

☼Perchlorate 0.98 ug/Kg0.15 Total/NA11.5 6850


☼Gasoline Range Organics (GRO)

-C7-C12

RL

0.55 mg/Kg

MDL

0.055


Total/NA1J0.069 8260B/CA_LUFT

MS☼Diesel Range Organics (C10-C24) 1.0 mg/Kg0.31 Total/NA11.2 B 8015B



☼Sulfate 4.9 mg/Kg0.24 Soluble121 9056

☼Perchlorate 0.98 ug/Kg0.15 Total/NA10.58 J 6850


Diesel Range Organics [C10-C28]

RL

48 ug/L

MDL

15


Total/NA1J B27 8015B

Client Sample ID: EPAZ5S8BS00 Lab Sample ID: 320-4479-4


RL

1.0 mg/Kg

MDL

0.31


Total/NA1B1.9 8015B





Client Sample ID: EPAZ5S8CS00 Lab Sample ID: 320-4479-5


RL

0.98 mg/Kg

MDL

0.30


Total/NA1B1.8 8015B



☼Sulfate 5.0 mg/Kg0.24 Soluble12.3 J 9056




RL

0.98 mg/Kg

MDL

0.29


Total/NA1B1.0 8015B







This Detection Summary does not include radiochemical test results.

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Detection SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Client Sample ID: EPAZ5S8CS13 (Continued) Lab Sample ID: 320-4479-7


RL

1.0 mg/Kg

MDL

0.31


Total/NA1B1.0 8015B





Client Sample ID: EPAZ5S8DS00 Lab Sample ID: 320-4479-8


RL

1.0 mg/Kg

MDL

0.30


Total/NA1B1.2 8015B





Client Sample ID: EPAZ5S8DS03 Lab Sample ID: 320-4479-9


RL

0.99 mg/Kg

MDL

0.30


Total/NA1B1.0 8015B




Client Sample ID: EPAZ5SMW4S00 Lab Sample ID: 320-4479-10


RL

1.0 mg/Kg

MDL

0.31


Total/NA1B17 8015B







RL

1.0 mg/Kg

MDL

0.31


Total/NA1J B0.54 8015B






RL

1.1 mg/Kg

MDL

0.32


Total/NA1J B0.65 8015B






This Detection Summary does not include radiochemical test results.

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Client Sample ResultsTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Lab Sample ID: 320-4479-1Client Sample ID: EPAZ5S8AS00Matrix: SolidDate Collected: 10/08/13 11:25

Percent Solids: 99.7Date Received: 10/09/13 09:00

Method: 8260B/CA_LUFTMS - Volatile Organic Compounds by GC/MSRL MDL

Gasoline Range Organics (GRO)

-C7-C12

ND 0.59 0.059 mg/Kg ☼ 10/09/13 17:48 10/18/13 18:20 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

4-Bromofluorobenzene (Surr) 90 70 - 131 10/09/13 17:48 10/18/13 18:20 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Method: 8015B - Diesel Range Organics (DRO) (GC)RL MDL

Diesel Range Organics (C10-C24) 1.6 B 1.0 0.31 mg/Kg ☼ 10/15/13 11:23 10/22/13 00:03 1


o-Terphenyl (Surr) 105 63 - 141 10/15/13 11:23 10/22/13 00:03 1


Method: 9056 - Anions, Ion Chromatography - SolubleRL MDL

Fluoride 1.5 J 2.5 0.30 mg/Kg ☼ 10/23/13 01:18 1


0.25 0.11 mg/Kg 10/23/13 01:18 1☼Nitrate 1.5

5.0 0.24 mg/Kg 10/23/13 01:18 1☼Sulfate 7.5

Method: 6850 - Perchlorate by LC/MS or LC/MS/MSRL MDL

Perchlorate 1.5 0.98 0.15 ug/Kg ☼ 10/21/13 08:07 10/22/13 23:06 1


Method: 8321A - Benzene Sulfonic Acids (LCMS)RL MDL

p-CBSA ND 10 0.88 ug/Kg ☼ 10/18/13 07:37 10/26/13 04:46 1


4-Bromobenzenesulfonic Acid 86 70 - 130 10/18/13 07:37 10/26/13 04:46 1


Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MSRL MDL

N-Nitrosodimethylamine ND * 5.3 0.80 ug/Kg ☼ 10/15/13 10:04 10/23/13 04:28 1


N-Nitrosodimethylamine-d6 67 50 - 150 10/15/13 10:04 10/23/13 04:28 1

Isotope Dilution Dil FacAnalyzedPreparedQualifier Limits%Recovery





-C7-C12

0.069 J 0.55 0.055 mg/Kg ☼ 10/09/13 17:48 10/18/13 18:43 1








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o-Terphenyl (Surr) 104 63 - 141 10/15/13 11:23 10/22/13 00:32 1



Fluoride 1.1 J 2.5 0.30 mg/Kg ☼ 10/23/13 01:30 1


0.25 0.11 mg/Kg 10/23/13 01:30 1☼Nitrate 0.95

4.9 0.24 mg/Kg 10/23/13 01:30 1☼Sulfate 21


Perchlorate 0.58 J 0.98 0.15 ug/Kg ☼ 10/21/13 08:07 10/22/13 23:57 1



p-CBSA ND 10 0.88 ug/Kg ☼ 10/18/13 07:37 10/26/13 05:38 1









Lab Sample ID: 320-4479-3Client Sample ID: EPAZ5S8AS3Matrix: WaterDate Collected: 10/08/13 13:30

Date Received: 10/09/13 09:00



-C7-C12

ND 50 15 ug/L 10/11/13 21:39 1


4-Bromofluorobenzene (Surr) 96 73 - 115 10/11/13 21:39 1



Diesel Range Organics [C10-C28] 27 J B 48 15 ug/L 10/14/13 10:08 10/22/13 06:49 1


o-Terphenyl (Surr) 95 56 - 145 10/14/13 10:08 10/22/13 06:49 1


Method: 9056 - Anions, Ion ChromatographyRL MDL

Fluoride ND 0.50 0.059 mg/L 10/09/13 14:43 1


0.050 0.022 mg/L 10/09/13 14:43 1Nitrate ND

1.0 0.049 mg/L 10/09/13 14:43 1Sulfate ND


Perchlorate ND 0.50 0.082 ug/L 10/16/13 07:14 10/19/13 09:18 1



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Lab Sample ID: 320-4479-3Client Sample ID: EPAZ5S8AS3Matrix: WaterDate Collected: 10/08/13 13:30



p-CBSA ND 1.0 0.097 ug/L 10/17/13 08:50 10/25/13 22:37 1





N-Nitrosodimethylamine ND 1.9 0.37 ng/L 10/14/13 09:48 10/22/13 17:02 1




Lab Sample ID: 320-4479-4Client Sample ID: EPAZ5S8BS00Matrix: SolidDate Collected: 10/08/13 08:30




-C7-C12

ND 0.55 0.055 mg/Kg ☼ 10/09/13 17:48 10/20/13 13:56 1







o-Terphenyl (Surr) 107 63 - 141 10/15/13 11:23 10/22/13 01:01 1



Fluoride 1.1 J 2.5 0.30 mg/Kg ☼ 10/23/13 01:41 1


0.25 0.11 mg/Kg 10/23/13 01:41 1☼Nitrate 2.9

5.0 0.24 mg/Kg 10/23/13 01:41 1☼Sulfate 9.1





p-CBSA ND 10 0.89 ug/Kg ☼ 10/18/13 07:37 10/26/13 06:14 1







N-Nitrosodimethylamine-d6 47 * 50 - 150 10/15/13 10:04 10/23/13 05:16 1



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Lab Sample ID: 320-4479-5Client Sample ID: EPAZ5S8CS00Matrix: SolidDate Collected: 10/08/13 09:50




