ANALYTICAL INNOVATION : SENSORS TRENDS AND NEEDS FOR … · LC. GC. SIA . Particle Size. Viscosity....

Renewable energies | Eco-friendly production | Innovative transport | Eco-efficient processes | Sustainable resources

FBA – IFP Energies nouvelles – CEA-CETAMA – "Nuclear analytical chemistry : New challenges and future trends" – Montpellier 26th may 2011

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ANALYTICAL INNOVATION : SENSORS

TRENDS AND NEEDS FOR ON LINE MICRO ANALYSIS FOR R&D

INNOVAL : INNOVATIVE PROJECT FOR MICRO PROCESS ANALYTICAL TECHNOLOGY

Dr. Franck BACO-ANTONIALIIFP Energies nouvellesBP3, 69360 Solaize, [email protected]


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Agenda

Introduction

Trends and needs for R&D on line micro analysis

INNOVAL Project

Technologic platform INDEED – AXEL'One :An collaborative platform

Conclusions and outlooks


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L’analyse des procédés: un enjeu pour l'industrie chimique

PRODUCTION

Products Quality

Safety of employees

and neighborhood

Environment protection

(pollution)

R&D

Reduction of costs

Process intensification

ANALYSIS = PROCESS CONDITIONS CONTROLS

Objective


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> Quality of the analysis

> Sampling safety

> Wastes management

> Installation cost ($ € )

>Energy consuming systems

Analysis

in the "heart

of

process"

Sampling loop

The future for industrial on line analysis : in situ analysis


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Evolution of needs in term of analyzers in R&D

μ Pilots HTE Pilots Process Intensification

Reducing of sample volume

"Classical" analyzers

μ

Analyzers

μCaptors


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• Employ more compact analyzers to be able to analyze in the heart of process "bring the analyzer to the sample"

• Reduce time of experimentation - Increase the number of tests in the same time

we needSmart analyzers to follow process stabilization, product quality, process control , ...

•Excellent repeatability, accurate systems, good accordance with standard methods, ...

Needs for R&D

and Process Intensification


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Next generation of analyzers:- compacts (micro analyzers, micro captors) - coupling with sampling microsystems- directly integrated in the process

>> Analysis at the closest of the reaction

New Standard (SP76)NeSSI TM

New Sampling and Sensor Initiative from

CPAC

PROBLEMATIC

> Difficulties of direct implementation on industrial sites and R&D laboratories

‐

Unsatisfactory accordance between analyzers and industrials and

R&D needs

‐ Some laboratories techniques are not always available for in situ application

Problematic


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Evolution of NeSSI

Gen III

Miniature/Modular (enabled by Mechanical Standard)

Smart Devices (enabled by Communication Standard)

Micro Analytical(enabled by Technology Advances)

End UserValue

Gen II

Gen I


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Programmable Substrate Heater

NeSSI “Sandwich”

concept

Ethernet LAN

Analyzer

ControllerV

A

P F

SAM

CANbus

PDA

Auxiliary Heating/Cooling

SubstrateT

T

Standard Sampling Interface

dcs o&m user

Standard Connectivity

Interface

Development Focus can be on Sensors !

R. Dubois, Dow


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What is NeSSI?


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The NeSSI Platform Will Also Become the Base for a Micro-Analytical Lab

NMRMSNIRRAMANLCGCSIA Particle SizeViscosityMoistureConductivityMass FlowEtc.


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Needs

Need to employ more compact analyzers to be able to analyze "in the heart of process"

Properties Molecular Properties Molecular

Analysis in liquids Analysis in gasesElementary analysis


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Elementary AnalysisIn situ analysis of elements in industrial liquids

traces of S, Ni & V in petroleum productstraces analysis of contaminants in ex biomass and chemical products, ...traces analysis of contaminants in waterfollowing of corrosion (traces of metals)...

Laser Induced Breakdown Spectroscopy


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IVEA –

SOLUTION

Development of LIBS on NeSSI platform


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Analysis in liquids -

Properties

In situ analysis of elements in industrial liquids

in situ density, viscosity analysis of liquids with μsystemsin situ refractive index analysis with μsystemsparticles analysis in liquid (solid, catalyst, macromolecules, ...)calculation of other properties using μspectrometers

Adaptation in function of specific needsSpecific developments


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Analysis in liquids -

Properties Example of In situ density with

AVENISENSE µdensimeter Response

to a periodic

feed

change

23

23.5

24

24.5

25

25.5

26

26.5

27

31/1/08 11:15 31/1/08 11:18 31/1/08 11:21 31/1/08 11:24 31/1/08 11:26 31/1/08 11:29 31/1/08 11:32 31/1/08 11:35 31/1/08 11:38 31/1/08 11:41

Time

Tem

pera

ture

(°C)

0.8405

0.8415

0.8425

0.8435

0.8445

0.8455

0.8465

0.8475

0.8485

0.8495

0.8505

dens

ity

(g/c

m3 )

T captor (°C)

Raw density

Corrected density

Gasoil A Gasoil A Gasoil A

Gasoil B Gasoil B

less than 30s – Flow 2ml/min

difference (A-B) 0.0006 g/cm3


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In situ analysis in different industrial liquids

in situ analysis with μspectrometric methods (miniaturized systems), using in situ probes

Development and performance optimization

in situ analysis of dissolved gases (traces) in hydrocarbons (H2, O2, ...)

optimization of liquid injection systems for on line GC analysis

in situ analysis of liquid by μGC (at the moment only used for gas analysis)...