-C7-C12

ND 0.55 0.055 mg/Kg ☼ 10/09/13 17:48 10/18/13 20:35 1







o-Terphenyl (Surr) 105 63 - 141 10/15/13 11:23 10/22/13 01:30 1



Fluoride 0.93 J 2.5 0.30 mg/Kg ☼ 10/23/13 01:53 1


0.25 0.11 mg/Kg 10/23/13 01:53 1☼Nitrate 0.57

5.0 0.24 mg/Kg 10/23/13 01:53 1☼Sulfate 2.3 J





p-CBSA ND 9.9 0.88 ug/Kg ☼ 10/18/13 07:37 10/26/13 06:31 1













-C7-C12

ND 0.54 0.054 mg/Kg ☼ 10/09/13 17:48 10/18/13 20:58 1








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o-Terphenyl (Surr) 104 63 - 141 10/15/13 11:23 10/22/13 01:59 1



Fluoride 1.2 J 2.5 0.30 mg/Kg ☼ 10/24/13 22:03 1


0.25 0.11 mg/Kg 10/24/13 22:03 1☼Nitrate 2.8

5.0 0.24 mg/Kg 10/24/13 22:03 1☼Sulfate 3.4 J





p-CBSA ND 10 0.89 ug/Kg ☼ 10/18/13 07:37 10/26/13 06:49 1













-C7-C12

ND 0.53 0.053 mg/Kg ☼ 10/09/13 17:48 10/18/13 21:21 1







o-Terphenyl (Surr) 103 63 - 141 10/15/13 11:23 10/22/13 02:28 1



Fluoride 1.1 J 2.5 0.30 mg/Kg ☼ 10/23/13 02:04 1


0.25 0.11 mg/Kg 10/23/13 02:04 1☼Nitrate 4.3

5.0 0.24 mg/Kg 10/23/13 02:04 1☼Sulfate 4.2 J





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p-CBSA ND 10 0.88 ug/Kg ☼ 10/18/13 07:37 10/26/13 07:06 1









Lab Sample ID: 320-4479-8Client Sample ID: EPAZ5S8DS00Matrix: SolidDate Collected: 10/08/13 10:35




-C7-C12

ND 0.56 0.056 mg/Kg ☼ 10/09/13 17:48 10/18/13 21:45 1







o-Terphenyl (Surr) 106 63 - 141 10/15/13 11:23 10/22/13 02:57 1



Fluoride 1.0 J 2.5 0.30 mg/Kg ☼ 10/23/13 02:39 1


0.25 0.11 mg/Kg 10/23/13 02:39 1☼Nitrate 1.5

5.0 0.24 mg/Kg 10/23/13 02:39 1☼Sulfate 6.3





p-CBSA ND 10 0.88 ug/Kg ☼ 10/18/13 07:37 10/26/13 07:24 1










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Lab Sample ID: 320-4479-9Client Sample ID: EPAZ5S8DS03Matrix: SolidDate Collected: 10/08/13 10:40




-C7-C12

ND 0.49 0.049 mg/Kg ☼ 10/09/13 17:48 10/18/13 22:08 1







o-Terphenyl (Surr) 102 63 - 141 10/15/13 11:23 10/22/13 03:26 1



Fluoride 1.2 J 2.5 0.30 mg/Kg ☼ 10/24/13 22:15 1


0.25 0.11 mg/Kg 10/24/13 22:15 1☼Nitrate 3.5

5.1 0.24 mg/Kg 10/24/13 22:15 1☼Sulfate 6.6


Perchlorate ND 0.99 0.15 ug/Kg ☼ 10/21/13 08:07 10/23/13 02:10 1



p-CBSA ND 10 0.89 ug/Kg ☼ 10/18/13 07:37 10/26/13 07:41 1









Lab Sample ID: 320-4479-10Client Sample ID: EPAZ5SMW4S00Matrix: SolidDate Collected: 10/08/13 07:05




-C7-C12

ND 0.58 0.058 mg/Kg ☼ 10/09/13 17:48 10/18/13 22:31 1





Diesel Range Organics (C10-C24) 17 B 1.0 0.31 mg/Kg ☼ 10/16/13 09:49 10/26/13 08:53 1



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o-Terphenyl (Surr) 605 X 63 - 141 10/16/13 09:49 10/26/13 08:53 1



Fluoride 1.2 J 2.5 0.30 mg/Kg ☼ 10/24/13 22:26 1


0.25 0.11 mg/Kg 10/24/13 22:26 1☼Nitrate 3.3

5.0 0.24 mg/Kg 10/24/13 22:26 1☼Sulfate 6.6





p-CBSA ND 9.9 0.87 ug/Kg ☼ 10/18/13 07:37 10/26/13 07:59 1













-C7-C12

ND 0.49 0.049 mg/Kg ☼ 10/09/13 17:48 10/18/13 22:54 1





Diesel Range Organics (C10-C24) 0.54 J B 1.0 0.31 mg/Kg ☼ 10/16/13 09:49 10/26/13 09:22 1


o-Terphenyl (Surr) 98 63 - 141 10/16/13 09:49 10/26/13 09:22 1



Fluoride 0.61 J 2.5 0.30 mg/Kg ☼ 10/24/13 22:38 1


0.25 0.11 mg/Kg 10/24/13 22:38 1☼Nitrate 1.3

5.1 0.24 mg/Kg 10/24/13 22:38 1☼Sulfate 2.4 J


Perchlorate ND I 0.98 0.15 ug/Kg ☼ 10/21/13 08:07 10/23/13 02:44 1



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p-CBSA ND 10 0.89 ug/Kg ☼ 10/18/13 07:37 10/26/13 08:17 1













-C7-C12

ND 0.48 0.048 mg/Kg ☼ 10/09/13 17:48 10/18/13 23:18 1





Diesel Range Organics (C10-C24) 0.65 J B 1.1 0.32 mg/Kg ☼ 10/16/13 09:49 10/26/13 09:51 1


o-Terphenyl (Surr) 93 63 - 141 10/16/13 09:49 10/26/13 09:51 1



Fluoride 1.3 J 2.6 0.31 mg/Kg ☼ 10/24/13 22:49 1


0.26 0.11 mg/Kg 10/24/13 22:49 1☼Nitrate 1.9

5.2 0.25 mg/Kg 10/24/13 22:49 1☼Sulfate 5.6





p-CBSA ND 10 0.92 ug/Kg ☼ 10/18/13 07:37 10/26/13 08:34 1










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Surrogate SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Method: 8260B/CA_LUFTMS - Volatile Organic Compounds by GC/MSPrep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (70-131)

BFB

90320-4479-1

Percent Surrogate Recovery (Acceptance Limits)

EPAZ5S8AS00

91320-4479-2 EPAZ5S8AS03

87320-4479-4 EPAZ5S8BS00

91320-4479-5 EPAZ5S8CS00

91320-4479-6 EPAZ5S8CS03

90320-4479-7 EPAZ5S8CS13

90320-4479-8 EPAZ5S8DS00

88320-4479-9 EPAZ5S8DS03

88320-4479-10 EPAZ5SMW4S00

88320-4479-11 EPAZ5SMW4S03

92320-4479-12 EPAZ5SMW4S08

90LCS 320-27878/9 Lab Control Sample


91MB 320-27878/11 Method Blank


Surrogate Legend

BFB = 4-Bromofluorobenzene (Surr)

Method: 8260B/CA_LUFTMS - Volatile Organic Compounds by GC/MSPrep Type: Total/NAMatrix: Water


BFB

96320-4479-3


EPAZ5S8AS3

108320-4479-3 - RA EPAZ5S8AS3



94LCSD 320-27338/10 Lab Control Sample Dup



Surrogate Legend

BFB = 4-Bromofluorobenzene (Surr)

Method: 8015B - Diesel Range Organics (DRO) (GC)Prep Type: Total/NAMatrix: Solid


OTPH1

103320-4452-C-11-D MS


Matrix Spike

109320-4452-C-11-E MSD Matrix Spike Duplicate

105320-4479-1 EPAZ5S8AS00

104320-4479-2 EPAZ5S8AS03

107320-4479-4 EPAZ5S8BS00

105320-4479-5 EPAZ5S8CS00

104320-4479-6 EPAZ5S8CS03

103320-4479-7 EPAZ5S8CS13


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Method: 8015B - Diesel Range Organics (DRO) (GC) (Continued)Prep Type: Total/NAMatrix: Solid


OTPH1

106320-4479-8


EPAZ5S8DS00

102320-4479-9 EPAZ5S8DS03

605 X320-4479-10 EPAZ5SMW4S00

98320-4479-11 EPAZ5SMW4S03

93320-4479-12 EPAZ5SMW4S08

117320-4518-B-2-E MS Matrix Spike

112320-4518-B-2-F MSD Matrix Spike Duplicate

100LCS 320-27563/2-A Lab Control Sample


101MB 320-27563/1-A Method Blank


Surrogate Legend

OTPH = o-Terphenyl (Surr)

Method: 8015B - Diesel Range Organics (DRO) (GC)Prep Type: Total/NAMatrix: Water


OTPH1

95320-4479-3


EPAZ5S8AS3



Surrogate Legend

OTPH = o-Terphenyl (Surr)

Method: 8321A - Benzene Sulfonic Acids (LCMS)Prep Type: Total/NAMatrix: Solid


4-Bromobenzenesulfonic Acid

86320-4479-1


EPAZ5S8AS00

89320-4479-1 MS EPAZ5S8AS00

85320-4479-1 MSD EPAZ5S8AS00

85320-4479-2 EPAZ5S8AS03

72320-4479-4 EPAZ5S8BS00

80320-4479-5 EPAZ5S8CS00

72320-4479-6 EPAZ5S8CS03

72320-4479-7 EPAZ5S8CS13

80320-4479-8 EPAZ5S8DS00

72320-4479-9 EPAZ5S8DS03

75320-4479-10 EPAZ5SMW4S00

79320-4479-11 EPAZ5SMW4S03

77320-4479-12 EPAZ5SMW4S08




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Surrogate Legend

4-Bromobenzenesulfonic Acid = 4-Bromobenzenesulfonic Acid

Method: 8321A - Benzene Sulfonic Acids (LCMS)Prep Type: Total/NAMatrix: Water


4-Bromobenzenesulfonic Acid

98320-4452-H-6-C MS


Matrix Spike

100320-4452-H-6-D MSD Matrix Spike Duplicate

102320-4479-3 EPAZ5S8AS3



Surrogate Legend

4-Bromobenzenesulfonic Acid = 4-Bromobenzenesulfonic Acid


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Isotope Dilution SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MSPrep Type: Total/NAMatrix: Solid


NDMA

53320-4421-C-3-C MSD

Percent Isotope Dilution Recovery (Acceptance Limits)

Matrix Spike Duplicate

53320-4421-D-3-B MS Matrix Spike

67320-4479-1 EPAZ5S8AS00

67320-4479-2 EPAZ5S8AS03

47 *320-4479-4 EPAZ5S8BS00

48 *320-4479-5 EPAZ5S8CS00

43 *320-4479-6 EPAZ5S8CS03

107320-4479-7 EPAZ5S8CS13

63320-4479-8 EPAZ5S8DS00

73320-4479-9 EPAZ5S8DS03

100320-4479-10 EPAZ5SMW4S00

70320-4479-11 EPAZ5SMW4S03

95320-4479-12 EPAZ5SMW4S08

63320-4518-B-2-C MS Matrix Spike

76320-4518-B-2-D MSD Matrix Spike Duplicate





Surrogate Legend

NDMA = N-Nitrosodimethylamine-d6

Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MSPrep Type: Total/NAMatrix: Water


NDMA

57320-4479-3

Percent Isotope Dilution Recovery (Acceptance Limits)

EPAZ5S8AS3

47320-4491-A-3-B MS Matrix Spike

64320-4491-A-3-C MSD Matrix Spike Duplicate



Surrogate Legend

NDMA = N-Nitrosodimethylamine-d6


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QC Sample ResultsTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Method: 8260B/CA_LUFTMS - Volatile Organic Compounds by GC/MS

Client Sample ID: Method BlankLab Sample ID: MB 320-27338/18

Matrix: Water Prep Type: Total/NA

Analysis Batch: 27338

RL MDL


-C7-C12

ND 50 15 ug/L 10/11/13 19:49 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier


MB MB

Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery

Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-27338/9




-C7-C12

500 539 ug/L 108 78 - 118

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

4-Bromofluorobenzene (Surr) 73 - 115

Surrogate

95

LCS LCS

Qualifier Limits%Recovery

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 320-27338/10




-C7-C12

500 535 ug/L 107 78 - 118 1 23

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD


Surrogate

94

LCSD LCSD



Matrix: Solid Prep Type: Total/NA


RL MDL


-C7-C12

ND 0.50 0.050 mg/Kg 10/18/13 14:50 1

MB MB



MB MB






-C7-C12

1.00 0.995 mg/Kg 99 79 - 123

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Method: 8260B/CA_LUFTMS - Volatile Organic Compounds by GC/MS (Continued)





Surrogate

90

LCS LCS





RL MDL


-C7-C12

ND 0.50 0.050 mg/Kg 10/20/13 13:33 1

MB MB



MB MB






-C7-C12

1.00 1.05 mg/Kg 105 79 - 123

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Surrogate

92

LCS LCS





RL MDL


-C7-C12

15.0 J 50 15 ug/L 10/22/13 16:55 1

MB MB



MB MB






-C7-C12

500 429 ug/L 86 78 - 118

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Surrogate

77

LCS LCS



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Method: 8015B - Diesel Range Organics (DRO) (GC)

Client Sample ID: Method BlankLab Sample ID: MB 320-27435/1-A


Analysis Batch: 27994 Prep Batch: 27435

RL MDL

Diesel Range Organics [C10-C28] 21.3 J 50 16 ug/L 10/14/13 10:08 10/22/13 05:22 1

MB MB


o-Terphenyl (Surr) 91 56 - 145 10/22/13 05:22 1

MB MB

Surrogate

10/14/13 10:08

Dil FacPrepared AnalyzedQualifier Limits%Recovery

Client Sample ID: Lab Control SampleLab Sample ID: LCS 320-27435/2-A



Diesel Range Organics

[C10-C28]

300 320 ug/L 107 53 - 123

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

o-Terphenyl (Surr) 56 - 145

Surrogate

100

LCS LCS





RL MDL

Diesel Range Organics (C10-C24) 0.704 J 1.0 0.30 mg/Kg 10/15/13 11:23 10/21/13 14:51 1

MB MB


o-Terphenyl (Surr) 101 63 - 141 10/21/13 14:51 1

MB MB

Surrogate

10/15/13 11:23






(C10-C24)

10.0 11.1 mg/Kg 111 67 - 113

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Surrogate

100

LCS LCS


Client Sample ID: Matrix SpikeLab Sample ID: 320-4452-C-11-D MS




(C10-C24)

0.61 J B 10.6 11.2 mg/Kg 99 67 - 113☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Surrogate

103

MS MS



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Method: 8015B - Diesel Range Organics (DRO) (GC) (Continued)