Analysis in liquids-

Molecular Analysis

min0 20 40 60 80 100

pA

10

15

20

25

30

35

40

45

FID1 A, (D:\DOCUMENTS AND SETTINGS\JACQUINE\BUREAU\ETUDE HPLIS\DATA\P20BARS\001F0101.D)

PIC

1

PIC

2

PIC

3

PIC

4


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NIR mini spectrometer


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On line dissolved

O2

in Liquid


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In situ analysis in different industrial gases

in situ analysis with μspectrometric methods using in situ probes

Development en optimization of performances

Optimization of Tunable Diode Laser for specific applications

Optimization of sensors Density, moisture, H2, ...

Analysis in corrosive environments (HF, HCl, ...)

Analysis in gases -

Properties and Molecular

Analysis

TDL


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Analysis in gases -

Properties Example of in situ density in gas phase in µPilot: total gas

flow 1l/h

density 1200

0

200

400

600

800

1000

1200

1400

23/0413:12

23/0418:00

23/0422:48

24/0403:36

24/0408:24

24/0413:12

24/0418:00

24/0422:48

25/0403:36

25/0408:24

25/0413:12

25/0418:00

25/0422:48

26/0403:36

26/0408:24

26/0413:12

26/0418:00

26/0422:48

27/0403:36

27/0408:24

27/0413:12

27/0418:00

27/0422:48

28/0403:36

28/0408:24

28/0413:12

28/0418:00

28/0422:48

29/0403:36

29/0408:24

29/0413:12

29/0418:00

29/0422:48

30/0403:36

30/0408:24

30/0413:12

30/0418:00

Date & Hour

Den

sity

(g/m

3)

GC analysisDensity (g/m3) at 15°C

CPG analysis for calculate gas density

Put to atmospheric presure of gas/liquid pot duringliquid sampling

No flow - Pilot's problem

Start Pilot

We are able to follow the "real life" of processBetter knowledge for R&D development


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At

line GC's

with

NeSSI

compatability


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At

line GC's

with

NeSSI

compatability

C2V SLS


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Kaiser Airhead

Raman Gas

Probe


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How to answer

to the needs

for Micro Analysis?

Micro Analysis Needs Collaborative project

USERSRequest ‐

Validation

LABORATORIESResearch

INSTRUMENTALISTSDevelopment & Industrialization

INNovAL Project


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Targets:

-Development of new in situ on line analyzers in accordance with industrial and R&D needs

> On the cutting

edge

of technology

-Optimization

available technologies presents on the market

-Development of new and innovating

solutions

INNovAL Project (AXELERA)"L'Analyse en Ligne au cœur du procédé"


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Skids

for development

of on line applications –

Evaluation in real conditions


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INNOVAL – Main Actors

USERSRequest ‐

Validation


INSTRUMENTALISTSDevelopment & Industrialization


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First innovative collaborative technological platform in Lyon

INDEED (2013)National Institute for the Development of Ecotechnology and Decarbonized Energy

INNovAL – A structuring project

USERSRequest ‐

Validation


INSTRUMENTALISTS

Development & Industrialization

INNovALINDEED


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Conclusion & outlooksIn R&D we need μanalyzers to intensify and optimize research productivity and results quality

Increase the links between industrials, academic laboratories and instrumentalists to develop new analytical solutions in accordance with real industrial needs

INNOVAL project

Need to employ an innovative collaborative platform in order to develop & evaluate analytical instruments : pre industrialization before implementation on site

Platform INDEED


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Lyon : Center of Excellence for "Industrial Analysis" in AXELERA

Academics laboratories in UCBLLaboratories in CNRS/SCAEcole des Mines de St. Etienne

in all laboratories : teams, evaluation benchesanalyzers, ....

In INDEED platformlaboratories for industrial experimentations,

Industrial users (Industrial partners : INnovAL, others)

Project of training in UCBL (Master II) specialized in "IndustrialAnalysis"


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Lyon : Center of Excellence for "Industrial

Analysis" in AXELERA

Reseach

laboratories

–

Industrial

laboratories

-

Training


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Thank you

Dr. Franck BACO-ANTONIALIIFP Energies nouvellesBP3, 69360 Solaize, [email protected]

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Renewable energies | Eco-friendly production | Innovative transport | Eco-efficient processes | Sustainable resources

www.ifpenergiesnouvelles.com

ANALYTICAL INNOVATION : SENSORS TRENDS AND NEEDS FOR … · LC. GC. SIA . Particle Size. Viscosity....

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Transcript of ANALYTICAL INNOVATION : SENSORS TRENDS AND NEEDS FOR … · LC. GC. SIA . Particle Size. Viscosity....