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4452-C-11-E MSD




(C10-C24)

0.61 J B 10.5 12.1 mg/Kg 109 67 - 113 8 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Surrogate

109

MSD MSD





RL MDL

Diesel Range Organics (C10-C24) 0.340 J 1.0 0.30 mg/Kg 10/16/13 09:49 10/28/13 11:53 1

MB MB


o-Terphenyl (Surr) 96 63 - 141 10/28/13 11:53 1

MB MB

Surrogate

10/16/13 09:49






(C10-C24)

10.0 10.2 mg/Kg 102 67 - 113

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Surrogate

105

LCS LCS


Client Sample ID: Matrix SpikeLab Sample ID: 320-4518-B-2-E MS




(C10-C24)

8.0 B 10.1 14.7 mg/Kg 67 67 - 113☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Surrogate

117

MS MS


Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4518-B-2-F MSD




(C10-C24)

8.0 B 10.3 13.7 F mg/Kg 56 67 - 113 7 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


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Method: 8015B - Diesel Range Organics (DRO) (GC) (Continued)

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4518-B-2-F MSD




Surrogate

112

MSD MSD


Method: 9056 - Anions, Ion Chromatography




RL MDL

Fluoride ND 0.50 0.059 mg/L 10/09/13 14:20 1

MB MB


ND 0.0491.0 mg/L 10/09/13 14:20 1Sulfate




Fluoride 7.50 7.50 mg/L 100 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 7.50 7.23 mg/L 96 90 - 110

Client Sample ID: Matrix SpikeLab Sample ID: 320-4482-A-1 MS ^10



Fluoride ND 50.0 48.2 mg/L 96 90 - 110

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: DuplicateLab Sample ID: 320-4482-A-1 DU ^10



Fluoride ND ND mg/L NC 10

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD




RL MDL

Nitrate ND 0.050 0.022 mg/L 10/09/13 14:20 1

MB MB





Nitrate 1.88 1.77 mg/L 94 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


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Method: 9056 - Anions, Ion Chromatography (Continued)

Client Sample ID: Matrix SpikeLab Sample ID: 320-4482-A-1 MS ^10



Nitrate 87 10.0 95.5 4 mg/L 87 90 - 110

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: DuplicateLab Sample ID: 320-4482-A-1 DU ^10



Nitrate 87 86.1 mg/L 0.8 10

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD


Matrix: Solid Prep Type: Soluble


RL MDL

Nitrate ND 0.25 0.11 mg/Kg 10/22/13 22:03 1

MB MB





Nitrate 5.00 4.99 mg/Kg 100 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




RL MDL

Fluoride ND 2.5 0.30 mg/Kg 10/22/13 22:03 1

MB MB


ND 0.245.0 mg/Kg 10/22/13 22:03 1Sulfate




Fluoride 25.0 23.7 mg/Kg 95 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 25.0 24.3 mg/Kg 97 85 - 115




RL MDL

Fluoride ND 2.5 0.30 mg/Kg 10/24/13 18:48 1

MB MB


ND 0.245.0 mg/Kg 10/24/13 18:48 1Sulfate


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Fluoride 25.0 24.7 mg/Kg 99 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Sulfate 25.0 24.8 mg/Kg 99 85 - 115

Client Sample ID: Matrix SpikeLab Sample ID: 320-4452-E-11-E MS



Fluoride 1.9 J 25.4 26.3 mg/Kg 96 85 - 115☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Sulfate 1.0 J 25.4 25.8 mg/Kg 97 85 - 115☼

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4452-E-11-F MSD



Fluoride 1.9 J 25.4 25.7 mg/Kg 94 85 - 115 2 15☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Sulfate 1.0 J 25.4 25.5 mg/Kg 96 85 - 115 1 15☼

Client Sample ID: DuplicateLab Sample ID: 320-4452-E-11-D DU



Fluoride 1.9 J 1.83 J mg/Kg 3 15☼

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD

Sulfate 1.0 J 1.53 J mg/Kg 40 15☼




RL MDL

Nitrate ND 0.25 0.11 mg/Kg 10/24/13 18:48 1

MB MB





Nitrate 5.00 5.14 mg/Kg 103 85 - 115

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: Matrix SpikeLab Sample ID: 320-4452-E-11-E MS



Nitrate 0.21 J 5.08 5.42 mg/Kg 102 85 - 115☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


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Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4452-E-11-F MSD



Nitrate 0.21 J 5.08 5.31 mg/Kg 100 85 - 115 2 15☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Client Sample ID: DuplicateLab Sample ID: 320-4452-E-11-D DU



Nitrate 0.21 J 0.239 J mg/Kg 11 15☼

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD

Method: 6850 - Perchlorate by LC/MS or LC/MS/MS




RL MDL

Perchlorate ND 0.50 0.082 ug/L 10/16/13 07:14 10/19/13 05:24 1

MB MB





Perchlorate 5.00 5.08 ug/L 102 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: Matrix SpikeLab Sample ID: 720-52885-A-10-B MS



Perchlorate ND 5.00 5.10 ug/L 102 80 - 120

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 720-52885-A-10-C MSD



Perchlorate ND 5.00 5.08 ug/L 102 80 - 120 0 15

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD




RL MDL

Perchlorate ND 1.0 0.15 ug/Kg 10/21/13 08:07 10/22/13 22:16 1

MB MB



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Method: 6850 - Perchlorate by LC/MS or LC/MS/MS (Continued)




Perchlorate 50.0 54.6 ug/Kg 109 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: EPAZ5S8AS00Lab Sample ID: 320-4479-1 MS



Perchlorate 1.5 49.5 56.4 ug/Kg 111 80 - 120☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: EPAZ5S8AS00Lab Sample ID: 320-4479-1 MSD



Perchlorate 1.5 49.7 57.4 ug/Kg 113 80 - 120 2 15☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Method: 8321A - Benzene Sulfonic Acids (LCMS)




RL MDL

p-CBSA ND 1.0 0.097 ug/L 10/17/13 08:50 10/25/13 21:09 1

MB MB


4-Bromobenzenesulfonic Acid 97 63 - 123 10/25/13 21:09 1

MB MB

Surrogate

10/17/13 08:50





p-CBSA 5.00 5.21 ug/L 104 60 - 127

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

4-Bromobenzenesulfonic Acid 63 - 123

Surrogate

104

LCS LCS


Client Sample ID: Matrix SpikeLab Sample ID: 320-4452-H-6-C MS



p-CBSA ND 5.00 5.29 ug/L 106 60 - 127

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Surrogate

98

MS MS



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Method: 8321A - Benzene Sulfonic Acids (LCMS) (Continued)

Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4452-H-6-D MSD



p-CBSA ND 5.00 5.31 ug/L 106 60 - 127 0 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Surrogate

100

MSD MSD





RL MDL

p-CBSA ND 10 0.88 ug/Kg 10/18/13 07:37 10/26/13 04:11 1

MB MB


4-Bromobenzenesulfonic Acid 91 70 - 130 10/26/13 04:11 1

MB MB

Surrogate

10/18/13 07:37





p-CBSA 50.0 56.4 ug/Kg 113 70 - 130

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Surrogate

88

LCS LCS


Client Sample ID: EPAZ5S8AS00Lab Sample ID: 320-4479-1 MS



p-CBSA ND 49.7 57.1 ug/Kg 115 70 - 130☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Surrogate

89

MS MS


Client Sample ID: EPAZ5S8AS00Lab Sample ID: 320-4479-1 MSD



p-CBSA ND 50.1 53.3 ug/Kg 106 70 - 130 7 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Surrogate

85

MSD MSD



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Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MS




RL MDL

N-Nitrosodimethylamine ND 2.0 0.39 ng/L 10/14/13 09:48 10/22/13 09:56 1

MB MB


N-Nitrosodimethylamine-d6 61 25 - 150 10/22/13 09:56 1

MB MB

Isotope Dilution

10/14/13 09:48





N-Nitrosodimethylamine 20.0 21.5 ng/L 108 58 - 150

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

N-Nitrosodimethylamine-d6 25 - 150

Isotope Dilution

57

LCS LCS


Client Sample ID: Matrix SpikeLab Sample ID: 320-4491-A-3-B MS



N-Nitrosodimethylamine ND 19.0 23.7 ng/L 125 58 - 150

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Isotope Dilution

47

MS MS


Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4491-A-3-C MSD



N-Nitrosodimethylamine ND 19.0 20.8 ng/L 109 58 - 150 13 20

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Isotope Dilution

64

MSD MSD





RL MDL

N-Nitrosodimethylamine ND 5.0 0.76 ug/Kg 10/15/13 10:04 10/23/13 00:56 1

MB MB



MB MB

Isotope Dilution

10/15/13 10:04



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Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MS (Continued)




N-Nitrosodimethylamine 5.00 6.87 * ug/Kg 137 70 - 130

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Isotope Dilution

66

LCS LCS


Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4421-C-3-C MSD



N-Nitrosodimethylamine ND * 4.63 7.71 F ug/Kg 166 70 - 130 12 35☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Isotope Dilution

53

MSD MSD


Client Sample ID: Matrix SpikeLab Sample ID: 320-4421-D-3-B MS



N-Nitrosodimethylamine ND * 4.80 6.85 F ug/Kg 143 70 - 130☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Isotope Dilution

53

MS MS





RL MDL

N-Nitrosodimethylamine ND 5.0 0.76 ug/Kg 10/16/13 09:54 10/23/13 23:39 1

MB MB



MB MB

Isotope Dilution

10/16/13 09:54





N-Nitrosodimethylamine 5.00 7.75 * ug/Kg 155 70 - 130

Analyte

LCS LCS


Spike

Added

%Rec.

Limits


Isotope Dilution

77

LCS LCS



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Method: GCMSMS_NDMA - Nitrosamines by Isotope Dilution and GC/CI/MS/MS (Continued)

Client Sample ID: Matrix SpikeLab Sample ID: 320-4518-B-2-C MS



N-Nitrosodimethylamine ND * 5.15 8.98 F ug/Kg 174 70 - 130☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits


Isotope Dilution

63

MS MS


Client Sample ID: Matrix Spike DuplicateLab Sample ID: 320-4518-B-2-D MSD



N-Nitrosodimethylamine ND * 5.35 7.80 F ug/Kg 146 70 - 130 14 35☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD


Isotope Dilution

76

MSD MSD



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QC Association SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


GC/MS VOA

Prep Batch: 27167

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Solid 5035320-4479-1 EPAZ5S8AS00 Total/NA

Solid 5035320-4479-2 EPAZ5S8AS03 Total/NA

Solid 5035320-4479-4 EPAZ5S8BS00 Total/NA

Solid 5035320-4479-5 EPAZ5S8CS00 Total/NA



Solid 5035320-4479-8 EPAZ5S8DS00 Total/NA

Solid 5035320-4479-9 EPAZ5S8DS03 Total/NA

Solid 5035320-4479-10 EPAZ5SMW4S00 Total/NA





Water 8260B/CA_LUFT

MS

320-4479-3 EPAZ5S8AS3 Total/NA

Water 8260B/CA_LUFT

MS

LCS 320-27338/9 Lab Control Sample Total/NA

Water 8260B/CA_LUFT

MS

LCSD 320-27338/10 Lab Control Sample Dup Total/NA

Water 8260B/CA_LUFT

MS

MB 320-27338/18 Method Blank Total/NA



Solid 8260B/CA_LUFT

MS

27167320-4479-1 EPAZ5S8AS00 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-2 EPAZ5S8AS03 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-5 EPAZ5S8CS00 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-6 EPAZ5S8CS03 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-7 EPAZ5S8CS13 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-8 EPAZ5S8DS00 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-9 EPAZ5S8DS03 Total/NA

Solid 8260B/CA_LUFT

MS

27167320-4479-10 EPAZ5SMW4S00 Total/NA

Solid 8260B/CA_LUFT

MS


Solid 8260B/CA_LUFT

MS


Solid 8260B/CA_LUFT

MS


Solid 8260B/CA_LUFT

MS




Solid 8260B/CA_LUFT

MS

27167320-4479-4 EPAZ5S8BS00 Total/NA


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GC/MS VOA (Continued)

Analysis Batch: 27955 (Continued)


Solid 8260B/CA_LUFT

MS


Solid 8260B/CA_LUFT

MS




Water 8260B/CA_LUFT

MS

320-4479-3 - RA EPAZ5S8AS3 Total/NA

Water 8260B/CA_LUFT

MS


Water 8260B/CA_LUFT

MS


GC Semi VOA

Prep Batch: 27435


Water 3510C320-4479-3 EPAZ5S8AS3 Total/NA

Water 3510CLCS 320-27435/2-A Lab Control Sample Total/NA

Water 3510CMB 320-27435/1-A Method Blank Total/NA

Prep Batch: 27563


Solid 3550B320-4452-C-11-D MS Matrix Spike Total/NA

Solid 3550B320-4452-C-11-E MSD Matrix Spike Duplicate Total/NA

Solid 3550B320-4479-1 EPAZ5S8AS00 Total/NA


Solid 3550B320-4479-4 EPAZ5S8BS00 Total/NA

Solid 3550B320-4479-5 EPAZ5S8CS00 Total/NA



Solid 3550B320-4479-8 EPAZ5S8DS00 Total/NA


Solid 3550BLCS 320-27563/2-A Lab Control Sample Total/NA

Solid 3550BMB 320-27563/1-A Method Blank Total/NA

Prep Batch: 27641


Solid 3550B320-4479-10 EPAZ5SMW4S00 Total/NA



Solid 3550B320-4518-B-2-E MS Matrix Spike Total/NA

Solid 3550B320-4518-B-2-F MSD Matrix Spike Duplicate Total/NA





Solid 8015B 27563320-4452-C-11-D MS Matrix Spike Total/NA

Solid 8015B 27563320-4452-C-11-E MSD Matrix Spike Duplicate Total/NA

Solid 8015B 27563320-4479-1 EPAZ5S8AS00 Total/NA


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GC Semi VOA (Continued)



Solid 8015B 27563320-4479-2 EPAZ5S8AS03 Total/NA

Water 8015B 27435320-4479-3 EPAZ5S8AS3 Total/NA

Solid 8015B 27563320-4479-4 EPAZ5S8BS00 Total/NA

Solid 8015B 27563320-4479-5 EPAZ5S8CS00 Total/NA



Solid 8015B 27563320-4479-8 EPAZ5S8DS00 Total/NA

Solid 8015B 27563320-4479-9 EPAZ5S8DS03 Total/NA

Water 8015B 27435LCS 320-27435/2-A Lab Control Sample Total/NA

Solid 8015B 27563LCS 320-27563/2-A Lab Control Sample Total/NA

Water 8015B 27435MB 320-27435/1-A Method Blank Total/NA

Solid 8015B 27563MB 320-27563/1-A Method Blank Total/NA



Solid 8015B 27641320-4479-10 EPAZ5SMW4S00 Total/NA



Solid 8015B 27641320-4518-B-2-E MS Matrix Spike Total/NA

Solid 8015B 27641320-4518-B-2-F MSD Matrix Spike Duplicate Total/NA

Solid 8015B 27641LCS 320-27641/2-A Lab Control Sample Total/NA



Solid 8015B 27641MB 320-27641/1-A Method Blank Total/NA

HPLC/IC

Leach Batch: 28355


Solid DI Leach320-4479-1 EPAZ5S8AS00 Soluble

Solid DI Leach320-4479-2 EPAZ5S8AS03 Soluble

Solid DI Leach320-4479-4 EPAZ5S8BS00 Soluble

Solid DI Leach320-4479-5 EPAZ5S8CS00 Soluble


Solid DI Leach320-4479-8 EPAZ5S8DS00 Soluble

Solid DI LeachLCS 320-28355/2-A Lab Control Sample Soluble

Solid DI LeachMB 320-28355/1-A Method Blank Soluble

Leach Batch: 28360


Solid DI Leach320-4452-E-11-D DU Duplicate Soluble

Solid DI Leach320-4452-E-11-E MS Matrix Spike Soluble

Solid DI Leach320-4452-E-11-F MSD Matrix Spike Duplicate Soluble


Solid DI Leach320-4479-9 EPAZ5S8DS03 Soluble

Solid DI Leach320-4479-10 EPAZ5SMW4S00 Soluble



Solid DI LeachLCS 320-28360/2-A Lab Control Sample Soluble


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HPLC/IC (Continued)

Leach Batch: 28360 (Continued)


Solid DI LeachMB 320-28360/1-A Method Blank Soluble



Solid 9056 28355320-4479-1 EPAZ5S8AS00 Soluble


Solid 9056 28355320-4479-4 EPAZ5S8BS00 Soluble

Solid 9056 28355320-4479-5 EPAZ5S8CS00 Soluble


Solid 9056 28355320-4479-8 EPAZ5S8DS00 Soluble

Solid 9056 28355LCS 320-28355/2-A Lab Control Sample Soluble

Solid 9056 28355MB 320-28355/1-A Method Blank Soluble





Solid 9056 28355320-4479-4 EPAZ5S8BS00 Soluble








Water 9056320-4479-3 EPAZ5S8AS3 Total/NA

Water 9056320-4482-A-1 DU ^10 Duplicate Total/NA

Water 9056320-4482-A-1 MS ^10 Matrix Spike Total/NA

Water 9056LCS 320-28576/4 Lab Control Sample Total/NA

Water 9056MB 320-28576/3 Method Blank Total/NA



Water 9056320-4479-3 EPAZ5S8AS3 Total/NA

Water 9056320-4482-A-1 DU ^10 Duplicate Total/NA

Water 9056320-4482-A-1 MS ^10 Matrix Spike Total/NA

Water 9056LCS 320-28577/4 Lab Control Sample Total/NA

Water 9056MB 320-28577/3 Method Blank Total/NA



Solid 9056 28360320-4452-E-11-D DU Duplicate Soluble

Solid 9056 28360320-4452-E-11-E MS Matrix Spike Soluble

Solid 9056 28360320-4452-E-11-F MSD Matrix Spike Duplicate Soluble



Solid 9056 28360320-4479-10 EPAZ5SMW4S00 Soluble





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HPLC/IC (Continued)






Solid 9056 28360320-4452-E-11-D DU Duplicate Soluble

Solid 9056 28360320-4452-E-11-E MS Matrix Spike Soluble

Solid 9056 28360320-4452-E-11-F MSD Matrix Spike Duplicate Soluble








LCMS

Prep Batch: 27424


Water 3510C320-4479-3 EPAZ5S8AS3 Total/NA

Water 3510C320-4491-A-3-B MS Matrix Spike Total/NA

Water 3510C320-4491-A-3-C MSD Matrix Spike Duplicate Total/NA

Water 3510CLCS 320-27424/2-A Lab Control Sample Total/NA

Water 3510CMB 320-27424/1-A Method Blank Total/NA

Prep Batch: 27542


Solid 3550B320-4421-C-3-C MSD Matrix Spike Duplicate Total/NA

Solid 3550B320-4421-D-3-B MS Matrix Spike Total/NA



Solid 3550B320-4479-4 EPAZ5S8BS00 Total/NA





Prep Batch: 27626


Water Filtration320-4479-3 EPAZ5S8AS3 Total/NA

Water Filtration720-52885-A-10-B MS Matrix Spike Total/NA

Water Filtration720-52885-A-10-C MSD Matrix Spike Duplicate Total/NA

Water FiltrationLCS 320-27626/2-A Lab Control Sample Total/NA

Water FiltrationMB 320-27626/1-A Method Blank Total/NA

Prep Batch: 27642






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LCMS (Continued)

Prep Batch: 27642 (Continued)





Solid 3550B320-4518-B-2-C MS Matrix Spike Total/NA

Solid 3550B320-4518-B-2-D MSD Matrix Spike Duplicate Total/NA



Prep Batch: 27742


Water Filtration320-4452-H-6-C MS Matrix Spike Total/NA

Water Filtration320-4452-H-6-D MSD Matrix Spike Duplicate Total/NA

Water Filtration320-4479-3 EPAZ5S8AS3 Total/NA

Water FiltrationLCS 320-27742/2-A Lab Control Sample Total/NA

Water FiltrationMB 320-27742/1-A Method Blank Total/NA

Prep Batch: 27854


Solid SHAKE320-4479-1 EPAZ5S8AS00 Total/NA

Solid SHAKE320-4479-1 MS EPAZ5S8AS00 Total/NA

Solid SHAKE320-4479-1 MSD EPAZ5S8AS00 Total/NA


Solid SHAKE320-4479-4 EPAZ5S8BS00 Total/NA

Solid SHAKE320-4479-5 EPAZ5S8CS00 Total/NA



Solid SHAKE320-4479-8 EPAZ5S8DS00 Total/NA


Solid SHAKE320-4479-10 EPAZ5SMW4S00 Total/NA



Solid SHAKELCS 320-27854/2-A Lab Control Sample Total/NA

Solid SHAKEMB 320-27854/1-A Method Blank Total/NA



Water 6850 27626320-4479-3 EPAZ5S8AS3 Total/NA

Water 6850 27626720-52885-A-10-B MS Matrix Spike Total/NA

Water 6850 27626720-52885-A-10-C MSD Matrix Spike Duplicate Total/NA

Water 6850 27626LCS 320-27626/2-A Lab Control Sample Total/NA

Water 6850 27626MB 320-27626/1-A Method Blank Total/NA

Prep Batch: 27966



Solid SHAKE320-4479-1 MS EPAZ5S8AS00 Total/NA

Solid SHAKE320-4479-1 MSD EPAZ5S8AS00 Total/NA


Solid SHAKE320-4479-4 EPAZ5S8BS00 Total/NA




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LCMS (Continued)

Prep Batch: 27966 (Continued)








Solid SHAKELCS 320-27966/2-A Lab Control Sample Total/NA

Solid SHAKEMB 320-27966/1-A Method Blank Total/NA



Water GCMSMS_NDM

A

27424320-4479-3 EPAZ5S8AS3 Total/NA

Water GCMSMS_NDM

A

27424320-4491-A-3-B MS Matrix Spike Total/NA

Water GCMSMS_NDM

A

27424320-4491-A-3-C MSD Matrix Spike Duplicate Total/NA

Water GCMSMS_NDM

A

27424LCS 320-27424/2-A Lab Control Sample Total/NA

Water GCMSMS_NDM

A

27424MB 320-27424/1-A Method Blank Total/NA



Solid 6850 27966320-4479-1 EPAZ5S8AS00 Total/NA

Solid 6850 27966320-4479-1 MS EPAZ5S8AS00 Total/NA

Solid 6850 27966320-4479-1 MSD EPAZ5S8AS00 Total/NA

Solid 6850 27966320-4479-2 EPAZ5S8AS03 Total/NA

Solid 6850 27966320-4479-4 EPAZ5S8BS00 Total/NA

Solid 6850 27966320-4479-5 EPAZ5S8CS00 Total/NA



Solid 6850 27966320-4479-8 EPAZ5S8DS00 Total/NA

Solid 6850 27966320-4479-9 EPAZ5S8DS03 Total/NA

Solid 6850 27966320-4479-10 EPAZ5SMW4S00 Total/NA



Solid 6850 27966LCS 320-27966/2-A Lab Control Sample Total/NA

Solid 6850 27966MB 320-27966/1-A Method Blank Total/NA



Solid GCMSMS_NDM

A

27542320-4421-C-3-C MSD Matrix Spike Duplicate Total/NA

Solid GCMSMS_NDM

A

27542320-4421-D-3-B MS Matrix Spike Total/NA

Solid GCMSMS_NDM

A

27542320-4479-1 EPAZ5S8AS00 Total/NA

Solid GCMSMS_NDM

A

27542320-4479-2 EPAZ5S8AS03 Total/NA

Solid GCMSMS_NDM

A

27542320-4479-4 EPAZ5S8BS00 Total/NA


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LCMS (Continued)



Solid GCMSMS_NDM

A

27542320-4479-5 EPAZ5S8CS00 Total/NA

Solid GCMSMS_NDM

A

27542320-4479-6 EPAZ5S8CS03 Total/NA

Solid GCMSMS_NDM

A


Solid GCMSMS_NDM

A




Solid GCMSMS_NDM

A

27642320-4479-7 EPAZ5S8CS13 Total/NA

Solid GCMSMS_NDM

A

27642320-4479-8 EPAZ5S8DS00 Total/NA

Solid GCMSMS_NDM

A

27642320-4479-9 EPAZ5S8DS03 Total/NA

Solid GCMSMS_NDM

A


Solid GCMSMS_NDM

A


Solid GCMSMS_NDM

A


Solid GCMSMS_NDM

A

27642320-4518-B-2-C MS Matrix Spike Total/NA

Solid GCMSMS_NDM

A

27642320-4518-B-2-D MSD Matrix Spike Duplicate Total/NA

Solid GCMSMS_NDM

A


Solid GCMSMS_NDM

A




Water 8321A 27742320-4452-H-6-C MS Matrix Spike Total/NA

Water 8321A 27742320-4452-H-6-D MSD Matrix Spike Duplicate Total/NA

Solid 8321A 27854320-4479-1 EPAZ5S8AS00 Total/NA

Solid 8321A 27854320-4479-1 MS EPAZ5S8AS00 Total/NA

Solid 8321A 27854320-4479-1 MSD EPAZ5S8AS00 Total/NA

Solid 8321A 27854320-4479-2 EPAZ5S8AS03 Total/NA

Water 8321A 27742320-4479-3 EPAZ5S8AS3 Total/NA

Solid 8321A 27854320-4479-4 EPAZ5S8BS00 Total/NA

Solid 8321A 27854320-4479-5 EPAZ5S8CS00 Total/NA



Solid 8321A 27854320-4479-8 EPAZ5S8DS00 Total/NA

Solid 8321A 27854320-4479-9 EPAZ5S8DS03 Total/NA

Solid 8321A 27854320-4479-10 EPAZ5SMW4S00 Total/NA



Water 8321A 27742LCS 320-27742/2-A Lab Control Sample Total/NA

Solid 8321A 27854LCS 320-27854/2-A Lab Control Sample Total/NA

Water 8321A 27742MB 320-27742/1-A Method Blank Total/NA

Solid 8321A 27854MB 320-27854/1-A Method Blank Total/NA


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General Chemistry



Solid D 2216320-4479-1 EPAZ5S8AS00 Total/NA

Solid D 2216320-4479-1 DU EPAZ5S8AS00 Total/NA

Solid D 2216320-4479-2 EPAZ5S8AS03 Total/NA

Solid D 2216320-4479-4 EPAZ5S8BS00 Total/NA

Solid D 2216320-4479-5 EPAZ5S8CS00 Total/NA



Solid D 2216320-4479-8 EPAZ5S8DS00 Total/NA

Solid D 2216320-4479-9 EPAZ5S8DS03 Total/NA

Solid D 2216320-4479-10 EPAZ5SMW4S00 Total/NA





Solid D 2216320-4498-B-1 DU Duplicate Total/NA


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Lab ChronicleClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-4479-1


Client Sample ID: EPAZ5S8AS00 Lab Sample ID: 320-4479-1Matrix: SolidDate Collected: 10/08/13 11:25


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 4.26 g 5.0 mL

Analysis 8260B/CA_LUFTM

S

1 27878 10/18/13 18:20 WLS TAL SACTotal/NA 4.26 g 5.0 mL

Prep 3550B 27563 10/15/13 11:23 ALH TAL SACTotal/NA 29.32 g 3 mL

Analysis 8015B 1 27994 10/22/13 00:03 UFB TAL SACTotal/NA 29.32 g 3 mL

Analysis 9056 1 28550 10/23/13 01:18 LW1 TAL SACSoluble 5 mL

Leach DI Leach 28355 10/22/13 14:30 LW1 TAL SACSoluble 10.07 g 50 mL


Prep SHAKE 27966 10/21/13 08:07 HJA TAL SACTotal/NA 3.07 g 10.00 mL

Analysis 6850 1 28088 10/22/13 23:06 NSS TAL SACTotal/NA 3.07 g 10.00 mL

Prep 3550B 27542 10/15/13 10:04 ALH TAL SACTotal/NA 9.51 g 0.5 mL

Analysis GCMSMS_NDMA 1 28138 10/23/13 04:28 VMN TAL SACTotal/NA 9.51 g 0.5 mL

Prep SHAKE 27854 10/18/13 07:37 HJA TAL SACTotal/NA 10.05 g 100 mL

Analysis 8321A 1 28437 10/26/13 04:46 DEG TAL SACTotal/NA 10.05 g 100 mL

Analysis D 2216 1 27427 10/14/13 09:52 JCB TAL SACTotal/NA

Client Sample ID: EPAZ5S8AS03 Lab Sample ID: 320-4479-2Matrix: SolidDate Collected: 10/08/13 11:45


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



S














Client Sample ID: EPAZ5S8AS3 Lab Sample ID: 320-4479-3Matrix: WaterDate Collected: 10/08/13 13:30



S

WLS10/11/13 21:391 TAL SAC27338

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 50 mL 50 mL


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Client Sample ID: EPAZ5S8AS3 Lab Sample ID: 320-4479-3Matrix: WaterDate Collected: 10/08/13 13:30



S

KSS10/22/13 17:181RA TAL SAC28211

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 50 mL 50 mL

Prep 3510C 27435 10/14/13 10:08 NGK TAL SACTotal/NA 1042.5 mL 3 mL

Analysis 8015B 1 27994 10/22/13 06:49 UFB TAL SACTotal/NA 1042.5 mL 3 mL

Analysis 9056 1 28576 10/09/13 14:43 LW1 TAL SACTotal/NA 5 mL

Analysis 9056 1 28577 10/09/13 14:43 LW1 TAL SACTotal/NA 5 mL

Prep Filtration 27626 10/16/13 07:14 HJA TAL SACTotal/NA 4.00 mL 4.00 mL

Analysis 6850 1 27864 10/19/13 09:18 NSS TAL SACTotal/NA 4.00 mL 4.00 mL

Prep 3510C 27424 10/14/13 09:48 LRH TAL SACTotal/NA 1051.3 mL 0.5 mL

Analysis GCMSMS_NDMA 1 28059 10/22/13 17:02 VMN TAL SACTotal/NA 1051.3 mL 0.5 mL

Prep Filtration 27742 10/17/13 08:50 HJA TAL SACTotal/NA 10.00 mL 10.00 mL

Analysis 8321A 1 28437 10/25/13 22:37 DEG TAL SACTotal/NA 10.00 mL 10.00 mL

Client Sample ID: EPAZ5S8BS00 Lab Sample ID: 320-4479-4Matrix: SolidDate Collected: 10/08/13 08:30


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Amount Amount

Final Batch

NumberFactor

Dil



S

1 27955 10/20/13 13:56 KSS TAL SACTotal/NA 4.63 g 5.0 mL













Client Sample ID: EPAZ5S8CS00 Lab Sample ID: 320-4479-5Matrix: SolidDate Collected: 10/08/13 09:50


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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NumberFactor

Dil



S





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Analysis 9056 LW110/23/13 01:531 TAL SAC28550

Type

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Method

Batch


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or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Soluble 5 mL












Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Initial

Amount Amount

Final Batch

NumberFactor

Dil



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Analysis 9056 1 28765 10/24/13 22:03 JCB TAL SACSoluble 5 mL











Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Dil



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Leach DI Leach LW110/22/13 14:30 TAL SAC28355

Type

Batch

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Batch


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or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Soluble 10.10 g 50 mL




Prep 3550B 27642 10/16/13 09:54 NGK TAL SACTotal/NA 9.19 g 0.5 mL





Client Sample ID: EPAZ5S8DS00 Lab Sample ID: 320-4479-8Matrix: SolidDate Collected: 10/08/13 10:35


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Method

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or Analyzed

Initial

Amount Amount

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NumberFactor

Dil



S
















Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Prep SHAKE HJA10/21/13 08:07 TAL SAC27966

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil








Client Sample ID: EPAZ5SMW4S00 Lab Sample ID: 320-4479-10Matrix: SolidDate Collected: 10/08/13 07:05


Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Method

Batch


Prepared

or Analyzed

Initial

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Final Batch

NumberFactor

Dil



S


Prep 3550B 27641 10/16/13 09:49 NGK TAL SACTotal/NA 29.19 g 3 mL














Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Initial

Amount Amount

Final Batch

NumberFactor

Dil



S










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Prep 3550B NGK10/16/13 09:54 TAL SAC27642

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil








Prep 5035 KSS10/09/13 17:48 TAL SAC27167

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Batch

Method

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Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

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S














Laboratory References:

TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600


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Certification SummaryClient: CH2M Hill Constructors, Inc. TestAmerica Job ID: 320-4479-1


Laboratory: TestAmerica SacramentoAll certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

A2LA NE-OS-22-13A2LA 01-31-14

A2LA DoD ELAP 2928-01 01-31-14

Alaska (UST) State Program 10 UST-055 12-18-13

Arizona State Program 9 AZ0708 08-11-14

Arkansas DEQ State Program 6 88-0691 06-17-14

California NELAP 9 1119CA 01-31-14

Connecticut State Program 1 PH-0691 06-30-15

Florida NELAP 4 E87570 06-30-14

Guam State Program 9 N/A 08-31-14

Hawaii State Program 9 N/A 01-31-14

Illinois NELAP 5 200060 03-17-14

Kansas NELAP 7 E-10375 10-31-14

Louisiana NELAP 6 30612 06-30-14

Michigan State Program 5 9947 01-31-14

Nebraska State Program 7 NE-OS-22-13 01-31-14

Nevada State Program 9 CA44 07-31-14

New Jersey NELAP 2 CA005 06-30-14

New York NELAP 2 11666 04-01-14

Northern Mariana Islands State Program 9 MP0007 02-01-14

Oregon NELAP 10 CA200005 03-28-14

Pennsylvania NELAP 3 68-01272 03-31-14

South Carolina State Program 4 87014 06-30-14

Texas NELAP 6 T104704399-08-TX 05-31-14

US Fish & Wildlife Federal LE148388-0 12-31-13

USDA Federal P330-11-00436 12-30-14

USEPA UCMR Federal 1 CA00044 11-06-14

Utah NELAP 8 QUAN1 01-31-14

Washington State Program 10 C581 05-05-14

West Virginia State Program 3 9930C 12-31-13

Wyoming State Program 8 8TMS-Q 01-31-14


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Method SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Method Method Description LaboratoryProtocol

SW8468260B/CA_LUFTM

S

Volatile Organic Compounds by GC/MS TAL SAC

SW8468015B Diesel Range Organics (DRO) (GC) TAL SAC

SW8469056 Anions, Ion Chromatography TAL SAC

EPA6850 Perchlorate by LC/MS or LC/MS/MS TAL SAC

SW8468321A Benzene Sulfonic Acids (LCMS) TAL SAC

TestAmerica SOPGCMSMS_NDMA Nitrosamines by Isotope Dilution and GC/CI/MS/MS TAL SAC

ASTMD 2216 Percent Moisture TAL SAC

Protocol References:

ASTM = ASTM International

EPA = US Environmental Protection Agency

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

TestAmerica SOP = TestAmerica, Inc., Standard Operating Procedure

Laboratory References:

TAL SAC = TestAmerica Sacramento, 880 Riverside Parkway, West Sacramento, CA 95605, TEL (916)373-5600


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Sample SummaryTestAmerica Job ID: 320-4479-1Client: CH2M Hill Constructors, Inc.


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

320-4479-1 EPAZ5S8AS00 Solid 10/08/13 11:25 10/09/13 09:00

320-4479-2 EPAZ5S8AS03 Solid 10/08/13 11:45 10/09/13 09:00

320-4479-3 EPAZ5S8AS3 Water 10/08/13 13:30 10/09/13 09:00

320-4479-4 EPAZ5S8BS00 Solid 10/08/13 08:30 10/09/13 09:00

320-4479-5 EPAZ5S8CS00 Solid 10/08/13 09:50 10/09/13 09:00

320-4479-6 EPAZ5S8CS03 Solid 10/08/13 10:00 10/09/13 09:00

320-4479-7 EPAZ5S8CS13 Solid 10/08/13 10:05 10/09/13 09:00

320-4479-8 EPAZ5S8DS00 Solid 10/08/13 10:35 10/09/13 09:00

320-4479-9 EPAZ5S8DS03 Solid 10/08/13 10:40 10/09/13 09:00

320-4479-10 EPAZ5SMW4S00 Solid 10/08/13 07:05 10/09/13 09:00

320-4479-11 EPAZ5SMW4S03 Solid 10/08/13 07:10 10/09/13 09:00

320-4479-12 EPAZ5SMW4S08 Solid 10/08/13 08:05 10/09/13 09:00


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Login Sample Receipt Checklist

Client: CH2M Hill Constructors, Inc. Job Number: 320-4479-1

Login Number: 4479

Question Answer Comment

Creator: Hytrek, Cheryl

List Source: TestAmerica Sacramento

List Number: 1

TrueRadioactivity wasn't checked or is </= background as measured by a survey

meter.

TrueThe cooler's custody seal, if present, is intact.

N/ASample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or

tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded.

TrueCOC is present.

TrueCOC is filled out in ink and legible.

TrueCOC is filled out with all pertinent information.

N/AIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time.

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

N/ASample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested

MS/MSDs

TrueContainers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.


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ANALYTICAL REPORTThe high-biased CCV in the original run sequence was clearly due to carry over from...

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Transcript of ANALYTICAL REPORTThe high-biased CCV in the original run sequence was clearly due to carry over from...